Mixed Carboxylate Esters Patents (Class 536/64)
-
Patent number: 12157808Abstract: This cellulose acetate has a total degree of acetyl substitution of 1.75 or more and 2.55 or less, and a degree of acetyl substitution at 2-position or a degree of acetyl substitution at 3-position is 0.7 or less. This cellulose acetate composition includes the cellulose acetate and an additive. The additive is one or more selected from the group consisting of (a) substances of which a pH of a 1 wt. % aqueous solution at 20° C. is 8 or more, (b) substances that dissolve in water at 20° C. in an amount of 2 wt. % or more, and (c) substances that exhibit biodegradability in seawater.Type: GrantFiled: December 22, 2022Date of Patent: December 3, 2024Assignee: DAICEL CORPORATIONInventors: Hiroyuki Matsumura, Hiroki Taniguchi, Akihiro Higuchi, Tomohiro Hashizume, Masaaki Kusumoto
-
Patent number: 12012513Abstract: A polyester composition comprising at least one polyester selected from the group consisting of poly(trimethylene terephthalate), polyethylene terephthalate, polybutylene terephthalate, and copolymers thereof; and at least one poly alpha-1,3-glucan ester having a degree of substitution of from about 0.3 to 3 moles of at least one acyl group per repeat unit of poly alpha-1,3-glucan. Articles prepared from these polyester compositions exhibit at least one improved physical property such as heat deflection temperature, tensile strength, Young's modulus, or impact strength. Such polyester compositions may also be prepared from renewable resources.Type: GrantFiled: February 7, 2019Date of Patent: June 18, 2024Assignee: NUTRITION & BIOSCIENCES USA 4, INC.Inventors: Ross S. Johnson, Vindhya Mishra
-
Patent number: 11956986Abstract: A flexible display screen includes: a flexible substrate (1); an OLED device layer (2) formed on the flexible substrate (1); an encapsulation layer(3), disposed on the OLED device layer(2) and encapsulating the OLED device layer (2); and an encapsulation protection layer (4) formed on the encapsulation layer (3). The embodiments of the present disclosure also provide a flexible display device and a manufacturing method of the flexible display screen.Type: GrantFiled: January 6, 2021Date of Patent: April 9, 2024Assignees: Chengdu BOE Optoelectronics Technology Co., Ltd., BOE Technology Group Co., Ltd.Inventors: Yaming Wang, Liqiang Chen, Yanxin Wang, Chuntong Jiang, Jiali Wang, Xu Li, Rui Hou, Le Chang
-
Patent number: 11253861Abstract: This invention discloses methods for producing modified cellulose, modified nanocellulose, modified nanocellulose functionalized with other functional species, and derivatives thereof. The present invention also provides cellulose, nanocellulose, and their derivatives that are safe to use inside an animal or human body and are biocompatible without costly purification. These cellulose or nanocellulose materials can be used in many different applications, including carrier for pharmaceutical active agents and other medical devices.Type: GrantFiled: September 11, 2020Date of Patent: February 22, 2022Assignee: Innotech Materials, LLCInventor: Wiechang Jin
-
Patent number: 10869883Abstract: A nutrient composition contains a cellulose acetate having a total degree of acetyl substitution of 0.4 to 1.1. The cellulose acetate may have a compositional distribution index (CDI) of 2.0 or less, where the CDI is specified by the formula: CDI=(Measured value of half height width of chemical composition)/(Theoretical value of half height width of chemical composition) where the measured value of half height width of chemical composition represents the half height width of chemical composition determined by HPLC analysis of a cellulose acetate propionate prepared by propionylating all residual hydroxy groups of the cellulose acetate (sample); and [Math. 1] the theoretical value of half height width of chemical composition =2.Type: GrantFiled: January 25, 2019Date of Patent: December 22, 2020Assignee: DAICEL CORPORATIONInventors: Shu Shimamoto, Toshikazu Nakamura, Shizuka Ukita, Tsuyoshi Nakamura, Ryoko Yamauchi, Hiroshi Kobayashi
-
Patent number: 10759872Abstract: Regioselectively substituted cellulose esters having a plurality of pivaloyl substituents and a plurality of aryl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in films, such as +A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.Type: GrantFiled: April 10, 2017Date of Patent: September 1, 2020Assignee: Eastman Chemical CompanyInventors: Matthew Allen Boone, Christopher Harlan Burk, Peter Borden Mackenzie, Jennifer A. Fish, Eduardo Gallas Cervo, Elaine Beatrice Mackenzie, Robert Joseph Maleski, Wesley McConnell, David William Norman, Tabatha Stearns, Bin Wang
-
