Acyclic Ether-oxygen Compound Patents (Class 528/301)
  • Patent number: 6184332
    Abstract: The invention concerns novel polyester polyols and their use as the polyol component in two-component polyurethane paints. The polyester polyols produce films which display exceptional properties after hardening. Owing to the low solvent requirement when reaction paints are prepared, they are particularly environmentally friendly. The permanence of the gloss of the hardened coatings should be stressed in particular.
    Type: Grant
    Filed: July 10, 1998
    Date of Patent: February 6, 2001
    Assignee: Synthopol Chemie Dr. rer. pol. Koch GmbH & Co. KG
    Inventor: Antonio Manuel Dos Santos
  • Patent number: 6172159
    Abstract: A water-reducible polyester resin for use in producing urethane coatings comprises the reaction product of: a) hexahydrophthalic anhydride, trimellitic anhydride or phthalic anhydride; b) 1,4-cyclohexane dimethanol or trimethylol propane or mixtures thereof; and c) a polyethylene glycol selected from the group consisting of polyethylene glycols, methoxy polyethylene glycols and trifunctional polyethylene glycols having a molecular weight no greater than approximately 1050; the reaction product having a functionality between approximately 2 and 2.6. Another water-reducible polyester resin comprises the same components and a specified nonionic surfactant. Urethane coatings containing such polyester resins and a diisocyanate are also disclosed.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: January 9, 2001
    Assignee: Accures Corporation
    Inventors: Robert J. Gaal, Jr., Roger W. Heitland
  • Patent number: 6169131
    Abstract: The invention relates to a plastic sheeting which is suitable, in particular, for application in the construction industry. It is obtained by employing polyetherester block copolymers and has good humidity-regulating properties and water impermeability. Flame retardancy in accordance with DIN 4102 B2 is obtained by employing melamine, melamine compounds or melamine condensates in the polyetherester composition for the sheeting.
    Type: Grant
    Filed: June 22, 1998
    Date of Patent: January 2, 2001
    Assignee: DSM N.V.
    Inventors: Henricus J. J. Goertz, Richerdes J. M. Hulskotte, Reinoldus J. M. Borggreve
  • Patent number: 6162890
    Abstract: Disclosed are linear, water-dispersible sulfopolyesters incorporating a low molecular weight polyethylene glycol and blocks of a high molecular weight polyethylene glycol. The block sulfopolyesters have improved toughness, abrasion resistance, flexibility, and adhesion. Particular utility is realized in polyester fiber sizing applications and as an adhesive.
    Type: Grant
    Filed: October 20, 1997
    Date of Patent: December 19, 2000
    Assignee: Eastman Chemical Company
    Inventors: Scott Ellery George, Bobby Jones Sublett, Richard Anthony Miller
  • Patent number: 6153723
    Abstract: The invention relates to oligoesters obtained by polycondensation ofa) from 40 to 52 mol %, preferably from 45 to 50 mol %, of one or more dicarboxylic acids or esters thereof,b) from 10 to 40 mol %, preferably from 20 to 35 mol %, of ethylene glycol and/or propylene glycol,c) from 3 to 20 mol %, preferably from 10 to 15 mol %, of polyethylene glycol,d) from 0.5 to 10 mol %, preferably from 1 to 7.5 mol %, of a water-soluble addition product of from 5 to 80 mol of an alkylene oxide with 1 mol of C.sub.1 -C.sub.24 -alcohols, C.sub.6 -C.sub.18 -alkylphenols or C.sub.8 -C.sub.24 -alkylamines ande) from 0.4 to 10 mol %, preferably from 0.5 to 8 mol %, of one or more polyols having from 3 to 6 hydroxyl groups.These oligoesters are used as soil release polymers in detergents.
    Type: Grant
    Filed: June 10, 1999
    Date of Patent: November 28, 2000
    Assignee: Clariant GmbH
    Inventors: Frank-Peter Lang, Johannes Becherer, Michael Wessling, Alexander Lerch
  • Patent number: 6147168
    Abstract: The present invention describes a polyoxaester copolymer and blends thereof that may be used to produce hydrogels, surgical devices such as sutures, sutures with attached needles, molded devices, drug matrices, adhesives, sealants and the like. The invention also contemplates a process for producing these polyesters. The polyoxaester copolymers of the present invention are formed from a first divalent repeating unit of formula IA:[--O--C(O)--R.sub.30 --C(O)--] IAa second divalent repeating unit of the formula IB:[O--C(O)--C(R.sub.1)(R.sub.2)--O--R.sub.3 --O--C(R'.sub.1)(R'.sub.2)--C(O)--] IBand a third repeating unit selected from the group of formulas consisting of:[--O--R.sub.4 --].sub.A, II[--O--R.sub.5 --C(O)--].sub.B, III([--O--R.sub.5 --C(O)].sub.P --O--).sub.L G XIand combinations thereof. These aliphatic polyoxaesters may be blended with other polymers that are preferably biocompatable.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: November 14, 2000
    Assignee: Ethicon, Inc.
