Contacting With Sulfur Or Phosphorus-containing Material Patents (Class 528/487)
  • Patent number: 5874524
    Abstract: Polymer powders which are redispersible in an aqueous medium are prepared by drying an aqueous polymer dispersion whose polymer particles dispersed in the aqueous medium have a positive or a negative electric surface charge, with the addition of a water-soluble polyelectrolyte as a drying assistant, the electric charge of the polyion being opposite to the electric surface charge of the disperse polymer particles.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: February 23, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Pakusch, Reinhold Dieing, Jurgen Tropsch
  • Patent number: 5866678
    Abstract: A method for the production of an absorbent resin having a very small residual monomer content either by adding to an absorbent resin powder a substance capable of reacting with the residual monomer in the absorbent resin powder thereby forming an absorbent resin composition having a water content in the range of 10 to 70% by weight and heat-treating the absorbent resin composition at a temperature in the range of 100.degree. to 200 .degree. C. while retaining the water content of the absorbent resin or by adding to an absorbent resin powder a substance capable of reacting with the residual monomer in the absorbent resin powder thereby forming an absorbent resin composition having a water content in the range of 25 to 55% by weight, heat-treating the absorbent resin composition at a temperature in the range of 120.degree. to 200 .degree. C.
    Type: Grant
    Filed: February 20, 1997
    Date of Patent: February 2, 1999
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Katsuhiro Kajikawa, Kinya Nagasuna, Yoshihiko Masuda
  • Patent number: 5844066
    Abstract: The present invention provides a process for the preparation of a lactic acid-based polyester having an excellent moldability, storage stability and biodegradability which has a less residual lactide left therein and is less susceptible to decomposition of lactic acid-based polyester and attachment of sublimed lactide to the molding apparatus, etc. at the devolatilization step and molding step after the polymerization reaction of lactic acid-based polyester. In the present invention, an organic chelating agent is added to a lactic acid-based polyester to deactivate the esterification catalyst used in the preparation of the lactic acid-based polyester, making it possible to inhibit the decomposition of lactic acid-based polyester at the devolatilizing process and molding process after polymerization reaction.
    Type: Grant
    Filed: September 10, 1996
    Date of Patent: December 1, 1998
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventor: Yasutoshi Kakizawa
  • Patent number: 5840831
    Abstract: A cured silicone powder inhibited from evolving unpleasant odors with the passage of time, and an efficient method for preparation of the cured silicone powder, in which the surface of the cured silicone powder is treated with an alkali, by dipping the cured silicone powder in an aqueous alkaline solution.
    Type: Grant
    Filed: August 13, 1997
    Date of Patent: November 24, 1998
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Tadashi Hamachi, Kazuo Kobayashi, Yoshitsugu Morita, Kiyotaka Sawa, Ryuji Tachibana
  • Patent number: 5834078
    Abstract: Poly(hydroxyaminoether) ammonium salts are prepared by contacting a poly(hydroxy amino ether) with a protonic acid or an alkyl halide in an amount and under reaction conditions sufficient to form a poly(hydroxy amino ether) ammonium salt having an oxygen transmission rate of less than about 0.5 cm.sup.3 -mil/100 in.sup.2 -atm(O.sub.2)-day.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: November 10, 1998
    Assignee: The Dow Chemical Company
    Inventors: Michael B. Cavitt, Jerry E. White, John M. Beckerdite, H. Craig Silvis
  • Patent number: 5830991
    Abstract: The invention provides an economical and efficient process for preparing a dimeric cyclic ester of an .alpha.-hydroxycarboxylic acid by depolymerizing a corresponding .alpha.-hydroxycarboxylic acid oligomer, which comprises the steps of (1) heating a mixture containing the .alpha.-hydroxycarboxylic acid oligomer and at least one high-boiling polar organic solvent having a boiling point within a range of 230.degree.-450.degree. C. to a temperature, at which the depolymerization of the oligomer takes place, under atmospheric pressure or reduced pressure, (2) dissolving the oligomer in the solvent until a residual rate of a melt phase of the oligomer reaches 0.5 or lower, (3) further continuing the heating at the temperature, at which the depolymerization of the oligomer takes place, to depolymerize the oligomer, (4) distilling out the dimeric cyclic ester formed together with the high-boiling polar organic solvent, and (5) recovering the dimeric cyclic ester from the distillate.
