Cycloaliphatic Ring-containing Reactant (other Than Aryl) Patents (Class 528/307)
  • Patent number: 7368165
    Abstract: A heat-sealable polymeric film includes a substrate layer of polymeric material having on a surface thereof a heat-sealable coating layer. The layer includes a copolyester and is less than 8 ?m in thickness. The copolyester consists essentially of repeat units of one or more aromatic dicarboxylic acids, one or more aliphatic dicarboxylic acids, and a stoichiometric amount of a glycol component consisting of one or more glycols selected from the group consisting of aliphatic glycols and cycloaliphatic glycols.
    Type: Grant
    Filed: June 16, 2005
    Date of Patent: May 6, 2008
    Assignee: DuPont Teijin Films U.S. Limited Partnership
    Inventors: Stephen William Sankey, Kenneth Evans, Mark Russell Hodgson
  • Patent number: 7358325
    Abstract: Sulfonated aromatic copolyesters and articles made therefrom, and processes for producing the sulfonated aromatic copolyesters and articles are provided. Articles that can be made from the sulfonated aromatic copolyesters include films, coatings and laminates. Some of the compositions and articles are biocompostable. The films can further be used to form shaped articles such as sheets, food packaging such as sandwich wraps, thermoformed containers, and coatings for, for example, films and other substrates. The sulfonated aromatic copolyesters contain a hydroxyalkanoic acid component.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: April 15, 2008
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Richard Allen Hayes
  • Patent number: 7332562
    Abstract: The present invention relates to a biodegradable copolyester of high molecular weight and narrow molecular weight distribution. The copolyester has a Mw of 100,000-600,000 g/mol, and a molecular weight distribution of 1.2-3.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: February 19, 2008
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry
    Inventors: Wei Chen, Guixiang Zhu, Xirong Chen, Jinglan Lu, Yanxia Zhang, Yifan Yan, Wei Zhang
  • Publication number: 20080008962
    Abstract: Novel polymerizable ester compounds having formulae (1) to (4) undergo no acid-induced decomposition by ?-elimination wherein A1 is a polymerizable functional group having a carbon-carbon double bond, R1 is H or —C—(R5)3, R2 and R3 are alkyl, R4 is H or alkyl, R5 is a monovalent hydrocarbon group, X is alkylene, Y is methylene, ethylene or isopropylidene, Z is alkylene, and n=1 or 2. Resist compositions comprising polymers derived from the ester compounds have excellent sensitivity and resolution and lend themselves to micropatterning lithography.
    Type: Application
    Filed: July 5, 2007
    Publication date: January 10, 2008
    Inventors: Takeru Watanabe, Takeshi Kinsho, Koji Hasegawa, Seiichiro Tachibana, Masaki Ohashi
  • Patent number: 7306835
    Abstract: The present invention relates to a thermo-shrinkable polyester film with a superior thermal shrinkage, which has an orientation angle of a molecular chain in a range of from 0° to about ±10° relative to a main shrinkage direction, and a molecular orientation ratio (MOR) in a range of from 1.29 to about 2.5, thereby preventing a label made from the film from curling or waving.
    Type: Grant
    Filed: January 29, 2007
    Date of Patent: December 11, 2007
    Assignee: Kolon Industries, Inc.
    Inventors: Ki Il Hong, Gi Sang Song
  • Patent number: 7282555
    Abstract: The present invention is a method for efficiently incorporating a nitrogen containing methine light absorber into a polyester resin. The method includes forming a reaction mixture comprising combining a diol component, a diacid component selected from the group consisting of dicarboxylic acids, dicarboxylic acid derivatives, and mixtures thereof, an antimony containing compound, a phosphorus containing compound, a metal containing compound, and a nitrogen containing methine light absorber. The reaction mixture is polymerized in a polycondensation reaction system. In another embodiment the light absorber is added while the reaction products of one reactor are being transferred to the next reactor in the polycondensation reaction system. The present invention is also directed articles made from the polyester resin.
    Type: Grant
    Filed: May 27, 2004
    Date of Patent: October 16, 2007
    Assignee: Eastman Chemical Company
    Inventors: Max Allen Weaver, Jason Clay Pearson, Dale Milton Blakely, Frederick Leslie Colhoun
  • Patent number: 7250485
    Abstract: A toner resin composition comprising a linear polyester resin (A) containing a C3 to C10 aliphatic diol component and a linear polyester resin (B) containing a C3 to C10 aliphatic diol component which differs from the linear polyester resin (A), or further comprising a vinyl-based resin (C), and a toner containing the toner resin composition as a binding resin. A toner excellent in low temperature fixability, offset resistance, gloss, etc. and excellent in range of fixing temperature can be obtained.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: July 31, 2007
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Hirokazu Ito, Masaru Sugiura, Yoko Tamura, Akifumi Kondou, Shinya Yamato
  • Patent number: 7244506
    Abstract: A high reflectivity coated substrate and coating composition employing a binder containing a polyester resin that includes a cycloaliphatic group and has a number average molecular weight from about 1,000 to 40,000. The binder contains less than 40 weight percent aromatic group containing compound and the weight ratio of pigment to binder is greater than 0.9:1. When the binder is blended with rutile TiO2 at a solids loading of 50 weight percent and coated to a dried film thickness of 0.00254 cm, the coating exhibits a Y-value of at least 85.5.
