Nitrogen-containign Silicon Compound Patents (Class 528/22)
  • Patent number: 9963596
    Abstract: The invention relates to an antimicrobial coating composition formed by admixing choline bitartrate or choline chloride, an aminopropyltrialkoxysilane and water. This coating composition is preferably sprayed onto a surface and allowed to dry. Preferably the surface is a stainless steel surface. The coating reduces the amount of E. Coli on the surface of the substrate.
    Type: Grant
    Filed: February 14, 2017
    Date of Patent: May 8, 2018
    Assignee: ALLIED BIOSCIENCE, INC.
    Inventors: Daniel Moros, Craig Grossman, Gavri Grossman
  • Patent number: 8859674
    Abstract: A moisture-curable resin composition comprising (a) at least one moisture-curable polymer having at least one hydrolysable silyl group; (b) at least one hydrocarbylalkoxysilane; and (c) at least one silane adhesion promoter containing a glycidoxy group. The composition may also contain additives including a catalyst for catalyzing the reaction between the moisture-curable polymer having at least one hydrolysable silyl group (a) with water under curing conditions, a filler, a plasticizer, and combinations thereof. The moisture-curable resin composition is useful in the production of adhesives, sealants and coatings for use in primerless concrete applications.
    Type: Grant
    Filed: March 31, 2011
    Date of Patent: October 14, 2014
    Assignee: Momentive Performance Materials Inc.
    Inventors: Misty Huang, Jeries Nesheiwat
  • Patent number: 8852844
    Abstract: There is disclosed a thermosetting composition for forming a silicon-containing film to form a silicon-containing film formed in a multilayer resist process used in lithography, including at least (A) a silicon-containing compound obtained by hydrolyzing and condensing a hydrolyzable silicon compound using an acid as a catalyst, (B) a thermal crosslinking accelerator (C) a monovalent or bivalent or more organic acid having 1 to 30 carbon atoms, (D) trivalent or more alcohol and (E) an organic solvent. There can be provided a composition for a silicon-containing film which can form a good pattern in a photoresist film, can form a silicon-containing film for an etching mask having a good dry etching resistance, can give a good storage stability and can be delaminated with a solution used in a delamination process in a multilayer resist process used for lithography, a substrate on which the silicon-containing film is formed, and further a method for forming a pattern.
    Type: Grant
    Filed: August 10, 2009
    Date of Patent: October 7, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Tsutomu Ogihara, Takafumi Ueda, Toshiharu Yano
  • Patent number: 8846844
    Abstract: The present invention relates to a polyolefin composition comprising (A) a crosslinkable polyolefin with hydrolysable silane groups which upon hydrolysation form an acid or a base, characterised in that the acid or base generates a gel content of at least 40% after 40 hours in the 90° C. cross-linking test, wherein the acid or base is added in an amount of 4.5 mmol/kg to an ethylene/vinyltrimethoxysilane copolymer with a MFR2=2 g/10 min, a density of 923 g/cm3, and 2 wt. % of vinyltrimethoxysilane and then is cross-linked in a waterbath at 90° C., and to a polyolefin composition comprising (i) a crosslinkable polyolefin with hydrolysable silane groups, and (ii) a non-polymeric compound with hydrolysable silane groups which upon hydrolysation form an acid or a base, characterised in that the acid or base generates a gel content of at least 40% after 40 hours in the 90° C. cross-linking test, wherein the acid or base is added in an amount of 4.
    Type: Grant
    Filed: May 14, 2010
    Date of Patent: September 30, 2014
    Assignee: Borealis AG
    Inventors: Kristian Dahlen, Roger Carlsson
  • Patent number: 8829143
    Abstract: Storage-stable reactive inorganic clusters and a process for preparing such storage-stable reactive inorganic clusters (e.g., silica structures) having, for example, reactive amino groups. The storage-stable reactive inorganic clusters may be used as a curing agent for thermosetting resin compositions such as epoxy resins.
    Type: Grant
    Filed: April 29, 2010
    Date of Patent: September 9, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Hynek Benes, Jean-Francois Gerard, Ludovic Valette
  • Patent number: 8658738
    Abstract: A curable resin composition, comprising 100 parts by mass of a (meth)acrylic polymer (A) having, at a terminal thereof, at least one crosslinkable silyl group; 0.1 to 100 parts by mass of a diamine compound (B) having a monovalent or bivalent aliphatic or alicyclic hydrocarbon group that has 8 or more carbon atoms and may be branched and having at least one primary amino group; and 0.1 to 100 parts by mass of a diamine compound (C) having a monovalent aliphatic or alicyclic hydrocarbon group that has 8 or more carbon atoms and may be branched, and having a crosslinkable silyl group and/or a (meth)acryloyl group.