    Type: Grant
    Filed: January 23, 1997
    Date of Patent: November 3, 1998
    Assignee: Kureha Kagaku Kagyo KK
    Inventors: Zenya Shiiki, Yukichika Kawakami
  • Patent number: 5824769
    Abstract: A process is described for removing heteropoly compounds from heteropoly compound-contaminated polyethers, polyesters and/or polyether esters, which comprises admixing the polymer or a solution of the same with a compound which contains at least one heteroatom which is selected from the group consisting of central atoms of heteropolyacids, is non-protic and is of a polarity so low that its addition leads to the heteropoly compounds separating out in a separate phase, and separating off the precipitated heteropoly compound phase. The remaining polymer phase is preferably further purified using a solid adsorbent.
    Type: Grant
    Filed: August 4, 1997
    Date of Patent: October 20, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Jurgen Weyer, Rolf Fischer
  • Patent number: 5807966
    Abstract: An increase in the molecular weight of virgin polycondensates and polycondensate recyclates can be achieved by heating to above the melting point or glass transition temperature and by the addition of diphosphonite.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: September 15, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rudolf Pfaendner, Heinz Herbst, Kurt Hoffmann
  • Patent number: 5807962
    Abstract: A sulfonated dicarboxylic acid and a diaromatic carbonate are reacted by a solution process to form a sulfonated aromatic diester such as diphenyl sodium 5-sulfoisophthalate. The sulfonated aromatic diester is reacted with an aromatic polymer precursor mixture such as bisphenol A and diphenyl carbonate, polymer or combination thereof, at a temperature above the melting point of the polymer or a member of the aromatic polymer precursor to form a randomly positioned sulfonated aromatic moiety in a polymer chain of a thermoplastic non-crosslinked aromatic polymer such as a linear polycarbonate.
    Type: Grant
    Filed: August 20, 1997
    Date of Patent: September 15, 1998
    Assignee: The Dow Chemical Company
    Inventors: Ray E. Drumright, Michael J. Mullins, William B. Marshall, Edvins L. Daiga
  • Patent number: 5804100
    Abstract: Deaggregated substituted and unsubstituted polyparaphenylenes, polyparaphenylevevinyles, polyanilines, polyazines, polythiophenes, poly-p-phenylene sulfides, polyfuranes, polypyrroles, polyselenophene, polyacetylenes formed from soluble precursors and combinations thereof and copolymers thereof and methods of fabrication are described. The deaggregated polymer molecules when subsequently doped show higher electrical conductivity. Agents such as lithium chloride, m-cresol and nonylphenol are used to deaggregate the polymer molecules. The deaggregating agents can be added prior to or during doping the molecules.
    Type: Grant
    Filed: January 9, 1995
    Date of Patent: September 8, 1998
    Assignee: International Business Machines Corporation
    Inventors: Marie Angelopoulos, Bruce K. Furman
  • Patent number: 5767231
    Abstract: A method for lowering the residual monomer content of non-vitrified processing aids for thermoplastic polymers involves subjecting an emulsion polymerizate containing methylmethacrylate and, optionally, up to 50% by weight of a comonomer to a post-catalysis step to reduce the residual monomer content followed by a spray-drying step where the residual monomer content is further reduced. The spray-drying step is performed at an exit temperature which is either above the boiling point of methylmethacrylate or if an optional comonomer is present which has a higher boiling point than methacrylate, at a temperature above the boiling point of the comonomer. The resulting product which is suitable for use as a non-vitrified processing aid has a residual monomer content of 100 ppm or less. The processing aid can be used with thermoplastics to form containers, e.g., beverage bottles of PVC, which would not adversely affect odor or taste of the contained food product.
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: June 16, 1998
    Assignee: Agomer Gesellschaft Mit Beschrankter Haftung
    Inventors: Volker Schull, Detlef Arnoldi
  • Patent number: 5760172
    Abstract: A process for preparing a styrenic resin is herein disclosed which comprises the step of volatilizing-extruding a styrenic polymer (SPS) powder having a syndiotactic configuration in the presence of water, an alcohol or an antioxidant by the use of an extruder to obtain pellets. According to this process, the operation of volatilization-extrusion is done in the presence of water, the alcohol or the antioxidant to stably and efficiently prepare the SPS pellets in which yellowing is inhibited, and the operation of the volatilization-extrusion is carried out in the presence of water to stably and efficiently prepare the SPS pellets containing a less amount of a remaining volatile component such as an unreacted monomer.
    Type: Grant
    Filed: January 27, 1997
    Date of Patent: June 2, 1998
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Tsutomu Onodera, Kazuyoshi Fukada, Takashi Saeki
  • Patent number: 5756657
    Abstract: A method for treating a plastic, such as polyethylene or polypropylene, to remove at least a portion of at least one contaminant includes combining the plastic with a supercritical medium, such as carbon dioxide or sulfur hexafluoride, whereby at least a portion of the contaminant dissolves in the supercritical medium. Alternatively, the plastic can be combined with a suitable liquid medium, such as carbon dioxide or liquid sulfur hexafluoride. At least a portion of the medium, containing the dissolved contaminant, is separated from the plastic, thereby removing at least a portion of the contaminant from the plastic.
