Abstract: Disclosed is a process for preparing a polyester or copolymer containing ester functionalities. The process can comprise: providing an optionally substituted lactone having a ring size of from 6 to 40 carbon atoms; and subjecting said lactone to metal mediated ring-opening polymerization using as catalyst a compound according to general formula (I): wherein M can be Al, Cr, Mn and Co; X and X? are independently a heteroatom; Y and Y? can be, independently, selected from O, N, S, P, C, Si, and B; Z can be selected from hydrogen, borohydrides, aluminum hydrides, carbyls, silyls, hydroxide, alkoxides, aryloxides, carboxylates, carbonates, carbamates, amidos, thiolates, phosphides, and halides; L1 and L2 can be independently an organic ligand linking X and Y together and linking X? and Y? together, respectively; and L3 is an optional organic ligand linking Y and Y? together.
Type:
Grant
Filed:
November 16, 2011
Date of Patent:
January 13, 2015
Assignee:
Saudi Basic Industries Corporation
Inventors:
Inge van der Meulen, Saskia Huijser, Erik Gubbels, Andreas Heise, Robert Duchateau, Cornelis Erne Koning
Abstract: A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.
Type:
Application
Filed:
October 4, 2012
Publication date:
December 18, 2014
Applicant:
Dow Coming Corporation
Inventors:
Kurt Brandstadt, Simon Cook, Gary Diamond, Keith Hall, Loren Lower, Avril Surgenor, Richard Taylor, James Tonge, Ming-Shin Tzou, Thomas Galbraith, James Shoemaker
Abstract: A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.
Type:
Application
Filed:
September 6, 2012
Publication date:
August 21, 2014
Applicant:
DOW CORNING CORPORATION
Inventors:
Kurt Brandstadt, Simon Cook, Gary Diamond, Keith Hall, Loren Lower, Avril Surgenor, Richard Taylor, James Tonge, Ming-Shin Tzou
Abstract: A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.
Type:
Application
Filed:
September 6, 2012
Publication date:
July 31, 2014
Inventors:
Kurt Brandstadt, Simon Cook, Gary Diamond, Keith Hall, Loren Lower, Avril Surgenor, Richard Taylor, James Tonge, MIng-Shin Tzou
Abstract: A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.
Type:
Application
Filed:
September 6, 2012
Publication date:
July 31, 2014
Applicant:
Dow Corning Corporation
Inventors:
Kurt Brandstadt, Simon Cook, Gary Diamond, Keith Hall, Loren Lower, Avril Surgenor, Richard Taylor, James Tonge, Ming-Shin Tzou
Abstract: The invention relates to a method for producing urethanes or ureas or mixtures of urethanes and ureas by oxidative carbonylation of organic amines in the presence of carbon monoxide, oxygen and a catalyst, where the catalyst used is a transition metal complex containing the structural feature: [Mn+(O˜N˜O)2?](n-2)+(L)m(Z?)n-2 and the method is carried out under halogen-free reaction conditions. The invention further relates to transition metal complexes containing said structural feature and also to the use of such transition metal complexes as catalysts in the production of urethanes or ureas or mixtures of urethanes and ureas.
Type:
Application
Filed:
August 9, 2011
Publication date:
November 14, 2013
Applicant:
Bayer Intellectual Property GmbH
Inventors:
Felix Gärtner, Andreas Jacob, Jörg Sundermeyer, Stephan Klein, Stefan Wershofen
Abstract: The invention relates to nanotechnology and is directed at nanocomposite materials with effectively controllable optical properties which can be used in non-linear optics, information engineering, for designing optical memory means etc. The inventive nanocomposite material comprises nanoparticles, intermediate bonding molecule particles which modify the space configuration when they are exposed to an external light action, and bondable molecule particles which exhibit the optical properties near nanoparticles, wherein the nanoparticles, intermediate bonding molecules and bondable molecules are connected in series so as to form a three-dimensional cluster structure. Moreover, the intermediate bonding molecule particles which modify the space configuration when they are exposed to an external light action can contain additional inclusions in the form of functional substituents which enhance the bonding properties thereof.
Type:
Application
Filed:
December 22, 2010
Publication date:
July 7, 2011
Inventors:
Evgeny P. GREBENNIKOV, Alexandr G. DEVYATKOV, Grigory E. ADAMOV
Abstract: The present invention provides a catalyst for use in the preparation of a coloured polymeric material, said catalyst comprising a coloured organometallic compound. Preferably, said catalyst comprises a metal such as aluminium and at least one organic chromophore, such as an azo chromophore, said chromophore being either directly bonded to said metal, or indirectly bonded to said metal through a ligand. The invention also envisages a method for the preparation of a coloured polymer, the method comprising performing a polymerisation reaction in the presence of such a catalyst. The method is particularly applicable to the preparation of poly(lactic acid), and offers significant benefits over the processes of the prior art, both economically and environmentally.
