Steam Stripping Or Steam Distilling Patents (Class 528/500)
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Patent number: 12194398Abstract: The present invention is concerned with a screening assembly comprising a separating device connected to a conduit for an effluent stream comprising a polymer and a mixture of hydrocarbons, wherein the separating device is configured to separate the effluent stream into a polymer-rich stream and a polymer-lean vapor stream, wherein the first separation device comprises an inlet, a first outlet for withdrawing a polymer-rich stream, and a second outlet for withdrawing a polymer-lean vapor stream, a screening device connected to the separating device via a conduit for the polymer-lean vapor stream, wherein the screening device comprises a first inlet connected to the conduit for the polymer-lean vapor stream, a first outlet for withdrawing a cleaned vapor stream, a second outlet for withdrawing a polymer-comprising condensed vapor stream, and at least one second inlet for introducing a condensed vapor stream.Type: GrantFiled: August 5, 2021Date of Patent: January 14, 2025Assignee: BOREALIS AGInventors: Henry Sleijster, Mohammad Al-Haj Ali, Mubashar Sattar, Noureddine Ajellal, Charlotta Weber
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Patent number: 12129318Abstract: The present invention relates to a method for preparing a vinyl chloride-based polymer, including: bulk polymerizing a vinyl chloride-based monomer in a polymerization reactor to prepare a vinyl chloride-based polymer; and adding water and vapor to the polymerization reactor, and heating to remove an unreacted vinyl chloride-based monomer, wherein an addition amount of the water is 0.500 to 5.000 parts by weight based on 100 parts by weight of the vinyl chloride-based polymer.Type: GrantFiled: September 14, 2021Date of Patent: October 29, 2024Assignee: LG CHEM, LTD.Inventors: Kun Ji Kim, Seong Yong Ahn, Heung Kwon Bae, Se Woong Lee, Dae Woo Lee, Hyun Kyou Ha
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Patent number: 10988555Abstract: The present invention is directed to a process for separating an olefin copolymer from volatile gases using a flash separator. The flash separator can be used with a solution or high pressure process. The mass transport of volatile gases from the viscous polymer melt is increased.Type: GrantFiled: September 18, 2017Date of Patent: April 27, 2021Assignee: BOREALIS AGInventors: Vasileios Kanellopoulos, Mohammad Al-Haj Ali, Apostolos Krallis
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Patent number: 10968406Abstract: The present invention relates to an apparatus for the hydroconversion of heavy oil products (the fresh load). Said apparatus comprises: a slurry bubble column hydroconversion reactor, which comprises a feed line in which the fresh load and the recirculated slurry phase are conveyed, an inlet line for a hydrogenating stream and an outlet for a reaction effluent through an outlet nozzle; a stripping column at high pressure and high temperature placed downstream of the reactor and directly connected to the reactor head through a pipeline in which the reaction effluent flows; said column having an inlet line for a stripping gas, an inlet for the reactor effluent, a head outlet for steam and an outlet for the slurry phase; lines and means for recirculating the slurry leaving the stripping column; lines and means for taking a drain stream, which has the function of preventing the accumulation of solids in the reactor.Type: GrantFiled: October 26, 2017Date of Patent: April 6, 2021Assignee: ENI S.P.A.Inventors: Mario Molinari, Susi Bonomi
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Patent number: 10934371Abstract: A process of stripping a dispersion of organic extender particles with volatile organic compounds and a method of reducing volatile organic compounds.Type: GrantFiled: December 22, 2016Date of Patent: March 2, 2021Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Zhen Qian, Jianming Xu, Alvin M. Maurice, Daoshu Lin, Yaguang Zhao, Jiayuan Yang, Han Lv
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Patent number: 10227420Abstract: A method for preparation of decontaminated natural rubber is provided. The method is characterized in that it comprises a decontamination step in which wet natural rubber coagulum passes through a system comprising an extruder and a filter installed at the extruder outlet, the extruder comprising an axially symmetrical grooved sheath comprising in its thickness grooves opening on the inner surface of the sheath.Type: GrantFiled: April 8, 2016Date of Patent: March 12, 2019Assignee: COMPAGNIE GENERALE DES ESTABLISSEMENTS MICHELINInventors: Jérôme Dussillols, Jean-Luc Merceron
