Chalcogen Double Bonded Directly To The Hetero Ring Patents (Class 534/789)
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Patent number: 10023742Abstract: The present invention relates to azo dyes of formula wherein R1 denotes C1-C12 alkyl which is unsubstituted or substituted by one or more C1-C12 alkoxy groups, hydroxyl groups, amino groups, cyano groups or halogen atoms and which may be interrupted one or more times by the radical —O—, —S—, —NR4—, —COO— or —OOC—; R4 is hydrogen or C1-C12 alkyl; either R2 is cyano and R3 is halogen or R2 is halogen and R3 is cyano; and Ar represents a carbocyclic or heterocyclic aromatic radical, to the process for the preparation thereof, to mixtures containing said dyes and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fiber materials, more especially textile materials.Type: GrantFiled: May 11, 2016Date of Patent: July 17, 2018Assignee: Huntsman International LLCInventors: Urs Lauk, Patric Nowack, Ralf Petermann, Romeo Dreier
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Patent number: 9376570Abstract: The present invention relates to azo dyes of formula (1), wherein R1 denotes C1-C12alkyl which is unsubstituted or substituted by one or more C1-C12alkoxy groups, hydroxyl groups, amino groups, cyano groups or halogen atoms and which may be interrupted one or more times by the radical —O—, —S—, —COO— or —OOC—: R4 is hydrogen or C1-C12alkyl; either R2 is cyano and R3 is halogen or R2 is halogen and R3 is cyano; and Ar represents a carbocyclic or heterocyclic aromatic radical, to the process for the preparation thereof, to mixtures containing said dyes and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fiber materials, more especially textile materials.Type: GrantFiled: June 26, 2013Date of Patent: June 28, 2016Assignee: Huntsman International LLCInventors: Urs Lauk, Patric Nowack, Ralf Petermann, Romeo Dreier
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Publication number: 20140196224Abstract: The present disclosure relates to a dye of formula (1a) and also to a process for its preparation and to its use in the dyeing or printing of semi-synthetic and, especially, synthetic hydrophobic fibre materials, more especially textile materials.Type: ApplicationFiled: March 18, 2014Publication date: July 17, 2014Applicant: Huntsman International LLCInventors: Antoine Clement, Alfons Arquint, Urs Lauk
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Publication number: 20110197377Abstract: The present invention relates to dyes of formula wherein R1 and R2 are each independently of the other hydrogen, vinyl, allyl or C1-C6alkyl which is unsubstituted or substituted by cyano, carboxy, hydroxy, C1-C6alkoxy or C6-C24aryl, R3 is hydrogen, C1-C6alkyl or C6-C24aryl, R4 is hydrogen, C1-C6alkyl or C6-C24aryl, 2-Cyano-C1-C6alkyl, 2-Alkoxy-C1-C6alkyl, 2-Oxo-C1-C6alkyl, n is 0, 1 or 2, and D denotes a radical of formula (2), (3), (4), (5), (6) or (7) wherein R5 is hydrogen, nitro, cyano or halogen, R6 and R7 are each independently of the other hydrogen, nitro, cyano or halogen, R8 and R9 are each independently of the other hydrogen, nitro, cyano or halogen, R10 and R11 are each independently of the other nitro, cyano, trifluoromethyl, carboxy, C1-C6alkyl, C1-C6alkoxy, C1-C6acylamino or halogen, R12 and R13 are each independently of the other hydrogen, nitro, cyano, trifluoromethyl, carboxy, C1-C6alkoxycarbonyl, C1-C6alkylsulfonyl, C1-C6alkylsulfonylamino, C1-C6acylamino or halogen, R14 represenType: ApplicationFiled: September 23, 2009Publication date: August 18, 2011Applicant: Huntsman International LLCInventors: Ralf Petermann, Christian Suppiger, Urs Lauk
