Abstract: The present invention provides the process for preparing a fluorine-containing polymer which can easily and efficiently separate a fluorine-containing polymer and water from an aqueous dispersion of a fluorine-containing polymer, and the fluorine-containing polymer obtained by the mentioned preparation process. Further the present invention provides the molded article obtained by crosslinking a curable composition comprising the above-mentioned fluorine-containing polymer and a crosslinking agent. The preparation process is a process for preparing a fluorine-containing polymer comprising a step for heat-treating an aqueous dispersion of a fluorine-containing polymer having a concentration of 3 to 70% by weight to obtain the fluorine-containing polymer having a water content of not more than 1% by weight.

Abstract: Methods for preparing active carbonate esters of water-soluble polymers are provided. Also provided are other methods related to the active carbonate esters of water-soluble polymers, as well as corresponding compositions.

Abstract: Methods for the purification of ethylene vinyl alcohol copolymers are provided.

Abstract: In a process for producing a poly(arylene sulfide) by polymerizing a sulfur source and a dihalo-aromatic compound in the presence of an alkali metal hydroxide in an organic amide solvent, the production process comprises washing a polymer obtained by the polymerization with a hydrophilic organic solvent containing water in a proportion of 1 to 30% by weight, thereby collecting a purified polymer, the content of nitrogen contained in an extract extracted by a mixed solvent containing 40% by weight of acetonitrile and 60% by weight of water from the purified polymer is at most 50 ppm on the basis of the weight of the polymer, and a poly(arylene sulfide), the content of nitrogen contained in an extract extracted by a mixed solvent containing 40% by weight of acetonitrile and 60% by weight of water from the purified polymer is at most 50 ppm on the basis of the weight of the polymer.

Abstract: To provide a polyimide film for molding that is light and has excellent surface smoothness, safety, moldability, heat resistance, and handleability and thus can be used as the reflector base material for illuminating devices. The polyimide film for molding is made of a thermoplastic polyimide obtained from a reaction between an aromatic tetracarboxylic acid or its dianhydride and an aromatic diamine. The lowest viscoelasticity of storage elasticity (E?) of viscoelasticity is 108 Pa or lower, and the tensile elongation at glass transition temperature (E?) A is 150% or higher.

Abstract: It is an object of the present invention to produce a polylactic acid having a high molecular weight such as a weight average molecular weight (Mw) of more than 100,000 from which only a stereocomplex crystal is grown even by repeating melting and crystallization. The present invention is a process of producing a polylactic acid, including the steps of: (i) obtaining a solid by kneading together poly(L-lactic acid) and poly(D-lactic acid) at a temperature of 160 to 225° C. and crystallizing the kneaded product; and (ii) melt kneading the obtained solid.

Abstract: Rosin modified phenolic resins are prepared by reacting together rosin, fatty acid, phenol and aldehyde. The fatty acid may be Monomer (derived from the fatty acid dimerization process). The reaction mixture may optionally include ?,?-olefinically unsaturated carboxylic acid(s) or anhydride(s), and polyol(s). The resin may be dissolved in a solvent to form a varnish. The resin may be used as a component of inks for lithographic or gravure printing.

Abstract: A fluoropolymer molding method and the resulting molded article are disclosed where the fluoropolymer is composed of fluoropolymer particles each having a multi-layer structure that consists of at least two types of fluoropolymers having different melting points, with at least one inner layer made of a fluoropolymer with a melting point higher than that of the outermost fluoropolymer. The fluoropolymer of the at least one inner layer is molded at a temperature higher than the melting point of the lowest melting point of the fluoropolymers that form the outermost layers of the multi-layer-structure fluoropolymer particles, and lower than the melting point of the fluoropolymer having the highest melting point. The resulting articles have excellent chemical liquid resistance and gas impermeability and low linear expansion coefficient.

