Ethylenically Unsaturated Carboxylic Acid Or Ethylenically Unsaturated Derivative Patents (Class 528/303)
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Patent number: 5922474Abstract: The present invention relates to polyesters formed by reacting components comprising: (a) from about 20 to about 45 mol% of a diol; (b) from about 4 to about 25 mol% of a polyol; (c) from about 5 to about 25 mol% of a diacid; (d) up to 6 mol% of an ethylenically unsaturated anhydride; and (e) from about 35 to about 45 mol% of a monofunctional fatty acid, where all mole percentages are based on the total mols of (a), (b), (c), (d) and (e). Further, the present invention is directed to liquid enamel compositions comprising: (1) from about 50 to about 90 wt. % of a polyester of the present invention; (2) about 10 to about 50 wt. % of a crosslinking agent; and (3) less than about 20 wt. % of a suitable organic solvent; where all weight percentages are based on the total weight of (1), (2) and (3). The liquid enamel compositions of the present invention have a viscosity of 50 to 1,000 mPa s (cP) at room temperature.Type: GrantFiled: January 22, 1998Date of Patent: July 13, 1999Assignee: Eastman Chemical CompanyInventor: Thauming Kuo
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Patent number: 5914384Abstract: A coating composition that forms a finish that is soil resistant and easily cleaned having a binder of(A) an acrylic polymer of polymerized hydroxyl containing monomers of hydroxy alkyl (meth)acrylates having 1-4 carbon atoms in the alkyl groups and polymerized monomers from the group of alkyl (meth)acrylates having 1-18 carbon atoms in the alkyl groups, styrene or any mixtures of the above and the acrylic polymer has a weight average molecular weight of about 2,000-20,000 determined by gel permeation chromatography,(B) an acrylic polymeric additive of polymerized hydroxyl containing monomers of hydroxy alkyl (meth)acrylates having 1-4 carbon atoms in the alkyl groups, polymerized monomers from the group of alkyl (meth)acrylates having 1-18 carbon atoms in the alkyl groups, styrene or any mixtures of the above and polymerized fluoro alkyl containing monomer represented by the formula ##STR1## where R is selected from the group of hydrogen or an alkyl group having 1-2 carbon atoms, X is a divalent radical andType: GrantFiled: November 21, 1997Date of Patent: June 22, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Douglas Robert Anton, Michael J. Darmon, William Frank Graham, Richard Ronald Thomas
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Patent number: 5900475Abstract: The present invention relates to a poly(allylamine) polymer and, more generally, a hydrocarbon amine polymer. Preferably, these polymers are crosslinked. The present invention also relates to methods of forming these polymers and methods for their use. Further, the present invention relates to alkylating agents that can be employed to form the polymers and to methods for forming the alkylating agents Generally, the polymer sequestrant includes a substituent bound to an amine of the polymer. The substituent includes a quaternary amine-containing moiety having one, two or three terminal hydrophobic substituents. A method of preparing quaternary amine-containing alkylating agents includes reacting an unsymmetrical dihalide with a tertiary amine having at least one hydrophobic substituent. A method for binding bile salts of bile acids in a mammal includes orally administering to the mammal a therapeutically-effective amount of the polymer sequestrant.Type: GrantFiled: June 6, 1996Date of Patent: May 4, 1999Assignee: GelTex Pharmaceuticals, Inc.Inventors: W. Harry Mandeville, III, Stephen Randall Holmes-Farley, John S. Petersen
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Patent number: 5880226Abstract: A magnetic recording medium has a substrate and an non-magnetic underlayer formed on the substrate and a magnetic layer formed on the non-magnetic layer. The magnetic layer include a magnetic powder and a binder for binding the magnetic powder on the non-magnetic layer. The binder includes at least a resin component containing at least an aminoquinone structure selected from an aminoquinone structure group shown with formulas (1-1) and (1-2) as a constitutional unit. As the magnetic powder, a metal magnetic powder mainly made of Fe and having a saturation magnetization .sigma.s is used. The magnetic layer has a saturation flux density Bm of 3500 to 5000 G and a coercive force of 1800 to 3000 Oe and a surface roughness SRa of 1 to 10 nm and a thickness of not more than 1.0 .mu.m.Type: GrantFiled: June 18, 1996Date of Patent: March 9, 1999Assignee: Victor Company of Japan, Ltd.Inventors: Kazuyoshi Watanabe, Noboru Watanabe
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Patent number: 5869191Abstract: Linear, tertiary carboxyl functional polyester resins obtainable by reaction ofa) at least one compound A.sub.1, comprising the reaction product of(i) a glycidylester of a mixture of certain highly branched saturated monocarboxylic acids isomers, and(ii) a mixture of said highly branched saturated monocarboxylic acids;b) at least one aromatic or cycloaliphatic dicarboxylic acid compound B;c) optionally at least one dihydroxymonocarboxylic acid compound C; andd) optionally at least one diol compound D; in a certain molar ratio of compounds A.sub.1 :B:C:D, at a temperature of from 100.degree. to 225.degree. C., until essentially all the non-tertiary carboxyl groups as initially present in the reaction mixture have been reacted.Type: GrantFiled: November 24, 1997Date of Patent: February 9, 1999Assignee: Shell Oil CompanyInventors: Ronald Petrus Clemons Van Gaalen, Petrus Gerardus Kooijmans, Eric Johannes Vos
