Ethylenically Unsaturated Carboxylic Acid Or Derivative Of An Ethylenically Unsaturated Carboxylic Acid Patents (Class 528/306)
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Patent number: 5840822Abstract: Mono(hydroxyalkyl)urea and 2-oxazolidone crosslinking agents and compositions which utilize such crosslinking agents are disclosed. The mono(hydroxyalkyl)urea crosslinking agents contain a single urea group, a single hydroxyl group, and have at least two carbon atoms disposed between the urea group and the hydroxyl group. The compositions contain a poly-functional molecule which contains at least two functional groups selected from the group consisting of carboxyl and anhydride.Type: GrantFiled: September 2, 1997Date of Patent: November 24, 1998Assignee: National Starch and Chemical Investment Holding CorporationInventors: Sharon P. Lee, Steven P. Pauls, Sr.
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Patent number: 5834118Abstract: Hyperbranched polyester of a polyol with 3 to 10 reactive hydroxyl groups, preferably of equivalent reactivity, and an aromatic polycarboxylic anhydride with 2 to 4 carboxyl groups, preferably 3 carboxyl groups, each hydroxyl group of the polyol forming an ester linkage with one anhydride group of the polycarboxylic anhydride, and further glycidyl (meth)acrylate or allyl glycidyl ether forming ester linkages with the remaining carboxyl groups of the anhydride and free hydroxyl groups. Further in the hyperbranched polyester (meth)acrylic anhydride and/or an aliphatic carboxylic anhydride form ester linkages with the free hydroxyl groups. The invention also comprises a process for the production of hyperbranched polyesters and such polyesters obtainable by the process. The hyperbranched polyesters can be used as resins, curable by UV irradiation, for the production of coatings, adhesives, laminates, foils and thin films and fibre-reinforced composites.Type: GrantFiled: May 9, 1997Date of Patent: November 10, 1998Assignee: Neste Oy of KeilaniemiInventors: Bengt R.ang.nby, Shi Wenfang
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Patent number: 5798434Abstract: A monomer mixture having a hydroxyl value ranging from 0 to 134 KOH mg/g, obtainable by polymerizing a mixed raw material of an unsaturated compound selected from the group consisting of fatty acids each having one carboxyl group and one double bond in the molecule and having 11 to 22 carbon atoms and lower alkyl esters thereof with an unsaturated compound selected from the group consisting of fatty acids each having one carboxyl group and 2 to 4 double bonds in the molecule and having 11 to 22 carbon atoms and whose iodine value ranges from 30 to 130 g (iodine)/100 g to give dimers and trimers, then converting the carboxyl groups (or the lower alkyl ester group in case of the lower alkyl esters) present in the resulting dimers and trimers into hydroxyl groups through reduction to give a mixture substantially consisting of dimer diols and trimer triols, and then subjecting the mixture having a dimer diol/trimer triol weight ratio ranging from 30/70 to 99/1 to an esterification reaction with an .alpha., .beta.Type: GrantFiled: August 30, 1996Date of Patent: August 25, 1998Assignee: Lion CorporationInventors: Hitoshi Kigawa, Hiroshi Yamagishi, Noriko Suzuki, Yoshikazu Asao
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Patent number: 5783635Abstract: An unsaturated polyester resin composition which comprises 100 parts by weight of a resin mixture comprising 25 to 80 parts by weight of an unsaturated polyester, 20 to 60 parts by weight of a comonomer and 1 to 10 parts by weight of a particulate crosslinked polymer and 100 to 400 parts by weight of an inorganic filler and in which the difference in refractive index between a product of copolymerization of the unsaturated polyester with the comonomer and the inorganic filler is 0.02 or below; and molded articles produced by curing the resin composition by heating under pressure. The resin composition has a high productivity, exhibits a texture excellent in both light transmittance and gloss, and is excellent in water resistance and which is suitable for the production of artificial marble.Type: GrantFiled: April 30, 1997Date of Patent: July 21, 1998Assignee: Takeda Chemical Industries, Ltd.Inventors: Koichi Akiyama, Kenichi Morita, Hideki Terada
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Patent number: 5780558Abstract: A low-cost way to modulate the reactivity and acid number of polyetherester thermoset resins is disclosed. "Beginning" and "end" methods for making dicyclopentadiene (DCPD)-modified polyetherester resins are described. The "beginning" method comprises first heating a polyether, DCPD, a diol, an insertion catalyst, and a carboxylic acid derivative to produce a mixture that contains the polyether and a DCPD-diol diester adduct. Increasing the temperature causes insertion of the DCPD-diol diester into the polyether to give a DCPD polyetherester resin. The "end" method reacts a polyetherester resin made by insertion with DCPD to give a DCPD polyetherester resin. Compared with DCPD polyester resins, those of the invention give more flexible thermosets. Compared with unmodified polyetherester resins, the DCPD polyetherester resins offer formulators more control over curing, which eliminates mold distortion and shrinking or cracking of thermoset parts.Type: GrantFiled: September 25, 1997Date of Patent: July 14, 1998Assignee: Arco Chemical Technology, L.P.Inventors: Jeffrey A. Klang, Lau S. Yang
