The Azo Group Is Attached Indirectly In The Same Azo Moiety To An Additional Azo Group Or To An Acyclic Chain Which Contains A -ch=n- Group By Nonionic Bonding Patents (Class 534/704)
  • Patent number: 8940059
    Abstract: Disclosed is an azo compound represented by the formula (1) below, a salt thereof, or a copper complex salt compound thereof. (In the formula, R1 and R2 independently represent a hydrogen atom, a sulfonic acid group, a lower alkyl group or a lower alkoxyl group; R3-R6 independently represent a hydrogen atom, a lower alkyl group or a lower alkoxyl group; R7 represents a lower alkyl group or a lower alkoxyl group; and n represents 0 or 1.
    Type: Grant
    Filed: December 21, 2010
    Date of Patent: January 27, 2015
    Assignees: Nippon Kayaku Kabushiki Kaisha, Polatechno Co., Ltd.
    Inventors: Yuichi Sadamitsu, Takahiro Higeta
  • Patent number: 8771378
    Abstract: Disclosed is an azo compound represented by the general formula (1) or a salt thereof: wherein R1 and R2 independently represent a hydrogen atom, a lower alkyl group or a lower alkoxy group; and n represents 1 or 2. Also disclosed are a dye-containing polarizing film and a dye-containing polarizing plate, each of which comprises a polarizing film base material and the azo compound contained in the base material.
    Type: Grant
    Filed: November 17, 2010
    Date of Patent: July 8, 2014
    Assignees: Nippon Kayaku Kabushiki Kaisha, Polatechno Co., Ltd.
    Inventors: Yuichi Sadamitsu, Takuto Nishiguchi, Hiroaki Ohno
  • Patent number: 7931702
    Abstract: Disclosed is an azo compound represented by the general formula (1) or a salt thereof: wherein R1 and R2 independently represent a hydrogen atom, a lower alkyl group or a lower alkoxy group; and n represents 1 or 2. Also disclosed are a dye-containing polarizing film and a dye-containing polarizing plate, each of which comprises a polarizing film base material and the azo compound contained in the base material.
    Type: Grant
    Filed: May 24, 2007
    Date of Patent: April 26, 2011
    Assignees: Nippon Kayaku Kabushiki Kaisha, Polatechno Co., Ltd.
    Inventors: Yuichi Sadamitsu, Takuto Nishiguchi, Hiroaki Ohno
  • Patent number: 7304147
    Abstract: The present invention relates to an azo compound represented by the following formula (1): wherein A denotes a phenyl group having 1 to 3 substituents such as sulfonic acid group, amino group, lower alkyl groups and lower alkoxyl groups, or a naphthyl group, B denotes hydrogen atom, sulfonic acid group, a lower alkyl group, a lower alkoxyl group or the like, each of R1 to R4 independently denotes hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxyl group or the like, D denotes —NHCO—, —N?N— or —NH—, E denotes hydrogen atom, a lower alkyl group or a phenyl group having 1 to 3 substituents such as hydroxyl group and amino group, n denotes 0 or 1, and m denotes 0 or 1, or a salt thereof, or a copper complex compound of either of them, which is used for a polarizing plate having excellent polarization performance and durability and furthermore little color leakage in visible light range.
    Type: Grant
    Filed: April 15, 2004
    Date of Patent: December 4, 2007
    Assignees: Nippon Kayaku Kabushiki Kaisha, Polatechno Co., Ltd.
    Inventors: Yuichi Sadamitsu, Kazuyuki Kawabe
  • Patent number: 6737517
    Abstract: A metal chelated azo dyestuff containing at least one hydrophilic group and having formula (1): wherein M is a metal; A, B and C are each independently a substituted or unsubstituted aromatic ring; D is an aromatic ring optionally substituted by a group other than an azo group; m is 0 or 1; n is an integer from 0 to 3; p is an integer from 0 to 2; q is an integer from 1 to 3; with the proviso that in the event of a plurality of B's, they are the same or different; R1 and R2 are each independently hydrogen or a substituent group; M is tridentate or of higher coordination; and optionally a metal ion coordinated to A and B, B and B in the event of plural B's separated by azo or B and C, in the form of the structure: —O—M—O—.
    Type: Grant
    Filed: August 12, 2002
    Date of Patent: May 18, 2004
    Assignee: Mitsubishi Chemical Corporation
    Inventor: Wataru Shimizu
  • Patent number: 5698682
    Abstract: The present invention provides a polarizing film having high heat resistance and a high degree of polarization and excellent optical properties by dyeing a polymer film with a novel azo compound represented by the following formula (1) or (2): ##STR1##
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: December 16, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yoriaki Matsuzaki, Ryu Oi, Rihoko Imai, Keisuke Takuma, Hisato Itoh
  • Patent number: 5602237
    Abstract: The invention provides a 1:2 metal complex in which at least one of the complexants is a polyazo compound of formula ##STR1## wherein --A.sub.1 --(CO).sub.p --OH signifies the radical of a diazo component of formula H.sub.2 N--A--(CO).sub.p --OH, in which the substituent --(CO).sub.p --OH is in ortho-position to the diazotizable amino group --NH.sub.2, --A-- is the ortho-bivalent radical and p signifies 0 or 1, or a modified derivative thereof,--X-- signifies an aromatic bivalent radical,--B.sub.1 signifies the radical of a coupling component HB, or a modified derivative thereof,m signifies 0 or 1,n signifies 0, 1 or 2and M signifies hydrogen or a cation, with the proviso that m+n=1 or 2,or a mixture of such complexes and to the use thereof as dyestuffs, in particular for the dyeing of a substrate dyeable with anionic dyes, especially of leather or pelts.
