Azo Bonded Directly To The Polycyclo Ring System Patents (Class 534/703)
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Patent number: 8092890Abstract: The optical information recording medium comprises a recording layer on a surface of a support. The surface of the support has pregrooves with a track pitch ranging from 50 to 500 nm, the recording layer comprises an azo metal complex dye, the azo metal complex dye is a complex of one or more azo dye and transition metal ions of which number is equal to or greater than the number of the azo dye. The azo metal complex dye comprises two or more transition metal ions per molecule, and in a molecule of the azo metal complex dye.Type: GrantFiled: April 11, 2008Date of Patent: January 10, 2012Assignee: FUJIFILM CorporationInventors: Kousuke Watanabe, Tetsuya Watanabe, Taro Hashizume, Masashi Ogiyama
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Publication number: 20100233415Abstract: The present invention is to provide an optical recording medium which is capable of performing good recording and reproducing by using a laser having a wavelength of 300 to 900 nm, a novel azo metal chelate compound, and a novel azo compound. Furthermore, the present invention is to provide an optical recording medium having an azo metal chelate compound in a recording layer.Type: ApplicationFiled: January 19, 2007Publication date: September 16, 2010Applicant: Mitsui Chemicals, Inc.Inventors: Taizo Nishimoto, Tsutomu Ishida, Kazuhiro Seino, Masataka Miyasato, Kenichi Fuji, Masao Imai, Eiichi Takahashi, Keiji Ueno, Hideo Usui, Yoshiaki Aso, Akira Ogiso, Rihoko Suzuki, Satoshi Kinoshita, Akihiro Kohsaka, Kenichi Kato, Takafumi Yoshida, Hiroyuki Sasaki, Yojiro Kumagae
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Publication number: 20090291246Abstract: An optical recording medium, which makes information be recorded and read with light having wavelength of 700 nm or shorter, with excellent light resistance, high-speed recording and high-density recording is provided. The optical recording medium comprises a substrate, a recording layer formed on the substrate and containing a host dye, which can make information be recorded or read by being irradiated with light having wavelength of 700 nm or shorter, and a reflective layer. The recording layer contains at least an azo metal-chelate dye additive, of which central metal ion is any one of Cu2+, Fe2+ and Co2+.Type: ApplicationFiled: August 10, 2006Publication date: November 26, 2009Inventors: Hisashi Shoda, Kenichi Satake, Yuko Naito
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Patent number: 6827770Abstract: A metal chelated dyestuff for inkjet recording comprising a water soluble azo metal chelated compound formed by an azo-based compound represented by the following general formula (1) having one or more hydrophilic group per molecule and a metal element; an aqueous inkjet recording liquid comprising an aqueous medium and the aforementioned metal chelated dyestuff; and an inkjet recording method using the aforementioned recording liquid are described, wherein the heterocyclic ring containing X1 is a triazole ring or the like; and Ar1 represents naphthyl group having a chelated group.Type: GrantFiled: June 18, 2002Date of Patent: December 7, 2004Assignee: Mitsubishi Chemical CorporationInventors: Tomohiro Chino, Masahiro Yamada, Hideo Sano, Wataru Shimizu, Yuukichi Murata
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Patent number: 6755903Abstract: A metal chelated dyestuff for inkjet recording is described, which is a water soluble azo metal chelated compound formed from an azo compound represented by the following general formula (1) and a metal element and is good at the clearness of color tone, light resistance, indoor discoloring and fading property, solubility, storage stability, and the like.Type: GrantFiled: June 24, 2002Date of Patent: June 29, 2004Assignee: Mitsubishi Chemical CorporationInventors: Masahiro Yamada, Tomio Yoneyama, Tomohiro Chino