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Patent number: 5856401Abstract: A method wherein polyesters are prepared under mild conditions by directly condensing hydroxycarboxylic acids or mixtures of polyfunctional alcohols and carboxylic acids in hydrophobic media using heterogeneous catalysts that can form a hydrophilic phase. The systems are inverse emulsions, inverse microemulsions and solid-in-liquid dispersions.Type: GrantFiled: January 27, 1998Date of Patent: January 5, 1999Assignee: Saam AssociatesInventor: John C. Saam
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Patent number: 5817722Abstract: Polyesterdiols having low viscosities of less than 3500 cps, high content of non-volatile matter in excess of 96 wt %, and narrow molecular weight distribution of less than about 1.4 are prepared by esterification of one or more aliphatic dicarboxylic acids or ester derivatives thereof using at least a 1.5 molar excess of one or more aliphatic diols until an acid number of less than 20 is achieved, and stripping excess diol from the polyesterdiol reaction product. Where esterification catalyst is used, catalyst is substantially removed prior to stripping excess unreacted diol from polyesterdiol reaction product. The polyesterdiols so produced are useful as (i) curable components in thermosettable resin compositions, particularly compositions essentially free of volatile organic solvent and also containing a crosslinking agent and a reactive hardening agent: and/or (ii) useful as coatings, paints and adhesives, providing coatings with very low content of volatile organic compounds.Type: GrantFiled: April 1, 1996Date of Patent: October 6, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Albert Ilya Yezrielev, Konstantinos R. Rigopoulos, Richard William Ryan, Karen K. Kuo, George Andrew Knudsen
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Patent number: 5783635Abstract: An unsaturated polyester resin composition which comprises 100 parts by weight of a resin mixture comprising 25 to 80 parts by weight of an unsaturated polyester, 20 to 60 parts by weight of a comonomer and 1 to 10 parts by weight of a particulate crosslinked polymer and 100 to 400 parts by weight of an inorganic filler and in which the difference in refractive index between a product of copolymerization of the unsaturated polyester with the comonomer and the inorganic filler is 0.02 or below; and molded articles produced by curing the resin composition by heating under pressure. The resin composition has a high productivity, exhibits a texture excellent in both light transmittance and gloss, and is excellent in water resistance and which is suitable for the production of artificial marble.Type: GrantFiled: April 30, 1997Date of Patent: July 21, 1998Assignee: Takeda Chemical Industries, Ltd.Inventors: Koichi Akiyama, Kenichi Morita, Hideki Terada
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Patent number: 5747607Abstract: A sheet molding composition is provided which exhibits controllable thickening. The composition includes a low molecular weight polyester in which some of the chain ends have been endcapped with functional groups which are unable to react with the thickeners employed in the sheet molding composition. The sheet molding composition has a low viscosity of from about 6 to about 20 million centipoise which allows molding at low pressures of from about 100 to about 300 psi.Type: GrantFiled: June 27, 1996Date of Patent: May 5, 1998Assignee: Owens-Corning Fiberglas Technology, Inc.Inventors: William G. Hager, Edward L. Wilson, Paul R. Krumlauf
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Patent number: 5736589Abstract: Absorbable polymers and blends of acrylated poly(alkylene diglycolate)s and aliphatic polyesters based on lactone monomers such as lactide, glycolide, e-caprolactone, p-dioxanone, and trimethylene carbonate are described. The polymers and blends exhibit a broad range of properties, useful in a variety of medical devices.Type: GrantFiled: July 30, 1996Date of Patent: April 7, 1998Assignee: Ethicon, Inc.Inventors: Kevin Cooper, Angelo Scopelianos
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Patent number: 5731391Abstract: A fluid which comprises an olefin-terminated polyester an unmodified polyester and a polymerized .alpha.-olefin is provided which facilitates the separation of blood into light and heavy phases via centrifugation in a blood collection vessel. The fluid is useful as a component of a partitioning composition formulated to have appropriate specific gravity to be positioned intermediate the light and heavy blood phases during centrifugation. A partitioning composition including a fluid of the invention provides a particular advantage in blood collection vessels used in therapeutic drug monitoring, due to the relatively low affinity between the fluid component of the composition and commonly monitored classes of drugs.Type: GrantFiled: September 27, 1996Date of Patent: March 24, 1998Assignee: Henkel CorporationInventors: William L. O'Brien, Alan C. Kilbarger
