Aryl-containing Carboxylic Acid Or Derivative Of An Aryl-containing Dicarboxylic Acid Patents (Class 528/308)
  • Patent number: 7253249
    Abstract: A resin composition is prepared by reacting components comprising dibasic acid, diamine, polyol and monoalcohol, wherein (a) at least 50 equivalent percent of the dibasic acid comprises polymerized fatty acid; (b) at least 50 equivalent percent of the diamine comprises ethylene diamine; (c) 10-60 equivalent percent of the total of the hydroxyl and amine equivalents provided by diamine, polyol and monoalcohol are provided by monoalcohol; and (d) no more than 50 equivalent percent of the total of the hydroxyl and amine equivalents provided by diamine, polyol and monoalcohol are provided by polyol. This resin composition may be formulated into, for example, personal care products, fragrance releasing products and candles.
    Type: Grant
    Filed: December 6, 2004
    Date of Patent: August 7, 2007
    Assignee: Arizona Chemical Company
    Inventor: Mark S. Pavlin
  • Patent number: 7250486
    Abstract: The present invention is a process and apparatus for conserving loss of heat while forming and crystallizing polymer particles in a liquid. The cooling liquid quenches the polymer during particle molding to facilitate shaping. The cooling liquid cools the polymer particles not below a temperature that allows adequate crystallization to occur. Cooling liquid is quickly switched with a warming liquid, so the temperature of the polymer is in the crystallization range and the heat of crystallization self-heats the polymer to a higher temperature.
    Type: Grant
    Filed: December 15, 2004
    Date of Patent: July 31, 2007
    Assignee: UOP LLC
    Inventor: James F. McGehee
  • Patent number: 7250485
    Abstract: A toner resin composition comprising a linear polyester resin (A) containing a C3 to C10 aliphatic diol component and a linear polyester resin (B) containing a C3 to C10 aliphatic diol component which differs from the linear polyester resin (A), or further comprising a vinyl-based resin (C), and a toner containing the toner resin composition as a binding resin. A toner excellent in low temperature fixability, offset resistance, gloss, etc. and excellent in range of fixing temperature can be obtained.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: July 31, 2007
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Hirokazu Ito, Masaru Sugiura, Yoko Tamura, Akifumi Kondou, Shinya Yamato
  • Patent number: 7250484
    Abstract: A method for enhancing solid state polymerization of polyethylene terephthalate is disclosed in which at least one monomeric unit of diacid and/or dimethyl ester comprising at least one pendant chemical side group is copolymerized with a diol and a diacid or a dimethyl ester. The at least one pendant chemical side group may include groups chosen from tertiary butyl, hexyl, pentyl, butyl, propyl, ethyl, methyl, nitrosyl (NO2) and sulfonyl (SO2) groups.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: July 31, 2007
    Assignee: Invista North America S.AR.L.
    Inventors: Michael William Gardner, Jill Barbara Cunningham, Derek J. Winter, Stephen D. Jenkins
  • Patent number: 7244506
    Abstract: A high reflectivity coated substrate and coating composition employing a binder containing a polyester resin that includes a cycloaliphatic group and has a number average molecular weight from about 1,000 to 40,000. The binder contains less than 40 weight percent aromatic group containing compound and the weight ratio of pigment to binder is greater than 0.9:1. When the binder is blended with rutile TiO2 at a solids loading of 50 weight percent and coated to a dried film thickness of 0.00254 cm, the coating exhibits a Y-value of at least 85.5.
    Type: Grant
    Filed: August 25, 2005
    Date of Patent: July 17, 2007
    Assignee: Valspar Sourcing, Inc.
    Inventors: Gregory Bryant Hayes, Thomas John Melnyk
  • Patent number: 7241485
    Abstract: A glass protecting film comprising at least 5 or more layers, of which at least one layer is the layer which comprises polyester having 1,4-cyclohexane dimethanol is one of the components, and a glass protecting comprising a multi-layer structure which comprises at least two kinds of thermoplastic resin, of which the difference of glass transition temperature is 40° C. or less, the face-impact strength is 18 J/mm or more, haze is 3% or less, are films which excel in transparency, tear resistance, and impact resistance, and are suitable for protecting glass and preventing damaged glass fragments.
    Type: Grant
    Filed: October 28, 2002
    Date of Patent: July 10, 2007
    Assignee: Toray Industries, Inc.
    Inventors: Syunichi Osada, Shigetoshi Maekawa, Kazumori Sonoda
  • Patent number: 7241855
    Abstract: A method is described for the manufacture of polyesters of aromatic dicarboxylic acids with aliphatic and/or cycloaliphatic dials, in which an aromatic dicarboxylic acid in the presence of a monocarboxylic acid or a mixture of a monocarboxylic acid present in a saturated solution with water or another suitable solvent is converted with an aliphatic or cycloaliphatic dial to a dicarboxylic acid alkanediolestercarboxylate and/or its oligomers, which are polycondensed in further process steps to the polyester.