    Type: Grant
    Filed: June 24, 2009
    Date of Patent: February 25, 2014
    Assignee: Kaneka Corporation
    Inventors: Jun Kotani, Nobuyuki Kobayashi, Hiroyuki Hosoda, Kazunori Ishikawa
  • Patent number: 8399575
    Abstract: The invention relates to materials which are based on organosilicon compounds, are storable with exclusion of water and are crosslinkable to elastomers on ingress of water at room temperature, which comprise organic acids and basic nitrogen or basic phosphorus, to processes for preparation thereof and to moldings produced therefrom.
    Type: Grant
    Filed: September 12, 2011
    Date of Patent: March 19, 2013
    Assignee: Wacker Chemie AG
    Inventor: Marko Prasse
  • Patent number: 8372257
    Abstract: A suspension type electrodeposition coating composition containing, as a resin component, block copolyimide having a siloxane bond in a molecular structure and an anionic group in a molecule. Preferably, the above-mentioned block copolyimide contains, as one of the diamine components, diamine having a siloxane, bond in a molecular structure. In addition, preferably, the above-mentioned anionic group is a carboxylic acid group or a salt thereof and/or a sulfonic acid group or a salt thereof. The electrodeposition coating composition has superior heat resistance, which does not easily develop peeling and cracks in the electrodeposited body, and is capable of efficiently forming a high-insulation electrodeposited film superior in the uniformity of film property.
    Type: Grant
    Filed: May 7, 2008
    Date of Patent: February 12, 2013
    Assignees: Mitsubishi Cable Industries, Ltd., PI R&D Co., Ltd.
    Inventors: Masanori Fujii, Toshihiro Zushi, Hiromasa Honjo, Toyokazu Nagato, Maw Soe Win, Shintaro Nakajima, Toshiyuki Goshima, Kiyoshi Ishii
  • Patent number: 8318258
    Abstract: Silsesquioxane resins useful in antireflective coatings wherein the silsesquioxane resin has the formula (PhSiO(3?x)/2(OR?)x)m(HSiO(3?x)/2(OR?)x)n(MeSiO(3?x)/2(OR?)x)o(RSiO(3?x)/2(OR?)x)p(R2SiO(3?x)/2(OR?)x)q where Ph is a phenyl group, Me is a methyl group; R is selected from a sulfur-containing organic functional group; R? is hydrogen atom or a hydrocarbon group having from 1 to 4 carbon atoms; R2 is selected from ester groups, polyether groups; and polyethylene oxide groups; x has a value of 0, 1 or 2; m has a value of 0.01 to 0.97; n has a value of 0.01 to 0.97; o has a value of 0.01 to 0.97; p has a value of 0.01 to 0.97; q has a value of 0 to 0.96; and m+n+o+p+q?1.
    Type: Grant
    Filed: December 5, 2008
    Date of Patent: November 27, 2012
    Assignee: Dow Corning Toray Co., Ltd.
    Inventor: Akihiko Shirahata
  • Patent number: 8293810
    Abstract: A resin composition suited for rapid prototyping is provided comprising (I) an actinic energy radiation-curable silicone composition, (II) an actinic energy radiation-sensitive polymerization initiator, and (III) an actinic energy radiation absorber. The resin composition experiences little viscosity buildup and maintains fluidity during long-term storage at elevated temperature, and is effective in rapid prototyping or shaping by stereolithography using any actinic energy radiation.
    Type: Grant
    Filed: August 29, 2005
    Date of Patent: October 23, 2012
    Assignees: Cmet Inc., Shin-Etsu Chemical Co., Ltd.
    Inventors: Takashi Ito, Tsuneo Hagiwara, Toshiyuki Ozai, Takeshi Miyao
  • Publication number: 20110046299
    Abstract: The invention relates to novel compounds with a guanidine structure, and more particularly nontoxic compounds with a silylated guanidine structure.
    Type: Application
    Filed: December 18, 2008
    Publication date: February 24, 2011
    Applicant: BlueStar Silicones France
    Inventors: Christian Maliverney, Laurent Saint-Jalmes
  • Patent number: 7803895
    Abstract: A novel organosilicon polymer, the main chain of which is composed of siloxane units and silalkylene units and to which are bonded organic groups with amide bonds linked to silicon atoms of the molecule.
    Type: Grant
    Filed: November 2, 2006
    Date of Patent: September 28, 2010
    Assignee: Dow Corning Toray Company, Ltd.
