Hydroxyalkyl Containing Patents (Class 536/91)
  • Patent number: 10370459
    Abstract: Disclosed are methods for the preparation of alkyl hydroxyalkyl cellulose ethers, and the use of such alkyl hydroxyalkyl cellulose ethers in the preparation and use of mortars and other cement-based systems; also disclosed is a hydraulic composition containing at least one retarder, at least one accelerator and a cellulose ether having a prolonged open time without deterioration of the other cement tile adhesive properties such as workability, setting time, strength development and sag resistance; and further disclosed are dry mortars containing encapsulated calcium chloride used in preparing mortar materials for use in construction, and the preparation and use of such mortars in cold weather environments is also disclosed.
    Type: Grant
    Filed: July 23, 2014
    Date of Patent: August 6, 2019
    Assignee: HERCULES LLC
    Inventors: Kelly A. Brush, Patrick J. Cowan, Wilfried Adolphe Hohn, Alexander Adolphe Kindler, Vera Louise Nilles
  • Patent number: 9266970
    Abstract: Provided is hydroxypropylmethylcellulose having a high thermal gelation temperature and a high thermal gel strength and a method for producing the same and a food comprising the hydroxypropylmethylcellulose. More specifically, provided is hydroxypropylmethylcellulose having an average substitution degree of a methoxy group of 1.0 to 2.0 per glucose unit, an average substitution degree of a hydroxypropoxy group of 0.05 to 0.4 per glucose unit, and a A/B value of 0.305 or greater wherein A represents a substitution degree of a methoxy group directly substituted for a hydroxy group on carbon at position 6 in a glucose unit free from a hydroxypropoxy group-substituted hydroxy group, B represents a substitution degree of a methoxy group per glucose unit, and the A/B represents a value of A divided by B.
    Type: Grant
    Filed: May 2, 2013
    Date of Patent: February 23, 2016
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Rumiko Itoh, Mitsuo Narita, Miyuki Fukasawa
  • Patent number: 9062128
    Abstract: Provided is hydroxyalkyl methylcellulose which can be dissolved at room temperature of 20 to 30° C. and has high thermoreversible gel strength during thermoreversible gelation. More specifically, provided is water-soluble hydroxyalkyl methylcellulose having a molar substitution of hydroxyalkoxyl groups of 0.05 to 0.1 and a substitution degree of methoxyl groups of 1.6 to 1.9, wherein the hydroxyalkoxyl groups are classified into substituted hydroxyalkoxyl groups having hydroxyl groups of hydroxyalkoxyl groups substituted further with methoxyl groups and unsubstituted hydroxyalkoxyl groups having hydroxyl groups of hydroxyalkoxyl groups not further substituted; and a ratio (A/B) of a molar fraction (A) of the substituted hydroxyalkoxyl groups to a molar fraction (B) of unsubstituted hydroxyalkoxyl groups is 0.4 or greater.
    Type: Grant
    Filed: December 6, 2010
    Date of Patent: June 23, 2015
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Kazuhisa Hayakawa, Rumiko Itoh
  • Patent number: 9024011
    Abstract: The present technology provides processes for cross-linking cellulose ethers under mild conditions. The processes include exposing a substantially dry cellulose ether film to a polyisocyanate to provide a cross-linked cellulose ether film, wherein the substantially dry cellulose ether film comprises alkoxide groups on the cellulose. The resulting cellulose ether films are highly cross-linked by polyurethane linkages and may be used as membranes in a variety of applications.
    Type: Grant
    Filed: September 2, 2010
    Date of Patent: May 5, 2015
    Assignee: University of Calcutta
    Inventors: Patit Paban Kundu, Ratan Pal Singh
  • Publication number: 20150059619
    Abstract: The present disclosure is directed to methods for producing a very low viscosity cellulose ether having little or no discoloration and cellulose ether products resulting therefrom. The method includes contacting a cellulose ether with an oxidizing agent and an acid to form a mixture. The mixture is then heated and neutralized. The method includes adding a second oxidizing agent to the mixture and forming a very low viscosity cellulose ether having a viscosity from 1.2 cP to less than 2 cP. The very low viscosity ether may also have an APHA color value of 1 to 100.
