Azo Bonded Directly To The Hetero Ring Patents (Class 534/707)
  • Patent number: 8932786
    Abstract: The new metal azo pigments comprising the adduct of a) at least two metal azo compounds of the formula (I) or their tautomeric forms in which the substituents have the definition indicated in the description, and b) at least one compound of the formula (II) in which R6 has the definition indicated in the description, are characterized in that in the X-ray diffractogram with a lattice constant of d=10.3 (±0.2) ? the metal azo pigment has a signal S1 with an intensity I1 and in the lattice constant range from d=16.05 ? to d=11.78 ? has no signal S2 whose intensity I2 in relation to the intensity I1 of signal S1, expressed as ratio I2/I1 of the background-corrected intensities, exceeds a value of 0.02, and are outstandingly suitable for producing pigment preparations and especially for producing color filters.
    Type: Grant
    Filed: July 2, 2013
    Date of Patent: January 13, 2015
    Assignee: LANXESS Deutschland GmbH
    Inventors: Hans-Ulrich Borst, Frank Linke, Heinz-Josef Fuellmann, Stephan Michaelis, Dirk Pfuetzenreuter, Sabine Endert
  • Patent number: 8933190
    Abstract: Disclosed is a process for preparing a polyester or copolymer containing ester functionalities. The process can comprise: providing an optionally substituted lactone having a ring size of from 6 to 40 carbon atoms; and subjecting said lactone to metal mediated ring-opening polymerization using as catalyst a compound according to general formula (I): wherein M can be Al, Cr, Mn and Co; X and X? are independently a heteroatom; Y and Y? can be, independently, selected from O, N, S, P, C, Si, and B; Z can be selected from hydrogen, borohydrides, aluminum hydrides, carbyls, silyls, hydroxide, alkoxides, aryloxides, carboxylates, carbonates, carbamates, amidos, thiolates, phosphides, and halides; L1 and L2 can be independently an organic ligand linking X and Y together and linking X? and Y? together, respectively; and L3 is an optional organic ligand linking Y and Y? together.
    Type: Grant
    Filed: November 16, 2011
    Date of Patent: January 13, 2015
    Assignee: Saudi Basic Industries Corporation
    Inventors: Inge van der Meulen, Saskia Huijser, Erik Gubbels, Andreas Heise, Robert Duchateau, Cornelis Erne Koning
  • Publication number: 20140016072
    Abstract: The new metal azo pigments comprising the adduct of a) at least two metal azo compounds of the formula (I) or their tautomeric forms in which the substituents have the definition indicated in the description, and b) at least one compound of the formula (II) in which R6 has the definition indicated in the description, are characterized in that in the X-ray diffractogram with a lattice constant of d=10.3 (±0.2) ? the metal azo pigment has a signal S1 with an intensity I1 and in the lattice constant range from d=16.05 ? to d=11.78 ? has no signal S2 whose intensity I2 in relation to the intensity I1 of signal S1, expressed as ratio I2/I1 of the background-corrected intensities, exceeds a value of 0.02, and are outstandingly suitable for producing pigment preparations and especially for producing colour filters.
    Type: Application
    Filed: July 2, 2013
    Publication date: January 16, 2014
    Applicant: LANXESS Deutschland GmbH
    Inventors: Hans-Ulrich BORST, Frank LINKE, Heinz-Josef FUELLMANN, Stephan MICHAELIS, Dirk PFUETZENREUTER, Sabine ENDERT
  • Publication number: 20130264545
    Abstract: The present invention relates to the use of dithiocarbamate compounds and to an assembly for use in an electronic device, said assembly comprising a self-assembled monolayer of at least one dithiocarbamate compound. The present invention also relates to an electronic device including such assembly.
    Type: Application
    Filed: July 21, 2010
    Publication date: October 10, 2013
    Applicant: SONY CORPORATION
    Inventors: Florian VON WROCHEM, Jurina WESSELS, Dequing GAO, William FORD, Sylvia ROSSELLI, Rene WIRTZ
  • Publication number: 20130202538
    Abstract: Photosensitive molecular switch, having a chelate ligand, a metal ion bonded coordinatively to the chelate ligand, the metal ion being selected from the group of metal ions consisting of Mn2+, Mn3+, Fe2+, Fe3+, Co2+ and Ni2+, a photochromic system which is bonded covalently to the chelate ligand and can be isomerized by irradiation, this system being bonded coordinatively to the metal ion in one configuration and not bonded to the metal ion in the other configuration.