Patent number: 10738134Abstract: Methods for the cross-metathesis of polysaccharides with one or more olefin-terminated side chains and cross-metathesized products are described. In an exemplary embodiment, a method for the synthesis of cellulose ?-carboxyesters via olefin cross-metathesis is described. Conditions of the reactions were relatively mild and the olefin-substituted polysaccharides and the appropriate monomeric olefin partners appear to follow Grubbs rules as summarized herein. The compounds and methods may be useful for structure-property studies, particularly those aimed at developing polymers for drug delivery, such as for controlled-release drug delivery systems, controlled-release coatings, increasing bioavailability of drugs, and maintaining drug supersaturation in the GI tract.Type: GrantFiled: September 26, 2014Date of Patent: August 11, 2020Assignee: Virginia Tech Intellectual Properties, Inc.Inventors: Kevin J. Edgar, Xiangtao Meng, John Matson
-
Patent number: 9458248Abstract: The present invention relates to cellulose mixed esters, processes for preparing these and uses of the cellulose mixed esters, for example in coating compositions. The cellulose mixed esters have glass transition temperatures that fall within an appropriate range to allow for film formation to occur at ambient temperatures and have a total degree of substitution per anhydroglucose unit of about 2.5 to about 3.5; a residual hydroxyl functionality per anhydroglucose unit of 0 to about 0.5; a degree of substitution per anhydroglucose unit by C2-C6 ester groups of about 0.5 to about 2.8; and a degree of substitution per anhydroglucose unit by Ievulinyl ester groups of about 0.2 to about 2.6.Type: GrantFiled: December 5, 2012Date of Patent: October 4, 2016Assignee: Resene Paints LimitedInventors: Mark Glenny, Colin Gooch, Simon Hinkley, Jennifer Mason, Cameron Tristram, Dennis Williams
-
Patent number: 9309385Abstract: The present invention relates to cellulose fibers wherein a part of the hydroxyl groups of the cellulose have been substituted with at least one of a carboxy group and formyl group of 0.1 mmol/g or larger based on the weight of the cellulose fibers, and have been further substituted with a chemical modification group other than the carboxy and formyl groups.Type: GrantFiled: August 21, 2013Date of Patent: April 12, 2016Assignee: Oji Holdings CorporationInventors: Tomokazu Umemoto, Naohide Ogita, Takanori Shimizu, Yasutomo Noishiki, Hiroyuki Nagatani, Go Banzashi
-
Patent number: 9040685Abstract: This invention provides cellulose ester interpolymers, and methods of oxidizing cellulose interpolymers and cellulose ester interpolymers. The invention also provides routes to access carboxylated cellulose ester derivatives with high acid numbers wherein the carboxyl group is attached directly to the cellulose backbone by a carbon-carbon bond. Through functionalization of an intermediate aldehyde, the corresponding cationic or zwitterionic cellulose ester derivatives can also be accessed. The interpolymers of the present invention have a number of end-use applications, for example, as binder resins in various types of coating compositions and as drug delivery agents.Type: GrantFiled: December 27, 2012Date of Patent: May 26, 2015Assignee: EASTMAN CHEMICAL COMPANYInventors: Charles Michael Buchanan, Norma Lindsey Buchanan, Susan Northrop Carty, Chung-Ming Kuo, Juanelle Little Lambert, Michael Orlando Malcolm, Jessica Dee Posey-Dowty, Thelma Lee Watterson, Matthew Davie Wood, Margaretha Soderqvist Lindblad
-
Patent number: 9040683Abstract: This invention provides cellulose ester interpolymers, and methods of oxidizing cellulose interpolymers and cellulose ester interpolymers. The invention also provides routes to access carboxylated cellulose ester derivatives with high acid numbers wherein the carboxyl group is attached directly to the cellulose backbone by a carbon-carbon bond. Through functionalization of an intermediate aldehyde, the corresponding cationic or zwitterionic cellulose ester derivatives can also be accessed. The interpolymers of the present invention have a number of end-use applications, for example, as binder resins in various types of coating compositions and as drug delivery agents.Type: GrantFiled: December 27, 2012Date of Patent: May 26, 2015Assignee: EASTMAN CHEMICAL COMPANYInventors: Charles Michael Buchanan, Norma Lindsey Buchanan, Susan Northrop Carty, Chung-Ming Kuo, Juanelle Little Lambert, Michael Orlando Malcolm, Jessica Dee Posey-Dowty, Thelma Lee Watterson, Matthew Davie Wood, Margaretha Soderqvist Lindblad
-
Patent number: 9040684Abstract: This invention provides cellulose ester interpolymers, and methods of oxidizing cellulose interpolymers and cellulose ester interpolymers. The invention also provides routes to access carboxylated cellulose ester derivatives with high acid numbers wherein the carboxyl group is attached directly to the cellulose backbone by a carbon-carbon bond. Through functionalization of an intermediate aldehyde, the corresponding cationic or zwitterionic cellulose ester derivatives can also be accessed. The interpolymers of the present invention have a number of end-use applications, for example, as binder resins in various types of coating compositions and as drug delivery agents.Type: GrantFiled: December 27, 2012Date of Patent: May 26, 2015Assignee: EASTMAN CHEMICAL COMPANYInventors: Charles Michael Buchanan, Norma Lindsey Buchanan, Susan Northrop Carty, Chung-Ming Kuo, Juanelle Little Lambert, Michael Orlando Malcolm, Jessica Dee Posey-Dowty, Thelma Lee Watterson, Matthew Davie Wood, Margaretha Soderqvist Lindblad
