Abstract: Water-soluble formaldehyde-free polycondensation products based on amino-s-triazines with at least two amino groups and glyoxylic acid, which contain as further component at least one amino compound and where the molar ratio of amino-s-triazine to glyoxylic acid to amino compound is 1:0.5 to 6.0:0.1 to 2.0. These polycondensation products are excellently suited as additives for aqueous suspensions of inorganic binders, especially cement, lime and gypsum. Building material mixtures which contain these polycondensation products remain workable for a considerably longer time and, in spite of this, also set more quickly.

Abstract: Flame retardant compositions of this invention are produced by incorporating a partially index (LOI) hydrolyzed amino condensation composition in a more flammable organic material. The partially hydrolyzed amino condensation compounds are produced by heating urea or heating urea with other nitrogen containing compounds that will condensate with or react with isocyanic acid and/or cyanic acid thereby producing an amino condensation compound which is then partially hydrolysis is done by reacting it with a limited amount of water. The partially hydrolyzed amino condensation compounds may be used alone or may be mixed with or reacted with carbonization auxiliaries, aldehydes and fillers to produce a partially hydrolyzed amino condensation composition which is incorporated in more flammable organic compositions such as polyurethanes, polyester resins, epoxy resins, vinyl resins and other resins.

Abstract: Novel substituted urea and oxime carbamate modified amino crosslinking agents, curable compositions containing the same, including curable powder coating compositions, are disclosed. Also disclosed is a novel process for preparing pyrrolidone urea.

Abstract: A process for preparing ashless and low-ash phenolic resole resins having no amine odor, and a process for preparing storage-stable mixtures or premix solutions of phenol-formaldehyde resin and urea or unrea-formaldehyde resins. These processes react phenol and formaldehyde in the presence of an effective catalytic amount of a low-volatile and strongly basic tertiary amino alcohol either alone or in combination with an inorganic base.

Abstract: Cationic urea/formaldehyde resins are obtainable by condensing urea and formaldehyde in a molar ratio of from 1:1.5 to 1:3 in the presence of polymers which contain not less than 1 mol % of polymerized vinylamine units and have Fikentscher K values of from 5 to 300, in an amount of from 5 to 50 g per mole of urea in the end product, where the mixture is first a) precondensed at a pH of from 8 to 14, then acidified and b) condensed at a pH of from 1 to 5 until gel formation begins, c) then from 0.3 to 1.5 moles of formaldehyde are added per mole of urea used, d) post-condensation is carried out and e) the resin solution is subsequently neutralized. The resins thus obtained are used in papermaking as assistants for increasing the dry and wet strength of paper and result in less dulling of the whiteness of the paper.

Abstract: Cationic urea/formaldehyde resins are obtainable by condensing urea and formaldehyde in a molar ratio of from 1:1.5 to 1:3 in the presence of polymers which contain not less than 1 mol % of polymerized vinylamine units and have Fikentscher K values of from 5 to 300, in an amount of from 5 to 50 g per mole of urea in the end product, where the mixture is first a) precondensed at a pH of from 8 to 14, then acidified and b) condensed at a pH of from 1 to 5 until gel formation begins, c) then from 0.3 to 1.5 moles of formaldehyde are added per mole of urea used, d) post-condensation is carried out and e) the resin solution is subsequently neutralized. The resins thus obtained are used in papermaking as assistants for increasing the dry and wet strength of paper and result in less dulling of the whiteness of the paper.

Abstract: A monomeric alkoxymethylated aminoplast crosslinking agent derived from a m-TMI/melamine 1:1 adduct and a process for its preparation is provided. The process comprises contacting melamine with M-TMI, contacting the adduct formed with formaldehyde, and contacting the hydroxymethylated adduct with an alcohol such as butanol. A curable composition comprising the monomeric aminoplast crosslinker and a polyfunctional active hydrogen-containing material is also provided. An improved method of coating using the curable composition to produce cured films or objects is also provided.