Abstract: This invention relates to a process for preparing polytrimethylene ether glycols or copolymers thereof by a polycondensation reaction using at least one acid catalyst, wherein the temperature of the reaction is controlled such that the average temperature during the first half of the reaction is higher than the average temperature during the second half of the reaction.

Abstract: This invention relates to a process for preparing polytrimethylene ether glycols or copolymers thereof having a number-average molecular weight of at least about 250 g/mole by a polycondensation reaction using at least one acid catalyst.

Abstract: A PBI compound includes imidazole nitrogens at least a portion of which are substituted with a moiety containing a carbonyl group, the substituted imidazole nitrogens being bonded to carbon of the carbonyl group. At least 85% of the nitrogens may be substituted. The carbonyl-containing moiety may include RCO—, where R is alkoxy or haloalkyl. The PBI compound may exhibit a first temperature marking an onset of weight loss corresponding to reversion of the substituted PBI that is less than a second temperature marking an onset of decomposition of an otherwise identical PBI compound without the substituted moiety. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may use more than 5 equivalents in relation to the imidazole nitrogens to be substituted.

Abstract: A process for preparing an aqueous aminoplastic urea-formaldehyde resin suitable for use in bonding lignocellulosic materials, which provides products of very low formaldehyde emission while maintaining superior performance.

Abstract: Stable NCO prepolymers are produced from polyisocyanates having a melting point greater than 70° C., preferably, naphthalene diisocyanate, having advantageous physical properties. An important feature of the process of the present invention is the rapid cooling of the prepolymer. The process of the present invention may be carried out on a continuous or batch basis. The prepolymers of the present invention are particularly suitable for the production of cast polyurethane elastomers.

Abstract: A method for reformulating reclaimed, contaminated mixed waste plastics into useful articles wherein a plurality of batches of the mixed waste plastics are preprocessed to produce substantially homogeneous mixtures of a desired particle size range that are characterized according to their respective apparent densities, and are thereafter blended to produce a mixed plastic feed material having a color predetermined to be desirable for reprocessing into at least one of such useful articles.

Abstract: A method for reformulating reclaimed, contaminated mixed waste plastics into useful articles wherein a plurality of batches of the mixed waste plastics are preprocessed to produce substantially homogeneous mixtures of a desired particle size range that are characterized according to their respective apparent densities, and are thereafter blended to produce a mixed plastic feed material having a plastic content predetermined to be desirable for reprocessing into at least one of such useful articles.

Abstract: A method for reformulating reclaimed, contaminated mixed waste plastics into useful articles wherein a plurality of batches of the mixed waste plastics are preprocessed to produce substantially homogeneous mixtures of a desired particle size range that are characterized according to their respective apparent densities, and are thereafter blended to produce a mixed plastic feed material having a target density predetermined to be desirable for reprocessing into at least one of such useful articles.

Abstract: Disclosed is a method for modifying a polymer by carrying out a thermally-induced reaction in a mixing apparatus having a high shear environment and devolatilization capabilities. Also disclosed are the resulting materials.

Abstract: A method for preparing multi-arm poly(ethylene glycol) (PEG) chlorides from multi-arm PEG polyols is described. The method comprises a process, wherein the multi-arm PEG polyol is reacted with thionyl chloride to form the multi-arm PEG chloride.

Abstract: Disclosed is a coordination polymer crystal with porous metal-organic frameworks (MOFs), in which, while a crystal state of the coordination polymer crystal is maintained, an additional material selected from the group consisting of an organic compound, a metal cluster, and an organometallic compound is chemically bonded to the coordination polymer crystal. Therefore it is possible easily adsorb and store more guest molecules regardless of a change in an ambient temperature or pressure due to the chemically bonded additional material.

