Abstract: Predominately amino terminated phosphonamide oligomers and their use as flame retardant additives in polyamides and copolyamides without detracting from melt processability are described herein. Other important properties such as strength, modulus, dyeing and thermal stability are maintained.

Abstract: A shock absorber is prepared from a material formed from branched molecules comprising associative groups. The branched molecules each contains at least bifunctional fragments and at least trifunctional fragments joined together by ester or thioester bridges alone or in combination with amide or urea bridges.

Abstract: The invention relates to a process for preparing an amine adduct, in which a polyamine component (A), a polyester component (B) and a hydrocarbon component (C) are reacted. The amine adduct is of particularly good suitability as a wetting agent and dispersant, especially for coatings and plastics applications.

Abstract: Hair treatment compositions are disclosed comprising a ?-amino ester compound in a cosmetically acceptable vehicle, such as a spray or cream. In embodiments, the compounds include a polybutadiene moiety. Methods of treating hair with the compositions to impart volume, texture and definition are also disclosed.

Abstract: There is described a process for producing a gel free hyperbranched polyamide polymer P having a polydispersity of at least 1.1 and a weight average molecular weight of at least 300 daltons, having primary amino groups (useful as a crosslinker). The process comprises the step of reacting Reagent A, a compound comprising at least one amino group (—NH2) and one functional group selected from the group consisting of a further amino group (—NH2), thiol (—SH) and a secondary amine radical (—NHR); (where R denotes a hydrocarbo group) (=functional amine) and Reagent B, an alpha-beta unsaturated Michael-reactive ester comprising a plurality of ester groups (=diester); in a molar ratio of amine A to diester B greater than 1 but less than 3 (preferably 2.1 to 2.9); to form the polyamide in a two stage reaction Michael addition and then amidation.

Abstract: A photoalignment material includes a photoalignment polymer having a photosensitive portion represented by the following Chemical Formula 1, R1 represents a cyclic compound, each of R2 and R3 represents a single bond, —(CnH2n)—, —(CxH2x)O(CyH2y)—, or —(CaH2a)O(CbH2b)O(CdH2d)—, “n” represents an integer in the range of 1 to 6, each of “x”, “y”, “a”, “b”, and “d” represents 0 or an integer in the range of 1 to 6, x+y is an integer in the range of 1 to 5, and a+b+d is an integer in the range of 1 to 6. Each hydrogen atom is replaceable with —CH3, —CH2—CH3, —OCH3, —OCH2CH3, —OCH2OCH3, F, or Cl, and each hydrogen atom of —CH3, —CH2—CH3, —OCH3, —OCH2CH3, or —OCH2OCH3 is replaceable with F or Cl.

Abstract: The process for preparing a polyamide based on dicarboxylic acids and diamines has the following stages: 1) providing an aqueous monomer mixture of dicarboxylic acids and diamines, the molar ratio of dicarboxylic acids to diamines being adjusted such that a molar deficiency of dicarboxylic acids or diamines of from 1 to 10 mol % is present at the outlet of stage 3), based on the other component in each case, 2) transferring the aqueous mixture from stage 1) to a continuous evaporator reactor in which diamines and dicarboxylic acids are reacted at a temperature in the range from 100 to 370° C. and a pressure in the range from 1 to 50 bar, 3) transferring the mixture from stage 2) to a separator which is operated at a temperature in the range from 100 to 370° C.

Abstract: A liquid crystal alignment agent is provided that includes a polymer including polyamic acid including a repeating unit represented by the following Chemical Formula 1, polyimide including a repeating unit represented by the following Chemical Formula 2, or a combination thereof. In Chemical Formulae 1 and 2, each X1, X2, Y1 and Y2 is the same as in the detailed description.

Abstract: There is described a process for producing a gel free hyperbranched polyamide polymer having primary amino groups (useful as a crosslinker). The process comprises the step of reacting at least one diamine and at least one unsaturated diester in a molar ratio of diamine to diester greater than 1 but less than 3 (preferably 2.1 to 2.9); to form the polyamide in a two stage reaction Michael addition and then amidation. The diamine in kept in excess with at least 5% of water by total weight of the diamine and diester, a reaction temperature less than the boiling point of the diamine; and is held under reduced pressure (30 mbar to 1 atms). Gelation does not occur even after substantially all ethylenic (—C?C—) double bonds; and >95% ester [—C(O)?O] groups have reacted. This violates the Flory rules which predict a gel would form based on the number of functional groups present and their degree of conversion.