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Patent number: 5721294Abstract: The invention relates to an air-drying aqueous polymer dispersion based on a core/shell polymer having an alkyd resin in the core and an addition polymer grafted thereon, with 50-90 weight percent of the core/shell polymer being composed of alkyd resin and 50-10 weight percent being composed of addition polymer, and with the alkyd resincontaining more than 40 and up to 80 weight percent of unsaturated fatty acid, at least 5 mole percent of which contains conjugated double bonds,having an acid number of not more than 5 (mg KOH/g), andhaving a number average molecular weight in the range of 400 to 5000, and with the addition polymer having an acid number in the range of 40 to 200 (mg KOH/g).The aqueous polymer dispersions according to the invention were found to be highly stable and to have a comparatively low viscosity, even at concentrations of 40 weight percent and above.Type: GrantFiled: January 16, 1997Date of Patent: February 24, 1998Assignee: Akzo Nobel NVInventors: Roelof Buter, Ingrid Gertruda Catharina Thijssen
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Patent number: 5703198Abstract: The invention relates to a radiation curable binder composition for powder paint formulations. The binder composition comprisesa) a polymer having a degree of unsaturation between 300 and 1800 grams per mole of unsaturated group (WPU), having a molecular weight Mn between 800 and 6800 and a viscosity between 1 dPas and 800 dPas andb) a crosslinking agent having vinyl ether, vinyl ester or (meth)acrylate functional groups.The polymer is an unsaturated polyester and/or an unsaturated polyacrylate.The binder composition can be used in the preparation of powder paint formulations which can be applied to heat-sensitive substrates such as wood and plastic and which can be cured with UV or electron beam radiation.Type: GrantFiled: July 24, 1995Date of Patent: December 30, 1997Assignee: DSM N.V.Inventors: Freddy Twigt, Robert Van Der Linde
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Patent number: 5677396Abstract: An improved process for making polyetherester resins is disclosed. The process comprises reacting a polyether with a diol diester in the presence of a catalyst that promotes random insertion of the diester into carbon-oxygen bonds of the polyether to produce the polyetherester resin. The process of the invention offers many advantages, including higher resin yields, reduced by-product generation, and the ability to make resins with low color and low acid numbers. The resins are useful for making polyetherester thermosets.Type: GrantFiled: March 20, 1996Date of Patent: October 14, 1997Assignee: ARCO Chemical Technology, L.P.Inventor: Jeffrey A. Klang
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Patent number: 5668236Abstract: The present invention relates to a hydrophilic highly swellable hydrogel based on (co)polymerized hydrophilic monomers or based on graft (co)polymers, characterized in that it is post-crosslinked with a polyamidoamine in an aqueous medium.Type: GrantFiled: April 29, 1996Date of Patent: September 16, 1997Assignee: Cassella AktiengesellschaftInventors: Fritz Engelhardt, Ulrich Riegel, Uwe Stuven, Helmut Klotzsche, Gustav Remmel
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Patent number: 5665151Abstract: The present invention provides inks which contain a near infrared fluorophoric compound incorporated into a water-dissipatible polyester backbone. The inks of the present invention are preferably colorless or "invisible" but could be made slightly colored if desirable. Specifically, the inks of the present invention comprise:A. between about 1 and 10 weight percent of at least one water-dissipatable polyester having from about 0.1 ppm by weight to about 10% by weight of a thermally stable near infrared fluorophoric compound copolymerized therein;B. between about 5 and 75 weight percent of at least aliphatic humectant;C. between about 0 and 15 weight percent of at least one lower aliphatic alcohol of no more than 3 carbon atoms;D. water and optionally up to about 2 weight percent of one or more additives;wherein the weight percentages of components A-D equal 100%.Type: GrantFiled: November 18, 1996Date of Patent: September 9, 1997Assignee: Eastman Chemical CompanyInventors: Nelson Zamora Escano, James John Krutak, Sr.
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Patent number: 5663290Abstract: A novel process has been developed for the crystallization of poly(ethylenenaphthalenedicarboxylate) (PEN) and its copolymers. The process comprises the step of maintaining the amount of water in said poly(ethylenenaphthalenedicarboxylate) below a critical moisture content ceiling throughout processing such that a separate drying step is not required.Type: GrantFiled: July 21, 1995Date of Patent: September 2, 1997Assignee: Eastman Chemical CompanyInventors: William Herbert Heise, Joseph Franklin Knight, Michael Alan Williams, Earl Edmondson Howell, Jr.
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Patent number: 5646237Abstract: This invention relates to linear, water-dispersible sulfopolyesters that incorporate higher order polyalkylene glycol units. The sulfopolyesters provide improved abrasion and blocking resistances in polyester fiber sizing applications.Type: GrantFiled: August 15, 1995Date of Patent: July 8, 1997Assignee: Eastman Chemical CompanyInventors: Scott Ellery George, Edgar William Lefler, IV, James Marshall Spain, Jr.
