Nitrogen-containing Polyhydroxy Compound Or Salt Of A Nitrogen-containing Polyhydroxy Compound Patents (Class 528/291)
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Patent number: 5608031Abstract: This invention relates to a polyester resin prepared by adding one or more dicarboxylic acid components to one or more glycol components containing 1,4-cyclohexanedimethanol equalling 100 mole %,the polyester resin having been prepared in the presence of a catalyst/stabilizer system consisting essentially of antimony compounds and phosphorous compounds and compounds selected from the group consisting essentially of zinc compounds, gallium compounds, and silicon compounds.Type: GrantFiled: November 30, 1995Date of Patent: March 4, 1997Assignee: Eastman Chemical CompanyInventors: Cheuk C. Yau, Leslie S. Moody
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Patent number: 5608016Abstract: The invention relates to salts of pyromellitic acid which comprise 1 mol of pyromellitic acid and 0.5 to 2 mol of a guanidine of the following composition: ##STR1## in which R, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different radicals from the group consisting of hydrogen, alkyl, cycloalkyl and aromatic hydrocarbon residues having 1 to 8 carbon atoms, and R.sup.1 and R.sup.2 and R.sup.3 and R.sup.4 may form a joint ring which may contain an oxygen atom as heteroatom. Also claimed are the preparation of the salts and their use for matt epoxide and hybrid powder coatings.Type: GrantFiled: April 3, 1996Date of Patent: March 4, 1997Assignee: Huels AktiengesellschaftInventors: Rainer Gras, Elmar Wolf
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Patent number: 5605764Abstract: Disclosed is a water-dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water-dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. Additional utility for the invention resides in the manufacture of recyclable articles where insolubility in body fluids combined with solubility in tap water are required.Type: GrantFiled: October 31, 1995Date of Patent: February 25, 1997Assignee: Eastman Chemical CompanyInventors: Richard A. Miller, Scott E. George, Theron E. Parsons, III, Mark A. Montgomery
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Patent number: 5605951Abstract: The present invention relates to a rubber composition containing silica reinforcement and to pneumatic tires having treads comprised of such rubber composition.A rubber composition comprises at least one elastomer, silica, carbon black and a silica coupler comprised of 3,3'-tetrathiodipropionitrile polysulfide mixture.Type: GrantFiled: February 20, 1996Date of Patent: February 25, 1997Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul H. Sandstrom, Lawson G. Wideman
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Patent number: 5597579Abstract: The present invention describes an aliphatic polyoxaamide polymer and blends thereof that may be used to produce surgical devices such as sutures, sutures with attached needles, molded devices, and the like. The aliphatic polyoxaamide of the present invention have a first divalent repeating unit of formula I:[X--C(O)--C(R.sub.1)(R.sub.2)--O--(R.sub.3)--O--C(R.sub.1)(R.sub.2)--C(O)-- ]Iand a second repeating unit selected from the group of formulas consisting of:[--Y--R.sub.17 --].sub.T, I[--O--R.sub.5 --C(O)--].sub.B, and II([--O--R.sub.9 --C(O)].sub.P --O--).sub.L G XIand combinations thereof, wherein X and Y are selected from the group consisting of --O-- and --N(R)--, provided both X and Y are not both --O-- and may be blended with a second polymer that is preferably biocompatable.Type: GrantFiled: March 5, 1996Date of Patent: January 28, 1997Assignee: Ethicon, Inc.Inventors: Rao S. Bezwada, Dennis D. Jamiolkowski
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Patent number: 5571876Abstract: Disclosed is a water-dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water-dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. Additional utility for the invention resides in the manufacture of recyclable articles where insolubility in body fluids combined with solubility in tap water are required.Type: GrantFiled: October 31, 1995Date of Patent: November 5, 1996Assignee: Eastman Chemical CompanyInventors: Richard A. Miller, Theron E. Parsons, III, Mark A. Montgomery
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Patent number: 5552511Abstract: Disclosed is a water-dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water-dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. Additional utility for the invention resides in the manufacture of recyclable articles where insolubility in body fluids combined with solubility in tap water are required.Type: GrantFiled: October 31, 1995Date of Patent: September 3, 1996Assignee: Eastman Chemical CompanyInventors: Richard A. Miller, Scott E. George, Alicia E. Barrett, Theron E. Parsons, III
