Sulfur-containing Reactant Patents (Class 528/290)
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Patent number: 6787589Abstract: This application discloses amber colored polyesters suitable for packaging food and beverages. The amber polyester compositions provide excellent blockage of UV and visible light over the wavelength ranges of from about 320-550 nm, rendering them suitable for packaging materials sensitive to ultraviolet and visible light over this wavelength range, particularly beer.Type: GrantFiled: October 31, 2002Date of Patent: September 7, 2004Assignee: Eastman Chemical CompanyInventors: Max Allen Weaver, Marc Alan Strand, Crystal Leigh Kendrick, Gerry Foust Rhodes, Gertrude Williams, Jason Clay Pearson, Timothy Alan Upshaw
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Publication number: 20040120927Abstract: The present invention is directed to synthetic, biodegradable, biocompatible polymers that are the reaction product of an &agr;,&bgr;-unsaturated polybasic acid or derivative thereof and a monoglyceride, and which further contain pended thereto a functional agent, and to medical devices and compositions containing such polymers.Type: ApplicationFiled: December 18, 2002Publication date: June 24, 2004Inventor: Aruna Nathan
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Patent number: 6716898Abstract: Disclosed are amber polyester compositions suitable for packaging food and beverages wherein the compositions significantly absorbs light of wavelengths shorter than about 550 nm which is achieved by a combination of several colorants, most of which are copolymerized into the polyester.Type: GrantFiled: May 1, 2002Date of Patent: April 6, 2004Assignee: Eastman Chemical CompanyInventors: Max Allen Weaver, Horst Clauberg, Samuel David Hilbert, Dale Milton Blakely, Sara Stanley Wells
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Patent number: 6699931Abstract: The present invention relates to modified alkyd polymers, and compositions made from such polymers, wherein the alkyd polymers are modified with polyol-containing latex compositions and/or diol-containing latex compositions. The invention further relates to compositions prepared from such modified alkyd compositions.Type: GrantFiled: March 8, 2002Date of Patent: March 2, 2004Assignee: Eastman Chemical CompanyInventors: Thauming Kuo, John David Moncier, Allan Scott Jones, David Logan Murray, Mahendra Kumar Sharma
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Patent number: 6590061Abstract: Functionalized homopolymers and copolymers of &agr;-amino acids of the general formula 1, wherein X is oxygen or sulphur; R1 could be alkyl, alkenyl, substituted alkyl, aryl or substituted aryl; structure [A]n represents a poly(amino acid) chain based on &agr;-amino acids or their derivatives with protected functional groups, wherein n could be in the range of 1-500; Y is either OH, or a structure of the formula 2, wherein R2 is H or an amino-acid residue, or a structure of the formula 3, wherein Z and Z′ are either NH or O; R3 is a chemical structure selected from alkyls, substituted alkyls, aryls, substituted aryls, or a polymer selected from a group comprising poly(ethylene oxide), poly(propylene oxide) and polybutadiene; P is hydrogen or an acyl group derived from a carboxylic acid selected from the group including alkanoic acids, succinic acid, maleic acid, acrylic acid, phthalic acids and cyclohexane dicarboxylic acids, or it is an acyl selected from a group consisting of compounds accorType: GrantFiled: January 29, 2001Date of Patent: July 8, 2003Assignee: Institute of Macromolecular Chemistry of the Academy of Sciences of the Czech RepublicInventors: Frantisek Rypacek, Milan Dvorak, Dana Kubies, Ludka Machova
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Patent number: 6437058Abstract: A polymer in the form of a novolac resin is provided wherein the novolac resin has a weight average molecular weight of 1,000-30,000, some of the hydrogen atoms of hydroxyl groups are replaced by 1,2-naphthoquinonediazidosulfonyl ester groups, and some of the hydrogen atoms of the remaining hydroxyl groups are replaced by substituted acetal groups and/or crosslinked within a molecule or between molecules with crosslinking groups having C—O—C linkages. The polymer is formulated into a positive resist composition having improved uniformity, sensitivity, resolution and pattern profile as well as improved heat resistance, film retention, substrate adhesion and storage stability.Type: GrantFiled: February 7, 2001Date of Patent: August 20, 2002Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tomoyoshi Furihata, Hideto Kato, Yoshinori Hirano
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Patent number: 6365705Abstract: Ionomers (charged polymers) have carboxylate recurring units in their backbones and ammonium counterions for the carboxylate recurring units. One or more positively charged nitrogen atoms of the counterions are positioned at tetrahedral vertices of one or more spiro bicyclic ring systems.Type: GrantFiled: October 30, 2000Date of Patent: April 2, 2002Assignee: Eastman Kodak CompanyInventor: Jeffrey W. Leon