    Inventors: Dennis D. Jamiolkowski, Rao S. Bezwada
  • Patent number: 6147016
    Abstract: A laminate sheet comprising (A) a polyester block copolymer which comprises 20 to 70 wt % of a hard segment consisting of an aromatic polyester and 80 to 30 wt % of a soft segment consisting of an aromatic polyester and (B) cloth on at least one side of which the polyester block copolymer is laminated, the melting point (T,.degree. C.) of the polyester block copolymer satisfying the following expressions: T0-5 >T>T0-60 and T>T'+10 (in which T is defined above, T0 is a melting point (0.degree. C.) of the aromatic polyester constituting the hard segment, and T' is a melting point (.degree. C.) of a random polymer obtained by adding 0.1 wt % of titanium tetrabutoxide to the polyester block copolymer and melting and kneading at 250.degree. C. for 3 hours).
    Type: Grant
    Filed: July 31, 1998
    Date of Patent: November 14, 2000
    Assignee: Teijin Limited
    Inventors: Noritugu Saiki, Hodaka Yokomizo
  • Patent number: 6133404
    Abstract: A biodegradable polyester is formed by carrying out esterification and polycondensation with a carboxylic acid monomer group comprising at least one aliphatic dicarboxylic acid containing 2 to 14 carbon atoms and at least one aromatic or alicyclic carboxylic acid, and at least one glycol in the presence of a composite catalyst comprising a titanium compound, a zinc compound, an antimony compound and a phosphorous compound. The composite catalyst significantly improves the reaction rate of polyester polymerization as well as increases the production amounts of the polyester, as compared with conventional catalysts. The polyester is high in molecular weight, excellent in thermal and mechanical properties by virtue of the introduction of the aromatic or alicyclic carboxylic acid or its derivative, in addition to showing good biodegradability. This polyester can replace preexisting, expensive aliphatic polyesters.
    Type: Grant
    Filed: February 2, 1999
    Date of Patent: October 17, 2000
    Assignee: National Institute of Technology and Quality
    Inventors: Hye Jung Kang, Sang Soon Park, Yong Joo Kim
  • Patent number: 6124423
    Abstract: A process for crystallizing a polyethylene naphthalate copolymer by:a) copolymerizing at least 60 mole % of 2,6-naphthalene dicarboxylic acid, based on the total moles of carboxylic acids, with polyols such as at least 80 mole % of ethylene glycol and from 2 mole % to 20 mole % of a polyol having three or more carbon atoms, each based on the total moles of polyols, to form PEN copolymer solids, andb) subsequently crystallizing the PEN copolymer solids by heating the solids to at least their sticking temperature at an average rate of at least 10.degree. C./min, to form agglomerate-free crystallized solids.The process may be performed under agitation. The pellets heated up in a during the crystallization step do not agglomerate or suddenly expand as the temperature rises to and through the sticking temperature of the PEN copolymers. The process allows one to rapidly heat up PEN during crystallization, and do so without conducting a prior drying step or a devolitilization step.
    Type: Grant
    Filed: June 24, 1999
    Date of Patent: September 26, 2000
    Assignee: Shell Oil Company
    Inventors: Ben Duh, Edwin Andrew Sisson, Douglas David Callander
  • Patent number: 6124043
    Abstract: A biaxially oriented film (1) which is substantially formed from a polyethylene naphthalate copolymer comprising ethylene-2,6-naphthalate units in an amount of 90 to 99.9 mol % based on the total of all recurring units and an isophthalic acid component or a decalin-2,6-dicarboxylic acid component in an amount of 0.1 to 10 mol % based on the total of all dicarboxylic acid components and which has (2) Young's modulus of 500 kg/mm.sup.2 or more in each of a longitudinal direction and a transverse direction, (3) a plane orientation coefficient of 0.230 to 0.275 and (4) a density of 1.350 g/cm.sup.3 or more.
    Type: Grant
    Filed: June 28, 1999
    Date of Patent: September 26, 2000
    Assignee: Teijin Limited
    Inventors: Ryoji Tsukamoto, Seiji Ito, Mitsuru Teramoto, Shinya Watanabe, Koji Furuya, Shinichi Kawai, Kenji Suzuki
  • Patent number: 6120895
    Abstract: Biodegradable polyesters based onA) 95-99.99 mol % of at least one polyester A containing as monomeric building blocks of an acid component comprisinga.sub.11) 20-95 mol % of at least one aliphatic or cycloaliphatic dicarboxylic acid or its ester-forming derivative anda.sub.12) 5-80 mol % of at least one aromatic dicarboxylic acid or its ester-forming derivative andat least one dihydroxy compound or at least one amino alcohol or their mixtures, andB) 0.01-5 mol % of a mixture comprising mono-, bi-, tri-, tetra- and higher-nuclear isocyanurates or corresponding compounds containing two, three or four functional groups capable of reacting with the end groups of polyester A, or mixtures of the isocyanurates and the corresponding compounds,as well as molding compositions comprising said polyesters, their manufacture and their use in the manufacture of moldings, filsm, fibers and coatings.
