The Hetero Ring Is Six-membered And Contains At Least Two Nitrogens Patents (Class 534/632)
  • Patent number: 11485712
    Abstract: Disclosed is a compound of Formula I, including N-oxides, and salts thereof, wherein R1, R2 and R3 are defined as set forth in the disclosure. Also disclosed is a process for preparing a compound of Formula I. A compound of Formula I can also be used as a synthetic intermediate to prepare pyridazinone-based herbicides.
    Type: Grant
    Filed: September 26, 2019
    Date of Patent: November 1, 2022
    Assignee: FMC Corporation
    Inventors: Stephen Frederick McCann, Thomas Martin Stevenson
  • Patent number: 10214648
    Abstract: The present invention relates to novel bisazo dyes, a process for their preparation and their use for dyeing and/or printing substrates.
    Type: Grant
    Filed: March 31, 2015
    Date of Patent: February 26, 2019
    Assignee: ARCHROMA IP GMBH
    Inventors: Asad Bilal Haleem, Shahid Ali Ahmed
  • Publication number: 20150096131
    Abstract: Reactive dyes of formula (1) wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, X is halogen, 3- or 4-carboxypyridin-1-yl, or 3- or 4-carbamoylpyridin-1-yl, Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, and q is the number 1 or 2, are suitable for dyeing and printing cellulosic or amide-group-containing fibre materials.
    Type: Application
    Filed: May 24, 2013
    Publication date: April 9, 2015
    Inventors: Georg Roentgen, Jean-Christophe Graciet, Rainer Hildebrand, Laszlo Fekete, Marie Schmidlin, Hubert Jean-Luc Christnacher
  • Publication number: 20100132135
    Abstract: Reactive dyes of formula (I), wherein D is a radical of formulae (II, IV, VI) or (VII), R1 is hydrogen, acetyl, sulfo, ?,?-dibromopropionylamino, ?-bromoacryloylamino, ?-chlomethylsulfonylbutyrylamino, ?-sulfatoethylsulfonylbutyrylamino or vinylsulfonylbutyrylamino, R2 is methyl or methoxy, X is halogen, Y is vinyl or ?-sulfatoethyl and Z is hydroxy, vinyl or ?-sulfatoethyl, are suitable especially for dyeing cotton and yield dyeings having good all-round fastness properties.
    Type: Application
    Filed: June 28, 2006
    Publication date: June 3, 2010
    Applicant: Huntsman International LLC
    Inventors: Georg Roentgen, Dragana Djokic, Laszlo Fekete
  • Patent number: 7598357
    Abstract: The present invention relates to a novel bis-reactive dye with N,N-dialkylamino bridge group, represented by the following formula (I): wherein E1, E2, R, R1, R2, R3, R4, R5, R6, G, G?, B, B?, X, m, and n are defined the same as the specification. The bis-reactive dye of the present invention is suitable for exhaust dyeing, cold pad batch, continuous dyeing, printing and digital spray printing materials that contain hydroxyl group or polyamine fibers.
    Type: Grant
    Filed: October 28, 2008
    Date of Patent: October 6, 2009
    Assignee: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Hong-Chang Huang, Ya-Cing Yu
  • Publication number: 20080207881
    Abstract: A reactive dyestuff containing an alkylthio-s-triazinyl reactive group of the following formula (I) is disclosed, wherein A, X, Y, Z, R, Q, and a are defined the same as the specification. It is suitable for exhaust dyeing, cold batch-up dyeing and continuous dyeing materials that contain hydroxyl group or nitrogen group fibers.
    Type: Application
    Filed: April 30, 2008
    Publication date: August 28, 2008
    Applicant: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Hsien-Chung Shia, Duncan Adrian Sidney Phillips, John Anthony Taylor
  • Publication number: 20080039614
    Abstract: A reactive dyestuff containing an alkylthio-s-triazinyl reactive group of the following formula (I) is disclosed, wherein A, X, Y, Z, R, Q, and a are defined the same as the specification. It is suitable for exhaust dyeing, cold batch-up dyeing and continuous dyeing materials that contain hydroxyl group or nitrogen group fibers.