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Patent number: 5552495Abstract: Disclosed is a water-dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water-dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. Additional utility for the invention resides in the manufacture of recyclable articles where insolubility in body fluids combined with solubility in tap water are required.Type: GrantFiled: October 31, 1995Date of Patent: September 3, 1996Assignee: Eastman Chemical CompanyInventors: Richard A. Miller, Theron E. Parsons, III, Mark A. Montgomery
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Patent number: 5543488Abstract: Disclosed is a water-dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water-dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. Additional utility for the invention resides in the manufacture of recyclable articles where insolubility in body fluids combined with solubility in tap water are required.Type: GrantFiled: July 29, 1964Date of Patent: August 6, 1996Assignee: Eastman Chemical CompanyInventors: Richard A. Miller, Scott E. George, Theron E. Parsons, III, Mark A. Montgomery
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Patent number: 5521013Abstract: Partially fluorinated polymer comprising a backbone and side-chains, in which the backbone and side-chains are each 4 atoms long and are chemically incompatible, one chain being at least predominantly hydrocarbon and the other comprising a C.sub.4+ perfluorocarbon moiety.Type: GrantFiled: May 16, 1995Date of Patent: May 28, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Anselm C. Griffin, Ladislav M. Wilson
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Patent number: 5519107Abstract: Novel polyesters prepared from a diol, a dicarboxylic acid or ester forming reactive derivative thereof and an aromatic amino acid, ester or alcohol are disclosed.Type: GrantFiled: November 17, 1994Date of Patent: May 21, 1996Assignee: General Electric CompanyInventors: John A. Tyrell, Gary F. Smith
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Patent number: 5510452Abstract: A liquid, pourable rheological additive especially useful for thickening organic and solvent-based compositions which in one aspect comprises an alkoxylated nitrogen-containing compound, polycarboxylic acid, and a functional chain ending unit. The additive, which exists in a pourable, pumpable form at up to a 100% rheologically active composition, exhibits excellent thickening efficiency for systems including inks, epoxies, polyesters, paints, greases and other systems, including ease of dispersibility, without adversely affecting gloss. The additive operates by both an associative and a reaction mechanism to provide rheological viscosity properties to such systems, and is also similarly useful for aqueous systems.Type: GrantFiled: July 11, 1994Date of Patent: April 23, 1996Assignee: Rheox, Inc.Inventor: Mahalingam Santhanam
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Patent number: 5505784Abstract: The invention relates to polycondensates which consist of at least 95 mol % of recurring structural units of the formula I ##STR1## where R.sup.1 is a 2,3-O-alkylidenetartaric acid derivative (II) or furo[2,5] (V), alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl or a heterocycle, X is --O--, --NH-- or --S-- and R.sup.2 is 2,3-O-alkylidene-L-threitol (III) or a compound of the formula VI, alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl or a heterocycle, with the proviso that more than 5 mol % of the radicals R.sup.1 and/or R.sup.2 are present in the polycondensate of the formula I, where R.sup.1 is compound of the formula II or R.sup.2 is a compound of the formula III or R.sup.1 is a compound of the formula II and R.sup.2 is a compound of the formula III, or in which more than 5 mol % of the radicals R.sup.1 and R.sup.2 are present in the polycondensate of the formula I, wherea) R.sup.1 is a compound of the formula V and R.sup.2 is a compound of the formula VI, orb) R.sup.Type: GrantFiled: January 10, 1995Date of Patent: April 9, 1996Assignee: Hoechst AktiengesellschaftInventors: Volker Krone, Michael Magerstadt, Axel Walch, Gunter Ditzinger, Norbert Lill
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Patent number: 5506334Abstract: The invention relates to new salts of pyromellitic acid, to a process for their preparation and to their use for the production of matt epoxide and hybrid powder coatings.Type: GrantFiled: April 6, 1995Date of Patent: April 9, 1996Assignee: Huels AktiengesellschaftInventors: Rainer Gras, Elmar Wolf