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Patent number: 9261801Abstract: The present embodiments disclose processes for preparing a polyester latex containing an amount of residual organic solvent which is less than 100 ppm by weight of the total weight of the polyester latex.Type: GrantFiled: April 4, 2014Date of Patent: February 16, 2016Assignee: XEROX CORPORATIONInventors: Yu Liu, Frank Ping-Hay Lee, Michael D'Amato, Yulin Wang, David Borbely, Harry Latchman, John Abate, Ivan Uschak, Rashid Mahmood, Ke Zhou, Marko Saban, Biritawit Asfaw
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Patent number: 9090746Abstract: A process for the removal of solvent from a polymeric solution including at least one elastomeric polymer. The polymeric solution is subjected to a stripping step by means of water vapor, in the presence of a dispersant system including: from 0.005% by weight to 1% by weight, with respect to the total weight of the dry elastomeric polymer, of at least one lamellar material; from 0.0005% by weight to 1% by weight, with respect to the total weight of the dry elastomeric polymer, of at least one cationic surfactant.Type: GrantFiled: November 23, 2012Date of Patent: July 28, 2015Assignee: VERSALIS S.P.A.Inventors: Maria Parisi, Piero Maestri
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Patent number: 8816045Abstract: The present invention relates to a method of removing volatile organic compounds (VOCs) from a latex using a membrane.Type: GrantFiled: March 7, 2013Date of Patent: August 26, 2014Assignees: Dow Global Technologies LLC, Regents of the University of MinnesotaInventors: Timothy C. Frank, Edward L. Cussler
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Patent number: 8691937Abstract: A method of preparing a low odor polymer latex composition includes the step of polymerizing a monovinylidene monomer, such as styrene, and a conjugated diene, such as butadiene, in the presence of a linear alkyl thiol chain transfer agent. The resulting polymer latex is treated with an oxidizing agent to oxidize residual chain transfer agent to volatile decomposition products that are then removed by steam stripping.Type: GrantFiled: December 16, 2010Date of Patent: April 8, 2014Assignee: Styron Europe GmbHInventors: Bernard Fouchet, Gerold Lohmueller, Patric Eckerle
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Patent number: 8557949Abstract: Process for the production of di- and poly(diamino diphenyl methane) comprising the steps of (a) reacting aniline and formaldehyde in the presence of an acid catalyst to produce a reaction mixture containing di- and polyamines; (b) neutralizing the reaction mixture containing di- and polyamines; (c) separating the neutralized reaction mixture into an organic phase containing di- and polyamines and an aqueous phase; (d) further treating the organic phase separated off in step (c) by (d1) washing with water followed by (d2) separating the washed mixture into an organic phase and an aqueous phase and (d3) further fractionation of the organic phase to produce purified di- and polyamines on the one hand and aniline/water on the other hand; (e) further treating the aqueous phase separated off in step (c) by (e1) washing with aniline followed by (e2) separating the washed mixture into an aqueous phase and an organic phase and (e3) further treatment of the aqueous phase to remove the aniline thereby leaving an effluType: GrantFiled: August 28, 2008Date of Patent: October 15, 2013Assignee: Huntsman International LLCInventors: Robert Carr, Johannes Lodewijk Koole, Willem Van Der Borden
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Patent number: 8530618Abstract: Process for recovering a polymer by injection of steam, and optionally liquid water, into a solution of this polymer comprising a polar aprotic organic solvent (PAOS) that has an azeotrope with water and an apolar organic compound that is miscible with the PAOS and immiscible with water and that acts as a phase separation agent (PSA), the boiling point of which is below that of the water/PAOS azeotrope, the amount of steam injected being sufficient to give rise to the substantial removal of the PSA via stripping and that of the PAOS via azeotropic distillation, and the total amount of water being sufficient to give rise to the precipitation of the polymer, this process being characterized in that the polymer solution also comprises an alcohol, at least during the precipitation of the polymer.Type: GrantFiled: September 18, 2008Date of Patent: September 10, 2013Assignee: SolvayInventors: Jean-Christophe Lepers, Denis Geets, Jean-Raphael Caille
