Containing -c(=x)-, Wherein X Is Chalcogen Patents (Class 534/850)
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Publication number: 20140013520Abstract: Dyes, compositions comprising dyes and methods for using the same are provided.Type: ApplicationFiled: April 24, 2013Publication date: January 16, 2014Inventors: Jana Lewis, Lorna Nagamoottoo-Casse, David Puerta
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Patent number: 8592565Abstract: The invention relates to carbon surfaces modified with one or more azide groups. The invention also relates to methods of modifying carbon surfaces with one or more azide groups.Type: GrantFiled: January 10, 2008Date of Patent: November 26, 2013Assignee: The Board of Trustees of the Leland Stanford Junior UniversityInventors: Christopher E. D. Chidsey, Anando Devadoss, Neal K. Devaraj
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Patent number: 8329775Abstract: Azo compounds that block visible light are disclosed. These light absorbers are particularly suitable for use in intraocular lens materials.Type: GrantFiled: January 18, 2011Date of Patent: December 11, 2012Assignee: Novartis AGInventor: Walter R. Laredo
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Publication number: 20120272990Abstract: Dyes, compositions comprising dyes and methods for using the same are provided.Type: ApplicationFiled: April 6, 2012Publication date: November 1, 2012Applicant: Living Proof, Inc.Inventors: Jana Lewis, Lorna Nagamoottoo-Casse, David Puerta
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Publication number: 20110154583Abstract: Dyes, compositions comprising dyes and methods for using the same are provided.Type: ApplicationFiled: December 21, 2010Publication date: June 30, 2011Applicant: Living Proof, Inc.Inventors: Jana Lewis, Lorna Nagamoottoo-Casse, David Puerta
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Publication number: 20090240329Abstract: The present invention relates to: novel compounds which are polymerizable functionalized derivatives of the yellow dye product known as C.I. Disperse Yellow 3, listed under CAS no. 2832-40-8, and have the formula the preparation of said novel compounds; their use as yellow dyes; polymerizable and/or crosslinkable compositions containing them; colored polymer matrices obtainable from such compositions; and finally intraocular lenses consisting wholly or partly of such colored polymer matrices.Type: ApplicationFiled: September 27, 2006Publication date: September 24, 2009Applicant: Corneal InnovationInventor: Cecile Gousse
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Publication number: 20090227691Abstract: It is an object of the present invention to provide a method for highly selectively releasing a molecule of interest such as an agent at a desired site while suppressing the influence of catabolic enzymes existing in vivo.Type: ApplicationFiled: November 6, 2008Publication date: September 10, 2009Applicant: RIKENInventors: Hiroshi ABE, Yoshihiro ITO, Aya SHIBATA, Hiroaki KODAMA
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Publication number: 20090123711Abstract: Dye of the formula (I) where Ra is —C6H5-substituted C1-C4-alkyl, Rb is methoxy or ethoxy Rc is methyl or ethyl, its preparation and also the use of this dye in dye mixtures.Type: ApplicationFiled: June 7, 2006Publication date: May 14, 2009Inventor: Helmut Sieber
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Patent number: 7101983Abstract: The present invention relates to novel dyestuffs of formula (I) wherein the substituents have the meanings defined in the claims, the production of such dyestuffs, the use of these dyestuffs and material dyed or printed by such dyestuffs.Type: GrantFiled: April 2, 2002Date of Patent: September 5, 2006Assignee: Clariant Finance (BVI) LimitedInventors: Robert Egli, Oliver Eich, Knut Göke
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Patent number: 7060807Abstract: Monoazo dyestuffs of the general formula (1) wherein R1, R2, R3 and n are as defined in claim 1, method for their preparation and a method for colouring a synthetic textile material or fiber blend thereof using such dyestuffs.Type: GrantFiled: September 22, 2004Date of Patent: June 13, 2006Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventor: Kiyoshi Himeno
