Reactant Contains Two Or More Rings Each Of Said Rings Having A Single Oxygen And Two Carbon Atoms Patents (Class 528/418)
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Patent number: 10414866Abstract: A polymer including a sub-unit comprising a Troger's base moiety represented by: Formula (I) wherein L comprises an arylene group including at least one substituent group selected from: i) a crosslinking bond and ii) a functional group selected from at least one of: hydroxyl, phosphonic acid, carboxylic acid and sulfonic acid and their corresponding salt or ester; alkynyl, alkynyl ether, cyanate, epoxide, glycidyl ether or ester.Type: GrantFiled: November 10, 2016Date of Patent: September 17, 2019Assignee: DOW GLOBAL TECHNOLOGIES LLCInventors: Robert E. Hefner, Jr., Ian A. Tomlinson, Brian L. Cramm
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Patent number: 10253225Abstract: The invention relates to structural adhesive compositions and more particularly to two-component (2K) structural adhesive compositions. The two components chemically react to bond structural surfaces. N-(3-Aminopropyl)cyclohexylamine (APCHA) has been found to be an improved curing agent for use with epoxy resins in 2K adhesive compositions. APHCA exhibits favorable features including viscosity, pot life and reactivity, and adhesive and thermal performance after curing with epoxy resin. These features and its unique chemistry allow the use of APCHA in curing agent formulations for structural adhesives, in particular wind turbine blade adhesives. APCHA solves issues with viscosity build-up, working time, through-cure, compatibility and adhesive performance that cannot be addressed with the commonly used amine formulations.Type: GrantFiled: December 14, 2017Date of Patent: April 9, 2019Assignee: Evonik Degussa GmbHInventors: Marieke Theodora Arnolda van Gorkom, Edze Jan Tijsma
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Patent number: 9908948Abstract: Enantiomers of butanediol diglycidyl ether (BDDE) are present in an enantiomerically enriched enantioenriched mixture of BDDE stereisomers or in an enantiomerically pure BDDE. Enantiomerically enriched or pure BDDE is useful as a cross-linking agent, such as in the preparation of a cross-linked hyaluronic acid product.Type: GrantFiled: August 28, 2015Date of Patent: March 6, 2018Assignee: GALDERMA S.A.Inventors: Jean-Guy Boiteau, Lars Nord, Thibaut Gerfaud
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Patent number: 9150685Abstract: Cured epoxy resins are widespread on account of their outstanding mechanical and chemical properties. It is common to use epoxy resins based on bisphenol A diglycidyl ether or bisphenol F diglycidyl ether, but for many sectors these are problematic because of their endocrine effect. The present invention relates to 2-phenyl-1,3-propanediol diglycidyl ether derivates and to curable epoxy resin compositions based thereon, as alternatives to the bisphenol A or bisphenol F diglycidyl ethers and to the epoxy resin compositions based thereon.Type: GrantFiled: November 7, 2013Date of Patent: October 6, 2015Assignee: BASF SEInventors: Ulrich Karl, Monika Charrak, Hans-Josef Thomas, Nicolas Marion
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Publication number: 20150141548Abstract: The present invention provides methods of making a low viscosity C15 alkenyl group containing diglycidyl ether composition comprising at least partially distilling a mixture of one or more C15 alkenyl group containing monoglycidyl ether and one or more C15 alkenyl group containing diglycidyl ether in the presence of a free radical inhibitor to remove at least some of the C15 alkenyl group containing monoglycidyl ether. The methods enable high solids, low viscosity epoxy resins from a renewable source. The present invention also provides compositions of C15 alkenyl group containing diglycidyl ether adducts of a polyamine.Type: ApplicationFiled: November 17, 2014Publication date: May 21, 2015Inventors: Ray E. Drumright, Robert E. Hefner, JR.