    Type: Application
    Filed: August 10, 2011
    Publication date: August 8, 2013
    Applicants: UNIVERSITATSKLINIKUM SCHLESWIG-HOLSTEIN, CHRISTAN-ALBRECHTS-UNIVERSITAT ZU KIEL
    Inventors: Rainer Herges, Olav Jansen, Felix Tuczek, Sugumar Venkataramani
  • Publication number: 20130065864
    Abstract: The present invention relates to novel iridium and/or rhodium containing complexes for use as a cytotoxic, such as an anti-cancer agent. There is also provided a method of preparing said compounds.
    Type: Application
    Filed: May 20, 2011
    Publication date: March 14, 2013
    Applicant: UNIVERSITY OF WARWICK
    Inventors: Abraha Habtemariam, Zhe Liu, Joan Josep Soldevila, Ana Maria Pizarro, Peter John Sadler
  • Patent number: 8350015
    Abstract: An objective of this invention is to extend the range of choosing organic dye compounds as radiation-absorbing agents in a variety of fields by providing a novel organic dye compound which absorbs short-wavelength visible radiation and exhibits a superior in optical resistance, solubility in solvents, and heat characteristics required in a novel field in which the organic dye compound is applied: The objective is attainable by providing a cyanine dye which has a specific structure and exhibits a major adsorption maximum at a wavelength longer than 400 nm in a solution.
    Type: Grant
    Filed: February 24, 2005
    Date of Patent: January 8, 2013
    Assignee: Kabushiki Kaisha Hayashibara Seibutsu Kagaku Kenkyujo
    Inventors: Yasushi Aizawa, Yoshinori Koyama, Ayashi Noguchi
  • Patent number: 8158317
    Abstract: An azo dye of the following formula: wherein R1, R2, R3, R4 and R6 each independently represent a hydrogen atom or a substituent; and R5 represent a substituent. The dye has an excellent optical characteristic with sharp absorption and excellent fastness.
    Type: Grant
    Filed: September 28, 2007
    Date of Patent: April 17, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Yoshihiko Fujie, Hisashi Mikoshiba, Takuma Amemiya, Ryuji Shinohara
  • Publication number: 20110129635
    Abstract: Disclosed is an optical information recording medium whose recording method is In-Groove recording, wherein such optical information recording medium offers good recording characteristics associated with high modulation degree and low jitter characteristics. This optical information recording medium includes: a disc-shaped substrate 2 having a through hole at the center and a guide groove 3 formed helically on one side; a reflective layer 4 formed on top of the aforementioned guide grooves 3 on the aforementioned substrate 2; a recording layer 5 formed on top of the aforementioned reflective layer 4 and made of an organic substance containing dye; a protective layer 6 formed on top of the aforementioned recording layer 5; and a light transmissive layer 6 formed on top of the aforementioned protective layer 6. The recording layer 5 contains an organic dye having a structure expressed by (Chemical Formula 1) and a functional group expressed by (Chemical Formula 2).
    Type: Application
    Filed: July 24, 2009
    Publication date: June 2, 2011
    Applicant: TAIYO YUDEN CO., LTD.
    Inventors: Takuo Kodaira, Takeo Tsuzuki
  • Patent number: 7947625
    Abstract: An ink sheet for heat-sensitive transfer recording material comprising an azo dye represented by the following formula (1): wherein R1, R2, R3 and R4 represent a hydrogen atom or substituent; and Het represents a heterocyclic group which may have substituents or a condensed ring.
    Type: Grant
    Filed: February 28, 2007
    Date of Patent: May 24, 2011
    Assignee: Fujifilm Corporation
    Inventors: Yoshihiko Fujie, Hisashi Mikoshiba, Kazufumi Omura, Ryuji Shinohara
  • Publication number: 20110031481
    Abstract: The present invention relates to the use of dithiocarbamate compounds and to an assembly for use in an electronic device, said assembly comprising a self-assembled monolayer of at least one dithiocarbamate compound. The present invention also relates to an electronic device including such assembly.