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Patent number: 8507643Abstract: A composition comprising glycerol and at least one cyclic oligomer of glycerol, a process for obtaining the composition, and its use in the manufacture of dichloropropanol and of derived products such as epichlorohydrin and epoxy resins.Type: GrantFiled: March 31, 2009Date of Patent: August 13, 2013Assignee: Solvay S.A.Inventors: Patrick Gilbeau, Bruno Jestin
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Patent number: 8497326Abstract: Disclosed are ionomer compositions neutralized by a combination of cesium and potassium that have antistatic properties. Also disclosed are articles, including laminates and monolayer or multilayer structures comprising such compositions to which neither powders nor dusts easily adhere electrostatically.Type: GrantFiled: September 9, 2008Date of Patent: July 30, 2013Assignee: E I du Pont de Nemours and CompanyInventors: Kazuyuki Nakata, David J. Walsh
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Patent number: 8481675Abstract: A process for recycling a polymer blend necessarily containing PLA, comprising grinding, compacting, dissolving in a solvent of PLA, removing the undissolved contamining polymers, alcoholysis depolymerisation reaction and purification steps.Type: GrantFiled: March 31, 2010Date of Patent: July 9, 2013Assignee: Galactic S.A.Inventors: Philippe Coszach, Jean-Christophe Bogaert, Jonathan Willocq
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Patent number: 8431677Abstract: Method for purifying a conventional polymer stream (PE, PP, PET, PVC, etc.) contaminated with not more than 50% PLA, comprising steps for the suspension of the polymer with solubilisation of the PLA fraction and the recovery of the purified polymer after separation.Type: GrantFiled: July 14, 2010Date of Patent: April 30, 2013Assignee: Galactic S. A.Inventors: Philippe Coszach, Jonathan Willocq
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Patent number: 8420702Abstract: Process for recycling a fiber reinforced polymer article, according to which the article, eventually cut in fragments, is dissolved in a solvent capable of dissolving the polymer but not the fibers and which is susceptible of forming an azeotrope with water, forming a solution; the fibers are recovered from the solution; the fibers are washed with solvent by putting them in the form of a slurry in the solvent and by agitating the slurry and/or by making the solvent circulate through it; the washed fibers are recovered from the slurry; and the recovered fibers are submitted to a stripping with steam in order to substantially remove the solvent.Type: GrantFiled: May 7, 2009Date of Patent: April 16, 2013Assignee: Solvay S.A.Inventors: Jacques Van Weynbergh, Stephane Noel
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Patent number: 8344099Abstract: A method for treating polymer particles with steam in a steaming vessel downstream a polymerization process, the method comprising contacting polymer particles with a counter-current flow of steam, wherein the flow rate of steam entering said steaming vessel is continuously maintained proportional to the production rate of said polymer in said polymerization process and to the gradient between the temperature (Tout) of the polymer exiting said steaming vessel and the temperature (Tin) of the polymer entering said steaming vessel.Type: GrantFiled: December 23, 2009Date of Patent: January 1, 2013Assignee: Basell Poliolefine Italia s.r.l.Inventors: Giorgio Ballarini, Antonio Mileo, Luca Soffritti, Enrico Soffritti, legal representative
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Patent number: 8338563Abstract: Method for purifying a solution of at least one plastic in a solvent, the said solution comprising insolubles, whereby the solution is purified using a centrifugal settler.Type: GrantFiled: November 15, 2005Date of Patent: December 25, 2012Assignee: Solvay (Societe Anonyme)Inventor: Bernard Vandenhende
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Patent number: 8334362Abstract: An apparatus and method for determining the standardized melt elasticity (sME) force of a thermoplastic polymer needed to stretch a strand of melted polymer at a speed about thirty three times faster than the speed of strand formation from a body of melted polymer under constant stress from an unencumbered dead weighted piston.Type: GrantFiled: November 18, 2009Date of Patent: December 18, 2012Assignee: Dow Global Technologies LLCInventors: Mark D. Alpeter, Marc A. Mangnus, Charles M. Cheatham, Marinus G. Nieuwenhuize, Jack M. Potter, Jr.