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Publication number: 20150133629Abstract: There is provided a diepoxy compound that can be polymerized to form a cured product having thermal stability that has excellent heat resistance, and can maintain excellent mechanical properties even if exposed to a high temperature environment. The saturated diepoxy compound of the present invention is represented by the following formula (1) and can be produced by hydrogenating the unsaturated bond of an unsaturated diepoxy compound represented by the following formula (2). In the following formulas, R1 to R20 are each an independent group and identically or differently represent a hydrogen atom, a methyl group, or an ethyl group.Type: ApplicationFiled: April 2, 2013Publication date: May 14, 2015Applicant: DAICEL CORPORATIONInventors: Kyuhei Kitao, Hideyuki Takai, Michihiro Sugahara
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Publication number: 20150118498Abstract: The present invention provides a resin composition having a suitable melting temperature for molding, a resin sheet containing the resin composition, a cured resin product excellent in thermal conductivity and heat resistance, and a substrate. They are prepared in the way that in the resin composition containing epoxy compounds and curing agent selected from 1,3,5-tris(4-aminophenyl)benzene and 1,3,5-tris(4-hydroxyphenyl)benzene, the content of 1,3,5-triphenylbenzene that is the main skeleton of the curing agent is 15 mass % or more and 50 mass % or less of the total organic substances in the resin composition.Type: ApplicationFiled: October 23, 2014Publication date: April 30, 2015Inventors: Tsuyoshi SUGIYAMA, Hiroshi SHUTOH
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Patent number: 9006385Abstract: Thermoset elastomer compositions are disclosed. Such elastomers are the reaction product of (a) an ambient temperature liquid epoxy-terminated prepolymer formed by reacting a polyoxyalkyleneamine having a molecular weight of from 3000 to 20,000 with an excess of epoxide, wherein the polyoxyalkyleneamine has at least 3 active hydrogen atoms and (b) a curing agent comprising at least one amine or polyamine having an equivalent weight of less than 200 and having 2 to 5 active hydrogen atoms. Such elastomers can be used in applications such as for sealants, adhesives, coatings, gaskets, jointing and cast elastomers.Type: GrantFiled: August 31, 2011Date of Patent: April 14, 2015Assignee: Dow Global Technologies LLCInventors: Nathan Wilmot, Rajat Duggal, Juan Carlos Medina, Harshad M. Shah, Alan K. Schrock
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Publication number: 20150093320Abstract: A liquid carbon precursor composition including (a) at least one aromatic epoxy resin; and (b)(i) at least one aromatic co-reactive curing agent or (b)(ii) at least one catalytic curing agent, or (b)(iii) a mixture thereof; wherein the liquid composition prior to adding optional components and curing, has a neat viscosity of less than 10,000 mPa-s, at 25° C.; and wherein the liquid precursor composition has a neat viscosity of less than 10,000 mPa-s at 25° C. prior to adding optional components, prior to curing, and prior to carbonizing; and wherein the liquid precursor composition being cured has a carbon yield of at least 35 weight percent as measured in the absence of optional components; a cured liquid carbon precursor composition; a carbonized material made from the above liquid carbon precursor composition; and processes for producing the above compositions.Type: ApplicationFiled: May 17, 2013Publication date: April 2, 2015Inventors: Hamed H. Lakrout, Maurice J. Marks, Ludovic Valette
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Publication number: 20150018515Abstract: A method of producing an epoxy compound, which comprises reacting hydrogen peroxide with a compound having a carbon-carbon double bond, in the presence of at least one of a tungsten compound and a molybdenum compound; and an onium salt comprising 20 or more carbon atoms and one or more of substituents convertible to a functional group containing an active hydrogen or a salt thereof.Type: ApplicationFiled: September 30, 2014Publication date: January 15, 2015Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Akemi HOSOKAWA, Haruhiko KUSAKA
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Publication number: 20150005458Abstract: The present invention relates to a matrix material for a carbon fiber-reinforced composite. The matrix material for the carbon fiber composite contains a matrix resin as a resin component. The matrix resin contains at least a first epoxy resin containing a polyfunctional glycidylamine-type epoxy resin having four epoxy groups in one molecule. The matrix resin may further contain at least one of a p-aminophenol-type epoxy resin having three epoxy groups in one molecule, and a tetramethylbiphenol-type solid epoxy resin having two epoxy groups in one molecule. The matrix resin has an average epoxy equivalency of 99 to 163.Type: ApplicationFiled: June 17, 2014Publication date: January 1, 2015Inventor: Shuichiro Yoshida
