At Least Two Such Hetero Rings Attached Indirectly To Each Other By Nonionic Bonding Patents (Class 534/634)
  • Patent number: 8293877
    Abstract: The present invention relates to a novel reactive dyestuff with a N-alkylamino group, represented by the following formula (I): wherein A1, A2, R1, R2, R3, R4, (R5)0-2, (R6)0-2, (Z1)0-1, (Z2)0-1, X1, X2 and n are defined the same as the specification. The reactive dyestuff of the present invention is suitable for exhaust dyeing, cold batch-up dyeing, continuous dyeing, printing and digital spray printing materials that contain hydroxyl group or amino group fibers.
    Type: Grant
    Filed: March 25, 2010
    Date of Patent: October 23, 2012
    Assignee: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Chen-Lung Kao, Chien-Yu Chen, Huei-Chin Huang
  • Patent number: 8066809
    Abstract: Reactive dyes of formula wherein R1 and R2 independently of one another are hydrogen or unsubstituted or substituted C1-C4alkyl, D is a radical of a diazo component of the formula X1 and X2 independently of one another are halogen, T is a fiber-reactive radical of the formula (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group, Hal is halogen, n is the number 0, 1 or 2, and m and q are independently of one another the number 0 or 1, are suitable for dyeing cellulosic or amide-group-containing fiber materials.
    Type: Grant
    Filed: July 31, 2007
    Date of Patent: November 29, 2011
    Assignee: Huntsman International LLC
    Inventors: Georg Roentgen, Laszlo Fekete
  • Publication number: 20110015378
    Abstract: The present invention relates to a novel reactive dyestuff with a N-alkylamino group, represented by the following formula (I): wherein A1, A2, R1, R2, R3, R4, (R5)0-2, (R6)0-2, (Z1)0-1, (Z2)0-1, X1, X2 and n are defined the same as the specification. The reactive dyestuff of the present invention is suitable for exhaust dyeing, cold batch-up dyeing, continuous dyeing, printing and digital spray printing materials that contain hydroxyl group or amino group fibers.
    Type: Application
    Filed: March 25, 2010
    Publication date: January 20, 2011
    Applicant: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Chen-Lung Kao, Chien-Yu Chen, Huei-Chin Huang
  • Publication number: 20100159140
    Abstract: Reactive dyes of formula wherein R1 and R2 independently of one another are hydrogen or unsubstituted or substituted C1-C4alkyl, D is a radical of a diazo component of the formula X1 and X2 independently of one another are halogen, T is a fibre-reactive radical of the formula (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group, Hal is halogen, n is the number 0, 1 or 2, and m and q are independently of one another the number 0 or 1, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
    Type: Application
    Filed: July 31, 2007
    Publication date: June 24, 2010
    Applicant: HUNTSMAN INTERNATIONAL LLC
    Inventors: Georg Roentgen, Laszlo Fekete
  • Patent number: 7598357
    Abstract: The present invention relates to a novel bis-reactive dye with N,N-dialkylamino bridge group, represented by the following formula (I): wherein E1, E2, R, R1, R2, R3, R4, R5, R6, G, G?, B, B?, X, m, and n are defined the same as the specification. The bis-reactive dye of the present invention is suitable for exhaust dyeing, cold pad batch, continuous dyeing, printing and digital spray printing materials that contain hydroxyl group or polyamine fibers.
    Type: Grant
    Filed: October 28, 2008
    Date of Patent: October 6, 2009
    Assignee: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Hong-Chang Huang, Ya-Cing Yu
  • Patent number: 7442780
    Abstract: New, highly multifunctional reactive dye compounds are provided. The number of leaving groups in the non-chromophoric part of the molecule added to the number of chromophore moieties is at least equal to 5, preferably in the range of from 5 to 12, more preferably from 5 to 6. The new reactive dye compounds preferably have at least two asymmetric bridges.