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Patent number: 6476202Abstract: Disclosed is a 5-acylamino-2-arylazo, nitro, or nitroso-4-substituted-phenol having the structural formula I: wherein: R* is an arylazo, nitro, or nitroso group, Y is a coupling-off group, and R′ is a substituent group. Also disclosed is a method of using the compound in a simplified process for making a photographic coupler.Type: GrantFiled: December 3, 2001Date of Patent: November 5, 2002Assignee: Eastman Kodak CompanyInventor: Chang-Kyu Kim
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Publication number: 20020111334Abstract: Compounds are disclosed represented by the following formula: 1Type: ApplicationFiled: August 29, 2001Publication date: August 15, 2002Inventors: Nnochiri Nkem Ekwuribe, Jennifer A. Riggs-Sauthier, Elizabeth Malson
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Patent number: 5942603Abstract: This invention related to a novel .beta.-crystal of the compound represented by the following formula (1), ##STR1## which is useful as a dyestuff. The .beta.-crystal of this invention is characterized by being stable in high temperature and having sharp peaks in the powder X-ray diffractometory.This invention is related to a process for producing a said .beta.-crystal, said process comprising heating a known thermally unstable .alpha.-crystal at a temperature higher than 15.degree. C., preferably higher than 40.degree. C. in water, a water-soluble organic solvent, or a solvent comprising water containing an anionic or nonionic surface active agent.Furthermore, this invention is related to a dyestuff composition containing of the said .beta.-crystal, and a process for dyeing comprising employing the said .beta.-crystal.Type: GrantFiled: December 11, 1997Date of Patent: August 24, 1999Assignee: Nippon Kayaku Co., Ltd.Inventors: Yasuo Murakami, Yoshiki Akatani
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Patent number: 5910578Abstract: Azo dyes of the formula ##STR1## where X is oxygen or a radical of the formula NR.sup.6, where R.sup.6 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.13 -alkyl,R.sup.1 is substituted or unsubstituted C.sub.1 -C.sub.13 -alkyl or substituted or unsubstituted phenyl,Y is hydrogen, halogen or cyano,Z is nitro or additionally cyano when Y is halogen or cyano,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, methoxymethyl or substituted or unsubstituted phenyl,R.sup.3 is hydrogen, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkyl, andR.sup.4 and R.sup.5 are each substituted or unsubstituted C.sub.2 -C.sub.13 -alkyl or C.sub.2 -C.sub.6 -alkenyl,are useful for dyeing or printing synthetic materials and are synthesizable using novel dinitroaminoaromatics as diazo components.Type: GrantFiled: July 15, 1998Date of Patent: June 8, 1999Assignee: BASF AktiengesellschaftInventors: Peter Saling, Erhard Klahr, Helmut Reichelt, Sabine Gruettner-Merten
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Patent number: 5744588Abstract: A blue type disperse dye mixture comprising 1.0 part by weight of at least one dye of the formula (1), from 0 to 0.2 part by weight of at least one dye of the formula (2), from 0.05 to 1.0 part by weight of at least one dye of the formula (3) and from 0.05 to 1.0 part by weight of at least one dye of the formula (4): ##STR1## wherein X is a chlorine atom or a bromine atom, R.sup.1 is a C.sub.1-5 alkyl group, R.sup.2 is a C.sub.1-4 alkyl group, and R.sup.3 is a C.sub.1-5 alkyl group or an allyl group, provided that R.sup.1, R.sup.2 and R.sup.3 may, respectively, be the same or different among the formulae (1) to (4).Type: GrantFiled: October 9, 1996Date of Patent: April 28, 1998Assignee: DyStar Japan Ltd.Inventors: Kiyoshi Himeno, Toshio Hihara, Yousuke Takahashi