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Patent number: 8912291Abstract: Embodiments include oxazolidone ring containing adducts obtainable by combining an aliphatic epoxy compound, an aromatic epoxy compound, and a diisocyanate. Embodiments further include a curable powder coating composition including a resin component and a hardener component, where the resin component includes the oxazolidone ring containing adduct.Type: GrantFiled: December 20, 2010Date of Patent: December 16, 2014Assignee: DOW Global Technologies LLCInventors: Joseph Gan, Emile C. Trottier
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Publication number: 20140357836Abstract: Provided are: a novel triepoxy compound capable of forming, through polymerization, a cured article having excellent heat resistance; a production method thereof; a curable composition including the triepoxy compound; and a cured article obtained by curing the curable composition. The triepoxy compound according to the present invention is represented by Formula (1). The triepoxy compound represented by Formula (1) may be obtained typically by oxidizing a compound represented by Formula (2) with an oxidizing agent. In Formulae (1) and (2), R1 to R2° are the same as or different from one another and each represent hydrogen atom, methyl group, or ethyl group.Type: ApplicationFiled: September 4, 2012Publication date: December 4, 2014Applicant: DAICEL CORPORATIONInventors: Kyuhei Kitao, Hideyuki Takai, Michihiro Sugahara
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Patent number: 8877341Abstract: According to the present invention, a polycarbonate resin having a repeat unit represented by the following formula (1) and a repeat unit represented by the following general formula (2), and an optical film using the same, can be provided. In the formula, Y is a cycloalkylene group having a carbon number of 4 through 20 or a structure represented by the following general formula (3). In the general formula (3), R1, R2, R3 and R4 are independently a hydrogen atom or a monovalent alkyl group having a carbon number of 1 through 5.Type: GrantFiled: August 13, 2007Date of Patent: November 4, 2014Assignee: Mitsubishi Gas Chemical Company, IncInventors: Noriyuki Kato, Kunitoshi Mimura
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Patent number: 8871892Abstract: An epoxy oxazolidone including the reaction product of (a) a divinylarene dioxide, and (b) an excess of a polyisocyanate to provide an epoxy oxazolidone composition; wherein the composition has an oxazolidone selectivity of greater than 40% relative to the total of the carbonyl compounds; a process for making the epoxy oxazolidone; and a curable epoxy resin composition including (i) the epoxy oxazolidone derived from a divinylarene dioxide such as divinylbenzene dioxide (DVBDO) and a polyisocyanate, (ii) at least one curing agent; and/or (iii) a catalyst. The cured product made from the above epoxy resin composition is thermally stable and offers improved properties such as a lower viscosity and a high heat resistance compared to known cured products prepared from known epoxy resins.Type: GrantFiled: October 15, 2010Date of Patent: October 28, 2014Assignee: Dow Global Technologies LLCInventor: Maurice J. Marks
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Patent number: 8846856Abstract: A novel hydroxyl-functional polyether derived from the reaction of (a) a divinylarene dioxide, particularly a divinylarene dioxide derived from divinylbenzene such as divinylbenzene dioxide (DVBDO); and (b) a diphenol; wherein the reaction product is thermally stable and exhibits an absence of self-polymerization (crosslinking or gelling) upon heating at elevated temperatures. The novel hydroxyl-functional polyether offers improved properties compared to known hydroxyl-functional polyethers such as solid epoxy resins, phenolic epoxy resins (hardeners), and poly(hydroxyl ethers).Type: GrantFiled: November 23, 2009Date of Patent: September 30, 2014Assignee: Dow Global Technologies LLCInventor: Maurice J. Marks
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Patent number: 8802792Abstract: Partially hydrogenated bisphenol-A based polymers. Coating compositions for food or beverage containers and medical devices, including a partially hydrogenated bisphenol-A based polymer. Food or beverage containers and medical devices coated with partially hydrogenated bisphenol-A based polymers. Food or beverage containers and medical devices made from partially hydrogenated bisphenol-A based polymers.Type: GrantFiled: September 17, 2010Date of Patent: August 12, 2014Assignee: Empire Technology Development LLCInventors: William B. Carlson, Gregory D. Phelan, Phillip A. Sullivan