Abstract: A new method of preparing a new aminoureaformaldehyde fertilizer composition which exhibits high cold water insoluble nitrogen (CWIN) levels and high Availability Indices (AI). The method utilizes the discoveries that ammonia compounds, usually ammonium salts, inhibit the urea-formaldehyde polymerization reaction and decrease the formation of hot water insoluble nitrogen (HWIN), and that the ammonium compounds take part in the reaction to form controlled release compounds which are both cold water soluble and insoluble. The process is carried out at elevated temperatures between 60 and 125.degree. F., so that it may be completed in an order of magnitude less time than either the dilute or concentrated conventional commercial ureaform processes, requiring between 2 and 20 minutes for completion. In the process, between 3 and 25 percent of the total nitrogen is supplied as ammonia nitrogen with the remainder from urea, respective formaldehyde to urea to ammonia mol ratio is 1.0, between 1.0 and 2.

Abstract: The use of alkoxybenzotriazoles to inhibit the corrosion of metallic surfaces in contact with an aqueous system. Systems and compositions containing alkoxybenzotriazole are also claimed.

Abstract: A process of producing melamine formaldehyde resins using crude or impure melamine is described. The process using the impure or crude melamine includes the control of the pH within the range of from about 8 to 10, and preferably 9 to 9.2 during at least the initial stages of the formaldehyde/melamine reaction. The pH control provides resins having commercially acceptable characteristics, with the cook times of the resin formation also being commercially acceptable.

Abstract: Ths invention relates to an improved method of preparing a solid amino-aldehyde condensation product wherein the solid condensation product precursor solution is fed to the bottom of the reaction vessel.

Abstract: A drilling fluid includes water, bentonite, a weighting agent, and an additive comprising a water-soluble polycondensate containing phosphorous and nitrogen such as phosphorylated-urea-formaldehyde or phosphorylated-melamine-formaldehyde. Such additives provide the desired rheological and filtration loss properties as well as thermal and shear stability. The additives are prepared by reacting phosphorous acid, urea and formaldehyde according to a Mannich-type reaction.

Abstract: A melamine-formaldehyde detackifer having less than 0.15% free formaldehyde comprises a melamine-formaldehyde polymer detackifier to which has been added a formaldehyde scavenging agent comprising an effective amount of urea, and an enhancer selected from glyoxal and acetylacetone. The use of the low free formaldehyde detackifier is also described.

Abstract: This invention relates to ethyleneurea-glutaraldehyde resins, urea-ethyleneurea-glutaraldehyde resins, their synthesis, as well as their application as an adhesive for wood panel manufacture. Molar ratio of ethyleneurea to glutaraldehyde can range from 0.3 to 3.5. Urea incorporated into ethyleneurea-glutaraldehyde resin can be high as two times the moles of glutaraldehyde used in the formulation and can be introduced at any stage during the reaction course, simply post added, or any combination of the above.

Abstract: A raw batch composition for use in making a shaped article such as a foundry shape or refractory article is disclosed. The composition comprises a mixture of an aggregate material; a phenol formaldehyde novolak resin; a phenol formaldehyde resole resin; and an ester functional curing agent. A shaped article prepared from the composition and processes for making a refractory body or foundry article are also disclosed.

Abstract: Low molecular weight urea-formaldehyde reaction products are provided. Such products exhibit cold water solubility. They find use as a sustained nitrogen-release source for animals and plants. A three-stage process is provided for preparing the reaction products. The first stage comprises reacting urea and formaldehyde in an alkaline, alcoholic solution. Then the solvent is distilled off to form a melt. In the final stage the melt is polymerized to form the cold water soluble, low molecular weight reaction product.

Abstract: Urea-formaldehyde resins, particularly useful for producing particle boards having lower rates of release of formaldehyde are synthesized in several stages including a stage of further condensing a first condensate having a F/U molar ratio of 1.8-2.3 and which was condensed at a pH of between 6 and 8. The further condensing is conducted at a pH of between 6 and 8 until a cloud point with water is reached at 10.degree.-40.degree. C. making it possible to obtain resins which are reactive and stable during storage.

Abstract: A glue composition comprises a heat-hardenable resin, urea and possibly one or several glue additives, and is characterized by the presence of an additional gluing compound is polyol having a functionality of at least equal to three. This glue can be used for mineral fibers in the manufacture of insulation products having improved properties.