Abstract: An installation for increasing the intrinsic viscosity of a polyester material by solid phase polycondensation (SSP) comprises a heatable reaction container (2, 2?) in which the polyester material (P) can be left to reside at a predetermined thermal treatment temperature for a predetermined residence time until it has reached a desired intrinsic viscosity, and a cooling container (6, 6?) arranged downstream of the reaction container, the cooling container (6, 6?) being designed for cooling the polyester material discharged from the reaction container to a first cooling temperature which is lower than the reaction temperature. Downstream of the cooling container (6, 6?), a polyester material separator (7) is arranged which is designed for diverting the polyester material flow to a polyester material processing machine (8) and/or to an intermediate storage container (10).

Abstract: Melamine-urea-formaldehyde resins may be prepared using processes including a first cook stage, a second cook stage, and a final addition wherein: the molar ratio of formaldehyde to urea and melamine (F:U+M) in the first cook stage is from about 2.0 to about 5.0; and the molar ratio of formaldehyde to urea and melamine (F:U+M) in the second cook stage is from about 1.5 to 3.0; and the molar ratio of formaldehyde to urea and melamine (F:U+M) in the final addition from about 0.4 to 0.70.

Abstract: A polymer blend has a base and blend components. The base and blend components could be a branched slow crystallizing PET and a faster crystallizing PET, respectively. The ratio of base and blend components result in a block copolymer, the melt processing time and branching or chain extender levels can be can be tailored to impart the polymer blend with sufficient melt strength and crystallization rates, such that it is slow enough during the blow molding process to produce a clear article and yet fast enough during the subsequent PET recycling process making it suitable for extrusion processes as well as for recycling. The combination of materials can be used to form monolayer or multilayer articles.

Abstract: A continuous process wherein polymers or polymeric materials can be subjected to multiple sequential processing systems of differing temperatures and process conditions to synergistically enhance the pelletization and crystallization of those polymers and polymeric formulations, dispersions, and solutions. The multiple sequential processing systems include the processes and equipment for mixing/extrusion, pelletization, multiple transportation processes, crystallization, multiple drying processes, and optional post-processing manipulations of pellets formed. Multiple serial and/or parallel crystallization processing systems are disclosed.

Abstract: A poly(arylene sulfide) having properties that a melt viscosity is 1 to 3,000 Pa·s as measured under conditions of a temperature of 310° C. and a shear rate of 1,216 sec?1, a pH is 7.0 to 12.0 as measured in a mixed solvent of water/acetone (volume ratio=2/1), a crystallization temperature is at most 220° C. as measured in the course of lowing the temperature of the polymer at a rate of 10° C./min from a molten state, and a whiteness degree is at least 70 as measured in the form of a melt molded or formed product, and a production process thereof.

Abstract: A process for the continuous thermal treatment of mixed substances, especially of solutions, suspensions and emulsions, wherein the continuous treatment of the mixed substances is divided into a main vaporization and a degassing stage, in which instance the main vaporization and the degassing take place in each case takes place in a separate mixer-kneader.

Abstract: A PBI compound includes imidazole nitrogens at least a portion of which are substituted with a moiety containing a carbonyl group, the substituted imidazole nitrogens being bonded to carbon of the carbonyl group. At least 85% of the nitrogens may be substituted. The carbonyl-containing moiety may include RCO—, where R is alkoxy or haloalkyl. The PBI compound may exhibit a first temperature marking an onset of weight loss corresponding to reversion of the substituted PBI that is less than a second temperature marking an onset of decomposition of an otherwise identical PBI compound without the substituted moiety. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may use more than 5 equivalents in relation to the imidazole nitrogens to be substituted.

Abstract: A method for the manufacture of crystallized polyesters with or without subsequent solid state polycondensation for the manufacture of bottles, foils, films and technical high-performance fibres, or with or without subsequent dealdehydization for the manufacture of bottles, foils, films and technical high-performance fibres.

