Sulfonyl Bonded Directly To A Bicyclo Ring System Patents (Class 534/883)
  • Publication number: 20120270183
    Abstract: Generally regarded as safe (GRAS) dyes can be used as photosensitizing dyes in oral compositions to provide anti-bacterial and anti-inflammatory efficacy. Embodiments include oral care compositions including photosensitizing dyes, methods of making the compositions, methods of using the compositions, and kits containing the compositions and light emitting devices.
    Type: Application
    Filed: December 20, 2010
    Publication date: October 25, 2012
    Applicant: COLGATE-PALMOLIVE COMPANY
    Inventors: Madhusudan Patel, Rosa Paredes, Mahmoud Hassan, Thomas Boyd
  • Patent number: 8119778
    Abstract: A reversible thermochromic system comprising a) a compound of the formula (I) or a tautomer thereof (I) wherein R1 is C1-C18alkyl, C2-C18alkenyl, C3-C12cycloalkyl, C3-C12cycloalkyl substituted by 1, 2 or 3 C1-C4alkyl; or C7-C12phenylalkyl; R2 and R3 are hydrogen or R2 and R3 together form a group —CH?CH—CH?CH—; and R4 is hydrogen, —NO2, —SO2—R1 or (4-nitrophenyl)azo; and b) a compound containing a group of the formula (II).
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: February 21, 2012
    Assignee: BASF SE
    Inventors: Walter Fischer, Abdel-Ilah Basbas, Martin Brunner, Rolf Benz, Manuele Vitali
  • Patent number: 6902612
    Abstract: Disclosed is a red pigment represented by Formula I: having a unique X-ray diffraction pattern. Also disclosed is a red pigment composition containing the pigment represented by Formula I and a surfactant. Also disclosed is a method of making a red pigment composition. Further disclosures relate to coating compositions, ink compositions, plastic compositions, electrostatic toner compositions, powder coating compositions, paint compositions, and paper compositions containing the red pigment represented by Formula I.
    Type: Grant
    Filed: September 8, 2003
    Date of Patent: June 7, 2005
    Assignee: Engelhard Corporation
    Inventor: Amrit P. Bindra
  • Patent number: 6375733
    Abstract: Disclosed are blue shade red to magenta monoazo pigments which are obtained by diazotization of 5-alkoxy-2-aminobenzenesulfonic acids, coupling of the diazonium compound with a hydoxynaphthalenesulfonic acid and subsequent laking of the coupling product with a divalent metal salt. The pigments are characterized by the formula: wherein R is a lower alkyl, e.g. a methyl or ethyl group, or a hydroxycarbyl group, R1 is hydrogen, chloro, a lower alkyl group such as methyl or ethyl, or a lower alkoxy group such as a methoxy or an ethoxy group, and M is Ca, Sr, Ba, Mn, Mg or Zn. The new pigments have a magenta color, excellent heat stability, bleed fastness and very high color strength. These pigments are suitable for the pigmenting of plastics, inks and coatings, among other materials.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: April 23, 2002
    Assignee: Engelhard Corporation
    Inventor: Amrit P. Bindra
  • Patent number: 6054114
    Abstract: Novel organometallic compounds for binding amyloid are described. Methods using such compounds for determining by imaging the localization or quantification of amyloid fibrils in a mammal, for diagnosing the degree of progression of Alzheimer's disease in a mammal, for monitoring the response to a therapy in a mammal having Alzheimer's disease, for identifying an agent useful for treating Alzheimer's disease, for treating Alzheimer's disease, and for detecting the presence of the infectious form of the prion protein, are also described.
    Type: Grant
    Filed: May 7, 1997
    Date of Patent: April 25, 2000
    Assignee: Massachusetts Institute of Technology
    Inventors: Peter T. Lansbury, Jr., Hogyu Han, Cheon-Gyu Cho, Weiguo Zhen, James D. Harper, Alan Davison
  • Patent number: 5677435
    Abstract: Disclosed are compositions comprising one or more compounds characterized by the formula: ##STR1## wherein R and R.sub.1 are independently hydrogen, chloro, methyl or ethyl groups.A process for preparing azo pigment compositions is also disclosed.Paint, ink and plastic compositions containing the foregoing pigments compositions are disclosed.
    Type: Grant
    Filed: September 24, 1996
    Date of Patent: October 14, 1997
    Assignee: Engelhard Corporation
    Inventor: Amrit Bindra
  • Patent number: 5026830
    Abstract: Process for the preparation of azo dyes of the formula ##STR1## in which K is the radical of a coupling component of the benzene or naphthalene series or of the heterocyclic series in which the hydroxyl group is attached to K in a position adjacent to the azo group, X is hydrogen or nitro and M is an alkali metal ion or ammonium ion, which comprises coupling a diazo component of the formula ##STR2## in the presence of an alkali metal chloride and ammonium chloride with a coupling component of the formula (3) ##STR3## K and X in the formulae (2) and (3) being as defined under formula (1). The present invention allows the preparation of the said azodyes in high yields.