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Patent number: 5506331Abstract: A polyester polymer comprising repeating units (I), or repeating units (I) and (II), and having a reduced viscosity (.eta..sub.sp /c) of 0.2 to 10.0 dl/g, measured at 20.degree. C. as a 0.5 g/dl solution dissolved in methylene chloride is prepared by allowing a dihydric phenol (III), or dihydric phenols (III) and (IV), to react with a carbonate precursor or a dibasic acid. An electrophotographic photoreceptor which comprises an electroconductive substrate and a photosensitive layer disposed on the electroconductive substrate and containing the polyester polymer as a charge transporting material or a binder resin. ##STR1## wherein, W is --O-- or single bond, X is a divalent group which is derived from a dihydric phenol containing a hydrazine structure, each of R.sup.25 and R.sup.26 is a halogen atom, an alkyl group, a cycloalkyl group or an aryl group, each of m and n is an integer of 0 to 4, Y is single bond, --O--, --S--, --SO--, --SO.sub.2 --, --CR.sup.27 R.sup.28 --, a 1,1-cycloalkylene group or an .alpha.Type: GrantFiled: December 28, 1993Date of Patent: April 9, 1996Assignee: Idemitsu Kosan Co., Ltd.Inventors: Tomohiro Nagao, Shuji Sakamoto, Hironobu Morishita, Hideyuki Miyamoto
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Patent number: 5498690Abstract: Carboxyl-containing polycondensation products having glass transition temperatures T.sub.G .gtoreq.20.degree. C. obtained from anhydrides of tricarboxylic or tetracarboxylic acids and diols, diamines or amino alcohols are used for cosmetic purposes, in particular as hair treatment compositions.Type: GrantFiled: January 27, 1995Date of Patent: March 12, 1996Assignee: BASF AktiengesellschaftInventors: Son N. Kim, Axel Sanner, Karin Sperling-Vietmeier
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Patent number: 5496670Abstract: A macroscopically isotropic side chain liquid crystal polymer is described containing photochromic mesogenic groups and which through irradiation with light is capable of being permanently or substantially permanently converted into an optically anisotropic phase without having been pre-oriented. The polymer is preferably a polyester between on the one hand either an aliphatic, optionally substituted, .alpha.,.omega.-dicarboxylic acid having a total chain length of up to 24 carbon atoms, or an aryl-, in particular phenyl-, carboxylic acid, and on the other hand an optionally substituted 1,3-propanediol containing the mesogenic group, or a group containing the mesogenic group, attached to the carbon in the 2-position. Furthermore, an optical storage device comprising a film of the polymer.Type: GrantFiled: August 30, 1993Date of Patent: March 5, 1996Assignees: Riso National Laboratory, Consiglio Nazionale della RichercheInventors: Soren Hvilsted, P. S. Ramanujam, Fulvio Andruzzi
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Patent number: 5475064Abstract: Polyester polymers having pendant carbamate groups are disclosed. The polymers are prepared by:(a) reacting a hydroxyalkyl cyclic carbonate with ammonia, ammonium hydroxide, or a primary amine to form a dihydric alcohol having a carbamate group appended thereto,(b) reacting the dihydric alcohol from (a) and a cyclic anhydride to form a half-ester diacid having a carbamate group appended thereto, and(c) reacting a mixture comprising the half-ester diacid from step (b) and a polyol to form a polyester having carbamate groups appended thereto.Type: GrantFiled: June 7, 1995Date of Patent: December 12, 1995Assignee: BASF CorporationInventors: Gregory L. Menovcik, Walter H. Ohrbom
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Patent number: 5416188Abstract: One embodiment of the present invention is directed to polysubstituted fullerene moieties having a plurality of substituents thereon, selected from the group consisting of hydroxy, oxide, nitro, amino, organocarboxy, amide, and mixtures thereof.Another embodiment is directed toward the preparation of the novel polysubstituted fullerenes. The method of forming polysubstituted fullerenes comprises contacting fullerenes with an electrophilic reagent such as nitronium ion or an organic peracid. When the electrophilic agent is nitronium ion, the fullerene is further contacted with a nucleophilic reagent. Polysubstituted fullerenes comprise a fullerene moiety selected from fullerenes or mixtures thereof having a plurality of substituents thereon.The polysubstituted fullerenes are particularly useful as cross-linking agents in polymers and/or as core building blocks of star polymers.Type: GrantFiled: February 18, 1994Date of Patent: May 16, 1995Assignee: Exxon Research & Engineering Co.Inventors: Long Y. Chiang, Ravindra B. Upasanj, John W. Swirczewski