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Patent number: 6362313Abstract: Allyl pendent benzazole polymer system having repeating units of the formula: wherein Bz is a benzazole unit selected from the group consisting of wherein X is —O—, —S— or —NH—, and R is selected from the group consisting of wherein Ar is an aromatic group; and wherein x has a value of about 1.0 to 0.1 and y has a value of 1.0−x.Type: GrantFiled: February 13, 2001Date of Patent: March 26, 2002Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Fred E. Arnold, Thuy D. Dang
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Patent number: 6245862Abstract: The present invention relates to a golf ball, comprising a cover, a core and optional intermediate layers, wherein the various ball components are formed from compositions comprising a sulfonated and/or phosphonated ionomer. The sulfonated and/or phosphonated ionomer preferably comprises sulfonated thermoplastic elastomers, sulfonated thermoplastic polymers, sulfonated thermoset polymers and mixtures thereof. The compositions include a blend of about 1 wt. % to about 99 wt. % of at least one sulfonated and/or phosphonated ionomer and about 99 wt. % to about 1 wt. % of at least co-component polymer. The co-component polymer may be a conventional ionomer, a thermoplastic, a thermoplastic elastomer, a thermoset polymer or mixtures thereof.Type: GrantFiled: May 28, 1998Date of Patent: June 12, 2001Assignee: Acushnet CompanyInventor: Murali Rajagopalan
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Patent number: 6214965Abstract: The present invention relates to a process for preparing an aqueous solution of sulfonated melamine-formaldehyde resin, and a cement composition in which the solution and a setting retarder are added to a concrete, a mortar, a cement paste or the like. And the process comprises the following step (A), step (B) and step (C): Step (A): a step of adjusting an aqueous solution containing melamine (a), formaldehyde (b), sulfanilic acid (c) and an alkali substance (d) to (a):(b):(c)=1:2.5-3.5:0.5-1.5 in molar ratio and its pH to 8.0-13.5, and thereafter heating the aqueous solution at 50-90° C. to conduct the reaction until free sulfanilic acid decreases to 40-90 mol % of the amount of sulfanilic acid charged; Step (B): a step of adding an inorganic acid to the reaction liquid obtained in the step (A) to adjust its pH to 6.0-8.0, and thereafter heating the reaction liquid at 50-90° C.Type: GrantFiled: October 19, 1999Date of Patent: April 10, 2001Assignee: Nissan Chemical Industries, Ltd.Inventors: Jun Uchida, Takaichi Sugiyama, Yuhji Sudoh, Keisuke Nakayama
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Patent number: 6174965Abstract: The present invention provides a polyester resin having in the molecule at least one quaternary ammonium base represented by the formula (wherein X is halogen and R is alkyl), and a process for its production. The present invention further provides a pigment dispersion containing a pigment and the above polyester resin as resin for dispersion of the pigment, and also provides a coating composition containing the above pigment dispersion.Type: GrantFiled: February 23, 1999Date of Patent: January 16, 2001Assignee: Kansai Paint Company, LimitedInventors: Fumio Yamashita, Yoshiyuki Yukawa, Haruhiko Aida
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Patent number: 6150494Abstract: The invention relates to a polymer prepared from the repeat units of residues of a monomer of at least one dicarboxylic acid or ester; a monomer comprising a diol, diamine or a mixture thereof; a monomer comprising at least one sulfonate group and at least one polyester reactive group, and a monomer comprising an optical brightener agent having at least one polyester reactive group. The invention further relates to a method for preparing a polymer. The invention further relates to method of marking an article or composition with the polymer. The invention further relates to a method for detecting and separating an article contacted with the polymer. The invention further relates to an article or composition contacted with the polymer. The invention further relates to a method for enhancing the optical brightness of an article or composition, by contacting the article or composition with the polymer.Type: GrantFiled: April 30, 1998Date of Patent: November 21, 2000Assignee: Eastman Chemical CompanyInventors: Richard Hsu-Shien Wang, James J. Krutak, Mahendra K. Sharma, Barbara C. Jackson
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Patent number: 6121351Abstract: Thermoplastic compositions containing certain anthraquinone polysulfonamide colorants incorporated therein as toners or colorants. The anthraquinone colorant moieties which are incorporated into the polymer chain of the polysulfonamide colorants are not leachable, sublimable or extractable and do not exude from the thermoplastic compositions. The anthraquinone polysulfonamide colorants may be added to the thermoplastic polymers during production or melt blended with the polymer by conventional techniques to produce transparent thermoplastic compositions useful for a variety of end uses where nonmigrating or nonextractable colorants are needed.Type: GrantFiled: August 7, 1997Date of Patent: September 19, 2000Assignee: Eastman Chemical CompanyInventors: Max Allen Weaver, Wayne Payton Pruett, Kay Hunt Shackelford, Samuel David Hilbert