    Type: Grant
    Filed: May 28, 2002
    Date of Patent: October 28, 2008
    Assignee: North Carolina State University
    Inventors: Wei Dong He, Peter Jeffrey Broadbent, David Malcolm Lewis
  • Patent number: 7439340
    Abstract: A reactive dyestuff containing an alkylthio-s-triazinyl reactive group of the following formula (I) is disclosed, wherein A, X, Y, Z, R, Q, and a are defined the same as the specification. It is suitable for exhaust dyeing, cold batch-up dyeing and continuous dyeing materials that contain hydroxyl group or nitrogen group fibers.
    Type: Grant
    Filed: February 15, 2007
    Date of Patent: October 21, 2008
    Assignee: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Hsien-Chung Shia, Duncan Adrian Sidney Phillips, John Anthony Taylor
  • Publication number: 20080207881
    Abstract: A reactive dyestuff containing an alkylthio-s-triazinyl reactive group of the following formula (I) is disclosed, wherein A, X, Y, Z, R, Q, and a are defined the same as the specification. It is suitable for exhaust dyeing, cold batch-up dyeing and continuous dyeing materials that contain hydroxyl group or nitrogen group fibers.
    Type: Application
    Filed: April 30, 2008
    Publication date: August 28, 2008
    Applicant: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Hsien-Chung Shia, Duncan Adrian Sidney Phillips, John Anthony Taylor
  • Patent number: 7132515
    Abstract: The invention relates to reactive dyes according to the given, defined general formula (I) wherein D1 and D2 , R and R*, in addition to M are defined as per claim 1.
    Type: Grant
    Filed: April 15, 2003
    Date of Patent: November 7, 2006
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventor: Joachim Eichhorn
  • Patent number: 7109313
    Abstract: The present invention relates to dyes of the general formula (I) where X1 is a radical —CH2CH2Z or —CH?CH2, Z being analkali-eliminable group, X2 is alkyl, alkoxy, halogen, COOM or SO3M, X3 is a heterocyclic reactive group of the general formula (IIa) or (IIb) ?or a reactive group of the formula (IIc), (IId) or (IIe) the stated variables being as defined in claim 1, to processes for preparing them and to their use for dyeing and printing hydroxyl-containing and/or carboxamido-containing material.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: September 19, 2006
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Stefan Meier, Werner Russ, Stefan Ehrenberg
  • Patent number: 7038023
    Abstract: The present invention refers to dyestuffs of the formula I wherein R is an optionally substituted alkyl group; each of R1, R2 and R3, independently, is H or an optionally substituted alkyl group; each of X1 and X2, independently, is a labile atom or group; and each of A1 and A2, independently, is a chromophoric residue, processes for their preparation and their use for dyeing and printing hydroxy- and/or carboxamido-containing fiber materials.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: May 2, 2006
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Warren James Ebenezer, Werner Russ
  • Patent number: 7026458
    Abstract: The present invention refers to dyestuffs of the formula (I) wherein R1 is H or (C1–C4)-alkyl; R2 is H or (C1–C4)-alkyl; each of X1 and X2, independently, is a labile atom or group; and M is H, an alkali metal, an ammonium ion or the equivalent of an alkaline earth metal, wherein compounds wherein R1 and R2 are H are excluded, mixtures of the dyestuffs of the formula (I) with dyestuffs of the formula (II) wherein each of X3 and X4, independently, is a labile atom or group; L is an organic linking group; and M is H, an alkali metal, an ammonium ion or the equivalent of an alkaline earth metal, processes for the preparation of said dyestuffs and said dyestuff mixtures and their use for dyeing and printing hydroxy- and/or carboxamido-containing fiber materials.
    Type: Grant
    Filed: September 9, 2004
    Date of Patent: April 11, 2006
    Assignee: DyStar Textilfarben GbmH & Co. Deutschland KG
    Inventors: Werner Russ, Warren James Ebenezer, Anthony Lawrence
  • Patent number: 6953845
    Abstract: Reactive dyes of formula wherein A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, R1, R2 and R3 are each hydrogen or unsubstituted or substituted C1-C4alkyl, X1 and X2 are halogen, B is an organic bridging member, T is a reactive radical as defined herein and V1 and V2 are each independently of the other N, C—H, C—Cl or C—F, give prints that are distinguished by brilliant color shades and good all-round properties.