    Type: Grant
    Filed: August 25, 2005
    Date of Patent: July 17, 2007
    Assignee: Valspar Sourcing, Inc.
    Inventors: Gregory Bryant Hayes, Thomas John Melnyk
  • Patent number: 7241485
    Abstract: A glass protecting film comprising at least 5 or more layers, of which at least one layer is the layer which comprises polyester having 1,4-cyclohexane dimethanol is one of the components, and a glass protecting comprising a multi-layer structure which comprises at least two kinds of thermoplastic resin, of which the difference of glass transition temperature is 40° C. or less, the face-impact strength is 18 J/mm or more, haze is 3% or less, are films which excel in transparency, tear resistance, and impact resistance, and are suitable for protecting glass and preventing damaged glass fragments.
    Type: Grant
    Filed: October 28, 2002
    Date of Patent: July 10, 2007
    Assignee: Toray Industries, Inc.
    Inventors: Syunichi Osada, Shigetoshi Maekawa, Kazumori Sonoda
  • Patent number: 7238411
    Abstract: The present invention is a multilayer polyester film comprising a layer A and a layer B which are laminated alternately, the layer A constituting the outermost layer on both sides of the film, wherein (1) the layer A comprises a polyester A, and the layer B comprises a polyester B, (2) the melting point of the polyester A is higher than the melting point of the polyester B by at least 15° C., (3) the layer A is a layer having an oriented structure, and the layer B is a layer having a substantially unoriented structure, (4) the ratio (a/b) of the total thickness (a) of the layer A to the total thickness (b) of the layer B is 0.01 to 3, and (5) the in-plane tensile strength of the multilayer polyester film is 50 MPa or lower at a maximum, and the difference between its maximum value and minimum value is 20 MPa or smaller; and a method for producing the multilayer polyester film.
    Type: Grant
    Filed: February 10, 2003
    Date of Patent: July 3, 2007
    Assignee: Teijin Limited
    Inventors: Tetsuo Yoshida, Tetsuo Ichihashi
  • Patent number: 7238770
    Abstract: The present invention relates to methods of making imide-modified polyester imide resins. The present invention further relates to forming these imide-modified polyester imide resins into articles, such as preforms, bottles, containers, sheets, films, fibers, and injection molded parts.
    Type: Grant
    Filed: January 28, 2005
    Date of Patent: July 3, 2007
    Assignee: Wellman, Inc.
    Inventors: Walter L. Edwards, Marion L. Andrews
  • Patent number: 7235623
    Abstract: Polyester compositions that provide a higher throughput in calendering processes may be prepared from a polyester having crystallization half time of at least 5 minutes, an inherent viscosity of about 0.55 to about 0.75 dL/g, a branching monomer, and a release additive. The polyester compositions show a combination of excellent melt strength with good shear response that permits higher calendering line speeds before melt fracture occurs. Also disclosed are processes for film or sheet by calendering the above compositions and the film or sheet produced therefrom. The polyester compositions, film, or sheet also may include plasticizers and/or flame retardants to increase their flexibility and enable their use in commercial applications requiring flame resistance. The film and sheet have excellent appearance and can be used in a wide range of decorative and packaging applications.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: June 26, 2007
    Assignee: Eastman Chemical Company
    Inventors: Marc Alan Strand, Rodney Layne Piner, Eric Jon Moskala
  • Patent number: 7211633
    Abstract: The invention is directed to polyester processes that utilizes a pipe reactor in the esterification, polycondensation, or both esterification and polycondensation processes. Pipe reactor processes of the present invention have a multitude of advantages over prior art processes including improved heat transfer, volume control, agitation and disengagement functions.
    Type: Grant
    Filed: April 7, 2004
    Date of Patent: May 1, 2007
    Assignee: Eastman Chemical Company
    Inventor: Bruce Roger DeBruin
  • Patent number: 7211634
    Abstract: Disclosed is a process for the preparation of high molecular weight polyesters by reacting one or more dicarboxylic acids directly with 1,4-cyclohexanedimethanol and, optionally, one or more diols. The process uses an overall diol to dicarboxylic acid molar ratio of about 0.97 to about 1.2 and an incremental addition of either the diacid or diol components. The process provides a shorter total reaction time and, thus, lessens the thermal degradation of polyester which may result in high color and reduced molecular weight.