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Patent number: 6046263Abstract: Products are described which are obtainable by reacting compounds of formula I with compounds of formula IIa or/and IIb and IIIa or/and IIIb and additionally, where appropriate, IV ##STR1## wherein the general symbols are as defined in claim 1, the compound of formula I being, for example, methyl 3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate, the compound of formula IIa being, for example, diethanolamine, the compound of formula IIIa being, for example, methyl oleate, and the compound of formula IV being, for example, sulfur. The cited products can be used as liquid antioxidants in organic materials.Type: GrantFiled: May 19, 1998Date of Patent: April 4, 2000Assignee: Ciba Specialty Chemicals CorporationInventors: Michael Rasberger, Samuel Evans, Paul Dubs, Stephan Allenbach
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Patent number: 6037421Abstract: The present invention provides a condensation polymer, selected from the group consisting of polyamides and polyesters, that comprises between about 0.5% and about 4.0%, based on the theoretical moles of monomeric repeat units, of a trifunctional repeat unit. One of the functional groups of the trifunctional repeat unit comprises a moiety that imparts a desired property to the polymer, such as stain resistance or UV stabilization. One particular embodiment of the invention is a nylon 66 polymer that comprises between about 0.5% and 4.0%, based on the theoretical moles of nylon 66 repeat units, of a trifunctional repeat unit having the general formula: ##STR1## wherein R is the functional group that imparts a desired property to the polymer; a, b, and c are separately integers from 0-5. Preferably a+b=5 and c is 3.Type: GrantFiled: September 29, 1998Date of Patent: March 14, 2000Assignee: Solutia Inc.Inventor: Jawed Asrar
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Patent number: 6018004Abstract: Biodegradable polyesters P1 obtainable by reaction of a mixture consisting essentially of(a1) a mixture consisting essentially offrom 35 to 95 mol % of adipic acid or ester-forming derivatives thereof or mixtures thereof,from 5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, andfrom 0 to 5 mol % of a sulfonate compound, the sum of the individual mole percentages being 100 mol %, and(a2) a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,the molar ratio of (a1) to (a2) being chosen within the range from 0.4:1 to 1.5:1,with the proviso that the polyesters P1 have a molecular weight (M.sub.n) within the range from 5000 to 50,000 g/mol, a viscosity number within the range from 30 to 350 g/ml (measured in 50:50 w/w o-dichlorobenzene/phenol at a concentration of 0.5% by weight of polyester P1 at 25.degree. C.) and a melting point within the range from 50 to 170.degree. C.Type: GrantFiled: May 14, 1997Date of Patent: January 25, 2000Assignee: BASF AktiengesellschaftInventors: Volker Warzelhan, Gunnar Schornick, Bernd Bruchmann, Ursula Seeliger, Motonori Yamamoto, Peter Bauer
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Patent number: 5998568Abstract: A method for making a polyester resin comprises reacting a first polyfunctional alcohol or polyfunctional thiol and a carbonate in the presence of a catalyst to form an alkoxylated intermediate. The catalyst comprises: (1) a metal, a salt of a metal, or mixtures thereof and (2) a quaternary ammonium salt, a tertiary amine, an imidazole, or mixtures thereof. The alkoxylated intermediate is then reacted with a polyfunctional organic acid or anhydride thereof to form the polyester resin.Type: GrantFiled: January 14, 1999Date of Patent: December 7, 1999Assignee: Reichhold, Inc.Inventors: Hildeberto Nava, Karin F. Nelson-Baron
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Patent number: 5969079Abstract: Thermomechanical and thermo-oxidative stabilities in resin composites across the range of aerospace "engineering thermoplastic" resins are improved by forming four crosslinks at each addition polymerization site in the backbone of the resin using crosslinking functionalities of the general formula: ##STR1## wherein Z= ##STR2## .beta.=the residue an organic radical selected from the group consisting of: ##STR3## R.sub.R =a divalent organic radical; X=halogen;Me=methylT=allyl or methallyl.G=--CH.sub.2 --,--S--, --CO--, --SO--, --O--, --CHR.sub.3 --, or --C(R.sub.3).sub.2 --;i=1 or 2;R.sub.3 =hydrogen, lower alkyl, lower alkoxy, aryl, or aryloxy; and.theta.=--C.tbd.N, --O--C.tbd.N, --S--C.tbd.N, or --CR.sub.3 .dbd.C(R.sub.3).sub.Type: GrantFiled: October 21, 1994Date of Patent: October 19, 1999Assignee: The Boeing CompanyInventors: Hyman R. Lubowitz, Clyde H. Sheppard
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Patent number: 5962557Abstract: A colored polyester copolymer comprising the reaction product of at least one linear thermoplastic polyester precursor and at least ten parts per million by weight of a residue of at least one 1,4-bis (2,6-dialkylanilino)-9,10-anthraquinone colorant. A composition may be formed comprising the copolymer in admixture with at least one thermoplastic polymer. The copolymer may be formed by reacting at least one thermoplastic polyester precursor with a 1,4-bis (2,6-dialkylanilino)-9,10-anthraquinone colorant which has a polyester reactive group.Type: GrantFiled: August 7, 1997Date of Patent: October 5, 1999Assignee: Eastman Chemical CorporationInventors: Max Allen Weaver, Brian Edison Maxwell, Gerry Foust Rhodes, James John Krutak, Sr.