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Patent number: 5637664Abstract: Polymeric, catalytically-active compounds having imidazole groups linked terminally and/or laterally to the polymer chain through reactive groups on the polymer chain are disclosed. The polymer chain is selected from the group consisting of polyether ketones; acidic, basic, or neutral ion exchange resins; polymeric isocyanates; polymers or copolymers containing maleic acid or maleic anhydride; and polymers containing benzyl halide groups.Type: GrantFiled: June 1, 1995Date of Patent: June 10, 1997Assignee: BASF AktiengesellschaftInventors: Bernd Bruchmann, Roland Minges, Christian Schade, Konrad Stiefenhoefer
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Patent number: 5637356Abstract: Polyesters are formed from diols and dibasic carboxylic acids at an OH/COOH ratio to provide --OH termination, and then end-capped with tribasic carboxylic acids. A major portion of the dibasic carboxylic acids used to form the polyesters have the formula: ##STR1## where x=8-32, y=0-8, x+y=8-32. The polyesters are used as support resins for forming acrylic resin emulsions. The polyester/acrylic acid emulsions are useful, for example, as textile size.Type: GrantFiled: March 5, 1996Date of Patent: June 10, 1997Assignee: Morton International, Inc.Inventors: Ronald J. Kerr, John P. Petrovich, Stephen J. Walker, J. Alvin Binkley
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Patent number: 5599875Abstract: Coating compositions and processes for coating wood and wood materials are described. The compositions comprise a first component comprising at least one reactive thinner and at least one unsaturated polyester, and a second component comprising a curing catalyst. The unsaturated polyester of the first component is the reaction product of: (a) a mixture of at least one saturated aliphatic dicarboxylic acid with 6 to 10 carbon atoms and at least one ethylenically unsaturated aliphatic dicarboxylic acid selected from maleic acid, fumaric acid, itaconic acid, citraconic acid, and mixtures thereof; (b) a diol component consisting of at least one of 1,4-dimethylolcyclohexane and substituted dimethylolcyclohexanes, with up to 50 mol % monomeric or oligomeric glycol, based on total moles of the diol component; and (c) up to 10 mol % of a polyol, based on total moles of polyester reactants. The compositions and processes of the invention result in coatings with improved hardness and aged cold crack resistance.Type: GrantFiled: August 28, 1995Date of Patent: February 4, 1997Assignee: BASF Lacke + Farben, AGInventors: Karl-Dieter Depping, Horst Hintze-Bruning
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Patent number: 5597651Abstract: Multi-component composites containing a linear polyester of an alkyl glycol and an aromatic diacid as one component, rubber as a second component, and a third component which is a compatibilizing polyester (polystyrene copolymer).Type: GrantFiled: October 26, 1995Date of Patent: January 28, 1997Assignee: Hoechst Celanese Corp.Inventors: Eui W. Choe, Charles E. Forbes, Jennifer A. Filbey, Stephan F. Sherriff
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Patent number: 5591809Abstract: The present invention provides novel one-step processes for preparing highly branched macromolecule polymers that have highly controlled molecular architectures. The process comprises the reaction of a branching monomer such as a substituted phenyl compound having the formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 are defined herein, with a core monomer and an end-capping monomer, such as a phenolic ester, for a sufficient period of time and at a sufficient temperature to directly produce the highly branched polymer, in a single processing step.Type: GrantFiled: August 18, 1995Date of Patent: January 7, 1997Assignee: Hoechst Celanese CorporationInventors: Richard Vicari, Kathleen N. Juneau, Carl D. Murphy
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Patent number: 5587007Abstract: The specification describes a method for preparing a phenol-modified dicyclopentadiene resin. The method comprises reacting (a) dicyclopentadiene, (b) a phenol selected from the group consisting of an alkyl phenol having the formula CH.sub.3 C.sub.n H.sub.2n C.sub.6 H.sub.4 OH, where n is from 1 to 9, and a bisphenol having the formula HOC.sub.6 H.sub.4 (CR.sub.2).sub.x C.sub.6 H.sub.4 OH, where R is independently hydrogen or a C.sub.1 -C.sub.6 alkyl group and x is from 1 to 4, or mixtures thereof; (c) a fatty acid or a derivative thereof selected from the group consisting of tall oil, a tall oil derivative, dimer fatty acid, linseed oil and mixtures thereof; and (d) an unsaturated organic diacid or an anhydride thereof, at a temperature and autogenous pressure sufficient to produce a phenol-modified dicyclopentadiene resin. The resin product exhibits improved compatibility with ink vehicles and formulations, particularly ARLO or alkyd modified inks.Type: GrantFiled: August 14, 1995Date of Patent: December 24, 1996Assignee: Arizona Chemical CompanyInventor: Daniel R. Curvin
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Patent number: 5510453Abstract: The invention relates to novel branched polyesters containing allyl groups, which polyesters are water-emulsifiable, and their use as raw materials for lacquers.Type: GrantFiled: April 7, 1995Date of Patent: April 23, 1996Assignee: Wolff Walsrode AktiengesellschaftInventors: Burkhard Kressdorf, Erhard Luhmann, Wolfgang Dannhorn, Lutz Hoppe
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Patent number: 5506333Abstract: A polyester is provided which facilitates the separation of blood into light and heavy phases via centrifugation in a blood collection vessel. The polyester is useful as a component of a partitioning composition formulated to have appropriate specific gravity to be positioned intermediate the light and heavy blood phases during centrifugation. A partitioning composition including a polyester of the invention provides a particular advantage in blood collection vessels due to its lighter and more consistent coloration. The polyester composition can be prepared with relative ease compared to prior art polyesters useful in blood partitioning compositions.Type: GrantFiled: February 16, 1995Date of Patent: April 9, 1996Assignee: Henkel CorporationInventors: William L. O'Brien, Alan C. Kilbarger