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Patent number: 8252892Abstract: A process for obtaining an elastomer in solid phase from its polymer solution which comprises: (a) optionally pre-concentrating the polymer solution coming from the production system by a flash process; (b) subjecting the polymer solution to a concentrating stripping operation by water vapor in a mixing device comprising internal moveable mixing parts which transfer minimal mechanical energy to the solution in the form of friction heat; and (c) subjecting the concentrated polymer phase coming from (b) to devolatilization by mechanical energy and/or vapor flow to remove residual solvent.Type: GrantFiled: November 5, 2009Date of Patent: August 28, 2012Assignee: Polimeri Europa S.p.A.Inventors: Fabio Montanari, Federica Mainardi, Gabriele Veneri
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Patent number: 8207291Abstract: Process for devolatilization of a polymer of an aromatic alkylene, such as styrene and, in particular, an improved process using water as a stripping agent (i) in which the total amount of water to be disposed of can be reduced, (ii) which allows at least a portion of the water to be recycled as stripping agent, reducing make-up requirements for the stripping agent, and (iii) which allows at least a portion of the aromatic alkylene monomer in the water to be recycled to the polymerization process (via the devolatilization steps) rather than being disposed.Type: GrantFiled: June 3, 2008Date of Patent: June 26, 2012Assignee: Ineos Europe LimitedInventor: Jean-Marc Galewski
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Patent number: 8143371Abstract: This invention relates to a process for preparing polytrimethylene ether glycols or copolymers thereof having a number-average molecular weight of at least about 250 g/mole by a polycondensation reaction using at least one acid catalyst.Type: GrantFiled: October 31, 2008Date of Patent: March 27, 2012Assignee: E I du Pont de Nemours and CompanyInventors: Mark Andrew Harmer, Christian Hoffmann, Scott Christopher Jackson, Edward R. Murphy, Rupert Spence
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Patent number: 8058389Abstract: Brominated polybutadiene polymers are recovered from a bromination reaction solution by forming the solution into droplets, thermally stripping the solvent from the droplets, and then washing the resulting particles. The washed particles are then recovered from the washing liquid. The droplets can be dispersed into a gaseous medium such as air and then transferred into a nonsolvent liquid for washing, or can be formed directly into the nonsolvent liquid. The process forms a particulate polymer material that is easily filterable and has low levels of volatile impurities and inorganic salts. Brominated polybutadiene polymers recovered in this manner are often very thermally stable.Type: GrantFiled: June 26, 2008Date of Patent: November 15, 2011Assignee: Dow Global Technologies LLC.Inventors: Ronald B. Leng, Avani M. Patel, Brian D. Scherzer, Derrick G. Wetters, Douglas C. Greminger
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Patent number: 8053550Abstract: Process for the purification of a vinyl chloride polymer (PVC) comprising at least one compound of a heavy metal, according to which: (a) the PVC is dissolved in a water-miscible polar organic solvent; (b) an aqueous solution comprising a reagent, which is either a base capable of reacting with the compound of the heavy metal (R1) or a dispersing agent capable of stabilizing the said compound (R2), is added to the organic solution, the water being introduced in an amount (Q) such that it brings about the formation of a two-phase medium, the continuous phase of which is the organic phase; (c) the two-phase medium is subjected to stirring for a time sufficient for the reagent to be able to interact with (exert its effect on) the compound of the heavy metal; (d) the precipitation of the PVC out of this two-phase medium is brought about.Type: GrantFiled: November 21, 2005Date of Patent: November 8, 2011Assignee: Solvay (Societe Anonyme)Inventors: Eric Fassiau, Murielle Manin
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Method for decomposing and reclaiming synthetic resin having ester bond in the composition structure
Patent number: 7985778Abstract: Synthetic resin containing ester bond is subjected to hydrolysis treatment to reclaim raw material component before polymerization. Method for decomposing and reclaiming synthetic resin having ester bond in composition structure thereof, by conducting hydrolysis treatment and then separation collection treatment. In the hydrolysis treatment, article containing synthetic resin to be decomposed and reclaimed is exposed to water vapor atmosphere filled under saturation water vapor pressure at treatment temperature at or below melting point of the synthetic resin. The synthetic resin in article to be treated is hydrolyzed by water vapor generated at the treatment temperature, to generate decomposition product before polymerizing to the synthetic resin containing an ester bond. The separation collection treatment is treatment in which the decomposition product generated by the hydrolysis treatment is separated into liquid component and solid component to be collected individually.Type: GrantFiled: March 6, 2007Date of Patent: July 26, 2011Inventor: Koichi Nakamura -