Abstract: A process for recycling a polymer blend necessarily containing PLA, comprising grinding, compacting, dissolving in a solvent of PLA, removing the undissolved contamining polymers, alcoholysis depolymerisation reaction and purification steps.

Abstract: A radiation-curable acrylate-modified aminoamide resin which is the Michael addition product of an aminoamide thermoplastic polymer derived from a polymerised unsaturated fatty acid with a polyol ester having at least three (meth)acrylate ester groups, the aminoamide thermoplastic polymer having an amine number of from 40 to 60 mgKOH/g, the ratio of the initial (meth) acrylate groups of the polyol ester to the initial amino functional groups of the aminoamide polymer being at least 4:1, is liquid at 25° C., and is useful as the resin component of various types of energy-curable coating composition, including inks, varnishes and lacquers, especially lithographic inks.

Abstract: Method for purifying a conventional polymer stream (PE, PP, PET, PVC, etc.) contaminated with not more than 50% PLA, comprising steps for the suspension of the polymer with solubilisation of the PLA fraction and the recovery of the purified polymer after separation.

Abstract: An epoxy resin curing agent which provides good adhesiveness to polyester in addition to excellent performance and high gas-barrier properties of epoxy resins, an epoxy resin composition containing the epoxy resin curing agent, an adhesive for laminating which mainly contains the composition, a laminate film obtained by using the adhesive, a multi-layer packaging material, and a packaging bag. The epoxy resin curing agent is a reaction product of (A) m-xylylenediamine or p-xylylenediamine, (B) a polyfunctional compound having one acyl group, which forms amide linkage by a reaction with polyamine and is capable of forming an oligomer; and (C) an aromatic dicarboxylic acid, an ester thereof, an amide thereof, an acid anhydride thereof, or an acid chloride thereof.

Abstract: It is an object of the present invention to provide a resin composition having improved heat resistance (high crystallinity) and transparency without impairing rigidity intrinsic to a polylactic acid based resin, a molded body formed from the resin composition, and a new polylactic acid based resin used in the resin composition. A polylactic acid based resin (A) according to the present invention is characterized by having a specific structural moiety and a weight average molecular weight (Mw) of 5,000 to 1,000,000. A polylactic acid based resin composition according to the present invention is characterized by containing the above-described polylactic acid based resin (A).

Abstract: The present invention relates to a process for surface treatment of a solid substrate in which photopolymerisation and covalent grafting are performed in situ on said substrate of a biocidal copolymer, wherein steps are taken in which: a) said solid substrate is put in contact with a formulation comprising: 1—at least one monomer comprising a biocidal group, 2—at least one copolymerisable compound with said biocidal monomer comprising a multifunctional monomer or oligomer mono- di- or selected amongst acrylate, epoxide or vinyl ether monomers or oligomers, 3—at least one photoprimer selected amongst radical and/or cationic photoprimers, and 4—at least one grafting agent on said substrate, and b) photocopolymerisation and covalent grafting of the copolymers obtained are carried into effect by subjecting said formulation in contact with said solid substrate to ultraviolet radiation.

Abstract: Poly(?-amino esters) prepared from the conjugate addition of bis(secondary amines) or primary amines to a bis(acrylate ester) are described. Methods of preparing these polymers from commercially available starting materials are also provided. These tertiary amine-containing polymers are preferably biodegradable and biocompatible and may be used in a variety of drug delivery systems. Given the poly(amine) nature of these polymers, they are particularly suited for the delivery of polynucleotides. Nanoparticles containing polymer/polynucleotide complexes have been prepared. The inventive polymers may also be used to encapsulate other agents to be delivered. They are particularly useful in delivering labile agents given their ability to buffer the pH of their surroundings.

Abstract: Provided are low-melt polyimides and poly(amic acids) (PAAs) for use in repair of electrical wire insulation, flat or ribbon wire harnesses, and flat surfaces comprised of high-performance polymers such as inflatables or solar panels applications. Also provided are methods and devices for repair of electrical insulation.