Abstract: Strongly exothermally setting urea-formaldehyde resin obtained by condensation of urea with formaldehyde under alkaline conditions, obtained by(a) condensation in a first condensation stage I of 0.2 to 0.7, preferably 0.5, moles of urea with 1.2 to 3 moles preferably 1.7 to 2.2, of formaldehyde in the form of solid paraformaldehyde, under exclusively alkaline conditions, at a spontaneuously establishing initial pH of 8 to 12, preferably 9 to 11;(b) in the presence of 1 to 10 mmoles of NaOH and 10 to 80 mmoles of NH.sub.3, orin the presence of 2.5 to 50 mmoles of guanidine base, and 0 to 80 mmoles of NH.sub.3, per mole of formaldehyde;(c) at a condensation temperature (I) of 90 to 110.degree. C.;(d) for a condensation time (I) of 10 to 100 minutes, preferably 15 to 70 minutes;(e) subsequent addition, in a second condensation stage II, of a further 0.2 to 0.7, preferably 0.5, moles of urea;(f) at a condensation temperature (II) of 105 to 120.degree. C.;(g) for a further condensation time (II) of 1.5 to 5 hours.

Abstract: A process and an apparatus for producing a novel polyol polymer is disclosed. The process comrises combining at an elevated reaction temperature and for a predetermined period of time an (1) addition-polymerizable monomer that is also a free-radical initiator together with an (2) ethylenically-unsaturated monomer that has a nucleophilic or an electrophilic moiety. The elevated temperature is so chosen as to be effective for initiating desired "addition copolymerization" of the addition-polymerizable monomer with the ethylenically-unsaturated monomer. The process further comprises combining with the addition-polymerizable monomers, at a preselected superatmospheric pressure, a polymerizable carbonyl carbon-containing ringed molecule.

Abstract: The preparation of aminoplastic resins containing melamine, having very low rates of formaldehyde emission, and being particularly useful for the production of particle boards. In a second stage of the process for preparing the resin, additional NH.sub.2 (melamine and urea) is added to a conventional condensate solution at an increased pH between 6 and 9 so as to lower the F/NH.sub.2 molar ratio to between 0.5 and 0.9. Urea is added in a third stage to obtain an F/NH.sub.2 of between 0.30 and 0.50, with the optional addition of borax.

Abstract: Urea-formaldehyde resins which may be cured to give products having a low total extractable formaldehyde content are prepared by the following process:(i) an aqueous solution containing more than 50% formaldehyde and urea are mixed in a formaldehyde:urea molar ratio of 2-3:1 at pH 6-11,(ii) this mixture is heated to at least 80.degree. C.,(iii) a mineral or organic acid is added to bring the mixture to pH 0.5-3.5,(iv) the mixture is heated at a temperature between 80.degree. C. and the reflux temperature, preferably for 15 minutes to 1 hour,(v) keeping the temperature at or above 80.degree. C., a base is added to bring the mixture to pH 6.5-9 and(vi) urea is added to the mixture at a temperature up to 45.degree. C. until the formaldehyde:urea molar ratio is within the range 0.8-1.8:1.

Abstract: Urea-formaldehyde resins which may be cured to give products having a low total extractable formaldehyde content are prepared by the following process:(i) aqueous 30-50% formaldehyde and urea are mixed in a formaldehyde:urea molar ratio of 2-3:1 at pH 6-11,(ii) this mixture is heated to at least 50.degree. C., preferably to at least 80.degree. C.,(iii) a mineral or organic acid is added to bring the mixture to pH 0.5-3.5,(iv) the mixture is heated at a temperature between 80.degree. C. and the reflux temperature, preferably for 15 minutes to 1 hour,(v) keeping the temperature at or above 80.degree. C., a base is added to bring the mixture to pH 6.5-9 and(vi) urea is added until the formaldehyde:urea molar ratio is within the range 0.8-8:1.In a modification of the process, solid particulate resins are obtained by reacting the mixture from step (v) with urea at a pH below 7 to increase the viscosity thereof, adding a base until the mixture reaches a pH of 6.5-9 and dehydrating the resulting mixture.

Abstract: The present invention provides an improved adhesive composition for wood gluing, comprising a formaldehyde condensation resin and a minor amount of a surface active agent. This invention further provides a method for manufacture of composite wood products comprising applying an adhesive composition, which includes a formaldehyde condensation resin and a small amount of a surface active agent, to the wood and curing the adhesive.