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Patent number: 5409764Abstract: A curable adhesive composition comprising an unsaturated polyester oligomer (A) of any of the following formulae (I) to (IV), obtained by reacting a compound (a) having a hydroxyl group and/or an amino group, a cyclic acid anhydride (b) and an epoxide (c) having an ethylenically unsaturated group, and an adhesive polymer (B), ##STR1## wherein: R.sub.1 is a divalent organic moiety having 1 to 40 carbon atoms,R.sub.2 is a divalent organic moiety having 1 to 10 carbon atoms,R.sub.3 is hydrogen or methyl,R.sub.4 is a monovalent organic moiety having 1 to 40 carbon atoms,R.sub.5 is a monovalent organic moiety having 1 to 40 carbon atoms,R.sub.6 is hydrogen or a monovalent organic moiety having 1 to 10 carbon atoms, andn is an integer of 2 or greater.Type: GrantFiled: September 23, 1994Date of Patent: April 25, 1995Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Tsukasa Otsuki, Masato Yanagi, Toshikazu Onikubo, Kouichi Iibuchi
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Patent number: 5401612Abstract: Polyesters containing nonlinear-optical chromophores, which have mean molecular weights M.sub.w of from 5000 to 500,000 and contain units of the formula (I) ##STR1## where A is a divalent radical,D is an electron donor,G is a heterocyclic ring as electron acceptor,x and y are identical or different numbers,m and n are identical or different numbers, andR.sup.1 and R.sup.2 are identical or different radicals, are suitable, for example, as components in communications technology.Type: GrantFiled: May 18, 1994Date of Patent: March 28, 1995Assignee: BASF AktiengesellschaftInventors: Karl-Heinz Etzbach, Ruediger Sens, Stefan Beckmann
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Patent number: 5391696Abstract: Polycondensates which contain tartaric acid derivatives, processes for their preparation and use thereof.The invention relates to polycondensates which consist of at least 95 mol % of recurring structural units of the formula I ##STR1## where R.sup.1 is a 2,3-O-alkylidenetartaric acid derivative (II) or furo[2,5] (V), alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl or a heterocycle, X is --O--, --NH-- or --S-- and R.sup.2 is 2,3-O-alkylidene-L-threitol (III) or a compound of the formula VI, alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl or a heterocycle, with the proviso that more than 5 mol % of the radicals R.sup.1 and/or R.sup.2 are present in the polycondensate of the formula I, where R.sup.1 is compound of the formula II or R.sup.2 is a compound of the formula III or R.sup.1 is a compound of the formula II and R.sup.2 is a compound of the formula III, or in which more than 5 mol % of the radicals R.sup.1 and R.sup.2 are present in the polycondensate of the formula I, wherea) R.sup.Type: GrantFiled: May 21, 1992Date of Patent: February 21, 1995Assignee: Hoechst AktiengesellschaftInventors: Volker Krone, Michael Magerstadt, Axel Walch, Gunter Ditzinger, Norbert Lill
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Patent number: 5384377Abstract: This invention provides certain blue substituted 1,4-bis(2,6-dialkylanilino) anthraquinones in combination with selected red anthraquinone and anthrapyridone (3H-dibenz[f,ij]isoquinoline-2,7-dione) compounds which provide a toner system useful in imparting a desirable neutral to slightly blue hue to polyesters having a yellow appearance. The thermally stable colored compounds can have polyester reactive groups and are preferably incorporated into the polyester polymer structure during polymerization.Type: GrantFiled: February 16, 1994Date of Patent: January 24, 1995Assignee: Eastman Chemical CompanyInventors: Max A. Weaver, Wayne P. Pruett, Gerry Rhodes, Samuel D. Hilbert, William W. Parham
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Patent number: 5384387Abstract: Novel polyesters prepared from a diol, a dicarboxylic acid or ester forming reactive derivative thereof and an aromatic amino acid, ester or alcohol are disclosed.Type: GrantFiled: May 4, 1993Date of Patent: January 24, 1995Assignee: General Electric CompanyInventors: John A. Tyrell, Gary F. Smith
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Patent number: 5372864Abstract: This invention provides certain blue substituted 1,4-bis(2,6-dialkylanilino) anthraquinones in combination with selected red anthraquinone and anthrapyridone (3H-dibenz[f,ij] isoquinoline-2,7-dione) compounds which provide a toner system useful in imparting a desirable neutral to slightly blue hue to polyesters having a yellow appearance. The thermally stable colored compounds can have polyester reactive groups and are preferably incorporated into the polyester polymer structure during polymerization.Type: GrantFiled: September 3, 1993Date of Patent: December 13, 1994Assignee: Eastman Chemical CompanyInventors: Max A. Weaver, Wayne P. Pruett, Gerry Rhodes, Samuel D. Hilbert, William W. Parham