    Type: Application
    Filed: February 15, 2007
    Publication date: February 14, 2008
    Applicant: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Hsien-Chung Shia, Duncan Adrian Sidney Phillips, John Anthony Taylor
  • Patent number: 6852135
    Abstract: Dyes of the general formula (1): where M is hydrogen, alkali, ammonium or the equivalent of an alkaline earth metal ion, X is halogen, alkoxy or an N-containing heterocycle, Q is a grouping of the formula (e) where Y is vinyl or an alkali-eliminable grouping and W is alkyl which may be interrupted by an O or an NR group and the radicals R1 and R2 represent alkyl, alkoxy, alkylcarbonylamino, arylcarbonylamino, and also the radicals R3 and R4 are alkyl or hydrogen, their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing material, preferably fiber material.
    Type: Grant
    Filed: July 14, 2001
    Date of Patent: February 8, 2005
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Joachim Steckelberg, Hermann Henk
  • Publication number: 20040211013
    Abstract: Method for the trichromatic dyeing or printing of synthetic polyamide fiber material, wherein at least one red reactive dye of formula 1
    Type: Application
    Filed: May 17, 2004
    Publication date: October 28, 2004
    Inventors: Jurgen Schmiedl, Klaus Koch, Wolfgang Mundle, Franz Gruner
  • Publication number: 20040187232
    Abstract: The invention provides a water-soluble ink capable of forming an image having good color hue and high fastness in various use and environmental conditions, which comprises a coloring composition comprising a disazo dye represented by the following formula 1: A1-N═N-A2-N═N-A3 and at least one other dye having a specific structure; in formula 1, A1, A2 and A3 each independently represents an aromatic group which may be substituted or a heterocyclic group which may be substituted, and A1 and A3 each is a monovalent group and A2 is a divalent group.
    Type: Application
    Filed: January 7, 2004
    Publication date: September 30, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Tomohiro Chino, Toshiki Fujiwara, Masaru Takasaki
  • Publication number: 20040138435
    Abstract: The present invention refers to dyestoffs of the formula I wherein Ar is a group of the formula II or of the formula III, D is a group of the formula IV, or of the formula V wherein the variables are defined as given in claim 1, processes for their preparation and their use for dyeing and printing hydroxy- and/or carboxamido-containing fibre materials.
    Type: Application
    Filed: November 6, 2003
    Publication date: July 15, 2004
    Inventor: Warren James Ebenezer
  • Publication number: 20040087780
    Abstract: A monoazo reactive red dyestuff of the formula (I), 1
    Type: Application
    Filed: October 17, 2002
    Publication date: May 6, 2004
    Applicant: EVERLIGHT USA, INC.
    Inventors: Huei-Chin Huang, Chia-Huei Yu
  • Publication number: 20040083924
    Abstract: Compouns of formula (I) 1
    Type: Application
    Filed: August 1, 2003
    Publication date: May 6, 2004
    Inventor: Martin Oberholzer
  • Publication number: 20040068102
    Abstract: Provided are novel yellow azo dyes which are useful in ink compositions, especially ink jet ink compositions. The dyes and ink compositions of the present invention exhibit a good balance of optical density, print reliability, water fastness and light fastness and exhibit improved water solubility, thus rendering the ink compositions to be especially suitable for printheads having small nozzle openings.
    Type: Application
    Filed: October 7, 2002
    Publication date: April 8, 2004
    Inventors: Ann P. Holloway, James Frederic Feeman
  • Publication number: 20040024189
    Abstract: The present writing relates to a novel fiber-reactive dye of the formula 1
    Type: Application
    Filed: May 29, 2003
    Publication date: February 5, 2004
    Inventors: Sung Yong Cho, Tae Chung Kang, Woo Jin Yoon, Sang Ki Yang, Sung Il Myung, Ho Lee
  • Patent number: 6670457
    Abstract: Compounds of the formula in which the variables are as defined in the claims, which are suitable as fiber-reactive dyes for dyeing widely varying fiber materials, are described.