    Type: Grant
    Filed: July 14, 2003
    Date of Patent: October 11, 2005
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Athanassios Tzikas, Hans Reichert, Herbert Klier
  • Patent number: 6946549
    Abstract: The present invention refers to dyestoffs of the formula I wherein Ar is a group of the formula II or of the formula III, D is a group of the formula IV, or of the formula V wherein the variables are defined as given in claim 1, processes for their preparation and their use for dyeing and printing hydroxy- and/or carboxamido-containing fiber materials.
    Type: Grant
    Filed: May 4, 2002
    Date of Patent: September 20, 2005
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventor: Warren James Ebenezer
  • Patent number: 6870035
    Abstract: Deep black-dyeing dye mixtures comprising a disazo dye conforming to the general formula (1), and one or more disazo dyes conforming to the general formula (2), wherein the amide group is in the 6, 7, or 8 position relative to the hydroxy group and wherein: M, n, W, R1, R2, R3, R4, R5, R11, L1, L2, L3 are as defined in claim 1 methods for their preparation and use thereof for dyeing hydroxyl- and/or carboxamido-containing fiber material.
    Type: Grant
    Filed: August 12, 2003
    Date of Patent: March 22, 2005
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Ronald Pedemonte, Joachim Steckelberg, Werner Russ
  • Patent number: 6864361
    Abstract: The present invention refers to dyestuffs of the formula I wherein each of R1, R2, R3, R4 and R5, independently, is H or an optionally substituted alkyl group; each of X1 and X2, independently, is a labile atom or group; each of x and y, independently, is 0 or 1 and at least one of x and y is 1; each of a and b is 2 to 5 and when each of x and y is 1, a>b; and z is 0, 1, 2, 3 or 4; and wherein the variables D1 and D2 are defined as given in claim 1, processes for their preparation and their use for dyeing and printing hydroxy- and/or carboxamido-containing fiber materials.
    Type: Grant
    Filed: July 1, 2003
    Date of Patent: March 8, 2005
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Warren James Ebenezer, Werner Russ
  • Patent number: 6864360
    Abstract: The present invention refers to trisazo dyes of the formula I or an alkali metal salt thereof; wherein: Ar1 is an optionally substituted arylene group; Ar2 is an optionally substituted aryl group; R1, R2, R3, R4, X1 and X2 are defined as given in claim 1; each of D1 and D2, independently, is a chromophore group of the formula ?wherein the variables are defined as given in claim 1, a process for their preparation and a process for colouring fibre material containing a group reactive with a reactive dye.
    Type: Grant
    Filed: July 21, 2001
    Date of Patent: March 8, 2005
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventor: Warren James Ebenezer
  • Patent number: 6809187
    Abstract: Reactive copper, cobalt or chromium complex compounds of the general formula (1) where R1-R5, M, Me, W1, X, k, l and m are each as defined in claim 1, processes for their preparation and their use for dyeing or printing textile fiber materials.
    Type: Grant
    Filed: April 10, 2003
    Date of Patent: October 26, 2004
    Assignee: Oystar Textil Farben GmbH & Co.
    Inventors: Stefan Ehrenberg, Klaus Kunde
  • Patent number: 6762288
    Abstract: The present invention relates to reactive azo dyes of the formula (I) or an alkali metal salt thereof, wherein A is formula (i) or (ii) C is an optionally substituted aromatic or heteroaromatic residue; and R1, R2, B, D, Y, a, b, c, d and n are defined as given in claim 1, a process for preparing said dyes and a process for colouring fibre material, which comprises applying thereto said dyes.