Abstract: Curing aminoplastic resins containing urea and melamine by adding as the curing catalyst, a triazinone derivative.

Abstract: This invention relates to an aqueous solution of water soluble urea-formaldehyde precondensate having a formaldehyde-to-urea (F/U) molar ratio of between about 1.20:1.0 and 1.70:1.0 and to a method for making the precondensate solution by reacting urea and formaldehyde in the presence of acid catalyst in aqueous solution having a pH between about 3.5 and 4.25; then, in neutral to slightly basic solution.

Abstract: Coating compositions comprise a clear, homogeneous binder mixture of polyether or polyester polymer, an amine-formaldehyde condensate resin, and an organic solvent; the mixture being miscible with water to application viscosity. The coating composition typically contains suspended solid particulates, including pigments and metal flakes.

Abstract: Urea-aldehyde polycondensates usable as surface coating binders are obtainable by step-wise reaction of(a) urea and/or urea derivatives with acidic CH aldehydes in a molar ratio of urea:aldehyde of 1:2 in the presence of acids and at from 60.degree. to 120.degree. C. with(b) a mixture of 3 moles of formaldehyde per mole or urea and 3 moles of an acidic CH aldehyde per mole of urea at from 60.degree. to 120.degree. C. with subsequent removal of the water of reaction and treatment of the reaction mixture with an alkali metal alcoholate at from 80.degree. to 100.degree. C.

Abstract: A water-based coating composition comprising as the first component, a mixture of a polyaldehyde chosen from the group consisting of glyoxal, glutaraldehyde and derivatives of glyoxal and glutaraldehyde, and a water dispersible component chosen from the group consisting of epoxy resin emulsions which can be emulsified in water, synthetic latexes stable at about pH 7 or less, low molecular weight resin emulsions, epoxy ester emulsions, water emulsified alkyds, and cationic, anionic and non-ionic asphalt emulsions and, as the second component, the non-gel reaction product of (I) urea-formaldehyde ether monomer, urea-formaldehyde phenol monomer, urea-nonylphenol formaldehyde monomer, thiourea-formaldehyde ether monomer, melamine formaldehyde ether monomer hexamethoxymethyl melamine, with (II) a polyamine chosen from a group consisting of primary and secondary amines and/or a monoamine, combined with (III) a hydroxide or oxide of calcium, strontium or barium.

Abstract: This invention relates to a linear, low-molecular-weight polyester-based polyol having terminal primary hydroxyl groups, low viscosity, high solids content and having the structural formula: ##STR1## where n is 1 or 2 and at least 70% by weight is n=1, and m=2-10, said polyol being substantially free of cyclohexane dimethanol.

Abstract: Novel anionic polymeric hydrogels based on sulfonated amino aldehyde resins and a process for preparing such hydrogels are described. The hydrogels may include poly(N-vinyl 2-pyrrolidone) and other additives. Such hydrogels may be prepared by a four step process in which melamine and/or urea are reacted with formaldehyde, sulfonated, condensed to form a viscous gel and dried.

Abstract: This invention relates to certain linear, low-molecular-weight polyester-based polyols having at least two hydroxyl groups, low viscosity, high solids content and having the structural formula: ##STR1## wherein R is a moiety derived from a saturated aliphatic polyhydric alcohol; n is 1 or 2, and at least about 50% by weight, of n is n=1; p is 0 to 4 inclusive and m is 2 to 10 inclusive; said polyol being substantially free of any unreacted polyhydric alcohol.

Abstract: Aminoplast compositions are cured using a sulfur and phosphorus containing catalyst.

Abstract: A low-formaldehyde binder consists essentially of(A) from 5 to 80% by weight of a water-soluble condensation product of carbonyl number 0-200 which has been prepared by alkaline condensation from 0.1 to 0.4 mole of an aliphatic or cycloaliphatic condensable ketone and 1 mole of formaldehyde, and(B) from 20 to 95% by weight of 4,5-dihydroxyimidazolidin-2-one and/or an unetherified, partially etherified or completely etherified condensation product thereof with an aliphatic monoaldehyde or dialdehyde.

