Ethylenically Unsaturated Reactant Patents (Class 528/345)
  • Patent number: 5510426
    Abstract: Higher molecular weight copolymers of polyaspartic acid which are suitable for the inhibition of scale deposition may be obtained by reacting maleic acid and ammonia in a stoichiometric excess, with a diamine or a triamine, at 120.degree.-350.degree. C., preferably 180.degree.-300.degree. C., and then converting the copolymer of polysuccinimide formed to a salt of a copolymer of polyaspartic acid by hydrolysis with a hydroxide.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: April 23, 1996
    Assignee: SRCHEM, Inc.
    Inventor: Louis L. Wood
  • Patent number: 5510427
    Abstract: Higher molecular weight copolymers of polyaspartic acid which are suitable for the inhibition of scale deposition may be obtained by reacting maleic acid and ammonia in a stoichiometric excess, with a diamine or a triamine, at 120.degree.-350.degree. C., preferably 180.degree.-300.degree. C., and then converting the copolymer of polysuccinimide formed to a salt of a copolymer of polyaspartic acid by hydrolysis with a hydroxide.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: April 23, 1996
    Assignee: SRCHEM, Inc.
    Inventor: Louis L. Wood
  • Patent number: 5504182
    Abstract: Thermoplastically processable aromatic polyether amideThermoplastically processable aromatic polyether amide of the formula (I) ##STR1## in which the symbols Ar, Ar', Ar.sub.1, Ar.sub.2, R, R', Y, x, y and z have the following meanings:Ar is a divalent, substituted or unsubstituted, aromatic or heteroaromatic radical or a group--Ar*--Q--Ar*--in whichQ is a bond or an --O--, --C(CH.sub.3).sub.2, --CO--, --S--, --SO-- or --SO.sub.2 -- bridge and Ar* is an aromatic radical. The carbonyl groups of the Ar radical are on non-adjacent ring carbon atoms.A is up to three different radicals.Ar' has the meaning given for Ar or is an Ar--Z--Ar group.In this case, Z is a --C(CH.sub.3).sub.2 -- or --O--Ar*--O--bridge.Y is a --C(CH.sub.3).sub.2 --, --SO.sub.2 --, --S-- or a --C(CF.sub.3).sub.2 --bridge and has up to two different meanings in the same polymer.Ar.sub.1 and Ar.sub.2 are identical or different from one another and are each a substituted or unsubstituted para- or meta-arylene radical.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: April 2, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Harald Cherdron, Willi Kreuder, Arnold Schneller, Otto Herrmann-Schonherr
  • Patent number: 5502117
    Abstract: Higher molecular weight copolymers of polyaspartic acid which are suitable for the inhibition of scale deposition may be obtained by reacting maleic acid and ammonia in a stoichiometric excess, with a diamine or a triamine, at 120.degree.-350.degree. C., preferably 180.degree.-300.degree. C., and then converting the copolymer of polysuccinimide formed to a salt of a copolymer of polyaspartic acid by hydrolysis with a hydroxide.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: March 26, 1996
    Assignee: Srchem, Inc.
    Inventor: Louis L. Wood
  • Patent number: 5496915
    Abstract: Polyimides are obtainable by reacting a dianhydride component with a diamine component, at least one diamine containing cycloaliphatic units, with the proviso that the dianhydride component is a mixture of different dianhydrides if the diamine component consists only of one diamine containing cycloaliphatic units and the diamine component is a mixture of different diamines if the dianhydride component consists of only one dianhydride.
    Type: Grant
    Filed: February 13, 1995
    Date of Patent: March 5, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Christian Fischer, Karin Elbl-Weiser, Ju/ rgen Koch
  • Patent number: 5496914
    Abstract: Polymers of maleic, fumaric or malic acids or maleic, fumaric or malic acid and ammonia with amino acids are prepared by heating at 180.degree.-350.degree. C., preferably 200.degree.-300.degree. C. The polymer formed may be converted to a salt by hydrolysis with a metal hydroxide or ammonium hydroxide.
    Type: Grant
    Filed: January 18, 1995
    Date of Patent: March 5, 1996
    Assignee: SRCHEM, Inc.
    Inventors: Louis L. Wood, Gary J. Calton
  • Patent number: 5491213
    Abstract: Polysuccinimide is prepared by reacting an unsaturated C.sub.2 dicarboxylic acid or anhydride thereof, e.g., maleic acid, fumaric acid, and maleic anhydride, with a particulate ammonium salt that is thermally decomposable to liberate ammonia. The reaction is carried out at a temperature which is above the thermal decomposition temperature of the ammonium salt and for a time period which is sufficient for the acid or anhydride to react with the ammonia liberated from the ammonium salt and for polymerization to occur. The present method avoids the prior art problems of controlling ammonia losses and water removal. The product polysuccinimide can be readily hydrolyzed to polyaspartic acid or a salt thereof, if desired.