    Type: Grant
    Filed: September 27, 2005
    Date of Patent: July 10, 2007
    Assignee: Zimmer Aktiengesellschaft
    Inventors: Stefan Deiss, Michael Reisen, Karl-Heinz Heldmann, Eckhard Seidel
  • Patent number: 7238411
    Abstract: The present invention is a multilayer polyester film comprising a layer A and a layer B which are laminated alternately, the layer A constituting the outermost layer on both sides of the film, wherein (1) the layer A comprises a polyester A, and the layer B comprises a polyester B, (2) the melting point of the polyester A is higher than the melting point of the polyester B by at least 15° C., (3) the layer A is a layer having an oriented structure, and the layer B is a layer having a substantially unoriented structure, (4) the ratio (a/b) of the total thickness (a) of the layer A to the total thickness (b) of the layer B is 0.01 to 3, and (5) the in-plane tensile strength of the multilayer polyester film is 50 MPa or lower at a maximum, and the difference between its maximum value and minimum value is 20 MPa or smaller; and a method for producing the multilayer polyester film.
    Type: Grant
    Filed: February 10, 2003
    Date of Patent: July 3, 2007
    Assignee: Teijin Limited
    Inventors: Tetsuo Yoshida, Tetsuo Ichihashi
  • Patent number: 7238831
    Abstract: Novel platform mesogens, intermediates, and polymerizable mesogens made therefrom.
    Type: Grant
    Filed: January 23, 2002
    Date of Patent: July 3, 2007
    Assignee: Southwest Research Institute
    Inventors: Stephen T. Wellinghoff, Douglas P. Hanson
  • Patent number: 7238417
    Abstract: The invention relates to a polyester film with a thickness of from about 4 to about 23 ?m, which comprises, alongside polyethylene terephthalate as main constituent, from about 2 to about 20% by weight of polyethylene naphthalate (based on the weight of the film), and has fewer than 30 pinholes per 100 m2. The invention further relates to a process for producing these films, and to the use of the films in packaging composites.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: July 3, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Holger Kliesch, Ursula Murschall, Thorsten Kiehne, Gottfried Hilkert, Bart Janssens
  • Patent number: 7238770
    Abstract: The present invention relates to methods of making imide-modified polyester imide resins. The present invention further relates to forming these imide-modified polyester imide resins into articles, such as preforms, bottles, containers, sheets, films, fibers, and injection molded parts.
    Type: Grant
    Filed: January 28, 2005
    Date of Patent: July 3, 2007
    Assignee: Wellman, Inc.
    Inventors: Walter L. Edwards, Marion L. Andrews
  • Patent number: 7235623
    Abstract: Polyester compositions that provide a higher throughput in calendering processes may be prepared from a polyester having crystallization half time of at least 5 minutes, an inherent viscosity of about 0.55 to about 0.75 dL/g, a branching monomer, and a release additive. The polyester compositions show a combination of excellent melt strength with good shear response that permits higher calendering line speeds before melt fracture occurs. Also disclosed are processes for film or sheet by calendering the above compositions and the film or sheet produced therefrom. The polyester compositions, film, or sheet also may include plasticizers and/or flame retardants to increase their flexibility and enable their use in commercial applications requiring flame resistance. The film and sheet have excellent appearance and can be used in a wide range of decorative and packaging applications.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: June 26, 2007
    Assignee: Eastman Chemical Company
    Inventors: Marc Alan Strand, Rodney Layne Piner, Eric Jon Moskala
  • Patent number: 7229696
    Abstract: The invention relates to an at least two-layer polyester film with a total thickness of from about 5 to about 200 ?m which comprises polyethylene terephthalate and from about 2 to about 20% by weight—based on the weight of the entire film—of polyethylene naphthalate, and also at least one functional outer layer.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: June 12, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Holger Kliesch, Ursula Murschall, Franz Hora, Guenther Crass, Herbert Peiffer, Bodo Kuhmann
  • Patent number: 7226986
    Abstract: The present invention relates to a process by which a carboxylic acid/diol mixture is obtained from a carboxylic acid/solvent slurry without isolation of a substantially dry carboxylic acid solid. More specifically, the present invention relates to a process by which a terephthalic acid/ethylene glycol mixture is obtained from a terephthalic acid/solvent slurry without isolation of a substantially dry terephthalic acid solid.