-
Publication number: 20150135990Abstract: Provided is a cellulose resin composition wherein roll contamination during processing and reduction in the productivity caused by roll contamination are inhibited. The cellulose resin composition is obtained by adding a polyester-based plasticizer to a cellulose resin, the cellulose resin composition being characterized in that the polyester-based plasticizer is produced from a polybasic acid, a polyhydric acid and, as required, a stopper, in which polyester-based plasticizer, components having a molecular weight of 430 or less are removed to an amount of 5 wt % or less.Type: ApplicationFiled: May 7, 2013Publication date: May 21, 2015Applicant: ADEKA CORPORATIONInventors: Masashi Harada, Yuji Yamazaki, Satoshi Kamimura, Yuki Tanaka
-
Patent number: 8940800Abstract: Disclosed are polymers of hydroxypropyl methyl cellulose acetate succinate (HPMCAS) and hydroxypropyl methyl cellulose acetate (HPMCA) with unique degrees of substitution of hydroxypropoxy, methoxy, acetyl, and succinoyl groups. When used in making compositions comprising a low-solubility drug and such polymers, the polymers provide enhanced aqueous concentrations and/or improved physical stability.Type: GrantFiled: June 26, 2012Date of Patent: January 27, 2015Assignee: Bend Research, Inc.Inventors: Walter C. Babcock, Dwayne T. Friesen, David Keith Lyon, Warren Kenyon Miller, Daniel Tod Smithey
-
Publication number: 20140331895Abstract: The present invention relates to cellulose mixed esters, processes for preparing these and uses of the cellulose mixed esters, for example in coating compositions. The cellulose mixed esters have glass transition temperatures that fall within an appropriate range to allow for film formation to occur at ambient temperatures and have a total degree of substitution per anhydroglucose unit of about 2.5 to about 3.5; a residual hydroxyl functionality per anhydroglucose unit of 0 to about 0.5; a degree of substitution per anhydroglucose unit by C2-C6 ester groups of about 0.5 to about 2.8; and a degree of substitution per anhydroglucose unit by Ievulinyl ester groups of about 0.2 to about 2.6.Type: ApplicationFiled: December 5, 2012Publication date: November 13, 2014Inventors: Mark Glenny, Colin Gooch, Simon Hinkley, Jennifer Mason, Cameron Tristram, Dennis Williams
-
Patent number: 8865923Abstract: A method for separating neutral and polar lipids from an oil of biological material, wherein the oil is fractionated using a mixture of a polar solvent comprising at least one carbon atom, water and an additional substance selected from the group consisting of: mono-, di- and oligosaccharides comprising from 3 to 10 monosaccharide units, said additional substance is present in an amount of at least 0.1 wt % calculated on the total weight of solvent, water and additional substance, to form at least two liquid fractions having different densities, wherein one fraction is rich in polar lipids and another fraction is rich in neutral lipids. An oil rich in polar lipids obtained from the method is disclosed, said oil I contains at least 40, preferably at least 50 lipid % polar lipids as calculated on the total amount of lipids in said oil and that the total amount of polar solvent and water in said oil is between 20 and 30 wt %. An oat oil containing high amounts of estolides of DGDG can further be obtained.Type: GrantFiled: March 10, 2010Date of Patent: October 21, 2014Assignee: Swedish Oat Fiber ABInventor: Magnus Härröd
-
Patent number: 8729253Abstract: Regioselectively substituted cellulose esters having a plurality of aryl-acyl substituents and a plurality of alkyl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in optical films, such as optical films having certain Nz values, ?A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.Type: GrantFiled: March 1, 2012Date of Patent: May 20, 2014Assignee: Eastman Chemical CompanyInventors: Charles Michael Buchanan, Michael Eugene Donelson, Elizabeth Guzman-Morales, Peter Borden Mackenzie, Bin Wang
-
Publication number: 20130116426Abstract: This invention provides cellulose ester interpolymers, and methods of oxidizing cellulose interpolymers and cellulose ester interpolymers. The invention also provides routes to access carboxylated cellulose ester derivatives with high acid numbers wherein the carboxyl group is attached directly to the cellulose backbone by a carbon-carbon bond. Through functionalization of an intermediate aldehyde, the corresponding cationic or zwitterionic cellulose ester derivatives can also be accessed. The interpolymers of the present invention have a number of end-use applications, for example, as binder resins in various types of coating compositions and as drug delivery agents.Type: ApplicationFiled: December 27, 2012Publication date: May 9, 2013Applicant: Eastman Chemical CompanyInventor: Eastman Chemical Company