    Type: Grant
    Filed: January 28, 1994
    Date of Patent: February 13, 1996
    Assignee: Donlar Corporation
    Inventor: Daniel A. Batzel
  • Patent number: 5478919
    Abstract: Aspartic acid precursors such as mono and diammonium maleate, maleamic acid, ammonium maleamate, ammonium malate and mixtures of these and other precursors are copolycondensed thermally with a variety of mono, di and multifunctional monomers containing amino, hydroxyl and carboxyl functional groups. The resulting condensation copolymers and terpolymers contain succinimide units derived from aspartic acid precursors, condensed with other functional group monomers usually though amide and ester linkages. Hydrolysis of the polysuccinimide copolymers and terpolymers with alkali, alkaline earth and ammonium hydroxide produces aspartic acid copolymer and terpolymer salts.
    Type: Grant
    Filed: July 29, 1994
    Date of Patent: December 26, 1995
    Assignee: Donlar Corporation
    Inventors: Larry P. Koskan, James F. Kneller, Daniel A. Batzel
  • Patent number: 5472823
    Abstract: A photosensitive resin composition comprising, as its main ingredient, a poly(amic acid) resin constituted of a diamino compound represented by formula: ##STR1## and optionally used other diamino compound and a tetracarboxylic acid dianhydride as its constituent monomers and/or a poly(amic acid) ester resin obtained by esterifying said poly(amic acid) resin and/or a polyimide resin obtained by a dehydrating or alcohol-eliminating ring-closure reaction of said poly(amic acid) resin or poly(amic acid) ester resin has an excellent developability and a high film strength and can form a relief patter of low thermal expansion.
    Type: Grant
    Filed: January 15, 1993
    Date of Patent: December 5, 1995
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Hideo Hagiwara, Makoto Kaji, Hiroshi Nishizawa, Kenji Suzuki, Yasunori Kojima
  • Patent number: 5470942
    Abstract: There is disclosed a process for preparing polyaspartic acid by thermal condensation of L-aspartic acid in a novel catalyst which shortens the reaction time and increases the molecular weight of the polymer. The novel catalyst is a catalytically effective methylenephosphonic acid. Typical catalysts are 1-hydroxyethylidene-1,1-diphosphonic acid and aminotris(methylenephosphonic acid). The methylenephosphonic acid is blended with the amino acid in a molar ratio of amino acid to catalyst in the range of from about 1:1 to 40:1.
    Type: Grant
    Filed: February 16, 1995
    Date of Patent: November 28, 1995
    Assignee: Monsanto Company
    Inventors: Gregory C. Alexander, Mark E. Jason, Dennis J. Kalota
  • Patent number: 5466760
    Abstract: Higher molecular weight copolymers of polyaspartic acid which are suitable for the inhibition of scale deposition may be obtained by reacting maleic acid and ammonia in a stoichiometric excess, with a diamine or a triamine, at 120.degree.-350.degree. C., preferably 180.degree.-300.degree. C., and then converting the copolymer of polysuccinimide formed to a salt of a copolymer of polyaspartic acid by hydrolysis with a hydroxide.
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: November 14, 1995
    Assignee: Srchem, Inc.
    Inventor: Louis L. Wood
  • Patent number: 5461138
    Abstract: A method for forming a homogeneous, concentrated, prepolymer composition, and a method of using the concentrated prepolymer composition to uniformly coat fibers is described. The prepolymer mixture is formed by dissolving a dialkyl, trialkyl, or tetraalkylester of biphenyltetracarboxylic acid in a solvent comprising ethyl acetate and methanol in a molar ratio of from about 1:3 to about 1:60, to form an ester solution. Diamine and end cap compound are added to the ester solution to form a monomer mixture solution. The end cap compound is a divalent compound characterized by (i) at least one unsaturated moiety, (ii) capable of reacting with the diamine or the ester to form an end cap radical that precludes further reaction of the diamine with the ester, and (iii) capable of undergoing addition polymerization. A portion of the solvent is evaporated from the monomer solution to form the substantially homogeneous, concentrated, prepolymer composition.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: October 24, 1995
    Assignee: TRW Inc.
    Inventors: Tito T. Serafini, Paul G. Cheng, Ward F. Wright
  • Patent number: 5461137
    Abstract: A method for forming a homogeneous, concentrated, prepolymer composition, and a method of using the concentrated prepolymer composition to uniformly coat fibers is described. The prepolymer mixture is formed by dissolving a dialkyl, trialkyl, or tetraalkylester of biphenyltetracarboxylic acid in a solvent comprising ethyl acetate and methanol in a molar ratio of from about 1:3 to about 1:60, to form an ester solution. Diamine and end cap compound are added to the ester solution to form a monomer mixture solution. The end cap compound is a divalent compound characterized by (i) at least one unsaturated moiety, (ii) capable of reacting with the diamine or the ester to form an end cap radical that precludes further reaction of the diamine with the ester, and (iii) capable of undergoing addition polymerization. A portion of the solvent is evaporated from the monomer solution to form the substantially homogeneous, concentrated, prepolymer composition.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: October 24, 1995
    Assignee: TRW Inc.