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Patent number: 5372747Abstract: According to the invention, oxyalkylates of aliphatic or cyclic, primarily primary diamines or polyamines, or block polymers (having recurring structural units of the abovementioned oxyalkylate type) produced by prior linking of such oxyalkylates with dicarboxylic acids, are converted into novel substances which are suitable for a very wide variety of areas of application in the field of interface-active agents and can be employed, for example, in the preparation of azo pigments to improve the coloristic properties, by esterification of the terminal hydroxyl group in these aminoxyalkylates using fatty acids or aromatic carboxylic acids and/or resin acids, and, if appropriate, subsequent reaction of free hydroxyl groups which are still present with dicarboxylic acids and sulfite to form the corresponding monoester (containing anionic radicals).Type: GrantFiled: March 2, 1992Date of Patent: December 13, 1994Assignee: Hoechst AktiengesellschaftInventors: Heinz Uhrig, Joachim Weide
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Patent number: 5356989Abstract: An aqueous dispersion suitable for use as various coatings is provided. The dispersion includes polyester resin (A), a water soluble organic compound (B), water (C), and a neutralizer (D). The polyester resin has an acid number of 50 equivalents/10.sup.6 g or more. The polycarboxylic acid component of the resin contains aromatic dicarboxylic acid having no metal sulfonate groups in an amount in the range of 50 to 99.99 mole percent, and dicarboxylic acid having a metal sulfonate group in an amount in the range of 0.01 to 20 mole percent based on the total moles of the polycarboxylic acid component. The polyol component of the resin contains diol in an amount in the range of 30 to 100 mole percent based on the total moles of the polyol component. The diol has an alkyl group with 1 to 3 carbon atoms on a side chain, and the total number of carbon atoms in the diol is 6 to 25. The water soluble organic compound has a boiling point in the range of 60.degree. to 250.degree. C.Type: GrantFiled: January 18, 1994Date of Patent: October 18, 1994Assignee: Toyo Boseki Kabushiki KaishaInventors: Hiroshi Tachika, Keiichiro Togawa, Hiroshi Fujimoto
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Patent number: 5354840Abstract: Functional-amine polyesters have at least a first residue of a first monomer, a second residue of a second monomer and from about 0.1 to about 3.0 mole percent of a functional-amine residue of a functional amine prepared by reacting the first and second monomers and the functional amine in an inert atmosphere. The functional amine has a functional group which facilitates polymerizing the amine and the first and second monomers. The amine residue facilitates reaction of the functional-amine polyester in an organic peroxide cross-linking reaction system.Type: GrantFiled: September 10, 1993Date of Patent: October 11, 1994Assignee: Xerox CorporationInventor: Peter G. Odell
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Patent number: 5344872Abstract: This invention relates to an aqueous dispersion of a water-dissipatable polyester and a styrenated acrylic copolymer in combination with either an acrylic polymer or a hydantoin-formaldehyde resin.Type: GrantFiled: February 19, 1993Date of Patent: September 6, 1994Assignee: Eastman Chemical CompanyInventors: Theo J. Debord, Nelson Z. Escano, Louis A. Wilkin
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Patent number: 5336753Abstract: The present invention relates to a polycondensation and/or addition product containing carboxyl groups and amino groups. This can be obtained by reactinga) polycarboxylic acids or anhydrides thereof, if appropriate together with monocarboxylic acids,b) polyols, if appropriate together with monools, and, if appropriatec) further modifying components, and, if appropriate,d) a component which is capable of reacting with the reaction product from a), b) and, if appropriate, c), with the proviso that the final product contains tertiary amino groups which originate from components a) and/or b) and/or d), and the reaction product from a), b), if appropriate c) and if appropriate d) has an acid number from 5 to 200, preferably 10 to 130, and an amine number from 3 to 150, preferably 10 to 100.Type: GrantFiled: January 8, 1993Date of Patent: August 9, 1994Assignee: BASF Lacke + Farben AGInventors: Werner A. Jung, Udo Vorbeck, Arno Schmitz, Wilhelm Heise, Lutz-Werner Gross
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Patent number: 5336714Abstract: Provided are water-dissipatable, sulfo-containing polyesters and polyester-amides having copolymerized therein thermally stable near infrared flourophoric compounds. The polymers are useful in coating or ink compositions, which are in turn useful for marking articles for identification/authentication purposes. Also provided is a method for invisibly marking such articles and a method for detecting and sorting articles by utilizing the near infrared flourophoric ink or coating compositions.Type: GrantFiled: December 30, 1993Date of Patent: August 9, 1994Assignee: Eastman Chemical CompanyInventors: James J. Krutak, Michael R. Cushman, William W. Parham, Clarence A. Coates, Max A. Weaver, Gabor Patonay