    Inventors: Masaru Ozaki, Shinya Oguri, Yasue Mizutani
  • Patent number: 7767774
    Abstract: This invention relates to a novel polymerization initiator capable of introducing an active amino proton into a polymerization starting terminal without losing polymerization activity, and a novel modified conjugated diene polymer being excellent in the interaction with a filler and capable of improving a low heat buildup of a rubber composition, and more particularly to a polymerization initiator being a diamine compound in which one amino group is protected with a silylating agent and an active proton of the other amino group is replaced with an alkali metal or an alkaline earth metal, and a modified conjugated diene polymer which can be produced by using such a polymerization initiator and is a homopolymer of a conjugated diene compound or a copolymer of a conjugated diene compound and an aromatic vinyl compound and has a residue derived from a diamine compound at its polymerization starting terminal.
    Type: Grant
    Filed: March 17, 2005
    Date of Patent: August 3, 2010
    Assignee: Bridgestone Corporation
    Inventors: Eiju Suzuki, Yoichi Ozawa
  • Patent number: 7695651
    Abstract: A flame retardant additive comprises (A) a gassing agent which is a compound containing both phosphorus and nitrogen, typically ammonium polyphosphate, which is surface coated with (B) a silicone-base water repellent treating agent comprising a co-hydrolytic condensate obtained through co-hydrolytic condensation of (i) an organosilicon compound and (ii) an amino group-containing alkoxysilane or a partial hydrolyzate thereof in the presence of an organic or inorganic acid. The additive is improved in moisture absorption resistance and dispersion and suited for use in resins or elastomers.
    Type: Grant
    Filed: February 15, 2005
    Date of Patent: April 13, 2010
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Kazuyuki Matsumura, Akira Yamamoto, Toshiaki Ihara
  • Patent number: 7531241
    Abstract: An object of the present invention is to provide a coating agent capable of giving a coating film having excellent adhesion to the base surface, and exhibiting excellent releasability with good surface lubricity.
    Type: Grant
    Filed: September 5, 2006
    Date of Patent: May 12, 2009
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Yoshinori Inokuchi
  • Publication number: 20080275194
    Abstract: Organopolysiloxanes having aminoalkyl groups are prepared by (i) reacting (A) linear, cyclic or branched organopolysiloxanes with (B) aminoalkylsilanes which have an SiC-bonded, basic nitrogen-containing hydrocarbon radical and 2 or 3 hydrolyzable groups, ?or the partial or complete hydrolysis products thereof, optionally in the presence of (C) basic catalysts and/or (D) chain-terminating reagents, and (ii) optionally, after the reaction (i) neutralizing the optionally used basic catalysts (c), with the proviso that compounds (A), (B) and, when used, (D) are reacted continuously in a reaction space whose ratio of length to diameter is equal to or greater than four.
    Type: Application
    Filed: April 29, 2008
    Publication date: November 6, 2008
    Applicant: WACKER CHEMIE AG
    Inventors: Daniel Schildbach, Johann Bindl, Gilbert Geisberger
  • Patent number: 7344811
    Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a polymeric charge transport material having the formula where n and m are each a distribution of integers, and the n units of R1—Si—X1—Ar1 and m units of R2—Si—X2—Ar2—X3-Z form either a random, an alternative, or a block copolymer; R1 and R2 comprise, each independently, an alkyl group, an alkoxy group, an alkenyl group, an alkynyl group, a heterocyclic group, or an aromatic group; X1, X2, and X3 comprise, each independently, a bond or a linking group; A1 and A2 are each a terminal group; Ar1 and Ar2 comprise, each independently, an aromatic group; and Z comprises a functional group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, imaging methods, and methods of preparing the polymeric charge transport material are described.
    Type: Grant
    Filed: October 28, 2004
    Date of Patent: March 18, 2008
    Assignee: Samsung Electronic Co., Ltd.
    Inventors: Asta Michaleviciute, Gintaras Buika, Juozas V. Grazulevicius, Zaimantas Peleckas, Edmundas Montrimas, Jonas Sidaravicius
  • Patent number: 7332541
    Abstract: Condensation curable systems employ ordinarily highly reactive polymers bearing methylene-linked alkoxysilyl groups. By limiting the amounts of activating compounds during the preparation of such polymers, the reactivity is sharply decreased, yet can be increased by addition of suitable catalysts. As a result, the polymers may be easily processed, yet the moisture curing times may be adjusted readily.