    Type: Application
    Filed: November 12, 2014
    Publication date: March 5, 2015
    Inventor: Charles B. Mallon
  • Patent number: 8822675
    Abstract: Provided is nonionic and excellently stable low-substituted hydroxypropylcellulose having improved compressibility and flowability, and further having improved disintegration and texture in oral cavity. More specifically provided is low-substituted hydroxypropylcellulose having a crystallinity of 60% or less, a degree of hydroxypropoxyl substitution of 5 to 9% by weight, and an aspect ratio of less than 2.5, wherein the crystallinity is calculated based on a diffraction intensity by wide-angle X-ray diffraction measurement according to the following formula (1): Crystallinity(%)={(Ic?Ia)/Ic}×100??(1) wherein Ic means a diffraction intensity at a diffraction angle 2? of 22.5° and Ia means a diffraction intensity at a diffraction angle 2? of 18.5°.
    Type: Grant
    Filed: March 8, 2011
    Date of Patent: September 2, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Naosuke Maruyama, Yasuyuki Hirama
  • Publication number: 20140083752
    Abstract: A degradable polymeric nanotube (NT) dispersant comprises a multiplicity of NT associative groups that are connected to a polymer backbone by a linking group where there are cleavable groups within the polymer backbone and/or the linking groups such that on a directed change of conditions, bond breaking of the cleavable groups results in residues from the degradable polymeric NT dispersant in a manner where the associative groups are uncoupled from other associative groups, rendering the associative groups monomelic in nature. The degradable polymeric nanotube (NT) dispersant can be combined with carbon NTs to form a NT dispersion that can be deposited to form a NT film, or other structure, by air brushing, electrostatic spraying, ultrasonic spraying, ink-jet printing, roll-to-roll coating, or dip coating. The deposition can render a NT film that is of a uniform thickness or is patterned with various thicknesses.
    Type: Application
    Filed: April 3, 2012
    Publication date: March 27, 2014
    Applicant: University of Florida Research Foundation, Inc.
    Inventors: Ryan M. Walczak, John R. Reynolds, Andrew Gabriel Rinzler, Andrew M. Spring, Svetlana V. Vasilyeva, Pooja Wadhwa
  • Publication number: 20140072526
    Abstract: The present invention relates to an adsorbate of a pharmaceutically compatible rasagiline salt comprising at least one pharmaceutically compatible adjuvant, wherein the at least one pharmaceutically compatible adjuvant is a water-soluble, organic solvent and the rasagiline salt is present in the adsorbate as an amorphous substance.
    Type: Application
    Filed: September 3, 2013
    Publication date: March 13, 2014
    Applicant: RATIOPHARM GMBH
    Inventors: Alexander Lehmann, Frank Muskulus, Julia Schulze-Nahrup
  • Publication number: 20140013999
    Abstract: A particulate cellulose derivative is obtained in a process of grinding and drying a moist cellulose derivative which comprises the steps of A) providing a cellulose derivative having a moisture content of from 60 to 95 percent, based on the total weight of the moist cellulose derivative, B) grinding and partially drying the moist cellulose derivative in a gas-swept impact mill; and C) contacting the ground and partially dried cellulose derivative with an additional amount of a drying gas outside the gas-swept impact mill. The obtained particulate cellulose derivative has a high untapped bulk density and a good flowability.
    Type: Application
    Filed: March 29, 2012
    Publication date: January 16, 2014
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Yvonne M. Goerlach-Doht, Juergen Hermanns, Peter E. Pierini, Marco Grossstueck, Michael Schreck
  • Publication number: 20140018531
    Abstract: The amount of water-insoluble fibers in a water-soluble cellulose derivative is reduced in a process comprising the steps of a) providing a water-soluble cellulose derivative having a residual amount of at least 20 ppm by weight of water-insoluble fibers in a 2 weight percent aqueous solution of the water-soluble cellulose derivative; b) mixing the water-soluble cellulose derivative of step a) with a liquid in a compounder to provide a moist water-soluble cellulose derivative having a temperature of at least 50 C and a moisture content of from 35 to 90 percent, based on the total weight of the moist cellulose derivative; and c) drying-grinding the mixture of step b) in a gas-swept impact mill to obtain a dried and ground cellulose derivative.
    Type: Application
    Filed: March 29, 2012
    Publication date: January 16, 2014
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Yvonne M. Goerlach-Doht, Juergen Hermanns, Peter E. Pierini
  • Publication number: 20140017319
    Abstract: A particulate cellulose derivative is obtained in a process of grinding and drying a moist cellulose derivative which comprises the steps of A) providing a cellulose derivative having a moisture content of from 60 to 95 percent, based on the total weight of the moist cellulose derivative, B) grinding and partially drying the moist cellulose derivative in a gas-swept impact mill; and C) contacting the ground and partially dried cellulose derivative with an additional amount of a drying gas outside the gas-swept impact mill. The obtained particulate cellulose derivative has a high untapped bulk density and a good flowability.