    Type: Grant
    Filed: June 26, 1996
    Date of Patent: May 26, 1998
    Assignee: University of Massachusetts Lowell
    Inventors: Samuel P. Sawan, W. Dale Spall, Abdelhafid Talhi
  • Patent number: 5753753
    Abstract: This invention relates to an improved process for producing a vinyl alcohol containing polymer having a narrow particle size without substantial reactor fouling. The process for producing the vinyl alcohol containing polymer involves hydrolyzing a vinyl ester containing polymer, e.g., a polymer containing polymerized vinyl alkanoate units in the presence of an alcoholic medium and a hydrolysis catalyst in the presence of an alcoholic medium having finely divided, inert material such as an alkali metal carbonate dispersed therein. The finely divided inert material acts as nucleating sites for the polyvinyl alcohol as it precipitates from the solution during hydrolysis.
    Type: Grant
    Filed: February 19, 1997
    Date of Patent: May 19, 1998
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Kien Van Phung, Dennis Sagl
  • Patent number: 5739266
    Abstract: The present invention relates to a process for modifying a polyethylene in an extruder by bringing the polyethylene into contact with oxygen or a gas mixture containing oxygen in the extruder, optionally in the presence of a relatively small quantity or preferably in the absence of short-term antioxidant agent. The polyethylene is then treated thermomechanically in the molten state in the extruder supplying a relatively high specific mechanical energy, the thermomechanical treatment is completed when the value of the loss tangent of the polyethylene characterizing its viscoelastic state decreases in a desired proportion. The polymer thus treated is particularly suitable for being transformed by blown extrusion into a film having a considerably increased bubble stability.
    Type: Grant
    Filed: August 16, 1995
    Date of Patent: April 14, 1998
    Assignee: BP Chemicals Limited
    Inventor: Alain Piana
  • Patent number: 5723570
    Abstract: A wholly aromatic polyamide fiber containing above about 600 ppm (about 0.2 mole percent) of sulfonate in the polymer main chain is provided. The sulfonate is represented by the general formulas (III) or (IV): ##STR1## where M is hydrogen, a metal cation, or a quaternary ammonium ion. The fiber exhibits excellent dyeability and can be cation-dyed without the use of a dye carrier.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: March 3, 1998
    Assignee: Industrial Technology Research Institute
    Inventors: Jen-Chang Yang, Jin-Chyueh Lin, Lien-Tai Chen
  • Patent number: 5717057
    Abstract: A method for manufacturing polycarbonate in which an aromatic dihydroxy compound and a carbonic acid diester can be effectively subjected to melt polycondensation using a small amount of a catalyst, making it possible to manufacture polycarbonate having outstanding color matching, outstanding thermal stability, color-matching stability, etc., during molding, and outstanding water resistance is characterized in that when an aromatic dihydroxy compound and a carbonic acid diester are subjected to melt polycondensation in the presence of a catalyst, the catalyst is dissolved or dispersed as a catalyst solution, this catalyst solution is added to the melt polycondensation reaction system, and the aromatic dihydroxy compound and carbonic acid diester are subjected to melt polycondensation.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: February 10, 1998
    Assignee: General Electric Company
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai
  • Patent number: 5710239
    Abstract: The present invention relates to a sulfonated water-soluble melamine-formaldehyde resin, to a method of manufacturing the resin, and to insulation products prepared using the resin. The resin is particularly useful for making thermal insulation having low moisture adsorption, high tensile strength and low formaldehyde emissions.
    Type: Grant
    Filed: February 29, 1996
    Date of Patent: January 20, 1998
    Assignee: Georgia-Pacific Resins, Inc.
    Inventor: Kim K. Tutin
  • Patent number: 5708132
    Abstract: Nitrile rubber can be synthesized by copolymerizing acrylonitrile and 1,3-butadiene in an aqueous emulsion. After these monomers have been polymerized, it is, of course, necessary to recover the polymer from the aqueous emulsion.