    Type: Grant
    Filed: March 17, 1999
    Date of Patent: September 19, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Christoph Kowitz, Peter Bauer, Dieter Bernhard Beimborn, Bernd Bruchmann, Uwe Faller, Martin Laun, Udo Pagga, Gunter Pipper, Volker Warzelhan
  • Patent number: 6114458
    Abstract: A branched radial block copolymer including the reaction product of a dendritic macromolecular initiator, and one or more chain extending monomers.
    Type: Grant
    Filed: September 23, 1998
    Date of Patent: September 5, 2000
    Assignee: International Business Machines Corporation
    Inventors: Craig Jon Hawker, James Lupton Hedrick, Olof Mikael Trollsas
  • Patent number: 6107446
    Abstract: The invention relates to a process for preparing polyester resins by first reacting a carboxylic acid or its corresponding anhydride with a saturated monohydric alcohol to form the half ester and then reacting the half ester with a polyol.
    Type: Grant
    Filed: December 2, 1999
    Date of Patent: August 22, 2000
    Assignee: Ashland Inc.
    Inventors: Roman Loza, Patricia McDaniel
  • Patent number: 6080834
    Abstract: A catalyst composition is disclosed. The composition comprises a titanium compound, a complexing agent, a solvent, and optionally a cocatalyst. The cocatalyst can be a cobalt/aluminum catalyst, an antimony compound, or combinations thereof. Also disclosed is a process for producing the composition. The process comprises combining a titanium compound, a complexing agent, a solvent, and optionally a cocatalyst. Further disclosed is a process for using the composition which comprises contacting a carbonyl compound, in the presence of the composition, with an alcohol under a condition suitable for esterification, transesterification, polymerization, or combinations thereof.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: June 27, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Donald Edward Putzig, Edward Francis McBride, Hiep Quang Do, James Arthur Trainham, Hermann Ludwig Jaeger, Heiner Schulte
  • Patent number: 6074660
    Abstract: The present invention describes a polyoxaester copolymers containing amines and/or amido groups and blends thereof with other polymers that may be used to produce surgical devices such as sutures, sutures with attached needles, molded devices, and the like. The polyoxaesters copolymer of the present invention is formed from a first divalent repeating unit of formula IA:[--C(O)--R.sub.30 --C(O)--] IAa second divalent repeating unit of the formula IB:[O--C(O)--C(R.sub.1)(R.sub.2)--O--(R.sub.3)--O--C(R.sub.1)(R.sub.2)--C(O)-- ]Iand a third repeating unit of the formula:[--O--R.sub.12 --].sub.U, XVIand optionally a fourth repeating unit with a formula selected from the group consisting of:[--O--R.sub.4 --].sub.A, II[--O--R.sub.5 --C(O)--].sub.B, III([--O--R.sub.5 --C(O)].sub.P --O--).sub.L G XIand combinations thereof wherein R.sub.12 contains an internal amine or internal amide group.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: June 13, 2000
    Assignee: Ethicon, Inc.
    Inventors: Dennis D. Jamiolkowski, Rao S. Bezwada
  • Patent number: 6068910
    Abstract: A polyester resin composition is calendered to produce a film or a sheet. The polyester resin composition is a polyester having a crystallization half time from a molten state of at least 5 minutes combined with an additive for preventing sticking of the polyester to calendering rolls.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: May 30, 2000
    Assignee: Eastman Chemical Company
    Inventors: Paul Mary Flynn, Richard Leon McConnell, Hubertus Jacobus Wilhelmus Moolenaar, Timothy Michael Sanders
  • Patent number: 6069227
    Abstract: The present invention relates to curable coatings comprising oligomeric condensation products of aromatic tri- or tetracarboxylic acids and dihydroxyalkyl (meth)acrylates.
    Type: Grant
    Filed: September 9, 1998
    Date of Patent: May 30, 2000
    Assignee: Bayer A.G.
    Inventors: Wolfgang Podszun, Ludger Heiliger, Michael Mager
  • Patent number: 6066714
    Abstract: A catalyst composition is disclosed. The composition comprises a titanium compound, a phosphorus compound, an amine, a solvent and optionally a cocatalyst in which the phosphorus compound has a formula selected from the group consisting of (R.sup.1 O).sub.x (PO)(OH).sub.3-x, (R.sup.1 O).sub.y (P.sub.2 O.sub.3)(OH).sub.4-y, and combinations thereof; the amine is a tertiary amine; each R.sup.1 is independently a linear or branched alkyl radical containing from 1 to about 20 carbon atoms per radical; x is 1 or 2; and y is 1, 2, or 3; and the cocatalyst can be a cobalt/aluminum catalyst, an antimony compound, or combinations thereof. Also disclosed is a process for producing the composition. The process comprises combining a titanium compound, a phosphorus compound, a solvent, an amine, a solvent, and optionally a cocatalyst. The phosphorus compound, amie, and solvent are the same as those disclosed above.