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Publication number: 20140179828Abstract: Epoxy resins comprising a diglycidyl ether of Formula 1 as defined herein are described. The diglycidyl ether contains a cycloaliphatic ring of 3-5 carbon atoms. The epoxy resins are made by a method comprising the steps of: (a) forming a reaction mixture comprising a diol of Formula 3 as defined herein, an epihalohydrin, a phase transfer catalyst, and optionally an organic solvent; (b) contacting a basic acting substance and water with the reaction mixture of step (a); (c) washing the mixture of step (b) with an aqueous solvent to substantially remove salts; and (d) isolating the epoxy resin. Curable and cured compositions comprising the epoxy resins are also disclosed. The epoxy resins have increased glass transition temperatures and reduced viscosity compared to epoxy resins derived from cyclohexanedimethanol.Type: ApplicationFiled: December 18, 2013Publication date: June 26, 2014Applicant: Dow Global Technologies LLCInventors: Robert E. Hefner, JR., Ray E. Drumright, Jinghang Wu
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Publication number: 20140128503Abstract: Cured epoxy resins are widespread on account of their outstanding mechanical and chemical properties. It is common to use epoxy resins based on bisphenol A diglycidyl ether or bisphenol F diglycidyl ether, but for many sectors these are problematic because of their endocrine effect. The present invention relates to 2-phenyl-1,3-propanediol diglycidyl ether derivates and to curable epoxy resin compositions based thereon, as alternatives to the bisphenol A or bisphenol F diglycidyl ethers and to the epoxy resin compositions based thereon.Type: ApplicationFiled: November 7, 2013Publication date: May 8, 2014Applicant: BASF SEInventors: Ulrich Karl, Monika Charrak, Hans-Josef Thomas
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Publication number: 20140114047Abstract: A hybrid polyfunctional aliphatic and/or cycloaliphatic epoxy (H-PACE) resin composition comprising, consisting of or consisting essentially of: (a) a moiety selected from the group consisting of an aliphatic moiety, a cycloaliphatic moiety, and combinations thereof provided by the polyfunctional aliphatic and/or cycloaliphatic epoxy (PACE) resin; and (b) a moiety selected from the group consisting of an aliphatic moiety, a cycloaliphatic moiety, and combinations thereof, wherein said moiety is not provided by the PACE resin, is disclosed. Processes for making and using such resin composition are also disclosed.Type: ApplicationFiled: June 14, 2012Publication date: April 24, 2014Applicant: DOW GLOBAL TECHNOLOGIES LLCInventor: Robert E. Hefner, JR.
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Publication number: 20140024741Abstract: The present invention relates to novel high-latency liquid hardeners for hardening of curable polymer resins, especially epoxy resins, and to epoxy resin compositions comprising liquid hardeners for the production of fibre composite materials.Type: ApplicationFiled: February 23, 2012Publication date: January 23, 2014Applicant: Alzchem AGInventors: Sylvia Strobel, Martin Ebner, Hans-Peter Krimmer, Monika Brandl
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Patent number: 8609806Abstract: To provide phosphorus-containing epoxy resins and phosphorus-containing epoxy resin compositions having high levels of appearance, yield and economic efficiency and cured products thereof that are used for various applications. A phosphorus-containing phenol compound represented by Formula (3) obtained by reacting a compound represented by Formula (2) with a compound represented by Formula (1), wherein in the peak area (A) of the component represented by Formula (1) on a chromatogram measured under specific conditions by gel permeation chromatography, peak area (B) on the high-molecular-weight side of the component of Formula (1), and total area (C) of peak area (A) and peak area (B), the value obtained by dividing peak area (B) by total area (C) is 8 area % or less, and epoxy resin compositions and cured products comprising the phosphorus-containing phenol compound as an essential ingredient.Type: GrantFiled: September 2, 2009Date of Patent: December 17, 2013Assignee: Nippon Steel & Sumikin Chemical Co., Ltd.Inventors: Tetsuya Nakanishi, Hideyasu Asakage, Seigo Takuwa
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Publication number: 20130261228Abstract: A curable composition or system including (a) at least one divinylarene dioxide, (b) at least one polythiol compound curing agent; and (c) at least one catalyst; wherein the resulting curable composition may be cured at ambient conditions to provide durable cured material.Type: ApplicationFiled: October 19, 2011Publication date: October 3, 2013Applicant: Dow Global Technologies LLCInventor: Maurice J. Marks
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Patent number: 8524857Abstract: A new class of compounds, namely diamino alcohols, is described, along with a process for their production and their use as hardeners, or curing agents, for epoxy resin systems, some of which have high glass transition temperatures, Tgs, such as greater than about 120° C.Type: GrantFiled: December 15, 2010Date of Patent: September 3, 2013Assignees: Dow Global Technologies LLC, ANGUS Chemical CompanyInventors: Asghar Akber Peera, Ian Tomlinson