    Type: Grant
    Filed: November 15, 2002
    Date of Patent: July 13, 2004
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventor: Warren James Ebenezer
  • Patent number: 6713613
    Abstract: A reactive dye compound comprising: (a) at least one chromophore moiety (b) at least one nitrogen-containing heterocycle (c) a linking group to link each chromophore moiety to each nitrogen-containing heterocycle; characterised in that at least one nitrogen-containing heterocycle is substituted with at least one oxy- or thio-carbonyl derivative wherein the oxy- or thio-carbonyl derivative is selected from Y wherein Y is —A(CO)R* wherein A is selected from O or S and wherein R* is an organic residue which comprises at least one nucleophilic group, and salts thereof.
    Type: Grant
    Filed: November 8, 2001
    Date of Patent: March 30, 2004
    Assignee: North Carolina State University
    Inventors: David Malcolm Lewis, Wei Dong He, Taher Iqbal Yousaf, Gilles Yves Marie Fernand Genain
  • Patent number: 6398822
    Abstract: Packaged hair coloring composition comprising a stable aqueous hair coloring composition comprising a compound of formula (I): wherein the variables are each as defined in the claims. The packaged hair coloring compositions of the present invention provide improved wash fastness of dye on hair, less color fade over time, improved consumer acceptance in terms of providing a single packaged hair dye composition and improved product stability.
    Type: Grant
    Filed: December 18, 2000
    Date of Patent: June 4, 2002
    Assignee: The Proctor & Gamble Company
    Inventors: Earl David Brock, Heather Holden Harper, Taher Iqbal Yousaf
  • Patent number: 6399751
    Abstract: This application relates to reactive dyes having at least one halobenzene nucleus linked to a chromophoric group via an amino linkage and additionally containing a second reactive group.
    Type: Grant
    Filed: July 24, 2000
    Date of Patent: June 4, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Warren James Ebenezer, David Greenwood, Michael Gordon Hutchings, Michael Alan Rabjohns, Andrea Maria Zamponi
  • Patent number: 6395885
    Abstract: The use of lithium as a cation for an anionic dye to enhance the light-fastness of the dye. Also claimed are the lithium salts of certain anionic dyes as defined in the description; mixed lithium/sodium salts of an anionic dye wherein the molar ratio of lithium to sodium is from 1:4 to 99:1 and at least 20 mole % of the total counter ions in the dye are lithium cations; inks containing the dyes; a method of ink jet printing using the inks; a substrate printed with the inks; an ink jet printer cartridge containing the ink and a ink jet printer containing the ink jet printer cartridge.
    Type: Grant
    Filed: December 5, 2000
    Date of Patent: May 28, 2002
    Assignee: Avecia Limited
    Inventors: Aidan Joseph Lavery, Janette Watkinson, John Parker Meyers
  • Patent number: 6372893
    Abstract: Claimed are novel azo dyes of the formula (I) where the substituents are each as defined in the claims, their preparation, their use as dyes and as an ingredient of an ink-jet printing ink and also substrates dyed with such compounds.
    Type: Grant
    Filed: October 31, 2000
    Date of Patent: April 16, 2002
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Rainer Nusser
  • Patent number: 6359121
    Abstract: A reactive disazo dye of the formula (I) D1—Y—D2 wherein each of D1 and D2 is a chromophore of the formula (II) in which X is fluorine, chlorine or optionally substituted pyridinium, an SO3H is present in the 5-or 6-position of the naphthalene nucleus, n is 0 or 1, and Y is a bridging group or a sulphonic acid salt of the dye of formula (I). The dyes may be used for dyeing, printing or ink-jet printing, for example, of textile materials and paper and are particularly valuable for coloring cellulosic textile materials.
    Type: Grant
    Filed: January 31, 2001
    Date of Patent: March 19, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Warren James Ebenezer, Donna Maria Mynett
  • Patent number: 6319290
    Abstract: Compounds of the general formula (I) wherein R1 represents hydrogen or a C1-C4-alkyl group, X represents the radical of aliphatic, cyclic or aromatic diamines and Y represents hydrogen or an alkali metal, and a process for their preparation and their use for dyeing organic substrates, and organic substrates dyed with these compounds.