    Type: Application
    Filed: July 21, 2010
    Publication date: February 10, 2011
    Applicant: SONY CORPORATION
    Inventors: Florian VON WROCHEM, Jurina WESSELS, Dequing GAO, William FORD, Sylvia ROSSELLI, Rene WIRTZ
  • Patent number: 7754863
    Abstract: The invention accordingly relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula (I) or a mesomeric or a tautomeric form thereof, wherein M1 is a metal cation in the oxidation state +3, a hydroxy or halogeno metal group wherein the metal is in the oxidation state +4, or an oxo metal group wherein the metal is in the oxidation state +5; (III) and (IV)are each independently of the other (V), (VI) or (VII); (VIII) is (IX), (X), (XI), (XII), (XIII), or (XIV); (XV) is (XVI) or C2-C8heteroaryl unsubstituted or mono- or poly-substituted by R10, R11, R12 and/or R13; Q1 is N or CR18, Q2 is N or CR19, Q3, Q5 and Q7 are each independently of the other CR20R21, O, S or NR22, Q4 is CR16 or N and Q6 is CR17 or N; and R2 and/or R6 are O, S or NR33. Please see the disclosure for the other substituents which are less relevant.
    Type: Grant
    Filed: July 6, 2005
    Date of Patent: July 13, 2010
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Jean-Pierre Bacher, Gisèle Baudin, Frédérique Wendeborn, Jean-Marie Adam, Urs Lehmann, Jean-Luc Birbaum
  • Publication number: 20100120951
    Abstract: [Problems] To microparticulate a yellow pigment having a structure derived from barbituric acid (e.g., C. I. Pigment Yellow 150) and increase the concentration of the pigment in a pigment composition comprising the pigment without increasing the viscosity of the composition after dispersion of the pigment, flocculation or precipitation in the composition, or increasing the viscosity of the composition over time; and to provide a stable pigment composition which can be used as a coloring agent for a color filter resist or a ink-jet ink.
    Type: Application
    Filed: April 22, 2008
    Publication date: May 13, 2010
    Applicant: Nippon Kayaku Kabushiki Kaisha
    Inventors: Shinjirou Takahashi, Akio Kuwahara
  • Publication number: 20100098898
    Abstract: The invention provides an azo metal chelate dye suitable for use in a recording layer of an optical recording medium capable of high-speed recording or an optical recording medium having plural recording layers, and an optical recording medium. The azo metal chelate dye comprises an azo dye compound represented by the general formula (1) and Zn2+: (wherein R1 represents a linear or branched alkyl group that may be substituted, or a cycloalkyl group that may be substituted; Y represents a linear or branched alkyl group substituted with at least two fluorine atoms; R2, R3, R4, R5 and R6 each independently represents a hydrogen atom or a linear or branched alkyl group that may be substituted, and R3 and R4, R4 and R5, or R5 and R6 may be bonded with each other to form a ring; and a proton is released from the compound of formula (1) to form the chelate dye together with Zn2+).
    Type: Application
    Filed: September 21, 2007
    Publication date: April 22, 2010
    Applicant: MITSUBISHI KAGAKU MEDIA CO., LTD
    Inventors: Hisashi Shoda, Naoyuki Uchida, Kenichi Satake, Yoshihiro Noda
  • Publication number: 20100086724
    Abstract: A recording layer including a novel organic dye compound (I) for a high density optical recording medium is provided. The organic dye compound (I) has the following general chemical structural formula: wherein [A]+ includes alkaline metal ion, wherein R1, R2, R3, R4, R5 and R6 each independently represent hydrogen, straight or branched C1-8 alkyl, C1-3 alkoxyl, halogen, nitro, benzyl group or substituted benzyl group wherein a substituent thereof is C1-2 alkyl, C1-2 alkoxyl, halogen or nitro. The organic dye compound (I) exhibits a maximum absorbance at a wavelength range of 400-550 nm.
    Type: Application
    Filed: September 24, 2009
    Publication date: April 8, 2010
    Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Shin-Shin Wang, Arumugam Balasubramanian, Chien-Liang Huang, Chung-Ta Cheng
  • Publication number: 20100075098
    Abstract: The present invention relates to pyridinone based azo dyes and/or of anionic azo metal complex dye salts made thereof with cationic basic yellow dyes, which are characterized by an unsaturated bond in beta-position to the endocyclic N atom of the pyridinone, and to their use in optical layers for optical data recording, preferably for optical data recording using a laser with a wavelength up to 450 nm. The invention further relates to a write once read many (WORM) type optical data recording medium capable of recording and reproducing information with radiation of blue laser, which employs pyridinone based azo dyes and/or anionic azo metal complex dye salts made thereof with cationic basic yellow dyes, which are characterized by an unsaturated bond in beta-position to the endocyclic N atom of the pyridinone, in the optical layer.