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Patent number: 8519091Abstract: The present invention provides curing agent compositions comprising the reaction product of polyalkyleneamine compounds and polyalkylene polyether polyol modified polyepoxide resins. Amine-epoxy compositions and thick layer compositions produced from these amine-epoxy compositions are also disclosed.Type: GrantFiled: April 10, 2007Date of Patent: August 27, 2013Assignee: Air Products and Chemicals, Inc.Inventor: Williams René Edouard Raymond
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Patent number: 8507643Abstract: A composition comprising glycerol and at least one cyclic oligomer of glycerol, a process for obtaining the composition, and its use in the manufacture of dichloropropanol and of derived products such as epichlorohydrin and epoxy resins.Type: GrantFiled: March 31, 2009Date of Patent: August 13, 2013Assignee: Solvay S.A.Inventors: Patrick Gilbeau, Bruno Jestin
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Patent number: 8450450Abstract: The present invention relates to an improved process for manufacturing polyether and copolyether glycols by polymerization of a reaction mixture comprising at least one tetrahydrofuran or at least one tetrahydrofuran and at least one other cyclic ether, for example, an alkylene oxide, in the presence of a particular perfluorosulfonic acid resin catalyst comprising a copolymer of tetrafluoroethylene (TFE) or chlorotrifluoroethylene (CTFE) and a monomer of the formula CF2?CF—O—CF2—CF2—SO2F.Type: GrantFiled: August 19, 2010Date of Patent: May 28, 2013Assignee: Invista North America S.A R.L.Inventor: Qun Sun
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Patent number: 8419972Abstract: A polymerizable liquid crystal composition is provided that is excellent in UV curing characteristics in the air and is excellent in orientation homogeneity, and a polymer film as a selective reflection film is provided that is obtained by orienting and polymerizing the composition on a supporting substrate. The liquid crystal composition contains a compound (1), a compound (2), a compound (3), a compound selected from a group of compounds represented by the formulae (4) to (6), and a surfactant. In the following formulae Y1 to Y4 and Y6 are each alkylene, A2, A3, A41, A42, A51, A52 and A6 are each a cyclic group, Z2 to Z4 and Z6 are each a bonding group, P4 and P6 are each an integer of from 0 to 3, R2, R31 and R32 are each hydrogen, halogen or alkyl, and Q1 and Q2 are each a polymerizable group.Type: GrantFiled: November 6, 2009Date of Patent: April 16, 2013Assignees: JNC Corporation, JNC Petrochemical CorporationInventors: Yoshiharu Hirai, Kazumi Hagihara
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Publication number: 20130019256Abstract: An information recording medium excellent in long storage and capable of high-density recording, method of manufacturing the information recording medium, and information recording material are provided. Pulse laser light is focused onto a recording layer in which a thermosetting epoxy resin having a skeleton with high planarity and a curing agent are polymerized to form a recording mark. With a cured material of a recording layer having a density equal to or larger than 1.210 g/cm3 and a glass transition temperature of 110° C. to 140° C., high-speed recording is possible.Type: ApplicationFiled: June 9, 2011Publication date: January 17, 2013Applicant: Sony Chemical & Information Device CorporationInventors: Kouki Hatsuda, KyungSung Yun
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Patent number: 8334092Abstract: The present invention relates to a photo-sensitive resin composition having superior heat-resistant and mechanical property, and a protective film for printed circuit board, and particularly provides a photo-sensitive resin composition including an acid-modified oligomer, a photo-polymerizable monomer, a photo-initiator, an epoxy resin, and a butadiene-modified epoxy resin including epoxy group and at least one double bond in the main chain, and a protective film for printed circuit board prepared by using the composition.Type: GrantFiled: June 20, 2011Date of Patent: December 18, 2012Assignee: LG Chem, Ltd.Inventors: Bo-Yun Choi, Byung-Ju Choi, Woo-Jae Jeong, Kwang-Joo Lee, Min-Su Jeong
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Publication number: 20120309933Abstract: A hydrolyzed divinylarene dioxide resin composition including the reaction product of (a) a divinylarene dioxide, and (b) water; a process for making the hydrolyzed divinylarene dioxide resin composition; and a curable hydrolyzed divinylarene dioxide resin composition made therefrom. The cured product made from the above hydrolyzed divinylarene dioxide resin composition offers improved properties such as a lower viscosity and a high heat resistance compared to known cured products prepared from known epoxy resins.Type: ApplicationFiled: December 8, 2010Publication date: December 6, 2012Inventors: Maurice J. Marks, E. Joseph Campbell