    Type: Grant
    Filed: December 9, 1999
    Date of Patent: November 20, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Detlef Kalweit, Martin Oberholzer
  • Patent number: 6248871
    Abstract: Reactive dyes containing piperazine have formula (I) wherein: each of D1 and D2, independently, is a chromophoric group; each of R1, R2, R3 and R4, independently, is H or an optionally substituted alkyl group; each of X1 and X2, independently, is a labile atom or group; each of x and y, independently is 0 or 1 and at least one of x and y is 1; each of a and b independently, is 1 to 5; the or each R5, independently, is alkyl; and z is 0 to 4. For colouration of a substrate the dyes can be applied at a pH above 7 by, for example, exhaust dyeing, padding or printing.
    Type: Grant
    Filed: January 24, 2000
    Date of Patent: June 19, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Warren James Ebenezer, Donna Maria Mynett
  • Patent number: 6222023
    Abstract: A bisazo compound represented by the following general formula (1): wherein the variables are as defined in the specification, or a salt thereof is superior in various performance for dyeing and printing a fiber material.
    Type: Grant
    Filed: March 24, 2000
    Date of Patent: April 24, 2001
    Assignee: Sumitomo Chemical, Company, Limited
    Inventors: Kouji Toishi, Katsumi Agata, Toshiyuki Araki
  • Patent number: 6214977
    Abstract: A bisazo compound represented by the following general formula (1): wherein the variables are as defined in the specification and a method for dyeing or printing a fiber material using them are provided.
    Type: Grant
    Filed: April 18, 2000
    Date of Patent: April 10, 2001
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kouji Toishi, Katsumi Agata, Toshiyuki Araki
  • Patent number: 6197941
    Abstract: Reactive dyes of the formula I where a is 1 or 2, b is 0 or 1, Y is vinyl or a radical of the formula C2H4Q, where Q is an alkali-detachable group, Het is the radical of a 5- or 6-membered aromatic hetero-cyclic ring having from 1 to 3 hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, W is either in case 1) the radical of a coupling component, of a monoazo dye or additionally, when b=0, of a disazo dye, which may each bear further fiber-reactive groups, or in case 2) the radical of a chromophore which optionally has further fiber-reactive groups and is derived from an optionally metallized mono- or disazo dye, a triphendioxazine, an anthraquinone, a metallized formazan or a metallized phthalocyanine, and L1 and L2 are each a bridge member, are useful for dyeing or printing hydroxyl-containing or nitrogenous substrates.
    Type: Grant
    Filed: March 29, 1999
    Date of Patent: March 6, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Andrea Zamponi, Manfred Patsch, Helmut Hagen, Bernd-Peter Walther
  • Patent number: 6191264
    Abstract: Reactive disazo dyes of the formula (1) wherein each R independently is RA or RB where RA is a group of the formula (2), RB is a group of the formula (3) in which R1, R2, R3, R4, R5 and R6 are as defined in the description and Y is a labile atom or group. The dyes may be used for dyeing, printing or ink-jet printing of textile materials, leather, paper, coated paper, hair or film.
    Type: Grant
    Filed: June 6, 2000
    Date of Patent: February 20, 2001
    Assignee: BASF Aktiengesellschaft
    Inventor: John Anthony Taylor
  • Patent number: 6180765
    Abstract: Reactive dyes containing two units each comprising a monoazo or disazo chromophore linked to a triazinylamino group, each of which units is linked by a diamine unit disposed between the triazine rings.
    Type: Grant
    Filed: January 24, 2000
    Date of Patent: January 30, 2001
    Assignee: BASF Aktiengesellschaft
    Inventor: Warren James Ebenezer
  • Patent number: 6159250
    Abstract: Doubled reactive dyes of the general formula I ##STR1## where Chr is a chromophore residue with or without further fiber-reactive groups and derived from a metallized or unmetallized mono- or disazo dye, from a triphendioxazine, from an anthraquinone, from a metallized formazan or from a metallized phthalocyanine,Z.sup.1, Z.sup.2 and Z.sup.3 are each independently of the others hydrogen or substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl,Hal is fluorine or chlorineL.sup.1 and L.sup.2 are each independently of the other C.sub.2 -C.sub.6 -alkylene with or without interruption by 1 or 2 unadjacent oxygen atoms, andA is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, substituted or unsubstituted phenyl, substituted or unsubstituted C.sub.2 -C.sub.3 -alkenyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, substituted or unsubstituted phenoxy or C.sub.1 -C.sub.6 -alkylamino,and their mixtures are prepared and useful for dyeing or printing hydroxyl-containing or nitrogenous substances.