    Type: Grant
    Filed: August 16, 2002
    Date of Patent: December 30, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rolf Deitz, Bernhard Müller, Athanassios Tzikas
  • Publication number: 20030212261
    Abstract: The present invention relates to reactive dyes of the general formula (1) 1
    Type: Application
    Filed: February 14, 2003
    Publication date: November 13, 2003
    Inventors: Stefan Meier, Werner Russ, Jorg Worner
  • Publication number: 20030191293
    Abstract: The invention relates to reactive dyes containing a halobenzene nucleus and, in particular, reactive dyes containing a halobenzene nucleus and two or more reactive components.
    Type: Application
    Filed: April 8, 2002
    Publication date: October 9, 2003
    Applicant: BASF Akiengesellschaft
    Inventors: Warren James Ebenezer, David Greenwood, Michael Gordon Hutchings, Michael Alan Rabjohns, Andrea Maria Zamponi
  • Publication number: 20030158395
    Abstract: 1.
    Type: Application
    Filed: June 3, 2002
    Publication date: August 21, 2003
    Applicant: BASF Akiengesellschaft
    Inventors: Warren James Ebenezer, David Greenwood, Michael Gordon Hutchings, Michael Alan Rabjohns, Andrea Maria Zamponi
  • Patent number: 6319290
    Abstract: Compounds of the general formula (I) wherein R1 represents hydrogen or a C1-C4-alkyl group, X represents the radical of aliphatic, cyclic or aromatic diamines and Y represents hydrogen or an alkali metal, and a process for their preparation and their use for dyeing organic substrates, and organic substrates dyed with these compounds.
    Type: Grant
    Filed: December 9, 1999
    Date of Patent: November 20, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Detlef Kalweit, Martin Oberholzer
  • Patent number: 6177552
    Abstract: Described are fiber-reactive water-soluble azo compounds which contain a group of the general formula (2) as diazo component where R21 is hydrogen, methyl, ethyl, methoxy, ethoxy or sulfo, R22 is hydrogen, methyl, ethyl, methoxy, ethoxy or sulfo, R23 is hydrogen, alkyl of 1 to 4 carbon atoms or phenyl, n is 2 or 3 and the group —SO2—Y is a fiber-reactive group of the vinyl sulfone series, and which are capable of dyeing hydroxy- and/or carboxamido-containing material, especially fiber material, such as cellulose fibers, for example cotton, or regenerated cellulose fibers and also wool and synthetic polyamide fibers in high color strength and good fastnesses.
    Type: Grant
    Filed: December 28, 1999
    Date of Patent: January 23, 2001
    Assignee: DyStarTextilfarben GmbH & Co. Deutschland KG
    Inventors: Uwe Reiher, Ron Pedemonte
  • Patent number: 6086640
    Abstract: For dyeing (printing, for example) cellulose fibers with a reactive dye, a blue compound is greatly desired, the blue compound being capable of generating a product dyed in blue at excellent dyeing reproducibility and with good light fastness and superior fastness against chlorine water, involving less staining of white area. The invention relates to a formazan compound in a free acid form as represented by the following formula I, a dyeing method of cellulose fibers using the same and a final dyed product prepared by the method, characterized in that the compound, the method and the product are suitable so as to overcome the problem.Formula I ##STR1## (wherein R represents hydrogen, sulfo group, hydroxyl group, halogen, a C1-C4 alkyl group, a C1-C4 alkoxyl group or carboxyl group; and M represents copper or nickel.