    Type: Application
    Filed: March 29, 2012
    Publication date: January 16, 2014
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Yvonne M. Goerlach-Doht, Juergen Hermanns, Marco Grossstueck
  • Publication number: 20130245249
    Abstract: Provided is hydroxypropylmethylcellulose having a high thermal gelation temperature and a high thermal gel strength and a method for producing the same and a food comprising the hydroxypropylmethylcellulose. More specifically, provided is hydroxypropylmethylcellulose having an average substitution degree of a methoxy group of 1.0 to 2.0 per glucose unit, an average substitution degree of a hydroxypropoxy group of 0.05 to 0.4 per glucose unit, and a A/B value of 0.305 or greater wherein A represents a substitution degree of a methoxy group directly substituted for a hydroxy group on carbon at position 6 in a glucose unit free from a hydroxypropoxy group-substituted hydroxy group, B represents a substitution degree of a methoxy group per glucose unit, and the A/B represents a value of A divided by B.
    Type: Application
    Filed: May 2, 2013
    Publication date: September 19, 2013
    Applicant: Shin-Etsu Chemical Co., Ltd.
    Inventors: Rumiko Itoh, Mitsuo Narita, Miyuki Fukasawa
  • Patent number: 8487089
    Abstract: The present invention relates to a water-soluble associative cellulose ether having a DP viscosity from 250 to 20,000 mPa·s, measured at a concentration of 1% by weight, and a molecular substitution, MS, from 0.0001 to 0.005 of a hydrophobic substituent containing an unsubstituted or substituted hydrocarbon group of 8-24 carbon atoms. The cellulose ether has a good thickening effect and advantageous application properties at low contents and can be used in an aqueous decorative paint composition, an aqueous paper coating composition, an aqueous organic filler composition, an aqueous cement slurry, an aqueous detergent composition or an aqueous personal care formulation.
    Type: Grant
    Filed: December 15, 2004
    Date of Patent: July 16, 2013
    Assignee: Akzo Nobel N.V.
    Inventors: Peter Boström, Leif Karlson
  • Publication number: 20130157922
    Abstract: The present invention is a water-based carrageenan gel composition that exhibits remarkable resistance against syneresis and mottling, made possible by the addition of relatively small amounts of nonionic cellulose derivatives such as methyl hydroxyethyl cellulose.
    Type: Application
    Filed: December 11, 2012
    Publication date: June 20, 2013
    Applicant: The Dial Corporation
    Inventor: The Dial Corporation
  • Publication number: 20130130949
    Abstract: A cellulose ether having (i) one or more substituents selected from the group consisting of methyl, hydroxyethyl and hydroxypropyl, (ii) one or more hydrophobic substituents, and (iii) one or more cationic, tertiary amino, or anionic substituents, and having a retained dynamic viscosity, % ?80/25, of at least 30 percent, wherein % ?80/25=[dynamic solution viscosity at 80° C./dynamic solution viscosity at 25° C.]×100, the dynamic solution viscosity at 25° C. and 80° being measured as 1% aqueous solution, is useful for modifying the viscosity of a composition selected from the group consisting of wellbore servicing fluids, cementitious formulations, ceramics, metal working fluids and cutting fluids.
    Type: Application
    Filed: August 10, 2011
    Publication date: May 23, 2013
    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLC
    Inventors: Emmett M. Partain, III, Russell L. Kreeger
  • Publication number: 20130118743
    Abstract: Novel nonionic cellulose ethers exhibit a reduced degree of thermal thinning and are efficient thickeners at elevated temperatures. The nonionic cellulose ether has hydroxyethyl groups and is further substituted with one or more hydrophobic substituents. The cellulose ether further has at least one of the properties a), b) or c): a) a retained dynamic viscosity, %?80/25, of at least 30 percent, wherein % ?180/25=[dynamic solution viscosity at 80° C./dynamic solution viscosity at 25° C.? 100, the dynamic solution viscosity at 25° C. and 80° C. being measured as 1% aqueous solution; b) a storage modulus of at least 15 Pascals at 25° C. and a retained storage modulus, % G?80/25, of at least 12 percent, wherein %G?80/25=[storage modulus at 80° C./storage modulus at 25° C.] 100, the storage modulus at 25° C. and 80° C. being measured as a 1% aqueous solution; c) a critical association concentration of less than 15 ppm as measured by light-scattering.