Abstract: A method of producing an embedded recycled container sheet includes: (a) providing a plurality of empty recycled plastic containers; (b) flattening the plurality of empty recycled plastic containers to reduce their width by at least 80%; (c) providing a base substrate of plastic; (d) placing the plurality of flattened, empty recycled plastic containers on the base substrate; and, (e) applying a molten top layer of plastic on the plurality of flattened, empty recycled plastic containers and on the base substrate, and cooling the molten top layer, so as to embed the plurality of empty recycled plastic containers between the top layer and the base substrate. A method of producing product from the resulting sheet involves creating the product using a processing step selected from the group consisting of molding, casting, cutting, machining, and combinations of these.

Abstract: Polyester compositions are disclosed that include polyester polymers or copolymers having incorporated therein titanium nitride particles that provide one or more of the following advantages: improving the reheat properties of the compositions, improving the color of the compositions through reduced yellowness, and improving the UV-blocking properties of the compositions. Processes for making such compositions are also disclosed. The titanium nitride particles may be incorporated in the polyester by melt compounding, or may be added at any stage of the polymerization, such as during the melt-phase of the polymerization. A range of particle sizes may be used, as well as a range of particle size distributions. The polyester compositions are suitable for use in packaging made from processes in which a reheat step is desirable, or decreased yellowness is desired, or increased resistance to the effects of ultraviolet light is desired, or any combination of the foregoing.

Abstract: An electrolyte membrane includes a nanocomposite ion complex that is a reaction product of a nanocomposite with a basic polymer. The nanocomposite includes a polymer having a sulfonic acid group and an unmodified clay. Either the unmodified clay has a layered structure and is dispersed in the polymer having the sulfonic acid group, and the polymer is intercalated between layers of the clay or the unmodified clay has an exfoliated structure and the exfoliated layers of the unmodified clay are dispersed in the polymer. The electrolyte membrane shows high mechanical strength, high ionic conductivity, and excellent methanol crossover impeding properties even when the degree of sulfonation of the polymer having the sulfonic acid group is high. When a methanol aqueous solution is used as a fuel, the fuel cell including the electrolyte membrane has a low methanol crossover, and thus, has a high operational efficiency and a long lifetime.

Abstract: A process for crystallizing a polyester polymer by introducing a molten polyester polymer, such as a polyethylene terephthalate polymer, into a liquid medium at a liquid medium temperature greater than the Tg of the polyester polymer, such as at a temperature ranging from 100° C. to 190° C., and allowing the molten polyester polymer to reside in the liquid medium for a time sufficient to crystallize the polymer under a pressure equal to or greater than the vapor pressure of the liquid medium. A process flow, underwater cutting process, crystallization in a pipe, and a separator are also described.

Abstract: A poly(2,6-dimethyl-1,4-phenylene ether) having a high molecular weight and a reduced content of low molecular weight species can be prepared by a method that includes specific conditions for the oxidative polymerization, chelation, and isolation steps. The poly(2,6-dimethyl-1,4-phenylene ether) is particularly useful for the fabrication of fluid separation membranes.

Abstract: Spheroidal polyester polymer particles, as well as preforms and stretch blow molded bottles made from the spheroidal particles, are provided which have: A) an It.V. of at least 0.72 dL/g, and either B) at least two melting peaks (on a DSC first heating scan), wherein one of said at least two melting peaks is a low peak melting point having a peak temperature within a range of 140° C. to 220° C.

Abstract: Process for preparing polymeric aromatic phosphonates and also polymeric aromatic phosphonates which can be prepared by the process of the invention and blends comprising these polymeric aromatic phosphonates and at least one further polymer and also films, composites and membranes comprising these polymers or blends, the use of the membranes of the invention in fuel cells or in separation technology and also fuel cells comprising the membranes of the invention.

Abstract: A basket is made from embedded recycled container sheet. The basket includes: a side wall and a bottom, the side wall and the bottom being connected to one another in the shape of a basket with an open top, the side wall being, at least in part, a plurality of flattened recycled containers embedded therein, and each of the plurality of flattened recycled containers being visibly recognizable. In some embodiments, the basket also includes a hanging mechanism attached to at least one of the side wall and the bottom. The side wall has a footprint that may be circular, conical, oval, square, rectangular, polygonal or irregular.