Abstract: A crosslinked aramid polymer comprising a first aramid backbone which is crosslinked through a poly(meth)acrylic acid with a second aramid backbone. The crosslinked aramid polymer is obtained by polymerizing a monomeric aromatic diamine with a monomeric aromatic diacid, or halide or ester thereof in the presence of poly(meth)acrylic acid, followed by a curing step. The crosslinked aramid polymer is crosslinked through its amide bonds and can be made to a fiber, film or fibrid.

Abstract: Polyamides according to formula (I): HO—[OC—(CH2)7—CH?CH—(CH2)7—CONH—(CH2)mNH]nH, where m is an integral number from 4 to 20, and n is an integral number from 30-10,000; formula (II): HO—[OC—(CxH2x-2y)—CONH—(CaH2a-2b)NH]nH where n is an integral number from 30-10,000, a and x each represent a value from 6-32, and b and y each represent a value from 0-12; formula (III): HO—{[OC—(CH2)16—CONH—(CH2)6NH]x—[CO—C6H4—CONH—(CH2)6NH]y}a+b—H, where a+b=n; a, b, n are integral numbers; and n represents a number from 30-10,000; and formula (IV): HO—{[OC—R1—CONH—R3—NH]x—[CO—R2—CONH—R4?—NH]y—[OC—R1—CONH—R4—NH]c—[CO—R2—CONH—R3?—NH]d}—H, where R1 and R3 are aliphatic with 4-22 carbon atoms; R2 and R4 are aromatic with 6-20 carbon atoms; a, b, m, n, and c, d, x, and y are integral numbers, c+d+x+y=a+b=m+n and equals 30 to 10,000 are provided. Methods for making the polyamides are also provided.

Abstract: Biodegradable poly(ester-amides) are synthesized from amino acids, diols and dicarboxylic acids where one or both of the diols and dicarboxylic acids contain unsaturation; e.g., from di-p-nitrophenyl dicarboxylates and p-toluenesulfonic acid salts of bis(alpha-amino acid) disesters of diols where one or both of the dicarboxylate and diol moieties contain unsaturation or from di-p-nitrophenyl dicarboxylates, and p-toluene-sulfonic acid salts of bis(alpha-amino acid) diesters of diols and p-toluenesulfonic acid salt of lysine ester where one or both of the dicarboxylate and diol moieties contain unsaturation. The polymers are useful as biodegradable carriers for drugs of other bioactive agents.

Abstract: It is an object of the present invention to provide a resin composition having improved heat resistance (high crystallinity) and transparency without impairing rigidity intrinsic to a polylactic acid based resin, a molded body formed from the resin composition, and a new polylactic acid based resin used in the resin composition. A polylactic acid based resin (A) according to the present invention is characterized by having a specific structural moiety and a weight average molecular weight (Mw) of 5,000 to 1,000,000. A polylactic acid based resin composition according to the present invention is characterized by containing the above-described polylactic acid based resin (A).

Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises (A) reacting a copolymer of an (i) an unsaturated acidic reagent; and (ii) a mono-olefin, with at least one linking hydrocarbyl di-primary amine, thereby producing a hybrid succinic anhydride copolymer having from about 10% to about 90% unreacted anhydride groups; and subsequently (B) reacting the hybrid succinic anhydride copolymer with a second amine compound, thereby producing the succinimide.

Abstract: A diamine compound is proposed as well as polymers, copolymers, polyamic acids, polyamic acid esters, or polyimides based on such compound. The compound is represented by one of the general formulae (Ia) and (Ib). It could be shown that such structures, in particular for a specific choice of the residue B, provide, if e.g. used as orientation layers, a photostable, vertically aligning material with an improved VHR.

Abstract: The present invention relates to novel imide oligomer compositions, polyimides formed therefrom, and methods for making and using the same. In particular, the invention relates to novel polyimide oligomers comprising 3,3?,4,4?-benzophenone tetracarboxylic dianhydride (BTDA), 2-(3,4-dicarboxy phenyl)-1-phenylacetylene anhydride (PE), and a mixture of 1,3-diaminobenzene and 4,4?-(1,3-phenylenediisopropylidene) bisaniline. The polyimide oligomers demonstrate low melt viscosity (these resins are melt processable) while retaining exceptional thermo-oxidative stability, high glass transition temperature, and good mechanical properties in the cured state.