    Inventors: Tito T. Serafini, Paul G. Cheng, Ward F. Wright
  • Patent number: 5426172
    Abstract: Mixtures of salts of organic carboxylic acids and organic compounds of non-salt character, dissolved in a C.sub.1 -C.sub.4 alkanol, can be concentrated or separated with a semipermeable membrane made from a copolyamide or copolyimide-amide which contains (a) a first aromatic diamine radical and (b) a second aromatic diamine radical which carries --SO.sub.3 M groups, where M is H.sup..sym., a monovalent to polyvalent metal cation or an ammonium cation. Provided the first diamine radical contains C.sub.1 -C.sub.4 alkyl groups in the o-positions to the amino groups, the copolymers are radiation-sensitive and can be used for producing protective layers or relief images, development being carded out in an aqueous alkaline medium.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: June 20, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Joseph Berger, Wolfgang Wernet
  • Patent number: 5424391
    Abstract: A method for producing polysuccinimide is provided. Thermal polymerization of fumaramic acid at a temperature of from about 160.degree. C. to about 330.degree. C. produces polysuccinimide. The reaction is optionally conducted in the presence of one or more processing aids, solvents or diluents. The polysuccinimide is particularly useful as a detergent additive.
    Type: Grant
    Filed: July 20, 1993
    Date of Patent: June 13, 1995
    Assignee: Rohm and Haas Company
    Inventors: Yi H. Paik, Graham Swift, Ethan S. Simon, Michael B. Freeman
  • Patent number: 5420229
    Abstract: A flushing vehicle for lithographic inks is the reaction product of a tall oil rosin-modified maleic ester resin with an acid number of less than about 30, and about 2-16 wt. %, based on the weight of the ester, of a polyamide resin with an amine number less than about 110. The flushing vehicle is prepared by heating a reaction mixture containing the rosin-modified ester and the polyamide resin to a temperature of about 190.degree.-280.degree. C.; and holding at a temperature of 190.degree.-280.degree. C. until the viscosity of the reaction mixture becomes constant.
    Type: Grant
    Filed: November 16, 1993
    Date of Patent: May 30, 1995
    Assignee: Resinall Corporation
    Inventors: Roger E. Burke, J. Gilbert Sprull
  • Patent number: 5393868
    Abstract: A method for producing polysuccinimide is provided. Thermal polymerization of maleamic acid at a temperature of from about 160.degree. C. to about 330.degree. C. produces polysuccinimide. The reaction is optionally conducted in the presence of one or more processing aids, solvents or diluents. The polysuccinimide is particularly useful as a detergent additive.
    Type: Grant
    Filed: October 13, 1992
    Date of Patent: February 28, 1995
    Assignee: Rohm and Haas Company
    Inventors: Michael B. Freeman, Yi H. Paik, Ethan S. Simon, Graham Swift
  • Patent number: 5391642
    Abstract: Higher molecular weight copolymers of polyaspartic acid which are suitable for the inhibition of scale deposition may be obtained by reacting maleic acid and ammonia in a stoichiometric excess, with a diamine or a triamine, at 120.degree.-350.degree. C., preferably 180.degree.-300.degree. C., and then converting the copolymer of polysuccinimlde formed to a salt of a copolymer of polyaspartic acid by hydrolysis with a hydroxide.
    Type: Grant
    Filed: June 17, 1994
    Date of Patent: February 21, 1995
    Assignee: SRCHEM Incorporated
    Inventor: Louis L. Wood
  • Patent number: 5373087
    Abstract: A process for preparing a polyaminopolymer which contains functionality comprises the steps of (a) contacting a polyfunctional amine with an unsaturated alkylating agent under reaction conditions to form an amine/unsaturated alkylating agent adduct; (b) contacting the adduct with a polyfunctional compound such that a polyaminopolymer is formed: (e) contacting the polyaminopolymer with a halogen, hypohalous acid or precursor thereof such that a polyaminopolymer having halohydrin or dihalo functionality is formed, and (d) raising the pH of the polyaminopolymer having halohydrin or vicinal dihalo functionality sufficiently to cause an increase in molecular weight. Alternatively, the invention is a process having steps (a), (b), (c) and optionally (d), but with a step (h) between steps (b) and (c) of contacting the polyaminopolymer with a crosslinking agent therefor having at least two functional groups reactive with amine groups such that a crosslinked polyaminopolymer is formed.