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Patent number: 6712890Abstract: A water soluble compound of Formula (1) or a salt thereof: wherein: Y is an electron withdrawing group; Y1 is H, alkyl or aryl, OR or NR2 in which each R independently is H, optionally substituted alkyl or optionally substituted aryl; or Y and Y1 together form a 5- or 6- membered ring; X1 is a group or atom with co-ordinates with M; M is hexa co-ordinate metal; G is a group of Formula (2), (3) or (4); and L1, L2 and L3, each independently represent ligands required to complete hexa-coordinate geometry around metal M; wherein: S is a water solubilizing group; Ar is a benzene or naphthalene group in which X is located ortho to the azo group; X is a group or atom which co-ordinates with M; Z provides atoms or groups which complete an optionally substituted 5- or 6-membered aromatic heterocyclic ring; Ring A is an optionally substituted aromatic ring; Ring B is an optionally substituted 5- or 6-membered aromatic heterocyclic ring; n is 0, 1, 2 or 3; and the * signify the points of attachment of tType: GrantFiled: January 18, 2002Date of Patent: March 30, 2004Assignee: Avecia LimitedInventors: Maria Soteri Hadjisoteriou, Rachel Anne James
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Patent number: 6689872Abstract: An optical recording medium dye is described. The optical recording medium dye is an azo metal chelate compound, wherein the azo metal chelate compound comprises the following structure: wherein R1 is a hydrogen atom, a C1-6 straight chain or branched alkyl group, an amino group, an alkylamino group or a tolylamino group; R2 is a hydrogen atom, a hydroxyl group, a halogen atom, an ether group, a C1-6 straight chain or branched alkyl group; R3 is a hydrogen atom, a C1-6 straight chain or branched alkyl group; R4 is a hydrogen atom, a C1-6 straight chain or branched alkyl group or a halogen atom; A3 is a residue forming a heterocyclic ring derivative together with a carbon atom and a nitrogen atom.Type: GrantFiled: September 17, 2002Date of Patent: February 10, 2004Assignee: Ritek CorporationInventors: Nae-Jen Wang, Ching-Huang Chen, Li-Ling Lin, Chao-Nan Kuo, Wen-Dar Liu, Wan-Chun Chen, Shyh-yeu Wang
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Publication number: 20030148216Abstract: An optical recording medium dye is described.Type: ApplicationFiled: September 17, 2002Publication date: August 7, 2003Inventors: Nae-Jen Wang, Ching-Huang Chen, Li-Ling Lin, Chao-Nan Kuo, Wen-Dar Liu, Wan-Chun Chen, Shyh-yeu Wang
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Patent number: 6447981Abstract: Metallized azo thioether dyes having an azo group linking a substituted 3-hydroxypyridine nucleus to a phenyl nucleus are disclosed. The phenyl nucleus has an thioether substituent ortho to the azo group but does not have electron withdrawing substituents on the phenyl nucleus. The dyes are useful in optical recording elements.Type: GrantFiled: May 26, 1998Date of Patent: September 10, 2002Assignee: Eastman Kodak CompanyInventors: Derek D. Chapman, Csaba A. Kovacs
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Publication number: 20020111465Abstract: The invention relates to solid pigment preparations containingType: ApplicationFiled: July 17, 2001Publication date: August 15, 2002Inventors: Frank Linke, Kent Faubion, Udo Herrmann
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Patent number: 6251933Abstract: A compound which is a 6-substituted seco indoline of the formula (I): wherein: X is halogen or OSO2R where R represents H or C1-5 alkyl optionally substituted with from 1 to 4 hydroxyl, acid (COOH) or amino groups which amino may be optionally substituted by one or two C1-5 alkyl groups; Y is N02, N3, NHOH, NHR, NRR, N═NR, N(O)RR, SR or SSR, where R is defined as above, but that in the case where Y is SSR or N═NR, then R can also be another moiety of formula (I); or Y is a group of formula:Type: GrantFiled: June 11, 1999Date of Patent: June 26, 2001Assignee: The Cancer Research Campaign Technology LimitedInventors: William Alexander Denny, Moana Tercel, Graham John Atwell, Jared Milbank
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Patent number: 5631352Abstract: Dye mixtures which comprise at least one anionic acid dye of the formula ##STR1## together with at least one anionic acid dye of the formula ##STR2## in which the substituents are as defined in claim 1, and the novel dyes of the formulae (1) and (2) are direct dyes for cellulosic fibre materials in particular. They have a high heat stability and are particularly suitable for one-bath, one-stage dyeing of polyester/cotton blend fabrics with a disperse dye for the polyester fibres under the dyeing conditions for polyester fibres.Type: GrantFiled: June 2, 1995Date of Patent: May 20, 1997Assignee: Ciba-Geigy CorporationInventor: Urs Lauk