    Type: Application
    Filed: May 7, 2008
    Publication date: March 25, 2010
    Inventors: Lars Luecke, Céderic Klein, Jean-Christophe Graciet, Martin Alexander Winter
  • Patent number: 7655767
    Abstract: The present invention relates to the use of thiazolyl-pyridinium based dyes in optical layers for optical data recording, preferably for optical data recording using a laser with a wavelength up to 450 nm. The invention further relates to a write only read many (WORM) type optical data recording medium capable of recording and reproducing information with radiation of blue laser, which employs a thiazolyl-pyridinium based type dye in the optical layer. The present invention further relates to new thiazolyl-pyridinium based dyes, of formula (V), (VI) or (VIII).
    Type: Grant
    Filed: August 31, 2005
    Date of Patent: February 2, 2010
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Andre Weiss
  • Publication number: 20090291246
    Abstract: An optical recording medium, which makes information be recorded and read with light having wavelength of 700 nm or shorter, with excellent light resistance, high-speed recording and high-density recording is provided. The optical recording medium comprises a substrate, a recording layer formed on the substrate and containing a host dye, which can make information be recorded or read by being irradiated with light having wavelength of 700 nm or shorter, and a reflective layer. The recording layer contains at least an azo metal-chelate dye additive, of which central metal ion is any one of Cu2+, Fe2+ and Co2+.
    Type: Application
    Filed: August 10, 2006
    Publication date: November 26, 2009
    Inventors: Hisashi Shoda, Kenichi Satake, Yuko Naito
  • Publication number: 20090290469
    Abstract: An aspect of the present invention relates to an optical information recording medium comprising a recording layer on a surface of a support, wherein the recording layer comprises at least one azo metal complex dye that is a complex of at least one azo dye and at least one metal ion, and the azo metal complex dye comprises equal to or more than four bonds, each of the bonds being formed between one azo dye molecule and one metal ion.
    Type: Application
    Filed: May 21, 2009
    Publication date: November 26, 2009
    Applicant: FUJIFILM Corporation
    Inventors: Kousuke Watanabe, Tetsuya Watanabe, Taro Hashizume
  • Publication number: 20090263611
    Abstract: [Problem]: An optical recording medium having a capability of recording and/or reading high density optical information using a short wavelength laser light is provided. [Means to Address the Problem]: The optical recording medium has a capability of recording and/or reading high density optical information using a short wavelength laser light having a wavelength of 350 nm to 530 nm. The optical recording medium has a recording layer containing a metal complex compound and formed on a substrate. The metal complex compound is composed of a cyclic ?-diketone azo compound represented by the general formula (I) or general formula (II) and a divalent metal ion coordinated to the cyclic ?-diketone azo compound.
    Type: Application
    Filed: July 11, 2006
    Publication date: October 22, 2009
    Applicant: Mitsubishi Kagaku Media Co., Ltd.
    Inventors: Takashi Miyazawa, Yutaka Kurose, Hisashi Shoda, Kenichi Satake, Yukiko Takahashi, Mayumi Kimura, Naoyuki Uchida, Hideki Tamagawa
  • Publication number: 20090227762
    Abstract: The present invention provides a catalyst for use in the preparation of a coloured polymeric material, said catalyst comprising a coloured organometallic compound. Preferably, said catalyst comprises a metal such as aluminium and at least one organic chromophore, such as an azo chromophore, said chromophore being either directly bonded to said metal, or indirectly bonded to said metal through a ligand. The invention also envisages a method for the preparation of a coloured polymer, the method comprising performing a polymerisation reaction in the presence of such a catalyst. The method is particularly applicable to the preparation of poly(lactic acid), and offers significant benefits over the processes of the prior art, both economically and environmentally.
    Type: Application
    Filed: October 31, 2006
    Publication date: September 10, 2009
    Applicant: UNIVERSITY OF LEEDS
    Inventors: Richard Simon Blackburn, Christopher Mark Rayner, Christopher Martin Pask, Patrick Columba McGowan
  • Publication number: 20080108799
    Abstract: The present invention relates to the use of thiazolyl-pyridinium based dyes in optical layers for optical data recording, preferably for optical data recording using a laser with a wavelength up to 450 mn. The invention further relates to a write only read many (WORM) type optical data recording medium capable of recording and reproducing information with radiation of blue laser, which employs a thiazolyl-pyridinium based type dye in the optical layer. The present invention further relates to new thiazolyl-pyridinium based dyes, of formula (V), (VI) or (VIII).
