Plural Carbocyclic Rings Bonded Directly To The Azo Group Patents (Class 534/798)
  • Patent number: 5064637
    Abstract: The present invention involves intradermal, percutaneous, parenteral, or enteral administration of a newly synthesized compound to detect, reduce, or eliminate the occurrence of allergic reactions to sulfonamides. The new compound is a substituted sulfonamide, the substituent being bound to the paraamino (4-position) group through an azo, amide, or other linkage. Because a purpose of the substituent is to make the new compound water soluble, it can take a variety of forms, but it must contain carbon and hydrogen, plus at least one of oxygen and nitrogen. Examples of usable substituents include imidazole, a carbohydrate, or an amino acid such as histidine, tyrosine, tryptophan, lysine, or tyrosine methyl ester; it may also be a synthetic polymer, polypeptde, polysaccharide, or an amino acid homopolymer.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: November 12, 1991
    Assignee: Board of Regents, The University of Texas System
    Inventor: Timothy J. Sullivan
  • Patent number: 5055567
    Abstract: The dyes according to the invention consist of a chromophore and a radical which, on heating, forms an isocyanate or isothiocyanate group. The latter reacts with a suitable group in the environment. Dyeings of excellent thermomigration fastness are obtained. The disclosed dyes are of the formulae ##STR1## where F is the radical of an azo, anthraquinone or tricyanovinyl dye which is free of water-solubilizing groups,B and B' are each independently of the other a direct bond or a bridge member, selected from the group consisting of a straight-chain or branched alkylene group having 2 to 8 C atoms or one of the following groups ##STR2## where R is hydrogen or C.sub.1 -C.sub.6 alkyl, n is an integer from 1 to 8 and m is an integer from 2 to 4,Z is O or S,V is a group which at a temperature between 180.degree. and 240.degree. C. is eliminated as a radical HV, andV' is a direct bond which is cleaved at a temperature between 180.degree. and 240.degree. C.
    Type: Grant
    Filed: April 10, 1989
    Date of Patent: October 8, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Liechti, Karl Emmenegger, Martin Trottmann
  • Patent number: 5006128
    Abstract: Compounds of the formula ##STR1## and salts thereof, whereinR.sub.1 is hydrogen or methyl,R.sub.2 is hydrogen, methyl or acetamido,R.sub.3 is hydrogen, methyl or methoxy,R.sub.4 is hydrogen, C.sub.1-4 alkyl or hydroxy(C.sub.2-4 alkyl),R.sub.5 is hydroxy(C.sub.2-4 alkyl) or hydroxy(C.sub.2-4 alkoxy)C.sub.2-4 alkyl, or--NR.sub.4 R.sub.5 is a 5- or 6-membered ring containing 1 to 3 hetero atoms which ring is unsubstituted or substituted by 1 to 3 substituents selected from C.sub.1-4 alkyl and C.sub.2-4 alkyl monosubstituted by hydroxy or amino, andthe two naphthyl-2 groups are identically substituted, with the proviso that when R.sub.3 is methoxy, R.sub.1 and R.sub.2 are different, solid and aqueous liquid dye compositions and printing inks comprising such compounds and salts and the use of such compounds and salts for dyeing and printing substrates, especially hydroxy group- and nitrogen-containing organic substrates.
    Type: Grant
    Filed: August 25, 1989
    Date of Patent: April 9, 1991
    Assignee: Sandoz Ltd.
    Inventor: Reinhard Pedrazzi
  • Patent number: 4988594
    Abstract: A photoconductor for electrophotography comprises an electroconductive substrate and a photoconductive layer formed on the substrate and including a novel disazo compound as a charge generating layer. The disazo compound is represented by the following general formula: ##STR1## wherein X1 stands for one of an alkyl group, an aryl group and an aromatic heterocyclic group, each of which groups may be or not may be substituted, X.sub.2 stands for one of a hydrogen atom, a cyano group, a carbamoyl group, a carboxyl group, an ester group and an acyl group, each of X.sub.3 and X.sub.4 stands for one of a hydrogen atom, a halogen atom, a nitro group, an alkyl group and an alkoxyl group, both of last two groups may be or not may be substituted, Z stands for one of a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group and an aromatic heterocyclic group, each of which groups may be or not may be substituted and --N.dbd.N--D--N--N.dbd.N-- stands for a disazo residual group.