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Patent number: 5777046Abstract: Amphiphilic polyesters containing(a) ester units derived from polyalkylene glycols having a molecular weight of from 500 to 7500 and aliphatic dicarboxylic acids and/or monohydroxymonocarboxylic acids and(b) ester units derived from aromatic dicarboxylic acids and polyhydric alcoholsand having molecular weights of from 1500 to 25,000,processes for preparing the amphiphilic polyesters by polycondensation, preparing first(a) aliphatic polyesters of polyalkylene glycols having a molecular weight of from 500 to 7500 with aliphatic dicarboxylic acids and/or monohydroxymonocarboxylic acids and then, within the aliphatic polyester thus obtained,(b) aromatic polyesters from aromatic dicarboxylic acids and polyhydric alcohols,reversing the order of the polycondensation, or condensing oligomeric aromatic polyesters (b) with oligomeric aliphatic polyesters (a), and use of the amphiphilic polyesters as additive in laundry detergents, other laundry detergent additives and laundry aftertreatments.Type: GrantFiled: August 5, 1996Date of Patent: July 7, 1998Assignee: BASF AktiengesellschaftInventors: Dieter Boeckh, Hans-Ulrich Jager, Gunnar Schornick
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Patent number: 5773531Abstract: A modified acrylic urethane prepolymer composition and an unsaturated polyester resin composition to which the prepolymer has been added. The prepolymer composition includes an acrylic urethane prepolymer prepared by the reaction of diisocyanate, like MDI, with an hydroxyl-containing acrylate monomer, such as a pentaerythritol triacrylate, which prepolymer composition may contain a styrene monomer and an inhibitor, such as benzoquinone, to retard the reaction of the prepolymer and styrene monomer prior to the addition of the prepolymer composition into the polyester resin composition. The employment of the modified urethane prepolymer composition provides for the reduction in the amount of styrene monomer used in the unsaturated resin composition and also provides for improved chemical and physical properties of the cured, unsaturated resin composition, such as a reduction in glass roll-out when the resin composition is employed with fiberglass.Type: GrantFiled: August 29, 1997Date of Patent: June 30, 1998Assignee: Hehr International Inc.Inventor: Stuart B. Smith
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Patent number: 5770659Abstract: Processes for making storage-stable epoxy-capped polyetherester resins are disclosed. In one process, a polyetherester resin is first made by inserting a carboxylic acid derivative into a polyether. Reacting the resin with a capping agent gives an intermediate resin with a reduced content of free carboxylic acid groups. Finally, the intermediate resin reacts with an epoxy compound in the presence of a finishing catalyst under conditions effective to give an epoxy-capped resin. The resins have low weight average molecular weights (less than about 8000), narrow molecular weight distributions (less than 6), and low viscosities, making them an excellent choice for low-VOC formulations. The finishing catalyst helps to minimize resin viscosity drift and improves shelf stability. Curing the resins with a vinyl monomer gives thermosets with an excellent balance of physical properties, including excellent water resistance.Type: GrantFiled: November 10, 1997Date of Patent: June 23, 1998Assignee: Arco Chemical Technology, L.P.Inventors: Gangfeng Cai, Daniel M. Trauth, Lau S. Yang
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Patent number: 5760101Abstract: A condensation product of a hydroxy(meth)acrylate compound corresponding to the formula ##STR1## in which R.sub.1 is hydrogen or methyl, A is a trivalent aliphatic residue with 3 to 15 C-atoms which is unsubstituted or substituted with OH groups and optionally contains up to 5 ether bridges, and an aromatic carboxylic acid anhydrides compound of the formula (II) or an aromatic carboxylic acid anhydride chloride compound of the formula (II) ##STR2## in which Ar is a benzene ring or a naphthalene ring, n is 1 or 2, and m is 0, 1 or 2. The condensation product has a molar mass of 300 and to 10,000 daltons. The condensation product is useful as an adhesive to bond dental filling materials to teeth.Type: GrantFiled: March 7, 1997Date of Patent: June 2, 1998Assignee: Heraeus Kulzer GmbHInventors: Ludger Heiliger, Wolfgang Podszun, Werner Finger
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Process for making unsaturated, thermosetting, brominated phthalic anhydride/polyol polyester resins
Patent number: 5760161Abstract: Unsaturated, thermosetting, brominated phthalic anhydride/polyol polyester resins are prepared by reacting brominated phthalic anhydride with polyol and an unsaturated polycarboxylic acid compound in the presence of an acid neutralizing agent under reaction conditions so as to form an unsaturated polyester resin product, the proportions of reactants being selected so as to provide, (i) at least about a 5:4 mole ratio of total moles of polyol to the sum of the moles of brominated phthalic anhydride, unsaturated polycarboxylic acid compound and any saturated polycarboxylic acid compounds in the reaction, and (ii) a bromine content of at least about 40 weight percent in the unsaturated polyester resin product.Type: GrantFiled: February 10, 1997Date of Patent: June 2, 1998Assignee: Albemarle CorporationInventors: Otto K. Goins, Jr., Todd M. Cooke, David R. Brackenridge -