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Patent number: 5569751Abstract: The present invention relates to new useful azo dyestuffs which are free from ionic groups, of the general formula I ##STR1## wherein X.sup.1, X.sup.2, X.sup.3, Y, R, R.sup.1 and R.sup.2 have the meanings given in Claim 1, mixtures of dyestuffs of the general formula I, the preparation of dyestuffs of the general formula I and their use for dyeing and printing hydrophobic fibre materials.Type: GrantFiled: May 24, 1995Date of Patent: October 29, 1996Assignee: Hoechst Mitsubishi Kasei Co.Inventor: Ulrich Buhler
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Patent number: 5563276Abstract: Acrylic acid or water-soluble derivatives thereof can be polymerized effectively in a short time using as a polymerization initiator an inorganic acid salt or organic acid salt of 2,2'-azobis(2-methylpropionamidoxime).Type: GrantFiled: April 18, 1995Date of Patent: October 8, 1996Assignee: Waco Pure Chemical Industries, Ltd.Inventors: Hideo Takeuchi, Toshiyasu Ito, Yutaka Kojima
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Patent number: 5559218Abstract: 2-Aroylcyclohexanediones I ##STR1## (A is C.sub.1 -C.sub.6 -alkylene; R.sup.1 is substituted phenyl or hetaryl which may furthermore carry a fused ring; R.sup.2 -R.sup.5 are each hydrogen or C.sub.1 -C.sub.4 -alkyl; R.sup.6 is H, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxycarbonyl and R.sup.7 is C.sub.1 -C.sub.4 -alkyl,with the proviso that R.sup.1 is not mono- or dihalophenyl)and the agriculturally useful salts thereof and the esters of I with C.sub.1 -C.sub.10 -carboxylic acids or inorganic acids.The 2-aroylcyclohexanediones I are suitable as herbicides and plant growth regulators.Type: GrantFiled: February 6, 1995Date of Patent: September 24, 1996Assignee: BASF AktiengesellschaftInventors: J urgen Kast, Wolfgang von Deyn, Christoph N ubling, Helmut Walter, Matthias Gerber, Karl-Otto Westphalen
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Patent number: 5554739Abstract: Processes for preparing a carbon product having an organic group attached to a carbon material. The carbon material is selected from graphite powder, a graphite fiber, a carbon fiber, a carbon cloth, a vitreous carbon product, and an activated carbon product. In one process at least one diazonium salt reacts with a carbon material in the absence of an externally applied electric current sufficient to reduce the diazonium salt. In another process at least one diazonium salt reacts with a carbon material in a protic reaction medium.Type: GrantFiled: December 15, 1994Date of Patent: September 10, 1996Assignee: Cabot CorporationInventor: James A. Belmont
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Patent number: 5550218Abstract: Compounds of the formula ##STR1## wherein A is C.sub.1-6 alkylene, D is a diazo component radical of the triazolyl, pyrazolyl, cyano(C.sub.1-4 alkyl)-imidazolyl, 4-chlorothiazolyl, 4-chlorotheinyl-2, 3-phenyl-1,2,4-thiadiazolyl-5, isothiazolyl-5, benzoisothiazolyl-3 or 1,3,4-thiadiazolyl-5 series or the phenyl series wherein the phenyl group is free of sulfonyl groups and may be substituted, by a maximum of 3 substituents 5-nitrothiazolyl-2, ##STR2## R.sub.1a is phenyl or phenyl substituted by 1 to 4 substituents each of which is independently halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, trifluoromethyl, hydroxy, nitro, formyl, cyano, --SCN, (C.sub.1-4 alkyl)carbonyl, (C.sub.1-4 alkyl)carbonylamino, (C.sub.1-4 alkoxy)carbonyl, (C.sub.1-4 alkyl)carbonyloxy, carbamoyl, (C.sub.1-2 alkoxy)(C.sub.2-3 alkoxy)carbonyl or phenyl, andR.sub.2 -R.sub.4 and R.sub.10 -R.sub.Type: GrantFiled: October 6, 1994Date of Patent: August 27, 1996Assignee: Sandoz Ltd.Inventor: Ruedi Altermatt
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Patent number: 5510225Abstract: Dye-donor element for use according to thermal dye sublimation transfer comprising a support having thereon a dye layer containing a bis(N,N-dialkyl(ene) or N,N-diaryl or N-alkyl(ene),N-aryl)aniline azo dye.Type: GrantFiled: June 10, 1993Date of Patent: April 23, 1996Assignee: AGFA-GEVAERT, N.V.Inventors: Wilhelmus Janssens, Luc Vanmaele