Abstract: A photoalignment material includes a photoalignment polymer having a photosensitive portion represented by the following Chemical Formula 1, R1 represents a cyclic compound, each of R2 and R3 represents a single bond, —(CnH2n)—, —(CxH2x)O(CyH2y)—, or —(CaH2a)O(CbH2b)O(CdH2d)—, “n” represents an integer in the range of 1 to 6, each of “x”, “y”, “a”, “b”, and “d” represents 0 or an integer in the range of 1 to 6, x+y is an integer in the range of 1 to 5, and a+b+d is an integer in the range of 1 to 6. Each hydrogen atom is replaceable with —CH3, —CH2—CH3, —OCH3, —OCH2CH3, —OCH2OCH3, F, or Cl, and each hydrogen atom of —CH3, —CH2—CH3, —OCH3, —OCH2CH3, or —OCH2OCH3 is replaceable with F or Cl.

Abstract: It is an object of the present invention to provide a water-borne resin composition which can form a film being excellent in flexibility and heat resistance without reducing an insulating property and can be used suitably for a cationic electrocoating composition. A water-borne resin composition, having a hydrolysable functional group and a polymerizable unsaturated carbon bond, wherein a base resin is at least one species selected from the group consisting of a polyamide-imide resin, a polyamide resin and a polyimide resin.

Abstract: The invention relates to the use of cationic polycondensation products as additives for fixing colours and/or inhibiting the running of colours, for washing products and washing aftertreatment products. Said cationic polycondensation products can be produced by the condensation of (A1) non-cyclic amines obtained by the reaction of (A1 a) mono(N,N-dialkylaminoalkyl)amines with (A1 b) bifunctional compounds selected from the group containing urea, thiourea, dialkyl carbonates, aliphatic and aromatic dicarboxylic acids, and aliphatic and aromatic diisocyanates, in a molar ratio 1.2:1 to 2.1:1, or (A2) mixtures of non-cyclic amines (A1) and cyclic amines (A3) in a molar ratio 10:1 to 1:10 with (B) bifunctional compounds selected from the group containing alkylene dihalogenides, dihalogen alkyl ethers, halomethyl oxiranes, and bisepoxides, in a molar ratio (B) to (A1) or (B) to (A2) from 0.6:1 to 1.3:1.

Abstract: Processes for forming adducts of amines with acrylic macromonomers are provided. Also provided are processes for using ring-closing reactions of the adducts to form lactams. The adducts are useful, for example, for making adhesives, surfactants, viscosity modifiers, processing aids, and other products.

Abstract: The instant invention relates to a liquid composition comprising a mixture of: (1) water and/or a polar solvent; (2) a colloidal dispersion of mineral particles; and (3) a phosphonate terminated poly(oxyalkene) polymer; the invention also relates to process for stabilizing aqueous and/or solvent-based dispersions of mineral particles comprising the step of adding an efficient stabilising amount of a phosphonate terminated poly(oxyalkene) polymer.

Abstract: A polyamide which contains a monoolefinically unsaturated compound chemically bonded at the end of the polymer chain, a process for preparing this polyamide, a polyamide obtainable by crosslinking this polyamide, and also fibers, films, and moldings, comprising at least one such polyamide.

Abstract: A process for preparing polyoxyalkylene phosphonates in high yield and purity without extensive isolation procedures. The process also enables hydroxy terminated polyoxyalkylene phosphonates to be produced with their attendant high aqueous solubility and the availability of the reactive group to have the end functionality easily molecularly modified. Products produced by these processes have enhanced dispersion, coating, adhesion, and plasticizing characteristics as a result of the lack of any steric hinderance on these polyoxyalkylene phosphonates.

Abstract: Polyamides useful as hotmelt adhesives and having improved resistance to hydrocarbons such as gasoline are obtained by reacting a) an acid component containing at least one C6 to C22 aliphatic dicarboxylic acid and b) an amine component containing at least one straight chain alkylene diamine having from 2 to 8 carbon atoms and at least one heterocyclic secondary diamine. The amine component may optionally also contain at least one branched chain alkylene diamine having from 3 to 10 carbon atoms and/or at least one C24 to C48 dimer amine.