    Type: Grant
    Filed: March 10, 2005
    Date of Patent: June 5, 2007
    Assignee: Eastman Chemical Company
    Inventors: Robert Lin, Timothy Alan Upshaw, Duane Alan Hall, Kenny Randolph Parker
  • Patent number: 7226664
    Abstract: The present invention is to provide a laminated polyester film with excellent adhesive properties for use in a laminating material, and the laminated polyester film is a film in which a resin layer including a polyester resin and a oxazoline-based cross-linking agent is laminated on at least one side surface of polyester film, diethylene glycol accounts for 40 mole % or more of all diol components constituting the polyester resin and the mass ratio of the polyester resin to the oxazoline-based cross-linking agent resin layer is within a range of 20/80 to 80/20. Furthermore, the present invention is to provide a flame-retardant polyester film in which a polyimide-including layer is laminated on both sides of the laminated polyester film and also a copper-clad laminated plate in which the flame-retardant polyester film is used, and also a circuit substrate in which the copper-clad laminated plate is used.
    Type: Grant
    Filed: May 24, 2006
    Date of Patent: June 5, 2007
    Assignee: Toray Industries, Inc.
    Inventors: Shotaro Tanaka, Junpei Ohashi, Yasushi Takada
  • Patent number: 7223459
    Abstract: This invention relates to a coextruded, transparent, biaxially oriented polyester film comprising a base layer (B) and a heatsealable top layer (A) which is peelable from at least CPET, the heatsealable and peelable top layer (A) consisting of a) 80–98 % by weight of polyester and b) 2–10 % by weight of inorganic and/or organic particles having an average diameter d50 of from 2.5 to 12.0 ?m (based on the mass of the top layer (A)), wherein c) the polyester is composed of 12–89 mol % of units derived from at least one aromatic dicarboxylic acid and 11–88 mol % of units derived from at least one aliphatic dicarboxylic acid, the sum of the dicarboxylic acid-derived molar percentages being 100, d) the ratio of particle diameter d50 and layer thickness dA of the top layer (A) being greater than/equal to 1.0 and e) the layer thickness of the top layer (A) dA being from 2.3 to 10.0 ?m. The invention further relates to a process for producing the film and to its use.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: May 29, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Bart Janssens, Gottfried Hilkert, Matthias Konrad
  • Patent number: 7217782
    Abstract: Energy savings are realized during the commercial production of polyethylene terephthalate by partially cooling polyethylene terephthalate pellets exiting a solid stating reactor by contact with water, and using the residual heat stored in the pellets to vaporize associated water to form dry pellets.
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: May 15, 2007
    Assignee: Eastman Chemical Company
    Inventors: Richard Gill Bonner, A Bob Debenport
  • Patent number: 7214761
    Abstract: A resin composition comprising an inorganic material with a thermal conductivity of 10 W/mK or higher at a temperature of 20° C. and an aromatic polyester is provided. The aromatic polyester may have structural units derived from (I) 2-hydroxy-6-naphthoic acid, (II) a compound selected from hydroquinone, 4,4?-dihydroxybiphenyl and 2,6-dihydroxynaphthalene, (III) naphthalenedicarboxylic acid and (IV) a compound selected from terephthalic acid, isophthalic acid and phthalic acid.
    Type: Grant
    Filed: May 10, 2005
    Date of Patent: May 8, 2007
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoshi Okamoto, Tomoya Hosoda
  • Patent number: 7214432
    Abstract: A coating composition comprising components A, B and optionally C, wherein component A comprises at least one hydroxy-terminated polyarylate. Component B is an organic species which can react with the hydroxy terminal groups of component A, and component C is a catalyst or mixture of catalysts. The hydroxy-terminated polyarylates are prepared by a solution polymerization method.
    Type: Grant
    Filed: September 30, 2003
    Date of Patent: May 8, 2007
    Assignee: General Electric Company
    Inventors: Glen David Merfeld, Rainer Koeniger, Ali Ersin Acar, Paul Dean Sybert, Zhaohui Su
  • Patent number: 7214415
    Abstract: Monolayer packages comprised of an oxygen scavenging composition suitable for direct contact with package contents and recycle with other polyester bottles are disclosed. The oxygen scavenging composition is comprised of a modified copolymer which is comprised of predominantly polyester segments and an oxygen scavenging amount of oxygen scavenging segments. The polyester segments comprise segments derived from typical bottling and packaging polyesters such as PET and PEN. Use of these oxygen scavenging copolymers in bottles provides a clear and rigid monolayer bottle similar in appearance to unmodified polyester bottles. In a series of preferred embodiments, bottles fabricated with the oxygen scavenging copolymers of this invention are over 99 wt % PET and contain less than 50 ppb of extractable components.