    Type: Grant
    Filed: November 8, 1993
    Date of Patent: December 13, 1994
    Assignee: The Dow Chemical Company
    Inventors: Otha G. Weaver, Jr., Wanda G. Buckner, Terry W. Glass
  • Patent number: 5357004
    Abstract: Higher molecular weight copolymers of polyaspartic acid which are suitable for the inhibition of scale deposition may be obtained by reacting maleic acid and ammonia in a stoichiometric excess, with a diamine or a triamine, at 120.degree.-350.degree. C., preferably 180.degree.-300.degree. C., and then converting the copolymer of polysuccinimide formed to a salt of a copolymer of polyaspartic acid by hydrolysis with a hydroxide. Alkyl or substituted alkyl groups may be incorporated in the backbone of the polymer by adding a alkyl or substituted alkyl monoamine to maleic acid and ammonia and heating at 120.degree. C. or more until polymerization has occurred.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: October 18, 1994
    Assignee: Srchem Incorporated
    Inventors: Gary J. Calton, Louis L. Wood
  • Patent number: 5354829
    Abstract: A polymeric reaction product is disclosed that is a silylated polyamine-containing polymer having moieties from fatty acid moieties and/or chain extenders as difunctional organo moieties and free amine moieties and hydrolyzed and/or hydrolyzable organofunctional silane moieties and that is at least water dispersible. The reactants that produce this product are a polyamine-containing polymer with fatty acid moieties and free amine moieties and at least one amine-reactable organo functional alkoxysilane or its hydrolysis products. The former reactant results from the reaction of a polyamine-containing polymer with free amine moieties with fatty acids alone or in mixtures with other fatty acids and/or dimer acids. The polymeric reaction product is combined with a predominant amount of water to form a fiber treating formulation that can reside on the surface of one or more treated fibers.
    Type: Grant
    Filed: June 30, 1992
    Date of Patent: October 11, 1994
    Assignee: PPG Industries, Inc.
    Inventors: Robert G. Swisher, Richard P. Beaver, Robert G. Briody, Louis J. Nehmsmann
  • Patent number: 5326850
    Abstract: Molding materials are composed ofA) from 40 to 100% by weight of a copolyamide based ona.sub.1) from 1 to 20 mol%, based on the copoly- amide, of at least one monomer that contains at least one olefinic double bond (monomers a.sub.1) from the group of the.alpha..sub.1) olefinically unsaturated lactams,.alpha..sub.2) olefinically unsaturated aminocarboxylic acids,.alpha..sub.3) olefinically unsaturated dicarboxylic acids,.alpha..sub.4) olefinically unsaturated diamines, anda2) from 80 to 99 mol%, based on the copolyamide, of at least one monomer that contains no olefinic double bonds (monomers a2) from the group of the.beta..sub.1) lactams.beta..sub.2) aminocarboxylic acids,.beta..sub.3) dicarboxylic acids,.beta..sub.4) diamines, andB) from 0 to 35% by weight of an impact modifying rubber,C) from 0 to 50% by weight of a filler and/or reinforcing agent,D) from 0 to 20% by weight of a flame retardant, andE) from 0 to 10% by weight of further additives and processing aids.
    Type: Grant
    Filed: March 3, 1993
    Date of Patent: July 5, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Goetz, Brigitte Gareiss, Andreas Deckers, Petra Baierweck
  • Patent number: 5322916
    Abstract: A polyamide precursor of a polybenzazole polymer is prepared by reacting an aromatic bis(alkenyl)ester with a ring forming, aromatic diamine. The precursor can be prepared in an organic solvent for the monomers to form a soluble polyamide precursor which can be subsequently cyclocondensed to form a PBX polymer. A polybenzoxazole precursor is prepared by the reaction of a bis(alkenyl)ester and a bis(ortho-hydroxyamine). A polybenzazole polymer is easily prepared by heating the polyamide, PBX precursor.
    Type: Grant
    Filed: March 16, 1993
    Date of Patent: June 21, 1994
    Assignee: The Dow Chemical Company
    Inventors: James J. O'Brien, Edmund P. Woo
  • Patent number: 5322922
    Abstract: Mixtures of salts of organic carboxylic acids and organic compounds of non-salt character, dissolved in a C.sub.1 -C.sub.4 alkanol, can be concentrated or separated with a semipermeable membrane made from a copolyamide or copolyimide-amide which contains (a) a first aromatic diamine radical and (b) a second aromatic diamine radical which carries --SO.sub.3 M groups, where M is H.sup..sym., a monovalent to polyvalent metal cation or an ammonium cation. Provided the first diamine radical contains C.sub.1 -C.sub.4 alkyl groups in the o-positions to the amino groups, the copolymers are radiation-sensitive and can be used for producing protective layers or relief images, development being carried out in an aqueous alkaline medium.