    Type: Grant
    Filed: April 15, 1999
    Date of Patent: May 23, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Donald Edward Putzig, Edward Francis McBride, Hiep Quang Do, James Arthur Trainham, Hermann Ludwig Jaeger, Heiner Schulte
  • Patent number: 6063465
    Abstract: A polyester container made from a polymer having ethylene glycol moieties, isosorbide moieties and terepthaloyl moieties, and the method of making the container is described. The polyester container is suitable for holding liquids and solids, and may be hot-filled or cold-filled. In particular, wide-mouth jars and narrow-necked bottles may be formed. The polyester has an inherent viscosity of at least 0.35 dL/g when measured as a 1% (weight/volume) solution of the polyester in o-chlorophenol at a temperature of 25.degree. C.
    Type: Grant
    Filed: April 23, 1998
    Date of Patent: May 16, 2000
    Assignee: HNA Holdings, Inc.
    Inventors: Larry F. Charbonneau, Robert E. Johnson
  • Patent number: 6048957
    Abstract: The present invention relates to a process for producing polyesters displaying exceptionally low acetaldehyde concentrations and good clarity comprising the steps of:polycondensing in the melt phase, a polyester monomer/oligomer mixture under conditions sufficient to form a precursor having in intrinsic viscosity less than 75% of a possible maximum intrinsic viscosity; andsolid stating said precursor under conditions sufficient to increase said intrinsic viscosity at least about 0.05 dl/g.
    Type: Grant
    Filed: April 24, 1998
    Date of Patent: April 11, 2000
    Assignee: Eastman Chemical Company
    Inventors: Michael Paul Ekart, James Earl Hataway, Perry Michael Murdaugh, Gary Walton Popwell
  • Patent number: 6046253
    Abstract: An ink jet ink composition comprising from about 0.5% to about 30% by weight of a pigment, a carrier and a sulfonated polyester dispersant in a ratio of dispersant:pigment from about 0.1:1 to about 5:1.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: April 4, 2000
    Assignee: Eastman Kodak Company
    Inventors: David Erdtmann, Elizabeth G. Burns, John Dicillo
  • Patent number: 6034202
    Abstract: The invention provides non-antimony containing polymerization catalysts for the condensation of polyesters. The catalyst is in the form of a clear chlorine and/or bromine containing solution of a metal glycoxide and a metal glycolate having a pH in the range of from 0 to about 1, and containing chlorine and/or bromine atoms at a number ratio of chlorine and/or bromine to total metal cations in the catalyst ranging from about 0.5:1 to about 3:1. Polyesters produced with this catalyst have improved melt elasticity, and higher melt viscosity. The former property is desirable for the preparation of large and complex shaped polyester containers, and the latter property is desirable for melt spinning of industrial grade fibers and tire cords.
    Type: Grant
    Filed: March 1, 1999
    Date of Patent: March 7, 2000
    Assignee: AlliedSignal Inc.
    Inventors: Shaul Moshe Aharoni, Konstantin Nikolaev Goranov
  • Patent number: 6028019
    Abstract: A water vapor permeable, waterproof polyether ester membrane contains 1 to 10% by weight of finely dispersed carbon particles, especially soot particles, having an average size of 5 to 40 nm.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: February 22, 2000
    Assignee: Akzo Nobel, NV
    Inventors: Jozef Christiaan Wilhelmus Spijkers, Henricus Joannes Maria Van De Ven
  • Patent number: 6027818
    Abstract: Copolyether ester elastomers are provided which contain epoxide compounds. The compositions show improved bloom resistance in the presence of diamines with minimum increase in melt viscosity. Also disclosed are methods to improve appearance and eliminate bloom from finished products comprising thermoplastic copolyesters by lowering the level of acid terminated oligomers in the thermoplastic copolyesters with epoxide compounds.
    Type: Grant
    Filed: June 11, 1999
    Date of Patent: February 22, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: James Michael McKenna
  • Patent number: 6020420
    Abstract: This invention provides crystalline, water-dispersible polyesters comprising residues of 4,4'-biphenyl dicarboxylic acid. The polyesters comprise residues of 4,4'-biphenyl dicarboxylic acid, at least one difunctional sulfomonomer in an amount sufficient to provide water dispersibility to the polyester, and a glycol or a mixture of glycols. The polyesters of the invention are useful in ink and adhesive compositions.
    Type: Grant
    Filed: March 10, 1999
    Date of Patent: February 1, 2000
    Assignee: Eastman Chemical Company
    Inventor: Scott Ellery George
  • Patent number: 6001910
    Abstract: A remoistenable hot melt adhesive composition comprising (i) 25 to 80% by weight of a sulfonated polyester;(ii) 3 to 40% by weight of an anionic or cationic plasticizer;(iii) 0 to 40% by weight of a polar tackifier;(iv) 0 to 3% by weight of an antioxidant; and(v) 10 to 35% by weight of a polar wax; and(vi) optionally 0 to 30% nonionic plasticizer, wherein the total of (i)-(vi) to equal 100% by weight.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: December 14, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Mitchell J. Blumenthal, Charles W. Paul, Matthew L. Sharak
  • Patent number: 5990265
    Abstract: Disclosed herein is a novel physical form of low molecular weight poly(trimethylene terephthalate). This form may be produced from molten low molecular weight poly(trimethylene terephthalate) material by means of rapid heat transfer from the material. The poly(trimethylene terephthalate) composition is suitable for use as a starting material for solid-state polymerization in order to produce polymers of higher molecular weight.