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Patent number: 5880220Abstract: Biodegradable polyetheresteramides P1 which are obtained by reacting(a1) a mixture containing20-95 mol % of adipic acid or ester-forming derivatives thereof or mixtures thereof and5-80 mol % of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and(a2) a mixture of dihydroxy compounds(a21) from 15 to 99.3 mol % of a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,(a22) from 0.2 to 85 mol % of a dihydroxy compound containing ether functionalities of the formula IHO--((CH.sub.2).sub.n --O).sub.m --H Iwhere n is 2, 3 or 4 and m is an integer from 2 to 250, or mixtures thereof and(a23) from 0.5 to 80 mol % of an amino-C.sub.2 -C.sub.12 -alkanol or amino-C.sub.5 -C.sub.10 -cycloalkanol,where the molar ratio of (a1) to (a2) is from 0.4:1 to 1.5:1, with the proviso, inter alia, that the polyetheresteramides P1 have a molecular weight (M.sub.Type: GrantFiled: July 3, 1997Date of Patent: March 9, 1999Assignee: BASF AktiengesellschaftInventors: Volker Warzelhan, Gunnar Schornick, Frank Braun, Ursula Seeliger, Motonori Yamamoto, Peter Bauer
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Patent number: 5863991Abstract: Biodegradable polyetheresteramides Q1 with a molecular weight (M.sub.n) in the range from 6000 to 80,000 g/mol, a viscosity number in the range from 30 to 450 g/ml (measured in o-dichlorobenzene/phenol (50/50 ratio by weight) at a concentration of 0.5% by weight polyetheresteramide Q1 at 25.degree. C.), and a melting point in the range from 50.degree. to 200.degree. C., obtained by reacting a1) from 95 to 99.9% by weight polyetheresteramide P1, obtained by reacting a mixture ofb1) 20-95 mol % adipic acid or ester-forming derivatives thereof, and5-80 mol % terephthalic acid or ester-forming derivatives thereof, andb2) a mixture of a dihydroxy compound selected from C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,b22) a dihydroxy compound which contains ether functionalities and has the formula IHO--((CH.sub.2).sub.n --O)).sub.m --H Iwhere n is 2, 3 or 4 and m is an integer from 2 to 250, andb23) from 0.5 to 80 mol % of an amino-C.sub.2 -C.sub.12 -alkanol or an amino-C.sub.5 -C.sub.Type: GrantFiled: July 3, 1997Date of Patent: January 26, 1999Assignee: BASF AktiengesellschaftInventors: Volker Warzelhan, Gunnar Schornick, Matthias Kroner, Ursula Seeliger, Motonori Yamamoto, Gerhard Ramlow
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Patent number: 5864002Abstract: A method of providing for manufacturing a colored polymer resin having the steps of:(a) blending a disazo colorant into a mixture of monomers, the colorant having a poly(oxyalkylene) substituent comprising from 2 to 200 alkylene oxide residues, bonded to each end of the disazo chromophore, the poly(oxyalkylene) substituent having a nucleophilic terminal group which is capable of reacting with at least a portion of the monomers;(b) providing conditions under which the monomers and disazo colorant polymerize to form a colored polymer resin.Type: GrantFiled: October 18, 1996Date of Patent: January 26, 1999Assignee: Milliken Research CorporationInventors: Eric B. Stephens, Mark E. Ragsdale, David J. Moody
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Patent number: 5852155Abstract: Disclosed are polyesteramide resin compositions having amide units of formula (I): ##STR1## and the units of the formula (II): ##STR2## wherein the polyesteramide is substantially devoid of units derived from butane diol. The ratio of (I) to (II) in the polyesteramide is preferably less than 1:3. Preferred polyesteramides have at least 80% of units of formula (I) separated by at least one of the units of formula (II).Type: GrantFiled: March 1, 1995Date of Patent: December 22, 1998Assignee: General Electric CompanyInventors: Jan Bussink, Reinoud Jaap Gaymans, Johannes Hubertus G. M. Lohmeijer, Ilias Nicholas Mamalis, Gary F. Smith, Antoinette Cornelia Maria van Bennekom
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Patent number: 5834412Abstract: Oligomeric or polymeric substituted or unsubstituted ethylene terephthalate esters comprising fluorescent whitening groups useful as soil release agents in laundry detergent compositions are described. The soil release agents of the present invention are especially suitable for use with polyester and polyester-blended fabric.Type: GrantFiled: June 4, 1997Date of Patent: November 10, 1998Assignee: The Procter & Gamble CompanyInventors: Robert Henry Rohrbaugh, Eugene Paul Gosselink
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Patent number: 5750635Abstract: This invention relates to a thermally stable polyester, comprising:a polyester resin prepared by adding a dicarboxylic acid to a glycol compound, said dicarboxylic acid selected from the group consisting of aliphatic dicarboxylic acids having a total of from 3 to 16 carbon atoms, alicyclic dicarboxylic acids having 7 to 12 carbon atoms, aromatic dicarboxylic acids containing a total of from 8 to 16 carbon atoms, and combinations thereof, and wherein said glycol is selected from the group consisting of glycols having from 2 to 12 carbon atoms, glycol ethers having from 4 to 12 carbon atoms, and combinations thereof,said polyester resin having been prepared in the presence of a catalyst system consisting essentially of one or more antimony compounds which is not reacted with .alpha.-hydroxy carboxylic acids, .alpha.,.beta.-dicarboxylic acids or derivatives thereof.Type: GrantFiled: December 6, 1996Date of Patent: May 12, 1998Inventors: Andrew Edwin Brink, Wayne Payton Pruett, Clinton Cherry, Kay Hunt Shackelford