    Type: Grant
    Filed: July 26, 1989
    Date of Patent: January 29, 1991
    Assignee: Fuji Electric, Co. Ltd.
    Inventors: Yoshimasa Hattori, Noboru Furusho, Youichi Nakamura, Masami Kuroda
  • Patent number: 4935499
    Abstract: Paper is colored by a process in which a compound which, in the form of the free acid, is of the formula I ##STR1## where, in each case independently of one another, A is unsubstituted or methyl substituted C.sub.1 -C.sub.6 -alkylene or vinylene,R is each hydrogen or C.sub.1 -C.sub.4 -alkyl,X is each --CO-- or --SO.sub.2 --,K is each a cationic group andY is hydrogen, chlorine or bromine.
    Type: Grant
    Filed: September 27, 1988
    Date of Patent: June 19, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Ruske, Hans-Juergen Degen
  • Patent number: 4931067
    Abstract: Method is set forth of dyeing a material comprising forming a solution having a basic salt of a water soluble dye of the formula: ##STR1## wherein n is 0 or 1;m is 0 or 1;m=1 when n=0;p=0 when m=1;p=1 when m=0;the subscripts 1 and 0 indicating, respectively, the presence and absence of the substituent subscripted;Y is CR.sub.2 COO, CR.sub.2 CR.sub.2 COO or CR.sub.2 CR.sub.2 CR.sub.2 COO;each R is independently hydrogen, methyl, ethyl, phenyl or phenyl substituted with methyl, ethyl, halo, cyano, ethynyl or nitro;G is CR, CR.sub.2 CR, CRCR.sub.2, CR.sub.2 CR.sub.2 CR, CR.sub.2 CRCR.sub.2 or CRCR.sub.2 CR.sub.2 ;E is OH, SH or NH.sub.
    Type: Grant
    Filed: March 27, 1987
    Date of Patent: June 5, 1990
    Assignee: SRI International
    Inventor: Ronald Swidler
  • Patent number: 4920222
    Abstract: 3,3-Diarylacrylic acid amides are prepared by the reaction of a benzophenone with an acetamide in the presence of a base characterized in that a sodium alcoholate is used as the base.
    Type: Grant
    Filed: January 30, 1989
    Date of Patent: April 24, 1990
    Assignee: Shell Internationale Research Maatschappij B.V.
    Inventors: Jurgen Curtze, Ludwig Schroder, Paul H. Briner
  • Patent number: 4880431
    Abstract: A monoazo compound of the following formula, ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently hydrogen or alkyl, R.sub.4 is alkyl or carboxy, A is ##STR2## in which R.sub.5 is hydrogen, methyl, methoxy, ethoxy, sulfo or carboxy, X is hydrogen or sulfo, n is 0 or 1, and the asterisked linkage bonds to the azo group, B.sub.1 and B.sub.2 are independently phenylene or naphthylene, W is hydrogen, carbamoyl, sulfoalkyl, cyano, sulfo, chloro or bromo, and Y.sub.1 and Y.sub.2 are independently --CH.dbd.CH.sub.2, --CH.sub.2 CH.sub.2 OSO.sub.3 H or the like, which is useful for dyeing hydroxy group- or carbonamide group-containing materials in a deep yellow color excellent in various fastness properties such as light fastness, perspiration-light fastness and chlorine fastness.
    Type: Grant
    Filed: December 8, 1987
    Date of Patent: November 14, 1989
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kazufumi Yokogawa, Naoki Harada, Takashi Omura
  • Patent number: 4861344
    Abstract: Water-soluble azo compounds having useful fiber-reactive dye properties conforming to the general formula ##STR1## in which: A is phenylene which may be substituted or unsubstituted, or is a radical of the formula ##STR2## in which W is a direct bond or a radical of the formula --CH.dbd.CH-- or --NH--CO--NH-- and R* denotes hydrogen, nitro, sulfo, carboxy, methyl, ethyl, methoxy or ethoxy;n is the number zero or 1;B is a radical of the formula ##STR3## where R is equal to carboxy or carbamoyl; M is hydrogen or an alkali metal; andK is one of five radicals described in the specification, each of which contains a fiber-reactive group.These azo compounds produce fast dyeings on carboxamido- and/or hydroxy-containing materials, in particular cellulose fibers. On cellulose, fast dyeings are also obtained in a weakly acid to neutral medium, for example together with disperse dyes for dyeing a polyester fiber portion.