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Patent number: 5270455Abstract: A metal complex suitable as dyes for the dyeing of a wide range of textile and non-textile materials, particularly leather and fur, said metal complex of a compound of the formula ##STR1## in which D and D.sub.1, independently of one another, are each the radical of a diazo component of the benzene or naphthalene series and M is a phenylene radical which may be further substituted.Type: GrantFiled: July 27, 1992Date of Patent: December 14, 1993Assignee: Ciba-Geigy CorporationInventor: Ulrich Schlesinger
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Patent number: 5145953Abstract: A biscyclobutarene monomer is prepared having two cyclobutarene moieties bridged by a divalent radical having at least one azo linkage. The monomers can be polymerized to form polymers exhibiting outstanding thermooxidative stability at high temperatures for prolonged time periods.Type: GrantFiled: February 2, 1988Date of Patent: September 8, 1992Assignee: The Dow Chemical CompanyInventors: Robert A. Kirchhoff, Alan K. Schrock
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Patent number: 5075429Abstract: A monoazo compound of the formula, ##STR1## wherein D is a heterocyclic or carbocyclic compound residue such as benzothiazolyl and phenyl, X is hydrogen, alkyl, alkoxy, halogeno, acylamino or the like, Y is hydrogen, halogeno, alkyl, alkoxy and the like, R.sub.1 is alkyl, R.sub.2 is C.sub.2 -C.sub.4 alkylene, B is a bridging group such as ##STR2## --O--, --S--, C.sub.1 -C.sub.6 alkylene and the like, and W.sub.1, W.sub.2, W.sub.3, Z.sub.1, Z.sub.2 and Z.sub.3 are independently hydrogen, alkyl, halogeno or the like, which is useful for dyeing hydrophobic fiber materials to give dyed or printed product of a deep color excellent in fastness properties, particularly those such as washing fastness, even after various finishing treatments of the product.Type: GrantFiled: October 10, 1989Date of Patent: December 24, 1991Assignee: Sumitomo Chemical Company LimitedInventors: Jun Yamamoto, Yasuyoshi Ueda, Takashi Omura, Yosuke Yamamoto, Hideo Hattori, Junichi Sekihachi
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Patent number: 5055567Abstract: The dyes according to the invention consist of a chromophore and a radical which, on heating, forms an isocyanate or isothiocyanate group. The latter reacts with a suitable group in the environment. Dyeings of excellent thermomigration fastness are obtained. The disclosed dyes are of the formulae ##STR1## where F is the radical of an azo, anthraquinone or tricyanovinyl dye which is free of water-solubilizing groups,B and B' are each independently of the other a direct bond or a bridge member, selected from the group consisting of a straight-chain or branched alkylene group having 2 to 8 C atoms or one of the following groups ##STR2## where R is hydrogen or C.sub.1 -C.sub.6 alkyl, n is an integer from 1 to 8 and m is an integer from 2 to 4,Z is O or S,V is a group which at a temperature between 180.degree. and 240.degree. C. is eliminated as a radical HV, andV' is a direct bond which is cleaved at a temperature between 180.degree. and 240.degree. C.Type: GrantFiled: April 10, 1989Date of Patent: October 8, 1991Assignee: Ciba-Geigy CorporationInventors: Peter Liechti, Karl Emmenegger, Martin Trottmann
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Patent number: 5037967Abstract: Disperse dyes containing a monoazo coupling component of the formula ##STR1## in which X is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, acylamino, halogen or a group of the formula --NH--CO--NHQ in which Q is hydrogen, C.sub.1 -C.sub.4 alkyl or phenyl,Y is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkoxy,R is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.12 alkenyl or phenyl, or Y and R, together with the nitrogen atom and the two C atoms linking them, form a 5-membered or 6-membered ring,B is a linear or branched C.sub.2 -C.sub.6 alkylene radical,W is halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy,Z is halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or nitro andm and n are each 0, 1, 2 or 3.Type: GrantFiled: November 7, 1989Date of Patent: August 6, 1991Assignee: Ciba-Geigy CorporationInventors: Angelo D. Casa, Peter Liechti, Max Dempfle