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Publication number: 20110078863Abstract: The present invention relates to dyes of formula wherein R1 is 2-methoxyethyl, 2-ethoxyethyl or 2-(2-ethoxyethoxy)ethyl, R2 is C1-C8alkyl which is unsubstituted or substituted by one or more hydroxy groups, halogen atoms, C1-C4alkoxy groups, C2-C8alkoxyalkoxy groups, C1-C4alkyl-COO— groups or C1-C4alkyl-OCO— groups, R3 is methyl, hydroxy, halogen, —NH—SO2—R5 or —NH—CO—R6, wherein R5 is methyl or ethyl and R6 is methyl, ethyl, methoxymethyl or 2-methoxyethyl, and R4 is ethyl or n-propyl, and also to a process for their preparation and to their use in the dyeing or printing of semi-synthetic and, especially, synthetic hydrophobic fibre materials, more especially textile materials.Type: ApplicationFiled: December 9, 2010Publication date: April 7, 2011Applicant: Huntsman International LLCInventors: Antoine CLÉMENT, Alfons ARQUINT, Urs LAUK
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Patent number: 7125966Abstract: The present invention relates to novel dyestuffs of formula (I) wherein the substituents have the meanings defined in the claims, the production of such dyestuffs, the use of these dyestuffs and material dyed or printed by such dyestuffsType: GrantFiled: October 17, 2003Date of Patent: October 24, 2006Assignee: Clariant Finance (BVI) LimitedInventor: Robert Egli
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Patent number: 7087731Abstract: The present invention relates to dyes of formula wherein R1 is hydrogen, methyl or —BHCO—C1–C4alkyl, R2 is C1–C4alkyl, it being possible for the alkyl chain, from C2 upwards, optionally to be interrupted by an oxygen atom, and R3 has, independent of R2, any of the meanings of R2, and to the process for the preparation thereof and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydmophobic fiber materials, especially textile materials.Type: GrantFiled: January 29, 2002Date of Patent: August 8, 2006Assignee: Ciba Specialty Chemicals CorporationInventors: Antoine Clément, Jean-Claud Wilhelm, Alfons Arquint, Urs Lauk
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Patent number: 7012137Abstract: The present invention relates to dyes of formula (I) wherein R is hydrogen or bromine, R1 is hydrogen, methyl or —NHCO—C1–C4alkyl, R2 is C1–C4alkyl substituted by C1–C4alkoxy and R3 has, independently of R2, any of the meanings of R2, and to the process for the preparation thereof and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic fiber materials, especially textile materials.Type: GrantFiled: January 29, 2002Date of Patent: March 14, 2006Assignee: Ciba Specialty Chemicals CorporationInventors: Antoine Clément, Jean-Claude Wilhelm, Alfons Arquint, Urs Lauk
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Patent number: 6555664Abstract: The present invention relates to dyes of formula wherein R is methyl or butyl, R1 is hydrogen, halogen, cyano or nitro, R2 is halogen or cyano, R3 is hydrogen, halogen, C1-C4alkyl or C1-C4alkoxy, R4 is hydrogen, C1-C4alkyl, halogen, CF3 or —NHCOR7 wherein R7 is C1-C4alkyl, R5 is C1-C6alkyl that is unsubstituted or substituted by hydroxy, cyano, acyloxy, or by phenoxy, x being a number from 0 to 4 and it being possible for the alkyl chain, from C2 upwards, optionally to be interrupted by one or more oxygen atoms, or is a radical of formula —CH2CH2—O—COR8, of formula or of formula and R6 is a radical of formula —CH2CH2—O—COR8 or of formula R8 and R9 each independently of the other being C1-C4alkyl and R10 being hydrogen or C1-C4alkyl, or, when R is methyl, R5 and R6 are each independently of the other C1-C4alkyl, with the proviso that when R is n-butyl andType: GrantFiled: June 28, 2001Date of Patent: April 29, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Urs Lauk, Antoine Clément, Romeo Dreier, Alfons Arquint
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Patent number: 6184363Abstract: The invention provides novel non-&bgr;-lactam inhibitors of &bgr;-lactamases. In particular, the invention provides such inhibitors which are boronic acids of formula (1) which is set forth in the specification. These compounds may be used with &bgr;-lactam antibiotics to treat &bgr;-lactam-antibiotic-resistant bacterial infections. These compounds are also antibacterial by themselves. Finally, the invention provides a pharmaceutical composition comprising these compounds.Type: GrantFiled: December 16, 1998Date of Patent: February 6, 2001Assignee: Northwestern UniversityInventors: Brian K. Shoichet, Grady Scott Weston