    Type: Grant
    Filed: April 28, 2006
    Date of Patent: May 1, 2007
    Assignee: Eastman Chemical Company
    Inventors: Daniel Lee Martin, Joseph Franklin Knight, Benjamin Fredrick Barton, Damon Bryan Shackelford
  • Patent number: 7208104
    Abstract: A mixture solution for preparing conducting polymers. The conducting polymer is formed from a mixture of monomer and oxidant solution. The oxidant solution has a high concentration, and also includes a five or six-member ring compound with a functional group which acts as a retardant for the polymerization. Thus, the mixture of a monomer and oxidant solution exhibits excellent stability at room temperature. The conducting polymer accumulating in the space of the capacitor element can be more efficiently formed by using this high concentration oxidant solution. Therefore, the immersion and polymerization processes to form conducting polymer as the electrolyte of a solid electrolytic capacitor can be limited to only a few occurrences.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: April 24, 2007
    Assignee: Industrial Technology Research Institute Material Research Laboratories
    Inventors: Li-Duan Tsai, Yi-Chang Du
  • Patent number: 7196158
    Abstract: A knitted/woven fabric of polyester fibers is produced from a polyester polymer obtained by condensation-polymerizing an aromatic dicarboxylate in the presence of a catalyst which comprises a mixture of a titanium compound ingredient (A) comprising a titanium alkoxide and at least one product of the reaction of the titanium alkoxide with a specific carboxylic acid or anhydride thereof and a specific phosphorus compound ingredient (B) and/or comprises a product of the reaction of a titanium compound ingredient (C) with a specific phosphorus compound ingredient (D). The knitted/woven fabric obtained has a satisfactory color tone (low value of b*) and is excellent in suitability for knitting/weaving and dyeability.
    Type: Grant
    Filed: December 24, 2003
    Date of Patent: March 27, 2007
    Assignee: Teijin Fibers Limited
    Inventors: Tsuyoshi Soeda, Shuji Minato, Norimitsu Kamiyama
  • Patent number: 7193029
    Abstract: The present invention provides certain sulfonated copolyetherester compositions containing hydroxyalkanoic acids and processes for producing such sulfonated aromatic copolyetheresters. The invention further provides shaped articles, preferably in the shape of films, coatings and laminates, having improved thermal properties, wherein the shaped articles are produced from the certain sulfonated copolyetherester compositions. Some of these materials are also biocompostable. The sulfonated copolyetheresters are produced from a mixture of an aromatic dicarboxylic acid component, hydroxyalkanoic acid component, a sulfonate component, a poly(alkylene ether) glycol component, a glycol component, an optional other glycol component, an optional branching agent, and an optional color reducing agent.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: March 20, 2007
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Richard Allen Hayes
  • Patent number: 7189441
    Abstract: The invention concerns polyester resins, more particularly polyethyleneterephthalate resins used for making hollow containers, such as bottles for packaging liquid substances, in particular aerated beverages, natural or mineral waters. The invention concerns a polyester comprising at least 92.5% in number of recurrent units derived from terephthalic acid of aliphatic diols having an intrinsic viscosity ranging between 0.45 dl/g and 0.70 dl/g, and an acetaldehyde content less than 3 ppm, preferably less than 1.5 ppm. The invention also concerns a method for obtaining polyester granules with low acetaldehyde content having an intrinsic viscosity in the range mentioned above. Said polyesters are used in particular for making hollow containers such as bottles and more particularly bottles designed to contain foodstuffs sensitive to acetaldehyde.
    Type: Grant
    Filed: July 11, 2002
    Date of Patent: March 13, 2007
    Assignee: Nestle Waters Management & Technology
    Inventors: Gérard Denis, Murielle Vigny, Gérard Perez, Jean-Luc Lepage
  • Patent number: 7173100
    Abstract: The present invention relates to a receiving-layer-forming polyester resin for use in a thermal-transfer image-receiving sheet, comprising: not less than 70 mol % of isophthalic acid and not more than 30 mol % of terephthalic acid as acid components; and not less than 30 mol % of diols having an alicyclic structure and not more than 30 mol % of ethylene glycol as diol components, and a thermal-transfer image-receiving sheet with a receiving layer formed on at least one of surfaces of the substrate sheet, in which the receiving layer is formed by such a receiving-layer-forming polyester resin.