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Patent number: 8318309Abstract: The present invention provides epoxy curing agent compositions comprising benzylated aminopropylated alkylenediamine compounds. Amine-epoxy compositions and articles produced from these amine-epoxy compositions are also disclosed.Type: GrantFiled: August 6, 2008Date of Patent: November 27, 2012Assignee: Air Products and Chemicals, Inc.Inventors: Gamini Ananda Vedage, Williams Rene Edouard Raymond, Michael Ian Cook, Robert Marjo Theodoor Rasing, Ellen Margaret O'Connell, Maw Lin Foo
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Publication number: 20120252996Abstract: The present invention relates to a curable bicyclic compound derived from biomass, solvent-free curable composition and a method for preparing thereof. The curable compound derived from biomass according to the invention comprises a bicycle structure, to which one of two epoxide functional groups are bonded.Type: ApplicationFiled: May 5, 2010Publication date: October 4, 2012Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGYInventors: Jin Ku Cho, Sang Yong Kim, Do Hoon Lee, Bo Ra Kim, Baek Jin Kim, Jae Won Jung, Sang Hyeup Lee, Jae Soung Lee
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Publication number: 20120214948Abstract: Methods of compounding nanoparticles with a resin, e.g., a curable resin and one or more surface modifying agents are described. The methods use wet milling technology, including both continuous and batch milling processes, and can be used to functionalize the nanoparticles and disperse the functionalized nanoparticles into the resin system in a single process. Methods of compounding curable resin systems containing reactive diluents are also disclosed.Type: ApplicationFiled: October 21, 2010Publication date: August 23, 2012Inventors: Peter D. Condo, Jung-Sheng Wu, Chad A. Haraldson, William J. Schultz, Emily S. Goenner, James E. Thorson, Wendy L. Thompson
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Patent number: 8242217Abstract: It is an object of the present invention to provide an epoxy resin curing agent which has a favorable pot life and good storage stability as a curing agent for epoxy resins and from which an epoxy resin cured product having good water resistance and hardness is obtained through curing. The present invention is an epoxy resin curing agent containing a secondary or tertiary branched thiol compound having a substituent on a carbon atom at the ?-position to a thiol group, and is also an epoxy resin composition comprising a polyvalent epoxy compound and the epoxy resin curing agent.Type: GrantFiled: December 8, 2008Date of Patent: August 14, 2012Assignee: Showa Denko K.K.Inventors: Yoshifumi Urakawa, Hideo Miyata, Isao Yamagami, Katsumi Murofushi
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Publication number: 20120148840Abstract: The fiber-reinforced polymer material, in particular for processing in the injection molding and extrusion method, is composed of granular materials having integrated long-fiber reinforcement. The granular materials are designed as wound elements (5), which have continuous fiber strands (3) including continuous reinforcing fibers (1) impregnated with polymer material (2). The wound elements (5) contain more than one turn (6) of the impregnated continuous fiber strands (3), wherein the turns (6) at least partially overlap each other such that the turns are arranged over each other and/or next to each other. The wound elements (5) can be continuously produced by winding and solidifying the impregnated continuous fiber strands (3) around a winding axis (23) or on a winding core (22) and subsequently separating the wound elements from each other, in particular by means of a winding core moved in an oscillating (+x1, ?x1) manner and using melted thermoplastic polymer material (2).Type: ApplicationFiled: August 23, 2010Publication date: June 14, 2012Inventor: David Stirnemann
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Patent number: 8198395Abstract: The present invention provides epoxy curing agent compositions comprising alkylated aminopropylated alkylenediamine compounds. Amine-epoxy compositions and articles produced from these amine-epoxy compositions are also disclosed.Type: GrantFiled: August 6, 2008Date of Patent: June 12, 2012Assignee: Air Products and Chemicals, Inc.Inventors: Gamini Ananda Vedage, Williams Rene Edouard Raymond, Ellen Margaret O'Connell, Maw Lin Foo, Peter Andrew Lucas
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Patent number: 8193280Abstract: Ionic liquid epoxide monomers that react with cross-linking agents to form polymers exhibiting high tensile and adhesive strengths are described. The polymers exhibit high tensile and adhesive strengths at extremely low temperatures and are stable at elevated temperatures. The polymer resins are particularly well-suited for use as adhesives, and in coatings, composites, and articles of manufacture.Type: GrantFiled: July 4, 2008Date of Patent: June 5, 2012Assignees: AZ Technology, Inc., The United States of America as represented by the National Aeronautics and Space AdministrationInventors: Mark S. Paley, Rhonda S. Libb, Richard N. Grugel, Richard Ernest Boothe