Patent number: 7977453Abstract: The present invention relates to processes for hydrolyzing polyphosphoric acid in shaped articles.Type: GrantFiled: March 27, 2006Date of Patent: July 12, 2011Assignees: E. I. du Pont de Nemours and Company, Magellan Systems International, LLCInventor: Christopher William Newton
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Patent number: 7943676Abstract: A method of recycling waste plastic foam materials firstly is to smash a waste material including polyurethane foam into fine particles so as to obtain a first starting material. The first starting material is then crisped and followingly milled into powder so as to obtain a second starting material. The second starting material is then placed into a mixer to mix with a first foaming reaction solution including polyol, catalyst and additives injected into the mixer so as to form a semi-treated foaming material. And then, the semi-treated foaming material is mixed with a second foaming reaction solution including diisocyanate injected into the mixer so as to obtain a completed-treated foaming material. Lastly, the completed-treated foaming material is poured into a mold and then water vapor is uniformly introduced into the mold so as to induce the completed-treated foaming material to proceed foaming reaction.Type: GrantFiled: February 7, 2008Date of Patent: May 17, 2011Inventor: Kun-Huang Chang
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Patent number: 7893195Abstract: Method for recovering a polymer from a liquid medium (1) substantially containing the polymer and a solvent for the latter, wherein: (a) this liquid medium (1) is injected into a reactor (2) containing a stirred substantially monophase liquid mixture comprising a major fraction by weight of a non-solvent and a minor fraction by weight of a solvent, the mixture having a composition and temperature such that the polymer precipitates therefrom progressively; (b) the polymer is recovered in the form of particles in suspension (5) in a liquid rich in non-solvent; (c) the polymer particles (9) are separated from the liquid.Type: GrantFiled: August 17, 2006Date of Patent: February 22, 2011Assignee: SOLVAY (Societe Anonyme)Inventors: Eric Fassiau, Bernard Vandenhende, Jean-Raphael Caille, Jean-Christophe Lepers
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Patent number: 7846986Abstract: Process for recovering at least one polymer in solution in a solvent by precipitation by means of a non-solvent introduced gradually into the solution to form the precipitation medium, whereby: in the course of the introduction of the non-solvent into the precipitation medium, there is first a phase separation (into a continuous phase rich in solvent, in which the polymer is dissolved, and into a disperse phase, consisting of droplets rich in non-solvent) and then there is a phase inversion (the continuous phase then becoming the phase rich in non-solvent, and the disperse phase becoming the phase rich in solvent containing the dissolved polymer) the non-solvent is initially introduced into the precipitation medium in liquid form only and in a quantity (Q?) which is not zero but is less than the quantity (Q) required to bring about the phase inversion, and is subsequently introduced into the precipitation medium at least partly in vapour form.Type: GrantFiled: July 14, 2004Date of Patent: December 7, 2010Assignee: Solvay S.A.Inventors: Eric Fassiau, Denis Geets
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Patent number: 7812061Abstract: A method for manufacturing a recycled polycarbonate raw material for a flame retardant resin composition from discarded and/or recovered optical discs using a polycarbonate resin as a substrate material, and includes (a) a step to identify if 2,2-bis(4-hydroxyphenyl)propane as a divalent phenol of the polycarbonate resin raw material is polymerized as the sole raw material in the polycarbonate resin as the substrate material of the discarded and/or recovered optical discs and (b) a step to remove impurities by a chemical treatment by separating only the discarded and/or recovered optical discs, wherein the polycarbonate resin is identified as polymerized by using 2,2-bis(4-hydroxyphenyl)propane as the sole raw material.Type: GrantFiled: May 10, 2007Date of Patent: October 12, 2010Assignee: Idemitsu Kosan Co., Ltd.Inventor: Toshio Isozaki
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Patent number: 7803253Abstract: A dehydration method of a water-containing substance using a liquefied matter, including a step (1) of contacting a liquefied matter of a substance which is in a gas phase under a condition at ambient temperature and atmospheric pressure with the water-containing substance, to dissolve contained water in the water-containing substance into the liquefied matter, for obtaining the liquefied matter containing a large amount of water; and a step (2) of vaporizing the substance out of the liquefied matter containing a large amount of water, to thereby separate the substance as the gas from water.Type: GrantFiled: May 12, 2006Date of Patent: September 28, 2010Assignee: Central Research Institute of Electric Power IndustryInventors: Hideki Kanda, Youichi Urakawa