    Type: Grant
    Filed: March 30, 2005
    Date of Patent: February 6, 2007
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Naoyuki Mitsuyasu, Masayasu Yamazaki, Taro Suzuki, Minoru Takahashi, Hirotoshi Kizumoto
  • Patent number: 7157525
    Abstract: The present invention relates to a thermoplastic elastomer resin which has good melt viscosity, melt tension, and thermal resistance, wherein it is prepared by introducing a chain extender and a stabilizer for hydrolysis to a thermoplastic elastomer resin produced through melt polymerization in the presence of hydroxy carboxylic acid compound and subjecting the mixture to reactive extrusion to increase the molecular weight and crosslinking degree of the elastomer resin. The thermoplastic elastomer resin according to the present invention has good properties for automobile parts, particularly constant velocity joint boots and bellows.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: January 2, 2007
    Assignee: Samyang Corporation
    Inventors: Sung-Hwan Cho, Sun-Woong Kim, Jun-Hee Lee, Oh-Kwun Son, Byung-Ho Lim
  • Patent number: 7153587
    Abstract: The present invention provides a polyester resin which comprises (a-1) 45 to 99% by mole of an oxycarboxylic acid unit having 5 carbon atoms or less, (a-2) 0.5 to 27.5% by mole of an aromatic dicarboxylic acid unit, and (a-3) 0.5 to 27.5% by mole of an aliphatic diol unit having 4 carbon atoms or less, and containing (a-1) to (a-3) in a total amount of 95% by mole or greater, wherein the relationship between the content of the oxycarboxylic acid, expressed as M % by mole, and the density ? (kg/m3) of the polyester resin, satisfies the formula ??1349+M×0.85.
    Type: Grant
    Filed: May 31, 2004
    Date of Patent: December 26, 2006
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Junji Tan, Yasuhiro Mutou, Seiji Ota, Toyoaki Sasaki
  • Patent number: 7153569
    Abstract: Biodegradable aliphatic-aromatic films are disclosed. The films comprise filler particles and a copolyester. The films have high vapor permeability and tensile strength and are suitable for use in absorbent and non-absorbent products.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: December 26, 2006
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ross Thomas Kaufman, Vasily Aramovich Topolkaraev, Gregory James Wideman, Richard Warren Tanzer
  • Patent number: 7150907
    Abstract: A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70–100 mol % of the carboxylate subunits are first carboxylate subunits and 0–30 mo1 % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: December 19, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Timothy J. Hebrink, William W. Merrill, Carl A. Stover
  • Patent number: 7147927
    Abstract: Disclosed are biaxially oriented polyester film produced from a polyester comprising: (1) diacid residues comprising at least 90 mole percent of terephthalic acid residues, naphthalenedicarboylic acid residues or combinations thereof; and (2) diol residues comprising at least 90 mole percent of 1,4-cyclohexanedimethanol residues; wherein the polyester comprises a total of 100 mole percent diacid residues and a total of 100 mole percent diol residues; wherein the polyester film is stretched at a ratio of about 2.5× to 3× in the machine direction (MD) and about 2.5× to 3× in the transverse direction (TD) at stretching temperatures between 90 and 1 10OC, wherein the stretched film is subsequently heat-set at an actual film temperature of from 260° C.
    Type: Grant
    Filed: June 25, 2003
    Date of Patent: December 12, 2006
    Assignee: Eastman Chemical Company
    Inventors: Thomas Joseph Pecorini, Gary Darrel Boone
  • Patent number: 7144614
    Abstract: This invention provides a novel polymerization catalyst other than antimony compounds, polyester produced by using the same and a process for producing polyester. The polycondensation catalyst of this invention is a polyester polymerization catalyst comprising an aluminum compound and a phosphorus compound having a specific structure. Further, this invention relates to polyester produced by using this polyester polymerization catalyst and a process for producing polyester. Further, this invention relates to fibers, films and hollow molded articles comprising the polyester.
    Type: Grant
    Filed: July 2, 2002
    Date of Patent: December 5, 2006
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Takahiro Nakajima, Ken-ichi Tsukamoto, Shoichi Gyobu, Nobuo Moriyama, Mitsuyoshi Kuwata, Yoshinao Matsui, Seisyu Hayashi, Katsuya Ito, Masaou Matsuda
  • Patent number: 7141627
    Abstract: An epoxy resin cured article has a high glass transition temperature and low dissipation factor. An epoxy resin composition from which the cured article can be having excellent solubility in solvents is used to produce the cured articles. A polyester as a curing agent of an epoxy resin composition having an aromatic polyhydroxy coumpound residue including an aryloxycarbonyl group at the molecule of the terminal, an aromatic polyvalent hydrocarbon group residue, and bulky structure, is used. Since the curing agent behaves as a polyfunctional curing agent, a cured article produced therefrom has a high crosslink density. Since highly polar hydroxyl groups are not formed during curing, a cured article has high glass transition temperature and a low dissipation factor. The cured article does not release low molecular weight carboxylic acids though hydrolysis of ester bonds at crosslinked bonds.
    Type: Grant
    Filed: October 27, 2003
    Date of Patent: November 28, 2006
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Satoshi Idemura, Masao Yamada, Koichi Fujimoto, Katsuji Takahashi
  • Patent number: 7128863
    Abstract: Disclosed herein is a heat-shrinkable co-polyester film having terephthalic acid and ethylene glycol as main components and containing 1,4-cyclohexanedimethanol at the amount of 3–40 mol %. The heat-shrinkable co-polyester film has a crystallization temperature of 80–220° C., a heat shrinkage (%) higher than 30% in at least one direction of longitudinal and transverse directions in 90° C. hot water, and a maximum shrinkage stress lower than 3 kg/mm2. The film is suitable for use as various wrapping materials, such as covering, binding and casing materials. Particularly, the film is used to cover a cap, body and shoulder, etc. of various vessels and rod-shaped molded articles and thus to provide labeling, protection, binding or an improvement in product value. Also, the film can be used for multi-package.