    Type: Grant
    Filed: August 9, 1999
    Date of Patent: July 11, 2000
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Toru Tabei, Eiichi Ogawa, Shin-ichi Namba
  • Patent number: 6022956
    Abstract: Described are fiber-reactive, water-soluble monoazo compounds conforming to the hereinbelow indicated and defined general formula (1) that are capable of dyeing hydroxyl- and/or carboxamido-containing material, especially fiber material, such as cellulose fibers, for example cotton, or regenerated cellulose fibers and also wool and synthetic polyamide fibers in red shades and in high color strength and good fastnesses. ##STR1## where M is hydrogen or an alkali metal, m is 1, 2 or 3, X is chlorine or fluorine, R.sup.0 is hydrogen or carboxyl, R is alkyl of 1 to 4 carbon atoms which is unsubstituted or substituted by hydroxyl, carboxyl, sulfo, sulfato, phosphate, chlorine, alkanoyloxy of 2 to 5 carbon atoms or alkoxy of 1 to 4 carbon atoms, and R is hydrogen, alkyl of 1 to 4 carbon atoms, which may be substituted, alkoxy of 1 to 4 carbon atoms, which may be substituted, alkanoylamino of 2 to 5 carbon atoms, optionally substituted benzoylamino or halogen, and R.sup.2 is hydrogen, carboxyl or sulfo and the --SO.
    Type: Grant
    Filed: May 10, 1999
    Date of Patent: February 8, 2000
    Assignee: Dy Star Textilfarben GmbH & Co. Deutschland KG
    Inventors: Jorg Dannheim, Manfred Hoppe
  • Patent number: 6005084
    Abstract: Fibre-reactive asymmetrical triphenodioxazine compounds conform to the formula I ##STR1## where the individual symbols are as defined in the description, and mixtures thereof and are present in the form of a free acid or as salt. They are used as reactive dyes for dyeing or printing hydroxyl-containing or nitrogenuos organic substrates, such as leather or fiber material consisting of or comprising natural or synthetic polyamides or natural or regenerated cellulose; the most preferred substrate is textile material consisting of or comprising cotton.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: December 21, 1999
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Detlef Kalweit, Roland Wald
  • Patent number: 5969113
    Abstract: Compounds of the formula ##STR1## in which the variables are as defined in the claims, which are suitable as fibre-reactive dyes for dyeing widely varying fibre materials, are described.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: October 19, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rolf Deitz, Bernhard Muller, Athanassios Tzikas
  • Patent number: 5952476
    Abstract: A red reactive dyestuff of the formula (I) ##STR1## wherein the substituents have the meaning given in the description. The red reactive dyestuff of the present invention is suitable for dying and printing on cellulose fiber such as cotton, artificial cotton, linen and artificial linen, etc., and polyamide and polyurethane fibers like wool, silk and nylon, etc. It is also suitable for dying and printing on mixed or cross-linking spinning of cellulose fiber or polyamide fiber and polyurethane fiber, polyacrylonitrile fiber and other fiber.
    Type: Grant
    Filed: August 21, 1998
    Date of Patent: September 14, 1999
    Assignee: Everlight USA, Inc.
    Inventors: Duncan Adrian Sidney Phillips, Yung-Chien Kao
  • Patent number: 5929217
    Abstract: Reactive dyes of the formula I ##STR1## where a is 1 or 2,b is 0 or 1,Z.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, halogen, nitro, amino, hydroxysulfonyl, C.sub.1 -C.sub.6 -alkoxycarbonyl, carbamoyl or C.sub.1 -C.sub.6 -mono- or dialkylcarbamoyl,A is methylene, carbonyl, sulfonyl or a radical of the formula CH.sub.2 --CO or CH.sub.2 --SO.sub.2,X is a direct linkage or a linker,Y.sup.1 is vinyl or a radical of the formula C.sub.2 H.sub.4 Q where Q is a group which can be eliminated under alkaline conditions,W is in case 1) the radical of a chromophore which may have further reactive groups, or in case 2) the radical of a coupling component to which additionally the radical of a diazo component may be linked via an azo bridge and which may have additional reactive groups, andL.sup.1 and L.sup.2 are each linkers,their intermediates and a process for dyeing or printing substrates having hydroxyl groups or nitrogen atoms using the novel dyes are described.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: July 27, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Patsch, Hermann Loffler, Claus Marschner
  • Patent number: 5808015
    Abstract: Dyestuffs of the formula ##STR1## wherein D is the radical of a carbo- or heterocyclic diazo component,X represents O, NH, NT, NCOT, NCCH.sub.2 T or NSO.sub.2 T,are preferably suitable, if m=n=l=o, for dyeing and printing hydrophobic synthetic fiber materials and mixtures thereof with naturally occurring fiber materials.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: September 15, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventor: Rainer Hamprecht
  • Patent number: 5760195
    Abstract: Reactive dyes of the formula ##STR1## wherein D is a radical of the formula ##STR2## and R.sub.1, R.sub.2, R.sub.3, X.sub.1 and V.sub.1 are as defined in claim 1, are particularly suitable for dyeing or printing natural or synthetic polyamide fibre materials.