    Type: Grant
    Filed: March 29, 1995
    Date of Patent: February 11, 1997
    Assignee: Sandoz Ltd.
    Inventors: Jordi B. Barra, Jose R. Sorolla
  • Patent number: 5231173
    Abstract: A metal chelate compound of a dis-azo compound represented by the following formula (I) with a metal: ##STR1## (wherein A is a residue forming a heterocyclic ring together with the carbon atom and the nitrogen atom to which it is bonded, X is a residue forming an aromatic group together with the two carbon atoms to which it is bonded, and D is an aromatic residue which may have a substituent, or a heterocyclic amine residue which may have a substituent, and Y is a group having active hydrogen) and an optical recording medium having a recording layer provided on a substrate so that information can be written in and/or read out by a laser, wherein the recording layer contains a metal chelate compound of the dis-azo compound represented by the above formula (I), with a metal.
    Type: Grant
    Filed: January 14, 1992
    Date of Patent: July 27, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Tetsuo Murayama, Shuichi Maeda, Satoru Imamura, Masako Takeuchi, Takumi Nagao
  • Patent number: 4670486
    Abstract: High molecular weight organic material is effectively colored by the incorporation therein of a copper or nickel complex of the ligand compound of formula I ##STR1## wherein A is an isocyclic or heterocyclic aromatic moiety, R is H, halogen, lower alkyl or alkoxy, R.sub.1 is H, lower alkyl, phenyl or substituted phenyl, and B is H, lower alkyl, ureido or substituted ureido, guanidino, anilino, benzamido or a heterocyclic aromatic moiety.
    Type: Grant
    Filed: June 13, 1985
    Date of Patent: June 2, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Georg Cseh, Paul Lienhard
  • Patent number: 4623720
    Abstract: 1:1 and 1:2 metal complexes comprising the unit of the formula ##STR1## wherein A and B, independently, are radicals of diazo or coupling components, with the proviso that when one of A and B is a radical of a diazo component, the other is a radical of a coupling component,T is --SO.sub.2 N(R.sub.1)-- or --N(R.sub.1)SO.sub.2 --, wherein R.sub.1 is hydrogen, C.sub.1-4 alkyl, C.sub.1-4 alkyl substituted by phenyl or carboxy or C.sub.2-4 alkyl substituted in the .beta.--, .gamma.-- or .delta.--position by phenoxy, C.sub.1-4 alkyl, chloro or hydroxy, with the proviso that T is --N(R.sub.1)SO.sub.2 -- when A is the radical of a diazo component and T is --SO.sub.2 N(R.sub.
    Type: Grant
    Filed: June 4, 1981
    Date of Patent: November 18, 1986
    Assignee: Sandoz Ltd.
    Inventor: Herbert Holliger
  • Patent number: 4599402
    Abstract: The novel compounds of the general formula I ##STR1## where A is a radical of a coupling or diazo component which, if necessary after conversion, is capable of complex formation, Ar is an unsubstituted or substituted aromatic or heterocyclic radical, D is a radical of a diazo component and Me is a Co.sup.2+, Cu.sup.2+, Zn.sup.2+, Mn.sup.2+ or Ni.sup.2+ ion, and the ring B can be further substituted, are very useful for dyeing cellulose fibers, polyesters and blends of cellulose fibers and polyesters.The present dyes are lightfast and fast to washing and to solvents.
    Type: Grant
    Filed: October 12, 1984
    Date of Patent: July 8, 1986
    Assignee: BASF Aktiengesellschaft
    Inventors: Johannes Dehnert, Werner Junemann
  • Patent number: 4517358
    Abstract: Cationic disazo compounds of the formula ##STR1## wherein K independently of one another are each a coupling component,R independently of one another are each an unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl group,R.sub.1 independently of one another are each hydrogen, unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, unsubstituted or substituted C.sub.1 -C.sub.4 -alkoxy, or halogen, andAn is an anionare useful as dyes, in particular as paper dyes, whereby dyeings fast to water are obtained. The dyeings obtained have very good fastness to light and to wet processing.Disazo compounds of the formula ##STR2## wherein K and R, are as defined above are useful as disperse dyes and as intermediates in the preparation of the above cationic disazo compounds.
    Type: Grant
    Filed: September 14, 1982
    Date of Patent: May 14, 1985
    Assignee: Ciba-Geigy Corporation
    Inventor: Visvanathan Ramanathan