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Patent number: 5504158Abstract: There is provided in accordance with the present invention polyphenylene ether/polyalkyleneterephthalamide compositions of high dimensional stabilities that are suitable for high temeprature applications comprising from about 20 to about 70 weight % of a functionalized polyphenylene ether; from about 20 to about 70 weight % of a polyalkyleneterephthalamide, wherein the polyalkyleneterephthalamide is derived from terephthalic acid and an .alpha.,.omega.-alkanediamine having 10 to 14 methylene groups; and from about 0 to about 20 weight % of a functionalized elastomeric polymer, wherein the blend absorbs less than 2 wt % of moisture and has a dimensional growth in water of less than 0.5%.Type: GrantFiled: January 10, 1995Date of Patent: April 2, 1996Assignee: AlliedSignal Inc.Inventors: Murali K. Akkapeddi, Jeffrey H. Glans
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Patent number: 5502118Abstract: Polymer salts whose anionic component is a polyester which comprises the product of reaction of the individual components a), b) and c) and if desired d) and if desired e), wherea) is a dicarboxylic acid or a reactive derivative of a dicarboxylic acid, being free from sulfo groups,b) is a difunctional aromatic, aliphatic or cycloaliphatic sulfo compound whose functional groups are hydroxyl or carboxyl, or hydroxyl and carboxyl,c) is an aliphatic, cycloaliphatic or aromatic diol, a polyetherdiol or a polycarbonatediol,d) is a polyfunctional compound (functionality>2) whose functional groups are hydroxyl or carboxyl, or hydroxyl and carboxyl, ande) is a monocarboxylic acidand whose cationic component comprises hydrogen atoms, metal cations, substituted ammonium cations, immonium cations, guanidinium cations, phosphonium, arsonium or stibonium cations or a mixture of the abovementioned cations, are suitable as charge control agents and charge improvers in electrophotographic toners and developers, in triboeleType: GrantFiled: September 21, 1994Date of Patent: March 26, 1996Assignee: Hoechst AktiengesellschaftInventors: Hans-Tobias Macholdt, Ru/ diger Bauer, Joachim Zo/ ller
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Patent number: 5500212Abstract: New bile acid sequestrant polymer compositions and a process for preparing the polymers in particulate form, preferably in spherical form, are described. The polymer particles are prepared by crosslinking an amine-containing polymer with an amount of a polyfunctional amine-reactive compound sufficient to crosslink the polymer so that it is essentially water insoluble and has bile acid sequestering efficacy greater than that of cholestyramine, preferably greater than about three times the efficacy of cholestyramine. A preferred polymerization process revolves suspension polymerization of water-soluble amine-containing monomers, such as dialkylaminoalkyl (meth)acrylate esters and dialkylaminoalkyl (meth)acrylamides, in the presence of polyfunctional amine-reactive compounds, such as substituted dihaloalkanes. Pharmaceutical compositions containing the bile acid sequestrant polymer particles and a method for lowering blood cholesterol levels using the pharmaceutical compositions are also described.Type: GrantFiled: June 6, 1995Date of Patent: March 19, 1996Assignee: Rohm and Haas CompanyInventors: Paul E. Bliem, Larry W. Steffier
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Patent number: 5474854Abstract: The invention is a polyester composition containing crosslinked polymer particles with ester bonds at the main chain. The particles are excellent in affinity to polyesters, and so the films formed from the polyester compositions do not have the particles falling off during high speed running, and do not have flaws in the film surfaces. The invention can prevent the generation of white powder and the flaws of magnetic faces caused by falling-off particles, and prevent the contamination in the production of films, even though these are problems caused when various conventional particles are added, and is especially suitable for use as products such as magnetic films.Type: GrantFiled: August 9, 1994Date of Patent: December 12, 1995Assignee: Toray Industries, Inc.Inventors: Nobuyuki Kagami, Masatoshi Aoyama, Masaru Suzuki, Keisuke Oshima
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Patent number: 5468780Abstract: Unsaturated polyester resin waste is glycolytically degraded to obtain industrially useful glycolic raw material. It is possible to synthesize unsaturated polyester resin by reacting this glycolic raw material with unsaturated dibasic acid and saturated dibasic acid. It is also possible to synthesize polyurethane resin by reacting the glycolic raw material with a diisocyanate compound.Type: GrantFiled: March 6, 1995Date of Patent: November 21, 1995Assignee: Miyaso Chemical Co.Inventors: Shizuo Kubota, Osamu Ito, Hiroyuki Miyamoto
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Patent number: 5456947Abstract: A determined amount of at least C.sub.8 dicarboxylic functional unsaturated anhydride or acid, excluding polymeric anhydrides and acids, is incorporated in an unsaturated polyester resin which comprises (1) a condensation polymer which is the reaction product of: (a) dicarboxylic acid, at least a portion of which contains ethylenic unsaturation, with (b) dihydric alcohols; and (2) an alpha-beta-ethylenically unsaturated copolymerizable monomer, to provide modified polyester resins for curable polyester resin systems having improved cohesive and adhesive strengths of the cured resin and improvement in adhesion of such systems to a wide range of substrates, especially substrates considered extremely difficult to bond to, viz., hot dipped galvanized steel, stainless steel, copper, bronze, tin, aluminum, solder, brass and glass (silicon oxide), while also reducing or effectively eliminating retardation of cure by the presence of galvanized (zinc) coated steel or the like.Type: GrantFiled: February 19, 1991Date of Patent: October 10, 1995Assignee: Fibre Glass-Evercoat Company, Inc.Inventors: David M. Parish, John A. Hatton, Jr.