    Type: Application
    Filed: August 10, 2011
    Publication date: May 16, 2013
    Applicant: UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY LLC
    Inventor: Emmett M. Partain, III
  • Publication number: 20120214982
    Abstract: There is provided a method for producing alkali cellulose comprising efficiently removing cellulose particles which are introduced by a pulp and have accumulated in a circulating alkali metal hydroxide solution. More specifically, there is provided a method for producing alkali cellulose, comprising at least the steps of bringing a pulp into contact with an alkali metal hydroxide solution to obtain a contact product, draining the contact product by a drainer, reusing an alkali metal hydroxide solution recovered in the step of draining for contact with a pulp, and adjusting an amount of cellulose particles in the recovered alkali metal hydroxide solution to 0.5% by weight or less prior to reusing for contact with the pulp.
    Type: Application
    Filed: February 16, 2012
    Publication date: August 23, 2012
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventor: Mitsuo Narita
  • Patent number: 8138331
    Abstract: A description is given of glyoxal-treated polysaccharide derivatives which, to decrease the unbound glyoxal, are treated with an aqueous solution of one or more water-soluble aluminium salts, or one or more water-soluble borates, or a combination of one or more water-soluble aluminium salts and one or more water-soluble borates, and, if appropriate, with suitable buffer substances to set the pH, and then dried. A description is likewise given of a process for decreasing the content of unbound glyoxal in glyoxal-treated polysaccharide derivatives.
    Type: Grant
    Filed: November 1, 2006
    Date of Patent: March 20, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Meinolf Brackhagen, Hartwig Schlesiger
  • Publication number: 20110282050
    Abstract: The throughput of a reactor for producing alkali cellulose and/or a cellulose derivative can be increased by using a granulated cellulose-based material for the preparation of alkali cellulose and/or a cellulose derivative. Cellulose derivatives of essentially the same quality can be produced as in known processes wherein powdered cellulose-based material is used for alkalization and derivatization.
    Type: Application
    Filed: November 30, 2007
    Publication date: November 17, 2011
    Inventors: Gunnar R. Merz, Hans-Peter Schneider, Wolfgang Beer
  • Publication number: 20110230655
    Abstract: A process is disclosed for regenerating or derivatizing cellulose. The process comprises the steps of providing a source of unrefined cellulose, and dissolving the unrefined cellulose in a molten inorganic salt. The source of unrefined cellulose may be a biomass, such as wood. The process permits the regeneration or derivatization of cellulose having a high degree of polymerization.
    Type: Application
    Filed: February 18, 2011
    Publication date: September 22, 2011
    Inventors: Jacob A. MOULIJN, Sjoerd Daamen, Paul O'Connor, Rob Van Der Meij
  • Publication number: 20110144322
    Abstract: Provided is hydroxypropylmethylcellulose having a high thermal gelation temperature and a high thermal gel strength and a method for producing the same and a food comprising the hydroxypropylmethylcellulose. More specifically, provided is hydroxypropylmethylcellulose having an average substitution degree of a methoxy group of 1.0 to 2.0 per glucose unit, an average substitution degree of a hydroxypropoxy group of 0.05 to 0.4 per glucose unit, and a A/B value of 0.305 or greater wherein A represents a substitution degree of a methoxy group directly substituted for a hydroxy group on carbon at position 6 in a glucose unit free from a hydroxypropoxy group-substituted hydroxy group, B represents a substitution degree of a methoxy group per glucose unit, and the A/B represents a value of A divided by B.
    Type: Application
    Filed: December 3, 2010
    Publication date: June 16, 2011
    Inventors: Rumiko Itoh, Mitsuo Narita, Miyuki Fukasawa
  • Publication number: 20110077391
    Abstract: Provided is hydroxyalkyl methylcellulose which can be dissolved at room temperature of 20 to 30° C. and has high thermoreversible gel strength during thermoreversible gelation. More specifically, provided is water-soluble hydroxyalkyl methylcellulose having a molar substitution of hydroxyalkoxyl groups of 0.05 to 0.1 and a substitution degree of methoxyl groups of 1.6 to 1.9, wherein the hydroxyalkoxyl groups are classified into substituted hydroxyalkoxyl groups having hydroxyl groups of hydroxyalkoxyl groups substituted further with methoxyl groups and unsubstituted hydroxyalkoxyl groups having hydroxyl groups of hydroxyalkoxyl groups not further substituted; and a ratio (A/B) of a molar fraction (A) of the substituted hydroxyalkoxyl groups to a molar fraction (B) of unsubstituted hydroxyalkoxyl groups is 0.4 or greater.