    Type: Grant
    Filed: November 19, 1996
    Date of Patent: June 2, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Marcel Frick
  • Patent number: 5731421
    Abstract: Reactive dyes of the formula ##STR1## in which K and Z are as defined in claim 1, are suitable in particular for the dyeing and printing of cellulose-containing fibre material and produce dyeings and prints having good fastness properties in high coloristic yield.
    Type: Grant
    Filed: June 30, 1995
    Date of Patent: March 24, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Athanassios Tzikas, Claudia Carisch
  • Patent number: 5721343
    Abstract: Fiber-reactive monoazo and disazo compounds of the formulaD-N.dbd.N--Kwhich compounds are in free acid or salt form, and mixtures thereof, are useful for dyeing or printing hydroxy group- or nitrogen-containing organic substrates, for example leather and fiber material comprising natural or synthetic polyamides or natural or regenerated cellulose; the most preferred substrate is a textile material comprising cotton.
    Type: Grant
    Filed: May 2, 1995
    Date of Patent: February 24, 1998
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Paul Doswald, Rainer Nusser, Roland Wald
  • Patent number: 5717078
    Abstract: Reactive dyes of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,X.sub.1 and X.sub.2 are halogen,B.sub.1 is an aromatic or aliphatic bridge member, or the radical of the formula --N(R.sub.2)--B.sub.1 --N(R.sub.3)-- is a piperazine radical,A.sub.1 is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore and,A.sub.2 is a radical of the formula ##STR2## in which D.sub.1 is substituted or unsubstituted phenyl or naphthyl,R.sub.5 and R.sub.6 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl, alk is substituted or unsubstituted C.sub.2 -C.sub.6 alkylene andZ is vinyl or a radical --CH.sub.2 --CH.sub.2 --U.sub.1, and U.sub.1 is a leaving group, andthe radicals A.sub.1 and A.sub.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: February 10, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Athanassios Tzikas, Peter Aeschlimann
  • Patent number: 5654410
    Abstract: Fibre-reactive monoazo compounds of the formula ##STR1## which compounds are in free acid or salt form, and mixtures thereof, are useful for dyeing or printing hydroxy group- or nitrogen-containing organic substrates, for example leather and fibre material comprising natural or synthetic polyamides or natural or regenerated cellulose; the most preferred substrate is a textile material comprising cotton.
    Type: Grant
    Filed: August 19, 1996
    Date of Patent: August 5, 1997
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Rainer Nusser, Roland Wald
  • Patent number: 5629410
    Abstract: The invention relates to compounds of formula ##STR1## wherein the variables are as claimed in the claims and which are suitable as fibre-reactive dyes for dyeing a wide range of fibre materials.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: May 13, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Deitz, Bernhard M uller, Athanassios Tzikas
  • Patent number: 5614613
    Abstract: A compound of the Formula (1) and salts thereof: ##STR1## wherein: R.sup.1 and R.sup.2 are each independently optionally substituted alkyl;R.sup.3 is H or optionally substituted alkyl;X is a labile atom or group;Y is a labile atom or group or a group of formula ##STR2## or --OR.sup.5 ; R.sup.4 is H or alkyl;R.sup.5 is H or optionally substituted alkyl or aryl; andm and n each independently have a value of 0 or 1.The compounds are useful for the coloration of textile materials.
    Type: Grant
    Filed: March 3, 1994
    Date of Patent: March 25, 1997
    Assignee: Zeneca Limited
    Inventor: John A. Taylor
  • Patent number: 5597902
    Abstract: Reactive dyestuffs which, in the form of the free acid, correspond to the following formula ##STR1## wherein D is the radical of an organic dyestuff of the monoazo, polyazo or metal complex azo series and the other substituents have the meaning given in the description, show improved application properties.