    Type: Grant
    Filed: August 7, 2003
    Date of Patent: February 19, 2008
    Assignee: Wacker Chemie AG
    Inventors: Wolfram Schindler, Volker Stanjek
  • Publication number: 20070260010
    Abstract: Organosilicon compounds containing urethane groups are prepared by reacting aminofunctional organosilicon compounds containing at least one siloxane unit AR a ? SiO 3 - a 2 ( I ) per molecule and at least two siloxane units of the formula XR b ? SiO 3 - b 2 ( II ) in which R are monovalent, optionally substituted C1-18 hydrocarbon radicals, A is a radical —R1(—NR2—R1)z—NR2—H, ??(III) where R1 is a divalent C1-18 organic radical, R2 is a hydrogen atom or C1-18 hydrocarbon radical, X is a group capable of condensation, a is 0 or 1, b is 1 or 2, z is 0 or an integer from 1 to 10, are reacted with organic carbonates (2) containing a group of the formula —O—C(?O)O—, ??(IV) and, in a second stage, the first stage reaction products are optionally condensed with silanes (3) bearing groups capable of condensation, to give higher molecular weight organosilicon compounds containing urethane groups.
    Type: Application
    Filed: May 3, 2007
    Publication date: November 8, 2007
    Applicant: WACKER CHEMIE AG
    Inventor: Christian Herzig
  • Patent number: 7195720
    Abstract: The invention provides a curable composition for a heat conductive material, having an excellent durability, a satisfactory heat conductive property and a high productivity with easily controllable surface tackiness, a heat conductive material obtained from such curable composition and a method for controlling the surface tackiness of the composition after curing. The curable composition for the heat conductive material is formed by a curable composition of heat curable type based on crosslinking by a hydrosilylation reaction and including a saturated hydrocarbon polymer containing at least an alkenyl group in a molecule, a curing agent containing at least two hydrosilyl groups in a molecule and a hydrosilylation catalyst, to which a heat conductive filler is incorporated, thereby providing a flexible elastomer with a satisfactory heat conductivity and with an easily controllable surface tackiness.
    Type: Grant
    Filed: February 11, 2003
    Date of Patent: March 27, 2007
    Assignee: Kaneka Corporation
    Inventor: Masashi Sakaguchi
  • Patent number: 7189781
    Abstract: Sealant composition comprising at least one of a) a moisture curable, radiation curable polyurethane prepolymer or b) a blend comprising a moisture curable polyurethane prepolymer and a radiation curable prepolymer. Also disclosed are insulating glass assemblies that use such dual-cure sealant compositions.
    Type: Grant
    Filed: March 13, 2003
    Date of Patent: March 13, 2007
    Assignee: H.B. Fuller Licensing & Finance Inc.
    Inventors: Margarita Acevedo, Mai T. Nguyen-Misra
  • Patent number: 7011452
    Abstract: A rolling bearing with shield plate comprises an outer ring having an outer ring raceway and a circumferential anchor groove, the anchor groove provided at an axial end portion separated from the outer ring raceway and having an outside facing side surface, an inner ring having an inner ring raceway, a plurality of rolling members between the outer ring raceway and the inner ring raceway, and a shield plate in a generally circular ring shape provided with an inside facing, radially outer portion and an outer peripheral edge portion which is anchored in the anchor groove of the outer ring, the shield plate having an elastic seal member attached generally circumferentially and radially inner than the outer peripheral edge portion of the shield plate, such that the seal member is elastically held between the shield plate and the anchor groove.
    Type: Grant
    Filed: January 30, 2004
    Date of Patent: March 14, 2006
    Assignee: NSK Ltd.
    Inventors: Hironori Suzuki, Takamasa Itsu, Hiroyuki Osawa, Takahiko Uchiyama
  • Patent number: 6956087
    Abstract: A process for producing polysiloxane prepolymers of improved homogeneity for use in the production of relatively high refractive index polymeric compositions is described herein. Polymeric compositions so produced are useful in the production of ophthalmic devices such as for example intraocular lenses and corneal inlays.
    Type: Grant
    Filed: December 13, 2002
    Date of Patent: October 18, 2005
    Assignee: Bausch & Lomb Incorporated
    Inventors: Yu-Chin Lai, Edmond T. Quinn, Xiaojun Michael Liu, Edmund P. Maziarz, III
  • Patent number: 6943265
    Abstract: The invention relates to a method for the production of hydroxyalkyl polysiloxanes of general formula (V) (SiO4/2)k(R12SiO3/2)m(R12SiO2/2)p(R13SiO1/2)q[O1/2SiR32—(CR42)b—OH]5[O1/2H]t (V), wherein organosiloxanes of general formula (VI) (SiO4/2)k(R1SiO3/2)m(R12SiO2/2)p(R13SiO1/2)q[O1/2H]r(VI) containing silanol are made to react with compounds having at least one unit of general formula (IV) [O—(CR42)b—SiR32]n—(IV).