Patent number: 5747607Abstract: A sheet molding composition is provided which exhibits controllable thickening. The composition includes a low molecular weight polyester in which some of the chain ends have been endcapped with functional groups which are unable to react with the thickeners employed in the sheet molding composition. The sheet molding composition has a low viscosity of from about 6 to about 20 million centipoise which allows molding at low pressures of from about 100 to about 300 psi.Type: GrantFiled: June 27, 1996Date of Patent: May 5, 1998Assignee: Owens-Corning Fiberglas Technology, Inc.Inventors: William G. Hager, Edward L. Wilson, Paul R. Krumlauf
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Patent number: 5736581Abstract: Disclosed are novel polyglycerine polyricinoleates as emulsifiers obtained by the esterification of polyricinoleic acid with a natural condensation rate of from 2 to 10 with a polyglycerine mixture comprising 5-35 wt. % glycerine, 15-40 wt. % diglycerines, 10-30 wt. % triglycerines, 8-20 wt. % tetraglycerines, and 3-10 wt. % pentaglycerines, and the remainder being oligoglycerines. The materials have improved emulsifying capacity.Type: GrantFiled: September 23, 1996Date of Patent: April 7, 1998Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Achim Ansmann, Rolf Kawa, Helga Gondek, Gabriele Strauss, Rainer Von Kries
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Patent number: 5736622Abstract: A collector that is intended to be used at deinking of waste paper according to the flotation process. The collector includes a polyester obtained through reaction between polyalkylene glycol, di and/or tricarboxylic acid and/or anhydrides thereof as well as a saturated fatty acid with 12-18 carbon atoms. The polyester shows a molecular weight between 3000-10000.Type: GrantFiled: December 22, 1995Date of Patent: April 7, 1998Assignee: Bim Kemi ABInventors: Peter W.ang.llberg, Enn Paart
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Patent number: 5731391Abstract: A fluid which comprises an olefin-terminated polyester an unmodified polyester and a polymerized .alpha.-olefin is provided which facilitates the separation of blood into light and heavy phases via centrifugation in a blood collection vessel. The fluid is useful as a component of a partitioning composition formulated to have appropriate specific gravity to be positioned intermediate the light and heavy blood phases during centrifugation. A partitioning composition including a fluid of the invention provides a particular advantage in blood collection vessels used in therapeutic drug monitoring, due to the relatively low affinity between the fluid component of the composition and commonly monitored classes of drugs.Type: GrantFiled: September 27, 1996Date of Patent: March 24, 1998Assignee: Henkel CorporationInventors: William L. O'Brien, Alan C. Kilbarger
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Patent number: 5705603Abstract: The invention relates to reaction products of polyetheramines with polymers containing dicarboxylic anhydride groups, which contain 20-80, preferably 40-60, mol % of bivalent structural units A and/or C and, if required, B ##STR1## in which R.sup.1 and R.sup.2, independently of one another, are hydrogen or methyl,a and b are equal to zero or one and a+b is equal to one,Y is X or NRR.sup.3,X is --OH, --O--C.sub.1-30 -alkyl, NR.sup.3 R.sup.4 or --O.sup..crclbar. N.sup..sym. R.sup.3 R.sup.4,R.sup.3 and R.sup.4, independently of one another, are hydrogen, C.sub.6 -C.sub.40 -alkyl or R,R is ##STR2## with the proviso that at least 1 mol % of the anhydride groups bonded to the polymer have reacted with a polyetheramine,Z is C.sub.2 -C.sub.4 -alkyl,n is a number from 1 to 1000,R.sup.5 is hydrogen, C.sub.1 -C.sub.30 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl or C.sub.6 -C.sub.30 -aryl andR.sup.6 is hydrogen or C.sub.1 -C.sub.Type: GrantFiled: June 22, 1995Date of Patent: January 6, 1998Assignee: Hoechst AktiengesellschaftInventors: Matthias Krull, Michael Feustel, Erdmann Mielcke
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Patent number: 5700856Abstract: A peroxide-generating composition for use in curing an unsaturated polyester resin and to the cured unsaturated polyester resin composition so prepared, particularly unsaturated polyester resin compositions containing inert filler materials used prepare a cast or molded product. The peroxide-generating composition comprises an allyl alcohol alkanoate, such as allyl alcohol propoxylate, which in the presence of a metal salt promoter, such as cobalt carboxylate, either with the allyl alcohol alkanoate or separately as a prepromoter in the unsaturated polyester resin composition provides for the generation from the allyl alcohol alkanoate of a peroxide to effect the in situ cure of the unsaturated polyester resin composition.Type: GrantFiled: April 10, 1996Date of Patent: December 23, 1997Assignee: Hehr International Inc.Inventor: Stuart B. Smith
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Patent number: 5696225Abstract: A process for making high-performance polyetherester resins and thermosets is disclosed. A polyether polyol reacts with a dicarboxylic acid or anhydride in the presence of an insertion catalyst to produce an acid-terminated polyetherester resin. Reaction of this resin reacts with a primary diol or a diepoxy compound gives a chain-extended polyetherester resin that can be cured with a vinyl monomer to produce a high-performance polyetherester thermoset. Properties of the thermosets rival or exceed those of more expensive high-performance iso and vinyl ester resins.Type: GrantFiled: February 28, 1996Date of Patent: December 9, 1997Assignee: ARCO Chemical Technology, L.P.Inventors: Gangfeng Cai, Jeffrey A. Klang, Lau S. Yang