-
Publication number: 20130116425Abstract: This invention provides cellulose ester interpolymers, and methods of oxidizing cellulose interpolymers and cellulose ester interpolymers. The invention also provides routes to access carboxylated cellulose ester derivatives with high acid numbers wherein the carboxyl group is attached directly to the cellulose backbone by a carbon-carbon bond. Through functionalization of an intermediate aldehyde, the corresponding cationic or zwitterionic cellulose ester derivatives can also be accessed. The interpolymers of the present invention have a number of end-use applications, for example, as binder resins in various types of coating compositions and as drug delivery agents.Type: ApplicationFiled: December 27, 2012Publication date: May 9, 2013Applicant: Eastman Chemical CompanyInventor: Eastman Chemical Company
-
Publication number: 20130116427Abstract: This invention provides cellulose ester interpolymers, and methods of oxidizing cellulose interpolymers and cellulose ester interpolymers. The invention also provides routes to access carboxylated cellulose ester derivatives with high acid numbers wherein the carboxyl group is attached directly to the cellulose backbone by a carbon-carbon bond. Through functionalization of an intermediate aldehyde, the corresponding cationic or zwitterionic cellulose ester derivatives can also be accessed. The interpolymers of the present invention have a number of end-use applications, for example, as binder resins in various types of coating compositions and as drug delivery agents.Type: ApplicationFiled: December 27, 2012Publication date: May 9, 2013Applicant: Eastman Chemical CompanyInventor: Eastman Chemical Company
-
Patent number: 8354525Abstract: This invention relates to novel compositions comprising regioselectively substituted cellulose esters. One aspect of the invention relates to processes for preparing regioselectively substituted cellulose esters from cellulose dissolved in ionic liquids. Another aspect of the invention relates to the utility of regioselectively substituted cellulose esters in applications such as protective and compensation films for liquid crystalline displays.Type: GrantFiled: August 12, 2009Date of Patent: January 15, 2013Assignee: Eastman Chemical CompanyInventors: Charles Michael Buchanan, Norma Lindsey Buchanan, Michael Eugene Donelson, Maryna Grigorievna Gorbunova, Thauming Kuo, Bin Wang
-
Patent number: 8344134Abstract: The present invention relates to cellulose esters having low hydroxyl content for use in optical applications, such as liquid crystal display (LCD) films. Films made with low hydroxyl levels and a given ratio of non-acetyl ester to hydroxyl level have been found to have low intrinsic birefringence. Therefore, these films can be cast, molded, or otherwise oriented without an appreciable birefringence or optical distortion (i.e. retardation). Such features make these films useful in polarizer, protective, and compensator films as well as molded optical parts, such as lenses. Furthermore, it has also been found that resins of the present invention can also be made to have “+C plate” behavior either by melt or solvent based processing, a characteristic which is not typical of cellulose esters. Such +C behavior allows films to be produced having unique compensatory behavior. Other embodiments of the invention relate to methods melt casting films while minimizing birefringence formation.Type: GrantFiled: August 22, 2008Date of Patent: January 1, 2013Assignee: Eastman Chemical CompanyInventors: Marcus David Shelby, Michael Eugene Donelson, Bradley Howard Dayvolt, Alan Kent Wilson, Bryan Kirkman
-
Publication number: 20120330002Abstract: This invention concerns the first environmentally benign heterogeneous modification of polysaccharide-based material in native solid state by thiol-ene “click chemistry”. The direct reaction of a thiol with an un-activated double or triple bond by thiol-ene and thiol-enyne click modification is thermally or photochemically catalyzed and is completely metal-free and allows for a highly modular approach to modifications of fibers and fiber-based materials.Type: ApplicationFiled: January 19, 2011Publication date: December 27, 2012Applicant: ORGANOCLICK ABInventors: Armando Cordova, Jonas Hafren
-