    Type: Grant
    Filed: August 1, 1996
    Date of Patent: January 13, 1998
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Donald Charles Grimm
  • Patent number: 5703189
    Abstract: An saturated nitrile-conjugated diene copolymer obtained by copolymerizing acrylonitrile with butadiene in the presence of a free radical initiator and an alkylthiol compound as a molecular weight modifier. A part of the monomers is incorporated in a monomer charge before polymerization, and the remainder thereof is added in a polymerization mixture during polymerization. The alkylthiol compound has 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and further has a sulfur atom directly bound to at least one of the tertiary carbon atoms. The copolymer has a Mooney viscosity of 15 to 450 and a bound nitrile content of 10 to 60% by weight. The breadth (.DELTA.AN) of compositional distribution of the unsaturated nitrile in the copolymer is 3 to 20. The copolymer is used in combination with a sulfur-containing vulcanizer.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: December 30, 1997
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Suguru Tsuji, Yuichi Uchizono
  • Patent number: 5698666
    Abstract: A process for finishing latex to form a dry resin and the resulting product. The process includes coagulating a latex of a thermoplastic polymer at a temperature at or just above the agglomeration temperature of the resin, dewatering the resin slurry to form a resin cake, drying the resin cake using extrusion technology to form a resin melt and solidifying the resin melt to form the resin. Preferred processes of the invention also include finishing the resin, such as by pelletizing and/or grinding it. More preferred processes of the invention include collecting and neutralizing the aqueous liquid byproducts from the dewatering and drying steps of the process. One embodiment of the invention includes utilizing water to solidify the resin melt, pelletizing the resin and drying the pellets.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: December 16, 1997
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Gary Lee Burroway, Lance Walter Lewis, John Charles Ullemeyer, Robert Donald Mate
  • Patent number: 5698658
    Abstract: A linear polyamide having a weight average molecular weight above 200,000 is made by heating a lower molecular weight molten polyamide with thorough mixing at a temperature of about 265.degree.-300.degree. C. for at least 5 minutes while an inert gas is swept gently through the reactor, the increase of molecular weight of the polyamide being catalyzed by a particular phosphinic acid derivative.
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: December 16, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ramdas Dujari, Daniel Gregory Tynan
  • Patent number: 5696195
    Abstract: Perfluorinated polymers are dissolved in supercritical carbon dioxide and/or sulfur hexafluoride at elevated temperatures and pressures. The solutions are useful for making foams, spun-bonded or paper-like webs, or for purification of polymers.
    Type: Grant
    Filed: June 4, 1996
    Date of Patent: December 9, 1997
    Assignees: E. I. Du Pont de Nemours and Company, Johns Hopkins University
    Inventors: William Howard Tuminello, Mark A. McHugh, Cynthia Asli Mertdogan
  • Patent number: 5679724
    Abstract: An ink for ink jet printing includes an emulsifiable polymer resin and a pigment, and may be made by: (a) combining (1) an emulsion of an emulsifiable polymer resin in an anionic medium with (2) a pigment and a cationic surfactant; and (b) aggregating particles in the mixture of step (a) to a desired particle size, thereby producing a solution of aggregated particles. The particles can optionally be coalesced to alter the particle size of the particles.
    Type: Grant
    Filed: September 29, 1995
    Date of Patent: October 21, 1997
    Assignee: Xerox Corporation
    Inventors: Guerino G. Sacripante, Raj D. Patel, Marcel P. Breton, Michael A. Hopper, Grazyna E. Kmiecik-Lawrynowicz, Beng S. Ong
  • Patent number: 5679767
    Abstract: The invention is a purification process of an aliphatic polyester prepared in the presence of a catalyst from a hydroxycarboxylic acid or a cyclic ester of a hydroxycarboxylic acid, or a combination of an aliphatic polyhydric alcohol with an aliphatic polybasic acid, or a mixture of these compounds, comprising deactivating the catalyst while maintaining the aliphatic polyester in a molten or dissolved state, or insolubilizing and separating the catalyst and successively removing low molecular compounds; and can provide aliphatic polyester which has a low content of unreacted monomers and low molecular weight compounds and is excellent in heat resistance and weatherability.
    Type: Grant
    Filed: November 29, 1995
    Date of Patent: October 21, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hiroshi Suizu, Masatoshi Takagi, Masanobu Ajioka, Akihiro Yamaguchi
  • Patent number: 5674968
    Abstract: A sulfonated dicarboxylic acid and a diaromatic carbonate are reacted by a solution process to form a sulfonated aromatic diester such as dipbenyl sodium 5-sulfoisophthalate. The sulfonated aromatic diester is reacted with an aromatic polymer precursor mixture such as bisphenol A and diphenyl carbonate, polymer or combination thereof, at a temperature above the melting point of the polymer or a member of the aromatic polymer precursor to form a randomly positioned sulfonated aromatic moiety in a polymer chain of a thermoplastic non-crosslinked aromatic polymer such as a linear polycarbonate.