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Patent number: 5691053Abstract: A coating material and coating process for color coating articles, such as motor vehicle bodies, and coated articles produced therewith. The coating contains a paint vehicle composed of at least one curable liquid-crystal polymer (LCP), the colored appearance of the coating being determined by mesogens of the paint vehicle which exhibit an interference effect, the mesogens automatically aligning themselves substantially perpendicular to the surface of the article during application of the coating material and adopting a chiral-nematic configuration in which they form a helix having a pitch length which can be influenced by heat within a specified temperature range. The liquid-crystal polymers are such that they are not crosslinked by heat and also such that the temperature level at which the pitch length of the helix can be influenced is above the temperature at which the color coated article is used.Type: GrantFiled: May 15, 1995Date of Patent: November 25, 1997Assignee: Daimler-Benz AGInventors: Michael Gailberger, Anne Barth, Hans Ruetger Kricheldorf, Volkmar Vill, Mihai Gurau, Matthias Berghahn
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Patent number: 5688906Abstract: A method for forming a polyamic acid having nonlinear optical (NLO) or pre-NLO side chains, which method includes the steps of:(1) providing a bis-(aromatic dicarboxylic acid anhydride) containing at least one NLO or pre-NLO side chain having the structure represented by:D-R-Awherein D, R and A form a delocalized resonance configuration in which R is a pi-conjugated non-centrosymmetric moiety, A is hydrogen or an electron withdrawing moiety and D is an electron donating moiety covalently linked to the bis-(aromatic dicarboxylic acid anhydride); and(2) reacting the bis-(aromatic dicarboxylic acid anhydride) with an aromatic diamine to form a polyamic acid having NLO or pre-NLO side chains. Methods for preparing polyamic acids having NLO or pre-NLO side chains by reacting aromatic diamines having NLO or pre-NLO side chains with bis-(aromatic dicarboxylic acid anhydrides) are also disclosed. Methods of forming the polyamic acids into polyimides having NLO side chains are also included.Type: GrantFiled: August 7, 1995Date of Patent: November 18, 1997Assignee: Enichem S.p.A.Inventors: Kwan-Yue Alex Jen, Kevin Joel Drost
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Patent number: 5670603Abstract: This invention relates to polymers having non-linear optical properties which polymers include fluorene moieties having at least one electron accepting group and at least one electon donating group substituted to different phenyl rings of the fluorene moiety.Type: GrantFiled: March 8, 1993Date of Patent: September 23, 1997Assignee: AlliedSignal Inc.Inventors: Chengjiu Wu, Jianhui Shan, Ajay Nahata
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Patent number: 5663290Abstract: A novel process has been developed for the crystallization of poly(ethylenenaphthalenedicarboxylate) (PEN) and its copolymers. The process comprises the step of maintaining the amount of water in said poly(ethylenenaphthalenedicarboxylate) below a critical moisture content ceiling throughout processing such that a separate drying step is not required.Type: GrantFiled: July 21, 1995Date of Patent: September 2, 1997Assignee: Eastman Chemical CompanyInventors: William Herbert Heise, Joseph Franklin Knight, Michael Alan Williams, Earl Edmondson Howell, Jr.
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Patent number: 5652320Abstract: The present invention provides an novel polymer having 1-2,000 equivalents of an N-sulfoamino group/10.sup.6 g of weight of the polymer.The polymer has excellent dispersibility of inorganic fine particles, hygroscopicity, and dye-affinity. The polymer provides a binder resin in which a magnetic or non-magnetic metal or metal oxide can highly be dispersed. The polymer also provides a magnetic recording medium which is excellent in electromagnetic conversion characteristic, surface smoothness, adhesion to non-magnetic substrates, and durability. The polymer provides a magnetic recording medium with improved travelling, travelling durability, signal-to-noise ratio, and drop-out. The polymer also provides a polyester fiber which has a high fiber strength and an excellent hygroscopicity and can be colored with cationic dyes.Type: GrantFiled: October 3, 1995Date of Patent: July 29, 1997Assignee: Sanyo Chemical Industries, Ltd.Inventors: Takashi Takemoto, Toshiro Shimada, Hiroshi Itayama
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Patent number: 5646237Abstract: This invention relates to linear, water-dispersible sulfopolyesters that incorporate higher order polyalkylene glycol units. The sulfopolyesters provide improved abrasion and blocking resistances in polyester fiber sizing applications.Type: GrantFiled: August 15, 1995Date of Patent: July 8, 1997Assignee: Eastman Chemical CompanyInventors: Scott Ellery George, Edgar William Lefler, IV, James Marshall Spain, Jr.