    Type: Grant
    Filed: June 23, 2004
    Date of Patent: October 31, 2006
    Assignee: Toray Saehan Inc.
    Inventors: Sang-Pil Kim, Byung-Sik Park, Gi-Jeong Moon, Sang-Duk Oh, Jung-Won Kim
  • Patent number: 7129301
    Abstract: A method for preparing a biodegradable copolyester includes: (a) optionally preparing an aromatic prepolymer by reacting a first aromatic dicarboxylic compound with a first aliphatic glycol; (b) reacting the aromatic prepolymer with a second aromatic dicarboxylic compound and a second aliphatic glycol so as to form a first reaction product; (c) reacting the first reaction product with an aliphatic dicarboxylic compound so as to form a second reaction product; and (d) performing polycondensation of the second reaction product.
    Type: Grant
    Filed: April 28, 2005
    Date of Patent: October 31, 2006
    Assignee: Far Eastern Textile Ltd.
    Inventors: Ru-Yu Wu, Chih-Wei Chu, Li-Ling Chang, Yi-Hsuan Tang, Ping-Sheng Lai
  • Patent number: 7125611
    Abstract: The invention relates to a composition comprising a polyester copolymer that comprises (a) recurring dibasic acid derived units and polyol derived units, at least 50 mole % of the dibasic acid derived units comprising dicarboxylic acid derived units each containing an alicyclic ring, (b) 25 to 75 mole % of the polyol derived units containing an aromatic ring not immediately adjacent to each hydroxyl group of the corresponding polyol, (c) 25 to 75 mole % of the polyol derived units of the polyester are non-aromatic, and (d) at least 0.1 mole percent, in sum total, of units derived from a multifunctional polyol having more than two hydroxy groups and/or units derived from a polyacid having more than two carboxylic acid groups and derivatives thereof. The invention is also directed to shaped articles, especially extruded films, made from such compositions. Examples of such extruded films are image-receiving layers for use in an image-recording element.
    Type: Grant
    Filed: February 26, 2003
    Date of Patent: October 24, 2006
    Assignee: Eastman Kodak Company
    Inventors: Teh-Ming Kung, Paul D. Yacobucci, Eric E. Arrington
  • Patent number: 7115686
    Abstract: A water-dilutable polyester resin ABCD having a mass fraction of from 1 to 10% of units derived from unsaturated cocondensed building blocks, an olefinic double bond content of from 10 to 2 000 mmol/kg, and a sulfonic acid group content of from 20 to 300 mmol/kg, modified if desired by copolymerizing olefinically unsaturated monomers in the presence of the polyester resin, a process for preparing them, and their use in particular in one-component coating compositions in combination with amino resin curatives.
    Type: Grant
    Filed: March 11, 2004
    Date of Patent: October 3, 2006
    Assignee: Surface Specialties Austria GmbH
    Inventors: Gerhard Reidlinger, Johann Billiani, Rudolf Jedlicka, Ewald Zrin, Julius Burkl, Johannes Scherz
  • Patent number: 7105627
    Abstract: A copolyester composition comprising units of residues of a) about 1–40 mole % of trans 3,3?, trans 4,4? stilbene dicarboxylic acid and the combination thereof, b) about 99˜60 mole % of cis,trans, and the combination thereof of 1,4 cyclohexane dicarboxylic acid, and c) about 50˜100 mole % of cis, trans, and the combination thereof of 1,4-cyclohexane dimethanol. The resulting copolyester may be characterized by its clarity, as well as enhanced heat performance due to the presence of the stilbene moiety.
    Type: Grant
    Filed: August 15, 2005
    Date of Patent: September 12, 2006
    Assignee: General Electric Company
    Inventors: Ganesh Kannan, Steven James Montgomery
  • Patent number: 7105260
    Abstract: A binder resin for a toner comprises a polyester component having a specific structure which is not soluble in tetrahydrofuran, and a polyester component having a specific branched structure which is soluble in tetrahydrofuran. The binder resin can provide a toner, which is superior in low-temperature fixation and offset resistance and can be used in high speed printing in response to the recent market demands owing to its specific structure.