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Patent number: 5321112Abstract: The invention provides hydroxy-functional cyanoacrylate ultraviolet radiation absorbing compounds. The radiation absorbing compounds can be incorporated into step growth polymers such as polyurethanes, polyesters, and polycarbonates. The invention also provides such polymers having the radiation compound incorporated therein and articles prepared therefrom.Type: GrantFiled: December 22, 1992Date of Patent: June 14, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventor: David B. Olson
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Patent number: 5321118Abstract: Disclosed is a novel monomer composition and its preparation that is useful in the production of polyesters. This novel monomer composition is 1-acetoacetamido-2,3-propane diol and can be used in the preparation of polyesters in combination with a dicarboxylic acid.Type: GrantFiled: September 30, 1993Date of Patent: June 14, 1994Assignee: Eastman Chemical CompanyInventors: John C. Hubbs, Robert J. Clemens
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Patent number: 5321098Abstract: The invention relates to a composition mixture comprising (i) at least one ester-acid, ester-salt or mixtures thereof and (ii) at least one amidic-acid, amidic-salt or mixtures thereof a polymer fabrics treated with the same. The treated polymer fabrics have improved wicking/wetting characteristics. The treated polymer fabrics maintain these characteristics upon repeated exposure to aqueous fluids.Type: GrantFiled: October 4, 1991Date of Patent: June 14, 1994Assignee: The Lubrizol CorporationInventor: Kasturi Lal
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Patent number: 5286837Abstract: Process for treating poly(esteramides) to improve the heat and storage stability thereof. Polymer is optionally suspended in a liquid medium, treated with an amide group-containing solvent, and then separated from the solvent and liquid medium (if any). Also, poly(esteramides) treated in this process and devices and articles comprising such poly(esteramides).Type: GrantFiled: December 8, 1992Date of Patent: February 15, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Thomas H. Barrows, Myhanh T. Truong, Paul R. Suszko, David W. Stegink
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Patent number: 5274025Abstract: This invention relates to a polymer blend comprising water-dissipatable, sulfonate containing, a hydantoin-formaldehyde resin.Type: GrantFiled: February 19, 1993Date of Patent: December 28, 1993Assignee: Eastman Kodak CompanyInventors: Rebecca R. Stockl, Hieu D. Phan, Gary T. Clark
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Patent number: 5194571Abstract: Provided are polyester compositions having thermally stable colorants copolymerized therein, said colorants comprised of at least one electron-rich aromatic moiety attached to a negatively substituted 2,5-dioxypyrrolin-3-yl moiety and containing at least one, and preferably, two polyester reactive groups. Also provided are polyester color concentrates and blends of the colored polyester compositions with other thermoplastic polymers and shaped or formed articles comprised of same.Type: GrantFiled: August 19, 1991Date of Patent: March 16, 1993Assignee: Eastman Kodak CompanyInventors: Max A. Weaver, Clarence A. Coates, William W. Parham, Samuel D. Hilbert, James J. Krutak, Wayne P. Pruett
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Patent number: 5189134Abstract: Novel nonlinearly optically active polymers, well suited for electrooptical applications, are prepared by copolymerizing a first difunctional monomer with a second difunctional comonomer, with at least one of such difunctional monomers including a polar charge transfer moiety containing at least one electron acceptor group and at least one electron donor group (D), and further wherein the polymerizable functional groups are borne by the one or more electron donor groups (D).Type: GrantFiled: September 18, 1989Date of Patent: February 23, 1993Assignee: Rhone-Poulenc ChimieInventors: Gerard Mignani, Pascal Barthelemy, Remi Meyrueix