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Patent number: 4985045Abstract: A monoazo dyestuff composition comprising at least two different individual compounds of the formula ##STR1## wherein R.sup.1 and R.sup.2, independently of each other, are linear or branched alkyl having 1 to 4 carbon atoms and R is linear or branched alkyl having 1 to 5 carbon atoms, and where said individual compounds differ from each other in at least the R moiety, has improved dyeing properties compared with the individual dyestuffs when used to dye or print hydrophobic fiber materials.Type: GrantFiled: October 30, 1989Date of Patent: January 15, 1991Assignee: Cassella AktiengesellschaftInventors: Ulrich Buhler, Klaus Hofmann
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Patent number: 4985043Abstract: Mixtures of monoazo dyes suitable for dyeing and printing hydrophobic fiber materials and mixtures thereof with natural fibers contain one or more dyes of the formula I ##STR1## and one or more dyes of the formula II ##STR2## in which Hal denotes bromo or chloro; R.sup.1 and R.sup.2, independently of one another, denote methyl or ethyl; R.sup.3, R.sup.4, R.sup.5 and R.sup.6, independently of one another, denote linear alkyl having 1 to 4 carbon atoms or alkenyl having 3 or 4 carbon atoms; and R denotes methyl, acetylamino, propionylamino, i-butyrylamino, or n-butyrylamino.Type: GrantFiled: March 15, 1989Date of Patent: January 15, 1991Assignee: Cassella AktiengesellschaftInventors: Ulrich Buhler, Manfred Hahnke, Reinhard Kuhn, Margarete Boos
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Patent number: 4978362Abstract: A thermoplastic resin composition is provided which contains a thermoplastic resin and a colorant in the form of a polyalkyleneoxy-trifluoromethyl aniline colorant provided in said thermoplastic resin in a minor amount sufficient to provide coloration to said resin, said colorant having the formula: ##STR1## wherein R.sub.1 is selected from H, a lower alkyl group containing from 1 to about 10 carbon atoms, CH.sub.2 Cl, CH.sub.2 Br, CH.sub.2 OH, phenyl or ##STR2## wherein R.sub.4 is H or a lower alkyl group containing from 1 to about 9 carbon atoms; R.sub.2 is H, CF.sub.3, a lower alkyl group containing from 1 to about 9 carbon atoms, Cl or Br; R.sub.3 is an aromatic or heteroaromatic containing group, and n is an integer from 2 to about 75.Type: GrantFiled: October 11, 1988Date of Patent: December 18, 1990Assignee: Milliken Research CorporationInventors: Edward W. Kluger, John W. Rekers
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Patent number: 4975410Abstract: A thermally-transferred color filter array element comprising a transparent support having thereon a thermally-transparent image comprising a repeating mosaic pattern of colorants in a receiving layer, one of the colorants being a mixture of a yellow dye and a cyan dye to form a green hue, said yellow dye having the formula: ##STR1## wherein: R.sup.1 and R.sup.2 represents hydrogen, alkyl, cycloalkyl, aryl or hetaryl; or can be taken together to form a 5- or 6-membered ring; or either or both of R.sup.1 and R.sup.2 can be joined to a carbon atom of the aromatic ring to form a 5- or 6-membered ring;R.sup.3 represents hydrogen or halogen:Y represents hydrogen, halogen, cyano, alkyl, alkoxy, aryl, hetaryl, aryloxy, acylamido, alkylsulfonamido, or arylsulfonamido; andn is a positive integer from 1 to 5; andsaid cyan dye having the formula: ##STR2## wherein R.sup.4 R.sup.5 represents hydrogen, alkyl, cycloalkyl, aryl or hetaryl;R.sup.6 represents hydrogen, alkyl or alkoxy;R.sup.5 may be taken together with R.sup.Type: GrantFiled: May 26, 1989Date of Patent: December 4, 1990Assignee: Eastman Kodak CompanyInventors: Helmut Weber, Steven Evans
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Patent number: 4937325Abstract: A monoazo dyestuff composition comprising at least two different individual compounds of the formula ##STR1## wherein R.sup.1 and R.sup.2, independently of each other, are linear or branched alkyl having 1 to 4 carbon atoms and R is linear or branched alkyl having 1 to 5 carbon atoms, and where said individual compounds differ from each other in at least the R moiety. The monoazo dyestuff mixtures are used for the dyeing and printing of hydrophobic fibers such as high molecular weight polyesters of their mixtures with natural fiber material.Type: GrantFiled: December 12, 1988Date of Patent: June 26, 1990Assignees: Cassella Aktiengesellschaft, Tokico Ltd.Inventors: Ulrich Buhler, Klaus Hofmann, Hiroshi Mitsuhashi, Harutsugu Ushiota, Akiharu Odagiri, Gen Kano, Susumu Sakamoto