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Patent number: 8053546Abstract: The use of 1,3-substituted imidazolium salts of the formula I in which R1 and R3 independently of one another are an organic radical having 1 to 20 C atoms, R2, R4, and R5 independently of one another are an H atom or an organic radical having 1 to 20 C atoms, it also being possible for R4 and R5 together to form an aliphatic or aromatic ring, X is an anion having a pKb of less than 13 (measured at 25° C., 1 bar in water or dimethyl sulfoxide), and n is 1, 2 or 3, with the exception as imidazolium salts of 1-ethyl-2,3-dimethylimidazolium acetate and 1-ethyl-2,3-dimethylimidazolium acetate-acetic acid complex, as latent catalysts for curing compositions comprising epoxy compounds.Type: GrantFiled: June 6, 2008Date of Patent: November 8, 2011Assignee: BASF SEInventors: Georg Degen, Matthias Maase, Lars Wittenbecher, Manfred Döring, Ulrich Arnold
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Patent number: 8030431Abstract: A curable mixture which includes at least (a) 10 to 100 percent by weight, in relation to the sum of the components (a) and (b), of at least one bi- or polyfunctional aromatic cyanate or a prepolymer formed from at least one bi- or polyfunctional aromatic cyanate or a mixture formed from the abovementioned cyanates and/or prepolymers; (b) 0 to 90 percent by weight, in relation to the sum of the components (a) and (b), of at least one mono-, bi- or polyfunctional epoxy resin; (c) 0.5 to 30 percent by weight, in relation to the sum of the components (a) and (b), of at least one mono-, bi- or polyfunctional aromatic amine; and (d) 0 to 5 percent by weight, in relation to the sum of the components (a) and (b), of at least one catalyst from the group consisting of transition metal compounds and boron trihalides.Type: GrantFiled: October 18, 2002Date of Patent: October 4, 2011Assignee: Lonza AGInventors: Ulrich Daum, Alessandro Falchetto, Sajal Das
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Patent number: 7993751Abstract: The present invention provides epoxy curing agent compositions comprising alkylated aminopropylated methylene-di-(cyclohexylamine) compounds. Amine-epoxy compositions and articles produced from these amine-epoxy compositions are also disclosed.Type: GrantFiled: August 6, 2008Date of Patent: August 9, 2011Assignee: Air Products and Chemicals, Inc.Inventors: Gamini Ananda Vedage, Williams Rene Raymond, Maw Lin Foo
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Patent number: 7989553Abstract: Disclosed is a novel epoxy-amine composition modified a hydroxyalkyl urethane, which is obtained as a result of a reaction between a primary amine (C1) and a monocyclocarbonate (C2), wherein modifier (C) is represented by the following formula (1): wherein R1 is a residue of the primary amine, R2 and R3 are the same or different and are selected from the group consisting of H, alkyl, hydroxyalkyl, and n satisfies the following condition: n?2. Diluents, pigments and additives can be used. Doping with the hydroxyalkyl-urethane modifier imparts to the cured composition superior coating performance characteristics, such as pot-life/drying, strength-stress, bonding, appearance, resistance to abrasion and solvents, etc., in a well-balanced state.Type: GrantFiled: March 26, 2009Date of Patent: August 2, 2011Assignees: Nanotech Industries, Inc., Polymate, Ltd.Inventors: Olga Birukov, Oleg Figovsky, Alexander Leykin, Leonid Shapovalov
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Patent number: 7915378Abstract: A material for solid polymer electrolyte, made of a polyether polymer having a moisture content in the range of 400 to 5,000 ppm by weight. A formed solid polymer electrolyte, which is made by mixing the material for solid polymer electrolyte together with an electrolyte salt compound soluble in the polyether polymer, has good ionic conductivity and high mechanical strength. A polyether polymer having a moisture content not larger than 0.04% by weight and a toluene-insoluble content not larger than 5% by weight. This polyether polymer gives a formed solid polymer electrolyte having a smooth surface.Type: GrantFiled: October 16, 2007Date of Patent: March 29, 2011Inventors: Hideyuki Nishio, Hidenori Onishi, Paul-Andre Lavoie, Richard Laliberte
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Patent number: 7906562Abstract: An epoxy resin possessing one or more primary hydroxyl groups and one or more epoxy groups in one molecule is useful in a photo-curing method.Type: GrantFiled: December 21, 2007Date of Patent: March 15, 2011Assignee: Nippon Steel Chemicals Co., Ltd.Inventor: Kazuo Ishihara