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Patent number: 5532342Abstract: An azo metal chelate compound of an azo compound of the formula (I) with a metal: ##STR1## wherein A is a residue forming a heterocyclic ring together with the carbon atom and the nitrogen atom to which it is bonded, X is a residue forming an aromatic group together with the two carbon atoms to which it is bonded, R.sup.1 is an alkyl group which may be substituted, an aryl group which may be substituted, an alkenyl group which may be substituted, or a cycloalkyl group which may be substituted, Y is a hydrogen atom or a cation, and n is an integer of from 1 to 3.Type: GrantFiled: April 17, 1995Date of Patent: July 2, 1996Assignee: Mitsubishi Chemical CorporationInventors: Tameichi Ochiai, Yutaka Kurose, Takumi Nagao, Takako Tsukahara, Satoru Imamura
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Patent number: 5330542Abstract: A dye-incorporated composition which comprises a cyanine type dye and an azo metal chelate compound comprising an azo type compound of the following formula (I): ##STR1## (wherein A is a residue forming a hetero ring together with the carbon atom and the nitrogen atom to which it is bonded, B is a residue forming an aromatic ring or a hetero ring together with the two carbon atoms to which it is bonded, and X is a group having an active hydrogen), and a metal, and an optical recording medium comprising a recording layer which contains the dye-incorporated composition.Type: GrantFiled: January 24, 1992Date of Patent: July 19, 1994Assignee: Mitsubishi Kasei CorporationInventors: Shuichi Maeda, Satoru Imamura, Kazuo Mitsuhashi, Takako Tsukahara
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Patent number: 5298608Abstract: A metal chelate compound comprising a monoazo compound of the following formula (I): ##STR1## (wherein A is a residue forming a hetero ring together with the carbon atom and the nitrogen atom to which it is bonded, B is a residue forming an aromatic group together with the two carbon atoms to which it is bonded, and X is a hydrogen atom or a cation), and a metal, and an optical recording medium comprising a substrate and a recording layer formed thereon for information to be written in and/or read out by laser, wherein said recording layer contains the metal chelate compound comprising a monoazo compound of the above formula (I) and a metal.Type: GrantFiled: January 16, 1992Date of Patent: March 29, 1994Assignee: Mitsubishi Kasei CorporationInventors: Tetsuo Murayama, Shuichi Maeda, Chiyoko Fukabori, Takumi Nagao
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Patent number: 5066796Abstract: Disclosed is an imaging member which comprises a conductive substrate and a photogenerating layer containing a compound selected from the group consisting of: ##STR1## and mixtures thereof, wherein Cp represents a coupler group, l, m, n, and o can each be 0, 1, 2, 3, or 4, the sum of l, m, n, and o is from 1 to 8, and M is selected from the group consisting of metals, metal oxides, metal halides, and metal hydroxy compounds.Type: GrantFiled: May 31, 1990Date of Patent: November 19, 1991Assignee: Xerox CorporationInventor: Kock-Yee Law
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Patent number: 4960870Abstract: The heavy metal complex dyes of azo or azomethine dyes of the formula ##STR1## in which D is the radical of a dizao component of the benzene, naphthalene or heterocyclic series, K--OH is the radical of the formula ##STR2## in which the symbols A, A', B and B' each represent a carbon atom or in which one of the symbols A, A', B or B' represents a nitrogen atom while the others represent a carbon atom, R is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or substituted or unsubstituted phenyl, and the ring E can be further substituted, Y is a nitrogen atom or a CH group, and n is 0 or 1, and in which --(CO).sub.n --OH is bonded to D in a position adjacent to --N.dbd.Y--, produce dyeings having good fastnesses particular very good crock, wet, wet crock and light fastness on nitrogen-containing or hydroxyl-containing fibre materials.Type: GrantFiled: February 1, 1988Date of Patent: October 2, 1990Assignee: Ciba-Geigy CorporationInventor: Urs Lehmann
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Patent number: 4892584Abstract: Novel metallized azo dyes are useful as infrared absorptive dyes in inks for ink-jet printing.Type: GrantFiled: December 5, 1988Date of Patent: January 9, 1990Assignee: Eastman Kodak CompanyInventor: Derek D. Chapman