    Type: Grant
    Filed: August 25, 1995
    Date of Patent: October 7, 1997
    Assignee: The Dow Chemical Company
    Inventors: Ray E. Drumright, Michael J. Mullins, William B. Marshall, Edvins L. Daiga
  • Patent number: 5663250
    Abstract: Protected functional initiator initiated elastomer solutions are deprotected and optionally ionic impurities removed by contact with a molten component such as sodium bisulphate monohydrate. This allows deprotection and removal of metal contaminants such as the initiator or residue from hydrogenation catalysts without the introduction of significant amounts of additional water which cause emulsion formation. In accordance with this invention, better metal removal is achieved and the process of metal removal operates more smoothly because of the absence of emulsion formation. Separation of the molten component containing the extracted metal contaminants can easily be carried out by simple liquid-liquid phase separation on either a continuous or batch basis.
    Type: Grant
    Filed: May 16, 1996
    Date of Patent: September 2, 1997
    Assignee: Shell Oil Company
    Inventors: Michael Wayne Potter, William Charles Malven, Cary Alan Veith
  • Patent number: 5650470
    Abstract: Polycarbonate compositions are redistributed by melt equilibration using diethyldimethylammonium hydroxide as the redistribution catalyst. This catalyst affords an odorless polycarbonate product having a very low residual amine level.
    Type: Grant
    Filed: June 7, 1996
    Date of Patent: July 22, 1997
    Assignee: General Electric Company
    Inventors: Patrick Joseph McCloskey, Eric Thomas Gohr, Timothy Hans Lemmen
  • Patent number: 5637631
    Abstract: A process for preparing a degradable copolymer of aliphatic polyester comprising the steps of reacting two or more kinds of aliphatic polyester homopolymer in the presence of a catalyst in a reaction mixture containing an organic solvent, and a degradable copolymer of aliphatic polyester obtained by said preparation process. The copolymers exhibits high transparency in addition to excellent strength and elongation, can be processed into various molded articles and formed items such as films and filaments, and can provide heat resistance by heat treatment of said molded articles and formed items. The copolymer can be suitably utilized for processed articles such as a film, breathable film, sheet, textile, monofilament, multifilament, yarn, non-woven fabric, flat yarn, staple, crimped fiber, ribbed tape, split yarn, conjugate fiber, laminate, blow-bottle, sheet, stretched sheet, foam and net.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: June 10, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Ikumi Kitada, Chojiro Higuchi, Masanobu Ajioka, Akihiro Yamaguchi
  • Patent number: 5627260
    Abstract: Quaternized tertiary aminomethyl acrylamide polymer emulsions are treated by 1) adjusting the pH to about 3.6 to about 4.8, 2) adding a formaldehyde scavenger, 3) adjusting the water content of the aqueous phase to result in about 10-45 weight percent of quaternized aminomethylated acrylamide polymer and 4) heating the resultant emulsion at from about 40.degree. C. to about 80.degree. C. for about 3 to about 20 hours so as to render them more stable, capable of inversion in water independent of water temperature or pH of the medium flocculant and superior dewatering ability.
    Type: Grant
    Filed: February 12, 1993
    Date of Patent: May 6, 1997
    Assignee: Cytec Technology Corp.
    Inventors: Sun Y. Huang, Andrea Leone-Bay, Joseph M. Schmitt, Paul S. Waterman
  • Patent number: 5625018
    Abstract: A chloroprene rubber having a shade of white only slightly tinged with pale yellow and exhibiting good tackiness is prepared by an aqueous radical emulsion polymerization of chloroprene or a mixture comprised of chloroprene and a copolymerizable monomer, wherein the polymerization is effected by using an alkali metal salt of a disproportioned rosin acid as an emulsifier, and a water-soluble polymeric substance as a dispersion stabilizer which has a sulfonic acid group and/or sulfate ester groups, which group has been introduced by an addition polymerization procedure or by a procedure of a polymeric reaction following an addition polymerization.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: April 29, 1997
    Assignee: Tosoh Corporation
    Inventors: Yoshitaka Tsutsumi, Takashi Yamamoto, Takeshi Hironaka, Tadashi Hayashi
  • Patent number: 5624789
    Abstract: The present invention provides methods for producing top anti-reflective coating compositions having a very low level of metal ions, utilizing specially treated ion exchange resins. A method is also provided for producing semiconductor devices using such top anti-reflective coating compositions.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: April 29, 1997
    Assignee: Hoechst Celanese Corporation
    Inventors: M. Dalil Rahman, Dana L. Durham
  • Patent number: 5612398
    Abstract: The present invention provides polycarbonates stabilized against .gamma.-radiation and their use for the production of medical equipment.