    Type: Grant
    Filed: May 30, 2003
    Date of Patent: September 12, 2006
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tomoya Terauchi, Hirotaka Uosaki, Hiroshi Matsuoka, Yuji Emura, Hiroyuki Takei, Hironobu Hashimoto
  • Patent number: 7087313
    Abstract: Disclosed is a biaxially stretched polylactic acid multilayer film and the use thereof as packaging film. The gist of the biaxially stretched polylactic acid multilayer film resides in the construction wherein a substrate layer (1) of the biaxially stretched film comprised of polylactic acid (A) has been laminated on at least one surface thereof with a coating layer (II) of an aliphatic polyester composition (D) comprised of 97˜5% by weight of an aliphatic polyester copolymer (B) having a melting point (Tm) of 80˜120° C., a crystallizing temperature (Tc) of 35˜75° C. and a difference of (Tm)?(Tc) within the range of 35˜55° C. and comprising an aliphatic or alicyclic dicarboxylic acid component (b1), an aliphatic or alicyclic dihydroxyl compound component (b2) and a difunctional aliphatic hydroxycarboxylic acid component (b3) and 3˜95% by weight of a polylactic acid copolymer (C) containing 7˜30% by weight of D-lactic acid, a total of the ingredients (B) and (C) being 100% by weight.
    Type: Grant
    Filed: July 21, 2005
    Date of Patent: August 8, 2006
    Assignee: Tohcello Co., Ltd.
    Inventors: Tohru Sawai, Junichi Narita, Hiroyuki Wakaki
  • Patent number: 7074879
    Abstract: There are disclosed polyester processes using a pipe reactor and corresponding apparatuses. In particular, there are disclosed processes and corresponding apparatuses including an esterification pipe reactor with a recirculating reaction zone (RR zone) and a plug reaction profile reaction zone (PRPR zone), especially when operated with a significant part of the overall conversion taking place in the plug reaction profile reaction zone (PRPR zone).
    Type: Grant
    Filed: June 6, 2003
    Date of Patent: July 11, 2006
    Assignee: Eastman Chemical Company
    Inventors: Bruce Roger DeBruin, Daniel Lee Martin
  • Patent number: 7064169
    Abstract: Polyester resin composition (C) comprises polyester resin (A), which comprises polyester resin (l) comprising a diol unit having a cyclic acetal structure (CA) and a dicarboxylic acid unit having no CA, polyester resin (m) comprising a dicarboxylic acid unit having CA and a diol unit having no CA and/or polyester resin (n) comprising a diol unit having CA and a dicarboxylic acid unit having CA, and polyester resin (B) having no CA. The sum of the fraction of the dicarboxylic acid unit having CA in the entire dicarboxylic acid unit and the fraction of the diol unit having CA in the entire diol unit in composition (C) is 0.05% by mole or greater. The polyester resin compositions are excellent in transparency, melt viscoelasticity, heat resistance and moldability, and exhibit a samll crystallization rate.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: June 20, 2006
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Tsuyoshi Ikeda, Takeshi Hirokane, Shojiro Kuwahara
  • Patent number: 7048978
    Abstract: To provide a polyester resin particularly useful in application to optical films, etc. A polyester resin which is an alicyclic polyester comprising dicarboxylic acid units and diol units, characterized by the following (1) to (4): (1) the dicarboxylic acid units are composed mainly of 1,4-cyclohexanedicarboxylic acid units, (2) the diol units are composed mainly of 1,4-cyclohexanedimethanol units, (3) the ratio of alkyl ester terminals to all terminals of the polyester is at most 5 mol %, and (4) the light transmittance of a molded plate of the resin having a thickness of 2 mm is at least 87%.
    Type: Grant
    Filed: April 27, 2005
    Date of Patent: May 23, 2006
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Tomohiko Tanaka, Atsushi Kasai
  • Patent number: 7026027
    Abstract: Disclosed are amorphous copolyesters having an inherent viscosity (IV) of at least about 0.5 dL/g measured at a temperature of 25° C. at 0.5 g/dL concentration in a solvent mixture of symmetric tetrachloroethane and phenol having a weight ratio of symmetric tetrachloroethane to phenol of 2:3 comprising (1) a diacid component comprising about 90 to 100 mole percent terephthalic acid residues and 0 to about 10 mole percent isophthalic acid residues; and (2) a diol component comprising about 10 to 70 mole percent 1,4-cyclohexanedimethanol residues and about 90 to 30 mole percent neopentyl glycol residues; wherein the amorphous copolyesters comprises 100 mole percent diacid component and 100 mole percent diol component. The amorphous copolyesters are useful in the manufacture or fabrication of medical devices which have improved resistance to degradation upon exposure to lipids, as a profile produced by profile extrusion and as an injection molded article.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: April 11, 2006
    Assignee: Eastman Chemical Company
    Inventors: Sam Richard Turner, Jonathan Terrill Milburn, Robert William Seymour, Kab Sik Seo
  • Patent number: 7022806
    Abstract: Macrocyclic oligoesters and compositions comprising macrocyclic oligoesters are prepared from intermediate molecular weight polyesters. In one embodiment, a diol is contacted with a dicarboxylic acid or a dicarboxylate in the presence of a catalyst to produce a composition comprising a hydroxyalkyl-terminated polyester oligomer. The hydroxyalkyl-terminated polyester oligomer is heated to produce a composition comprising an intermediate molecular weight polyester which preferably has a molecular weight between about 20,000 Daltons and about 70,000 Daltons. The intermediate molecular weight polyester is heated and a solvent is added prior to or during the heating process to produce a composition comprising a macrocyclic oligoester. An optional step is to separate the macrocyclic oligoester from the composition comprising the macrocyclic oligoester.