Abstract: The reaction of dimer acids, C6 to C18 aliphatic dicarboxylic acids, dimer amines, alkylene diamines having from 2 to 8 carbon atoms, and polyoxyalkylene diamines provides polyamides having excellent cold flexibility, high heat resistance, and low moisture absorbency (low water vapor transmission).

Abstract: The energy levels (HOMO, LUMO) of the conjugated polymer are tuned independently, so that an energy match on both sides of the device can be accomplished while keeping the emission color in the blue region. Such polymers can be formed by polymerization of a mixture of monomers. The mixture of the monomers contains at least one monomer having an electron-deficient group sandwiched by two aromatic hydrocarbon groups (“Monomer (I)”) and at least one hole transporting (“HT”) monomer. The mixture of monomers may also contain a solubility enhancement (“SE”) monomer and/or a Branching Monomer. Such polymers can be used in fabricating light emitting diodes to achieve some of the best device performance to date including high efficiency and blue color purity.

Abstract: Golf balls comprising thermoplastic, thermoset, castable, or millable compositions are presently disclosed. These compositions comprise reaction products of polyacids and polyamines. The polyacid is chosen from polymerized fatty polyacids and polyacid telechelics. These compositions can be used in any one or more portions of the golf balls, such as inner center, core, inner core layer, intermediate core layer, outer core layer, intermediate layer, cover, inner cover layer, intermediate cover layer, and/or outer cover layer.

Abstract: A polymer compound contains a cyclic structure represented by the following general formula (1): wherein each of X and Y represent an alkylene group or the like, where X and Y may be the same or different, Z represents a bond derived from an alkylene group or the like having from 1 to 20 carbon atoms, which is bonded to a group represented by Y belonging to another cyclic structure, m represents 0 or an integer of 1 or more and n represents an integer of 2 or more, provided that the integer represented by m is independent in respective repeating units, and a total number of the bond represented by Z is 1 or more.

Abstract: A process for producing alkali metal polymaleimide salts by alkaline hydrolysis of maleimide polymers prepared by polymerization of maleimide monomers in the presence of a metal oxide and alcohol initiator or a base. In particular, the process produces alkali metal polymaleimide salts with particular ratios of C—N and C—C connected maleimide-derived monomer units which are dependent on the particular initiator used to synthesize the maleimide polymer. The alkali metal polymaleimide salts, which have chelating and anti-scaling properties, are useful as chelating agents and detergent builders and as such are suitable biodegradable replacements for synthetic polymers and sodium polyaspartate.

Abstract: A photoactive polymer from the class of polyimides, polyamide acids and esters thereof comprises as a side-chain a photocrosslinkable group of the general formula (I) wherein the broken line indicates the point of linkage to the polyimide main chain and wherein: B is a straight-chain or branched alkyl residue which is optionally substituted, wherein one or more non-adjacent CH2 groups may independently be replaced by a group Q; D represents an oxygen atom or —NR1— wherein R1 represents a hydrogen atom or lower alkyl; and S3 represents a spacer unit. The polymers may be used as orientation layers for liquid crystals and in the construction of unstructured and structured optical elements and multi-layer systems.

Abstract: A polymer comprising: a polymeric backbone comprising at least one unit having the structure (I), wherein R-R4 comprise groups selected from the group consisting of H, C1-C12 alkyl, C6-C18 aryl, C7-C18 aralkyl, C6-C18 cycloalkyl or any of the group consisting of C1-C12 alkyl, C6-C18 aryl, C7-C18 aralkyl, C6-C18 cycloalkyl substituted, within the carbon chain or appended thereto, with one or more heteroatoms; R and R2 or R and R4 or R and R1 or R2 and R3 may be joined so that with the carbon atom(s) to which they are attached they together form a saturated, partially unsaturated or unsaturated ring system respectively, may have a pendent group which may incorporate a linker unit, (for example a peptide linkage) or a unit having the structure (I); A comprises a proton donating moiety selected from the group consisting of formula (1).