Abstract: A method of storing information. The method including: applying a layer of one or more poly(aryl ether ketone) copolymers to a substrate and thermally curing the layer to form a resin layer, each of the one or more poly(aryl ether ketone) copolymers comprising (a) a first monomer including an aryl ether ketone and (b) a second monomer including an aryl ether ketone and a hydrogen bonding cross-linking moiety, each of the one or more poly(aryl ether ketone) copolymers having two terminal ends, each terminal end having a phenylethynyl moiety, and bringing a thermal-mechanical probe heated to a temperature of greater than 100° C. into proximity with the resin layer multiple times to induce deformed regions at points in the resin layer, the thermal-mechanical probe heating the points in the resin layer of the resin and thereby writing information in the resin layer.

Abstract: An embedded recycled container sheet binder includes a front cover and a back cover, the front cover and the back cover being connected to one another for opening and closing, at least one of the front cover and the back cover being, at least in part, a plurality of flattened recycled containers embedded in a plastic base, and each of the plurality of flattened recycled containers being visibly recognizable. The plurality of flattened recycled containers is preferably embedded between a base substrate of plastic and a top layer of plastic. The base substrate is a recycled plastic base substrate selected from the group consisting of clear plastic, opaque plastic, colored plastic and combinations thereof. In some preferred embodiments, the embedded recycled container sheet binder the top layer is a recycled plastic selected from the group consisting of clear plastic, opaque plastic and combinations thereof.

Abstract: The disclosure defined by this invention provides a method for extruding thermoplastic polymers which includes the step of creating high pressure steam in the extruding apparatus so as to prevent scorching and to solubilize contaminants. The method can be used in a neutralization step of ionomers in an extrusion process to obtain an extrudate having good light transmission and improved impact resistance.

Abstract: Cardanol based dimers are provided. The cardanol dimers are formed by hydrosilylation with silanes. Cardanol based dimers may be further reacted to form epoxy curing agents and epoxies which can be used as anti-fouling coatings on ship hulls and marine structures. The cardanol dimers may also be used to produce friction particles or phenolic resins. Methods of synthesizing the cardanol based dimers, the epoxy curing agents and the epoxies are also provided.

Abstract: Synthetic resin containing ester bond is subjected to hydrolysis treatment to reclaim raw material component before polymerization. Method for decomposing and reclaiming synthetic resin having ester bond in composition structure thereof, by conducting hydrolysis treatment and then separation collection treatment. In the hydrolysis treatment, article containing synthetic resin to be decomposed and reclaimed is exposed to water vapor atmosphere filled under saturation water vapor pressure at treatment temperature at or below melting point of the synthetic resin. The synthetic resin in article to be treated is hydrolyzed by water vapor generated at the treatment temperature, to generate decomposition product before polymerizing to the synthetic resin containing an ester bond. The separation collection treatment is treatment in which the decomposition product generated by the hydrolysis treatment is separated into liquid component and solid component to be collected individually.

Abstract: A fluororubber composition including a polyol-crosslinkable fluororubber; a cross-linking accelerator comprising a quaternary ammonium salt; and a polyol crosslinking agent; wherein the weight ratio X (quaternary ammonium salt/polyol crosslinking agent) between the cross-linking accelerator and the polyol crosslinking agent is in a range of 0.40 to 0.60; and a production method of a cross-linked fluororubber product, comprising the steps of: previously polyol-crosslinking, as required, the fluororubber composition; and subsequently heat treating the polyol-crosslinked composition, in a temperature range of 200° C. to 300° C. for 0.1 to 48 hours. The fluororubber composition has surface has a lower friction coefficient, and the surface roughness of the cross-linked fluororubber product can be increased without applying a treatment to a mold.