    Type: Grant
    Filed: February 7, 2002
    Date of Patent: September 13, 2005
    Assignee: Consortium fur Elektrochemische Industrie, GmbH
    Inventors: Oliver Schäfer, Thomas Kammel, Bernd Pachaly
  • Patent number: 6905772
    Abstract: Disclosed are abrasion and impact resistant coating compositions, and substrates coated therewith. These coating compositions provide high abrasion and impact resistance, chemical protection to the substrate, and exhibit enhanced stability to high temperature and high humidity conditions. Coating compositions may also be tailored to provide a balanced combination of abrasion resistance, impact resistance, and weatherability. These coatings may be transparent or not, depending on the intended applications. These coatings may also comprise additives such as UV absorbers, corrosion inhibitors, and electrically conductive materials. Substrates for use herein may be plastic or metal.
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: June 14, 2005
    Assignee: Triton Systems, Inc.
    Inventors: Robert Shoup, Norman Rice, Dorette Simes, Jon Nebo, George T. Georges
  • Patent number: 6830818
    Abstract: A silicone compound, either alone or in combination with a photoacid generator, is added to a branched polysilane compound. According to this constitution, highly reliable polymer material and polymer film can be realized which have excellent stability of refractive index against heat and high transparency and, when the photoacid generator is contained, can cause a change in refractive index upon exposure to ultraviolet light with high sensitivity and high resolution.
    Type: Grant
    Filed: March 22, 2002
    Date of Patent: December 14, 2004
    Assignees: Hitachi Cable, Ltd., Nippon Paint Co., Ltd.
    Inventors: Katsuyuki Imoto, Hiroshi Tsushima, Emi Watanabe
  • Patent number: 6827985
    Abstract: A photocurable silicone composition which includes an additive which provides cure-through-volume of the overall composition. The additive is desirably a curable amino silyl-terminated polyorganosiloxane.
    Type: Grant
    Filed: November 4, 2002
    Date of Patent: December 7, 2004
    Assignee: Henkel Corporation
    Inventors: Michael P. Levandoski, Alfred A. DeCato
  • Patent number: 6790815
    Abstract: The present invention relates to a product of reaction between a primary and/or secondary amine and one or more active ingredients. By the present invention, there is provided a release of the active component over a longer period of time than by the use of the active itself.
    Type: Grant
    Filed: March 31, 2003
    Date of Patent: September 14, 2004
    Assignee: Procter & Gamble Company
    Inventors: Jean-Luc Philippe Bettiol, Alfred Busch, Hugo Denutte, Christophe Laudamiel, Peter Marie Kamiel Perneel, Marie Montserrat Sanchez-Pena, Johan Smets
  • Publication number: 20040073031
    Abstract: The invention relates to a method for the production of hydroxyalkyl polysiloxanes of general formula (V) (SiO4/2)k(R12SiO3/2)m(R12SiO2/2)p(R13SiO1/2)q[O1/2SiR3213 (CR42)b—OH]s[O1/2H]t (V), wherein organosiloxanes of general formula (VI) (SiO4/2)k(R1SiO3/2)m(R12SiO2/2)p(R13SiO1/2)q[O1/2H]r(VI) containing silanol are made to react with compounds having at least one unit of general formula (IV) [O—(CR42)—SiR32]n— (IV).
    Type: Application
    Filed: September 2, 2003
    Publication date: April 15, 2004
    Inventors: Oliver Schfer, Thomas Kammel, Bernd Pachaly
  • Patent number: 6664359
    Abstract: A tackified composition comprising (a) a polydiorgannosiloxane polyurea segmented copolymer comprising the reaction product of (i) at least one polyaminie, wherein the polyamine comprises at least one polydiorganosiloxane diamine, or a mixture of at least one polydiorganosiloxane diamine and at least one organic polyamine, and (ii) at least one polyisocyanate, wherein the mol ratio of isocyanate to amined is between 0.9:1 and 0.95:1 or between 1.05:1 and about 1.3:1, and (b) silicate resins. The tackified compositions are useful as pressure sensitive adhesives, particularly for foamed backing tapes, medical tapes and the like, hot melt adhesives, vibration dampers, anti-corrosive materials.
    Type: Grant
    Filed: October 2, 1997
    Date of Patent: December 16, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Lani S. Kangas, Mieczyslaw H. Mazurek, Kurt C. Melancon, Walter R. Romanko, Audrey A. Sherman
  • Patent number: 6566322
    Abstract: Disclosed are silicone polymer based compounds, which include a hydrophobic silicone polymer backbone and a hydrophilic component. The hydrophilic component may act as a chelating agent to bind a metal. The hydrophilic component may be hydrophilic prior to binding with a metal or after binding. Also disclosed are methods of making these compounds. The compounds are useful in a variety of applications.