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Patent number: 5179191Abstract: A polycondensation and/or addition product containing carboxyl groups and tertiary amino groups, coating agents based on the latter, and the use thereof.The present invention relates to a polycondensation and/or addition product containing carboxyl groups and amino groups. This can be obtained by reactinga) polycarboxylic acids or anhydrides thereof, if appropriate together with monocarboxylic acids,b) polyols, if appropriate together with monools, and, if appropriatec) further modifying components, and, if appropriate,d) a component which is capable of reacting with the reaction product from a), b) and, if appropriate, c), with the proviso that the final product contains tertiary amino groups which originate from components a) and/or b) and/or d), and the reaction product from a), b), if appropriate c) and if appropriate d) and an acid number from 5 to 200, preferably 10 to 130, and an amine number from 3 to 150, preferably 10 to 300.Type: GrantFiled: February 27, 1989Date of Patent: January 12, 1993Assignee: BASF Lacke & Farben AktiengesellschaftInventors: Werner A. Jung, Udo Vorbeck, Arno Schmitz, Wilhelm Heise, Lutz-Werner Gross
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Patent number: 5176959Abstract: Crosslinked polymer microparticles are produced by emulsion polymerizing a monomer mixture containing a crosslinking monomer having a plurality of polymerizable sites in the molecule in an aqueous medium containing a polymeric amide-acid and a neutralizing base as an emulsifier/dispersant. The polymer microparticles are incorporated to thermosetting coating compositions for rheology control and other purposes. The amide-acid moieties of the emulsifier/diapersant are capable upon curing of the coating composition of cyclizing into an imide ring and the polymer amide-acid retained on the polymer microparticles, which imide moieties do not adversely affect the properties of cured films of the coating composition.Type: GrantFiled: February 26, 1991Date of Patent: January 5, 1993Assignee: Nippon Paint Company LimitedInventors: Mitsuo Yamada, Ryuzo Mizuguchi
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Patent number: 5138020Abstract: PBZ polymers are synthesized by the reaction of AA- and BB-monomers. The BB-monomer is conveniently synthesized and isolated as a phosphate salt having a uniform number of phosphate ions associated with each BB-monomer ion. Such high purity monophosphate and diphosphate salts can be obtained by precipitating the monomer from an aqueous acid solution by adjusting the pH balance or from a mixture of phosphoric acid and a volatile, polar, saturated organic liquid at a relatively low temperature.Type: GrantFiled: April 21, 1989Date of Patent: August 11, 1992Assignee: The Dow Chemical CompanyInventors: William J. Harris, Ming-Biann Liu, Luke R. Kleiss, Zenon Lysenko, Steven Rosenberg
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Patent number: 5124431Abstract: Disclosed herein is a process for producing an azo group-containing polymer comprising polycondensing a compound having an azo group in the main molecular chain and an alcoholic hydroxyl group, phenolic hydroxyl group, imino group or amino group at both ends thereof with a dicarboxylic acid chloride or a carbonate precursor except the polycondensation of a compound having an azo group in the main molecular chain and an alcoholic hydroxyl group at both ends thereof with a carbonate precursor.Type: GrantFiled: October 3, 1990Date of Patent: June 23, 1992Assignee: Mitsubishi Kasei CorporationInventors: Takayuki Ohta, Shiho Sano, Ryoko Aso
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Patent number: 5102973Abstract: A conjugated system-containing organic high molecular compound is described, which contains a recurring unit represented by the following structural formula (I) and has a number-average molecular weight of 1,000 or more: ##STR1## wherein m represents an integer of from 2 to 10; n represents an integer of from 1 to 23; B and B' respectively represent --NHCO-- and --CONH--, --CONH-- and --NHCO--, ##STR2## --A-- is selected from the group consisting of ##STR3## wherein R.sup.1-4 and R.sup.5-8 each independently is selected from the group consisting of a hydrogen atom, a halogen atom, an alkyl group having 1 to 5 carbon atoms, an amino group, an alkylamino group having 1 to 5 carbon atoms, a hydroxyl group, an alkoxyl group having 1 to 5 carbon atoms, a cyano group, a nitro group, and groups of the following formulae (a), (b), and (c), provided that the groups of --A-- may be the same or different: ##STR4## wherein R.sup.9-12, R.sup.13-16, and R.sup.Type: GrantFiled: October 5, 1990Date of Patent: April 7, 1992Assignees: Mitsubishi Petrochemical Co., Ltd., Kazuyoshi Iimura, Seiji UjiieInventors: Kazuyoshi Iimura, Seiji Ujiie, Mitsutaka Miyabayashi
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Patent number: 5093456Abstract: This invention provides synthetic routes for novel single isomers of monocarbamate diols and their polymerization to provide novel polyesters, polyurethanes, polycarbonates, and the like having pendant carbamate groups on the polymer chain. Devices using some of these novel polymers which demonstrate nonlinear optical activity are also disclosed.Type: GrantFiled: June 14, 1989Date of Patent: March 3, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Smarajit Mitra, Cecil V. Francis