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Patent number: 5731095Abstract: A water-soluble or water-dispersible fluorine-containing dendritic polymer surfactant having at least one terminal fluorocarbon moiety and at least one terminal anionic moiety, and which is suitable for use in preparing protective coating compositions is disclosed. The water-soluble or water-dispersible fluorine-containing dendritic polymer surfactants are represented by the general formula: ##STR1## where D represents a dendritic polymer, R.sub.F represents a fluorocarbon containing moiety, A.sup.- represents an anionic containing moiety, C.sup.+ represents a cation, T represents a terminal group of the dendritic polymer which has not been functionalized with a fluorocarbon or anionic moiety, n and m are at least each at least one, and the sum of n+m+q is the total number of terminal groups on the dendritic polymer. Also disclosed is a coating composition capable of forming a highly crosslinked, non-stick, protective coating.Type: GrantFiled: October 23, 1996Date of Patent: March 24, 1998Assignee: Oxazogen, Inc.Inventors: Larry A. Milco, Donald A. Tomalia
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Patent number: 5728671Abstract: Oligomeric or polymeric substituted or unsubstituted ethylene terephthalate esters comprising fluorescent whitening groups useful as soil release agents in laundry detergent compositions are described. The soil release agents of the present invention are especially suitable for use with polyester and polyester-blended fabric.Type: GrantFiled: December 21, 1995Date of Patent: March 17, 1998Assignee: The Procter & Gamble CompanyInventors: Robert Henry Rohrbaugh, Eugene Paul Gosselink
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Patent number: 5709940Abstract: This invention relates to linear, water-dispersible sulfopolyesters prepared using high molecular weight polyethylene glycol blocks and low molecular weight polyethylene glycol. The high molecular weight polyethylene glycol has the formula H--(OCH.sub.2 CH.sub.2).sub.n --OH where n is 20 to 500, and the low molecular weight polyethylene glycol has the structure H--(OCH.sub.2 CH.sub.2).sub.n' --OH where n' is 2 to 6. The sulfopolyesters are useful as textile fiber sizes that possess improved adhesion, flexibility, and abrasion resistance.Type: GrantFiled: May 21, 1996Date of Patent: January 20, 1998Assignee: Eastman Chemical CompanyInventors: Scott E. George, Bobby J. Sublett
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Patent number: 5708122Abstract: Poly(ester-imides) containing t-butylhydroquinone and trimellitic anhydride as part of the repeat units, as well as other monomers, are useful as molding resins. The polymers have a high glass transition temperature and are particularly useful in applications requiring good wear resistance.Type: GrantFiled: April 19, 1996Date of Patent: January 13, 1998Assignee: E. I. Du Pont de Nemours and CompanyInventor: Robert Ralph Luise
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Patent number: 5688899Abstract: An improved clarity copolyester of a diethylene glycol modified poly(ethylene terephthalate) has a b* value of less than 15, preferably less than 10. The copolyester composition has an inherent viscosity of about 0.4 to 1.0 dL/g and comprises (A) 100 mol percent dicarboxylic acid residue component, (B) 100 mol percent diol residue component, (C) catalyst residues and (D) color control agent residues. The dicarboxylic acid residue component comprises at least 75 mol percent of terephthalic acid residues. The diol residue component comprises 10 to 50 mol percent diethylene glycol residue and 50 to 90 mol percent ethylene glycol residue. The catalyst residues comprise 20 to 100 ppm manganese, 50 to 300 ppm antimony, 0 to 100 ppm titanium and 40 to 150 ppm phosphorus, based on the weight of the copolyester.Type: GrantFiled: January 21, 1997Date of Patent: November 18, 1997Assignee: Eastman Chemical CompanyInventors: Marc Alan Strand, Bobby Jones Sublett, Jimmy Ray Trotter
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Patent number: 5670607Abstract: This invention relates to compositions of miscible electrically conductive polyaniline and to conductive articles formed from such compositions. Specifically, the invention relates to polyaniline dioctylsulfosuccinate which is miscible with some common organic solvents. UV-Visible spectra of dilute solutions of this polymer show a linear dependence of absorbance on concentration. Solution with high concentrations of polymer, >50 w %, can be prepared and uniform films can be cast from these solutions without any loss in electrical conductivity. The solutions and films are stable.Type: GrantFiled: June 7, 1996Date of Patent: September 23, 1997Assignee: Gumbs Associates, Inc.Inventor: ChenChang Chen
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Patent number: 5668243Abstract: This invention relates to a polyester resin prepared by adding one or more dicarboxylic acid components to one or more glycol components containing 1,4-cyclohexanedimethanol equalling 100 mole %, the polyester resin having been prepared in the presence of a catalyst/stabilizer system consisting essentially of antimony compounds and phosphorous compounds and compounds selected from the group consisting essentially of zinc compounds, gallium compounds, and silicon compounds.Type: GrantFiled: October 15, 1996Date of Patent: September 16, 1997Assignee: Eastman Chemical CompanyInventors: Cheuk Chung Yau, Leslie Shane Moody
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Patent number: 5665151Abstract: The present invention provides inks which contain a near infrared fluorophoric compound incorporated into a water-dissipatible polyester backbone. The inks of the present invention are preferably colorless or "invisible" but could be made slightly colored if desirable. Specifically, the inks of the present invention comprise:A. between about 1 and 10 weight percent of at least one water-dissipatable polyester having from about 0.1 ppm by weight to about 10% by weight of a thermally stable near infrared fluorophoric compound copolymerized therein;B. between about 5 and 75 weight percent of at least aliphatic humectant;C. between about 0 and 15 weight percent of at least one lower aliphatic alcohol of no more than 3 carbon atoms;D. water and optionally up to about 2 weight percent of one or more additives;wherein the weight percentages of components A-D equal 100%.Type: GrantFiled: November 18, 1996Date of Patent: September 9, 1997Assignee: Eastman Chemical CompanyInventors: Nelson Zamora Escano, James John Krutak, Sr.