    Type: Grant
    Filed: May 26, 2000
    Date of Patent: May 20, 2003
    Assignee: McMaster University
    Inventors: Michael A. Brook, Rodica-Sinziana Himmeldirk
  • Patent number: 6368535
    Abstract: A condensation reaction curable silsesquioxane resin composition and methods for its preparation and cure are disclosed. By modifying the silsesquioxane resin with a silyl-terminated hydrocarbon, such as a silphenylene, the resulting silsesquioxane resin has improved strength and toughness without significant loss of modulus.
    Type: Grant
    Filed: August 6, 1999
    Date of Patent: April 9, 2002
    Assignee: Dow Corning Corporation
    Inventors: Dimitris Elias Katsoulis, Bizhong Zhu
  • Patent number: 6335412
    Abstract: The present invention provides a curable composition comprising a reactive silicon group-containing saturated hydrocarbon polymer which features a high curing rate and a high degree of adhesiveness to various adherends. This invention is relates to a curable composition which comprises (A) a saturated hydrocarbon polymer having at least one silicon-containing group containing a hydroxyl or hydrolyzable group bound to the silicon atom and capable of forming a siloxane bond, (B) a tetravalent tin compound, and (C) a silicon compound of the general formula (1) R1aSi(OR2)4-a   (1) wherein R1 and R2 each independently represents a substituted or unsubstituted hydrocarbon group containing 1 to 20 carbon atoms; a represents any of 0, 1, 2 and 3.
    Type: Grant
    Filed: April 26, 2000
    Date of Patent: January 1, 2002
    Assignee: Kaneka Corporation
    Inventors: Toshihiko Okamoto, Makoto Chiba, Junji Takase
  • Patent number: 6328912
    Abstract: A mixture for stabilizing polyolefins containing A) either (A1) at least one compound of the formula in which R1 is for example C1-C10alkyl; R2 is C3-C10alkylene; R3 is for example hydrogen or C1-C8alkyl; and n1 is a number from 2 to 50; or (A2) a product obtainable by reacting a product—obtained by reaction of a polyamine of the formula in which n2′, n2″ and n2′″ are a number from 2 to 12 with cyanuric chloride—with a compound of the formula wherein R4 is for example hydrogen or C1-C12alkyl; and R5 is as defined for R3 and B) magnesium oxide, magnesium hydroxide, C) zinc oxide, zinc hydroxide or an organic salt of zinc or magnesium, or a hydrotalcite; and at least one of C1) an UV absorber or C2) 2 pigment.
    Type: Grant
    Filed: July 10, 1997
    Date of Patent: December 11, 2001
    Assignee: CIBA Specialty Chemicals Corp.
    Inventor: François Gugumus
  • Patent number: 6214961
    Abstract: A method of producing a branched silicone oil which comprises mixing 100 parts by weight of an organopolysiloxane represented by the following formula (I) and/or an organopolysiloxane represented by the following formula (II) with 0.1 to 100 parts by weight of an organopolysiloxane represented by the following formula (III) and causing these oranopolysiloxanes to undergo condensation and equilibration reactions by heating them in the presence of basic catalysts: wherein R1 and R2 are each a monovalent hydrocarbon group containing 1 to 20 carbon atoms, m is an integer from 3 to 7, and n is an integer of 0 or above; wherein R3 is a monovalent hydrocarbon group containing 1 to 20 carbon atoms, p is a number from 1 to 100, and q is a number from 0 to 100.
    Type: Grant
    Filed: November 27, 1998
    Date of Patent: April 10, 2001
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Yoshitaka Aoki
  • Patent number: 6020450
    Abstract: A room temperature curable fluoropolymer composition is provided which comprises (A) a straight chain fluoropolymer compound containing, in its backbone chain, at least one structure selected from a perfluoroalkylene structure and a perfluoropolyether structure and having a hydrolyzable silyl group at both ends of its molecular chain, (B) an organic compound having at least one carbonyl group per molecule, and (C) one compound selected from (C-1) an organic compound having at least one primary amino group per molecule and (C-2) a compound having at least one proton per molecule and having an acid dissociation constant (pKa) in water of 2 or less. Another room temperature curable composition is also provided which comprises said (A) component, (B') an organosilicon compound having at least two silanol groups per molecule, and (C') a condensation accelerator.
