Abstract: Condensation polymers or addition polymers which contain sterically hindered polyalkylpiperidine groups are proposed as light stabilizers for plastics. The polymers concerned are relatively low-molecular polymers and a difunctional derivative of a polyalkylpiperidine is additionally used for the manufacture of these. The piperidine radical can be present in the main chain or as a side group of the polymeric stabilizer. Polymeric stabilizers of this type do not tend to migrate out of the plastic or to be removed by extraction; they are therefore very permanent in use.
Abstract: Novel carboxylic acid metal salt/amine complexes of the formula(A.sup..crclbar.).sub.2 Me.sup.2+ .multidot.NH.sub.2 --R.sub.1 --NH.sub.2in which A is the anion of cyanoacetic acid, pyrrolidonecarboxylic acid, maleimidylcarboxylic acid, succinylimidylcarboxylic acid, benzenesulphonic acid or toluenesulphonic acid or of a methanephosphonic acid monoester or benzenephosphonic acid monoester, Me.sup.2+ is a divalent metal cation and R.sub.1 is a long-chain polyoxyalkylene radical, are obtained by reacting 1 mol of a carboxylic acid metal salt of the formula(A.sup..crclbar.).sub.2 Me.sup.2+with 1 mol of a diamine of the formulaH.sub.2 N--R.sub.1 --NH.sub.2in a polar organic solvent and in the temperature range of 25.degree. to 200.degree. C. to give the complex compounds of the formula.The novel complex compounds are valuable curing agents for epoxide resins and in mixtures with epoxide resins have an advantageous storage stability.
Type:
Grant
Filed:
October 31, 1978
Date of Patent:
August 19, 1980
Assignee:
Ciba-Geigy Corporation
Inventors:
Friedrich Stockinger, Sameer H. Eldin, Friedrich Lohse
Abstract: New polyether polyols of predetermined structure are prepared by reacting polyether bis alcoholates with selected bis epoxides. Specifically, a polyoxyalkylene glycol is converted to the bis alcoholate, and then the bis alcoholate is reacted with an equivalent amount of a glycol bis glycidyl ether, with the reactants being mixed together all at once. The polyether polyalcoholate thus obtained is converted to a high molecular weight polyether polyol by acid neutralization or ion exchange.
Type:
Grant
Filed:
October 29, 1976
Date of Patent:
September 12, 1978
Assignee:
BASF Wyandotte Corporation
Inventors:
Herbert Helfert, Pauls Davis, William Keith Langdon