    Type: Application
    Filed: August 31, 2005
    Publication date: May 8, 2008
    Inventor: Andre Weiss
  • Patent number: 7244298
    Abstract: A metal chelate compound of Formula (1) or a salt thereof: [A-N?N—B]M??Formula (1) wherein: A is an optionally substituted pyridyl ring; and B is of the Formula (2): wherein: X and W are substituents other than H; M is a metal chelated to A-N?N—B; and n is 0 to 4, also claimed are compositions and inks containing a compound of Formula (1), a process for ink jet printing using the inks and an ink jet printer cartridge containing the ink.
    Type: Grant
    Filed: March 3, 2004
    Date of Patent: July 17, 2007
    Assignee: Fujifilm Imaging Colorants Limited
    Inventors: Clive Edwin Foster, Clive Moscrop, Gavin Wright, Rachel Anne James
  • Patent number: 7238227
    Abstract: A metal chelate compound of Formula: (1) or a salt thereof: [A—N?N—B] M (1) wherein: A is a 5- or 6-membered heterocyclic ring other than a triazole ring, optionally carrying one or more substituents; B is of the Formula (2a) or (2b). Formula (2a) (2b) wherein: X, Y and W are substituents other than H; M is a metal chelated to A—N?N—B; and n is 0 to 4.
    Type: Grant
    Filed: February 17, 2004
    Date of Patent: July 3, 2007
    Assignee: Fujifilm Imaging Colorants Limited
    Inventors: Clive Edwin Foster, Gavin Wright, Kevin Johnson, Mairi Elizabeth Raggatt, Prakash Patel
  • Patent number: 7150782
    Abstract: A metal chelate compound obtainable from contacting a transition metal salt with a compound of the Formula (1): wherein: x represents plural atoms required to form at least one optionally substituted 5- to 7-membered heterocyclic ring; and Ar is an optionally substituted stilbene, acenaphthylene, phenanthrene or anthracene group carrying a hydroxy, amino or carboxy group adjacent to the —N?N— group shown in Formula (1) or 6-hydroxyquinoline where the hydroxy group is adjacent to the —N?N— group shown in Formula (1); provided that when the compound of Formula (1) is of Formula: that, p, the level of sulfonation, is not in the range 1 to 2. Also compositions, inks, printed substrates and inkjet cartridges.
    Type: Grant
    Filed: May 20, 2004
    Date of Patent: December 19, 2006
    Assignee: Fujifilm Imaging Colorants Limited
    Inventors: Clive Edwin Foster, John Mayall, Mark Kenworthy
  • Patent number: 7147697
    Abstract: A metal chelate compound obtainable from contacting a transition metal salt with a compound of the Formula (1) or a salt thereof: wherein p is 1 to 2. Also compositions, inks, printed substrates, ink-jet cartridges and ink-jet printers.
    Type: Grant
    Filed: May 20, 2004
    Date of Patent: December 12, 2006
    Assignee: Fujifilm Imaging Colorants Limited
    Inventors: Clive Edwin Foster, John Mayall, Mark Kenworthy, Rachel Anne James
  • Patent number: 7097700
    Abstract: A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; and an ink jet recording method, are presented.
    Type: Grant
    Filed: December 29, 2004
    Date of Patent: August 29, 2006
    Assignee: Mitsubishi Chemical Corporation
    Inventor: Wataru Shimizu
  • Patent number: 7094280
    Abstract: A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; and an ink jet recording method, are presented.
    Type: Grant
    Filed: December 20, 2004
    Date of Patent: August 22, 2006
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Wataru Shimizu, Masahiro Yamada
  • Patent number: 7081160
    Abstract: An azobarbituric acid metal complex pigment comprising an azobarbituric acid metal complex of the formula (1), melamine and a compound of the formula (2), which pigment has an average primary particle diameter of 20 nm to 200 nm and a pigment primary particle aspect ratio of 1:1 to 3:1 and is fine and excellent in flowability, transparency and stability with time, and a process for the production of the above pigment
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: July 25, 2006
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventor: Naoki Hamada
  • Patent number: 7025815
    Abstract: A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; an ink set employing such a recording fluid; and an ink jet recording method, are presented.
    Type: Grant
    Filed: December 7, 2004
    Date of Patent: April 11, 2006
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Wataru Shimizu, Mio Ishida, Hideo Sano, Yukichi Murata
  • Patent number: 6979364
    Abstract: A metal chelate compound of the Formula (1) and salts thereof: wherein: one of A and B is OH and the other is an azotriazole group; and M is a metal or boron; and n is 0 to 4; compositions and inks containing a compound of Formula (1), a process for ink jet printing using the inks and an ink jet printer cartridge containing the ink.