    Type: Grant
    Filed: December 3, 1992
    Date of Patent: June 21, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Joseph Berger, Wolfgang Wernet
  • Patent number: 5320886
    Abstract: This invention relates primarily to organofunctional monomers, predominantly dimethacrylates and/or diacrylates containing one or more (predominantly two carboxyl groups, with moieties that provide sufficient affinity with water to allow any desired amount of water and/or miscible fugitive solvents to be mixed homogeneously with these monomers and formulations containing them. The activity of water in the monomer formulations can be adjusted so that it is equal to the water activity in biological tissues. This promotes biocompatibility and enhances the adhesive characteristics of polymers prepared from these formulations. Probability statistics are disclosed that optimize the compositions of polymer reaction products.
    Type: Grant
    Filed: November 14, 1991
    Date of Patent: June 14, 1994
    Assignee: American Dental Association Health Foundation
    Inventor: Rafael L. Bowen
  • Patent number: 5292858
    Abstract: Copolymers of polyamino acids formed by reaction of an alcohol with maleic anhydride to form the half ester followed by addition of ammonia, ammonia and an amine, or ammonia and a polyamine. The mixture is then heated to 120.degree.-350.degree. C. to form polysuccinimide or a derivative thereof. The resulting polysuccinimide may be hydrolyzed to form a derivative of polyaspartic acid or its salt.
    Type: Grant
    Filed: March 16, 1993
    Date of Patent: March 8, 1994
    Assignee: SRCHEM Incorporated
    Inventor: Louis L. Wood
  • Patent number: 5286810
    Abstract: Higher molecular weight copolymers of polyaspartic acid which are suitable for the inhibition of scale deposition may be obtained by reacting maleic acid and ammonia in a stoichiometric excess, with a diamine or a triamine, at 120.degree.-350.degree. C., preferably 180.degree.-300.degree. C., and then converting the copolymer of polysuccinimide formed to a salt of a copolymer of polyaspartic acid by hydrolysis with a hydroxide.
    Type: Grant
    Filed: April 7, 1993
    Date of Patent: February 15, 1994
    Assignee: SRCHEM Incorporated
    Inventor: Louis L. Wood
  • Patent number: 5278255
    Abstract: The present invention is a process for preparing a polyaminopolymer which contains functionality comprising the steps of (a) contacting a polyfunctional amine with an unsaturated alkylating agent under reaction conditions to form an amine/unsaturated alkylating agent adduct; (b) contacting the adduct with a polyfunctional compound such that a polyaminopolymer is formed; (c) contacting the polyaminopolymer with a halogen, hypohalous acid or precursor thereof such that a polyaminopolymer having halohydrin or dihalo functionality is formed; and (d) raising the pH of the polyaminopolymer having halohydrin or vicinal dihalo functionality sufficiently to cause an increase in molecular weight. Alternatively, the invention is a process having steps (a), (b), (c) and optionally (d), but with a step (h) between steps (b) and (c) of contacting the polyaminopolymer with a crosslinking agent therefor having at least two functional groups reactive with amine groups such that a crosslinked polyaminopolymer is formed.
    Type: Grant
    Filed: August 11, 1992
    Date of Patent: January 11, 1994
    Assignee: The Dow Chemical Company
    Inventors: Otha G. Weaver, Jr., Terry W. Glass, Wanda G. Buckner
  • Patent number: 5274047
    Abstract: Semipermeable composite membrane, with a porous carrier substrate, whereby said carrier substrate is provided with a polymer network obtained by polycondensation, especially interfacial polymerization, which is built up of at least one reactive polyfunctional monomer or oligomer or prepolymer or polymer, and at least one acid halide containing polymer.The specialty of this semi-permeable composite membrane consists therein that the acid halide containing polymere itself is built up of one or more vinyl containing monomers.The acid halide containing polymer is generally a copolymer of acryloylchloride H.sub.2 C.dbd.CHCOCl or methacryloyl chloride H.sub.2 C.dbd.C(CH13)COCl with one or more vinyl containing monomers.Usually the vinyl containing monomer is an acrylate or an acrylamide or a mixture thereof.
    Type: Grant
    Filed: February 21, 1992
    Date of Patent: December 28, 1993
    Assignee: X-Flow B.V.
    Inventors: Dirk M. Koenhen, Aloysius H. A. Tinnemans
  • Patent number: 5272247
    Abstract: The present invention provides a polyimide having all of small dielectric constant, small thermal expansion coefficient, high heat resistance, high glass transition temperature and high mechanical properties, a precursor of the polyimide, and processes for producing them. A polyimide precursor whose molecular chain comprises repeating units represented by the following general formula (1) and repeating units represented by the following general formula (2): ##STR1## wherein R.sup.1 is at least one kind of tetravalent organic group selected from the group consisting of ##STR2## R.sup.2 is at least one kind of divalent organic group having a linear structure which is selected from the group consisting of ##STR3## m is an integer of 1 to 4, and R.sup.3 is a divalent organic group having a non-linear structure which contains at least two aromatic rings.