Abstract: A radiation-curable composition is comprised of the reaction product of an amine-terminated (poly)aminoamide and a mono-(meth)acrylate or a poly-(meth)acrylate. The radiation-curable composition is a liquid at room temperature and does not undergo substantial volume contraction upon curing and exhibit excellent adhesion to porous and non porous substrates alike.

Abstract: The present invention relates to polyaspartate mixtures containing a) 5 to 50 equiv. %, based on the total equivalents of aspartate groups, of a polyoxypropylene polyaspartate corresponding to the formula wherein X1 represents the residue obtained by removing the amino groups from a polyoxypropylene polyamine having a functionality of n, R1 and R2 are identical or different and represent organic groups which are inert to isocyanate groups at a temperature of 100° C. or less, R3 and R4 are identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100° C. or less and n is 2 to 4, and b) 50 to 95 equiv.

Abstract: A separating agent that serves as an optical resolution agent is composed of a novel, useful optically active polymer. The separating agent is obtained through anionic polymerization of a novel maleimide and serves to separate optically active compounds.

Abstract: Alkoxylated, condensed basic amino acid-containing polymers comprising the addition products of alkylene oxides with homocondensates of basic amino acids, condensates of mixtures of two or more basic amino acids and cocondensates of basic amino acids and cocondensable compounds, and a process for the production of alkoxylated, condensed basic amino acid-containing polymers which comprises reacting homocondensates of basic amino acids, condensates of mixtures of two or more basic amino acids and cocondensates of basic amino acids and cocondensable compounds with at least one alkylene oxide selected from the group consisting of C2- and C30-alkylene oxides and styrene oxide.

Abstract: This invention concerns novel rosin-fatty acid vinylic polyamide polymer resin compositions and the process for preparing them. More particularly, the invention concerns novel rosin-fatty acid vinylic polyamide graft polymer compositions that exhibit properties that make them useful as resins for improving the adhesion of water-based inks and coatings to plastic substrates.

Abstract: The invention describes polyamides having both strongly hydrophilic groups and unsaturated groups, the polyamides consequently being water-dispersible and curable. The hydrophilic groups are distributed along the chain, whereas the unsaturated groups are located at the ends. The polyamides of the invention are useful in many applications, especially in the preparation of intimate blends of polyamides with vinyl, acrylic and/or styrene polymers.

Abstract: A free radical-curable epoxy composition comprises epoxy resin and a copolymerizable material including a monomer having amide, acrylamide, or hydroxyl functionality, and is advantageously devoid of any cationic catalyst ingredient.

Abstract: A coating, adhesive or sealant composition curable by Michael reaction comprises (A) a Michael acceptor which is a compound or polymer containing at least two activated olefinic double bonds and (B) a Michael donor which is a compound or polymer containing at least two nucleophilic groups. The double bonds of the Michael acceptor (A) are activated by two adjacent electron-withdrawing groups. Alternatively or additionally, the Michael donor (B) contains &bgr;-ketoamide, enamine carboxylate, enamine amide, pyrazolone, isoxazolone, hydantoin, rhodanine, thio-substituted unsaturated ester, thio-substituted lactone or phosphonite or phosphinite ester groups. More rapid ambient temperature curing is achieved.

Abstract: A curable composition is placed on a candle, and then the composition is exposed to curing conditions such as ultraviolet light, to thereby cure the coating composition and provide a candle having a cured coating. The curable composition may be the reaction product of TMPTA (trimethylolpropanetriacrylate), itself the reaction product of trimethylolpropane and acrylic acid) and oleyl amine (an unsaturated primary amine having eighteen carbons). The candle may be made of wax or a gelled solvent, i.e., a mixture of gellant and solvent, particularly a hydrocarbon or other low polarity solvent. The undiluted coating may be applied by spraying on the oily surface of the candle. Ultraviolet cure of the coating occurs in 1-2 seconds.

Abstract: The present invention relates to novel crosslinkable amphiphilic block copolymers of formula wherein the variables are as defined in the claims, a process for their preparation and their use for the manufacture of mouldings. The block copolymers of the invention are especially useful for the manufacture of ophthalmic mouldings such as in particular contact lenses.

Abstract: Benzobisazole polymers having repeating units of the formula wherein Z is wherein X is —S—, —O— or —NH—.