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Patent number: 5453326Abstract: The present invention relates to a polymeric film in-line coated with polyamido-polyethyleneimine to render the film receptive to direct extrusion coating with other polymers or to ink adhesion and to a method of making the same. Additionally, the present invention relates to an oriented polymeric film which has been in-line coated with polyamido-polyethyleneimine so that it has anti-static properties for other packaging applications.Type: GrantFiled: December 22, 1994Date of Patent: September 26, 1995Inventor: Junaid A. Siddiqui
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Patent number: 5451656Abstract: Polyester polymers having pendant carbamate groups are disclosed. The polymers are prepared by:(a) reacting a hydroxyalkyl cyclic carbonate with ammonia, ammonium hydroxide, or a primary amine to form a dihydric alcohol having a carbamate group appended thereto,(b) reacting the dihydric alcohol from (a) and a cyclic anhydride to form a half-ester diacid having a carbamate group appended thereto, and(c) reacting a mixture comprising the half-ester diacid from step (b) and a polyol to form a polyester having carbamate groups appended thereto.Type: GrantFiled: December 21, 1994Date of Patent: September 19, 1995Assignee: BASF CorporationInventors: Gregory L. Menovcik, Walter H. Ohrbom
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Patent number: 5436103Abstract: Modified unsaturated linear polymers have at least a first residue, a second residue and an acid residue. The first, second and acid residues correspond to a first, second and acid monomers used to prepare the polymers. The first monomer may be a diacid, anhydride, diacid ester or mixture thereof. The second monomer may be a diol or glycol. The acid monomer may be an aromatic dicarboxylic acid, different than the first monomer. The first residue is present in a concentration not less than about 7.5 mole % and the acid residue is present in a concentration ranging between 2.5 mole % and 12.5 mole %, based on the total mole monomer ratio of the polymer. The polymers have a glass transition temperature ranging from about 54.degree. C. to about 64.degree. C.Type: GrantFiled: August 27, 1993Date of Patent: July 25, 1995Assignee: Xerox CorporationInventors: Robert D. Bayley, Carol A. Fox, Thomas R. Hoffend, James R. Paxson
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Patent number: 5432249Abstract: The present invention provides a novel liquid crystalline polyester comprising structural units represented by the following general formulae A, B, C and D: ##STR1## where X and Y are each independently H, Cl, Br or an alkyl group having 1 to 4 carbon atoms, the molar ratio of A/B is in the range from 49/1 to 20/30 and that of C/D is in the range from 10/40 to 45/5.Type: GrantFiled: December 21, 1994Date of Patent: July 11, 1995Assignee: Nippon Oil Company, LimitedInventors: Yoshihiro Kumagai, Takuya Matsumoto, Iwane Shiozaki, Shigeki Takikawa
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Patent number: 5420205Abstract: A binder composition suitable for coating agents is described, that contains one or more unsaturated polyesters with an acid number of 5-60 mg KOH/g, a hydroxyl number of 50-200 mg KOH/g and a weight-average molecular weight (Mw) of 500-3000 g/mol, that are obtainable by reaction ofA) one or more alpha,beta-ethylenically unsaturated dicarboxylic acids or their anhydrides,B) one or more hydroxy-functional allyl ethers andC) one or more ethylenically unsaturated compounds with an oxirane group in the molecule,in the molar ratio of A):B):C)=(2 to 4):(2 to 4):(0.5 to 1.8). The composition is suitable in particular for filling putties and filling compounds that dry rapidly, even at low temperatures.Type: GrantFiled: June 20, 1994Date of Patent: May 30, 1995Assignee: Herberts Gesellschaft mis beschrankter HaftungInventors: Heinz D. Becker, Klaus Bederke, Gerhard Bremer, Herrmann Kerber, Birgit Precht, Fritz Sadowski, Werner Stephan
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Patent number: 5420227Abstract: Modified acid polyesters obtained by reaction of polyols with unsaturated polycarboxylic acids or anhydrides thereof and conjugated dienoic acids. These products are suitable as curing agents for epoxy resins, in particular for curing tin can finishes.Type: GrantFiled: December 10, 1993Date of Patent: May 30, 1995Assignee: Hoechst AGInventors: Armin Pfeil, Paul Oberressl, Reiner-Kurt Illgen
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Patent number: 5420166Abstract: The present invention is directed to a method for treating cross-linked (cured) filled or untilled unsaturated polyester for deriving an alcohol recycle reactant useful in the synthesis of alcohol-formed derivative products. The first step of the method is the attrition of the cured unsaturated polyester to form particulates thereof. In the next step of the process, at least a fraction of any filler or fiberglass in the cured unsaturated polyester is separated to form a cured unsaturated polyester regrind. The next step is the subjecting of the cured unsaturated polyester regrind to agitated, uncatalyzed or catalyzed glycolysis in the presence of excess glycol and, optionally, a transesterification catalyst under agitation at elevated transesterification temperature. The final step of the process is the recovery of the recycle alcohol reactant for use in the synthesis of alcohol-formed derivative products.Type: GrantFiled: September 30, 1994Date of Patent: May 30, 1995Assignee: Ashland Oil, Inc.Inventors: Timothy A. Tufts, Chung-Chieh Tsai, Stephen S. Hupp