    Type: Grant
    Filed: May 20, 2003
    Date of Patent: December 27, 2005
    Assignee: Avecia Limited
    Inventors: Gavin Wright, Kevin Johnson, Mairi Elizabeth Raggatt, Prakash Patel
  • Patent number: 6969421
    Abstract: A process for printing an image on a substrate comprising applying thereto by means of an ink jet printer an ink containing a metal chelate compound of the Formula (1) and salts thereof: wherein: one of A and B is OH and the other is an azotriazole group; each W independently is a carboxy or carbonamido group; each X independently is a substituent other than H, sulphonamido, carboxy, sulpho and carbonamido; J is a sulphonamido group; M is a metal or boron; a, p, q and n are each independently 0, 1, 2, 3 or 4; and (p+q+a+n) is 0, 1, 2, 3 or 4. Also claimed are compounds of Formula (1), compositions and inks containing a compound of Formula (1) and an ink jet printer cartridge containing the ink.
    Type: Grant
    Filed: May 20, 2003
    Date of Patent: November 29, 2005
    Assignee: Avecia Limited
    Inventors: Gavin Wright, Kevin Johnson, Mairi Elizabeth Raggatt, Prakash Patel
  • Patent number: 6881830
    Abstract: Metal complexes of metals of the scandium group with an azo compound which conforms to the formula (I) or to one of its tautomeric structures where R is OH, NH2, NH—CN, arylamino or acylamino, R? is NH2, NH—CN, arylamino or acylamino and R1 and R1? are independently —OH or —NH2.
    Type: Grant
    Filed: March 25, 2003
    Date of Patent: April 19, 2005
    Assignee: Bayer Chemicals AG
    Inventors: Ulrich Feldhues, Frank Linke, Ronald Göbel, Udo Herrmann, Sabine Endert
  • Patent number: 6827770
    Abstract: A metal chelated dyestuff for inkjet recording comprising a water soluble azo metal chelated compound formed by an azo-based compound represented by the following general formula (1) having one or more hydrophilic group per molecule and a metal element; an aqueous inkjet recording liquid comprising an aqueous medium and the aforementioned metal chelated dyestuff; and an inkjet recording method using the aforementioned recording liquid are described, wherein the heterocyclic ring containing X1 is a triazole ring or the like; and Ar1 represents naphthyl group having a chelated group.
    Type: Grant
    Filed: June 18, 2002
    Date of Patent: December 7, 2004
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Tomohiro Chino, Masahiro Yamada, Hideo Sano, Wataru Shimizu, Yuukichi Murata
  • Patent number: 6755903
    Abstract: A metal chelated dyestuff for inkjet recording is described, which is a water soluble azo metal chelated compound formed from an azo compound represented by the following general formula (1) and a metal element and is good at the clearness of color tone, light resistance, indoor discoloring and fading property, solubility, storage stability, and the like.
    Type: Grant
    Filed: June 24, 2002
    Date of Patent: June 29, 2004
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masahiro Yamada, Tomio Yoneyama, Tomohiro Chino
  • Patent number: 6689872
    Abstract: An optical recording medium dye is described. The optical recording medium dye is an azo metal chelate compound, wherein the azo metal chelate compound comprises the following structure: wherein R1 is a hydrogen atom, a C1-6 straight chain or branched alkyl group, an amino group, an alkylamino group or a tolylamino group; R2 is a hydrogen atom, a hydroxyl group, a halogen atom, an ether group, a C1-6 straight chain or branched alkyl group; R3 is a hydrogen atom, a C1-6 straight chain or branched alkyl group; R4 is a hydrogen atom, a C1-6 straight chain or branched alkyl group or a halogen atom; A3 is a residue forming a heterocyclic ring derivative together with a carbon atom and a nitrogen atom.
    Type: Grant
    Filed: September 17, 2002
    Date of Patent: February 10, 2004
    Assignee: Ritek Corporation
    Inventors: Nae-Jen Wang, Ching-Huang Chen, Li-Ling Lin, Chao-Nan Kuo, Wen-Dar Liu, Wan-Chun Chen, Shyh-yeu Wang
  • Publication number: 20040020405
    Abstract: A metal chelate compound of the Formula (1) and salts thereof: 1
    Type: Application
    Filed: May 20, 2003
    Publication date: February 5, 2004
    Applicant: Avecia Limited
    Inventors: Gavin Wright, Kevin Johnson, Mairi Elizabeth Raggatt, Prakash Patel
  • Publication number: 20030148216
    Abstract: An optical recording medium dye is described.