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Patent number: 6087480Abstract: Preparation of sparingly soluble aromatic amines by catalytic hydrogenation of the corresponding aromatic nitro compounds in the presence of hydrogen, a solvent and a catalyst having a particle size of not less than 0.5 mm, wherein the aromatic nitro compound selected is a compound whose corresponding amine is soluble to an extent of not more than 50% by weight in the solvent used under the reaction conditions of the hydrogenation, and also their use for preparing azo compounds.Type: GrantFiled: December 16, 1998Date of Patent: July 11, 2000Assignee: Ciba Specialty Chemcals CorporationInventor: Bernd Lamatsch
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Patent number: 6008332Abstract: Disperse azo dyes of formula ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.2 alkyl, halogen, NH--CO--R.sub.5 or O--SO.sub.2 --R.sub.6 ; R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, unsubstituted C.sub.1 -C.sub.8 alkoxy or C.sub.1 -C.sub.8 alkoxy which is substituted by halogen, cyano, phenyl, --Y--C.sub.1 -C.sub.8 alkyl or --Y-phenyl; R.sub.3 is unsubstituted C.sub.1 -C.sub.8 alkyl or C.sub.1 -C.sub.8 alkyl which is substituted by hydroxy, cyano, vinyl, phenyl, halogen, --X-phenyl or --X--C.sub.1 -C.sub.8 alkyl, and --X--C.sub.1 -C.sub.8 alkyl may be substituted by halogen or cyano and --X-phenyl may be substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen; R.sub.4 is hydrogen or, independently of R.sub.3, has the meaning of R.sub.3, and R.sub.3 and R.sub.4, together with the linking nitrogen atom, can also be a heterocyclic radical; R.sub.5 is unsubstituted C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkyl which is substituted by halogen, phenyl, cyano or C.sub.1 -C.sub.Type: GrantFiled: July 17, 1996Date of Patent: December 28, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Paul Herzig, Romeo Dreier
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Patent number: 5962658Abstract: Derivatives of (3-oxoisoindolin-1-ylidine)propandinitrile, and a method for preparing the derivatives, are disclosed herein. The (3-oxoisoindolin-1-ylidine)propandinitrile derivatives can be prepared easily and at low cost. Also, the derivatives show good heat resistance at temperatures required for manufacturing an electro-optic device, and can minimize light loss at a near infrared light wavelength range by replacing hydrogen of the C--H bond with halogen atom. As a result, the derivatives of the present invention are useful as an optical material for an electro-optic device. In addition, the (3-oxoisoindolin-1-ylidine)propandinitrile derivatives can be used as an intermediate for synthesizing a new compound having good electro-optic characteristics and heat resistance.Type: GrantFiled: September 18, 1998Date of Patent: October 5, 1999Assignee: SamSung Electronics Co., Ltd.Inventors: Dong-Hack Suh, Hyun-Cheual Choi, Tae-Hyung Rhee
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Patent number: 5919846Abstract: A novel colorant compound is provided which is the addition product of an organic chromophore having at least one reactive hydroxyl or amine substituent, a polyisocyanate, and a carboxylic acid, sulfonic acid, or salt of either thereof. The polyisocyanate, added in a molar excess relative to the number of such reactive substituents, reacts with the reactive hydroxyl or amine groups to provide terminal isocyanate groups. Subsequently, the carboxylic acid or salt thereof, also added in an amount excessive in relation to the number of terminal isocyanate groups, reacts therewith to from urethane moieties on the colorant. Such a compound provides excellent ink compositions upon dilution and are very soluble within all the standard ink diluents. Furthermore, such colorants provide good jettability, waterfastness, washfastness, and the like, within ink-jet applications on various types of printing substrates.Type: GrantFiled: February 19, 1998Date of Patent: July 6, 1999Assignee: Milliken Research CorporationInventors: Raj Batlaw, John W. Miley