    Type: Grant
    Filed: November 29, 2004
    Date of Patent: April 4, 2006
    Assignee: Cyclics Corporation
    Inventor: Gary R. Faler
  • Patent number: 7011930
    Abstract: Temperature sensitive, water soluble polymers are disclosed, together with a method for control the LCST of the polymer. The polymers include hydrophillic components and hydrophobic components joined by linking groups such as ester or amide groups wherein the hydrophilic components includes m ethylene oxide groups, the hydrophobic components consist of aliphatic groups such as n ethylenes and/or n cycloaliphatic groups, and where 1?m?30 and 1?n?30. Substrates bearing the grafted temperature responsive polymers also are disclosed. Microfluidic devices which include the temperature responsive polymers also are disclosed.
    Type: Grant
    Filed: March 14, 2003
    Date of Patent: March 14, 2006
    Assignee: The Penn State Research Foundation
    Inventors: Evangelos Manias, Mindaugas Rackaitis, Kenneth E. Strawhecker
  • Patent number: 7005002
    Abstract: Branched, amorphous, polyester-based macropolyols having a narrow molecular weight distribution and a process for making the macropolyol.
    Type: Grant
    Filed: May 5, 2004
    Date of Patent: February 28, 2006
    Assignee: Degussa AG
    Inventors: Patrick Glöckner, Giselher Franzmann, Martin Schmitthenner
  • Patent number: 7001651
    Abstract: Disclosed is a heat-shrinkable polyester film having a specific composition. A heat shrinkage factor of a 10 cm square sample of the film in a maximal shrinkage direction of the film is not less than 20% under the condition that the sample is immersed in hot water of 85° C. for 10 seconds, and then in water of 25° C. for 10 seconds. The number of test pieces of the film having a rupture ratio of not more than 5% is not more than 10% to the total number of the test pieces under the condition that a tensile test of drawing the film in a direction orthogonal to the maximal shrinkage direction of the film is conducted with a distance between corresponding chucks of 100 mm, each test piece having 15 mm in width, a temperature of 23° C., and a drawing rate of 200 mm/min.
    Type: Grant
    Filed: July 9, 2002
    Date of Patent: February 21, 2006
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Satoshi Hayakawa, Norimi Tabota, Yoshinori Takegawa, Katsuya Ito, Shigeru Komeda, Katsuhiko Nose
  • Patent number: 6974660
    Abstract: Temperature sensitive, water soluble polymers are disclosed, together with a method for control the LCST of the polymer. The polymers include hydrophillic components and hydrophobic components joined by linking groups such as ester or amide groups wherein the hydrophilic components includes m ethylene oxide groups, the hydrophobic components consist of aliphatic groups such as n ethylenes and/or n cycloaliphatic groups, and where 1?m?30 and 1?n?30. Substrates bearing the grafted temperature responsive polymers also are disclosed. Microfluidic devices which include the temperature responsive polymers also are disclosed.
    Type: Grant
    Filed: May 14, 2004
    Date of Patent: December 13, 2005
    Assignee: Penn State Research Foundation
    Inventors: Evangelos Manias, Mindaugas Rackaitis, Kenneth E Strawhecker
  • Patent number: 6974631
    Abstract: The present invention provides a high reflectivity lighting fixture, comprising a coated reflector and a light source. The reflector is coated with a composition that includes a cycloaliphatic group containing polyester resin and a pigment. The present invention also provides coating compositions that may be used on other articles where high reflectivity is desired.
    Type: Grant
    Filed: March 3, 2003
    Date of Patent: December 13, 2005
    Assignee: Valspar Sourcing, Inc.