    Type: Grant
    Filed: February 8, 2005
    Date of Patent: May 8, 2007
    Assignee: BP Corporation North America Inc.
    Inventors: James M. Tibbitt, Paul J. Cahill, George E. Rotter, David P. Sinclair, Gary T. Brooks, Raymond T. Behrends
  • Patent number: 7211633
    Abstract: The invention is directed to polyester processes that utilizes a pipe reactor in the esterification, polycondensation, or both esterification and polycondensation processes. Pipe reactor processes of the present invention have a multitude of advantages over prior art processes including improved heat transfer, volume control, agitation and disengagement functions.
    Type: Grant
    Filed: April 7, 2004
    Date of Patent: May 1, 2007
    Assignee: Eastman Chemical Company
    Inventor: Bruce Roger DeBruin
  • Patent number: 7211306
    Abstract: Coextruded, biaxially oriented polyester films which have a base layer (B) and have a heatsealable outer layer (A) that can be peeled from APET/CPET and from CPET, where the outer layer (A) includes a) from 80 to 98% by weight of polyester and b) from 2 to 10% by weight of inorganic and/or organic particles with a median diameter d50 of from 3 to 12 ?m, and where c) the polyester is composed of from 12 to 89 mol % of units derived from at least one aromatic dicarboxylic acid and of from 11 to 88 mol % of units derived from at least one aliphatic dicarboxylic acid, and d) the ratio calculated from the particle size d50 of the particles and the layer thickness dA of the outer layer (A) is greater than or equal to 1.5, and the shrinkage of the films, at least in one direction, is more than 5%. The films of the invention are especially suitable, owing to their property of self-venting, as a lid film for APET/CPET or CPET trays.
    Type: Grant
    Filed: November 9, 2004
    Date of Patent: May 1, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Bart Janssens, Gottfried Hilkert, Matthias Konrad
  • Patent number: 7211634
    Abstract: Disclosed is a process for the preparation of high molecular weight polyesters by reacting one or more dicarboxylic acids directly with 1,4-cyclohexanedimethanol and, optionally, one or more diols. The process uses an overall diol to dicarboxylic acid molar ratio of about 0.97 to about 1.2 and an incremental addition of either the diacid or diol components. The process provides a shorter total reaction time and, thus, lessens the thermal degradation of polyester which may result in high color and reduced molecular weight.
    Type: Grant
    Filed: April 28, 2006
    Date of Patent: May 1, 2007
    Assignee: Eastman Chemical Company
    Inventors: Daniel Lee Martin, Joseph Franklin Knight, Benjamin Fredrick Barton, Damon Bryan Shackelford
  • Patent number: 7205379
    Abstract: The present invention discloses a process for the preparation of a stabilized polyester that is low in the generation of aldehydes which comprises reacting one or more diacids with one or more diols in an esterification process, and/or one or more diesters with one or more diols in a transesterification process in the presence of an effective amount of a stabilizer selected from the group consisting of (a) a polyhydric alcohol which is for example poly(ethylene-co-vinyl alcohol), poly(styrene-co-allyl alcohol), maltitol, isomalt, sorbitol, xylitol, sucrose, mucic acid dibutylester, mucic acid di(phenyl-1-ethyl)ester, pentaerythritol or dipentaerythritol; (b) a compound of the formula II, which is for example di-iso-octyl-phosphinic acid; (c) a sterically hindered amine which is for example Tinuvin 123 or Tinuvin 622; (d) a polyacrylamide or a cationic acrylamide copolymer; or (e) a hydroxyamine and/or a nitrone.
    Type: Grant
    Filed: March 19, 2002
    Date of Patent: April 17, 2007
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Dirk Simon, Dari Lazzari, Stephen Mark Andrews, Heinz Herbst
  • Patent number: 7205040
    Abstract: Coextruded, biaxially oriented polyester films which have a base layer (B) and have a heatsealable outer layer (A) that can be peeled from APET/CPET and from CPET, where the outer layer (A) comprises from 80 to 99% by weight of polyester and from 1 to 10% by weight of inorganic and/or organic particles with a median diameter d50 of from 2.5 to 12 ?m, and where the polyester is composed of from 12 to 89 mol % of units derived from at least one aromatic dicarboxylic acid and of from 11 to 88 mol % of units derived from at least one aliphatic dicarboxylic acid, and the ratio calculated from the particle size d50 of the particles and the layer thickness dA of the outer layer (A) is ?1, and the base layer (B) comprises poly(-xyleneadipamide). The films of the invention are suitable, owing to their increased oxygen barrier, as a packaging material for foods and other consumable goods or as a lid film for APET/CPET or CPET trays.