    Type: Grant
    Filed: June 22, 1998
    Date of Patent: November 23, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Elwood Neal Blanchard, Craig Robert Gochanour, Kenneth Wayne Leffew, Jan M. Stouffer
  • Patent number: 5973104
    Abstract: A film-formable high molecular polyetherpolyester comprising structural unit (1) of formula (1) and functional group (2) of formula (2) and having a number-average molecular weight of 40,000 to 10,000,000, wherein the molar ratio of functional group (2) to R in the polyetherpolyester is in the range of 1.0 to 3.0. This polyetherpolyester can be produced by carrying out a chain extension reaction of a low molecular polyalkylene oxide of 1,000 to 30,000 in number-average molecular weight with a polyvalent acid anhydride at 0.003 MPa or higher in a molar ratio of (acid anhydride group)/(hydroxyl group)=0.8 to 1.0.
    Type: Grant
    Filed: October 21, 1997
    Date of Patent: October 26, 1999
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Teruki Matsushita, Hiroshi Itoh, Hiroya Kobayashi, Koji Fukuhara, Yoshinobu Yamamoto
  • Patent number: 5962626
    Abstract: The present invention provides a polyethylene glycol (PEG) ester surfactant comprising at least one polyethylene glycol moiety and at least one fatty acyl moiety characterized in that said moieties are linked by a linkage incorporating a biodegradable methylene diester unit of formula (I)--CO.O.C(R.sup.1)(R.sup.2).O.CO-- (I)where R.sup.1 and R.sup.2 may, for example, each be a hydrogen atom or a monovalent organic group attached through a carbon atom or R.sup.1 and R.sup.2 together may, for example, form a divalent organic group attached through carbon atoms.
    Type: Grant
    Filed: November 25, 1997
    Date of Patent: October 5, 1999
    Assignee: Nycomed Imaging AS
    Inventors: Per Strande, Harald Dugstad, Balin Balinov, Jan Alfheim, Joseph Arukwe
  • Patent number: 5959067
    Abstract: The current invention relates to an alkyd resin particularly useful in high-solids coating compositions. The alkyd resin comprises the reaction product of an unsaturated fatty acid, a polyol, and the adduct of an .alpha.,.beta.-unsaturated dicarboxylic acid to an unsaturated fatty acid wherein the resin containsa) about 5 to about 40 weight % of the adduct of an .alpha.,.beta.-unsaturated dicarboxylic acid to an unsaturated fatty acid,b) about 50 to about 90 weight % of an unsaturated fatty acid which is not part of an adduct,c) about 8 to about 18 weight % of a polyol free from carboxylic groups,d) about 1 to about 30 weight % of an at least two hydroxyl groups-containing monocarboxylic acid,e) optionally, up to about 10 weight % of a dicarboxylic and/or a tricarboxylic acid, andf) optionally, up to 15 weight % of one or more monomers other than the monomers (a) through (e).Also disclosed is their use in coating compositions, particularly high-solids coating compositions having a VOC of less than 170.
    Type: Grant
    Filed: September 23, 1998
    Date of Patent: September 28, 1999
    Assignee: Akzo Nobel N.V.
    Inventors: Petrus Josephus Bakker, Dick Boekee
  • Patent number: 5958552
    Abstract: A laminated film comprising (A) an aromatic polyester film; and (B) a hydrophilic coating layer which is present on at least one side of the aromatic polyester film (A) and has a surface energy of at least 54 dyne/cm, the coating layer comprising (a) 50 to 80% by weight of a copolyester which contains a dicarboxylic acid component having a sulfonate group in an amount of 1 to 16 mol % of the total of all dicarboxylic acid components and has a secondary transition point of 20 to 90.degree. C., (b) 10 to 30% by weight of poly(alkylene oxide) homopolymer having a number average molecular weight of 600 to 2,000, and (c) 3 to 25% by weight of fine particles having an average particle diameter of 20 to 80 nm, based on the total of components (a), (b) and (c). The above laminated film is useful as a transparency for an overhead projector and a recording paper for an ink jet printer.
    Type: Grant
    Filed: February 26, 1996
    Date of Patent: September 28, 1999
    Assignee: Teijin Limited
    Inventors: Masayuki Fukuda, Hiroshi Tomita
  • Patent number: 5958567
    Abstract: The present invention relates to a polyester ether film comprising a polyester ether comprising a dicarboxylic acid moiety comprising principally terephthalic acid, its ester derivative or a mixture thereof, and a diol moiety comprising principally tetramethylene glycol and polytetramethylene oxide glycol, the percentage of the polytetramethylene oxide glycol residue in said polyester ether being 1 to 30% by weight based on the weight of said polyester ether.