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Patent number: 7790804Abstract: The invention provides a process for the purification of polymer polyols that ensures a reduction of acrylonitrile, styrene as well as the residual amounts of optionally used chain regulator, and of occurring recombination products of the initiator when azo initiators are used, to levels of <25 ppm of acrylonitrile, <50 ppm styrene, <50 ppm chain regulator and <280 ppm of recombination products by stripping using packed columns.Type: GrantFiled: June 22, 2007Date of Patent: September 7, 2010Assignee: Bayer MaterialScience AGInventors: Michael Brockelt, Ludwig Deibele, Manfred Dietrich, Markus Hadley, Jan Thomas Leu, Guido Naberfeld, Ralf Dohrn
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Patent number: 7790777Abstract: Process for recovering at least one polymer in solution in a solvent by precipitation by means of a non-solvent fluid, whereby the precipitation takes place in a precipitation medium comprising two dispersants of which one [dispersant(I)] has a greater affinity for the non-solvent and the other [dispersant (II)] has a greater affinity for the solvent.Type: GrantFiled: July 14, 2004Date of Patent: September 7, 2010Assignee: Solvay S.A.Inventors: Eric Fassiau, Denis Geets
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Patent number: 7786254Abstract: A process to perform the finishing of polyolefins produced by gas-phase catalytic polymerization of one or more ?-olefins in the presence of a polymerization diluent selected from a C3-C5 alkane, wherein the polyolefin granules discharged from the gas-phase reactor are subjected to: (1) a first degassing step in which said polyolefin is counter-currently contacted with a gaseous stream containing at least 85% by mol of a stripping agent selected from a C3-C5 alkane, said gaseous stream being continuously derived from the monomer recovery section of the polymerization plant; (2) a second degassing step in which said polyolefin is counter-currently contacted with steam, the amount of steam being from 10 to 200 Kg per 1000 kg of polyolefin.Type: GrantFiled: August 1, 2007Date of Patent: August 31, 2010Assignee: Basell Polyolefine GmbHInventors: Pietro Baita, Giuseppe Penzo, Gabriele Mei
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Patent number: 7745567Abstract: A process for continuously stripping a polymer dispersion comprising a heat exchanger with minimal internal obstructions for the stripper. The process is particularly adapted to dispersions that are heat and shear sensitive. The process is able to extract hydrophobic VOC's more efficiently than a single, jacketed tube design.Type: GrantFiled: October 29, 2007Date of Patent: June 29, 2010Assignee: Rohm and Haas CompanyInventors: James Kent Carpenter, Adam Loyack
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Patent number: 7745568Abstract: A process is provided for recovering polymer solids from a polymerisation reactor effluent. The process comprises extracting the polymerisation effluent from a polymerisation reactor; passing the effluent, or a part thereof, to a flash vessel for flashing liquid in the effluent to vapour, and removing said vapour from said flash vessel; passing the polymer solids from the flash vessel to a transfer apparatus which comprises a transfer vessel; passing the polymer solids from the transfer vessel to a purging means for removing residual liquid from the polymer solids; wherein the polymer solids are passed from the flash vessel to the purging means in a continuous flow such that a quantity of polymer solids is maintained in the transfer vessel. An apparatus for performing the process is also provided.Type: GrantFiled: February 8, 2005Date of Patent: June 29, 2010Assignee: Total Petrochemicals Research FeluyInventor: Hugo Vandaele
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Patent number: 7736525Abstract: A method of making an alkoxylated polyethyleneimine (APEI) product having reduced discoloration includes treating a composition including a component selected from the group of polyethyleneimine (PEI), APEI intermediate, and combinations thereof that is used to make the APEI product. The method of treating the composition includes heating a composition that includes an adduct of a conjugate base and PEI, water, and the component at a temperature of from 158 to 338° F. for a period of at least three hours in the absence of additional water in order to substantially decompose the adduct in the composition. The aqueous solutions of APEI product thus made have Gardner color values of less than 6.Type: GrantFiled: February 7, 2006Date of Patent: June 15, 2010Assignee: BASF CorporationInventors: Chacko Thankachan, Klaus J. Friedrich, Daniel E. Coker