    Type: Grant
    Filed: December 3, 1998
    Date of Patent: February 1, 2000
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Takashi Matsuda, Takafumi Sakamoto, Shinichi Sato, Noriyuki Koike, Yasuo Tarumi, Tsuneo Kimura, Yasushi Yamamoto, Masatoshi Arai
  • Patent number: 5969074
    Abstract: A reaction of perfluoroolefins with bis(silyl) ethers to produce novel partially fluorinated and perfluorinated copolymers and macrocyclic compounds is disclosed.
    Type: Grant
    Filed: May 21, 1993
    Date of Patent: October 19, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: William Brown Farnham, Mario Joseph Nappa
  • Patent number: 5932676
    Abstract: There is provided a liquid coating composition comprising a silicone resin and an acetal or hemi-acetal-containing solvent, which is excellent in storage stability and coating property, and useful for forming a silicon-containing coating film on the surface of a substrate useful for electronic devices, the silicon-containing coating film being satisfactorily used as interlayer insulating films, levelling films and protecting films for semiconductor devices.
    Type: Grant
    Filed: June 16, 1997
    Date of Patent: August 3, 1999
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoshi Taguchi, Yuji Yoshida, Hideki Nezu
  • Patent number: 5789515
    Abstract: A colorant composition has the structure ABXYZ, whereA is an organic chromophore;B is an electrophilic reactive group covalently bonded to A directly or through a linking group;X is a nucleophilic linking group covalently bonding B and YY is a poly(oxyalkylene)-polysiloxane copolymer; andZ is a terminal group for Y.The colorant composition can be prepared from a reactive dye AB which is reacted with XYZ, a poly(oxyalkylene)-polysiloxane copolymer.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: August 4, 1998
    Assignee: Milliken Research Corporation
    Inventor: John D. Bruhnke
  • Patent number: 5777059
    Abstract: The present invention relates to a silicone composition prepared by reacting a mixture of (i) a polyisobutylene compound, (ii) a polyorganosiloxane, (iii) a silicon compound, and (iv) a catalytic amount of a catalyst. The compositions of this invention are resistant to phase separation and are useful as foam control compositions in foam producing systems.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: July 7, 1998
    Assignee: Dow Corning Corporation
    Inventors: Teresa Lynn Datz-Siegel, Kenneth Christopher Fey
  • Patent number: 5760136
    Abstract: A block copolymer comprising siloxane segments, amphoteric monomer units and/or cationic nonomer units, and if necessary monomer units of precursors thereof, and nonionic monomer units, obtained by polymerization in the presence of a special azo group-containing polysiloxane compound is useful as paint resins, coating resins and base materials for hair cosmetics.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: June 2, 1998
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Kazuhiro Kato, Kazushige Muto, Masahiro Sogo
  • Patent number: 5741441
    Abstract: A non-liquid scatter standard for use in nephelometry and turbidimetry systems which comprises a clear silicon rubber gel in which an effective light scattering amount of inorganic particles are suspended. The particles have an index of refraction greater than that of the silicon rubber gel.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: April 21, 1998
    Assignee: Beckman Instruments, Inc.
    Inventors: Richard P. Watts, Jack D. McNeal
  • Patent number: 5688888
    Abstract: Organopolysiloxane oils and gums are produced by the condensation of silanol-terminated organosiloxane in the presence of an effective amount of a peralkylated phosphazene base as a catalyst and at reduced pressure.
    Type: Grant
    Filed: April 8, 1996
    Date of Patent: November 18, 1997
    Assignee: General Electric Company
    Inventors: Frank Steven Burkus, II, Krzysztof Matyjaszewski, Slawomir Rubinsztajn
  • Patent number: 5612438
    Abstract: Novel curable siloxane polymers having integral ultra-violet light absorbers are disclosed which are useful in preparing a variety of commercial silicone products requiring excellent resistance to loss of UV protection due to external forces.
    Type: Grant
    Filed: October 25, 1995
    Date of Patent: March 18, 1997
    Assignee: General Electric Company
    Inventors: William J. Raleigh, Raymond J. Thimineur, James A. Campagna
  • Patent number: 5569688
    Abstract: To a heat-curable silicone rubber composition comprising (a) an organopolysiloxane having at least two alkenyl groups in a molecule, (b) an organohydrogenpolysiloxane having at least two hydrogen atoms in a molecule, and (c) a platinum catalyst is added (d) ammonia or an ammonia precursor so that ammonia or ammonia precursor is present in an amount of 10 to 500 parts by weight of nitrogen per million parts by weight of the total of components (a), (b) and (c) in a cured product of the heat-curable silicone rubber composition. The composition cures into a silicone rubber having minimized compression set without a need for secondary vulcanization.