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Patent number: 5654367Abstract: An alternating copolymer comprising a repeating unit of the formula:--Z--(X--Y).sub.n -- (I)wherein n is at least 2, X is O, S, Se or Te, and Y and Z are independently an aromatic or substituted aromatic group, and at least one other repeating unit, which is useful as a photosensitive material used in a spatial light modulator.Type: GrantFiled: May 26, 1995Date of Patent: August 5, 1997Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Akio Takimoto, Hirofumi Wakemoto, Eiichiro Tanaka, Masanori Watanabe, Junko Asayama, Hisahito Ogawa, Shigehiro Sato, Fumiko Yokotani
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Patent number: 5652320Abstract: The present invention provides an novel polymer having 1-2,000 equivalents of an N-sulfoamino group/10.sup.6 g of weight of the polymer.The polymer has excellent dispersibility of inorganic fine particles, hygroscopicity, and dye-affinity. The polymer provides a binder resin in which a magnetic or non-magnetic metal or metal oxide can highly be dispersed. The polymer also provides a magnetic recording medium which is excellent in electromagnetic conversion characteristic, surface smoothness, adhesion to non-magnetic substrates, and durability. The polymer provides a magnetic recording medium with improved travelling, travelling durability, signal-to-noise ratio, and drop-out. The polymer also provides a polyester fiber which has a high fiber strength and an excellent hygroscopicity and can be colored with cationic dyes.Type: GrantFiled: October 3, 1995Date of Patent: July 29, 1997Assignee: Sanyo Chemical Industries, Ltd.Inventors: Takashi Takemoto, Toshiro Shimada, Hiroshi Itayama
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Patent number: 5650481Abstract: This invention relates to a polyester resin prepared by adding one or more dicarboxylic acid components to one or more glycol components containing 1,4-cyclohexanedimethanol equalling 100 mole %,the polyester resin having been prepared in the presence of a catalyst/stabilizer system consisting essentially of antimony compounds and phosphorous compounds and compounds selected from the group consisting essentially of zinc compounds, gallium compounds, and silicon compounds.Type: GrantFiled: October 15, 1996Date of Patent: July 22, 1997Assignee: Eastman Chemical CompanyInventors: Cheuk Chung Yau, Leslie Shane Moody
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Patent number: 5637637Abstract: This invention relates to waterborne copolymeric colorant compositions having a dye covalently bonded in the polymer backbone which is prepared by emulsion polymerization of an alkaline solution of a reactive dye and a vinyl monomer. The waterborne copolymeric colorant compositions are useful in formulating waterborne coatings, paints, inks, and primers in various household, personal care and cosmetic applications.Type: GrantFiled: June 30, 1995Date of Patent: June 10, 1997Assignee: Eastman Chemical CompanyInventors: Mahendra K. Sharma, Imelda L. Watson
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Patent number: 5613494Abstract: Polycondensates which contain tartaric acid derivatives, processes for their preparation and use thereof.The invention relates to polycondensates which consist of at least 95 mol % of recurring structural units of the formula I ##STR1## where R.sup.1 is a 2,3-O-alkylidenetartaric acid derivative (II) or furo[2,5] (V), alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl or a heterocycle, X is --O-- --NH-- or --S-- and R.sup.2 is 2,3-O-alkylidene-L-threitol (III) or a compound of the formula VI, alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl or a heterocycle, with the proviso that more than 5 mol % of the radicals R.sup.1 and/or R.sup.2 are present in the polycondensate of the formula I, where R.sup.1 is compound of the formula II or R.sup.2 is a compound of the formula III or R.sup.1 is a compound of the formula II and R.sup.2 is a compound of the formula III, or in which more than 5 mol % of the radicals R.sup.1 and R.sup.2 are present in the polycondensate of the formula I, wherea) R.sup.Type: GrantFiled: May 4, 1995Date of Patent: March 25, 1997Assignee: Hoechst AktiengesellschaftInventors: Volker Krone, Michael Magerstadt, Axel Walch, Gunter Ditzinger, Norbert Lill
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Patent number: 5605951Abstract: The present invention relates to a rubber composition containing silica reinforcement and to pneumatic tires having treads comprised of such rubber composition.A rubber composition comprises at least one elastomer, silica, carbon black and a silica coupler comprised of 3,3'-tetrathiodipropionitrile polysulfide mixture.Type: GrantFiled: February 20, 1996Date of Patent: February 25, 1997Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul H. Sandstrom, Lawson G. Wideman