    Type: Grant
    Filed: December 22, 1999
    Date of Patent: December 12, 2000
    Assignee: BASF Aktiengesellschaft
    Inventor: Manfred Patsch
  • Patent number: 6160101
    Abstract: Azo dyes comprising at least one structural unit of the formula (1) ##STR1## The azo dyes according to the invention are particularly suitable for dyeing cotton and wool and produce dyeings with good allround properties.
    Type: Grant
    Filed: March 6, 2000
    Date of Patent: December 12, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Athanassios Tzikas, Rolf Deitz
  • Patent number: 6127531
    Abstract: A dyestuff according to formula (I) ##STR1## or a salt thereof wherein the substituents have the definitions as defined in claim 1.The dyestuffs are useful for dyeing or printing nitrogen-containing or hydroxy-group-containing organic substrates and for the production of printing inks.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: October 3, 2000
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Rainer Nusser
  • Patent number: 6068667
    Abstract: The present invention relates to novel, three component, mixtures comprising red reactive dyes which in the free acid forms are represented by the formula (I), (II) and (II'),a) a red reactive dye of formula (I) ##STR1## where the variables are as described in the claims. The mixtures are suitable for dyeing and printing cellulose containing fibre materials and produce dyeings and prints which exhibit good build up and fastness properties.
    Type: Grant
    Filed: May 5, 1999
    Date of Patent: May 30, 2000
    Assignee: Everlight USA, Inc.
    Inventors: Ming-Mei Yeh, Ting-Jui Chang, Sheena Lee, Da-Jong Yin
  • Patent number: 6060591
    Abstract: The disclosed dyes (which are fiber-reactive and are useful for dyeing materials containing OH and/or carboxamide groups) are compounds of the formula (1)Fb--Z.sub.n (1)in which:Fb is the radical of various classes of dyestuffs, including the formazans, azomethines, phthalocyanines, etc., and particularly sulfo group-containing monoazo or disazo dyes of the formulas (a-1) through (a-5):D.sup.1 --N.dbd.N--K.sup.2 -- (a-1)--D.sup.2 --N.dbd.N--(E--N.dbd.N).sub.v --K.sup.1 (a-2)--D.sup.2 --N.dbd.N--(E--N.dbd.N).sub.v --K.sup.2 -- (a-3)D.sup.1 --N.dbd.N--K.sup.0 --N.dbd.N--D.sup.2 -- (a-4)--D.sup.1 --N.dbd.N--K.sup.0 --N.dbd.N--D.sup.2 -- (a-5)in which in which D.sup.1 is a substituted or unsubstituted phenyl or naphthyl radical, D.sup.2 is the radical of a diazo component and K.sup.1, K.sup.2, and K.sup.0 are various coupling components, and E is a middle component.
    Type: Grant
    Filed: December 1, 1997
    Date of Patent: May 9, 2000
    Assignee: Dy Star Textilfarben GmbH & Co. Deutschland K.G.
    Inventors: Wilfried Hansmann, Hermann Henk, Stefan Ehrenberg, Wolfram Reddig
  • Patent number: 6046311
    Abstract: Dyes containing a 5,6-difluoropyrimidin-4-yl radical as fiber-reactive group are useful for dyeing hydroxy- and/or carboxamido-containing material, including fiber material, for example cellulose fibers, wool and polyamide.