    Type: Application
    Filed: September 17, 2002
    Publication date: August 7, 2003
    Inventors: Nae-Jen Wang, Ching-Huang Chen, Li-Ling Lin, Chao-Nan Kuo, Wen-Dar Liu, Wan-Chun Chen, Shyh-yeu Wang
  • Publication number: 20030088077
    Abstract: The present invention provides a dyestuff good at the clearness of color tone, light resistance, indoor discoloring and fading property, solubility, storage stability, and the like, when the dyestuff is used as a water soluble dyestuff for inkjet recording.
    Type: Application
    Filed: June 24, 2002
    Publication date: May 8, 2003
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Masahiro Yamada, Tomio Yoneyama, Tomohiro Chino
  • Patent number: 6534636
    Abstract: This invention provides azo-metal complex dyes for a high-density optical disc recording medium having the following formula (I): wherein R1 reprents C1-8 alkoxyl, carboxy, C1-8 alkoxycarbonyl, or amide; R2, R3, R4 and R5 can be the same or not, which are hydrogen, C1-8 alkyl, C1-8 alkoxyl, carboxy, C1-8 alkoxycarbonyl; C1-6 alkylaminealkylenecarboxy, amide, nitro, trifluoro-methyl, sulfonic acid fluoride group, sulfonic acid group or halogen atom; X reprents carbon or nitrogen atom; and M reprents Mg+2, Mn+2, Co+2, Ni+2, Cu+2 or Zn+2, These azo-metal complex dyes whose spectra are capable of matching wavelength of 400 nm˜700 nm visible light can be used as a high-density optical disc recording medium.
    Type: Grant
    Filed: May 16, 2001
    Date of Patent: March 18, 2003
    Assignee: Industrial Technology Research Institute
    Inventors: Shin-Shin Wang, Hui-Ping Tsai, Wen-Yih Liao, Chien-Liang Huang, Tzuan-Ren Jeng
  • Patent number: 6525181
    Abstract: The object of the present invention is to provide organic dye compounds which exert satisfactory optical absorption properties and thermal resistance when used in high density optical recording media. The above object is solved by specific trimethine cyanine dyes, light absorbents and optical recording media which comprise the cyanine dyes, and preparations for the cyanine dyes comprising either reacting a benzoindolium compound having a compatible leaving group with a pyrazinoimidazolium compound having a reactive methyl group; or reacting a benzoindolium compound having a reactive methyl group with a pyrazinoimidazolium compound having a compatible leaving group.
    Type: Grant
    Filed: October 23, 2001
    Date of Patent: February 25, 2003
    Assignee: Kabushiki Kaisha Hayashibara Seibutsu Kagaku Kenkyujo
    Inventors: Chiaki Kasada, Katsumi Orita, Kentaro Yano, Toshio Kawata, Shigeo Yasui
  • Patent number: 6448385
    Abstract: The invention relates to a process for preparing metal complexes of polyvalent metal ions with azo compounds of formula (I) or tautomeric structures, in which R and R′ are —OH, —NH2, —NH—CN, aryl-amino, acylamino, or p-chlorophenyl, and R1 and R1′ are independently —OH or —NH2, that intercalate an intercalate by (1) stirring an aqueous dispersion of an alkali metal salt of the azo compound with the polyvalent metal salt at 10 to 35° C., (2) admixing an aqueous solution, dispersion, or emulsion of the intercalate, (3) passing the mixture through a reaction zone at 85 to 140° C., while regulating the pH so that the product dispersion leaving the reaction zone has a pH of 0.5 to 3, (4) adjusting the pH of the mixture to at least pH 5, and (5) isolating the intercalated metal complex.
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: September 10, 2002
    Assignee: Bayer Aktiengesellchaft
    Inventors: Udo Herrmann, Lothar Weismantel, Frank Linke, Ronald Göbel, Bernhard Krumbach, Wolfgang Frank
  • Patent number: 6350307
    Abstract: Metal complexes of an azo compound which conforms to the formula (I) or one of its tautomeric structures wherein R and R′ are independently OH, NH2, NH—CN, acylamino or arylamino, R1 and R1′ are independently —OH or —NH2, and which contain at least one guest compound, characterized in that the metal complexes correspond to the mono-, di-, tri- and tetrainions of the azo compounds of the formula (I) with the metals selected from the group consisting of Ca, Zn, Cu, Fe, Co, Sr, Ba, Cr, Sn, Al, Mg, Cd, Pb and La.