    Type: Grant
    Filed: January 12, 1995
    Date of Patent: March 18, 1997
    Assignee: Bayer AG
    Inventors: Gerhard Fennhoff, Ralf Hufen, Klaus Kircher, Wolfgang Ebert
  • Patent number: 5606009
    Abstract: The present invention provides copolymerized copolyester-carbonates having improved flow and formability, in addition to excellent mechanical properties, heat resistance, transparency, and water resistance obtained by copolymerization of two or more aromatic dihydroxy compounds and a compound capable of reacting with those aromatic dihydroxy compounds to form carbonate linkages, characterized in that, of all the constituent repeating units derived from aromatic dihydroxy compounds, 2-40 mole % are derived from resorcin and/or substituted resorcins.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: February 25, 1997
    Assignee: General Electric Company
    Inventors: Takeshi Sakashita, Tomoaki Shimoda, Takashi Nagai
  • Patent number: 5594098
    Abstract: The present invention provides methods for producing water insoluble, aqueous alkali soluble novolak resins having a very low level of metal ions, utilizing treated ion exchange resins. A method is also provided for producing photoresist composition having a very low level of metal ions from such novolak resins and for producing semiconductor devices using such photoresist compositions.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: January 14, 1997
    Assignee: Hoechst Celanese Corporation
    Inventors: M. Dalil Rahman, Dana L. Durham
  • Patent number: 5587449
    Abstract: In the process for the preparation, with simultaneous end group stabilization, of polyacetal copolymers in a homogeneous phase and working up thereof, cyclic formaldehyde oligomers are copolymerized with cyclic acetals in the presence of an initiator in a polymerization reactor and immediately thereafter the initiator is deactivated by addition of basic substances, the unstable chain ends being degraded down to 0.01% to 1% in the presence of residual monomer, the product losing the majority of the residual monomer at the reactor outlet by letting down into a pelletizing device and the residual monomer which remains and the impurities dissolved in the product being removed by extraction with solvents and the product being pelletized, after drying and stabilization.
    Type: Grant
    Filed: August 31, 1995
    Date of Patent: December 24, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Dietrich Fleischer, Michael Hoffmockel, Karl-Friedrich Muck, Gunter Sextro
  • Patent number: 5580952
    Abstract: A process for producing a resin for the chromatographic extraction of metal ions is provided, the process involving:treating an acidic bidentate organic phosphonate metal complexing agent with an alcohol or ketone solvent containing an aqueous alkaline solution, thereby forming the corresponding salt of the phosphonate compound;mixing the bidentate organic phosphonate salt with an absorbent resin in an alcohol or ketone solvent containing an aqueous alkaline solution, thereby absorbing the phosphonate salt in the resin;washing the resin containing bidentate complexing agent with an aqueous alcohol or ketone solution; anddrying the washed resin, wherein the process provides improved chromatographic extraction of metal ions.
    Type: Grant
    Filed: January 9, 1995
    Date of Patent: December 3, 1996
    Assignee: Japan Atomic Energy Research Institute
    Inventors: Johkun Akatsu, Takaumi Kimura
  • Patent number: 5580949
    Abstract: The present invention provides methods for producing water insoluble, aqueous alkali soluble novolak resins having a very low level of metal ions, utilizing treated ion exchange resins. A method is also provided for producing photoresist composition having a very low level of metal ions from such novolak resins and for producing semiconductor devices using such photoresist compositions.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: December 3, 1996
    Assignee: Hoechst Celanese Corporation
    Inventors: M. Dalil Rahman, Dana L. Durham
  • Patent number: 5569740
    Abstract: There are provided a deproteinized natural rubber latex which comprises a purified product of proteolytically treated natural rubber latex and contains fine particles of natural rubber latex, a deproteinized natural rubber which comprises a dehydrated product of the deproteinized natural rubber latex, and a process for the production of deproteinized natural rubber latex which comprises subjecting a latex solution prepared by (1) adding water and/or a surfactant to a natural rubber latex and then proteolytically treating the resulting latex solution or (2) proteolytically treating a natural rubber latex and then adding water and/or a surfactant to the treated natural rubber latex, to purification using a rotary plate membrane separation apparatus.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: October 29, 1996
    Assignees: Nitto Denko Corporation, Kao Corporation, Sumitomo Rubber Industries, Ltd.