Type:
Application
Filed:
October 31, 2006
Publication date:
September 10, 2009
Applicant:
UNIVERSITY OF LEEDS
Inventors:
Richard Simon Blackburn, Christopher Mark Rayner, Christopher Martin Pask, Patrick Columba McGowan
Abstract: The present invention relates to the use of Basic Yellow dyes as dye component for optical data recording media. In a preferred aspect the present invention relates to Basic Yellow dyes together with a metalazo complex dye as dye components for optical data recording media. In a more preferred aspect, the invention relates to a write once read many (WORM) type optical data recording medium capable of recording and reproducing information with radiation of blue laser of preferably 405 nm, which employs a Basic Yellow dye together with a metalazo complex dye and a further recording dye in the optical layer.
Type:
Application
Filed:
April 5, 2006
Publication date:
January 15, 2009
Inventors:
Pascal Steffanut, Jean-Christophe Graciet, Lars Lucke, Martin Alexander Winter
Abstract: Materials for optical recording media are disclosed. Specifically, the materials are metal chelate compounds of azo dyes, which are formed from sulfamoylated m-diaminobenzene compounds and benzene ring-containing azo compounds. Further, the invention provides an optical recording medium, characterized in that said metal chelate compounds of azo dyes are employed onto the optical recording medium to form a recording layer. The invention also discloses a process for the production of an optical recording medium.
Abstract: Charge control agent comprising a metal complex salt compound of Formula (I) containing substantially no monoazo compound constituting the ligand thereof, toner containing the charge control agent, and process for manufacturing a metal complex salt compound of Formula (I), which comprises a metallizing reaction for metallizing a monoazo compound of Formula (II) with iron, nickel, aluminum, titanium or zirconium to produce a metal complex salt compound, in which metallizing reaction a monohydric or dihydric alcohol is used as a reaction-promoting solvent:
R: alkyl (C4 to 12); Y: halogen or alkyl (C 1 to 5); p and q: number of monoazo compounds coordinated to the metal M; p: 1, 2, 3 or 4; q: 0, 1, 2 or 3; p+q: 1 to 6; L1 and L2 is —O—; one of L3 and L4 is —O—, while the other is an —OH group or an —O− ion; M is iron, nickel, aluminum, titanium or zirconium; (Mx+)m: m number of metals of atomic valence x; m: 1 to 4; x: 2 or more; Z−: the
Type:
Grant
Filed:
February 11, 2003
Date of Patent:
June 29, 2004
Assignee:
Orient Chemical Industries, Ltd.
Inventors:
Masashi Yasumatsu, Akihiro Tada, Shun-ichiro Yamanaka
Abstract: Inks comprising a dye of formula (1)
wherein
X is hydroxy, unsubstituted or hydroxy-substituted C1-C4alkyl, vinyl or a radical —CH2—CH2—Z, wherein Z is a group removable under alkaline conditions or is C1-C24alkoxy unsubstituted or substituted in the alkyl moiety, which may further be interrupted in the alkyl moiety by oxygen; phenoxy unsubstituted or substituted in the phenyl ring; C1-C4alkylthio unsubstituted or substituted in the alkyl moiety; phenylthio unsubstituted or substituted in the phenyl ring; amino; N-mono- or N,N-di-C1-C24alkylamino unsubstituted or substituted in the alkyl moiety, which may further be interrupted in the alkyl moiety by oxygen or by a radical —NR1— in which R1 is hydrogen or unsubstituted or further substituted C1-C4alkyl; C10-C20terpeneamino; C5-C7cycloalkylamino unsubstituted or substituted in the cycloalkyl ring; phenyl- or naphthyl-amino or N—C1-C4alkyl-N-phenyl- or N—C1-C4alkyl-N-naphthyl-amino unsubstituted or su
Abstract: An object of the present invention is to provide an optical recording medium that is excellent in recording and reading-out characteristics in the case of using a shortwave semiconductor laser and is good in light resistance and durability.
Abstract: 1:2 chromium complex dyes of the formula:
in which R signifies C1-9-alkyl or a radical of the formula:
R1 signifies C1-4-alkyl,
R2 signifies hydrogen or —SO3M,
R3 signifies hydrogen, methyl or methoxy,
R4 signifies hydrogen, methyl, methoxy or chloro,
n signifies from 0 to 3,
M signifies hydrogen or a non-chromophoric cation and Kat+signifies hydrogen or a non-chromophoric cation, are suitable for dyeing artificially produced oxide layers on aluminium or aluminium alloys and so give rise to highly lightfast dyeings in yellow shades.