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Patent number: 5808015Abstract: Dyestuffs of the formula ##STR1## wherein D is the radical of a carbo- or heterocyclic diazo component,X represents O, NH, NT, NCOT, NCCH.sub.2 T or NSO.sub.2 T,are preferably suitable, if m=n=l=o, for dyeing and printing hydrophobic synthetic fiber materials and mixtures thereof with naturally occurring fiber materials.Type: GrantFiled: September 18, 1996Date of Patent: September 15, 1998Assignee: Bayer AktiengesellschaftInventor: Rainer Hamprecht
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Patent number: 5723587Abstract: Disperse dyes of formula ##STR1## wherein D is the radical of a diazo component of the benzene, naphthalene, diphenyl, azobenzene, thiophene, benzothiazole, benzisothiazole, thiazole, thiadiazole, indazole, benzotriazole, pyrazole, anthraquinone, naphtholimide, chromone or diphenylene oxid series;X is hydrogen, methyl, halogen or --NH--CO--R, wherein R is methyl, ethyl, propyl, isopropyl, ethoxy or amino;Y is hydrogen, halogen, methoxy or --O--(CH.sub.2).sub.n --OR', wherein R' is hydrogen, CH.sub.3 or CH.sub.2 CH.sub.2 CN, and n is an integer from 1 to 6;R.sub.3 is C.sub.1 -C.sub.6 alkyl, andR.sub.4 is hydrogen, C.sub.1 -C.sub.6 alkyl or alkyl.The dyes are particularly suitable for dyeing polyester textile material and are distinguished in particular by very good lightfastness.Type: GrantFiled: August 8, 1996Date of Patent: March 3, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Antoine Clement, Athanassios Tzikas
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Patent number: 5532345Abstract: Compounds of the formula ##STR1## in which the variables are as defined in the claims, which are suitable as fibre-reactive dyes for dyeing or printing widely varying fibre materials, are described.Type: GrantFiled: May 26, 1995Date of Patent: July 2, 1996Assignee: Ciba-Geigy CorporationInventors: Paul Herzig, Anton Andreoli
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Patent number: 5278293Abstract: Azo dyestuffs of the formula ##STR1## having the substituent meanings given in the description, are outstandingly suitable for dyeing and printing materials containing hydroxyl groups and amide groups.Type: GrantFiled: October 31, 1990Date of Patent: January 11, 1994Assignee: Bayer AktiengesellschaftInventors: Karl-Josef Herd, Manfred Hoppe, Hermann Henk, Klaus Kunde, Frank-Michael Stuohr
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Patent number: 5264032Abstract: Pigment preparation essentially comprisinga) at least one pigment from the class of azo, anthrapyrimidine, anthanthrone, quinacridone, perinone, diketopyrrolopyrrole, dioxazine, flavanthrone, indanthrone, isoindolinone, isoviolanthrone, perylene, phthalocyanine, pyranthrone or thioindigo pigments or a mixture of pigments belonging to various classes, andb) at least one dispersant of the formula (I) ##STR1## in which P, independently of the pigments mentioned in a), is a radical of an anthanthrone azo, quinacridone, perinone, diketopyrrolopyrrole, dioxazine, indanthrone, perylene, phthalocyanine or thioindigo pigment,R.sup.1 and R.sup.2, independently of one another, are hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.Type: GrantFiled: October 21, 1992Date of Patent: November 23, 1993Assignee: Hoechst AGInventors: Erwin Dietz, Manfred Urban