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Publication number: 20100130719Abstract: The present invention relates to a process for devolatilization of a polymer of an aromatic alkylene, such as styrene, and in particular, to an improved process using water as a stripping agent (i) in which the total amount of water to be disposed of can be reduced, (ii) which allows at least a portion of the water to be recycled as stripping agent, reducing make-up requirements for the stripping agent, and (iii) which allows at least a portion of the aromatic alkylene monomer in the water to be recycled to the polymerisation process (via the devolatilization steps) rather than disposed of.Type: ApplicationFiled: June 3, 2008Publication date: May 27, 2010Inventor: Jean-Marc Galewski
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Patent number: 7723466Abstract: A tackifier resin is provided comprising monomer units from at least one aromatic monomer and at least one acrylate monomer; wherein the tackifier resin has a low residual monomer concentration. In other embodiments of the invention, the tackifier resin does not significantly decrease the moisture vapor transport rate of an adhesive composition comprising the tackifier resin, does not significantly increase fogging of an adhesive composition comprising the tackifier resin, and does not significantly exhibit skin sensitivity properties. A process to produce the tackifier resin is also provided. The process comprises contacting a tackifier resin product stream with at least one carrier at a temperature sufficient to remove a portion of at least one residual monomer from the tackifier resin product stream to produce the tackifier resin.Type: GrantFiled: December 19, 2007Date of Patent: May 25, 2010Assignee: Eastman Chemical CompanyInventors: Michel Hendrikus Theelen, Derek William Bamborough, Elisabeth Eduarda Catharina Geertruida Gielens
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Patent number: 7579385Abstract: Disclosed are dried porous crumbs of a hydrogenated block copolymer which is obtained by hydrogenating a block copolymer comprising (a) at least one polymer block composed mainly of aromatic vinyl monomer units and (b) at least one polymer block composed mainly of conjugated diene monomer units, and which has a molecular weight of 70,000 or more. The dried porous crumbs have a water content of 1% by weight or less and having the capability of absorbing an oil in an amount of 1.0 or more, in terms of the ratio of the weight of an oil, which is absorbed by the dried porous crumbs when the dried porous crumbs are immersed in the oil at 25° C. under atmospheric pressure for 1 minute, to the weight of the dried porous crumbs. Also disclosed is a method for producing the same.Type: GrantFiled: April 28, 1999Date of Patent: August 25, 2009Assignee: Asahi Kasei Kabushiki KaishaInventors: Yasumasa Yamakoshi, Toshinori Shiraki, Masami Kamaya
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Patent number: 7541427Abstract: An objective of the present invention is to provide a desolvation method for removing a solvent efficiently from a polymer solution. In the present desolvation method where the solvent is removed from the polymer solution by steam stripping using an apparatus comprising a pipe which connects a gas phase portion of a desolvation tank at the downstream and a liquid phase portion of a desolvation tank at the upstream, and an opening-degree adjusting mean (for example, pressure adjusting valve) fixed to this pipe, pressures are controlled such that a pressure difference (?P=P2?P1) between pressures of each gas phase portion of desolvation tanks at the downstream and at the upstream is allowed to be larger by from 0.005 to 0.6 MPa, preferably from 0.05 to 0.3 MPa than a pressure difference when the opening-degree adjusting mean is fully opened.Type: GrantFiled: June 14, 2004Date of Patent: June 2, 2009Assignees: JSR Corporation, International Center for Environmental Technology TransferInventors: Nobuaki Katayama, Katsunori Ishii, Naritsugu Kumai
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Patent number: 7517946Abstract: In the dehydration step, a mixture comprising an organic amide solvent and a sulfur source is heated, vapor volatilized is guided to a distillation column, a fraction comprising the organic amide solvent as a principal component is refluxed into a reaction vessel, a fraction comprising water and hydrogen sulfide is cooled to discharge hydrogen sulfide that is not condensed by the cooling and reflux a part of water condensed into the distillation column, the remaining water is discharged, a relational expression between the total amount of water of an amount of water refluxed and an amount of water discharged without being refluxed, and an amount of hydrogen sulfide discharged from the reaction vessel is determined in advance, and an amount of hydrogen sulfide discharged from the reaction vessel is calculated out from a measured value of the total amount of water on the basis of the relational expression to control a charged molar ratio of the sulfur source to a dihalo-aromatic compound.Type: GrantFiled: December 19, 2003Date of Patent: April 14, 2009Assignee: Kureha CorporationInventors: Hiroyuki Sato, Tatsuya Kawasaki, Yasushi Nakazawa
