Abstract: Sulfonated aromatic copolyesters and articles made therefrom, and processes for producing the sulfonated aromatic copolyesters and articles are provided. Articles that can be made from the sulfonated aromatic copolyesters include films, coatings and laminates. Some of the compositions and articles are biocompostable. The films can further be used to form shaped articles such as sheets, food packaging such as sandwich wraps, thermoformed containers, and coatings for, for example, films and other substrates. The sulfonated aromatic copolyesters contain a hydroxyalkanoic acid component.

Abstract: The invention is directed to polyester processes that utilizes a pipe reactor in the esterification, polycondensation, or both esterification and polycondensation processes. Pipe reactor processes of the present invention have a multitude of advantages over prior art processes including improved heat transfer, volume control, agitation and disengagement functions.

Abstract: An aliphatic polyester polyether copolymer is provided having an aliphatic polyester moiety comprising 35 to 50 molar % of an aliphatic diol unit, 35 to 50 molar % of an aliphatic dicarboxylic acid unit and 0 to 30 molar % of an aliphatic oxycarboxylic acid unit and a polyether moiety, wherein ?sp/C is not less than 1.40 and the ratio by weight of the polyether moiety to the aliphatic polyester polyether copolymer is 0.1 to 90% by weight.

Abstract: A polyester based on poly(trimethylene terephthalate) consisting essentially of trimethylene terephthalate repeating units, comprising at least one kind of compound selected from the group consisting of alkali metal compounds, alkaline earth metal compounds and manganese compounds in an amount of 10 to 150 ppm expressed in terms of the metal element in a molar ratio of the total amount of elements of the contained alkali metal elements, alkaline earth metal elements and manganese element to the amount of the contained phosphorus element within the range of the following formula (I): 0?P/M?1??(I) wherein, P is the molar amount of the phosphorus element in the polyester; M is the total amount of the alkali metal elements, alkaline earth metal elements and manganese element.

Abstract: A method of synthesizing biodegradable aliphatic polyesters from one or more aliphatic dicarboxylic acids or diesters of the said acids and one or more linear or branched aliphatic glycols, comprising a first esterification or transesterification step and a second deglycolation under vacuum step, in which the catalyst is monobutylstannoic acid both for the esterification or transesterification step and for the deglycolation under vacuum step.

Abstract: A low shrinkage, polymerizable oligomer comprises units of the structure: AB??(I) wherein A is an organic radical comprising 1 to about 6 (meth)acrylate groups and 0 to about 5 hydroxy groups; B is an organic radical comprising 1 to about 5 epoxide groups, and wherein A and B are linked through the reaction of an epoxide and a hydroxy group. In one embodiment, a dental restorative material comprises the low shrinkage, polymerizable dental oligomer, a filler system, and a curing system. These polymerizable dental resins may be used for a variety of dental materials, treatments, and restorative functions, including crown and bridge materials, fillings, adhesives, sealants, luting agents or cements, denture base materials, orthodontic materials and sealants, and other dental restorative materials.

Abstract: The present invention relates to methods of making imide-modified polyester imide resins. The present invention further relates to forming these imide-modified polyester imide resins into articles, such as preforms, bottles, containers, sheets, films, fibers, and injection molded parts.

Abstract: A coating composition comprising components A, B and optionally C, wherein component A comprises at least one hydroxy-terminated polyarylate. Component B is an organic species which can react with the hydroxy terminal groups of component A, and component C is a catalyst or mixture of catalysts. The hydroxy-terminated polyarylates are prepared by a solution polymerization method.

Abstract: Disclosed is a process for the preparation of high molecular weight polyesters by reacting one or more dicarboxylic acids directly with 1,4-cyclohexanedimethanol and, optionally, one or more diols. The process uses an overall diol to dicarboxylic acid molar ratio of about 0.97 to about 1.2 and an incremental addition of either the diacid or diol components. The process provides a shorter total reaction time and, thus, lessens the thermal degradation of polyester which may result in high color and reduced molecular weight.