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Patent number: 4920222Abstract: 3,3-Diarylacrylic acid amides are prepared by the reaction of a benzophenone with an acetamide in the presence of a base characterized in that a sodium alcoholate is used as the base.Type: GrantFiled: January 30, 1989Date of Patent: April 24, 1990Assignee: Shell Internationale Research Maatschappij B.V.Inventors: Jurgen Curtze, Ludwig Schroder, Paul H. Briner
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Patent number: 4914190Abstract: Disperse dyes of the formula ##STR1## in which X is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen, Y is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.4 alkoxy, R is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.12 alkenyl or phenyl, or Y and R, together with the nitrogen atom and the two C atoms linking them, form a 5- or 6-ring, B is a straight-chain or branched C.sub.2 -C.sub.6 alkylene radical, Z is a bridge member of the formula ##STR2## or a direct bond and A is a radical of the formula ##STR3## which radicals are unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, halogen or nitro are suitable in particular for dyeing textile material made of polyester fibers.Type: GrantFiled: March 11, 1988Date of Patent: April 3, 1990Assignee: Ciba-Geigy CorporationInventors: Peter Liechti, Angelo Della Casa
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Patent number: 4841009Abstract: Described herein are novel substantially linear monomeric compositions which can be polymerized with one or more difunctional monomers to give novel polymeric compositions having liquid crystal properties. This invention is also directed to a process for preparation of the novel substantially linear monomeric compositions.Type: GrantFiled: July 5, 1985Date of Patent: June 20, 1989Assignee: Amoco CorporationInventor: Donald R. Kelsey
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Patent number: 4837308Abstract: A universally usable process for preparing azo dyestuffs by oxidative coupling consists in carrying out the oxidation in the presence of redox mediators with a standard potential of 0.2-1.5 volts and, if appropriate, an additional oxidizing agent with a standard potential of 0.25-2.5 volts, wherein the sum of the oxidation equivalents should be at least 4. The preferred redox mediator is iodine. The process is particularly suitable for the preparation of heteroaromatic azo dyestuffs using an aniline coupling component.Type: GrantFiled: January 12, 1988Date of Patent: June 6, 1989Assignee: Bayer AktiengesellschaftInventor: Rainer Gerlach
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Patent number: 4835261Abstract: Azo compounds of the formula I ##STR1## where D=diazo componentR.sub.1 and R.sub.2 =alkyl or aralkylX=H, hydrocarbon radical or acylare useful dyestuffs or dyestuff intermediates.Type: GrantFiled: March 12, 1987Date of Patent: May 30, 1989Assignee: Bayer AktiengesellschaftInventor: Klaus Leverenz
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Patent number: 4810783Abstract: An azo dyestuff of the formula ##STR1## wherein D=a diazo component,R.sub.1 and R.sub.2 =alkyl or aralkyl,R.sub.3 =H, R or OR.sub.1 andR.sub.4 =a hydrocarbon radical or acyl,which are prepared in a simple manner by aminolysis with ammonia or an amine of the formula ##STR2## of an azo compound of the formula ##STR3## these dyestuffs dye polyester fibres in blue-green to green shades with good fastness to light.Type: GrantFiled: March 3, 1987Date of Patent: March 7, 1989Assignee: Bayer AktiengesellschaftInventor: Klaus Leverenz