    Type: Grant
    Filed: December 1, 1998
    Date of Patent: September 28, 1999
    Assignee: Mitsubishi Engineering-Plastics Corporation
    Inventors: Nobukatsu Wakabayashi, Katsuhiko Sugiura, Tatsuhiko Hatakeyama
  • Patent number: 5955550
    Abstract: This invention relates to a polymeric vehicle which reduces or eliminates VOCs in coating compositions by providing a formulated coating composition which does not require an organic solvent for application to a substrate. The polymeric vehicle of the invention comprises at least one linear oligoester diol effective for crosslinking with a crosslinker, and having a number average molecular weight within controlled limits of a polydispersity index effective for controlling the viscosity of the polymeric vehicle.
    Type: Grant
    Filed: November 10, 1997
    Date of Patent: September 21, 1999
    Assignees: Exxon Chemical Patents, Inc., Eastern Michigan University
    Inventors: Frank N. Jones, Shou-Kuan Fu, Xiaoying Yuan, Jun Hua, Vijay Swarup
  • Patent number: 5952436
    Abstract: A general approach to making water-resistant polyetherester resins and thermosets is disclosed. In one aspect, an unsaturated polyetherester resin prepared by inserting a carboxylic acid derivative into a polyether is co-cured with a vinyl monomer and a di- or polyisocyanate to give a water-resistant, thermoset that has excellent dimensional stability, flexibility, and strength properties. Processes for making low-viscosity resins that give thermosets with good water resistance are also described. In one process, an unsaturated polyetherester resin intermediate reacts with a mono-functional isocyanate or fatty alcohol to produce an easy-to-formulate, low-viscosity, low-molecular-weight capped resin.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: September 14, 1999
    Assignee: Arco Chemical Technology, L.P.
    Inventors: Gangfeng Cai, Jeffrey A. Klang, Lau S. Yang
  • Patent number: 5939138
    Abstract: A treatment for reducing friction of seat belts which is characterized by containing therein a polyether polyester having an average molecular weight of 2000-15000 which is obtained from a polyether diol and an aliphatic carboxylic acid, and preferably further containing a silicone compound. This treatment can be applied to either seat belt yarns in the yarn-making step or to seat belt webbing. The resulting seat belt is superior in slip properties and retains them even after wear. It is also superior in retractiablity and wear resistance (durability).
    Type: Grant
    Filed: October 6, 1997
    Date of Patent: August 17, 1999
    Assignee: Toray Industries, Inc.
    Inventors: Hideo Nagahara, Hiroyuki Terasawa, Isoo Saito, Eiji Ohtsubo
  • Patent number: 5936045
    Abstract: Biodegradable polymers comprising a polyether ester P1 obtained by reactinga first mixture of20-95 mol% of adipic acid or ester-forming derivatives thereof or mixtures thereof,5-80 mol% of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and0-5 mol% of a compound containing sulfonate groups,and a second mixture of15-99.8 mol% of a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,85-0.2 mol% of a dihydroxy compound IHO--?(CH.sub.2).sub.n --O!.sub.m --H(n=2, 3 or 4, m=2-250)with0-5 mol%, based on the first mixture, of a compound D having at least three groups capable of ester formation,and a bisoxazoline C1, their preparation and their use in the manufacture of biodegradable molding materials.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: August 10, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Warzelhan, Gunter Pipper, Ursula Seeliger, Peter Bauer, Dieter Bernhard Beimborn, Motonori Yamamoto
  • Patent number: 5922474
    Abstract: The present invention relates to polyesters formed by reacting components comprising: (a) from about 20 to about 45 mol% of a diol; (b) from about 4 to about 25 mol% of a polyol; (c) from about 5 to about 25 mol% of a diacid; (d) up to 6 mol% of an ethylenically unsaturated anhydride; and (e) from about 35 to about 45 mol% of a monofunctional fatty acid, where all mole percentages are based on the total mols of (a), (b), (c), (d) and (e). Further, the present invention is directed to liquid enamel compositions comprising: (1) from about 50 to about 90 wt. % of a polyester of the present invention; (2) about 10 to about 50 wt. % of a crosslinking agent; and (3) less than about 20 wt. % of a suitable organic solvent; where all weight percentages are based on the total weight of (1), (2) and (3). The liquid enamel compositions of the present invention have a viscosity of 50 to 1,000 mPa s (cP) at room temperature.
    Type: Grant
    Filed: January 22, 1998
    Date of Patent: July 13, 1999
    Assignee: Eastman Chemical Company
    Inventor: Thauming Kuo
  • Patent number: 5917000
    Abstract: A manufacturing process of continuously producing a polyether-ester amide elastomer, which is adapted for mass production and reducing manufacturing cost, includes the steps of melting a poly (tetra methylene ether) glycol reactant, a .epsilon.-caprolactam reactant and an adipic acid reactant, pre-polymerizing the melted reactants by esterification and ring-opening reaction to form a pre-polymer and highly polymerizing the pre-polymer to form the polyether-ester amide elastomer. The polyether-ester amide elastomer is specifically used as a raw ingredient for producing a polyether-ester amide elastic fiber by drying the polyether-ester amide elastomer in a drying device, extruding the dried polyether-ester amide elastomer by an extruder, and molten spinning the extruded polyether-ester amide elastomer to form the polyether-ester amide elastic fiber.