Abstract: The present invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where AO is for each AO independently at each instance EO, PO or BO where EO is O—CH2-CH2- PO is independently at each instance O—CH2-CH(CH3)- or O—CH(CH3)-CH2- BO is independently at each instance O—CH2-CH(CH2-CH3)- or O—CH(CH2-CH3)-CH2- p1+p2+p3 is 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74 or 75, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.

Abstract: The present invention provides certain sulfonated copolyetherester compositions containing hydroxyalkanoic acids and processes for producing such sulfonated aromatic copolyetheresters. The invention further provides shaped articles, preferably in the shape of films, coatings and laminates, having improved thermal properties, wherein the shaped articles are produced from the certain sulfonated copolyetherester compositions. Some of these materials are also biocompostable. The sulfonated copolyetheresters are produced from a mixture of an aromatic dicarboxylic acid component, hydroxyalkanoic acid component, a sulfonate component, a poly(alkylene ether) glycol component, a glycol component, an optional other glycol component, an optional branching agent, and an optional color reducing agent.

Abstract: The invention concerns polyester resins, more particularly polyethyleneterephthalate resins used for making hollow containers, such as bottles for packaging liquid substances, in particular aerated beverages, natural or mineral waters. The invention concerns a polyester comprising at least 92.5% in number of recurrent units derived from terephthalic acid of aliphatic diols having an intrinsic viscosity ranging between 0.45 dl/g and 0.70 dl/g, and an acetaldehyde content less than 3 ppm, preferably less than 1.5 ppm. The invention also concerns a method for obtaining polyester granules with low acetaldehyde content having an intrinsic viscosity in the range mentioned above. Said polyesters are used in particular for making hollow containers such as bottles and more particularly bottles designed to contain foodstuffs sensitive to acetaldehyde.

Abstract: Biodegradable block copolyesters obtained from crystalline blocks and amorphous blocks, wherein the repeating units of both blocks are of the dicarboxylic acid/diol type. Said copolyesters are characterized by a melting temperature equal to or less than 15% lower than the starting crystalline polymer temperature, and by increased tenacity that makes them particularly useful in the production of different types of objects.

Abstract: The present invention relates to a thermoplastic elastomer resin which has good melt viscosity, melt tension, and thermal resistance, wherein it is prepared by introducing a chain extender and a stabilizer for hydrolysis to a thermoplastic elastomer resin produced through melt polymerization in the presence of hydroxy carboxylic acid compound and subjecting the mixture to reactive extrusion to increase the molecular weight and crosslinking degree of the elastomer resin. The thermoplastic elastomer resin according to the present invention has good properties for automobile parts, particularly constant velocity joint boots and bellows.

Abstract: The present invention provides certain aromatic copolyetheresters that include hydroxyalkanoic acid residues, and processes for making the copolyetheresters, and articles containing the copolyetheresters. The copolyetheresters have desirable thermal properties, and can be used in forming shaped articles, such as films, coatings and laminates. The copolyetheresters are produced from a mixture of aromatic dicarboxylic acids, hydroxyalkanoic acids, a poly(alkylene ether) glycol, a glycol component, optional other glycol, optional branching agents, and optional color reducing agent components. Some of the copolyetheresters are biocompostable.

Abstract: A water-dilutable polyester resin ABCD having a mass fraction of from 1 to 10% of units derived from unsaturated cocondensed building blocks, an olefinic double bond content of from 10 to 2 000 mmol/kg, and a sulfonic acid group content of from 20 to 300 mmol/kg, modified if desired by copolymerizing olefinically unsaturated monomers in the presence of the polyester resin, a process for preparing them, and their use in particular in one-component coating compositions in combination with amino resin curatives.