    Type: Grant
    Filed: April 27, 1993
    Date of Patent: January 28, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Konrad Bootz, Manfred Hoppe, Eckhard Bock, Wolfram Reddig, Thomas Eizenh ofer, Wolfgang Harms, Karl-Joseph Herd
  • Patent number: 5591834
    Abstract: Reactive dyestuffs of the formula ##STR1## in which Z is a cyano-free pyrimidine reactive group and the remaining groups have the meaning given in the description, are highly suitable for the dyeing and printing of hydroxyl- or amido-containing materials.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: January 7, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Konrad Bootz, Karl-Josef Herd
  • Patent number: 5578712
    Abstract: Fibre-reactive monoazo compounds of the formula ##STR1## which compounds are in free acid or salt form, and mixtures thereof, are useful for dyeing or printing hydroxy group- or nitrogen-containing organic substrates, for example leather and fibre material comprising natural or synthetic polyamides or natural or regenerated cellulose; the most preferred substrate is a textile material comprising cotton.
    Type: Grant
    Filed: May 2, 1995
    Date of Patent: November 26, 1996
    Assignee: Sandoz Ltd.
    Inventors: Markus Doerr, Roland Wald
  • Patent number: 5554732
    Abstract: Fibre-reactive disazo compounds of the formula ##STR1## which compounds are in free acid or salt form, and mixtures thereof, are useful for dyeing or printing hydroxy group- or nitrogen-containing organic substrates, for example leather and fibre material comprising natural or synthetic polyamides or natural or regenerated cellulose; the most preferred substrate is a textile material comprising cotton.
    Type: Grant
    Filed: May 2, 1995
    Date of Patent: September 10, 1996
    Assignee: Sandoz Ltd
    Inventors: Rainer Nusser, Roland Wald
  • Patent number: 5548071
    Abstract: The invention relates to compounds of the formula ##STR1## where the variables are each as defined in the claims. The compounds are suitable for use as dyes, in particular for dyeing and printing cellulose-containing fibre materials and produce dyeings and prints having good allround fastness properties.
    Type: Grant
    Filed: May 13, 1994
    Date of Patent: August 20, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Deitz, Athanassios Tzikas, Paul Herzig
  • Patent number: 5514782
    Abstract: Water-soluble monoazo compounds of the formula ##STR1## are described, suitable as fiber-reactive dyes for dyeing hydroxy- and/or carboxamido-containing material, in particular fiber material, such as wool and cellulose fiber materials, in which D is phenylene which can be substituted by 1 or 2 substituents customary in diazo components of fiber-reactive dyes and/or by a group of the formula Y--SO.sub.2 --(CH.sub.2).sub.m -- where Y has one of the meanings given below and m is the number 1 or 2, or is naphthylene which can be substituted by 1 or 2 substituents customary in diazo components of fiber-reactive dyes, or is benzothiazol-2-yl containing the group aforementioned Y--SO.sub.2 --(CH.sub.2).sub.n -- bonded to the carbocyclic ring thereof and can be substituted by a further substituent customary in fiber-reactive dyes, n is the number zero, 1 or 2, the group Y-SO.sub.
    Type: Grant
    Filed: April 1, 1993
    Date of Patent: May 7, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Jorg Dannheim
  • Patent number: 5502173
    Abstract: 2,4,6-trifluoro-5-chloro-pyrimidine and the aqueous solution of a salt of 2-amino-5-aminomethyl-naphthalene-1-sulphonic acid are simultaneously metered into a reactor in approximately equimolar amounts and afford a valuable intermediate for the preparation of high-purity dyes.
    Type: Grant
    Filed: September 27, 1994
    Date of Patent: March 26, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Ja/ ger, Siegbert Arnold, Richard Sommer
  • Patent number: 5498700
    Abstract: Reactive dyestuffs of the formula ##STR1## produce bluish red dyes having excellent fastness properties on hydroxyl- and amido-containing fibre material.