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Patent number: 7393915Abstract: The object of this invention is to provide a new process for producing polyorganosiloxane-containing resin which comprises reducing volatile siloxane, characterized in that polyorganosiloxane-containing resin in a slurry state is heat-stripped in producing polyorganosiloxane-containing resin.Type: GrantFiled: April 14, 2004Date of Patent: July 1, 2008Assignee: Kaneka CorporationInventors: Kazunori Saegusa, Tomoyuki Yoshimi, Hiroshi Tone
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Publication number: 20080103289Abstract: A process for continuously stripping a polymer dispersion comprising a heat exchanger with minimal internal obstructions for the stripper. The process is particularly adapted to dispersions that are heat and shear sensitive. The process is able to extract hydrophobic VOC's more efficiently than a single, jacketed tube design.Type: ApplicationFiled: October 29, 2007Publication date: May 1, 2008Inventors: James Kent Carpenter, Adam Loyack
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Patent number: 7364668Abstract: The present invention provides a process for producing an amino composition by addition reaction between a polyamine and an unsaturated hydrocarbon compound in the presence of a strongly basic alkali metal catalyst to obtain an amino composition containing not more than 2% by weight of unreacted polyamine and preferably not more than 10 ppm of alkali metal.Type: GrantFiled: December 3, 2004Date of Patent: April 29, 2008Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Hisayuki Kuwahara, Tsutomu Numoto, Masatoshi Echigo, Shun Ogawa
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Patent number: 7345132Abstract: Provided an industrially excellent method of producing a phenol novolak resin having an ortho ratio of 30% or more by: (1) a method of reacting a phenol and an aldehyde using an oxalic acid catalyst at 110 to 160° C. under pressure; or (2) a method of reacting a phenol and an aldehyde under pressure while removing the heat of reaction by a condenser with controlling a pressure so that water or an organic solvent present in the reaction system is refluxed.Type: GrantFiled: January 19, 2005Date of Patent: March 18, 2008Assignee: Chang Chun Plastics Co. LtdInventors: Noriaki Saito, Ichishi Aizu, Nobuyuki Nakajima, Masahiro Fujiwara, Koji Yano
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Patent number: 7314909Abstract: A poly(arylene ether)/polystyrene blend may be prepared by melt kneading a carboxylic acid compound, a poly(arylene ether), and a polystyrene to form an intimate blend, and steam stripping the intimate blend, where melt kneading is conducted with a specific energy consumption of about 0.1 to about 0.3 kilowatt-hour per kilogram of blend. The method allows the formation of an intimate resin blend while minimizing the styrene monomer content of the final blend.Type: GrantFiled: October 12, 2005Date of Patent: January 1, 2008Assignee: General Electric CompanyInventors: Geoffrey H. Riding, Katsuhisa Kumagai, Kim G. Balfour, Robert Hossan
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Patent number: 7304124Abstract: A stripping process is provided which continuously strips volatile substances from a dispersion containing a polymer particles through stripping the volatile substances from a dispersion by blowing an inert gas into the dispersion to draw the volatile substances into the inert gas, removing the volatile substances from the gas mixture of the inert gas and the stripped volatile substances and circulating the purified inert gas obtained by removing the volatile substances from the gas mixture, and blowing the purified inert gas into the dispersion. Also provided is a production process for a toner which uses this stripping process.Type: GrantFiled: November 1, 2002Date of Patent: December 4, 2007Assignee: Zeon CorporationInventors: Takeo Fujino, Kazuhiro Sato
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Patent number: 7279244Abstract: The object of this invention is to provide a solid polymer electrolyte which is excellent in durability and of low cost, and membranes, solutions for electrode catalyst coating, membrane/electrode assemblies and fuel cells which use the electrolyte. According to this invention, there can be provided a fuel cell which comprises an electrode assembly having an electrode catalyst membrane formed therein, said catalyst membrane comprising a polymer electrolyte membrane held between an anode on one side of the principal plane of the electrolyte membrane and a cathode on the other side of the principal lane thereof, current collecting plates provided each independently in close contact, to the anode side and the cathode side of the electrode assembly, and electroconductive separators having gas supply passages to the anode and to the cathode provided on the outside surfaces of the current collecting plates.Type: GrantFiled: July 8, 2005Date of Patent: October 9, 2007Assignee: Hitachi, Ltd.Inventors: Makoto Morishima, Tomoichi Kamo, Toshiyuki Kobayashi, Kenji Yamaga, Tohru Koyama