    Inventors: Yasuyuki Tanaka, Kazuhiko Shibata, Kenichi Ikeda, Yuji Nishida, Masaharu Hayashi, Shinichi Nakade, Akihito Kuga, Eiji Kanamaru
  • Patent number: 5567784
    Abstract: The production of diene rubbers polymerized by means of Nd catalysts and having reduced cold flow and low intrinsic odor is effected by the polymerization of diolefines adiabatically at temperatures of -20.degree. to 150.degree. C. in the presence of inert organic solvents and in the presence of metallo-organic mixed catalysts based on neodymium carboxylate, by subsequently depressurizing the reaction mixture obtained in this manner by reducing the pressure, and by treating the reaction mixture thereafter with disulphur dichloride, sulphur dichloride and/or thionyl chloride.
    Type: Grant
    Filed: September 20, 1995
    Date of Patent: October 22, 1996
    Assignee: Bayer AG
    Inventors: Wolfgang Wieder, Dieter Kuhlmann, Wolfgang Nentwig
  • Patent number: 5567802
    Abstract: Polycarbonate compositions are redistributed by melt equilibration using as the redistribution catalyst a tetraorganophosphonium hydroxide, preferably a tetra-(C.sub.1-6 alkyl)phosphonium hydroxide. Such catalysts have numerous advantages including greater redistribution efficiency, decreased color in the redistributed product and the capability of employment in the anhydrous state.
    Type: Grant
    Filed: November 20, 1995
    Date of Patent: October 22, 1996
    Assignee: General Electric Company
    Inventor: Patrick J. McCloskey
  • Patent number: 5548060
    Abstract: A method for the alkylsulfonation of polymeric and cyclic trimer phosphazenes that includes reacting the phosphazene with a sultone. This method can be used to prepare sulfonated phosphazenes that are useful as biomedical materials, membranes, reversibly cross-linkable polymers, surfactants, and polyelectrolytes.
    Type: Grant
    Filed: August 8, 1994
    Date of Patent: August 20, 1996
    Assignee: Penn State Research Foundation, Inc.
    Inventors: Harry R. Allcock, Eric H. Klingenberg, Mark P. Weller
  • Patent number: 5541284
    Abstract: The subject invention relates to method for processing crude polyoxymethylene in which the isolation of unstable components from crude polyoxymethylene, such as residual monomers which are at least partly in the form of cyclic formaldehyde derivatives, is effected by treatment of the crude polyoxymethylene with an inert gaseous medium. The method of the invention is characterized in that the gaseous medium contains at least 10 volume % of water vapor, and less than 0.1 volume % of a volatile base, and/or less than 1 volume % of a volatile solvent. In an alternative variant method, the gaseous medium contains at least 10 volume % of water vapor and the treatment occurs at a temperature between 114.degree. C and the softening temperature of the crude polyoxymethylene and at a pressure of less 1.2 .multidot.10.sup.5 Pa.
    Type: Grant
    Filed: March 20, 1995
    Date of Patent: July 30, 1996
    Assignee: Dequssa Aktiengesellschaft
    Inventors: Detlef Arnoldi, Udo Gropp, Edwin Nun
  • Patent number: 5525638
    Abstract: Described is a continuous process for removing polyphosphoric acid from a polybenzazole dope filament, which comprises: (a) contacting the dope filament with water or a mixture of water and polyphosphoric acid under conditions sufficient to reduce the phosphorous content of the filament to less than about 10,000 ppm by weight; and then (b) contacting the dope filament with an aqueous solution of an inorganic base under conditions sufficient to convert at least about 50 percent of the polyphosphoric acid groups present in the filament to a salt of the base and the acid. It has been discovered that contacting the dope filament with a solution of a base after washing the filament to remove most of the residual phosphorous advantageously leads to an improvement in the initial tensile strength of the filament, as well as improved retention of tensile strength and/or molecular weight (of the polybenzazole polymer) following exposure to light and/or high temperatures.
    Type: Grant
    Filed: July 12, 1995
    Date of Patent: June 11, 1996
    Assignee: The Dow Chemical Company
    Inventors: Ashish Sen, Yoshihiko Teramoto
  • Patent number: 5521231
    Abstract: A process for producing a thermoplastic polymer powder which comprises adding a polymer (B) and/or an inorganic compound (C) to a coagulation slurry or a powder of a thermoplastic polymer (A) obtained from emulsion polymerization and having a glass transition temperature Tg defined by the following equation (1), in an amount of 0.1-10 parts by weight to 100 parts by weight of the thermoplastic polymer (A), compacting the thermoplastic polymer (A) at a temperature in a range of (Tg-30) to (Tg+50).degree. C., and comminuting it:Tg=W.sub.1 .times.Tg.sub.1 +W.sub.2 .times.Tg.sub.2 + . . . +W.sub.n .times.Tg.sub.n ( 1)wherein n is the number of the monomers forming the thermoplastic polymer (A); W.sub.1, W.sub.2, . . . W.sub.n each represents weight fraction of each monomer i (i=1, 2, . . . n) in the polymer (A); and Tg.sub.1, Tg.sub.2, . . . Tg.sub.n each represents the glass transition temperature of the polymer composed of each monomer i.