Abstract: There are disclosed polyester processes using a pipe reactor and corresponding apparatuses. In particular, there are disclosed processes and corresponding apparatuses including an esterification pipe reactor with a recirculating reaction zone (RR zone) and a plug reaction profile reaction zone (PRPR zone), especially when operated with a significant part of the overall conversion taking place in the plug reaction profile reaction zone (PRPR zone).

Abstract: A polyester resin produced by polycondensing a dicarboxylic acid component containing an aromatic dicarboxylic acid or its ester-forming derivative as the main component and a diol component containing ethylene glycol as the main component in the presence of at least an antimony compound and a phosphorus compound, via an esterification reaction or an ester exchange reaction, which is characterized in that the amount of antimony eluted when immersed in hot water of 95° C. for 60 minutes in the form of particles having a number average particle weight of 24 mg, is not more than 1 ?g per 1 g of the polyester resin, as antimony atoms (Sb).

Abstract: Polyester compositions and methods of producing and using same are provided. The polyester compositions at least include an anionic diacid monomer or diester monomer thereof and a polyether. The polyester compositions of the present invention can be effectively utilized, for example, to treat crude oil during production and refinery processing.

Abstract: Temperature sensitive, water soluble polymers are disclosed, together with a method for control the LCST of the polymer. The polymers include hydrophillic components and hydrophobic components joined by linking groups such as ester or amide groups wherein the hydrophilic components includes m ethylene oxide groups, the hydrophobic components consist of aliphatic groups such as n ethylenes and/or n cycloaliphatic groups, and where 1?m?30 and 1?n?30. Substrates bearing the grafted temperature responsive polymers also are disclosed. Microfluidic devices which include the temperature responsive polymers also are disclosed.

Abstract: This invention relates to a water-soluble fiber and a method of manufacturing the fiber. The water-soluble fiber of the invention is composed of a high molecular compound with a weight average molecular weight of not less than 10,000, which high molecular compound is obtainable by reacting a polyalkylene oxide compound, which is obtainable by addition polymerization of an ethylene oxide-containing alkylene oxide and an organic compound containing two active hydrogen atoms, with a polycarboxylic acid, an anhydride thereof, a lower alkyl ester thereof, or a diisocyanate and is manufactured by spinning the same high molecular compound. The water-soluble fiber of the invention is not only high in elongation and tensile strength but is readily soluble in water.

Abstract: Disclosed is a process that comprises contacting, in the presence of an esterification or transesterification or polycondensation catalyst composition, a toner, and a phosphorus compound, a carbonyl compound and an alcohol under a condition suitable for esterification, transesterification, or polymerization.

Abstract: A poly(trimethylene-ethylene ether) amide comprises a soft segment from poly(trimethylene-ethylene ether) glycol and a polyamide hard segment, preferably joined by ester linkages. The poly(trimethylene-ethylene ether) ester amides in accordance with the invention are particularly useful as shaped articles. The shaped articles are, preferably, prepared from fibers, fabrics or films.

Abstract: Temperature sensitive, water soluble polymers are disclosed, together with a method for control the LCST of the polymer. The polymers include hydrophillic components and hydrophobic components joined by linking groups such as ester or amide groups wherein the hydrophilic components includes m ethylene oxide groups, the hydrophobic components consist of aliphatic groups such as n ethylenes and/or n cycloaliphatic groups, and where 1?m?30 and 1?n?30. Substrates bearing the grafted temperature responsive polymers also are disclosed. Microfluidic devices which include the temperature responsive polymers also are disclosed.

Abstract: A polyether ester comprises poly(trimethylene-ethylene ether) ester soft segment and alkylene ester hard segment. Preferably, the polyether ester is a thermoplastic elastomer in which the hard segment comprises C2 to C12 alkylene ester. The composition is prepared by providing and reacting: (a) poly(trimethylene-ethylene ether) glycol (b) at least one polyester. Fiber made from this composition is particularly useful in making films, membranes and fabrics.