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Patent number: 5256784Abstract: Nonlinear-optic (NLO) compositions containing functionalized merocyanine dyes, such that the molecules, comprising the NLO-active compositions have a functional group at each end of the molecule and each functional group differing in reactivity, thus permitting stepwise reaction of each functional group, and NLO-active molecules prepared from hemioxonol dyes derviatived with (meth)acrylate or (meth)acrylamide groups, and their uses in devices such as second harmonic generators or polymer integrated optics.Type: GrantFiled: January 16, 1992Date of Patent: October 26, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Cecil V. Francis, Elisa M. Cross, Roberta E. Harelstad, Paul F. Korkowski, Peter C. Leung, David W. Macomber, John E. Trend
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Patent number: 5218095Abstract: The novel dispersion dyes of the formula ##STR1## in which R.sub.1 is a C.sub.2 -C.sub.8 alkyl radical which is substituted by hydroxyl, halogen, a radical --X--C.sub.1 -C.sub.8 alkyl or --X--phenyl, in which X is a bridging member of the formula --O--, ##STR2## and R.sub.2 and R.sub.3, independently of one another, are each an unsubstituted C.sub.1 -C.sub.8 alkyl radical or a C.sub.2 -C.sub.8 alkyl radical which is substituted as mentioned for R.sub.1, or in which R.sub.1 and R.sub.2 together with the nitrogen atom linking them are a heterocyclic radical, are suitable in particular for the dyeing of polyester textile material.Type: GrantFiled: February 15, 1991Date of Patent: June 8, 1993Assignee: Ciba-Geigy CorporationInventor: Martin Trottmann
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Patent number: 5200512Abstract: There are described azo compounds which possess fiber-reactive groups and have valuable dye properties and are capable of dyeing hydroxy- and/or carboxamido-containing materials, in particular fiber materials, such as cellulose fibers and natural and synthetic polyamide such as wool, in strong, fast shades. They conform to the formula (1) ##STR1## where D is phenyl or naphthyl which are each substituted, at least one of these substituents being a water-solubilizing group or containing a water-solubilizing group;Y is fluorine, chlorine or a group of the formula--A--RwhereA is oxygen or the group NH andR is hydrogen, cycloalkyl or alkyl which may be interrupted by one or two hetero groups, or is benzyl, sulfomethyl, .beta.-sulfoethyl or cyano;X is fluorine, chlorine or a group conforming to the formula --NH--B, whereB is a group of the formula (3a), (3b) or (3c) ##STR2## where alk is alkylene which may be interrupted by one or two hetero groups,Z is a vinyl or an ethyl group which is substituted in the .beta.Type: GrantFiled: December 27, 1991Date of Patent: April 6, 1993Assignee: Hoechst AGInventor: Uwe Reiher
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Patent number: 5187265Abstract: The present invention relates to a chromogenic benzoisothiazolone polymer derivative for measuring the presence or appearance of thiols in an aqueous system.Type: GrantFiled: February 28, 1992Date of Patent: February 16, 1993Assignee: Miles Inc.Inventors: James P. Albarella, David L. Garling, Robert P. Hatch
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Patent number: 5156971Abstract: A diagnostic test for environmental bacillus which comprises the steps of inoculating an agar growth medium comprising a nitrate source, luminol and 3-amino-L-tyrosine (3AT) with the sample, incubating the inoculated medium and determining the presence of the bacillus. The novel medium preferably comprises potassium nitrate, luminol, 3-amino-L-tyrosine and trypticase soy agar. Antibiotics and/or a specific bacteriophage may be added to the medium surface in localized areas to show specific bacterial lysis for identification. The novel medium and the methods of this invention are suitable for the identification of B. anthracis.Type: GrantFiled: January 15, 1992Date of Patent: October 20, 1992Inventors: Johnathan L. Kiel, John L. Alls, Richard A. Weber, Jill E. Parker