    Type: Grant
    Filed: November 9, 2004
    Date of Patent: April 17, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Bart Janssens, Gottfried Hilkert, Matthias Konrad
  • Patent number: 7198857
    Abstract: A polyester film for forming which is excellent in formability especially at low temperatures and low pressures and in solvent resistance and heat resistance and is reduced in environmental burden. The polyester film for forming is a biaxially oriented polyester film comprising a copolyester as a component, and is characterize in that (1) the stress at 100% elongation of the film in each of the machine direction and the transverse direction is 10 to 1,000 MPa at 25° C. and is 1 to 100 MPa at 100° C.; (2) the storage viscoelasticity (E?) of the film in each of the machine direction and the transverse direction is 10 to 1,000 MPa at 100° C. and is 5 to 40 MPa at 180° C.; and (3) the degree of heat distortion (initial load, 49 mN) of the film in the machine direction is ?3% to +3% at 175° C.
    Type: Grant
    Filed: August 30, 2004
    Date of Patent: April 3, 2007
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Katsufumi Kumano, Shinya Higashiura, Katsuya Ito, Masatoshi Tanabe, Shinji Fujita, Yasushi Sasaki
  • Patent number: 7196158
    Abstract: A knitted/woven fabric of polyester fibers is produced from a polyester polymer obtained by condensation-polymerizing an aromatic dicarboxylate in the presence of a catalyst which comprises a mixture of a titanium compound ingredient (A) comprising a titanium alkoxide and at least one product of the reaction of the titanium alkoxide with a specific carboxylic acid or anhydride thereof and a specific phosphorus compound ingredient (B) and/or comprises a product of the reaction of a titanium compound ingredient (C) with a specific phosphorus compound ingredient (D). The knitted/woven fabric obtained has a satisfactory color tone (low value of b*) and is excellent in suitability for knitting/weaving and dyeability.
    Type: Grant
    Filed: December 24, 2003
    Date of Patent: March 27, 2007
    Assignee: Teijin Fibers Limited
    Inventors: Tsuyoshi Soeda, Shuji Minato, Norimitsu Kamiyama
  • Patent number: 7196159
    Abstract: A process for the production of polytrimethylene terephthalate (PTT), wherein the process comprises: (i) one or more esterification steps, wherein terephthalic acid (TPA) or an alkyl diester of terephthalic acid is reacted with 1,3-propanediol (PDO); and (ii) one or more subsequent polycondensation steps, wherein the process further comprises the addition of a protic acid, other than terephthalic or isophthalic acid, before and/or during the one or more esterification steps, wherein the protic acid has a dissociation constant of at most 4 (pKa measured in water at 25° C.), and wherein the total amount of protic acid added before and/or during the one or more esterification steps is in the range of from 0.001 to 10 millimole of acid per kilogram of polytrimethylene terephthalate produced.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: March 27, 2007
    Assignee: Shell Oil Company
    Inventors: Donald Ross Kelsey, Cecilia Zuqi Tse, Emery Don Johnson
  • Patent number: 7193109
    Abstract: The present invention relates to a process by which a carboxylic acid/diol mixture is obtained from a carboxylic acid/solvent slurry without isolation of a substantially dry carboxylic acid solid. More specifically, the present invention relates to a process by which a terephthalic acid/ethylene glycol mixture is obtained from a terephthalic acid/solvent slurry without isolation of a substantially dry terephthalic acid solid.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: March 20, 2007
    Assignee: Eastman Chemical Company
    Inventors: Robert Lin, Timothy Alan Upshaw, Duane Alan Hall, Kenny Randolph Parker
  • Patent number: 7193029
    Abstract: The present invention provides certain sulfonated copolyetherester compositions containing hydroxyalkanoic acids and processes for producing such sulfonated aromatic copolyetheresters. The invention further provides shaped articles, preferably in the shape of films, coatings and laminates, having improved thermal properties, wherein the shaped articles are produced from the certain sulfonated copolyetherester compositions. Some of these materials are also biocompostable. The sulfonated copolyetheresters are produced from a mixture of an aromatic dicarboxylic acid component, hydroxyalkanoic acid component, a sulfonate component, a poly(alkylene ether) glycol component, a glycol component, an optional other glycol component, an optional branching agent, and an optional color reducing agent.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: March 20, 2007
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Richard Allen Hayes
  • Patent number: 7193020
    Abstract: A film comprising a resin alloy of a liquid-crystalline polyester, a polyimide and an optional inorganic filler is provided. The film is excellent in heat resistance and dimensional stability.