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Patent number: 4804747Abstract: (i) A compound of the formula: ##STR1## wherein R is H, a metal or a group containing a tetravalent N atom;X is S, O, ##STR2## R.sup.1 is NO.sub.2, CN or COOY; Y is H, C.sub.1-4 -alkyl, a metal or a group containing a tetravalent N atom;R.sup.2 and R.sup.3 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms;R.sup.4 and R.sup.5 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms; andR.sup.6 and R.sup.7 are each independently H or a non-hydrophilic group containing up to 4 carbon atoms; orR.sup.4 and R.sup.6 together comprise ring fused to Ring A and R.sup.5 and R.sup.7 are as hereinbefore defined; orR.sup.5 and R.sup.7 together comprise ring fused to Ring A and R.sup.4 and R.sup.6 are as hereinbefore defined; orR.sup.2 and R.sup.4 together with the N atom to which R.sup.2 is attached form a ring fused to Ring A and R.sup.3 and R.sup.5 are as hereinbefore defined; orR.sup.3 and R.sup.Type: GrantFiled: October 16, 1986Date of Patent: February 14, 1989Assignee: Imperial Chemical Industries PLCInventors: Simon Allen, Paul F. Gordon, Richard A. Hann
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Patent number: 4800195Abstract: Novel N-phenyl-N'benzoylureas which are useful as insecticides and acaricides.Type: GrantFiled: October 13, 1983Date of Patent: January 24, 1989Assignee: The Dow Chemical CompanyInventors: Michael J. Burgess, Robert A. Sewell, David P. Clifford
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Patent number: 4795746Abstract: Novel N-phenyl-N'benzoylureas which are useful as insecticides and acaricides.Type: GrantFiled: March 4, 1988Date of Patent: January 3, 1989Assignee: The Dow Chemical CompanyInventors: Michael J. Burgess, David P. Clifford, Robert A. Sewell
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Patent number: 4795807Abstract: Azo disperse dyestuffs are prepared by diazotization and coupling in an aqueous phase, the coupling being carried out in the presence of an ester of a lower aliphatic carboxylic acid.Type: GrantFiled: March 30, 1987Date of Patent: January 3, 1989Assignee: Cassella AktiengesellschaftInventors: Ulrich Buhler, Friedrich Schophoff, Wolf Weidemuller
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Patent number: 4776886Abstract: A halftone gravure printing ink(A) about 2 to about 20% by weight of colorant,(B) about 10 to about 40% by weight of resin and(C) about 80 to about 50% by weight of solventwherein said colorant comprises azo dyestuff of the formula ##STR1## in which A.sub.1, A.sub.2 and A.sub.3 denote hydrogen, halogen, --CN, --NO.sub.2, C.sub.1 -C.sub.6 -alkyl, cycloalkyl, C.sub.1 -C.sub.18 -alkoxy, optionally substituted phenoxy, optionally substituted C.sub.1 -C.sub.18 -alkylsulphonyl, optionally substituted phenylsulphonyl, optionally substituted sulphamoyl, optionally substituted carbamoyl, optionally substituted phenylazo, C.sub.1 -C.sub.18 -alkoxycarbonyl, --CF.sub.3, --SCN, C.sub.1 -C.sub.12 -alkylmercapto, C.sub.1 -C.sub.6 -alkylcarbonyl, optionally substituted phenylcarbonyl or --OH,A.sub.4 and A.sub.5 denote hydrogen, halogen, optionally substituted C.sub.1 -C.sub.6 -alkyl, optionally substituted C.sub.1 -C.sub.6 -alkoxy, --NH--CO--CH.sub.2 CH.sub.2 OA.sub.8, --NH--CO--A.sub.8, --NH--SO.sub.2 --A.sub.Type: GrantFiled: August 4, 1986Date of Patent: October 11, 1988Assignee: Bayer AktiengesellschaftInventors: Manfred Lorenz, Rainer Hamprecht, Artur Haus
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Patent number: 4704452Abstract: Monoazo compounds of the formula ##STR1## in which one of the two substituents R.sub.1 or R.sub.2 or both substituents are C.sub.3 -C.sub.8 -alkyl or a group of the formula ##STR2## in which R.sub.3 and R.sub.4 are independently of each other hydrogen or C.sub.1 -C.sub.4 -alkyl and R.sub.5 is hydrogen, halogen or C.sub.1 -C.sub.4 -alkyl and the other of the two substitutents R.sub.1 or R.sub.2, when the two are not C.sub.3 -C.sub.8 -alkyl or a group of the formula (1a), is hydrogen, halogen or C.sub.1 -C.sub.4 -alkyl, and KK is the radical of a coupling component which is free of water-solubilizing groups the two described. These compounds can be used as dyes for dyeing or printing for example polyester fibre materials.Type: GrantFiled: December 19, 1985Date of Patent: November 3, 1987Assignee: Ciba-Geigy CorporationInventor: Peter Liechti