    Type: Grant
    Filed: February 24, 1995
    Date of Patent: May 28, 1996
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Fumio Suzuki, Haruki Sato, Masaki Sugihara, Wataru Hadano
  • Patent number: 5514772
    Abstract: A method for producing a powdery and granular polymer by two coagulation steps comprising coagulating a latex of the polymer, the latex containing a sulfuric acid ester series and/or sulfonic acid series anionic surface active agents, with an acid to an amount of the polymer of 40 to 80 wt. % at a first coagulation step, and then bringing coagulation to completion with an acid or salt at a second coagulation step. According to the present invention, a powdery and granular polymer having a sharp particle size distribution and a high bulk specific gravity can be obtained.
    Type: Grant
    Filed: February 16, 1994
    Date of Patent: May 7, 1996
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Fumio Suzuki, Haruki Sato, Masaki Sugihara, Wataru Hadano
  • Patent number: 5510457
    Abstract: A method for preparing a processable polyisothianaphthene polymer includes steps of dissolving an isothianaphthene monomer in a solvent and introducing therein an initiator to initiate a polymerization reaction to produce a precursor of poly(dihydroisothianaphthene), dissolving thoroughly the precursor of poly(dihydroisothianaphthene) in the solvent in an appropriate ratio to obtain a poly(dihydroisothianaphthene) solution, proceeding a dehydrogenation reaction for the poly(dihydroisothianaphthene) solution by introducing a dehydrogenation agent to obtain a polyisothianaphthene microgel solution, and terminating the dehydrogenation reaction by introducing an inhibitor. This invention offers a simple, feasible, and economical way to prepare a large-area film with uniform film thickness, excellent stability, and good electrochromic, conducting, and mechanical properties.
    Type: Grant
    Filed: April 24, 1995
    Date of Patent: April 23, 1996
    Assignee: National Science Council
    Inventors: Show-An Chen, Chin-Chang Lee
  • Patent number: 5510399
    Abstract: A process for the chemical agglomeration of a finely dispersed, aqueous synthetic rubber emulsion which involves:contacting the finely dispersed, aqueous synthetic rubber emulsion with an agglomeration agent of a water-soluble or water-dispersible copolymer, wherein the copolymer contains10 to 90% by weight of one or more hydrophobic, water-insoluble, olefinically unsaturated monomers; and90 to 10% by weight of one or more hydrophilic, water-soluble and salt-forming, olefinically unsaturated monomers;at a temperature and concentration sufficient to cause agglomeration of the finely dispersed, aqueous synthetic rubber emulsion,and the use of the thus obtained high solids synthetic rubber emulsion in the production of foamed shaped articles and foamed latices is provided.
    Type: Grant
    Filed: November 18, 1994
    Date of Patent: April 23, 1996
    Assignee: Huels Aktiengesellschaft
    Inventor: Thomas Sauer
  • Patent number: 5508376
    Abstract: Alcohol-soluble aromatic heterocyclic polymers and copolymers having repeating units of the formulae I or II: ##STR1## wherein Q is a benzobisazole of the formula: ##STR2## wherein X is --O-- or --S--; wherein x has a value of 0.0 to 1.00 and y has a value of 0.05 to 1.00, and R is selected from the group consisting of: ##STR3## and R' is selected from the group consisting of alkyl having 1 to 5 carbon atoms, alkaryl having 7 to 12 carbon atoms, aralkyl having 7 to 12 carbon atoms and substituted aromatic having 1 to 3 substituent groups. The alcohol-soluble polymers and copolymers may be used for fabricating organic/inorganic hybrid composites with metal alkoxides M(OZ).sub.v, wherein M is Si, Ti, Al or the like and Z is a lower alkyl group. These polymers and copolymers can also be used to coat materials or substrates which are susceptible to attack by highly corrosive acids.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: April 16, 1996
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Thuy D. Dang, Jom P. Chen, Fred E. Arnold
  • Patent number: 5504122
    Abstract: Dimethyl terephthalate is recovered from polymer mixtures containing polymers of terephthalic acid and glycol and a chloride polymer, by adding base to neutralize the hydrochloric acid formed by the degradation of the chloride polymer.
    Type: Grant
    Filed: April 11, 1995
    Date of Patent: April 2, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Robert E. Michel, George M. Williamson