    Type: Grant
    Filed: May 26, 2005
    Date of Patent: March 20, 2007
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Toyonari Ito, Satoshi Okamoto
  • Patent number: 7189451
    Abstract: Multilayer, biaxially oriented polyester films which include as a constituent of the base layer B, a crystallizable polyester with increased diethylehe glycol content and/or increased polyethylene glycol content, and/or increased isophthalic acid content, preferably polyethylene terephthalate. The outer layers of the inventive films advantageously include at least one IR-reflective pigment and one UV stabilizer. The inventive films advantageously feature adjustable mattness, diffuse scattering power for visible light, high light transmittance, IR reflectance, and good thermoformability, and are suitable for thermally protective coatings or thermally protective packaging.
    Type: Grant
    Filed: July 1, 2005
    Date of Patent: March 13, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Thorsten Kiehne, Ursula Murschall, Holger Kliesch
  • Patent number: 7189452
    Abstract: Biaxially oriented polyester films formed from a crystallizable polyester having increased diethylene glycol content and/or increased polyethylene glycol content, and/or increased isophthalic acid content, preferably polyethylene terephthalate. The films of the invention further include at least one IR-reflective pigment and one UV stabilizer. The inventive films feature adjustable mattness, diffuse scattering power for visible light, high light transmittance and IR reflectance and good thermoformability, and are suitable for thermally protective coatings or thermally protective packaging.
    Type: Grant
    Filed: July 1, 2005
    Date of Patent: March 13, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Thorsten Kiehne, Ursula Murschall, Holger Kliesch
  • Patent number: 7189797
    Abstract: A poly(ethylene aromatic dicarboxylate ester) resin usable for the production of fibers, films and bottle-formed articles, is produced by polycondensing a diester of an aromatic dicarboxylic acid with ethylene glycol by using a catalyst including a non-reacted mixture or reaction product of a titanium compound component including at least one member selected from titanium alkoxides and reaction products of the titanium alkoxides with aromatic polyvalent carboxylic acids or anhydrides thereof, with a specific phosphorus compound, in which catalyst the contents of titanium and phosphorus elements are controlled.
    Type: Grant
    Filed: September 18, 2002
    Date of Patent: March 13, 2007
    Assignee: Teijin Limited
    Inventors: Nobuo Minobe, Ryoji Tsukamoto, Tomoyoshi Yamamoto, Tomoyuki Kishino, Kenichi Ishihara
  • Patent number: 7186452
    Abstract: This invention relates to a coextruded, transparent, biaxially oriented polyester film comprising a base layer (B) and a heatsealable top layer (A) which is peelable from at least the APET side of an APET/CPET tray, the heatsealable and peelable top layer (A) consisting of a) 50–95% by weight of polyester and b) 5–40% by weight of a polyester-incompatible polymer (=anti-PET polymer) based on the mass of the top layer (A), wherein c) the polyester is composed of 20–95 mol % of units derived from at least one aromatic dicarboxylic acid and 5–80 mol % of units derived from at least one aliphatic dicarboxylic acid, and d) the layer thickness dA is from 1.3 to 3.0 ?m. The invention further relates to a process for producing the film and to its use.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: March 6, 2007
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Bart Janssens, Bodo Kuhmann, Harald Mueller
  • Patent number: 7183362
    Abstract: In the invention, a polyester resin comprising dicarboxylic acid constitutional units and diol constitutional units wherein 5 to 60 mol % of the diol constitutional units has a cyclic acetal skeleton is produced by a process comprising an oligomerization step and a polymerization step. In the oligomerization step, an ester having a limited acid value is transesterified with a diol having a cyclic acetal skeleton in the presence of a basic compound to obtain an oligomer. The oligomer is then polymerized in the subsequent polymerization step to increase the molecular weight.
    Type: Grant
    Filed: November 29, 2004
    Date of Patent: February 27, 2007
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Takeshi Hirokane, Shojiro Kuwahara, Tsuyoshi Ikeda, Nobuya Saegusa, Tomohito Oyama
  • Patent number: 7179869
    Abstract: In the invention, a polyester resin having dicarboxylic acid constitutional units and diol constitutional units wherein 5 to 60 mol % of the diol constitutional units has a cyclic acetal skeleton is produced by a process including an oligomerization step and a polymerization step. In the oligomerization step, an ester having a limited acid value is transesterified with a diol having a cyclic acetal skeleton in the presence of a titanium compound to obtain an oligomer. The oligomer is then polymerized in the subsequent polymerization step to increase the molecular weight.
    Type: Grant
    Filed: March 11, 2005
    Date of Patent: February 20, 2007
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Takeshi Hirokane, Tomohito Oyama, Shojiro Kuwahara
  • Patent number: 7169860
    Abstract: Biodegradable block copolyesters obtained from crystalline blocks and amorphous blocks, wherein the repeating units of both blocks are of the dicarboxylic acid/diol type. Said copolyesters are characterized by a melting temperature equal to or less than 15% lower than the starting crystalline polymer temperature, and by increased tenacity that makes them particularly useful in the production of different types of objects.