    Type: Grant
    Filed: August 29, 1988
    Date of Patent: June 25, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Horst Langfeld, Claudio Puebla, Gunter Sereinig
  • Patent number: 5003051
    Abstract: A process for the preparation of azo dyes of the formula ##STR1## in which X is --NH.sub.2 or --OH, A is a benzene or naphthalene radical which can be substituted by nitro, halogen, sulfo, C.sub.2 -C.sub.6 alkanoylamino, C.sub.1 -C.sub.6 -alkoxycarbonylamino, sulfonamido and sulfone groups and B is a benzene radical which is monosubstituted or disubstituted by C.sub.1 -C.sub.6 alkyl, or a naphthalene radical which can be substituted by amino, phenylamino, C.sub.1 -C.sub.6 alkylamino and sulfo, or a 1-phenyl-3-methyl-5-pyrazlone radical which can be substituted by halogen, C.sub.1 -C.sub.6 alkyl and C.sub.1 -C.sub.6 alkoy, these radicals being bound to the azo group in the o-position with respect to the hydroxyl or amino groups, comprises diazotizing in aqueous solution an amine of the formula ##STR2## in the presence of at least one ketone of the formula ##STR3## in which R.sub.1 and R.sub.2, independently of one another, are each C.sub.1 -C.sub.
    Type: Grant
    Filed: August 23, 1989
    Date of Patent: March 26, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Ulrich Schlesinger, Peter Loew, Alois Puntener
  • Patent number: 4904767
    Abstract: Asymmetric 1:2-chrome complex dyes of the formula: ##STR1## wherein A is the radical of 1-hydroxynaphthalene or 2-hydroxynaphthalene,R.sub.1 is hydrogen, chlorine or methyl,R.sub.2 is hydrogen, nitro or chlorine, andKa.sup.+ is a cation, and of the substituents X.sub.1, X.sub.2 and X.sub.3 one is an SO.sub.3 group, and the other two are hydrogen, X.sub.3 being hydrogen when R.sub.1 is chlorine and R.sub.2 is hydrogen,give blue shades on leather and other polyamides, which shades are lightfast and fast to wet processing.
    Type: Grant
    Filed: June 29, 1987
    Date of Patent: February 27, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Fabio Beffa, Alois Puntener, Peter Loew
  • Patent number: 4804415
    Abstract: A process for producing an azo pigment, which comprises coupling an aromatic diazonium compound with 3-hydroxy-2-naphthoic acid and at least one binaphthol and optionally, laking the resulting pigment.
    Type: Grant
    Filed: July 31, 1987
    Date of Patent: February 14, 1989
    Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo
    Inventors: Ryuzo Ueno, Shigeru Ito, Shin Fujimoto, Mayumi Iwao
  • Patent number: 4675389
    Abstract: Physiologically acceptable cation salts of (2-alkoxy-4-sulfonyl-5-alkylphenyl)azo-1-hydroxynaphthalene sulfonic acids useful as blue-red colorants for textile fabrics, cellulosic fibers and edible compositions are prepared by diazotizing 2-alkoxy-4-sulfonyl-5-alkylanilines and coupling the resulting diazo compounds to a 1-hydroxynaphthalene mono- or disulfonic acid.
    Type: Grant
    Filed: June 5, 1984
    Date of Patent: June 23, 1987
    Assignee: The Hilton-Davis Chemical Co.
    Inventors: Wayne L. Cook, Robert P. Huth
  • Patent number: 4560746
    Abstract: The disodium salt of 1-[(6-methoxy-4-sulfo-3-methylphenyl)azo]-2-naphthol-6-sulfonic acid (FD and C Red 40), the disodium salt of 1-[(4-sulfophenyl)azo]-2-naphthol-6-sulfonic acid (FD and C Yellow 6), the trisodium salt of 1-[1-(4-sulfonaphthyl)azo]-2-naphthol-3,6-disulfonic acid (FD and C Red 2), the disodium salt of 2-[1-(4-sulfonaphthyl)azo]-1-naphthol-4-sulfonic acid (Carmoisine) and the sodium salt of 2-(2-quinolyl)-1,3-indanedione-sulfonic acid (D and C Yellow 10) are prepared and purified in high yield and in a high state of purity by subjecting their aqueous reaction mixtures to ultrafiltration through a membrane of such structure and under such conditions that the impurities are separated from the reaction mixtures, and the products are concentrated in high purity concentrates from which the products can be isolated directly by evaporation of the solvent.
    Type: Grant
    Filed: November 30, 1984
    Date of Patent: December 24, 1985
    Assignee: The Hilton-Davis Chemical Co.
    Inventors: Robert W. J. Rebhahn, Wayne L. Cook
  • Patent number: 4560744
    Abstract: Compounds which in the form of the free acids correspond to the formula ##STR1## where A is a radical of a diazo component or of an amine,B is a radical of a coupling component or of an aldehyde,R.sup.1 is chlorine or bromine,R.sup.2 is methoxy or ethoxy,X is .dbd.N-- or .dbd.CH--,Y is --O-- or --COO-- andZ is --O-- or --NH--,are dyes which are very suitable for dyeing nylons and natural polyamides.
    Type: Grant
    Filed: March 6, 1981
    Date of Patent: December 24, 1985
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans Baumann, Klaus Grychtol