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Patent number: 5594089Abstract: Thermomechanical and thermo-oxidative stabilities in heterocycle or heterocycle sulfone resin composites are improved by forming four crosslinks at each addition polymerization site in the backbone of the resin using crosslinking functionalities.Type: GrantFiled: October 21, 1994Date of Patent: January 14, 1997Assignee: The Boeing CompanyInventors: Hyman R. Lubowtiz, Clyde H. Sheppard
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Patent number: 5530059Abstract: Disclosed is a water-dissipatable alkyd resin containing a sulfonate group. The alkyd resin is prepared by reacting at least one monoglyceride, a polycarboxylic acid, and a polyol sulfomonomer adduct containing at least one sulfonate group. The alkyd resin is useful to prepare cross-linked coatings such as obtained with oil based paints.Type: GrantFiled: November 25, 1994Date of Patent: June 25, 1996Inventors: William W. Blount, Jr., Thauming Kuo
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Patent number: 5521013Abstract: Partially fluorinated polymer comprising a backbone and side-chains, in which the backbone and side-chains are each 4 atoms long and are chemically incompatible, one chain being at least predominantly hydrocarbon and the other comprising a C.sub.4+ perfluorocarbon moiety.Type: GrantFiled: May 16, 1995Date of Patent: May 28, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Anselm C. Griffin, Ladislav M. Wilson
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Patent number: 5505784Abstract: The invention relates to polycondensates which consist of at least 95 mol % of recurring structural units of the formula I ##STR1## where R.sup.1 is a 2,3-O-alkylidenetartaric acid derivative (II) or furo[2,5] (V), alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl or a heterocycle, X is --O--, --NH-- or --S-- and R.sup.2 is 2,3-O-alkylidene-L-threitol (III) or a compound of the formula VI, alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl or a heterocycle, with the proviso that more than 5 mol % of the radicals R.sup.1 and/or R.sup.2 are present in the polycondensate of the formula I, where R.sup.1 is compound of the formula II or R.sup.2 is a compound of the formula III or R.sup.1 is a compound of the formula II and R.sup.2 is a compound of the formula III, or in which more than 5 mol % of the radicals R.sup.1 and R.sup.2 are present in the polycondensate of the formula I, wherea) R.sup.1 is a compound of the formula V and R.sup.2 is a compound of the formula VI, orb) R.sup.Type: GrantFiled: January 10, 1995Date of Patent: April 9, 1996Assignee: Hoechst AktiengesellschaftInventors: Volker Krone, Michael Magerstadt, Axel Walch, Gunter Ditzinger, Norbert Lill
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Patent number: 5506060Abstract: Crosslinkable, polyaromatic, polyether or polyester oligomers can have glass transition temperatures above 900.degree. F. while exhibiting desirable toughness for aerospace applications and ease of processing. A plurality (i.e. three or more) of generally linear aryl arms extend outwardly like spokes from a central aromatic hub through ether or ester linkages. Each spoke usually includes electronegative linkages, and is capped with one or two crosslinking functionalities (i.e. unsaturated hydrocarbon sites) which may be thermally or chemically activated to complete the advanced composite during curing. Among other methods, linear and multidimensional polyether oligomers are synthesized using nitrophthalic anhydride or halophthalic anhydride, dialcohols, or polyols, diamines, and suitable end caps.Type: GrantFiled: June 5, 1995Date of Patent: April 9, 1996Assignee: The Boeing CompanyInventors: Hyman R. Lubowitz, Clyde H. Sheppard
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Patent number: 5506331Abstract: A polyester polymer comprising repeating units (I), or repeating units (I) and (II), and having a reduced viscosity (.eta..sub.sp /c) of 0.2 to 10.0 dl/g, measured at 20.degree. C. as a 0.5 g/dl solution dissolved in methylene chloride is prepared by allowing a dihydric phenol (III), or dihydric phenols (III) and (IV), to react with a carbonate precursor or a dibasic acid. An electrophotographic photoreceptor which comprises an electroconductive substrate and a photosensitive layer disposed on the electroconductive substrate and containing the polyester polymer as a charge transporting material or a binder resin. ##STR1## wherein, W is --O-- or single bond, X is a divalent group which is derived from a dihydric phenol containing a hydrazine structure, each of R.sup.25 and R.sup.26 is a halogen atom, an alkyl group, a cycloalkyl group or an aryl group, each of m and n is an integer of 0 to 4, Y is single bond, --O--, --S--, --SO--, --SO.sub.2 --, --CR.sup.27 R.sup.28 --, a 1,1-cycloalkylene group or an .alpha.Type: GrantFiled: December 28, 1993Date of Patent: April 9, 1996Assignee: Idemitsu Kosan Co., Ltd.Inventors: Tomohiro Nagao, Shuji Sakamoto, Hironobu Morishita, Hideyuki Miyamoto