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Patent number: 5086160Abstract: A thermotropic copolyester, showing a liquid-crystalline structure of nematic type within a desired temperature range, contains umits deriving from:(a) a saturated bicarboxy aliphatic acid;(b) 4,4'-di-hydroxy-diphenyl,(c) 4-hydroxybenzoic acid; and(d) 4-hydroxy-benzoic acid bearing an alkyl substituent or a halogen atom bonded to the aromatic ring.Such a copolyester constitutes a material endowed with self-reinforcing characteristics, originating, through the usual transformation processes by injection or by extrusion techniques, marked molecular orientations, which supply the manufactured articles with high stiffness characteristics.Said material can be also used as a reinforcing agent when is mixed, by means of the usual techniques, with the traditional thermoplastic polymers.Type: GrantFiled: June 1, 1990Date of Patent: February 4, 1992Assignee: Eniricerche S.p.A.Inventors: Ugo Pedretti, Bruno Bresci, Cesarina Bonfanti, Pier L. Magagnini, Francesco P. La Mantia, Arnaldo Roggero
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Patent number: 5086161Abstract: A composition useful for incorporation into polymer compositions employed for food packaging or the like comprising a bis- or tris-methine compound having the structural formula ##STR1## wherein A is selected from the radicals ##STR2## wherein R' and R" are each selected from chlorine, bromine, fluorine, alkyl, alkoxy, aryl, aryloxy and arylthio;each n is independently 0, 1, 2;R.sub.1 is selected from a large variety of radicals such as cycloalkyl, phenyl, and straight or branched alkyl which may be subsituted;R.sub.2 is alkylene or the like;R.sub.3, R.sub.4, and R.sub.5 are each selected from hydrogen and alkyl; andP and Q and P.sup.1 and Q.sup.1 are selected from cyano, carbalkoxy, carbaryloxy, carbaralkyloxy, or the like.The invention compositions are especially useful in combination with molding or fiber-grade condensation polymer; most preferably such polymer having compolymerized therein a total of from 1.Type: GrantFiled: May 6, 1991Date of Patent: February 4, 1992Assignee: Eastman Kodak CompanyInventors: Max A. Weaver, Wayne P. Pruett, Samuel D. Hilbert
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Patent number: 5039782Abstract: The present invention pertains to polymeric whitening agents which contain both a fluorescent portion and a hydrophilic portion. These copolymers may be used on certain substrates, such as polyester or soiled cottons, for a greater brightening than previously known.Type: GrantFiled: December 11, 1990Date of Patent: August 13, 1991Assignee: Lever Brothers Company, division of Conopco, Inc.Inventors: Matthew E. Langer, Ferial Khorshahi, Michael P. Aronson
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Patent number: 5032670Abstract: Disclosed are color concentrate compositions which comprise a polyester having copolymerized therein at least 0.5 weight percent of an anthraquinone colorant compound having the formula ##STR1## wherein AQ is a 1,5- or 1,8-anthraquinonylene radical; R.sup.1 and R.sup.2 are the same or different and are unsubstituted or substituted alkyl, cycloalkyl or aryl; and X is a group reactive with at least one of the functional groups of the monomers from which the polyester is prepared. Amorphous polyesters and partially-crystalline polyesters are preferred embodiments of the color concentrates. Also disclosed are colored semicrystalline powders which may be obtained from the amorphous and partially-crystalline color concentrates by a dissolution-crystallization-precipitation procedure.Type: GrantFiled: August 30, 1989Date of Patent: July 16, 1991Assignee: Eastman Kodak CompanyInventors: William W. Parham, James J. Krutak, Max A. Weaver, Clarence A. Coates, Jr., Terry A. Oldfield
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Patent number: 5030708Abstract: Provided are novel methine colorants derived from acetaldehyde, 1,3-dihydro-7-methoxycarbonyl-1,1,3-trimethyl-2H-benz[e]indol-2-ylidine and polyester compositions and concentrates having these colorants copolymerized therein. Also provided are novel intermediates useful for making the colorants.Type: GrantFiled: December 17, 1990Date of Patent: July 9, 1991Assignee: Eastman Kodak CompanyInventors: James J. Krutak, William W. Parham, Clarence A. Coates, Jr., Terry A. Oldfield, Wayne P. Pruett, Samuel D. Hilbert, Max A. Weaver
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Patent number: 5008443Abstract: Energetic binders, and, more specifically, a class of nitramine-containing homopolymers and co-polymers characterized by favorable viscosity and glass transition temperature are prepared.Type: GrantFiled: September 25, 1989Date of Patent: April 16, 1991Assignee: Olin CorporationInventors: Roger W. Day, Rahim Hani