Patent number: 8329893Abstract: The present invention relates to cellulose esters having low hydroxyl content for use in optical applications, such as liquid crystal display (LCD) films. Films made with low hydroxyl levels and a given ratio of non-acetyl ester to hydroxyl level have been found to have low intrinsic birefringence. Therefore, these films can be cast, molded, or otherwise oriented without an appreciable birefringence or optical distortion (i.e. retardation). Such features make these films useful in polarizer, protective, and compensator films as well as molded optical parts, such as lenses. Furthermore, it has also been found that resins of the present invention can also be made to have “+C plate” behavior either by melt or solvent based processing, a characteristic which is not typical of cellulose esters. Such +C behavior allows films to be produced having unique compensatory behavior. Other embodiments of the invention relate to methods melt casting films while minimizing birefringence formation.Type: GrantFiled: August 22, 2008Date of Patent: December 11, 2012Assignee: Eastman Chemical CompanyInventors: Marcus David Shelby, Michael Eugene Donelson, Bradley Howard Dayvolt, Alan Kent Wilson, Bryan Kirkman
-
Publication number: 20120263890Abstract: Regioselectively substituted cellulose esters having a plurality of aryl-acyl substituents and a plurality of alkyl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in optical films, such as optical films having certain Nz values, ?A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.Type: ApplicationFiled: March 1, 2012Publication date: October 18, 2012Applicant: EASTMAN CHEMICAL COMPANYInventors: Charles Michael Buchanan, Michael Eugene Donelson, Elizabeth Guzman-Morales, Peter Borden Mackenzie, Bin Wang
-
Publication number: 20120263889Abstract: Regioselectively substituted cellulose esters having a plurality of aryl-acyl substituents and a plurality of alkyl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in optical films, such as optical films having certain Nz values, ?A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.Type: ApplicationFiled: March 1, 2012Publication date: October 18, 2012Applicant: EASTMAN CHEMICAL COMPANYInventors: Charles Michael Buchanan, Michael Eugene Donelson, Elizabeth Guzman-Morales, Peter Borden Mackenzie, Bin Wang
-
Publication number: 20120264833Abstract: Disclosed are polymers of hydroxypropyl methyl cellulose acetate succinate (HPMCAS) and hydroxypropyl methyl cellulose acetate (HPMCA) with unique degrees of substitution of hydroxypropoxy, methoxy, acetyl, and succinoyl groups. When used in making compositions comprising a low-solubility drug and such polymers, the polymers provide enhanced aqueous concentrations and/or improved physical stability.Type: ApplicationFiled: June 26, 2012Publication date: October 18, 2012Inventors: Walter C. Babcock, Dwayne T. Friesen, David Keith Lyon, Warren Kenyon Miller, Daniel Tod Smithey
-
Publication number: 20120262650Abstract: Regioselectively substituted cellulose esters having a plurality of aryl-acyl substituents and a plurality of alkyl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in optical films, such as optical films having certain Nz values, ?A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.Type: ApplicationFiled: March 1, 2012Publication date: October 18, 2012Applicant: EASTMAN CHEMICAL COMPANYInventors: Charles Michael Buchanan, Michael Eugene Donelson, Elizabeth Guzman-Morales, Peter Borden Mackenzie, Bin Wang
-
Publication number: 20120264930Abstract: Regioselectively substituted cellulose esters having a plurality of aryl-acyl substituents and a plurality of alkyl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in optical films, such as optical films having certain Nz values, ?A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.Type: ApplicationFiled: March 1, 2012Publication date: October 18, 2012Applicant: EASTMAN CHEMICAL COMPANYInventors: Charles Michael Buchanan, Michael Eugene Donelson, Elizabeth Guzman-Morales, Peter Borden Mackenzie, Bin Wang
-
Patent number: 8273872Abstract: Ionic liquids and cellulose ester compositions and processes for producing ionic liquids and cellulose esters. Cellulose esters can be produced by esterifying cellulose in a reaction medium comprising one or more halide ionic liquids and at least one binary component. Cellulose esters prepared via the methods of the present invention can have a degree of substitution (“DS”) of at least 1.5 and can comprise a plurality of ester substituents, where at least 50 percent of the ester substituents comprise alkyl esters having a carbon chain length of at least 6 carbons.Type: GrantFiled: August 25, 2011Date of Patent: September 25, 2012Assignee: Eastman Chemical CompanyInventors: Charles Michael Buchanan, Norma Lindsey Buchanan
-
Publication number: 20120238741Abstract: Ionic liquids and cellulose ester compositions and processes for producing ionic liquids and cellulose esters. Cellulose esters can be produced by subjecting a cellulose-ionic liquid solution comprising cellulose, one or more ionic liquids, and one or more co-solvents to esterification to thereby produce an esterified medium comprising a cellulose ester. The co-solvents employed in the present invention can be either miscible or immiscible with the cellulose-ionic liquid solution but can be readily dispersed or soluble in the esterified medium.Type: ApplicationFiled: June 1, 2012Publication date: September 20, 2012Applicant: EASTMAN CHEMICAL COMPANYInventors: Charles Michael Buchanan, Norma Lindsey Buchanan