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Patent number: 5644004Abstract: A novel and safe ethylenically unsaturated peroxyester composition derived from an ethylenically unsaturated dicarboxylic acid is provided, as well as processes for making and using the composition. The peroxyester composition comprises about 0.04 to about 0.70 mole fraction of a first component compound having a formula I: ##STR1## about 0.32 to about 0.50 mole fraction of a second component compound having a formula II: ##STR2## about 0.04 to about 0.70 mole fraction of a third component compound having a formula III: ##STR3## wherein Q is an unsaturated ethylene divalent radical and R.sup.1 and R.sup.2 are organic substituents. Polymeric-peroxides are prepared via polymerizing the peroxyester compositions. The peroxyester compositions are also used for curing unsaturated polyester resins and for initiating polymerization of ethylenically unsaturated monomers.Type: GrantFiled: January 25, 1995Date of Patent: July 1, 1997Assignee: Elf Atochem North America, Inc.Inventor: Jose Sanchez
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Patent number: 5644005Abstract: A biodegradable block copolymer made from the transesterfication of a poly(propylene fumarate) prepolymer and a poly(ethylene oxide) prepolymer. The block copolymer poly(propylene fumarate -co- ethylene oxide) is capable of crosslinking at body temperature. Crosslinking requires an appropriate crosslinking monomer and an initiator. The biodegradable block copolymer has utility as a vascular implant became it can be injected as a fluid into the vascular system and crosslinked in situ.Type: GrantFiled: April 24, 1996Date of Patent: July 1, 1997Assignee: Rice UniversityInventors: Laura J. Suggs, Richard G. Payne, Michael J. Yaszemski, Antonios G. Mikos
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Patent number: 5639801Abstract: An anhydride-containing thermoplastic resin such as a styrene maleic anhydride copolymer is processed in a vented extruder in the present of a nitrogenous chemical blowing agent to both imidize at least a portion of the anhydride groups and remove volatile residues such as unreacted styrene monomer from the resin.Type: GrantFiled: May 18, 1995Date of Patent: June 17, 1997Assignee: Nova Chemicals Inc.Inventors: Ramesh Mallikarjun, William J. Cleland
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Patent number: 5614299Abstract: The heat-resistant unsaturated polyester resin composition of the present invention consists essentially of (a.sub.1) an unsaturated polyester which is obtained by the reaction of (.alpha..sub.1) a polybasic acid component containing at least an ethylenic unsaturated polybasic acid with (.alpha..sub.2) a polyhydric alcohol component, and (a.sub.2) a diluent monomer component for the unsaturated polyester, wherein the polyhydric alcohol component (.alpha..sub.2) contains 2-methyl-1,3-propanediol and 1,4-cyclohexanedimethanol in the total amount of 50 mol % or more, and 2-methyl-1,3-propanediol and 1,4-cyclohexanedimethanol are in the molar ratio of 9:1 to 5:5. The fiber-reinforced composite material of the present invention comprises the above resin composition and reinforcing fibers. The molded article manufactured using this composite material exhibits excellent strength and rigidity even under high temperatures of over 200.degree. C.Type: GrantFiled: February 26, 1996Date of Patent: March 25, 1997Assignee: Kabushiki Kaisha Kobe Seiko ShoInventors: Koji Yamamoto, Takeshi Kuri
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Patent number: 5613494Abstract: Polycondensates which contain tartaric acid derivatives, processes for their preparation and use thereof.The invention relates to polycondensates which consist of at least 95 mol % of recurring structural units of the formula I ##STR1## where R.sup.1 is a 2,3-O-alkylidenetartaric acid derivative (II) or furo[2,5] (V), alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl or a heterocycle, X is --O-- --NH-- or --S-- and R.sup.2 is 2,3-O-alkylidene-L-threitol (III) or a compound of the formula VI, alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl or a heterocycle, with the proviso that more than 5 mol % of the radicals R.sup.1 and/or R.sup.2 are present in the polycondensate of the formula I, where R.sup.1 is compound of the formula II or R.sup.2 is a compound of the formula III or R.sup.1 is a compound of the formula II and R.sup.2 is a compound of the formula III, or in which more than 5 mol % of the radicals R.sup.1 and R.sup.2 are present in the polycondensate of the formula I, wherea) R.sup.Type: GrantFiled: May 4, 1995Date of Patent: March 25, 1997Assignee: Hoechst AktiengesellschaftInventors: Volker Krone, Michael Magerstadt, Axel Walch, Gunter Ditzinger, Norbert Lill
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Patent number: 5612444Abstract: A two-step process for making polyetherester resins is disclosed. A low molecular weight polyol reacts with an aromatic dicarboxylic acid in step one to produce a polyester intermediate. In step two, the polyester intermediate reacts with an anhydride or an aliphatic dicarboxylic acid in the presence of an insertion catalyst to produce a polyetherester resin that contains greater than about 10 wt. % of recurring units derived from the aromatic dicarboxylic acid. The polyetheresters are useful for making thermoset resins with excellent mechanical properties and chemical resistance.Type: GrantFiled: March 28, 1995Date of Patent: March 18, 1997Assignee: ARCO Chemical Technology, L.P.Inventors: Gangfeng Cai, Lau S. Yang, Jeffrey A. Klang