    Type: Grant
    Filed: April 29, 1998
    Date of Patent: June 29, 1999
    Inventors: J. H. Tsai, J. S. Chiou, Y. K Twu
  • Patent number: 5914374
    Abstract: A urethanized polyester is claimed which is suitable as an additive for aqueous coating systems, which is obtainable by, in a first reaction stage (A), subjecting(a) from 10 to 45 mol-% of one or more diols,(b) from 5 to 50 mol-% of one or more polyols having at least 3 OH groups, and(c) from 35 to 47 mol-% of one or more aromatic, aliphatic or cycloaliphatic polycarboxylic acids and/or reactive derivatives thereof to a polycondensation reaction in a manner known per se until the reaction mixture has an acid number of from 1 to 10, and, in a reaction stage (B), reacting the resulting reaction product in a manner known per se with an organic polyisocyanate. The urethanized polyester is outstandingly suitable as an additive for aqueous coating materials in order to improve the rheological stabilization of coating materials.
    Type: Grant
    Filed: February 20, 1997
    Date of Patent: June 22, 1999
    Assignee: BASF Coatings AG
    Inventors: Vera Block, Harald Borgholte, Uwe Meisenburg, Heinz-Peter Rink, Ludwig Moorkamp
  • Patent number: 5900322
    Abstract: This invention relates to binary blends of cellulose esters and aliphatic-aromatic copolyesters, cellulose esters and aliphatic polyesters as well as ternary blends of cellulose esters and/or aliphatic polyesters and/or aliphatic-aromatic copolyesters and/or polymeric compounds as well as fibers, molded objects, and films prepared therefrom.
    Type: Grant
    Filed: December 10, 1996
    Date of Patent: May 4, 1999
    Assignee: Eastman Chemical Company
    Inventors: Charles M. Buchanan, Robert M. Gardner, Matthew D. Wood, Alan W. White, Steven C. Gedon, Fred D. Barlow, Jr.
  • Patent number: 5886133
    Abstract: This invention relates to a process of producing a moldable polyethylene terephthalate or modified polyethylene terephthalate having an inherent viscosity greater than 0.6 dL/g comprising reacting the diacid component with the diol component such that a combination of a titanium-based catalyst and a phosphorus-based catalyst is used during the polycondensation steps.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: March 23, 1999
    Assignee: Eastman Chemical Company
    Inventors: Samuel D. Hilbert, Thomas G. Davis
  • Patent number: 5880220
    Abstract: Biodegradable polyetheresteramides P1 which are obtained by reacting(a1) a mixture containing20-95 mol % of adipic acid or ester-forming derivatives thereof or mixtures thereof and5-80 mol % of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and(a2) a mixture of dihydroxy compounds(a21) from 15 to 99.3 mol % of a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,(a22) from 0.2 to 85 mol % of a dihydroxy compound containing ether functionalities of the formula IHO--((CH.sub.2).sub.n --O).sub.m --H Iwhere n is 2, 3 or 4 and m is an integer from 2 to 250, or mixtures thereof and(a23) from 0.5 to 80 mol % of an amino-C.sub.2 -C.sub.12 -alkanol or amino-C.sub.5 -C.sub.10 -cycloalkanol,where the molar ratio of (a1) to (a2) is from 0.4:1 to 1.5:1, with the proviso, inter alia, that the polyetheresteramides P1 have a molecular weight (M.sub.
    Type: Grant
    Filed: July 3, 1997
    Date of Patent: March 9, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Warzelhan, Gunnar Schornick, Frank Braun, Ursula Seeliger, Motonori Yamamoto, Peter Bauer
  • Patent number: 5880225
    Abstract: A process for making polyetherester resins is disclosed. A glycol ester of an aromatic diacid such as terephthalic acid is reacted with a polyether and a source of a dicarboxylic acid such as maleic anhydride to produce a polyetherester resin, wherein the aromatic diester content may be conveniently adjusted as desired. The process permits the preparation of unsaturated polyetherester resins with relatively high levels of terephthalate repeating units while avoiding the difficulties associated with the direct use of terephthalic acid in previously known procedures. Such unsaturated polyetheresters are useful for making thermoset resins with excellent mechanical and physical properties. New glycol esters based on 2-methyl-1,3-propanediol, and polyester resins and thermosets made from the glycol esters, are also disclosed.
    Type: Grant
    Filed: July 15, 1998
    Date of Patent: March 9, 1999
    Assignee: Arco Chemical Technology, L.P.