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Patent number: 5114431Abstract: A disperse dye mixture comprising a red disperse dye of the following formula (A): ##STR1## and at least one red disperse dye of the following formula (B): ##STR2## wherein R.sup.1 is C.sub.2 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy C.sub.2 -C.sub.3 alkyl or C.sub.1 -C.sub.4 alkoxyethoxyethyl, in a weight ratio of (B)/(A) of from 0.1 to 5.Type: GrantFiled: February 12, 1991Date of Patent: May 19, 1992Assignee: Hoechst Mitsubishi Kasei Co., Ltd.Inventors: Riyouichi Sekioka, Kouichi Seto
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Patent number: 5043269Abstract: A novel chromogenic substrate to peroxidase enzymes is provided which is comprised of a mixture of a colorless mixture of two compounds, such as, 3-methyl-2-benzothiazolinone hydrazone and 2-hydroxy-2,4,6-cycloheptatrienone, which undergo an oxidative coupling in the presence of peroxidase and hydrogen peroxide forming a purple indamine dye. Under certain circumstances the dye will precipitate out from the buffered solution and thus provide a permanent record of the determination. The mixture is also stable and unaffected by oxygen of the air or by hydrogen peroxide.Type: GrantFiled: February 16, 1988Date of Patent: August 27, 1991Inventor: Spyros Theodoropulos
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Patent number: 5037968Abstract: Keto compounds in which to the carbon atom in the neighboring position to the keto compounds there is bonded at least one strongly electron attracting substituent and/or in which there is conjugating with the carbon-oxygen-double bond of the keto group a .pi.-electron system have the ability of interacting selectively with the anions of oxa acids yielding adducts, chelates or complexes.Provided that in the corresponding keto compounds the keto group is a part of a chromophore, then the shifting of the absorption in the visible range or the ultraviolet range of the wave lengths is observed, compared with the corresponding absorption of the free keto compound.The corresponding keto compounds are used for the determination of the anions of the oxa acids and they e.g. can be the ion sensitive component of a corresponding ions sensitive part for the determination of said anions. Several of said keto compounds can be also used as color indicator for the anions of the oxa acids.Type: GrantFiled: March 11, 1988Date of Patent: August 6, 1991Assignee: Willi MollerInventors: Wilhelm Simon, Erno Pretsch
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Patent number: 5003050Abstract: A water-soluble luminescent compound having repeating units of the formula: ##STR1## The product, which is a polymer having repeating units comprising diazo-linked luminol and hydroxyindole, is referred to as diazoluminomelanin (DALM), since one of the precursors to this product, 3-amino-L-tyrosine (3AT) is closely related to the biological substrates which are converted into melanin.Also provided is a method for preparing DALM which comprises reacting 3AT with an alkali metal nitrite, and reacting the resulting diazonium salt with luminol.DALM can be used for chemiluminescent immunoassays for biological and chemical agents; in radiofrequency and ionizing radiation dosimeters; and for RNA/DNA hybridization assays for viruses and genetic detection.Type: GrantFiled: March 7, 1990Date of Patent: March 26, 1991Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Johnathan L. Kiel, Gerald J. O'Brien