Abstract: Monoazo metal compound of formula [I] which is excellent in charge control or charge-enhancing property, and toner for developing electrostatic images and powdery paint for electrostatic painting incorporating thereof:D.sub.3 (Met).sub.2 [I]D is a ligand based on a monoazo compound of formula [II] or [III], Met is a metal atom, and the 3 molecules of D are coordinated to the 2 atoms of Met: ##STR1## R.sup.1 -R.sup.10, and R.sup.21 -R.sup.28 are each H, halogen, nitro, alkyl or haloalkyl, aryl, aralkyl, --SO.sub.2 N(R.sup.11).sub.2 (R.sup.11 is H, alkyl, aryl, aralkyl), --N(R.sup.12).sub.2 (R.sup.12 is H, lower alkyl, aryl, aralkyl, acyl), --CONH(R.sup.13) (R.sup.13 is H, a lower alkyl, aryl, aralkyl); 2 or more of R.sup.1 -R.sup.10 and/or R.sup.21 -R.sup.28 may bind together to form an aromatic or aliphatic ring.
Abstract: A compound of formula (I) or a mixture thereof ##STR1## The compounds are useful as solvent dyestuffs and exhibit high solubility in alcoholic solvents, e.g. ethanol.
Abstract: Compounds of formula (I) ##STR1## wherein R.sub.1 is H or SO.sub.3 M, ##STR2## M is hydrogen or a non-chromophoric cation and X.sup.+ is hydrogen or a non-chromophoric cation, are useful as dyes for oxidized aluminium substrates.
Abstract: A process for preparing a mixed aluminium-heavy metal dyestuff complex, in which the amount of heavy metal present is 10-98% and that of aluminium is 2 to 90% comprisingi) reacting the metal free dyestuff with less than a stoichiometric amount of a heavy metal compound followed byii) reacting the product with an aluminium compound in an amount to produce a stoichiometric excess of metal (calculated on all the metal present) to form a mixed aluminium-heavy metal complex.
Abstract: Disclosed is an original approach to solving the environmental problem associated with the use of Cr-based metallized azo dyes to deliver black shades on natural and synthetic substrates. This invention affords methods for both the synthesis of metallized dyes and the generation of black dyeings using those dyes without employing metals designated as priority pollutants at any stage in either method. The key element of the disclosure is the use of black 1:2 Fe complexes of azo dyes in lieu of currently used Cr-based complexes which are based on environmentally unfriendly priority pollutant metals without compromising the desirable high fastness properties of the latter complexes, an accomplishment heretofore assumed unachievable.
Type:
Grant
Filed:
April 16, 1993
Date of Patent:
December 27, 1994
Assignee:
North Carolina State University
Inventors:
Harold S. Freeman, Abraham Reife, Jolanta Sokolawska-Gajda
Abstract: Metal-azo dyes with excellent solubility in organic media are provided. The metal-containing dyes of the present invention have a nucleus of the formula: ##STR1## wherein the substituents have the meaning given in the description. Dye-donor sheets comprising the above-mentioned dyes are also disclosed.
Type:
Grant
Filed:
September 8, 1992
Date of Patent:
May 24, 1994
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: The present invention relates to a dye-containing light-polarizing film wherein a disazo dye represented by the formula (I) is used: ##STR1## wherein Me represents a transition metal, being copper, nickel, zinc or iron, R represents a 1-naphthol or 2-naphthol residue which is bonded to azo group at the position adjacent to its hydroxyl group forming a complex bond together with the transition metal and which may have a substituent such as a sulfonic acid, sulfonamide, amino, acylamino or arylamino group or a hydroxyl group not adjacent to the azo group, X and Y represent a hydrogen atom, a C.sub.1 -C.sub.4 alkyl, lower alkoxy, carboxylic acid, sulfonic acid, sulfonamide, sulfonalkylamide, amino, acrylamino or nitro group or a halogen atom, and Z represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl or lower alkoxy group, said formula (I) having from 1 to 3 sulfonic acid groups.
Type:
Grant
Filed:
December 18, 1992
Date of Patent:
May 10, 1994
Assignee:
Sumitomo Chemical Company, Limited
Inventors:
Toyokazu Okada, Koji Higashi, Shinjiro Kawasaki, Yutaka Nishii
Abstract: The invention concerns new diorganotin compounds derived from N-cyclohexyl-N'-hydroxy diazenium oxide, as well as bactericides and fungicides which are suitable as disinfectants, as preservatives for wood and other materials, for bactericidal and fungicidal finishing of textiles, plastics, building materials or as biocides for paint systems and which contain these diorganotin compounds as active ingredients.