    Type: Application
    Filed: December 6, 2010
    Publication date: March 31, 2011
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Kazuhisa HAYAKAWA, Rumiko ITOH
  • Patent number: 7402668
    Abstract: A process of preparing alkylhydroxyalkylcellulose (e.g., methylhydroxyethylcellulose and methylhydroxypropylcellulose) by reaction of cellulose in the presence of alkali metal hydroxide with an alkylating agent and a hydroxyalkylating agent is described. The process includes: (a) alkalizing cellulose by means of 0.9 to 2.9 equivalents of an alkali metal hydroxide I/AGU of the cellulose in the form of an aqueous alkali metal hydroxide solution, in the presence of a suspension medium containing at least 0.2 equivalents of an alkylating agent I/AGU of the cellulose; (b) reacting the alkalized cellulose of step (a) with alkylating agent I and a hydroxyalkylating agent at a temperature above 65° C.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: July 22, 2008
    Assignee: Dow Wolff Cellulosics GmbH
    Inventors: Wolfgang Dannhorn, Erik-Andreas Klohr, Martin Kowollik, Hartwig Schlesiger, Jörn-Bernd Pannek
  • Patent number: 7351422
    Abstract: Proposed is a novel soluble trauma-healing and hemostatic cellulose fiber capable of absorbing and readily dissolving hemorrhaging trauma loci when applied thereto and of promoting the hemostatic action of blood platelets and fibrin and cell adhesion to the trauma site. The coagulation protein-containing soluble trauma-healing and hemostatic cellulose fiber is produced in that after treatment of a natural or regenerated cellulose fiber with an aqueous sodium hydroxide solution, said fiber is carboxymethylated by reaction with a monochloro acetic acid solution for a given time (hours) in such a manner that the degree of partial substitution of the glucose units constituting the cellulose molecule (etherification degree) is 0.5-less than 1.0% and that, furthermore, the coagulation proteins fibrinogen, thrombin, and coagulation factor XIII are imparted by surface application or chemical bonding.
    Type: Grant
    Filed: February 22, 2001
    Date of Patent: April 1, 2008
    Assignee: Hogy Medical Co., Ltd.
    Inventors: Yoshio Jo, Motonori Aoshima, Koji Tanabe, Koichi Matsushita, Toshiki Inoue
  • Patent number: 7319146
    Abstract: The present invention relates to a nonionic methyl ethyl hydroxyethyl cellulose ether having a flocculation temperature of 70-95° C., a DS-methyl of 0.1-0.8 and a DS-ethyl of 0.1-0.7. The cellulose ether has versatile properties and may be used as a thickening agent or a rheology modifier in an aqueous formulation, such as an aqueous latex-containing paint composition. A process for manufacturing the cellulose ether is also disclosed.
    Type: Grant
    Filed: January 16, 2004
    Date of Patent: January 15, 2008
    Assignee: Akzo Nobel N.V.
    Inventors: Peter Boström, Kenneth Sundberg
  • Patent number: 7262181
    Abstract: The present invention relates to hemostatic materials made of water-soluble cellulose ether derivatives, such as methylcellulose, ethylcellulose, hydroxyethylcellulose, and pharmaceutically acceptable salts of carboxymethylcellulose, especially to hemostatic materials made of water-soluble cellulose ether derivatives capable of being absorbed in live body. The present invention also relates to the use of water-soluble cellulose hemostatic materials for the preparation of internal and external hemostatic articles and pharmaceutical compositions, and hemostatic articles and pharmaceutical compositions thereof.
    Type: Grant
    Filed: April 30, 2001
    Date of Patent: August 28, 2007
    Assignee: Beijing Textile Research Institute
    Inventors: Mei Zhang, Jinyu Zhang, Xia Song
  • Patent number: 7244840
    Abstract: A nonionic water-soluble cellulose ether is characterized in that when 3 pbw of the nonionic water-soluble cellulose ether is added to a mixture of 90 pbw of cordierite, 10 pbw of ordinary Portland cement, and 33 pbw of water, immediately followed by kneading at 20° C. and 20 rpm, a maximum torque for kneading is reached within 180 seconds from the addition. It is suitable as an admixture for extrudable hydraulic compositions. The hydraulic composition to which the inventive admixture is added can be kneaded within a brief time into a uniform mass which is smoothly extrudable.