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Patent number: 5498690Abstract: Carboxyl-containing polycondensation products having glass transition temperatures T.sub.G .gtoreq.20.degree. C. obtained from anhydrides of tricarboxylic or tetracarboxylic acids and diols, diamines or amino alcohols are used for cosmetic purposes, in particular as hair treatment compositions.Type: GrantFiled: January 27, 1995Date of Patent: March 12, 1996Assignee: BASF AktiengesellschaftInventors: Son N. Kim, Axel Sanner, Karin Sperling-Vietmeier
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Patent number: 5492998Abstract: Novel polymers of general formula: ##STR1## wherein R is an alkyl or aryl group that contains an active hydrogen atom (as determined by the Zerewitinoff test); A is a spacing group having at least one carbon atom; B is a spacing group having at least two carbon atoms; and R and R' are alkyl or aryl groups. The polymer is synthesized via the Mannich pathway, involving formation of an imine intermediate.Type: GrantFiled: January 20, 1995Date of Patent: February 20, 1996Assignees: Lifesource International, Ltd., Jojani Inc.Inventor: Nicholas M. Irving
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Patent number: 5453482Abstract: Provided is a new process useful for preparing arylsulfonyl halides, which comprises the addition or drowning of halosulfonation reaction products, produced by the reaction of aromatic compounds (arenes), with excess halosulfonic acid, into C.sub.3 -C.sub.6 aliphatic ketones, preferably acetone, isopropyl alcohol, or mixtures thereof, instead of drowning into water as is known in the art of aromatic sulfonyl chloride preparation. Less heat of reaction is observed, thus making the drowning of the halosulfonation reaction mixture safer and more controllable. Further, less hydrogen chloride gas is evolved from the drowning mixture and generally more highly pure arylsulfonyl chlorides are produced.Type: GrantFiled: March 18, 1994Date of Patent: September 26, 1995Assignee: Eastman Chemical CompanyInventors: Max A. Weaver, William W. Parham, James J. Krutak, Kim S. Chamberlin
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Patent number: 5449739Abstract: A shaped article of an aromatic heterocyclic copolymer can be produced by (a) reacting (i) an aromatic diaminodithiol compound, hydrogen atoms of thiol groups of the aromatic diaminodithiol compound being substituted with substituted or unsubstituted alkyl groups, and (ii) an aromatic diamino compound separately with (iii) a dicarboxylic acid derivative in an organic solvent to produce two types of oligomers; (b) reacting the two oligomers in an organic solvent to produce a precopolymer; (c) heating the precopolymer to cause a thiazole ring closure reaction, thereby producing the aromatic heterocyclic copolymer; (d) finely comminuting the aromatic heterocyclic copolymer to obtain fine powder; and (e) molding the powder at an elevated temperature to form an article of a desired shape.Type: GrantFiled: March 15, 1994Date of Patent: September 12, 1995Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Hiroshi Akita, Hiroto Kobayashi
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Patent number: 5423432Abstract: Provided are water-dissipatable, sulfo-containing polyesters and polyester-amides having copolymerized therein thermally stable near infrared flourophoric compounds. The polymers are useful in coating or ink compositions, which are in turn useful for marking articles for identification/authentication purposes. Also provided is a method for invisibly marking such articles and a method for detecting and sorting articles by utilizing the near infrared flourophoric ink or coating compositions.Type: GrantFiled: May 5, 1994Date of Patent: June 13, 1995Assignee: Eastman Chemical CompanyInventors: James J. Krutak, Michael R. Cushman, William W. Parham, Clarence A. Coates, Max A. Weaver, Gabor Patonay
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Patent number: 4606681Abstract: A device for rethreading and cleaning threaded pipe studs having an elongated casing having an outside surface provided with flat portions for attaching to a torquing means, which casing is provided with a straight channel therethrough shaped to allow passage of the pipe stud with at least a portion of the channel sidewalls having an inside diameter slightly larger than the outside diameter of the pipe studs, and having multiple threading dies attached to the channel sidewalls at one open end with the teeth protruding perpendicularly from the channel sidewalls, wherein the teeth on each threading die projects consecutively shallower into the channel as they progress from the open end.Type: GrantFiled: April 27, 1983Date of Patent: August 19, 1986Inventor: Bobby W. Collins