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Patent number: 4663440Abstract: A brown reactive dye represented by a free acid of the formula, ##STR1## wherein R is a hydrogen atom or a C.sub.1 to C.sub.4 alkyl group, X is --SO.sub.2 CH.sub.2 CH.sub.2 Cl, --SO.sub.2 CH.dbd.CH.sub.2, --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H or --SO.sub.2 CH.sub.2 CH.sub.2 OPO.sub.3 H.sub.2, rings A, B and C are each a benzene or naphthalene ring which may have other substituent, m is 0 to 3 and n is 0 to 1.This dye is suitable for dyeing cellulose fibers brown to afford dyeings superior in fastnesses, acid stability, build-up property and level dyeing property.Type: GrantFiled: May 26, 1981Date of Patent: May 5, 1987Assignee: Sumitomo Chemical Company, LimitedInventors: Takashi Omura, Masaki Sunami, Yasuo Tezuka
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Patent number: 4645832Abstract: Reactive azo dyes represented by the general formula (I) or (II): ##STR1## wherein M is a hydrogen atom or an alkali metal, R.sup.1 is a hydrogen atom, a chlorine atom, a lower alkyl group, a lower alkoxy group, a nitro group or a carboxyl group, R.sup.2 and R.sup.8 are a lower alkyl group, a lower alkoxy group or a sulfonic acid group, R.sup.3, R.sup.7 and R.sup.9 are a hydrogen atom, a lower alkyl group, a lower alkoxy group, an acetylamino group or a sulfonic acid group, R.sup.4 and R.sup.5 are a hydrogen atom, a methyl group, a methoxy group or a sulfonic acid group, R.sup.6 is a hydrogen atom, a lower alkyl group, a lower alkoxy group or a sulfonic acid group, Z.sup.1 is a chlorine atom, a fluorine atom, an aliphatic or an aromatic amino residual group, a methoxy group or a phenoxy group, Z.sup.2 is the same one as Z.sup.1 when Z.sup.3 is ##STR2## Z.sup.2 is a chlorine atom or a fluorine atom when Z.sup.Type: GrantFiled: April 9, 1985Date of Patent: February 24, 1987Assignee: Mitsubishi Chemical Industries LimitedInventors: Toshio Niwa, Yoshiaki Kato
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Patent number: 4544373Abstract: There are described new azo dyes of the formula ##STR1## wherein R.sub.1 is an optionally substituted alkyl group, R.sub.2 is a substituted aliphatic radical, unsubstituted C.sub.3 -C.sub.10 -alkyl or cycloalkyl, and R.sub.3 and R.sub.4 are alkyl groups; and mixtures thereof with analogous azo dyes in which R.sub.4 is H; and also the production and use of these new azo dyes and of the said mixtures thereof for dyeing and printing synthetic fibres, particularly polyester fibres. The dyes are fast to light, have good affinity to the material and a good build-up, have high coloring strength and are stable to hydrolysis.Type: GrantFiled: March 17, 1980Date of Patent: October 1, 1985Assignee: Ciba-Geigy CorporationInventors: Angelo Della Casa, Peter Aeschlimann
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Patent number: 4536569Abstract: A compound of the formula, ##STR1## wherein R.sup.1 is methyl or ethyl, R.sup.2 and R.sup.3 are each C.sub.5 -- or C.sub.6 --alkyl, and Z is chlorine for use as a blue disperse dye of hydrophobic fibers, either alone or as a mixed dye in combination with anthraquinone; the compound combines low cost relative to anthraquinone with superior stability in the dye bath and excellent dyeability; mixed dyes retain anthraquinone-imparted brilliance of color, have good color fastness, dyeability and reproducibility characteristics, and maintain low cost.Type: GrantFiled: March 26, 1981Date of Patent: August 20, 1985Assignee: Sumitomo Chemical Company, LimitedInventors: Kiyoyasu Hashimoto, Kenji Yoshinaga, Yoshio Mori, Junzaburo Seino, Hirohito Kenmochi, Katsunobu Sato
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Patent number: 4524168Abstract: Compounds of the formula ##STR1## wherein the symbols D is the radical of a carbocyclic or heterocyclic diazo component, X is hydrogen, halogen, methyl or methoxy, each of A.sub.1 and A.sub.2 independently of the other is unsubstituted phenyl or phenyl which is substituted by halogen, C.sub.1 -C.sub.4 alkyl, methoxy, ethoxy, phenyl or phenoxy, are suitable for the mass coloration of organic polymers.Type: GrantFiled: November 8, 1982Date of Patent: June 18, 1985Assignee: Ciba-Geigy CorporationInventor: Arnold Wick