    Type: Grant
    Filed: January 27, 2006
    Date of Patent: July 17, 2007
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshiaki Sasage, Tsutomu Yamakawa
  • Patent number: 7151173
    Abstract: A nonionic water-soluble cellulose ether is characterized in that when 3 pbw of the nonionic water-soluble cellulose ether is added to a mixture of 90 pbw of cordierite, 10 pbw of ordinary Portland cement, and 33 pbw of water, immediately followed by kneading at 20° C. and 20 rpm, a maximum torque for kneading is reached within 180 seconds from the addition. It is suitable as an admixture for extrudable hydraulic compositions. The hydraulic composition to which the inventive admixture is added can be kneaded within a brief time into a uniform mass which is smoothly extrudable.
    Type: Grant
    Filed: March 19, 2003
    Date of Patent: December 19, 2006
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshiaki Sasage, Tsutomu Yamakawa
  • Patent number: 7098327
    Abstract: A process for the production of dual-functional ion exchange resins from lignocellulosic agricultural material involving anionization of the lignocellulosic agricultural material with citric acid and then cationization of the lignocellulosic agricultural material with dimethyloldihydroxyethylene urea (DMDHEU) and choline chloride, or cationization of the lignocellulosic agricultural material with DMDHEU and choline chloride and then anionization of the lignocellulosic agricultural material with citric acid.
    Type: Grant
    Filed: August 19, 2004
    Date of Patent: August 29, 2006
    Assignee: The United States of America as represented by the Secretary of Agriculture
    Inventors: Wayne E. Marshall, Lynda H. Wartelle
  • Patent number: 7005515
    Abstract: The process for preparing an alkyl hydroxyalkyl cellulose ether comprises the steps of: a) alkalizing cellulose to obtain alkali cellulose, b) reacting alkali cellulose with an alkyl halogenide until an alkyl cellulose ether with a D.S.(alkyl) value of from 0.7 to 2.5. is attained, c) removing excess alkyl halogenide from the reaction mixture, and d) reacting the alkyl cellulose ether with an alkylene oxide in a liquid suspending agent to produce an alkyl hydroxyalkyl cellulose ether. An alkyl hydroxyalkyl cellulose ether is produced which has an D.S.(alkyl) of from 0.7 to 2.5 and an MS (hydroxyalkyl) from 0.03 to 2.0, wherein not more that 15 percent of the hydroxyalkyl groups are capped with an alkyl group.
    Type: Grant
    Filed: March 4, 2002
    Date of Patent: February 28, 2006
    Assignee: Dow Global Technologies Inc.
    Inventors: Hans P. Schneider, Wolfgang H. Beer, Stephen J. Merryweather
  • Patent number: 6958393
    Abstract: A description is given of cellulose derivatives having gel-like rheological properties in aqueous solution characterized in that: a) cellulose is alkalized with aqueous alkali metal hydroxide solution in the presence of a suspension medium, b) the alkalized cellulose is reacted with one or more alkylene oxides, c) then reacted with an alkyl halide present in the suspension medium d) subsequently or simultaneously the alkalized cellulose is reacted with a crosslinking agent in an amount of 0.0001 to 0.05 eq, where the unit “eq” represents the molar ratio of crosslinking agent relative to the anhydroglucose unit (AGU) of the cellulose used, and e) after, if appropriate, further addition of alkali metal hydroxide and/or alkylating agent, the resultant irreversibly crosslinked cellulose derivative is separated off from the reaction mixture, if appropriate purified and dried.
    Type: Grant
    Filed: July 23, 2003
    Date of Patent: October 25, 2005
    Assignee: Wolff Cellulosics GmbH & Co. KG
    Inventors: Hartwig Schlesiger, Arne Henning Kull, Erik-Andreas Klohr
  • Patent number: 6939961
    Abstract: A process for preparing low-viscosity water-soluble cellulose ethers by the oxidative decomposition of higher-viscosity cellulose ethers with hydrogen peroxide is described. The process involves: (a) forming, under conditions of intensive mixing and at temperatures of 65-125° C., a mixture of, (i) one or more higher-viscosity cellulose ethers, and (ii) an aqueous solution of hydrogen peroxide, the proportions of the mixture being selected in such a way that the hydrogen peroxide content is 0.1-10 wt. % in relation to the dry cellulose ether, the solids content of the mixture is at least 25 wt. % in relation to the total weight of the mixture; and (b) agitating continuously the mixture of step (a) at temperatures of 65-125° C. until at least approximately 90% of the hydrogen peroxide has been spent.