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Patent number: 5612425Abstract: Molding compositions based on polyaryl ethers A, are obtainable by reacting polyaryl ethers I with repeating structural elements ##STR1## or derivatives thereof substituted by C.sub.1 -C.sub.6 -alkyl, alkoxy, aryl, chlorine or fluorine in the nucleus, where X and Z, independently of one another, are each --SO.sub.2 --, --O--, --S--, >C.dbd.O a chemical bond or --CRR'--, R and R' are each hydrogen, C.sub.1 -C.sub.6 -alkyl or alkoxy, R' is also aryl or fluoro- or chloro-substituted aryl, with the proviso that X and Z are not both --O--, with a reactive compound which, besides a C--C double or triple bond, contains one or more carbonyl, carboxylic acid, carboxylate, acid anhydride, amide, imide, carboxylic ester, amino, hydroxyl, epoxy, oxazoline, urethane, urea, lactam or halobenzyl moieties.Type: GrantFiled: May 14, 1993Date of Patent: March 18, 1997Assignee: BASF AktiengesellschaftInventors: Martin Weber, Klaus Muehlbach, Eckhard M. Koch
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Patent number: 5610205Abstract: A process for making polyetheresters is disclosed. A polyether is reacted with a carboxylic acid in the presence of a strong protic acid or a metal salt of a strong protic acid to promote insertion of the carboxylic acid into polyether carbon-oxygen bonds to produce a polyetherester. The polyetheresters are useful for various applications in the polyurethane and unsaturated polyester industries.Type: GrantFiled: May 14, 1996Date of Patent: March 11, 1997Assignee: ARCO Chemical Technology, L.P.Inventors: Lau S. Yang, Jeffrey A. Klang
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Patent number: 5597651Abstract: Multi-component composites containing a linear polyester of an alkyl glycol and an aromatic diacid as one component, rubber as a second component, and a third component which is a compatibilizing polyester (polystyrene copolymer).Type: GrantFiled: October 26, 1995Date of Patent: January 28, 1997Assignee: Hoechst Celanese Corp.Inventors: Eui W. Choe, Charles E. Forbes, Jennifer A. Filbey, Stephan F. Sherriff
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Patent number: 5591809Abstract: The present invention provides novel one-step processes for preparing highly branched macromolecule polymers that have highly controlled molecular architectures. The process comprises the reaction of a branching monomer such as a substituted phenyl compound having the formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 are defined herein, with a core monomer and an end-capping monomer, such as a phenolic ester, for a sufficient period of time and at a sufficient temperature to directly produce the highly branched polymer, in a single processing step.Type: GrantFiled: August 18, 1995Date of Patent: January 7, 1997Assignee: Hoechst Celanese CorporationInventors: Richard Vicari, Kathleen N. Juneau, Carl D. Murphy
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Patent number: 5587007Abstract: The specification describes a method for preparing a phenol-modified dicyclopentadiene resin. The method comprises reacting (a) dicyclopentadiene, (b) a phenol selected from the group consisting of an alkyl phenol having the formula CH.sub.3 C.sub.n H.sub.2n C.sub.6 H.sub.4 OH, where n is from 1 to 9, and a bisphenol having the formula HOC.sub.6 H.sub.4 (CR.sub.2).sub.x C.sub.6 H.sub.4 OH, where R is independently hydrogen or a C.sub.1 -C.sub.6 alkyl group and x is from 1 to 4, or mixtures thereof; (c) a fatty acid or a derivative thereof selected from the group consisting of tall oil, a tall oil derivative, dimer fatty acid, linseed oil and mixtures thereof; and (d) an unsaturated organic diacid or an anhydride thereof, at a temperature and autogenous pressure sufficient to produce a phenol-modified dicyclopentadiene resin. The resin product exhibits improved compatibility with ink vehicles and formulations, particularly ARLO or alkyd modified inks.Type: GrantFiled: August 14, 1995Date of Patent: December 24, 1996Assignee: Arizona Chemical CompanyInventor: Daniel R. Curvin
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Patent number: 5569737Abstract: A process for making polyetheresters is disclosed. A polyether is reacted with a carboxylic acid in the presence of a strong protic acid or a metal salt of a strong protic acid to promote insertion of the carboxylic acid into polyether carbon-oxygen bonds to produce a polyetherester. The polyetheresters are useful for various applications in the polyurethane and unsaturated polyester industries.Type: GrantFiled: April 10, 1995Date of Patent: October 29, 1996Assignee: Arco Chemical Technology, L.P.Inventors: Lau S. Yang, Jeffrey A. Klang
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Patent number: 5548059Abstract: Unsaturated linear polymers have repeating units of a reaction product of a first monomer, a second monomer, a third monomer and optionally a fourth monomer. The linear polymers have a glass transition temperature ranging from about 52.degree. C. to about 61.degree. C. The first monomer should have a weight average molecular weight less than 200. The second monomer may be a dicarboxylic acid or diester which is different than the third monomer. A concentration of second residues of the polymer, derived from the second monomer, ranges from about 3 wt. % to about 15 wt. %, based on the total weight of the polymer. The third monomer is an aromatic dicarboxylic acid or an ester thereof. In the polymer, a concentration of third residues, derived from the third monomer, ranges from about 40 wt. % to about 55 wt. %, based on the total weight of the polymer. The fourth monomer is a diol having a higher molecular weight than the first monomer.Type: GrantFiled: January 3, 1995Date of Patent: August 20, 1996Assignee: Xerox CorporationInventors: Robert D. Bayley, Carol A. Fox, Thomas R. Hoffend, Hadi K. Mahabadi, Enno E. Agur, Guerino Sacripante, Michael S. Hawkins