Abstract: The invention relates to a transparent, UV-stabilized, single or multi-layered thermoformable film which contains, as a principal constituent, a crystallizable thermoplastic, preferably polyethylene terephthalate, and at least one UV-stabilizer. The inventive films are characterized by having a good stretchability, thermoformability and good optical and mechanical properties. Said films are suitable for outdoor uses just like shaped bodies made of the same.

Abstract: An aqueous dispersion based on an amorphous unsaturated polyester resin obtained by polycondensing a mixture of Dicidol isomers and one or more saturated and/or unsaturated dicarboxylic acids.

Abstract: Allyletherester monomers to be used as an intermediate product for the production of graft copolymers and/or their salts for use as cement dispersants are prepared by an esterification reaction of ?-allyl-?-hydroxy-polyoxyalkylene refined so as to have peroxide value less than 5.0 meq/kg and aliphatic monocaboxylic acid under a specified condition in the absence of solvent and in the presence of an antioxidant.

Abstract: The invention is directed to polyester processes that utilizes a pipe reactor in the esterification, polycondensation, or both esterification and polycondensation processes. Pipe reactor processes of the present invention have a multitude of advantages over prior art processes including improved heat transfer, volume control, agitation and disengagement functions. The pipe reactor processes and apparatus of the present invention are built and operated at a much lower cost than conventional polyester processes.

Abstract: Disclosed is a polyether ester elastomer comprising a copolymer of (A) at least one aromatic dicarboxylic acid or an ester-forming derivative thereof; (B) at least one diol selected from the group consisting of an aliphatic diol and an alicyclic diol, each having 2 to 10 carbons; and (C) a polyoxytetramethylene glycol (PTMG) having a number average molecular weight of from 500 to 4000, a molecular weight distribution (Mw/Mn) of 2.0 or less, a content of high molecular weight PTMG molecules of 10% by weight or less, and a heteropolyacid content of from 10 to 900 ppb by weight, wherein the polyether ester elastomer contains PTMG units in an amount of from 10 to 90% by weight, based on the weight of the polyether ester elastomer.

Abstract: The present invention is to provide a production method of chemical reactive substances with stable quality by which solidification, gel formation, and the resulting blockade within material injection nozzles are prevented, and contamination of a reaction system with the gelled matter is prevented, as well as occurrence of problems on a production process due to the gelled matter is suppressed, when the chemical reactive substances are produced by injecting the liquid materials containing reactive substances having unsaturated double bonds into the reaction vessel through the material injection nozzles of the reaction vessel. The present invention is a production method of a chemical reactive substance which comprises injecting a liquid material containing a reactive substance having an unsaturated double bond into a reaction vessel through a material injection nozzle of said reaction vessel and causing a reaction at a reaction temperature of not less than 50° C.

Abstract: The present invention relates to a thermoplastic resin composition comprising an ethylene-vinyl alcohol copolymer and a modified polyester type thermoplastic elastomer produced by modifying a polyester type thermoplastic elastomer with an unsaturated carboxylic acid or its derivative, and a multi-layer laminate comprising a layer A comprising the thermoplastic resin composition as defined in the above, and at least one layer B comprising a thermoplastic resin composition other than the composition as defined in the above.

Abstract: Liquid composition which can be polymerized into organic glasses, by means of radical polymerization with low shrinkage, comprising the product obtained from the trans-esterification of a diallycarbonate (A) with a mixture of one or more linear or branched aliphatic diols (B), containing from three to ten carbon atoms in the molecule, with a linear or branched aliphatic polyol (C), containing from four to twenty carbon atoms and from three to six hydroxyl groups in the molecule. The molar ratio A/(B+C) in the above polymerizable liquid composition ranges from 2/1 to 5/1 and the quantity of (C) in the mixture (B+C) is equal to or less than 25% by weight with respect to the total weight of this mixture.