Abstract: The invention relates to a continuous or discontinuous method for the production of highly condensed polyesters in the solid state, comprising a crystallization of a polyester material, wherein the crystallization is carried out in the presence of a gas with a dew point of (less than or equal to) ?approximately ?10° C. The invention also relates to a method for the production of polyester formed bodies using the polyester material obtained for the production of bottles, films and high strength threads.

Abstract: The present invention relates to processes for hydrolyzing polyphosphoric acid in shaped articles.

Abstract: A method for reformulating reclaimed, contaminated mixed waste plastics into useful articles wherein a plurality of batches of the mixed waste plastics are preprocessed to produce substantially homogeneous mixtures of a desired particle size range that are characterized according to their respective apparent densities, and are thereafter blended to produce a mixed plastic feed material having a rheology predetermined to be desirable for reprocessing into at least one of such useful articles.

Abstract: Process for heating a polymer-containing stream being transferred from a polymerization reactor to a degassing vessel operating at a pressure between 6 bara and 12 bara. The process includes passing the stream through a heater having a transfer line for the stream and a device for heating the transfer line. The pressure drop in the heater is between 5% and 50% of the total pressure drop between the polymerization reactor and the entry to the degassing vessel. The pressure drop across the length of the heater is less than 0.5 barh per tonne of polymer, and the average Reynolds number across the cross-section of the stream at any point along the length of the transfer line of the heater is greater than 500,000, such that at least 90 mol% of the hydrocarbon fluids withdrawn from the polymerization reactor operation are vaporized before entry into the degassing vessel.

Abstract: To establish an efficient and economical useful component recovery method capable of recovering high purity useful components from a dyed polyester fiber. A method for recovering useful components from a dyed polyester fiber, includes a dye extraction step, a solid liquid separation step, a depolymerization reaction step, an ester interchange reaction step, and a useful component separation step, for recovering useful components from the dyed polyester fiber, wherein the dye extraction step includes a step of extracting and removing a dye at the glass transition temperature of the polyester or higher and at 220° C. or less with a xylene extracting solvent and an alkylene glycol extracting solvent in combination.

Abstract: The present invention relates to a process for producing water-absorbing polymeric particles by polymerizing a monomer solution comprising at least one ethylenically unsaturated acid-functional monomer less than 55 mol % neutralized and drying the resulting polymeric gel by means of a heated gas stream in at least two temperature zones.

Abstract: A process is described for removing isobutene oligomers from an isobutene polymer by stripping the isobutene polymer with vapors of a saturated hydrocarbon having at least 8 carbon atoms and at least partly driving out the isobutene oligomers. Troublesome isobutene oligomers are substantially removed without impairing the reactivity of the isobutene polymer (expressed as the content of the methylidene double bonds).

Abstract: The present invention relates to a continuous process for heat treatment of a particulate thermoplastic material comprising a thermoplastic semi-crystalline polymer in the solid state in a single flow-through installation comprising one or more heating zones, wherein each heating zone comprises a contact heater consisting of an array of heating plates, the granulate material is transported as a moving packed bed in the flow-through installation, the process comprises one or more heating steps and in each heating step the particulate material is heated through contact heating via the contact heater, or one of the contact heaters, and optionally a flow of inert gas is applied in one or more heating zones with a mass ratio G/M of at most 2, wherein G is the inert gas flow in kg/hour and M is the particulate material flow in kg/hour.

Abstract: A method of recycling waste plastic foam materials firstly is to smash a waste material including polyurethane foam into fine particles so as to obtain a first starting material. The first starting material is then crisped and followingly milled into powder so as to obtain a second starting material. The second starting material is then placed into a mixer to mix with a first foaming reaction solution including polyol, catalyst and additives injected into the mixer so as to form a semi-treated foaming material. And then, the semi-treated foaming material is mixed with a second foaming reaction solution including diisocyanate injected into the mixer so as to obtain a completed-treated foaming material. Lastly, the completed-treated foaming material is poured into a mold and then water vapor is uniformly introduced into the mold so as to induce the completed-treated foaming material to proceed foaming reaction.