Abstract: A method for detecting and measuring the concentration in solution of polyhydroxyl compounds, such as sugars. The invention makes use of certain dyes that, when linked to a derivative of boronic acid (or boronate ion), arsenious acid (or arsenite ion), or germanic acid (or germanate ion), exhibit quantitative responses to the presence of polyhydroxyl species.
Abstract: Transition metal complexes of the compounds of the formulae I and II ##STR1## in which A is an isocylic or heterocyclic aromatic radical, R is --H, halogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy, R.sub.1 is --H, C.sub.1 -C.sub.4 -alkyl or phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, --NO.sub.2, --CONH.sub.2, --CONHR.sub.2 or C.sub.2 -C.sub.5 -N-alkylcarbamoyl, X is --CH.dbd. or --N.dbd. andB is --H, C.sub.1 -C.sub.4 -alkyl, --NHCONH.sub.2, --NHCONH-C.sub.1 -C.sub.4 -alkyl, --NHCONR.sub.2, --NHCSNH.sub.2, --NHCSR.sub.3, --NHC(NH)NH.sub.2, --NHR.sub.2, --NHCOR.sub.3, --NHSO.sub.2 R.sub.3 or a heterocyclic aromatic radical, and R.sub.2 and R.sub.3 are phenyl or substituted phenyl, are suitable for pigmenting high-molecular organic material.
Abstract: High molecular weight organic material is effectively colored by the incorporation therein of a copper or nickel complex of the ligand compound of formula I ##STR1## wherein A is an isocyclic or heterocyclic aromatic moiety, R is H, halogen, lower alkyl or alkoxy, R.sub.1 is H, lower alkyl, phenyl or substituted phenyl, and B is H, lower alkyl, ureido or substituted ureido, guanidino, anilino, benzamido or a heterocyclic aromatic moiety.
Abstract: Disclosed are chrome complex dyes of the formula ##STR1## and of the formula ##STR2## wherein Z and Z' independently of one another are each nitrogen or --CH--;X and X' independently of one another are each oxygen, or a group of the formula --NR--, in which R is hydrogen or C.sub.1 -C.sub.4 -alkyl, provided X is oxygen when Z is --CH-- and provided X' is oxygen when Z' is --CH--;A and B independently of one another are each a diazo component of a benzene or naphthalene radical which carries the hydroxyl or carboxyl group in the o-position with respect to the azo group;C and D independently of one another are each a benzene or naphthalene radical which carries in the o-position with respect to the azo or azomethine group a hydroxyl or carboxyl group, or the radical of an aliphatic or cycloaliphatic aminocarboxylic acid, if n.sub.2 or n.sub.
Abstract: Chrome azo-azomethine dyes are disclosed which contain a benzthiazolylphenyl or stilbenyl radical bound via an aldehyde group to the aldehyde moiety of the azomethine dyes. The dyes are particularly useful for dyeing wool, polyamide and leather.
Abstract: The present invention relates to novel chromium complex dyes of the formula ##STR1## wherein Z is hydrogen, chloro, bromo, nitro, lower alkyl or acylamino;L is H.sub.
Type:
Grant
Filed:
April 13, 1983
Date of Patent:
October 14, 1986
Assignee:
Ciba-Geigy Corporation
Inventors:
Gerhard Back, Fabio Beffa, Arthur Buhler
Abstract: Photographic elements, diffusion transfer assemblages and coordination complexes are described which employ a novel nondiffusible compound capable of releasing at least one diffusible dye moiety having the formula: ##STR1## wherein: (a) D.sup.1, D.sup.2 and D.sup.3 each independently represents the atoms necessary to complete an aromatic heterocyclic nucleus having at least one ring of 5 to 7 atoms;(b) Z.sup.1 and Z.sup.2 each independently represents the atoms necessary to complete an aromatic carbocyclic or heterocyclic nucleus having at least one ring of 5 to 7 atoms or a ketomethine group;(c) G.sup.1 and G.sup.2 each independently represents a metal chelating group;(d) Me is a polyvalent, hexacoordinate metal ion,(e) CAR represents a ballasted carrier moiety capable of releasing the diffusible dye moiety as a function of development of the silver halide emulsion layer under alkaline conditions; and(f) n is 1, 2 or 3.
Abstract: The novel asymmetric 1:2 chrome complex dyes of the formula I given in claim 1 are suitable in particular for dyeing wool or polyamide and especially leather.