-
Publication number: 20120238742Abstract: Ionic liquids and cellulose ester compositions and processes for producing ionic liquids and cellulose esters. Cellulose esters can be produced by subjecting a cellulose-ionic liquid solution comprising cellulose, one or more ionic liquids, and one or more co-solvents to esterification to thereby produce an esterified medium comprising a cellulose ester. The co-solvents employed in the present invention can be either miscible or immiscible with the cellulose-ionic liquid solution but can be readily dispersed or soluble in the esterified medium.Type: ApplicationFiled: June 1, 2012Publication date: September 20, 2012Applicant: EASTMAN CHEMICAL COMPANYInventors: Charles Michael Buchanan, Norma Lindsey Buchanan
-
Patent number: 8263195Abstract: A cellulose ester film is provided and includes a polycondensate obtained from a diol and a dicarboxylic acid, and the polycondensate contains the following (1) and (2). (1) A dicarboxylic acid residue containing an aromatic dicarboxylic acid residue and an aliphatic dicarboxylic acid residue having an average carbon number of 4.0 to 5.0, in which a ratio of the aromatic dicarboxylic acid residue represented by the following equation is from 40% by mole to 95% by mole: The ratio of the aromatic dicarboxylic acid residue=[(the number of moles of the aromatic dicarboxylic acid residue)/((the number of moles of the aromatic dicarboxylic acid residue)+(the number of moles of the aliphatic dicarboxylic acid residues))]×100. (2) An aliphatic diol residue having an average carbon number of 2.0 to 3.0.Type: GrantFiled: June 4, 2010Date of Patent: September 11, 2012Assignee: FUJIFILM CorporationInventors: Hiromichi Furukawa, Mamoru Sakurazawa
-
Publication number: 20120197011Abstract: The present invention relates to esters of diacids and cellulosic materials and methods for making thereof. The ester has the chemical composition of Formula (I) Formula I where R1, R2, and R3 can be the same or different, and each of which is selected from —H, —COR?, —R??, or —COR? COOH, with the proviso that at least one of the R1, R2, or R3 is —COR? COOH; R? is an alkyl, alkenyl, alkynyl, or aromatic group; R? is an alkyl, alkenyl, or alkynyl group having 4 or more carbon atoms (?C4); and R?? is an alkyl, alkenyl, alkynyl, polyol, or aromatic group.Type: ApplicationFiled: September 21, 2010Publication date: August 2, 2012Applicant: Virginia Tech Intellectual Properties, Inc.Inventors: Kevin J. Edgar, Nilanjana Kar
-
Publication number: 20120146468Abstract: A cellulose derivative, contains A) a hydrocarbon group; B) a group containing an acyl group: —CO—RB and an ethyleneoxy group: —C2H4—O— (RB represents a hydrocarbon group); and C) an acyl group: —CO—RC (RC represents a hydrocarbon group). A method for preparing the cellulose derivative, a resin composition containing the cellulose derivative, a case for an electric and electronic device and a method for preparing a molded body are also provided.Type: ApplicationFiled: August 11, 2010Publication date: June 14, 2012Applicant: FUJIFILM CORPORATIONInventors: Shigeki Uehira, Youichirou Takeshima
-
Publication number: 20120095207Abstract: Ionic liquids and cellulose ester compositions and processes and apparatus for producing ionic liquids and cellulose esters. Cellulose esters can be produced by dissolving cellulose in carboxylated ionic liquids and thereafter contacting the cellulose solution with at least one acylating reagent. Cellulose esters produced via the present invention can comprise ester groups that originate from the carboxylated ionic liquid and/or the acylating reagent.Type: ApplicationFiled: December 20, 2011Publication date: April 19, 2012Applicant: EASTMAN CHEMICAL COMPANYInventors: Charles Michael Buchanan, Norma Lindsey Buchanan, Robert Thomas Hembre, Juanelle Little Lambert
-
Patent number: 8158777Abstract: Ionic liquids and cellulose ester compositions and processes for producing ionic liquids and cellulose esters. Cellulose esters can be produced by esterifying cellulose in a reaction medium comprising one or more halide ionic liquids and at least one binary component. Cellulose esters prepared via the methods of the present invention can have a degree of substitution (“DS”) of at least 1.5 and can comprise a plurality of ester substituents, where at least 50 percent of the ester substituents comprise alkyl esters having a carbon chain length of at least 6 carbons.Type: GrantFiled: August 11, 2008Date of Patent: April 17, 2012Assignee: Eastman Chemical CompanyInventors: Charles Michael Buchanan, Norma Lindsey Buchanan
-