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Patent number: 5418301Abstract: The invention relates to a dendritic macromolecule of the polyester type comprising a central initiator molecule or initiator polymer having one or more reactive hydroxyl groups (A). The groups (A) are under formation of an initial tree structure bonded to reactive carboxyl groups (B) of a monomeric chain extender having the two reactive groups (A) and (B). The tree structure is optionally extended and further branched from the initiator molecule or initiator polymer by addition of further molecules of a monomeric chain extender by means of bonding between the reactive groups (A) and (B) thereof and is thereafter optionally further extended by reaction with a chain stopper. The invention also comprises a process for preparation of the dendritic macromolecule.Type: GrantFiled: July 13, 1994Date of Patent: May 23, 1995Assignee: Perstorp ABInventors: Anders Hult, Eva Malmstrom, Mats Johansson, Kent Sorensen
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Patent number: 5416187Abstract: This invention provides an improved process for preparing phenol-functional polyester resins which are useful in thermosetting coating compositions. The process involves a polycondensation reaction comprising a two-step charging procedure and suitable reaction conditions.Type: GrantFiled: April 4, 1994Date of Patent: May 16, 1995Assignee: Eastman Chemical CompanyInventors: Thauming Kuo, Jeffery E. G. Powell
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Patent number: 5414068Abstract: New bile acid sequestrant polymer compositions and a process for preparing the polymers in particulate form, preferably in spherical form, are described. The polymer particles are prepared by crosslinking an amine-containing polymer with an amount of a polyfunctional amine-reactive compound sufficient to crosslink the polymer so that it is essentially water insoluble and has bile acid sequestering efficacy greater than that of cholestyramine, preferably greater than about three times the efficacy of cholestyramine. A preferred polymerization process involves suspension polymerization of water-soluble amine-containing monomers, such as dialkylaminoalkyl (meth)acrylate esters and dialkylaminoalkyl (meth)acrylamides, in the presence of polyfunctional amine-reactive compounds, such as substituted dihaloalkanes. Pharmaceutical compositions containing the bile acid sequestrant polymer particles and a method for lowering blood cholesterol levels using the pharmaceutical compositions are also discribed.Type: GrantFiled: January 24, 1994Date of Patent: May 9, 1995Assignee: Rohm and Haas CompanyInventors: Paul E. Bliem, Larry W. Steffier
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Patent number: 5409764Abstract: A curable adhesive composition comprising an unsaturated polyester oligomer (A) of any of the following formulae (I) to (IV), obtained by reacting a compound (a) having a hydroxyl group and/or an amino group, a cyclic acid anhydride (b) and an epoxide (c) having an ethylenically unsaturated group, and an adhesive polymer (B), ##STR1## wherein: R.sub.1 is a divalent organic moiety having 1 to 40 carbon atoms,R.sub.2 is a divalent organic moiety having 1 to 10 carbon atoms,R.sub.3 is hydrogen or methyl,R.sub.4 is a monovalent organic moiety having 1 to 40 carbon atoms,R.sub.5 is a monovalent organic moiety having 1 to 40 carbon atoms,R.sub.6 is hydrogen or a monovalent organic moiety having 1 to 10 carbon atoms, andn is an integer of 2 or greater.Type: GrantFiled: September 23, 1994Date of Patent: April 25, 1995Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Tsukasa Otsuki, Masato Yanagi, Toshikazu Onikubo, Kouichi Iibuchi
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Patent number: 5409989Abstract: A resin composition for toners, composed essentially of a suspension polymerizate of:(a) 5 to 40% by weight per total polymer of a polyester comprising at least one aromatic diol component an at least one aliphatic diol component, and having a weight average molecular weight of 3,000 to 30,000, an acid value of 0.5 to 10 mgKOH/g, and an OH value of 10 to 60 mgKOH/g;(b) 60 to 95% by weight per total polymer of a vinyl monomer; and(c) 0.1 to 1.0% by weight per total polymer of a divinyl monomer,wherein said suspension polymerizate hasa glass transition temperature of 40.degree. to 70.degree. C.,an acid value of 0.1 to 10 mgKOH/g, anda softening temperature of 100.degree. to 160.degree. C.Type: GrantFiled: December 27, 1993Date of Patent: April 25, 1995Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Hirokazu Ito, Masahiro Ito, Keiji Yoshida, Syuji Takahiro, Motoshi Inagaki