    Type: Grant
    Filed: October 21, 1991
    Date of Patent: December 21, 1993
    Assignee: Hitachi, Ltd.
    Inventors: Hideo Sotokawa, Fusaji Shoji, Fumio Kataoka, Hidetaka Satou
  • Patent number: 5268422
    Abstract: Functionalized poly(hydroxyalkanoate) derivatives having the general structural formula: ##STR1## wherein Y is hydrogen, a saccharide moiety or an alkenyl moiety having a molecular weight in the range of from about 25 to about 100,000; R.sub.1, R.sub.2 and R.sub.3 are, independently, hydrogen, an aromatic moiety, an alkyl moiety or an alkenyl moiety, said alkyl moiety or alkenyl moiety including from one to about nine carbon atoms; A is carbonyl or methylene; X is oxygen or imino (--NH); Z is selected from the group consisting of hydrogen, a saccharide moiety, an alkyl moiety and an alkenyl moiety having a molecular weight in the range of from about 25 to about 100,000, with the proviso that if Y is hydrogen, Z is not hydrogen; r.sub.1, r.sub.2 and r.sub.
    Type: Grant
    Filed: November 9, 1992
    Date of Patent: December 7, 1993
    Inventor: Manssur Yalpani
  • Patent number: 5254669
    Abstract: The present invention relates to a process for the manufacture of a crosslinked polymer, wherein a crosslinking reaction is carried out between an organic crosslinking agent which is a polyacid or a derivative of a polyacid, and a long chain alkylpolyamine having at least two amine functional groups which may be primary and/or secondary and which is not a succinimide. The long chain alkylpolyamine can be obtained by a method comprising reacting a corresponding long chain alkylcarbonyl compound with an amine. The long chain carbonyl compound is for example prepared by ozonolysis of a polyolefin which can be a polybutene. The obtained crosslinked polymer can be used as an additive in lubricant compositions.
    Type: Grant
    Filed: August 25, 1992
    Date of Patent: October 19, 1993
    Assignee: BP Chemicals Limited
    Inventor: John R. Blackborow
  • Patent number: 5243019
    Abstract: A fluorine-containing aromatic polyamide obtained by reacting an aromatic dicarboxylic acid having a perfluoroalkenyloxy group with a diamine is excellent in water repellency, water resistance, heat resistance, etc.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: September 7, 1993
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Shinji Takeda, Masami Yusa, Yasuo Miyadera
  • Patent number: 5213890
    Abstract: A heat resistant composite film is described, which comprises (I) a thermoplastic film and (II) a cured layer of a thermosetting resin composition comprising (A) 100 parts by weight of an aliphatic diamine having a spiroacetal ring, (B) from 5 to 150 parts by weight of an ester derived from maleic acid and an alcohol represented by formula (I), and (C) from 20 to 250 parts by weight of an ester derived from a tetracarboxylic acid and an alcohol represented by formula (I),R.sup.1 --(OR.sup.2).sub.n --OH (I)wherein R.sup.1 represents an alkyl group having from 1 to 4 carbon atoms; R.sup.2 represents an alkylene group having from 2 to 4 carbon atoms; and n represents 0 or an integer of from 1 to 3. The composite film is resistant to temperatures of 150.degree. C. or higher while exhibiting flexibility.
    Type: Grant
    Filed: August 19, 1991
    Date of Patent: May 25, 1993
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Kaoru Kanayama, Noriko Okazaki
  • Patent number: 5196509
    Abstract: In one embodiment this invention provides polymalonamide polymers with side chains which exhibit nonlinear optical response.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: March 23, 1993
    Assignee: Hoechst Celanese Corp.
    Inventor: Diane E. Allen
  • Patent number: 5191016
    Abstract: Functionalized poly(hydroxyalkanoate) derivatives having the general structural formula: ##STR1## wherein Y is hydrogen, a saccharide moiety or an alkenyl moiety having a molecular weight in the range of from about 25 to about 100,000; R.sub.1, R.sub.2 and R.sub.3 are, independently, hydrogen, an aromatic moiety, an alkyl moiety or an alkenyl moiety, said alkyl moiety or alkenyl moiety including from one to about nine carbon atoms; A is carbonyl or methylene; X is oxygen or imino (--NH); Z is selected from the group consisting of hydrogen, a saccharide moiety, an alkyl moiety and an alkenyl moiety having a molecular weight in the range of from about 25 to about 100,000, with the proviso that if Y is hydrogen, Z is not hydrogen; r.sub.1, r.sub.2 and r.sub.