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Patent number: 4994563Abstract: The azo dyes of the formula ##STR1## in which D is a diazo component, R.sub.1 and R.sub.2 independently of one another are each a C.sub.1 -C.sub.10 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl radical each of which is substituted or unsubstituted, or R.sub.1 and R.sub.2, together with the nitrogen atom linking them, are a 5-membered, 6-membered or 7-membered ring each of which is unsubstituted or substituted by heteroatoms, R.sub.3 is hydrogen, halogen or a C.sub.1 -C.sub.10 alkyl, C.sub.1 -C.sub.10 alkoxy or phenoxy radical each of which is substituted or unsubstituted, X is --CO-- or --SO.sub.2 --, n is the number 1, 2, 3, 4, 5 or 6 and M is a cation, produce dyeings of good fastness properties on fibre materials containing nitrogen or containing hydroxyl groups. This application also relates to the preparation and use of said azo dyes and to intermediates utilized in the preparation of said azo dyes.Type: GrantFiled: June 27, 1989Date of Patent: February 19, 1991Assignee: Ciba-Geigy CorporationInventors: Harald Walter, Rudolf Hurter
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Patent number: 4965345Abstract: Solvent dyes of the formula ##STR1## where ##STR2## R.sup.1 and R.sup.2 are each, independently of the other, hydrogen, methyl, ethyl, methoxy or ethoxy,n is 0 or 1 andk, if n is 0, is the radical of a coupling component of the pyrazolone series or, if n is 1, is the radical of a coupling component of the pyrazolone, 2-naphthol, hydroxyquinoline, aniline, naphthylamine, pyridone or 2,6-diaminopyridine series,R.sup.3 and R.sup.4 each independently of the other being C.sub.1 -C.sub.22 -alkyl which may be substituted or interrupted by oxygen, imino or C.sub.1 -C.sub.4 -alkylimino, subject to the proviso that COR has more than 8 carbon atoms, are very highly suitable for coloring organic substrates.Type: GrantFiled: October 2, 1987Date of Patent: October 23, 1990Assignee: BASF AktiengesellschaftInventor: Hermann Loeffler
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Patent number: 4940492Abstract: Colorant mixtures for use in printing inks contain isoquinoline-azo pigments of the formula I ##STR1## where X is chlorine, bromine, C.sub.1 -C.sub.4 -alkoxy or nitro,n is 1, 2 or 3, and the ring A can be substituted, and an isoquinoline-azo dye of the formula II ##STR2## where Y is C.sub.6 -C.sub.20 -alkoxy which may be interrupted by one or more oxygen atoms, and the ring B can be substituted.Type: GrantFiled: June 22, 1988Date of Patent: July 10, 1990Assignee: BASF AktiengesellschaftInventors: Heinrich Kowarsch, Johannes P. Dix
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Patent number: 4734490Abstract: Novel monoazo compounds of the formula I ##STR1## and mixtures of these compounds with one another are described. The substituents X, R, R.sub.1, R.sub.2 and R.sub.3 are defined as follows: R is a phenyl or naphthyl radical which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, or is a cycloalkyl radical which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, or is a C.sub.1 -C.sub.8 -alkyl radical which is unsubstituted or substituted by cyano, halogen, phenyl or sulfophenyl, or is a propenyl radical which is unsubstituted or substituted by halogen, X is hydrogen or halogen, R.sub.1 is hydrogen or a C.sub.1 -C.sub.4 -alkyl radical, R.sub.2 is C.sub.1 -C.sub.8 -alkyl radical, a C.sub.1 -C.sub.4 -sulfatoalkyl radical, a C.sub.1 -C.sub.4 -sulfoalkyl radical or a cycloalkyl radical and R.sub.3 is a C.sub.1 -C.sub.4 -alkyl radical, or is a cycloalkyl radical which is unsubstituted or substituted by C.sub.1 -C.sub.Type: GrantFiled: August 28, 1986Date of Patent: March 29, 1988Assignee: Ciba-Geigy CorporationInventors: Hansrudolf Schwander, Christian Zickendraht
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Patent number: 4499015Abstract: Chromium complex dyestuffs of the formula ##STR1## wherein X denotes hydrogen or nitro,Y denotes hydrogen, nitro or chlorine andZ denotes hydrogen, nitro, chlorine, alkyl, alkoxy, alkylsulphonyl, arylsulphonyl or SO.sub.2 NW.sub.1 W.sub.2 andW.sub.1 and W.sub.2 denote hydrogen, aryl or alkyl, with the proviso thatY and Z do not simultaneously represent nitro, are particularly suitable for dyeing polyamides and wool, on which they produce level dyeings having good general fastness properties.Type: GrantFiled: August 6, 1982Date of Patent: February 12, 1985Assignee: Bayer AktiengesellschaftInventor: Walter Scholl