    Type: Grant
    Filed: November 15, 1999
    Date of Patent: September 6, 2005
    Assignee: Wolf Walsrode AG
    Inventor: Hartwig Schlesiger
  • Patent number: 6933381
    Abstract: Process for the production of polysaccharide ethers, e.g. cellulose ethers, are disclosed wherein salts formed during the process, e.g., sodium nitrate or sodium acetate, are converted to their corresponding acids and bases by means of an electric current, preferably in combination with a bipolar membrane and suitable catiion and/or anion membranes. The acids and bases recovered from the process can be recycled, thereby avoiding the need to provide for disposal of salts.
    Type: Grant
    Filed: February 2, 2001
    Date of Patent: August 23, 2005
    Inventors: Charles B. Mallon, John S. Vames, John I. Sarlis, Benito See, David M. Trampe, Rathin Datta
  • Patent number: 6891034
    Abstract: Described is a process of preparing alkylhydroxyalkyl cellulose, e.g., methylhydroxypropyl cellulose (MHPC). The process includes: (a) alkylating cellulose with an aqueous caustic solution containing from 1.5 to 5.5 equivalents of alkali metal hydroxide, e.g., NaOH, per anhydroglucose unit (AGU) of said cellulose, in the presence of a suspension agent, e.g., dimethyl ether, which contains alkyl halide, e.g., methyl chloride, in an amount of from (equivalents of alkali metal hydroxide per AGU minus 1.4) to (equivalents of alkali metal hydroxide per AGU plus 0.8); (b) reacting the alkalised cellulose of step (a) with one or more alkylene oxides, e.g., propylene oxide, at a temperature higher than 65° C., e.g., 85° C.
    Type: Grant
    Filed: August 3, 2001
    Date of Patent: May 10, 2005
    Assignee: Wolff Walsrode AG
    Inventors: Wolfgang Dannhorn, Hartwig Schlesiger, Jörn-Bernd Pannek, Gerolf Weissach
  • Patent number: 6843845
    Abstract: An admixture comprising (A) a nonionic water-soluble hydroxyethyl cellulose and/or hydroxyethyl ethyl cellulose having a viscosity of at least 500 mPa·s as measured in a 1 wt % aqueous solution at 20° C., and (B) another nonionic water-soluble cellulose ether having a viscosity of at least 1,500 mPa·s as measured in a 1 wt % aqueous solution at 20° C. is suited for use in extrudable hydraulic compositions, because the hydraulic compositions comprising the admixture are effectively extrudable into hardened products having improved surface properties, minimized spring-back and good dimensional accuracy.
    Type: Grant
    Filed: March 11, 2003
    Date of Patent: January 18, 2005
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshiaki Sasage, Tsutomu Yamakawa
  • Patent number: 6602994
    Abstract: A method for producing derivatized microfibrillar polysaccharide, including but not limited to cellulose, derivatized by steric and/or electrostatic forces, where the electrostatic forces are provided by anionic charge or by a combination of both anionic and cationic charge, by stabilizing and/or microfibrillating a polysaccharide starting material. A method of modifying the rheological properties of a composition of matter using derivatized microfibrillar polysaccharide. Method of improving coatings, paper manufacture, and the stability of emulsions, dispersions, and foams using a derivatized microfibrillar polysaccharide. Compositions that include derivatized microfibrillar polysaccharide, including paper compositions, comestible compositions, non-comestible spreadable compositions, and emulsions, dispersion, and foams.
