Plural Monocyclic Benzene Rings Attached Directly To Each Other By Nonionic Bonding And Are Between Azo Groups Patents (Class 534/715)
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Patent number: 7638610Abstract: A self-dispersible metal complex colorant is represented by formula 1, which has improved storage stability, may embody various colors and has improved fastness, such as light resistance, water resistance and the like: wherein each of A1 and A2 is independently a moiety which includes a substituted or unsubstituted C2-C30 alkenylene group having at least one double bond and is conjugated with an azo group; each of X1 and X2 is selected from the group consisting of a hydroxy group, a C1-C4 alkoxy group, a carboxyl group, and a substituted or unsubstituted amino group; M is a polyvalent transition metal; L is a neutral or anionic ligand; T is a mono- or poly-substituted hydrophilic functional group; n is an integer between 1 and 3; and J is a linker. The self-dispersible metal complex colorant may be used in various fields employing colors, such as fibers, foods, drugs, cosmetics, coatings, inks or ceramics.Type: GrantFiled: August 6, 2004Date of Patent: December 29, 2009Assignee: Samsung Electronics Co., Ltd.Inventors: Kyung-hoon Lee, Seung-min Ryu, Yeon-kyoung Jung
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Patent number: 7364597Abstract: A metal complex colorant represented by formula 1 may embody various colors and has improved fastness, such as light resistance, water resistance and the like: wherein each of A1 and A2 is independently a moiety which includes a substituted or unsubstituted C2-C30 alkenylene group having at least one double bond and is conjugated with an azo group; each of X1 and X2 is selected from the group consisting of a hydroxy group, a C1-C4 alkoxy group, a carboxyl group, and a substituted or unsubstituted amino group; M is a polyvalent transition metal; L is a neutral or anionic ligand; n is an integer from 1 to 3; and J is a linker. The metal complex colorant may be used in various fields employing colors, such as fibers, foods, drugs, cosmetics, coatings, inks or ceramics.Type: GrantFiled: August 6, 2004Date of Patent: April 29, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Yeon-kyoung Jung, Seung-min Ryu, Kyung-hoon Lee
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Patent number: 6749674Abstract: Disclosed are metal complexes of trisazo dyes of the general formula 4 wherein R1 through R6 are as defined in the specification. The dyes are useful for dyeing and printing natural and synthetic fiber materials, recording fluids, especially for the inkjet process, liquid formulations for paper pulp dyeing, and also as colorants for electrophotographic toners, powder coatings and color filters including the dyes of the invention.Type: GrantFiled: March 23, 2001Date of Patent: June 15, 2004Assignee: Clariant GmbHInventors: Josef Geisenberger, Andreas Wuzik
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Publication number: 20030187234Abstract: Charge control agent comprising a metal complex salt compound of Formula (I) containing substantially no monoazo compound constituting the ligand thereof, toner containing the charge control agent, and process for manufacturing a metal complex salt compound of Formula (I), which comprises a metallizing reaction for metallizing a monoazo compound of Formula (II) with iron, nickel, aluminum, titanium or zirconium to produce a metal complex salt compound, in which metallizing reaction a monohydric or dihydric alcohol is used as a reaction-promoting solvent: 1Type: ApplicationFiled: February 11, 2003Publication date: October 2, 2003Applicant: ORIENT CHEMICAL INDUSTRIES, LTD.Inventors: Masashi Yasumatsu, Akihiro Tada, Shun-Ichiro Yamanaka
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Publication number: 20010027734Abstract: Disclosed are metal complexes of trisazo dyes of the general formula 4 1Type: ApplicationFiled: March 23, 2001Publication date: October 11, 2001Applicant: Clariant GmbHInventors: Josef Geisenberger, Andreas Wuzik