    Type: Grant
    Filed: October 19, 2004
    Date of Patent: January 30, 2007
    Assignee: Novamont S.p.A.
    Inventors: Catia Bastioli, Giandomencio Cella, Tiziana Milizia
  • Patent number: 7166342
    Abstract: A heat-shrinkable resin film which has heat shrinkage in the maximum shrinkage direction of 20% or higher when a 10 cm×10 cm square sample cut out thereof is immersed in hot water at 85° C. for 10 seconds, pulled out, subsequently immersed in water at 25° C. for 10 seconds, and then pulled out, characterized in that a content of nitrogen atoms in a surface of the film is 0.1% to 3.0% and the surface of the film has wet tension of 36 mN/m or higher; and a film roll obtained by winding up the heat-shrinkable resin film characterized in that when the rolled film is sampled at a first sampling part located up to 2 m apart from the end of the rolled film and at other sampling parts located after the first sampling part at intervals of about 100 m and an average content of nitrogen atoms of each sample is calculated, then the content of nitrogen atoms of each sample is within the ±0.8% range based on the above average content of nitrogen atoms.
    Type: Grant
    Filed: December 26, 2002
    Date of Patent: January 23, 2007
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Satoshi Hayakawa, Norimi Tabota, Hiroshi Nagano
  • Patent number: 7157139
    Abstract: A process utilizing PET as a reactive constituent to manufacture other polymers containing the pre-condensed moieties by the rapid transesterification of the condensation polymer with a pre-made modifying polymer containing the desired mix of other monomers. The process involves as a first step the manufacture of a modifying polymer containing the desired mix of acids and alcohols to a specific molecular weight such molecular weight dependent on the desired final level of utilized condensation polymer and the finished molecular weight. The second step of the process involves the rapid buildup of molecular weight and/or polymer uniformity by the rapid transesterification of the condensation polymer with the modifying polymer. The second step can be performed in any suitable vessel including an extrusion line. The process has the advantage of greatly reduced cycle times over other condensation polymer utilization processes such as the recycling of PET into other materials.
    Type: Grant
    Filed: April 19, 2004
    Date of Patent: January 2, 2007
    Inventors: Keith Salsman, Grant Doney
  • Patent number: 7157525
    Abstract: The present invention relates to a thermoplastic elastomer resin which has good melt viscosity, melt tension, and thermal resistance, wherein it is prepared by introducing a chain extender and a stabilizer for hydrolysis to a thermoplastic elastomer resin produced through melt polymerization in the presence of hydroxy carboxylic acid compound and subjecting the mixture to reactive extrusion to increase the molecular weight and crosslinking degree of the elastomer resin. The thermoplastic elastomer resin according to the present invention has good properties for automobile parts, particularly constant velocity joint boots and bellows.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: January 2, 2007
    Assignee: Samyang Corporation
    Inventors: Sung-Hwan Cho, Sun-Woong Kim, Jun-Hee Lee, Oh-Kwun Son, Byung-Ho Lim
  • Patent number: 7153569
    Abstract: Biodegradable aliphatic-aromatic films are disclosed. The films comprise filler particles and a copolyester. The films have high vapor permeability and tensile strength and are suitable for use in absorbent and non-absorbent products.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: December 26, 2006
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ross Thomas Kaufman, Vasily Aramovich Topolkaraev, Gregory James Wideman, Richard Warren Tanzer
  • Patent number: 7153587
    Abstract: The present invention provides a polyester resin which comprises (a-1) 45 to 99% by mole of an oxycarboxylic acid unit having 5 carbon atoms or less, (a-2) 0.5 to 27.5% by mole of an aromatic dicarboxylic acid unit, and (a-3) 0.5 to 27.5% by mole of an aliphatic diol unit having 4 carbon atoms or less, and containing (a-1) to (a-3) in a total amount of 95% by mole or greater, wherein the relationship between the content of the oxycarboxylic acid, expressed as M % by mole, and the density ? (kg/m3) of the polyester resin, satisfies the formula ??1349+M×0.85.
    Type: Grant
    Filed: May 31, 2004
    Date of Patent: December 26, 2006
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Junji Tan, Yasuhiro Mutou, Seiji Ota, Toyoaki Sasaki
  • Patent number: 7150907
    Abstract: A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70–100 mol % of the carboxylate subunits are first carboxylate subunits and 0–30 mo1 % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: December 19, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Timothy J. Hebrink, William W. Merrill, Carl A. Stover
  • Patent number: 7148293
    Abstract: Process for preparing essentially uncrosslinked hyperbranched, water-soluble or water-dispersible polyesters from dicarboxylic acids and polyether polyols having at least 3 OH groups. Water-soluble hyperbranched polyesters which are obtainable by such a process and their use for producing printing inks, adhesives, coatings, paints and varnishes.