Abstract: An aqueous, resinous solution of a curable, polymeric reaction product, the cured polymeric flame resistant coating and methods for producing them are provided. The solution is formed by direct reaction or prepolymer reaction and chain extension reaction of a methylol and/or hydroxyl-containing quaternary phosphonium compound, divalent nitrogen-containing compound and a heteroatom-containing compound. A nitrogen-containing compound has at least 2 active hydrogen and/or methylol radicals. The direct or prepolymer reaction has present a tertiary amine.

Abstract: A process for producing an inorganic compound-containing urea resin, which comprises adding an acidic gelling agent to an aqueous urea-formaldehyde precondensate solution to prepare a urea resin-containing product, and either(1) mixing the product with a reactant which reacts with the gelling agent to form inorganic particles substantially insoluble in water, or(2) separating the urea resin from the product, mixing the resin-freed mother liquor with such a reactant as stated above, and mixing the resulting inorganic particles with the separated urea resin.

Abstract: This invention is directed to adducts of a poly(active hydrogen) organic compound and a polyepoxide comprising the reaction product of a poly(active hydrogen) organic compound and a polyepoxide containing two or more epoxy groups per molecule, said poly(active hydrogen) organic compound being employed in an amount at least sufficient to effect substantially complete reaction of the epoxy groups of the polyepoxide. The adducts are useful in the formulation of high solids coating compositions, polyurethane elastomers, inks, sealants, adhesives and the like.

Abstract: A process for the manufacture of a solid urea-formaldehyde resin comprises steps (a) to (d). Step (a), the initial reaction step is carried out under specified conditions with an F:U ratio of at least 2.5 to 1. The F:U ratio is lowered by addition of urea in step (c) and water is evaporated without precipitation of the resin in step (d).

Abstract: A fire retardant composition in a stable liquid form comprises the reaction product of an aqueous aldehyde, preferably formaldehyde, solution, at least one alcohol solvent, an alkanolamine, an organic catalyst, ammonium hydroxide, urea and an aqueous phosphoric acid solution. The aldehyde and urea are included in an approximately 1:1 weight ratio. A method of forming the reaction product comprises adding urea to a mixture of aldehyde, alcohol, alkanolamine, organic catalyst and ammonium hydroxide, and heating the resultant mixture to at least 150.degree. F.

Abstract: An amino-formaldehyde moulding composition is made by compounding togetheran aqueous amino-formaldehyde resin solution to provide 0 to 90 percent by weight of the resin component of the composition, filler to make up 20 to 60 percent by weight of the moulding composition andUF resin which had a low degree of condensation, is solid at room temperature, contains a modifier and makes up 4 to 80 percent by weight of the moulding composition.The moulding compositions themselves are also claimed.

Abstract: A process for the preparation of curable etherified aminoplast resins based on urea/aldehyde polycondensates, and the preparation of surface coating resins.Urea is first reacted with an .alpha.,.alpha.-dialkylaldehyde, as much as 50 mol % of which may be replaced by formaldehyde, in a molar ratio urea/aldehyde of about 1:2, at from 50.degree. to 120.degree. C., in the presence of an acid and in the presence or absence of an alcohol or of other organic solvents, and the 2-oxohexahydropyrimidine derivative obtained in this cyclocondensation is then condensed with formaldehyde in the presence of one or more alcohols and an acid.These aminoplast resins are useful as both acid-curable resins and as resins for baking finishes.

Abstract: An aliphatic isocyanate compound containing at least one N-methylene isocyanate group of the formula: ##STR1## formed as a reaction product of isocyanic acid and a compound containing at least one N-alkoxymethyl group of the formula: ##STR2## wherein R is C.sub.1 -C.sub.8 alkyl.