    Type: Grant
    Filed: March 19, 1998
    Date of Patent: April 4, 2000
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Wilfried Hansmann, Hermann Henk, Stefan Ehrenberg, Wolfram Reddig
  • Patent number: 5998591
    Abstract: There is provided a bisazo compound which is useful as a reactive dye for dyeing or printing a fiber material in an orange to scarlet or red color; the bisazo compound being represented by the following formula (1): ##STR1## wherein m and n represents 0 or 1; W represents a divalent connecting group represented by --NH-- or --NHCONH--;D.sup.1 and D.sup.2 represent a group represented by the following formula (2a), (2b), (2c) or (2d) ##STR2## wherein Y represents --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 L, in which L represents a group eliminatable by the action of an alkali.
    Type: Grant
    Filed: May 20, 1998
    Date of Patent: December 7, 1999
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kouji Toishi, Nobutaka Kunimi, Yoshiteru Ohta
  • Patent number: 5984978
    Abstract: There are described reactive dyes of formula ##STR1## wherein the variables are as defined in the claims. The reactive dyes of formula (1) are suitable especially for dyeing or printing cellulosic fiber materials.
    Type: Grant
    Filed: February 6, 1998
    Date of Patent: November 16, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Herbert Klier, Athanassios Tzikas
  • Patent number: 5976197
    Abstract: A process for defining a substrate is provided. The process comprises applying to the substrate a water soluble dye having at least two electrophilic groups and a nucleophilic agent having a molecular weight below 600 and at least one group selected from aliphatic primary amino groups and secondary amino groups.
    Type: Grant
    Filed: January 30, 1998
    Date of Patent: November 2, 1999
    Assignee: Zeneca Limited
    Inventors: Michael Gordon Hutchings, Colin Michael Brennan, Neil Anthony Tallant, Andrew Paul Shawcross, Prakash Patel, Warren James Ebenezer
  • Patent number: 5969113
    Abstract: Compounds of the formula ##STR1## in which the variables are as defined in the claims, which are suitable as fibre-reactive dyes for dyeing widely varying fibre materials, are described.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: October 19, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rolf Deitz, Bernhard Muller, Athanassios Tzikas
  • Patent number: 5962655
    Abstract: There is provided a monoazo compound which is useful as a reactive dye for dyeing or printing a fiber material in an orange to scarlet color; and intermediate compounds for producing the compound is provided; the monoazo compound being represented by the following formula (1): ##STR1## wherein m represents 0 or 1; R.sup.1 represents a hydrogen atom or a lower alkyl group; D represents a specific diazo component of benzene type having substitution of a fiber reactive group; B.sup.1 represents a direct bond or connecting group; Z.sup.1 represents an alkylcarbonyl group, phenylcarbonyl group or a fiber-reactive group of vinylsulfone, triazine or pirimidine type; a group represented by --NR.sup.1 -- bonds to 6-position or 7-position of a naphthalene ring;and the intermediate compounds being represented by the following formulae (A) or (B): ##STR2## wherein U represents a connecting group such as alkylene and the like, Y represents vinyl or --CH.sub.2 CH.sub.
    Type: Grant
    Filed: January 20, 1998
    Date of Patent: October 5, 1999
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Nobutaka Kunimi, Shigeru Sasaki, Kouji Toishi, Atsushi Inoue
  • Patent number: 5931975
    Abstract: Dyes of the formula ##STR1## in which A.sub.1 and A.sub.2 independently of one another are the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye,R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,Y.sub.1 and Y.sub.2 independently of one another are halogen, carboxypyridinium, substituted or unsubstituted amino or a heterocyclic radical bonded via a nitrogen atom andn is a number from 1 to 7,are particularly suitable for dyeing or printing fiber materials containing hydroxyl groups or nitrogen. Dyeings with good fastness properties are obtained with a high dyeing yield.