    Inventors: Gregory Bryant Hayes, Thomas John Melnyk
  • Patent number: 6946188
    Abstract: A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
    Type: Grant
    Filed: October 1, 2003
    Date of Patent: September 20, 2005
    Assignee: 3M Innovative Properties Company
    Inventors: Timothy J. Hebrink, William W. Merrill, Carl A. Stover
  • Patent number: 6939616
    Abstract: A film roll of a heat-shrinkable polyester film characterized in that the heat-shrinkable polyester film meets the following requirements (1) and (2). (1) When samples are cut off therefrom at an almost equal interval along the longitudinal direction, and immersed in hot water at 85° C. for 10 seconds, subsequently in water at 25° C. and withdrawn, heat-shrinkage percentages in the maximum shrinkage direction of all the samples are 20% or more. (2) When raw polymers used for production of the film above comprises of a major constitutional unit and one or more sub constitutional units different therefrom; and the content of the primary sub constitutional unit is determined, the content of the primary sub constitutional unit in each sample is more than 7 mole % in 100% of all constitutional units, and when an average of the contents of the primary sub constitutional unit is calculated, the contents thereof of all the samples fall within a range of ±2 mole % relative to the average.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: September 6, 2005
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Satoshi Hayakawa, Norimi Tabota, Yoshinori Takegawa, Katsuya Ito, Shigeru Komeda, Katsuhiko Nose
  • Patent number: 6927275
    Abstract: The process of the present invention for producing a polyester resin comprising a dicarboxylic acid constitutional unit and a diol constitutional unit having a cyclic acetal skeleton comprises a step (1) of subjecting a diol (A) having a cyclic acetal skeleton and an ester (D) to transesterification reaction and a step (2) of mainly converting the resultant oligomer into a high polymer. The step (1) simultaneously satisfies the requirements (i) to (iv) as described in the specification. In the process of the present invention, the polyester resins having excellent moldability and mechanical properties are stably produced by a transesterification method which is less detrimental to environments.
    Type: Grant
    Filed: September 11, 2003
    Date of Patent: August 9, 2005
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Takeshi Hirokane, Tsuyoshi Ikeda, Shojiro Kuwahara, Takamasa Kawashima, Tomohito Oyama
  • Patent number: 6924349
    Abstract: Disclosed is a copolyester resin composed mainly of terephthalic acid, ethyleneglycol, 1,4-cyclohexanedimethanol, polyethyleneglycol bisphenol-A and a multifunctional monomer. According to the current invention, the multifunctional monomer and polyethyleneglycol bisphenol-A are additionally copolymerized along with 1,4-cyclohexanedimethanol, whereby the resultant copolyester resin can have low haze and high melt viscosity and melt strength, with superior moldability due to low melt pressure. In addition, extrusion blow molded articles and profile extruded articles, such as bottles and tubes, are provided by use of the copolyester resin having superior properties.
    Type: Grant
    Filed: June 17, 2004
    Date of Patent: August 2, 2005
    Assignee: SK Chemicals Co., Ltd.
    Inventors: Myoung-Ryoul Lee, Jae-Young Jeon, Sung-Ho Park, Jong-Ryang Kim
  • Patent number: 6914120
    Abstract: This invention relates to a process for producing a polyester comprising the steps of: (g) obtaining an aqueous homogenous solution of isosorbide; (h) feeding the aqueous homogenous solution of step (a) into a reactor; (i) feeding one or more glycols and one or more dicarboxylic acids either into the aqueous solution of step (a) or into the reactor of step (b) either prior to, during and/or subsequent to step (b); (j) esterifying the reactor contents at sufficient temperatures and pressures, and optionally in the presence of suitable catalysts, to effect esterification; (k) forming a prepolymer; and (l) polycondensing the prepolymer at sufficient temperatures and pressures in the presence of a suitable catalyst to effect polycondensation to form a polyester.
    Type: Grant
    Filed: November 13, 2002
    Date of Patent: July 5, 2005
    Assignee: Eastman Chemical Company
    Inventors: Ted Calvin Germroth, Sam Richard Turner, Lanny Calvin Treece
  • Patent number: 6914101
    Abstract: The present invention relates to a polyester block copolymer composition which is obtained by reacting 0.5 to 5.0 parts by weight of an epoxy compound (C) having two or more functionalities with 100 parts by weight of a polyester block copolymer (P) having an acid value of 0 to 5 mgKOH/g obtained by reacting a crystalline aromatic polyester (A) having a hydroxyl group at a molecular terminal with a lactone (B) and optionally with a polyfunctional compound (D) having three or more groups selected among carboxyl, hydroxyl, and/or ester groups thereof. The composition has such excellent moldability that it is applicable to molding techniques including blow molding without arousing any trouble. It is satisfactory in heat resistance, water resistance, impact resistance, or flame retardancy, and has rubber-like elasticity.
    Type: Grant
    Filed: April 1, 2002
    Date of Patent: July 5, 2005
    Assignee: Daicel Chemical Industries, Ltd.
    Inventor: Masanori Sakane
  • Patent number: 6905765
    Abstract: A polyether ester comprises poly(trimethylene-ethylene ether) ester soft segment and alkylene ester hard segment. Preferably, the polyether ester is a thermoplastic elastomer in which the hard segment comprises C2 to C12 alkylene ester. The composition is prepared by providing and reacting: (a) poly(trimethylene-ethylene ether) glycol (b) at least one polyester. Fiber made from this composition is particularly useful in making films, membranes and fabrics.
    Type: Grant
    Filed: July 17, 2003
    Date of Patent: June 14, 2005
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Hari Babu Sunkara