Abstract: Urea and formaldehyde are mixed in a mole ratio of about 1:2. The mixture is condensed for 30 minutes at a pH of 7.0 to 7.4 and a temperature between 80.degree. and 85.degree. C. The condensation is continued at a pH of 4.8 to 5.8 at the same temperature until the viscosity reaches values between 15 and 50 mPa.s. The mole ratio of urea to formaldehyde is adjusted to a value of 1:1.80 to 1:1.90 by adding urea. The condensation is continued under acidic conditions at the same temperature, until the viscosity reaches values of 35 to 80 mPa.s. At a pH of 5.8 to 6.5, the mole ratio of urea to formaldehyde is adjusted to a value between 1.0:1.0 and 1.0:1.30 by adding urea. The temperature is allowed to drop freely. When the temperature has dropped to below 50.degree. C., the pH is adjusted to a value of 7.0 to 8.0.

Abstract: A U.F. foam that is diamensionally stable, but low in formaldehyde, was made by adding to a conventional solution of a urea formaldehyde resin precondensate, before foaming, up to 50% urea, relative to the solid resin substance, and one or several connecting agents from the group of sulfurous alkyl compounds, saturated monobasic carbonic acids, saturated and unsaturated dicarbonic acids, purine compounds, inorganic acids of the group of halogens and chalcogens, and their salts, phosphoric acids and their salts, alkali metal salts and alkaline earth metal salts, in such quantity and in such a way that the pH of the resulting solution remains above 7; and subsequently foaming the solution with a hardener/foaming-agent solution in the conventional manner.

Abstract: A carrier web coated with amino resin wherein at least one surface is resinated is produced by applying a spreadable amino resin dispersion containing 70-90% by weight of amino resin and 30-10% by weight of a liquid dispersant to at least one surface of an uncoated carrier web in an apparatus comprising:(a) unwinding station for unwinding uncoated carrier webs from rotatable supply rolls,(b) means for conveying the uncoated webs comprising a plurality of cooperating pressure rolls rotatably mounted in parallel relationship,(c) a coating means for applying a brushable amino resin dispersion to the web, and(d) a belt press for compression-molding and curing the coated web.

Abstract: Urea-formaldehyde precursors are produced in a two-stage process. In the first stage, urea is slowly added to an acidic solution of formaldehyde at a pH of 1.0 or less, at a rate that maintains the temperature at 50.degree. C. but not in excess of 98.degree. C. When an F/U mole ratio of 3.25:1 to 2.5:1 has been attained, the pH is adjusted to the basic side, generally from about 7.2 to about 8.0. In the second stage, additional urea is added to the condensate produced in the first stage, to attain an F/U mole ratio of 3.0:1 to 2.5:1. The condensate and precursor have fertilizer applications. The precursor is useful in urea-formaldehyde resin production.

Abstract: To obtain a UF foam which is low in formaldehyde, yet is dimensionally stable, up to 96% urea is dissolved in an approximately 10 to 30% aqueous extract of an alkyl, aryl or alkaryl sulphonic acid, said solution being mixed with a conventional hardener/foaming agent solution containing the sodium salt of an alkyl, aryl or alkaryl sulphonic acid in an aqueous diluent usually employed for foaming, in a ratio sulphonic acid solution to sodium sulphonate solution of 1:1 to 1:4, the pH value being adjusted to 0 up to 3 and said mixture being foamed together with a urea formaldehyde resin precondensate solution in the usual manner.

Abstract: The wet fastness properties of direct or reactive dyeings on cellulosic substrates are improved by aftertreatment with an agent comprising(A) a linear or crosslinked polymer comprising repeating units containing at least two quaternary nitrogen atoms linked by bridging groups connected to the quaternary nitrogen atoms by alkylene or arylene groups; optionally(B) an N-methylol derivative of a urea, melamine, guanamine, triazinone, urone, carbamate or acid amide;and, as an essential component,(C) a catalyst for the cross-linking of N-methylol compounds of the type (B) above,and subsequently carrying out a heat-curing step.Certain of the quaternary polymers (A), containing melamine groups, are novel.

Abstract: Aftertreatment of dyeings on cotton or nylon with (A) a polybasic compound which is the product of reacting a primary or secondary amine with cyanamide, dicyandiamide, guanidine or biguanidine and, sequentially or simultaneously (B) a precondensate formed by reacting a compound of type (A) with an N-methylol derivative gives wet fastness properties superior to those given by either (A) or (B) used alone.

Abstract: A composition of matter useful as a high solids coating is disclosed. The composition contains at least one cycloaliphatic diol and at least one methylolamino curing agent.