    Type: Grant
    Filed: July 19, 1990
    Date of Patent: March 2, 1993
    Inventor: Manssur Yalpani
  • Patent number: 5189134
    Abstract: Novel nonlinearly optically active polymers, well suited for electrooptical applications, are prepared by copolymerizing a first difunctional monomer with a second difunctional comonomer, with at least one of such difunctional monomers including a polar charge transfer moiety containing at least one electron acceptor group and at least one electron donor group (D), and further wherein the polymerizable functional groups are borne by the one or more electron donor groups (D).
    Type: Grant
    Filed: September 18, 1989
    Date of Patent: February 23, 1993
    Assignee: Rhone-Poulenc Chimie
    Inventors: Gerard Mignani, Pascal Barthelemy, Remi Meyrueix
  • Patent number: 5183847
    Abstract: Alkali-soluble resins, their preparation and use are disclosed herein. The resins are carboxylated polyamide/acrylic resins and are synthesized in a two-step fusion process in which a polyamide is first condensed with a carboxylated rosin and this intermediate product is then further condensed with an acrylic or styrene/acrylic copolymer.
    Type: Grant
    Filed: September 21, 1988
    Date of Patent: February 2, 1993
    Assignee: BASF Corporation
    Inventors: Sobhy El-Hefnawi, Shailesh C. Shah, Basil Wasyliw
  • Patent number: 5180424
    Abstract: The invention is a printing ink comprising a zinc-containing metal resinate complexed with aminopolyester resins and the process for preparing them. In particular, the invention relates to aminopolyester resins having properties which make them useful as resinate dilution extenders in formulating vehicles for gravure and intaglio printing inks.
    Type: Grant
    Filed: May 18, 1992
    Date of Patent: January 19, 1993
    Assignee: Westvaco Corporation
    Inventor: G. Frederick Hutter
  • Patent number: 5175234
    Abstract: Polyimide oligomers include (1) linear, monofunctional crosslinking oligomers prepared by condensing a monoanhydride end cap with a diamine that includes alternating ether and "Sulfone" (--SO.sub.2 --, --S--, --CO--, --(CF.sub.3).sub.2 C--, or --(CH.sub.3).sub.2 C--) linkages connecting alternating aromatic radicals and with a dianhydride (or dianhydride mixture), particularly the unsaturated, aliphatic dianhydride commonly known as MCTC; (2) linear, mono- or difunctional crosslinking oligomers prepared by condensing an amine end cap with a diamine and a dianhydride; and (3) multidimensional, crosslinking oligomers having an aromatic hub and at least three radiating arms connected to the hub, each arm including a crosslinking end cap at its distal end and at least one imide linkage.Blends, prepregs, and composites can be prepared from the oligomers.
    Type: Grant
    Filed: November 7, 1989
    Date of Patent: December 29, 1992
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard
  • Patent number: 5126429
    Abstract: This invention relates to amorphous, flexible elastomeric polyamides based on dimer fatty acids and special disecondary diamines which have a glass transition temperature below 10.degree. C., to the production of these elastomeric polyamides and to their use as rubbers, plasticizers and, in particular, high-impact modifiers for thermoplastics or as flexible segments for the synthesis of thermoplastic elastomers and as additives for other purposes.
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: June 30, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Burkhard Kohler, Hans-Detlef Heinz, Heinrich Schrage
  • Patent number: 5109105
    Abstract: Polyamide advanced composites are formed by the condensation of diacid halides (or dicarboxylic acids) and diamines in a linear or multidimensional morphology with crosslinkable end caps that provide improved solvent-resistance. The diamines and diacid halides generally include "sulfone" linkages in aryl chains to impart the desired combination of physical properties to the oligomers, prepregs, and composites. Linear oligomers have mono- or difunctional crosslinking end caps at the ends of polyarylamide chains. Multidimensional oligomers have a hub and three or more radiating amide arms, each arm having a mono- or difunctional crosslinking end cap at its distal end.
    Type: Grant
    Filed: June 7, 1989
    Date of Patent: April 28, 1992
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard
  • Patent number: 5101012
    Abstract: This invention relates to a composition prepared by reacting(a) at least one reaction product of a hydrocarbyl substituted carboxylic acid or anhydride having a hydrocarbyl group containing from about 8 to about 150 carbon atoms and at least one polyamine wherein the reaction product has at least one NH group capable of addition to a double bond; with(b) at least one sulfo compound represented by the following formula: ##STR1## wherein each R.sub.1 is independently hydrogen or a hydrocarbyl group;a is zero or one;Q is a hydrocarbylene group or --C(X)N(R.sub.2)Q'--;R.sub.2 is hydrogen or a hydrocarbyl group;X is sulfur or oxygen;each Q' is a hydrocarbylene group; andZ is --S(O)OH, or --S(O).sub.2 OH or an ester, a metal salt or an ammonium salt of the sulfo compound.The invention also relates to polymer fabrics treated with the compositions of the present invention. The treated polymer fabrics have improved wicking/wetting characteristics.