    Type: Grant
    Filed: July 24, 2003
    Date of Patent: December 12, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Jean-Francois Stumbe, Bernd Bruchmann, Dietmar Häring
  • Patent number: 7147927
    Abstract: Disclosed are biaxially oriented polyester film produced from a polyester comprising: (1) diacid residues comprising at least 90 mole percent of terephthalic acid residues, naphthalenedicarboylic acid residues or combinations thereof; and (2) diol residues comprising at least 90 mole percent of 1,4-cyclohexanedimethanol residues; wherein the polyester comprises a total of 100 mole percent diacid residues and a total of 100 mole percent diol residues; wherein the polyester film is stretched at a ratio of about 2.5× to 3× in the machine direction (MD) and about 2.5× to 3× in the transverse direction (TD) at stretching temperatures between 90 and 1 10OC, wherein the stretched film is subsequently heat-set at an actual film temperature of from 260° C.
    Type: Grant
    Filed: June 25, 2003
    Date of Patent: December 12, 2006
    Assignee: Eastman Chemical Company
    Inventors: Thomas Joseph Pecorini, Gary Darrel Boone
  • Patent number: 7144615
    Abstract: This invention relates to a coextruded, transparent, biaxially oriented polyester film comprising a base layer (B) and a heatsealable top layer (A) which is peelable with respect to at least CPET. The heatsealable and peelable top layer (A) consists of a) 70–97% by weight of polyester and b) 3–20% by weight of a polyester-incompatible polymer (=anti-PET polymer) based on the mass of the top layer (A), wherein c) the polyester is composed of 20–95 mol % of units derived from at least one aromatic dicarboxylic acid and 5–80 mol % of units derived from at least one aliphatic dicarboxylic acid, the sum of the dicarboxylic acid-derived molar percentages being 100, and d) the layer thickness of the top layer (A) dA is from 1.7 to 6.0 ?m. The invention further relates to a process for producing the film and to its use.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: December 5, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Gottfried Hilkert, Matthias Konrad, Cynthia Bennett, Paul Broemmel
  • Patent number: 7144974
    Abstract: In a polyester production method, a titanium compound having a radical selected from a carbonyl group, a carboxyl group, or an ester group, and a phosphorous compound having a structure illustrated in Formula (I), are added This yields a polyester composition which does not exhibit increased filter pressure when forming, which has excellent filament and film forming properties, and which has a polymer color tone superb to that of conventional products.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: December 5, 2006
    Assignee: Toray Industries, Inc.
    Inventors: Keisuke Honda, Kunihiro Morimoto, Masatoshi Aoyama, Tatsuya Nagano, Minoru Fujimori
  • Patent number: 7144614
    Abstract: This invention provides a novel polymerization catalyst other than antimony compounds, polyester produced by using the same and a process for producing polyester. The polycondensation catalyst of this invention is a polyester polymerization catalyst comprising an aluminum compound and a phosphorus compound having a specific structure. Further, this invention relates to polyester produced by using this polyester polymerization catalyst and a process for producing polyester. Further, this invention relates to fibers, films and hollow molded articles comprising the polyester.
    Type: Grant
    Filed: July 2, 2002
    Date of Patent: December 5, 2006
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Takahiro Nakajima, Ken-ichi Tsukamoto, Shoichi Gyobu, Nobuo Moriyama, Mitsuyoshi Kuwata, Yoshinao Matsui, Seisyu Hayashi, Katsuya Ito, Masaou Matsuda
  • Patent number: 7141293
    Abstract: This invention relates to a coextruded, transparent, biaxially oriented polyester film comprising a base layer (B) and a heatsealable top layer (A) which is peelable from at least APET, the heatsealable and peelable top layer (A) consisting of a) 60–97% by weight of polyester and b) 3–30% by weight of a polyester-incompatible polymer (=anti-PET polymer), based on the mass of the top layer (A), wherein c) the polyester being composed of 25–95 mol % of units which derive from at least one aromatic dicarboxylic acid and 5–75 mol % of units which derive from at least one aliphatic dicarboxylic acid, the sum of the dicarboxylic acid-derived molar percentages being 100, and d) the layer thickness of the top layer (A) dA being from 0.7 to 2.5 ?m.
    Type: Grant
    Filed: September 29, 2004
    Date of Patent: November 28, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Bart Janssens, Gottfried Hilkert, Matthias Konrad