    Type: Grant
    Filed: October 16, 1997
    Date of Patent: August 3, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Bernhard Muller, Patric Nowack
  • Patent number: 5929217
    Abstract: Reactive dyes of the formula I ##STR1## where a is 1 or 2,b is 0 or 1,Z.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, halogen, nitro, amino, hydroxysulfonyl, C.sub.1 -C.sub.6 -alkoxycarbonyl, carbamoyl or C.sub.1 -C.sub.6 -mono- or dialkylcarbamoyl,A is methylene, carbonyl, sulfonyl or a radical of the formula CH.sub.2 --CO or CH.sub.2 --SO.sub.2,X is a direct linkage or a linker,Y.sup.1 is vinyl or a radical of the formula C.sub.2 H.sub.4 Q where Q is a group which can be eliminated under alkaline conditions,W is in case 1) the radical of a chromophore which may have further reactive groups, or in case 2) the radical of a coupling component to which additionally the radical of a diazo component may be linked via an azo bridge and which may have additional reactive groups, andL.sup.1 and L.sup.2 are each linkers,their intermediates and a process for dyeing or printing substrates having hydroxyl groups or nitrogen atoms using the novel dyes are described.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: July 27, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Patsch, Hermann Loffler, Claus Marschner
  • Patent number: 5925746
    Abstract: Azo dyes of the formula (1) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are each hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,R.sub.5, R.sub.6, R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen or sulfo,D.sub.1 and D.sub.2 independently of one another are each a radical of the benzene or naphthalene series, andY.sub.1 and Y.sub.2 independently of one another are each halogen, substituted or unsubstituted amino, morpholino or piperidin-1-yl or are piperazin-1-yl which is unsubstituted or substituted on the nitrogen,with the proviso that D.sub.1 and D.sub.2 are not both sulfophenyl if Y.sub.1 and Y.sub.2 are chlorine and R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are hydrogen, are dyes for various substrates, especially cellulosic fibre materials.
    Type: Grant
    Filed: June 17, 1998
    Date of Patent: July 20, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lauk, Patric Nowack
  • Patent number: 5892006
    Abstract: The invention relates to dye mixtures which contain dyes of the formulae ##STR1## and to dyes of the formula ##STR2## in which A.sub.1, A.sub.2, A.sub.3, B, B.sub.1, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, Z.sub.1, Z.sub.2, X.sub.1, X.sub.2 and X.sub.3 are as defined in claim 1.The dyes and dye mixtures are distinguished by generally good properties and produce dyeings and prints having good wet and light fastness properties.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: April 6, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Athanassios Tzikas
  • Patent number: 5886159
    Abstract: A bisazo compound represented by the following general formula (I) or its salt is a useful fiber-reactive dye: ##STR1## where D is a phenyl or naphthyl group; B is a phenylene group, etc.; U is an aliphatic or aromatic linking group; Z is a vinyl group, etc.; and X and Y are a halogen atom, a pyridinio group, etc.
    Type: Grant
    Filed: August 18, 1997
    Date of Patent: March 23, 1999
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Nobutaka Kunimi, Kouji Toishi
  • Patent number: 5872228
    Abstract: Reactive dyestuffs of the formula (I) ##STR1## wherein A denotes the radical of a diazo component andX is a fibre-reactive heterocyclic radicalare obtained by hydrolysis of maleylated azo dyestuffs of the formula (IV) ##STR2## and subsequent reaction with reactive components of the formula X-Hal without intermediate isolation, the other substituents having the meaning given in the description.
    Type: Grant
    Filed: August 5, 1997
    Date of Patent: February 16, 1999
    Assignee: Bayer AG
    Inventor: Klaus Kunde
  • Patent number: 5847090
    Abstract: A monoazo compound useful for dyeing or printing a fiber material represented by the following general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or alkyl; U.sup.1 and U.sup.2 represent a group of the following general formula (U1), (U2) or (U3): ##STR2## wherein Y.sup.1, Y.sup.2 and Y.sup.3 represent --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 Z wherein Z represents a group which can be eliminated by the action of an alkali; and X.sup.1 and X.sup.2 represent halogeno, pyridinio or a group of the following general formula (X1), (X2), (X3) or (X4): ##STR3## or a salt thereof.
    Type: Grant
    Filed: June 4, 1997
    Date of Patent: December 8, 1998
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Nobutaka Kunimi, Atsushi Inoue, Toshiyuki Araki