    Inventors: Lau S. Yang, Gangfeng Cai, Diandre Armstead
  • Patent number: 5869594
    Abstract: The invention relates to novel hot-melt masses consisting of a statistically built-up copolyether ester based on terephthalic acid and a mixture of aliphatic diols. Terephthalic acid is used as the single acid component and its molar amount, relative to the total amount of acid, is 100 molar %. A combination of butane diol, diethylene glycol, polyethylene and optionally triethylene glycol is present as diol component. The molar amount of butane diol is less than 75 molar %, the amount of diethylene glycol is between 5 and 60 molar %, the amount of triethylene glycol between 0 and 40 molar % and at least 2 and at the most 10 molar % of a higher-molecular polyethylene glycol component with a molar mass of 600-4000 g/mole is used, relative to the total acid amount and total diol amount of 100 molar % in each instance. The melting point of the copolyether ester adhesive masses is between 90.degree. and 190.degree. C.
    Type: Grant
    Filed: August 12, 1997
    Date of Patent: February 9, 1999
    Assignee: EMS-Inventa AG
    Inventors: Eberhard Kinkelin, Gerhard Poessnecker, Jurgen Spindler
  • Patent number: 5863991
    Abstract: Biodegradable polyetheresteramides Q1 with a molecular weight (M.sub.n) in the range from 6000 to 80,000 g/mol, a viscosity number in the range from 30 to 450 g/ml (measured in o-dichlorobenzene/phenol (50/50 ratio by weight) at a concentration of 0.5% by weight polyetheresteramide Q1 at 25.degree. C.), and a melting point in the range from 50.degree. to 200.degree. C., obtained by reacting a1) from 95 to 99.9% by weight polyetheresteramide P1, obtained by reacting a mixture ofb1) 20-95 mol % adipic acid or ester-forming derivatives thereof, and5-80 mol % terephthalic acid or ester-forming derivatives thereof, andb2) a mixture of a dihydroxy compound selected from C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,b22) a dihydroxy compound which contains ether functionalities and has the formula IHO--((CH.sub.2).sub.n --O)).sub.m --H Iwhere n is 2, 3 or 4 and m is an integer from 2 to 250, andb23) from 0.5 to 80 mol % of an amino-C.sub.2 -C.sub.12 -alkanol or an amino-C.sub.5 -C.sub.
    Type: Grant
    Filed: July 3, 1997
    Date of Patent: January 26, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Warzelhan, Gunnar Schornick, Matthias Kroner, Ursula Seeliger, Motonori Yamamoto, Gerhard Ramlow
  • Patent number: 5859150
    Abstract: The present invention describes a prepolymer of an aliphatic polyoxaester having a polymerizable end group that may be used to produce hydrogels, surgical devices such as sutures, sutures with attached needles, molded devices, and the like.
    Type: Grant
    Filed: November 5, 1997
    Date of Patent: January 12, 1999
    Assignee: Ethicon, Inc.
    Inventors: Dennis D. Jamiolkowski, Rao S. Bezwada
  • Patent number: 5859083
    Abstract: A water vapor permeable, waterproof polyether ester membrane contains 1 to 10% by weight of finely dispersed carbon particles, especially soot particles, having an average size of 5 to 40 nm.
    Type: Grant
    Filed: January 2, 1997
    Date of Patent: January 12, 1999
    Assignee: Akzo Nobel NV
    Inventors: Jozef Christiaan Wilhelmus Spijkers, Henricus Joannes Maria Van de Ven
  • Patent number: 5854359
    Abstract: A process for making polyetherester resins is disclosed. A glycol ester of an aromatic diacid such as terephthalic acid is reacted with a polyether and a source of a dicarboxylic acid such as maleic anhydride to produce a polyetherester resin, wherein the aromatic diester content may be conveniently adjusted as desired. The process permits the preparation of unsaturated polyetherester resins with relatively high levels of terephthalate repeating units while avoiding the difficulties associated with the direct use of terephthalic acid in previously known procedures. Such unsaturated polyetheresters are useful for making thermoset resins with excellent mechanical and physical properties.
    Type: Grant
    Filed: February 18, 1998
    Date of Patent: December 29, 1998
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Lau S. Yang
  • Patent number: 5847070
    Abstract: New compounds including bis-.beta.-hydroxy ethyl bibenzoate containing less than 2.5%, and preferably less than 1%, diethylene glycol and a process for the production of the bis-.beta.-hydroxy ethyl bibenzoate by the condensation of 4,4'-biphenyl dicarboxylic acid and ethylene glycol at low temperature and pressure in the presence of a catalyst are disclosed. Use of the compounds to produce polyesters is also disclosed.
    Type: Grant
    Filed: December 1, 1994
    Date of Patent: December 8, 1998
    Assignee: Monsanto Company
    Inventors: Jawed Asrar, David J. Weinkauff, A. Hameed Bhombal
  • Patent number: 5837381
    Abstract: Poly(alkylene dicarboxylate) polymers and copolymers having tetraalkyl- or trialkylammonium ion end groups and methods of synthesis, thereof. The methylene-containing copolymers, in general, adhere to glass and metals, including aluminum, iron, and copper. Poly(methylene-co-ethylene terephthalate) is a clear film useful in the protection of metals or glass from corrosion or scratching. Glass may be bound to glass or to metal using the polymers of the present invention or metal to metal seals may be made.
    Type: Grant
    Filed: September 15, 1997
    Date of Patent: November 17, 1998
    Inventors: A. G. Pinkus, Rajan Hariharan