    Type: Grant
    Filed: October 8, 1999
    Date of Patent: February 26, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Frank Linke, Kent Faubion, Udo Herrmann, Richard Sommer
  • Publication number: 20020015915
    Abstract: An object of the present invention is to provide an optical recording medium that is excellent in recording and reading-out characteristics in the case of using a shortwave semiconductor laser and is good in light resistance and durability.
    Type: Application
    Filed: June 5, 2001
    Publication date: February 7, 2002
    Inventors: Yoshiyuki Nagataki, Yuichi Sakurai, Kouji Takazawa, Yoshiharu Iinuma, Masatoshi Taniguchi, Noriko Ueda
  • Patent number: 6340745
    Abstract: Phthalocyanines of the formula where Me is twice hydrogen, twice lithium, magnesium, zinc, copper, nickel, VO, TiO, AlCl, AlOH, AlOCOCH3, AlOCOCF3, SiCl2 or Si(OH)2, at least four of the radicals R1 to R16 are each independently of the others a five- or six-membered saturated nitrogen-containing heterocyclic radical which is bonded to the phthalocyanine structure via a ring nitrogen atom and which can additionally contain further hetero atoms, and any remaining radicals R1 to R16 are each hydrogen, halogen, hydroxysulfonyl or C1-C4-dialkylsulfamoyl, subject to the proviso that tetrakispiperidinylphthalocyanine shall be excluded, and heterocyclyl-substituted phthalocyanines are useful for marking liquids, in particular mineral oils.
    Type: Grant
    Filed: November 19, 1999
    Date of Patent: January 22, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Frank Meyer, Christos Vamvakaris, Karin Heidrun Beck, Gerhard Wagenblast, Bernhard Albert
  • Publication number: 20010047087
    Abstract: The invention relates to a process for preparing metal complexes of polyvalent metal ions with azo compounds of formula (I) 1
    Type: Application
    Filed: March 30, 2001
    Publication date: November 29, 2001
    Inventors: Udo Herrmann, Lothar Weismantel, Frank Linke, Ronald Gobel, Bernhard Krumbach, Wolfgang Frank
  • Patent number: 6284877
    Abstract: A metal chelate compound obtained from an azo compound of the following formula [a] or [b] and a metal salt: wherein each of A2 and A3 is a residue forming, together with the carbon atom and the nitrogen atom to which A2 or A3 is bonded, a heterocyclic ring which may have a substituent, B1 is a residue forming, together with the carbon atoms to which B1 is bonded, an aromatic or heterocyclic ring which may have a substituent, and Y is a C1-6 linear or branched alkyl group substituted by at least two fluorine atoms.
    Type: Grant
    Filed: July 6, 2000
    Date of Patent: September 4, 2001
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yuko Okamoto, Yutaka Kurose, Shuichi Maeda, Yuki Suzuki
  • Patent number: 6281338
    Abstract: Mono- or dipotassium salts of azo compounds conforming to the formula (I) or one of its tautomeric structures where R and R′ are independently OH, NH2, NH—CN, acylamino or arylamino and R1 and R1′are independently —OH or —NH2, and also their hydrates.
    Type: Grant
    Filed: September 19, 2000
    Date of Patent: August 28, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventors: Richard Sommer, Frank Linke, Udo Herrmann
  • Patent number: 6225023
    Abstract: A sulfonamide compound of the formula (1): wherein X is a hydrogen atom, an alkyl or alkoxy group which may be substituted, or a halogen atom, Y Is an alkyl group having at least two fluorine atoms, and each of R1 and R2 which are independent of each other, is an alkyl group which may be substituted, or R1 may be bonded to X or R2 to form a ring.
    Type: Grant
    Filed: October 7, 1998
    Date of Patent: May 1, 2001
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yuko Okamoto, Yutaka Kurose, Shuichi Maeda, Yuki Suzuki
  • Patent number: 6211346
    Abstract: Metal complexes of an azo compound which in the form of its tautomeric structures conforms to the formula (I) wherein the substituents are each as defined in the description, and which metal complexes host a compound as guest compound, characterized in that they have a dispersing harshness of less than 250.
    Type: Grant
    Filed: October 8, 1999
    Date of Patent: April 3, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventors: Frank Linke, Kent Faubion, Udo Herrmann, Dirk Pfützenreuter, Ronald Göbel