Abstract: Temperature sensitive, water soluble polymers are disclosed, together with a method for control the LCST of the polymer. The polymers include hydrophillic components and hydrophobic components joined by linking groups such as ester or amide groups wherein the hydrophilic components includes m ethylene oxide groups, the hydrophobic components consist of aliphatic groups such as n ethylenes and/or n cycloaliphatic groups, and where 1≦m≦30 and 1≦n≦30. Substrates bearing the grafted temperature responsive polymers also are disclosed. Microfluidic devices which include the temperature responsive polymers also are disclosed.

Abstract: The present invention is directed to a series of polyester compounds made from the reaction of (a) a difunctional hydroxy compound, specifically polyoxyalkylene glycols, (b) a difunctional carboxylic acid, specifically dimer acid and hydrogenated dimer acid, and (c) a capping carboxylic acid, which only contains one acid group. These compounds are very well suited to the preparation of products for the personal care market.

Abstract: The present invention provides a process for the preparation of low styrene content resins prepared by first reacting an unsaturated carboxylic acid, its corresponding anhydride or mixtures thereof with a monohydric alcohol, DCPD and water and reacting the product of the first step with a polyol and optionally an oil containing unsaturation, its corresponding fatty acid or mixtures thereof.

Abstract: Process for the preparation of heat-stable, antimony-free polyesters of neutral color and the products which can be prepared by this process A process for the preparation of heat-stable, antimony-free polyesters of neutral color by esterification of aromatic dicarboxylic acids or transesterification of lower aliphatic esters of aromatic dicarboxylic acids with aliphatic diols and subsequent polycondensation in which a possible transesterification is carried out in the presence of 20 to 120 ppm, based on the catalyst metal, of a transesterification catalyst, after the esterification or transesterification has ended, phosphoric acid, phosphorous acid and/or phosphonic acids or a derivative thereof are added to the esterification or transesterification batch as a completing agent in an amount which is 100% of the amount equivalent to the transesterification catalyst employed and up to 99% of the amount equivalent to the cobalt to be employed, up to 80 ppm of cobalt in the form of a cobalt compound are then adde

Abstract: Disclosed is a sequentially ordered biodegradable lactide (or glycolide or lactide/glycolide)/&egr;-caprolactone multi-block copolymers having proper degradation properties and enhanced mechanical properties such as flexibility and elasticity and a process for the preparation thereof.

Abstract: A PCT copolyester composition having at least about 70 mole % terephthalic acid and at least about 70 mole % 1,4-cyclohexanedimethanol and an inherent viscosity of greater than about 0.9 dL/g is prepared by solid state polymerizing a copolyester composition having a starting inherent viscosity of from about 0.4 to about 0.8 dL/g for a period of from about 1 minute to 100 hours and at a temperature of from about 140° C. to about 2° C. below the melting point of the copolyester to produce a copolyester having an inherent viscosity of greater than about 0.9 dL/g. Another aspect of the present invention is an extrusion blow molded article made from the copolyester prepared by the solid state polymerization process.

Abstract: A polyester resin produced by polycondensing a dicarboxylic acid component containing an aromatic dicarboxylic acid or its ester-forming derivative as the main component and a diol component containing ethylene glycol as the main component in the presence of at least an antimony compound and a phosphorus compound, via an esterification reaction or an ester exchange reaction, which is characterized in that the amount of antimony eluted when immersed in hot water of 95° C. for 60 minutes in the form of particles having a number average particle weight of 24 mg, is not more than 1 &mgr;g per 1 g of the polyester resin, as antimony atoms (Sb).

Abstract: This invention concerns a method for increasing the polymerization rate of polyester polymers in the solid state by adding a catalytic amount of zinc p-toluenesulfonate to a polyester polymer melt that is essentially free of antimony and germanium, before solid state polymerization.