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Publication number: 20110039982Abstract: Epoxy resins comprising a cis, trans-1,3- and -1,4-cyclohexanedimethylether moiety and processes for preparing the epoxy resins. The process of preparation of the epoxy resins comprises reacting (a) a mixture of a cis-1,3-cyclohexanedimethanol, a trans-1,3-cyclohexanedimethanol, a cis-1,4-cyclohexanedimethanol, and a trans-1,4-cyclohexanedimethanol, (b) an epihalohydrin, (c) a basic acting substance, (d) optionally, a solvent, (e) optionally, a catalyst, and/or (f) optionally, a dehydrating agent. The process may be a slurry epoxidation process, an anhydrous epoxidation process, or a Lewis acid catalyzed coupling and epoxidation process.Type: ApplicationFiled: May 4, 2009Publication date: February 17, 2011Inventors: Robert E. Hefner, JR., John W. Hull, JR., James W. Ringer, John N. Argyropoulos
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Patent number: 7847020Abstract: An isobutene polymer which has an average of at least 1.4 terminal 1,3-propanediol groups is described, as is a crosslinking product thereof. Suitable crosslinkers are difunctional or higher-functionality isocyanates or epoxy compounds having at least two epoxide groups. The crosslinking products exhibit high storage moduli even at elevated temperatures.Type: GrantFiled: August 28, 2006Date of Patent: December 7, 2010Assignee: BASF AktiengesellschaftInventors: Hans Peter Rath, Arno Lange, Helmut Mach, J. Richard Blackborow
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ALICYCLIC DIEPOXY COMPOUND, EPOXY RESIN COMPOSITION COMPRISING THE SAME, AND CURED ARTICLE THEREFROM
Publication number: 20100249341Abstract: Disclosed is an alicyclic diepoxy compound which gives a cured article suffering from no deterioration in properties even when used in hot and humid surroundings or used under such conditions as to give a strong acid, which is highly reactive upon curing, and which gives a cured article superior typically in thermal stability. Specifically, the alicyclic diepoxy compound includes a 3,4,3?,4?-diepoxybicyclohexyl compound represented by following Formula (1): wherein R1 to R18 each represent a hydrogen atom, a halogen atom, a hydrocarbon group which may have an oxygen atom or a halogen atom, or a substituted or unsubstituted alkoxy group, in which the alicyclic diepoxy compound contains isomers of the 3,4,3?,4?-diepoxybicyclohexyl compound in a content of less than 20% based on the total of the 3,4,3?,4?-diepoxybicyclohexyl compound and the isomers thereof in terms of peak area ratio as determined by gas chromatography.Type: ApplicationFiled: June 29, 2007Publication date: September 30, 2010Inventors: Atsushi Sato, Hideyuki Takai, Hisashi Maeshima, Kyuhei Kitao -
Publication number: 20100150510Abstract: The present invention provides a flexible optical waveguide in which at least one of a lower cladding layer, a core layer, and an upper cladding layer is composed of an epoxy film formed using an epoxy resin composition containing a polyglycidyl compound having a polyalkylene glycol chain(s) and at least two glycidyl groups or an epoxy film having a glass transition temperature (Tg) of 100° C. or lower, a process for its production, and an epoxy resin composition for flexible optical waveguides.Type: ApplicationFiled: October 30, 2007Publication date: June 17, 2010Inventors: Shimpei Sato, Kozo Tajiri, Yoko Matsui, Tomomi Makino
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Patent number: 7723464Abstract: Novel compositions of matter comprise certain derivatives of 9,9-dialkyl fluorene diamine (AFDA). The resultant compositions, whether compositions of matter or monomers that are subsequently incorporated into a polymer, are unique and useful in a variety of applications. Useful applications of AFDA-based material include heavy ion radiation shielding components and components of optical and electronic devices.Type: GrantFiled: February 13, 2007Date of Patent: May 25, 2010Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Donovan M. Delozier, Kent A. Watson, John W. Connell, Joseph G. Smith, Jr.
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Publication number: 20100117027Abstract: A polymerizable liquid crystal composition is provided that is excellent in UV curing characteristics in the air and is excellent in orientation homogeneity, and a polymer film as a selective reflection film is provided that is obtained by orienting and polymerizing the composition on a supporting substrate. The liquid crystal composition contains a compound (1), a compound (2), a compound (3), a compound selected from a group of compounds represented by the formulae (4) to (6), and a surfactant. In the following formulae Y1 to Y4 and Y6 are each alkylene, A2, A3, A41, A42, A51, A52 and A6 are each a cyclic group, Z2 to Z4 and Z6 are each a bonding group, P4 and P6 are each an integer of from 0 to 3, R2, R31 and R32 are each hydrogen, halogen or alkyl, and Q1 and Q2 are each a polymerizable group.Type: ApplicationFiled: November 6, 2009Publication date: May 13, 2010Inventors: Yoshiharu Hirai, Kazumi Hagihara