Patent number: 8153782Abstract: Processes for recycling an ionic liquid comprising employing an initial ionic liquid as a solvent and/or reagent resulting in a modified ionic liquid and thereafter subjecting at least a portion of the modified ionic liquid to at least one anion exchange process to produce a reformed ionic liquid. The initial ionic liquid can be employed in a cellulose esterification process, thereby producing the modified ionic liquid. At least a portion of the reformed ionic liquid can be recycled to a point upstream in the cellulose esterification process.Type: GrantFiled: February 13, 2008Date of Patent: April 10, 2012Assignee: Eastman Chemical CompanyInventors: Charles Michael Buchanan, Norma Lindsey Buchanan
-
Patent number: 8148518Abstract: Ionic liquids and cellulose ester compositions and processes and apparatus for producing ionic liquids and cellulose esters. Cellulose esters can be produced by dissolving cellulose in carboxylated ionic liquids and thereafter contacting the cellulose solution with at least one acylating reagent. Cellulose esters produced via the present invention can comprise ester groups that originate from the carboxylated ionic liquid and/or the acylating reagent.Type: GrantFiled: February 13, 2008Date of Patent: April 3, 2012Assignee: Eastman Chemical CompanyInventors: Charles Michael Buchanan, Norma Lindsey Buchanan, Robert Thomas Hembre, Juanelle Little Lambert
-
Publication number: 20110301525Abstract: This invention relates to biomaterial compositions, methods and kits for producing hydrogels with tunable physico-chemical properties. Specifically, the invention relates to producing cellulosic hydrogels having optimized physico-chemical properties enabling support of cell growth or as replacement or filler for tissue repair, reconstruction or augmentation.Type: ApplicationFiled: November 12, 2009Publication date: December 8, 2011Inventors: Steven B. Nicoll, Simone S. Stalling, Anna T. Reza
-
Patent number: 8026357Abstract: A cellulose acylate film, comprising a cellulose acylate having at least one substituent (Substituent A) comprising an aromatic group having at least one C4 or longer aliphatic group, is disclosed.Type: GrantFiled: October 29, 2008Date of Patent: September 27, 2011Assignee: FUJIFILM CorporationInventors: Tomoko Kuwabara, Kunihiro Atsumi
-
Patent number: 7879994Abstract: This invention provides cellulose ester interpolymers, and methods of oxidizing cellulose interpolymers and cellulose ester interpolymers. The invention also provides routes to access carboxylated cellulose ester derivatives with high acid numbers wherein the carboxyl group is attached directly to the cellulose backbone by a carbon-carbon bond. Through functionalization of an intermediate aldehyde, the corresponding cationic or zwitterionic cellulose ester derivatives can also be accessed. The interpolymers of the present invention have a number of end-use applications, for example, as binder resins in various types of coating compositions and as drug delivery agents.Type: GrantFiled: November 23, 2004Date of Patent: February 1, 2011Assignee: Eastman Chemical CompanyInventors: Charles Michael Buchanan, Norma Lindsey Buchanan, Susan Northrop Carty, Chung-Ming Kuo, Juanelle Little Lambert, Jessica Dee Posey-Dowty, Thelma Lee Watterson, Matthew Davie Wood, Michael Orlando Malcolm, Margaretha Soderqvist Lindblad
-
Publication number: 20110001907Abstract: Thanks to a cellulose ester film comprising at least one kind of a polycondensed ester obtained from at least one kind of an aliphatic diol having an average carbon number of 2.0 to 2.5 and a dicarboxylic acid mixture containing at least one kind of an aromatic ring-containing dicarboxylic acid and at least one kind of an aliphatic dicarboxylic acid and having an average carbon number of 6.0 to 10.0, an excellent cellulose ester film yielding little process contamination at the production and ensuring high production efficiency, a retardation film with excellent characteristics, and a polarizing plate and a liquid crystal display device each using the film, are provided.Type: ApplicationFiled: December 22, 2008Publication date: January 6, 2011Applicant: FUJIFILM CorporationInventors: Mamoru Sakurazawa, Yasuo Mukunoki, Hiroaki Sata
-
Publication number: 20110001904Abstract: A cellulose ester film comprising at least one polycondensate ester that comprises a dicarboxylic acid residue mixture having an average carbon number of from 5.5 to 10.0 and comprising an aromatic dicarboxylic acid residue and an aliphatic dicarboxylic acid residue, and an aliphatic diol residue having an average carbon number of from 2.5 to 7.0.Type: ApplicationFiled: July 1, 2010Publication date: January 6, 2011Applicant: FUJIFILM CorporationInventors: Hiromichi Tachikawa, Jun Takeda, Yoshiaki Hisakado, Ryousuke Takada, Akira Ikeda, Mamoru Sakurazawa
-