    Type: Grant
    Filed: October 20, 1994
    Date of Patent: October 29, 1996
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Noriyuki Meguriya, Takeo Yoshida
  • Patent number: 5561174
    Abstract: Disclosed is a liquid epoxy resin composition comprising (A) a liquid epoxy resin, (B) a dimethylpolysiloxane having epoxy groups at its both ends, and (C) a dispersing agent comprising the reaction product of (C-1) a dimethylpolysiloxane having amino groups or carboxyl groups reactive with epoxy resins at its side chains or both ends and having phenyl groups or polyether groups for improving its compatibility with epoxy resins at its side chains, and (C-2) an epoxy resin having the same structure as the component (A). The composition has a reduced internal stress, while maintaining the heat resistance intrinsic to epoxy resins, and has excellent resistance, crack resistance and heat shock resistance.
    Type: Grant
    Filed: September 29, 1995
    Date of Patent: October 1, 1996
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Yoshinori Saito, Masaaki Hirayama, Shunjiro Imagawa, deceased
  • Patent number: 5561176
    Abstract: A process for treating fillers, preferably precipitated silica, to improve the physical property profile of heat curable and room temperature vulcanizable silicone rubbers and a composition for room temperature vulcanizable rubbers comprising the silica filler treated by the process of the invention.
    Type: Grant
    Filed: September 7, 1995
    Date of Patent: October 1, 1996
    Assignee: General Electric Company
    Inventors: Theresa A. Garafalo, Robert A. Smith
  • Patent number: 5534608
    Abstract: Linear triorganosiloxy-terminated polydiorganosiloxanes having a silanol content of less than about 200 ppm are prepared by condensing linear higher molecular weight polydiorganopolysiloxanediols having one Si-bonded hydroxyl group in each terminal unit and a silanol content of preferably greater than about 1000, in two separate stages, one using a fixed bed of a solid form of a conventional equilibration catalyst, and the other using a condensation/disproportionation catalyst, e.g., a phosphonitrilic halide or an oligomer thereof or a reaction product thereof with water, an alcohol, an acid, or a siloxane or silane, until the polydiorganosiloxane has reached the desired low content of silanol groups, e.g., below 200 ppm, by weight. The two stages can be carried out in either order, and a conventional monofunctional chain terminating agent can be present in either or both stages. The process preferably does not increase the cyclic byproduct content.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: July 9, 1996
    Assignee: General Electric Company
    Inventors: Dennis P. Thompson, Patricia P. Anderson, Donald Slick
  • Patent number: 5527578
    Abstract: The invention relates to a radiation curable release coating composition comprising:(a) from about 0.05 to about 25 percent by weight of polymer selected from the group consisting of polymers falling within the general formula: ##STR1## and mixtures thereof, wherein: X are monovalent moieties having ethylenic unsaturation which can be the same or different;Y are divalent linking groups which can be the same or different;D are monovalent moieties which can be the same or different selected from the group consisting of hydrogen, an alkyl group of 1 to about 10 carbon atoms, aryl, and substituted aryl;R are divalent hydrocarbon groups which can be the same or different;R.sup.1 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl;R.sup.2 are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl;R.sup.
    Type: Grant
    Filed: September 12, 1994
    Date of Patent: June 18, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mieczyslaw H. Mazurek, Steven S. Kantner, Albert I. Everaerts
  • Patent number: 5516868
    Abstract: A vinyl copolymer is provided comprising a silanol group-containing (meth)acryl siloxane unit of formula (1): ##STR1## wherein R.sup.1 is hydrogen or methyl, R.sup.2, R.sup.3, and R.sup.4 are independently a monovalent C.sub.1 -C.sub.8 hydrocarbon group or a siloxy group, R.sup.5 is a monovalent C.sub.1 -C.sub.8 hydrocarbon group, n=1 to 12, and a=0 or 1. The vinyl copolymer is prepared by copolymerizing a polymerizable vinyl monomer with a silanol group-containing (meth)acryl siloxane in the presence of a radical initiator or by emulsion polymerizing a polymerizable vinyl monomer with a silanol group-containing (meth)acryl siloxane in an aqueous medium in the presence of a surfactant and a polymerization initiator. The copolymer is blended with a condensation catalyst to form a room temperature curable resin composition which crosslinks in the presence of moisture into a cured coating having weatherability, flexibility, and adherence.
    Type: Grant
    Filed: June 30, 1995
    Date of Patent: May 14, 1996
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshio Yamazaki, Shinichi Morioka, Nobuyuki Syzuki, Ichinobe Shoji