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: August 29, 1989
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ludwig Schlafer, Hartmut Springer, Reinhard Hahnle
  • Patent number: 4840642
    Abstract: Compounds of the formula ##STR1## and salts thereof, useful for dyeing and printing hydroxy group - or nitrogen-containing organic substrates, for example, leather and fibrous materials containing or consisting of natural or synthetic polyamides or natural or regenerated cellulose; preferably textile material containing or consisting of cotton which is preferably dyed using the exhaust dyeing method.
    Type: Grant
    Filed: September 4, 1987
    Date of Patent: June 20, 1989
    Assignee: Sandoz Ltd.
    Inventors: Gunther Auerbach, Helmut A. Moser
  • Patent number: 4678497
    Abstract: Triazine-substituted azobenzenesulfonamides useful as preemergent and postemergent herbicides, selected from compounds of Formulae I or II ##STR1## or agriculturally suitable salts thereof, wherein R, R.sub.1, R.sub.2, R.sub.3 and A are as defined herein.
    Type: Grant
    Filed: January 13, 1986
    Date of Patent: July 7, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Wallace C. Petersen
  • Patent number: 4664714
    Abstract: A pigment composition consisting of 100 parts by weight of a pigment, and from 0.1 to 30 parts by weight of a pigment dispersant of formula ##STR1## in which Q is (a) an anthraquinone dye or pigment radical, (b) an azo dye or pigment radical, (c) a benzimidazolone dye or pigment radical, (d) a phthalocyanine dye or pigment radical, (e) a quinacridone dye or pigment radical, (f) a dioxazine dye or pigment radical, (g) an anthrapyrimidine dye or pigment radical, (h) an anthanthrone dye or pigment radical, (i) an indanthrone dye or pigment radical, (j) a falvanthrone dye or pigment radical, (k) a pyranthrone dye or pigment radical, (l) a perinone dye or pigment radical, (m) a perylene dye or pigment or (n) a thioindigo dye or pigment radical; X is a direct bonds, --CH.sub.2 --; ##STR2## Y.sub.1 is NH or --O--; Z is in which Y.sub.2 is --NH-- or --O--, or --NH--X--Q when n is 1; R.sub.1 and R.sub.
    Type: Grant
    Filed: April 10, 1985
    Date of Patent: May 12, 1987
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Hiromitsu Katsura, Shigeyuki Ehashi, Motohiko Kashioka, Makoto Sakamoto
  • Patent number: 4628083
    Abstract: The invention relates to new arylazo compounds of the general formula ##STR1## wherein R.sub.1 and R.sub.2 independently of each other represent hydrogen or C.sub.1-3 alkyl, R.sub.3 represents hydrogen, halogen, C.sub.1-3 alkyl, C.sub.1-3 alkoxy, carboxy, C.sub.1-3 alkoxycarbonyl, C.sub.1-3 alkylcarbonyl or a group X--NH--SO.sub.2 --, wherein X represents a heterocyclic ring, R.sub.4 represents hydrogen, halogen or C.sub.1-3 alkyl, and n is the integer 1 or 2, the two groups ##STR2## being the same or different when n is 2, and lactones and salts thereof. The compounds of formula I have a high inhibiting effect on prostaglandin synthetizing and inactivating enzymes and may therefore be used as a drug and anti-fertility agent. The invention also relates to preparation of the compounds of formula I as well as pharmaceutical compositions containing the same.
    Type: Grant
    Filed: January 18, 1985
    Date of Patent: December 9, 1986
    Assignee: Pharmacia AB
    Inventor: Karl H. Agback
  • Patent number: 4496738
    Abstract: 1,2,4-Triazole derivatives of the formula ##STR1## where R.sup.1 is alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, or unsubstituted or substituted aryl, heteroaryl or arylalkyl,R.sup.2 is hydrogen or, independently of R.sup.1, has one of the meanings given for R.sup.1,R.sup.3 and R.sup.4 independently of one another are each hydrogen, halogen, nitro or lower alkyl andZ is hydroxyl or a --O.sup..crclbar. M.sup..sym. radical, where M.sup..sym. is one equivalent of a metal cation or is an unsubstituted or substituted ammonium ion,their preparation, and fungicides containing these compounds.
    Type: Grant
    Filed: June 18, 1982
    Date of Patent: January 29, 1985
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Stubenrauch, Eberhard Ammermann, Gerhard Hamprecht, Ernst-Heinrich Pommer