Patent number: 7709034Abstract: A process for extracting the water soluble fiber from corn fiber hulls is provided comprising the steps of subjecting the corn fiber hulls to a destarching process, a dewatering process, and exposing the destarched and dewatered corn fiber hulls to a thermochemical treatment to obtain a water-soluble non-caloric corn fiber. A water-soluble non-caloric corn fiber composition is disclosed comprising a destarched corn fiber hull produced by subjecting corn fiber hulls to a non-alkaline destarching process to obtain a destarched corn fiber, dewatering said destarched corn fiber hull, and exposing said destarched and dewatered corn fiber hull to one or more thermochemical treatments to obtain a water-soluble non-caloric corn fiber. Foods and a pharmaceutical comprising the water-soluble non-caloric corn fiber composition are disclosed.Type: GrantFiled: April 19, 2006Date of Patent: May 4, 2010Assignee: Archer-Daniels-Midland CompanyInventors: Charles Abbas, Kyle E. Beery, Thomas P. Binder
-
Publication number: 20100093996Abstract: The present invention relates to cellulose esters having low hydroxyl content for use in optical applications, such as liquid crystal display (LCD) films. Films made with low hydroxyl levels and a given ratio of non-acetyl ester to hydroxyl level have been found to have low intrinsic birefringence. These films can be cast, molded, or otherwise oriented without an appreciable birefringence or optical distortion (i.e. retardation). Such features make these films useful in polarizer, protective, and compensator films as well as molded optical parts, such as lenses. Furthermore, it has also been found that resins of the present invention can also be made to have “+C plate” behavior either by melt or solvent based processing, a characteristic which is not typical of cellulose esters. Such +C behavior allows films to be produced having unique compensatory behavior. Other embodiments of the invention relate to methods melt casting films while minimizing birefringence formation.Type: ApplicationFiled: December 10, 2009Publication date: April 15, 2010Applicant: Eastman Chemical CompanyInventors: Marcus David Shelby, Michael Eugene Donelson, Bradley Howard Dayvolt, Alan Kent Wilson, Bryan Kirkman
-
Patent number: 7662801Abstract: The present invention relates to the preparation of a series of oxidized cellulose esters suitable for use as a drug carrier in the development of biodegradable controlled and/or sustained release pharmaceutical, agricultural, and veterinary compositions, such as films, compacts, microspheres, and pellets. The esters are prepared by acylation of oxidized cellulose having at least 3% carboxyl groups. The resulting oxidized cellulose esters are soluble in aqueous alkaline solutions, water, and a variety of organic solvents.Type: GrantFiled: December 13, 2005Date of Patent: February 16, 2010Assignee: University of Iowa Research FoundationInventors: Vijay Kumar, Yang Dang
-
Patent number: 7649089Abstract: A new cellulose excipient, OCCAE, suitable for use as a binder, filler, and/or disintegrant in the development of solid dosage forms and as a bodying agent or a drug carrier in the preparation of topical formulations is described. The cellulose excipient is formed by reacting an oxidized cellulose ester with an alcohol in the presence of a catalyst. The invention also describes the formation of controlled release microspheres using OCCAE and/or oxidized cellulose esters that may be used to control the release of drug in a patient over a time period of several hours to several days.Type: GrantFiled: October 28, 2004Date of Patent: January 19, 2010Assignee: University of Iowa Research FoundationInventors: Vijay Kumar, Yang Dong
-
Patent number: 7604852Abstract: A process for producing a cellulose acylate film, the process comprising melt-cast filming a composition comprising a cellulose acylate that has a specific acyl substitution degree, and that has a residual sulfate in an amount equal to or less than a definite amount (in terms of an amount of a sulfur atom), and a a cellulose acylate film produced by the process, a high-quality retardation film, a polarizing plate, an optical compensatory film, an anti-reflective film and an image display device using same.Type: GrantFiled: September 15, 2005Date of Patent: October 20, 2009Assignee: Fujifilm CorporationInventor: Toyohisa Oya
-
Patent number: 7595392Abstract: The present invention relates to the preparation of a series of oxidized cellulose esters suitable for use as a drug carrier in the development of biodegradable controlled and/or sustained release pharmaceutical, agricultural, and veterinary compositions, such as films, compacts, microspheres, and pellets. The esters are prepared by acylation of oxidized cellulose having at least 3% carboxyl groups. The resulting oxidized cellulose esters are soluble in aqueous alkaline solutions, water, and a variety of organic solvents.Type: GrantFiled: December 6, 2001Date of Patent: September 29, 2009Assignee: University of Iowa Research FoundationInventors: Vijay Kumar, Yang Dong