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Patent number: 5408013Abstract: An unsaturated polyester resin composition capable of affording a molded product having a small cured volume shrinkage, a superior dimensional stability, a surface quality and a high hardness, a sheet-form molding material using the composition and a process for producing a fiber-reinforced plastic molded product are provided, which composition comprises a saturated polyester obtained by reacting a saturated dibasic acid component containing 20% by mol or more of adipic acid with a saturated glycol component and having a number average molecular weight of 4,000 or higher and an acid value of 2 to 8 KOH mg/g, an unsaturated polyester and an ethylenic unsaturated monomer; which sheet-form molding material has the unsaturated resin composition together with a fiber reinforcing material placed between two films.Type: GrantFiled: December 1, 1993Date of Patent: April 18, 1995Assignee: Hitachi Chemical Co., Ltd.Inventors: Hiroyuki Kawakami, Masaaki Yasuda, Shoichi Sasaki
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Patent number: 5405910Abstract: Acryl modified polyester resins are prepared by a process which comprises reacting an acid mixture with an alcohol mixture to form hydroxyl polyester prepolymers, solution polymerizing acryl monomers with acidic acryl monomers having carboxyl groups to form acryl resins, and reacting said hydroxyl polyester prepolymers with said acryl resins and polycarboxylic acids having at least two carboxyl groups.A powder coating composition is composed of inorganic pigment or organic pigment, a flowing agent, a curing agent, a curing accelerator, other stabilizers and the acryl modified polyester resins prepared according to the above process.Type: GrantFiled: December 12, 1990Date of Patent: April 11, 1995Assignee: Korea Chemical CoInventors: Weon-seok Kim, Bong-jin Kim
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Patent number: 5401602Abstract: Low fix temperature toner resins are fabricated by a reactive melt mixing process wherein polymer resins are cross-linked at high temperature and high shear. The resins are particularly suitable for high speed fusing, show excellent offset resistance and wide fusing latitude and superior vinyl offset properties.Type: GrantFiled: March 23, 1993Date of Patent: March 28, 1995Assignee: Xerox CorporationInventors: Hadi K. Mahabadi, Enno E. Agur, Gerald R. Allison, Michael S. Hawkins, Stephan Drappel, Maria N. V. McDougall, Bernard Grushkin, Thomas R. Hoffend, Angelo J. Barbetta
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Patent number: 5397641Abstract: A thermosetting powder composition which comprises (a) a specific a carboxyl-terminated polyester and (b) a glycidyl group-containing acrylic copolymer. The carboxyl-terminated polyester (a) has an acid number of 15 to 70 mg of KOH/g and must be prepared in two steps. In the first step, a hydroxyl-terminated polyester is prepared from at least one polycarboxylic acid other than 1,4-cyclohexanedicarboxylic acid, and at least one aliphatic or cycloaliphatic polyol and in the second step, the resulting hydroxyl-terminated polyester is esterified with 1,4-cyclohexanedicarboxylic acid exclusively. In addition, the composition of the polyester (a) is very specific: it contains at least 75 mole % of terephthalic acid, at least 10 mole % of 1,4-cyclohexanedicarboxylic acid and at most 14 mole % of at least one other aromatic and/or aliphatic and/or cycloatiphatic polycarboxylic acid, based on a total carboxylic acid content of 100 mole %.Type: GrantFiled: March 8, 1994Date of Patent: March 14, 1995Assignee: U C B S.A.Inventors: Luc Moens, Daniel Maetens, Jean-Luc Dallons, Jean-Marie Loutz
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Patent number: 5397671Abstract: A reactive melt mixing process for preparing toner resin, comprising: melting a reactive base resin, thereby forming a polymer melt; adding to said polymer melt a free radical initiator compound and optionally a vinyl monomer compound to form a second melt; and heating and mixing under high shear said second melt with optional addition of a vinyl monomer compound to form a partially crosslinked and partially gelled toner resin.Type: GrantFiled: February 10, 1994Date of Patent: March 14, 1995Assignee: Xerox CorporationInventors: Robert D. Bayley, Carol A. Fox, Thomas R. Hoffend
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Patent number: 5395692Abstract: This invention relates to a polyester comprising repeating units having the structure: ##STR1## wherein R.sup.1 is selected from the group consisting of hydrogen, alkyl having 1 to 6 carbon atoms and aryl having 6 to 10 carbon atoms and R.sup.2 is selected from the group consisting of hydrogen, alkyl having 1 to 6 carbon atoms, and aryl having 6 to 10 carbon atoms.Type: GrantFiled: May 6, 1994Date of Patent: March 7, 1995Assignee: Eastman Chemical CompanyInventors: Alan W. White, Joseph R. Zoeller