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Patent number: 5523380Abstract: A polymer comprising an .alpha.-glycol structure unit ##STR1## and a carboxylic acid-based structure unit ##STR2## provides superior results with respect to dispersibility, a chelating ability and a viscosity-stabilizing effect and is useful as a detergent builder, pigment- and cement-dispersing agents, a hydrogen peroxide stabilizer and a gas barrier agent. This polymer can further comprise the following lactone structure unit. ##STR3## This polymer can be produced by copolymerizing a conjugated diene monomer and a carboxylic acid-based monomer and oxidizing a copolymer obtained.Type: GrantFiled: July 13, 1994Date of Patent: June 4, 1996Assignee: Nippon Shokubai Co., Ltd.Inventors: Hideyuki Tahara, Hiroshi Itoh, Keiji Kofuji, Masahito Takagi
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Patent number: 5519107Abstract: Novel polyesters prepared from a diol, a dicarboxylic acid or ester forming reactive derivative thereof and an aromatic amino acid, ester or alcohol are disclosed.Type: GrantFiled: November 17, 1994Date of Patent: May 21, 1996Assignee: General Electric CompanyInventors: John A. Tyrell, Gary F. Smith
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Patent number: 5512633Abstract: Copolymers of vinyl aromatic monomers and propoxylated allyl alcohols having an average of 2 or less oxypropylene groups are disclosed. The copolymers, which have hydroxyl numbers of 80-260 mg KOH/g and number average molecular weights from 500-3500, are particularly useful for polyurethanes, alkyd resins and coatings, melamine-based coatings, and unsaturated polyester resins.Type: GrantFiled: April 12, 1995Date of Patent: April 30, 1996Assignee: Arco Chemical Technology, L.P.Inventor: Shao-Hua Guo
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Patent number: 5510453Abstract: The invention relates to novel branched polyesters containing allyl groups, which polyesters are water-emulsifiable, and their use as raw materials for lacquers.Type: GrantFiled: April 7, 1995Date of Patent: April 23, 1996Assignee: Wolff Walsrode AktiengesellschaftInventors: Burkhard Kressdorf, Erhard Luhmann, Wolfgang Dannhorn, Lutz Hoppe
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Patent number: 5505784Abstract: The invention relates to polycondensates which consist of at least 95 mol % of recurring structural units of the formula I ##STR1## where R.sup.1 is a 2,3-O-alkylidenetartaric acid derivative (II) or furo[2,5] (V), alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl or a heterocycle, X is --O--, --NH-- or --S-- and R.sup.2 is 2,3-O-alkylidene-L-threitol (III) or a compound of the formula VI, alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl or a heterocycle, with the proviso that more than 5 mol % of the radicals R.sup.1 and/or R.sup.2 are present in the polycondensate of the formula I, where R.sup.1 is compound of the formula II or R.sup.2 is a compound of the formula III or R.sup.1 is a compound of the formula II and R.sup.2 is a compound of the formula III, or in which more than 5 mol % of the radicals R.sup.1 and R.sup.2 are present in the polycondensate of the formula I, wherea) R.sup.1 is a compound of the formula V and R.sup.2 is a compound of the formula VI, orb) R.sup.Type: GrantFiled: January 10, 1995Date of Patent: April 9, 1996Assignee: Hoechst AktiengesellschaftInventors: Volker Krone, Michael Magerstadt, Axel Walch, Gunter Ditzinger, Norbert Lill
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Patent number: 5504158Abstract: There is provided in accordance with the present invention polyphenylene ether/polyalkyleneterephthalamide compositions of high dimensional stabilities that are suitable for high temeprature applications comprising from about 20 to about 70 weight % of a functionalized polyphenylene ether; from about 20 to about 70 weight % of a polyalkyleneterephthalamide, wherein the polyalkyleneterephthalamide is derived from terephthalic acid and an .alpha.,.omega.-alkanediamine having 10 to 14 methylene groups; and from about 0 to about 20 weight % of a functionalized elastomeric polymer, wherein the blend absorbs less than 2 wt % of moisture and has a dimensional growth in water of less than 0.5%.Type: GrantFiled: January 10, 1995Date of Patent: April 2, 1996Assignee: AlliedSignal Inc.Inventors: Murali K. Akkapeddi, Jeffrey H. Glans
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Patent number: 5502118Abstract: Polymer salts whose anionic component is a polyester which comprises the product of reaction of the individual components a), b) and c) and if desired d) and if desired e), wherea) is a dicarboxylic acid or a reactive derivative of a dicarboxylic acid, being free from sulfo groups,b) is a difunctional aromatic, aliphatic or cycloaliphatic sulfo compound whose functional groups are hydroxyl or carboxyl, or hydroxyl and carboxyl,c) is an aliphatic, cycloaliphatic or aromatic diol, a polyetherdiol or a polycarbonatediol,d) is a polyfunctional compound (functionality>2) whose functional groups are hydroxyl or carboxyl, or hydroxyl and carboxyl, ande) is a monocarboxylic acidand whose cationic component comprises hydrogen atoms, metal cations, substituted ammonium cations, immonium cations, guanidinium cations, phosphonium, arsonium or stibonium cations or a mixture of the abovementioned cations, are suitable as charge control agents and charge improvers in electrophotographic toners and developers, in triboeleType: GrantFiled: September 21, 1994Date of Patent: March 26, 1996Assignee: Hoechst AktiengesellschaftInventors: Hans-Tobias Macholdt, Ru/ diger Bauer, Joachim Zo/ ller
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Patent number: 5494964Abstract: Polyester resins suitable as binders for electrophotographic toners and for acceptor layers for the thermal diffusion printing process based on hydroxyl-containing prepolymers of olefinically unsaturated monomers obtained by(1) polymerization of a mixture of(a) from 60 to 90% by weight of styrene or of a styrene derivative,(b) from 0 to 40% by weight of one or more C.sub.1 -C.sub.Type: GrantFiled: September 30, 1994Date of Patent: February 27, 1996Assignee: BASF AktiengesellschaftInventors: Georg Meichsner, Thomas Wuensch, Rainer Dyllick-Brenzinger