    Type: Grant
    Filed: August 6, 1991
    Date of Patent: March 31, 1992
    Assignee: The Lubrizol Corporation
    Inventor: Kasturi Lal
  • Patent number: 5098991
    Abstract: A process is disclosed for preparation of anhydrides containing additional carboxylic acid moieties and dianhydrides of disubstituted maleic anhydride compounds wherein the acid anhydrides and dianhydrides retain their alkene character. The resulting alkene compounds are useful as precursors for polyesters, thermally stable polyamide-imides and polyimides which are also disclosed, as well as a process for their preparation.
    Type: Grant
    Filed: January 8, 1990
    Date of Patent: March 24, 1992
    Assignee: Amoco Corporation
    Inventors: Steven J. Behrend, David A. Young, Ellis K. Fields
  • Patent number: 5093421
    Abstract: A new copolymer polyamide resin having very low water absorption which comprises copolymerized therein 99 to 5 parts by weight of polyamide polymeric component having at least one kind of repeating unit represented by the formula (1) or (2) below and 1 to 95 parts by weight of polyolefin component having an average molecular weight of 500 to 10,000, both terminals of said polyolefin being carboxylic acid groups, amino groups, or hydroxyl groups.--NH(CH.sub.2).sub.n CO-- (1)(where n is an integer from 5 to 11.)--NHXNHCOYCO (2)(where X is C.sub.m H.sub.2m (m is an integer from 6 to 12), isophorone group, phenylene group, or cyclohexylene group; and Y is C.sub.l H.sub.2l (l is an integer from 4 to 10), phenylene group, or cyclohexylene group.
    Type: Grant
    Filed: February 2, 1990
    Date of Patent: March 3, 1992
    Assignee: Daicel Chemical Industries Co., Ltd.
    Inventors: Koichiro Arita, Hajime Suzuki
  • Patent number: 5079338
    Abstract: An improvement in thermosetting bis(isoimide) resin compositions is achieved by replacing a small part of the unsaturated carboxylic acid anhydride starting material with a stoichiometrically equivalent amount of a poly(diolefin)-unsaturated carboxylic acid anhydride adduct.
    Type: Grant
    Filed: October 15, 1990
    Date of Patent: January 7, 1992
    Inventors: Thomas A. Schenach, John D. Harper
  • Patent number: 5079339
    Abstract: The present invention is an improved polyamide copolymer having monomer units including repeat units of the formula ##STR1## where n is from 10 to 14 and preferably is 12 (1,12-dodecanediamine), units derived from a symmetrical diacid or derivatives of said diacid, preferably a symmetrical aromatic dicarboxylic acid. The copolymer has minor amounts, preferably 3 to 30 and more preferably 5 to 10 mol percent, of units derived from an additional comonomer.
    Type: Grant
    Filed: August 13, 1990
    Date of Patent: January 7, 1992
    Assignee: Allied-Signal Inc.
    Inventors: Murali K. Akkapeddi, Jeffrey H. Glans
  • Patent number: 5072003
    Abstract: Compounds are disclosed which are anhydrides containing additional carboxylic acid moieties and dianhydrides of disubstituted maleic anhydride compounds wherein the acid anhydrides and dianhydrides retain their alkene character. These compounds are useful as precursors for polyesters, thermally stable polyamide-imides and polyimides.
    Type: Grant
    Filed: June 11, 1990
    Date of Patent: December 10, 1991
    Assignee: Amoco Corporation
    Inventors: Steven J. Behrend, Ellis K. Fields
  • Patent number: 5026823
    Abstract: This invention relates to novel polyimides derived from alicyclic dianhydrides and a process for synthesizing the polyimides.
    Type: Grant
    Filed: September 12, 1989
    Date of Patent: June 25, 1991
    Assignee: The Dow Chemical Company
    Inventors: John D. Summers, Thomas O. Jeanes
  • Patent number: 5025070
    Abstract: A new copolymer polyamide resin having very low water absorption which comprises copolymerized therein 99 to 5 parts by weight of polyamide polymeric component having at least one kind of repeating unit represented by the formula (1) or (2) below and 1 to 95 parts by weight of polyolefin component having an average molecular weight of 500 to 10,000, both terminals of said polyolefin being carboxylic acid groups, amino groups, or hydroxyl groups.--NH(CH.sub.2).sub.n CO-- (1)(where n is an integer from 5 to 11.)--NHXNHCOYCO-- (2)(where X is C.sub.m H.sub.2m (m is an integer from 6 to 12), isophorone group, phenylene group, or cyclohexylene group; and Y is C.sub.l H.sub.2l (l is an integer from 4 to 10), phenylene group, or cyclohexylene group).
    Type: Grant
    Filed: July 17, 1986
    Date of Patent: June 18, 1991
    Assignee: Daicel Chemical Industries Co., Ltd.
    Inventor: Hajime Suzuki