Abstract: Liquid composition polymerizable, by means of radicalic polymerization, into organic glass, comprising the product obtained from the transesterification of a mixture of diallyl carbonate (A) and a phthalic ester (B), with one or more polyols (C), linear or branced, containing from two to eight carbon atoms in the molecule.

Abstract: The present invention relates to a non crosslinked block polymer. It also relates to a process for the preparation thereof and to the use thereof particularly in pharmaceutical compositions. The block polymer according to the invention contains sequences of polyethylene glycol linked to sequences of polyester and/or polycarbonate. The polyester sequences are selected in particular from polyfumarate, polymaleate and polysuccinate sequences.

Abstract: The present invention provides poly(trimethylene terephthalate) copolymerized with ester-forming sulfonate and a fiber thereof. The polymer of the present invention is high in melting point, small in loss of melting viscosity and has a high molecular weight. The fiber of the present invention is high in toughness, excellent in whiteness and dyeable with a cationic dye, whereby it is useful for clothing, carpets or non-woven sheets, etc.

Abstract: The invention relates to flame-retardant, unsaturated polyester resins made from unsaturated and saturated dicarboxylic acids and/or their anhydrides, from polyhydric alcohols, from one or more monomers and from a reactive phosphorus compound, which contain structural units of the formula IV where R1 is straight-chain or branched alkyl, cycloalkyl, aryl or alkylaryl groups having from 1 to 18 carbon atoms and R2 is methyl or hydrogen. The invention likewise relates to a process for preparing such polyester resins and to their use.

Abstract: This invention relates to a water-soluble fiber and a method of manufacturing the fiber. The water-soluble fiber of the invention is composed of a high molecular compound with a weight average molecular weight of not less than 10,000, which high molecular compound is obtainable by reacting a polyalkylene oxide compound, which is obtainable by addition polymerization of an ethylene oxide-containing alkylene oxide and an organic compound containing two active hydrogen atoms, with a polycarboxylic acid, an anhydride thereof, a lower alkyl ester thereof, or a diisocyanate and is manufactured by spinning the same high molecular compound. The water-soluble fiber of the invention is not only high in elongation and tensile strength but is readily soluble in water.

Abstract: Polyesters suitable as plasticizers and obtainable by reacting aliphatic dicarboxylic acids, neopentyl glycol, at least one other diol and a nonanol mixture, where the nonanol mixture is mainly composed of 1-nonanol, of monomethyloctanols, of dimethylheptanols and of monoethylheptanols. The nonanol mixture is also described, as is the use of the plasticizers.

Abstract: Applicant has discovered processes for preparing polyglycerols and polyglycerol esters in high yield and with minimal formation of cyclic polyglycerols and cyclic polyglycerol esters. Furthermore, the processes of this invention produce a high proportion of linear polyglycerols and polyglycerol esters. The linear polyglycerols have very desirable physical characteristics, including a clear appearance at melt, a desirable Gardner color, a mild odor, and a bland taste. The polyglycerols and polyglycerol esters prepared by the method of the present invention are well suited for use as cosmetic and food additives. Since few, if any, cyclic polyglycerols and polyglycerol esters are formed by the processes of this invention, costly and time consuming distillation steps to remove such by-products are not needed.

Abstract: A process for preparing polyester pellets which involves blending polyethylene terephthalate and polyethylene isophthalate copolymer before solid state polymerization, the polyethylene isophthalate copolymer being composed of dicarboxylic acid constituent units derived from dicarboxylic acids containing terephthalic acid and isophthalic acid and diol constituent units derived from diols containing ethylene glycol and 1,3-bis(2-hydroxyethoxy)benzene, palletizing the blend and crystallizing the pellets.

Abstract: A polyether ester elastomer comprising about 90-about 60 weight % polytrimethylene ether ester soft segment and about 10-about 40 weight % trimethylene ester hard segment, and use thereof in fibers and other shaped articles. The fibers have excellent physical properties, including superior strength and stretch recovery.