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Patent number: 5474854Abstract: The invention is a polyester composition containing crosslinked polymer particles with ester bonds at the main chain. The particles are excellent in affinity to polyesters, and so the films formed from the polyester compositions do not have the particles falling off during high speed running, and do not have flaws in the film surfaces. The invention can prevent the generation of white powder and the flaws of magnetic faces caused by falling-off particles, and prevent the contamination in the production of films, even though these are problems caused when various conventional particles are added, and is especially suitable for use as products such as magnetic films.Type: GrantFiled: August 9, 1994Date of Patent: December 12, 1995Assignee: Toray Industries, Inc.Inventors: Nobuyuki Kagami, Masatoshi Aoyama, Masaru Suzuki, Keisuke Oshima
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Patent number: 5456947Abstract: A determined amount of at least C.sub.8 dicarboxylic functional unsaturated anhydride or acid, excluding polymeric anhydrides and acids, is incorporated in an unsaturated polyester resin which comprises (1) a condensation polymer which is the reaction product of: (a) dicarboxylic acid, at least a portion of which contains ethylenic unsaturation, with (b) dihydric alcohols; and (2) an alpha-beta-ethylenically unsaturated copolymerizable monomer, to provide modified polyester resins for curable polyester resin systems having improved cohesive and adhesive strengths of the cured resin and improvement in adhesion of such systems to a wide range of substrates, especially substrates considered extremely difficult to bond to, viz., hot dipped galvanized steel, stainless steel, copper, bronze, tin, aluminum, solder, brass and glass (silicon oxide), while also reducing or effectively eliminating retardation of cure by the presence of galvanized (zinc) coated steel or the like.Type: GrantFiled: February 19, 1991Date of Patent: October 10, 1995Assignee: Fibre Glass-Evercoat Company, Inc.Inventors: David M. Parish, John A. Hatton, Jr.
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Patent number: 5451667Abstract: Fumaric acid derivatives of the formula ##STR1## wherein R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.8 alkyl group or a metallic cation, andR.sub.2 is a saturated or unsaturated aliphatic C.sub.6 -C.sub.24 alkyl group, psoralen-9-yl, retinyl, .alpha.-tocopheryl (vitamin E), calciferyl, corticosteroid-21-yl or monosaccharid-.omega.-yl; a group of fumaric acid derivatives based on glycerol, alkane diol or polyol molecules; and fumaric acid derivatives of the formula ##STR2## wherein n is an integer from to 30 to 260,R.sub.3 is a hydrogen atom or a C.sub.1 -C.sub.3 alkyl group,R.sub.4 is one of the R.sub.3 groups and n is the number of molecule repetitions, processes for their production and compositions containing same are described. These compounds are useful as drugs for the treatment of cryptogenically-caused diseases and have antisporiatic as well as antimicrobial action.Type: GrantFiled: October 8, 1992Date of Patent: September 19, 1995Inventors: Peter P. Speiser, Rajendra K. Joshi
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Patent number: 5451656Abstract: Polyester polymers having pendant carbamate groups are disclosed. The polymers are prepared by:(a) reacting a hydroxyalkyl cyclic carbonate with ammonia, ammonium hydroxide, or a primary amine to form a dihydric alcohol having a carbamate group appended thereto,(b) reacting the dihydric alcohol from (a) and a cyclic anhydride to form a half-ester diacid having a carbamate group appended thereto, and(c) reacting a mixture comprising the half-ester diacid from step (b) and a polyol to form a polyester having carbamate groups appended thereto.Type: GrantFiled: December 21, 1994Date of Patent: September 19, 1995Assignee: BASF CorporationInventors: Gregory L. Menovcik, Walter H. Ohrbom
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Patent number: 5442037Abstract: A shape-memory polyester prepolymer is prepared with at least one kind of dicarboxylic acid component and at least one kind of diol, triol or polyol component in such a way to have unsaturated end group, wherein the dicarboxylic acid component comprises aromatic dicarboxylic acid in an amount of not less than 80% by mole based on the total mole of the dicarboxylic acid component; the diol component comprises a diol containing 2-10 carbon atoms in an amount of not less than 80% by mole based on the total mole of the diol component; a repeating unit of the ester bond ranging in number from 2 to 50; and the end group has crosslinkable, ethylenically unsaturated bond. The prepolymer shows particularly excellent heat resistance and excellent chemical resistance and also exhibits excellent transparency.Type: GrantFiled: September 7, 1994Date of Patent: August 15, 1995Assignee: Tong Yang Nylon Co., Ltd.Inventors: Chang-Hwang Lee, Jae-Yeon Hwang, Byeong-Seok Chae
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Patent number: 5436314Abstract: A process for making polyetheresters is disclosed. A polyether is reacted with a carboxylic acid in the presence of a strong protic acid or a metal salt of a strong protic acid to promote insertion of the carboxylic acid into polyether carbon-oxygen bonds to produce a polyetherester. The polyetheresters are useful for various applications in the polyurethane and unsaturated polyester industries.Type: GrantFiled: April 18, 1994Date of Patent: July 25, 1995Assignee: ARCO Chemical Technology, L.P.Inventors: Lau S. Yang, Jeffrey A. Klang