    Type: Grant
    Filed: September 1, 1994
    Date of Patent: March 12, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hermann Henk, Wilfried Hansmann
  • Patent number: 5463031
    Abstract: Reactive dyestuffs of the formula ##STR1## in which the substituents have the meanings given in the description are highly suitable for the dyeing and printing of cellulose materials and nitrogen-containing materials.They produce dyeings and prints having good wet and light fastness properties.
    Type: Grant
    Filed: April 12, 1994
    Date of Patent: October 31, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Jager, Frank-Michael Stohr, Karl K. Schundehutte
  • Patent number: 5459244
    Abstract: Novel polyfunctional azo reactive dyestuffs of the formula (I) ##STR1## in which Y denotes CH.sub.2 CH.sub.2 OSO.sub.3 H, CH.sub.2 CH.sub.2 Cl, CH.sub.2 CH.sub.2 OH or CH.dbd.CH.sub.2,X denotes F, Cl or OCH.sub.3, andR denotes hydrogen or C.sub.1 -C.sub.4 -alkyl, have been found, and a process for their preparation and their use for dyeing and printing hydroxyl- and amido-containing materials in hues having improved fastness properties are described.
    Type: Grant
    Filed: September 28, 1994
    Date of Patent: October 17, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventor: Klaus Kunde
  • Patent number: 5459245
    Abstract: Reactive dyestuffs which, in the form of the free acid, have the following formula ##STR1## in which the substituents have the meaning given in the description, are suitable for the dyeing and printing of hydroxyl- and amido-containing materials, in particular cellulose materials.
    Type: Grant
    Filed: October 27, 1994
    Date of Patent: October 17, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventor: Horst Jaeger
  • Patent number: 5459246
    Abstract: New reactive dyestuffs which, in the form of the free acid, correspond to the following formula ##STR1## wherein the substituents have the meaning given in the description, are suitable for dyeing and printing materials containing hydroxyl groups or amide groups, in particular cellulose materials.
    Type: Grant
    Filed: May 4, 1993
    Date of Patent: October 17, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Jager, Klaus Wunderlich
  • Patent number: 5436324
    Abstract: Improved reactive dyestuffs of the following formula (I) ##STR1## in which the substituents have the meaning given in the description. The improved reactive dyestuffs are highly suitable for the dyeing and printing of natural or synthetic OH-- and/or amido-containing materials, in particular, those made of cellulose and polyamides.
    Type: Grant
    Filed: July 23, 1992
    Date of Patent: July 25, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfram Reddig, Karl-Josef Herd
  • Patent number: 5432266
    Abstract: Preparation of water-soluble reactive dyes containing vinylsulphonyl and .beta.-sulphatoethylsulphonyl groups by the oxidation of dyes containing .beta.-hydroxyethylmercapto radicals, and then sulphation and, if appropriate, conversion of the .beta.-sulphatoethylsulphonyl radical to the vinylsulphonyl radical with bases.
    Type: Grant
    Filed: April 1, 1993
    Date of Patent: July 11, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl-Josef Herd, Peter Roschger
  • Patent number: RE37004
    Abstract: A water-soluble monoazodye having the following formula (I) in its free acid form: ##STR1## wherein X is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 W wherein W is a leaving group removable by alkali; R.sup.1 is methyl, --NHCONH.sub.2 or --NHCOT.sup.1 wherein T.sup.1 is methyl, ethyl, --CH.sub.2 CH.sub.2 COOH or --CH.dbd.CHCOOH; R.sup.2 is hydrogen, lower alkyl or lower alkoxy; and Z is ##STR2## wherein P is cyano or halogen, each of Q and U which are independent of each other, is halogen, V is halogen or ##STR3## and Y is halogen or a group of the following formula (1) or (2): ##STR4## wherein R.sup.3, A, R.sup.4 and E are as defined in the disclosure and G is as defined above, has a moderate yellow to orange color and is particularly suitable for dyeing cellulose fibers or nitrogen-containing fibers.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: December 26, 2000
    Assignee: Dystar Japan Ltd.
    Inventors: Yousuke Takahashi, Yukihara Shimizu, Toshio Hihara, Kiyoshi Himeno