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Patent number: 4497734Abstract: Asymmetrical 1:2 chromium complex dyestuffs which, in the form of the free acid, correspond to the formula ##STR1## wherein X represents CO or a direct bond andm represents 0 or 1 andthe rings a, b and c and, if present, fused-on benzene rings can carry further substituents customary in the chemistry of metal complex dyestuffs,are used for dyeing materials containing amide groups, in particular leather, and produce dyeings having a green hue and good general fastness properties.Type: GrantFiled: August 3, 1982Date of Patent: February 5, 1985Assignee: Bayer AktiengesellschaftInventor: Winfried Mennicke
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Patent number: 4495100Abstract: Nondiffusible compounds capable of releasing at least one diffusible cyan dye moiety having the formula: ##STR1## wherein: (a) Y represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring;(b) CAR represents a ballasted carrier moiety capable of releasing the diffusible cyan dye moiety as a function of development of a silver halide emulsion layer under alkaline conditions;(c) R represents a hydroxy group, a salt thereof, or a hydrolyzable precursor thereof, or CAR which is linked to the dye moiety through an oxygen atom thereon; and(d) n is 0, 1 or 2 with the proviso that when n is 0, then R is CAR which is linked to the dye moiety through an oxygen atom thereon.Type: GrantFiled: June 15, 1983Date of Patent: January 22, 1985Assignee: Eastman Kodak CompanyInventors: James A. Reczek, James K. Elwood
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Patent number: 4495099Abstract: Nondiffusible compounds capable of releasing at least one diffusible magenta dye moiety having the formula: ##STR1## wherein: (a) X represents the atoms necessary to complete a 5- or 6-membered heterocyclic ring;(b) Y represents the atoms necessary to complete a 5- or 6-membered heterocyclic fused ring;(c) CAR represents a ballasted carrier moiety capable of releasing the diffusible magenta dye moiety as a function of development of a silver halide emulsion layer under alkaline conditions;(d) R represents a hydroxy group, a salt thereof, or a hydrolyzable precursor thereof, or CAR which is linked to the dye moiety through an oxygen atom thereon; and(e) n is 0, 1 or 2, with the proviso that when n is 0, then R is CAR which is linked to the dye moiety through an oxygen atom thereon.Type: GrantFiled: June 15, 1983Date of Patent: January 22, 1985Assignee: Eastman Kodak CompanyInventors: Steven Evans, James K. Elwood
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Patent number: 4495098Abstract: Coordination complexes of a polyvalent metal ion and a nondiffusible compound capable of releasing at least one diffusible cyan dye moiety having the formula: ##STR1## wherein: (a) Y represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring;(b) CAR represents a ballasted carrier moiety capable of releasing the diffusible cyan dye moiety as a function of development of a silver halide emulsion layer under alkaline conditions;(c) R represents a hydroxy group, a salt thereof, or a hydrolyzable precursor thereof, or CAR which is linked to the dye moiety through an oxygen atom thereon; and(d) n is 0, 1 or 2 with the proviso that when n is 0, then R is CAR which is linked to the dye moiety through an oxygen atom thereon.Type: GrantFiled: June 15, 1983Date of Patent: January 22, 1985Assignee: Eastman Kodak CompanyInventors: James A. Reczek, James K. Elwood
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Patent number: 4481141Abstract: Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible compound having a releasable yellow dye moiety or precursor thereof, the compound having the formula: ##STR1## wherein: (a) X represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring;(b) Z represents alkyl, substituted alkyl, aryl or substituted aryl;(c) R represents CN or J-L;(d) J represents a bivalent ##STR2## (e) L represents alkyl, substituted alkyl, aryl, substituted aryl, or can be taken together with Z to complete a carbonyl-containing 5- or 6-membered heterocyclic or carbocyclic ring;(f) Z.sup.Type: GrantFiled: April 14, 1983Date of Patent: November 6, 1984Assignee: Eastman Kodak CompanyInventor: Steven Evans