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Patent number: 6197467Abstract: Charge control agent comprising a metal complex salt compound having a monoazo compound as a ligand, wherein the metal complex salt compound is amorphous, and which is excellent in charge control properties, heat resistance and light fastness, good in dispersibility in, and wettability with, toner resins, hardly damages the photoreceptor when used in a toner, and is unlikely to drop from toner particles during charging; process for manufacturing the charge control agent, comprising subjecting a crystalline metal complex salt compound having a monoazo compound as a ligand to wet milling in an organic solvent, or dissolving the crystalline metal complex salt compound in an organic solvent, and subsequently re-dispersing it in water; and toner for developing electrostatic images comprising said charge control agent, a toner resin, and a coloring agent, and method of use thereof.Type: GrantFiled: April 22, 1998Date of Patent: March 6, 2001Assignee: Orient Chemical IndustriesInventors: Shun-ichiro Yamanaka, Kazuaki Sukata, Masashi Yasumatsu
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Patent number: 5698683Abstract: A process for preparing a mixed aluminium-heavy metal dyestuff complex, in which the amount of heavy metal present is 10-98% and that of aluminium is 2 to 90% comprisingi) reacting the metal free dyestuff with less than a stoichiometric amount of a heavy metal compound followed byii) reacting the product with an aluminium compound in an amount to produce a stoichiometric excess of metal (calculated on all the metal present) to form a mixed aluminium-heavy metal complex.Type: GrantFiled: May 12, 1995Date of Patent: December 16, 1997Assignee: Clariant Finance (BVI) LimitedInventors: Bansi Lal Kaul, Dominique Pflieger
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Patent number: 5160504Abstract: Use of metal complex dyes comprised of metalizable azo compounds to dye metal-tanned leather which makes possible good permeability and excellent color fastness to rubbing and color fastness to light.Type: GrantFiled: October 28, 1991Date of Patent: November 3, 1992Assignee: Orient Chemical Industries, Ltd.Inventors: Takashi Ono, Tatsuya Yagyu, Katsumi Fukuda, Minako Terasaki
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Patent number: 5095100Abstract: Metal complex dyes comprising a metalizable azo compound represented by one of Formulas [I] through [IV]: ##STR1## In Formulas [I] through [IV], Ps represents a phosphono group in the form of a free acid or a salt; Sf represents a sulfo group in the form of a free acid or a salt; m is 0, 1 or 2. R.sup.1 represents a hydrogen atom or an amino group; X represents a hydroxyl group, an alkoxy group having a carbon number of 1 or 2 or a carboxyl group. Y represents a hydroxyl group, an alkoxy group having a carbon number of 1 or 2, a carboxyl group or a methyl group; R.sup.2 represents a hydrogen atom or a hydroxyl group; A represents a phenyl group or naphthyl group selected from the group comprising the following 1 through 4: ##STR2## In the above formulas 1 through 4, Sf has the same definition as above; n is 0, 1 or 2. R.sup.3 represents a hydroxyl group or a carboxyl group; R.sup.4 represents a hydroxyl group, a carboxyl group or an amino group; R.sup.5 and R.sup.Type: GrantFiled: June 12, 1990Date of Patent: March 10, 1992Assignee: Orient Chemical Industries, Ltd.Inventors: Takashi Ono, Tatsuya Yagyu, Katsumi Fukuda, Minako Terasaki
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Patent number: 4594410Abstract: Azo dyes of the formula ##STR1## and external salts thereof, wherein F is the residue of a monoazo or disazo compound in 1:1 metal complex form or of a trisazo, disazoazoxy or tetrakisazo compound in metal-free or 1:1 metal complex form,each X is independently --NR.sub.2 --Q--NR.sub.3 R.sub.4 or --NR.sub.2 --Q--N.sup..sym. R.sub.5 R.sub.6 R.sub.7,whereinQ is linear or branched C.sub.2-6 alkylene or --NH--CO--CH.sub.2 --,R.sub.2 is hydrogen or C.sub.1-4 alkyl,each of R.sub.3 and R.sub.4 is independently hydrogen; C.sub.1-6 alkyl; C.sub.2-6 alkyl monosubstituted by cyano or hydroxy in the 2-, 3-, 4-, 5- or 6-position; phenyl(C.sub.1-3 alkyl); phenyl(C.sub.1-3 alkyl) having, on the phenyl ring, 1, 2 or 3 substituents selected from chloro, C.sub.1-4 alkyl and C.sub.1-4 alkoxy; C.sub.5-6 cycloalkyl or C.sub.5-6 cycloalkyl substituted by 1, 2 or 3 C.sub.1-4 alkyl groups or --NR.sub.3 R.sub.Type: GrantFiled: August 18, 1982Date of Patent: June 10, 1986Assignee: Sandoz Ltd.Inventor: Reinhard Pedrazzi