    Type: Grant
    Filed: February 10, 1999
    Date of Patent: August 5, 2003
    Assignee: Hercules Incorporated
    Inventors: Mary Jean Cash, Anita N. Chan, Herbert Thompson Conner, Patrick Joseph Cowan, Robert Alan Gelman, Kate Marritt Lusvardi, Samuel Anthony Thompson, Frank Peine Tise
  • Publication number: 20030065166
    Abstract: A description is given of a process for the industrial preparation of methylhydroxyalkylcelluloses (MHACs) by reaction of cellulose with alkali metal hydroxide and subsequent reaction with an alkyl halide and hydroxyalkylating agent, characterized in that the reaction is carried out batchwise in a reactor which has an L/D ratio of less than 2.5 and in which the unmixed regions are minimized and the batch reactor is preceded at the inlet by a continuously operated cellulose milling facility and is followed at the outlet by a continuously running plant for milling and drying the products, with the product being transported by action of gravity.
    Type: Application
    Filed: September 11, 2002
    Publication date: April 3, 2003
    Inventors: Torsten Holtkotter, Stefan Michel, Gerd Sonnenberg
  • Publication number: 20030065165
    Abstract: A process of preparing alkylhydroxyalkylcellulose (e.g., methylhydroxyethylcellulose and methylhydroxypropylcellulose) by reaction of cellulose in the presence of alkali metal hydroxide with an alkylating agent and a hydroxyalkylating agent is described. The process includes: (a) alkalizing cellulose by means of 0.9 to 2.9 equivalents of an alkali metal hydroxide I/AGU of the cellulose in the form of an aqueous alkali metal hydroxide solution, in the presence of a suspension medium containing at least 0.2 equivalents of an alkylating agent I/AGU of the cellulose; (b) reacting the alkalized cellulose of step (a) with alkylating agent I and a hydroxyalkylating agent at a temperature above 65° C.
    Type: Application
    Filed: July 17, 2002
    Publication date: April 3, 2003
    Inventors: Wolfgang Dannhorn, Erik-Andreas Klohr, Martin Kowollik, Hartwig Schlesiger, Jorn-Bernd Pannek
  • Patent number: 6531593
    Abstract: Cellulose derivatives are formed by first crosslinking cellulose and subsequently reacting the crosslinked cellulose with a reagent capable of forming a cellulose ether or ester. Many crosslinking agents are suitable but those forming ether linkages between cellulose chains are preferred. The crosslinking, in effect, increases the D.P of the cellulose so that wood celluloses are then suitable for forming compositions that previously could only be formed very high D.P celluloses; e.g., those derived from cotton linters.
    Type: Grant
    Filed: May 16, 2000
    Date of Patent: March 11, 2003
    Assignee: Weyerhaeuser Company
    Inventors: Mengkui Luo, Richard A. Jewell, Amar N. Neogi
  • Patent number: 6525192
    Abstract: The present invention provides a low-substituted hydroxypropyl cellulose having a loose bulk density of not less than 0.40 g/mL and a tap bulk density of not less than 0.60 g/mL and a process for producing the same.
    Type: Grant
    Filed: May 11, 1999
    Date of Patent: February 25, 2003
    Assignee: Shin-Etu Chemical Co., Ltd.
    Inventors: Sakae Obara, Hiroshi Umezawa, Naosuke Maruyama, Fumie Tanno
  • Patent number: 6482876
    Abstract: The invention relates to an agglomerate containing at least one of the following water-soluble or water-dispersible materials as a bonding base polymer: carboxylized and/or alkoxylized starch, cellulose ether and fully synthetic vinyl polymers and/or polyacrylates. The agglomerate is characterized in that it contains a blasting agent which produces a high swelling pressure, but, advantageously, does not gel. The agglomerate can have a regular geometric form or not. Its weight should be between 0.5 and 500 g. The agglomerate is used in particular in the production of lump-free paste.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: November 19, 2002
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Sandra Witt-Nuesslein, Werner Haller, Bernhard Schoettmer, Monika Boecker, Wolfgang Seiter, Ingo Hardacker, Heinz-Peter Hoffmann
  • Patent number: 6380381
    Abstract: The present invention provides low-substituted hydroxypropyl cellulose exhibiting good granulation characteristics and tablet properties. Specifically, there is provided low-substituted hydroxypropyl cellulose having a hydroxypropoxyl content in the range of 5.0 to 16.0% by weight and an apparent average degree of polymerization in the range of 350 to 700.
    Type: Grant
    Filed: May 17, 2000
    Date of Patent: April 30, 2002
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Sakae Obara
  • Publication number: 20020038018
    Abstract: Described is a process of preparing alkylhydroxyalkyl cellulose, e.g., methylhydroxypropyl cellulose (MHPC). The process includes: (a) alkylating cellulose with an aqueous caustic solution containing from 1.5 to 5.5 equivalents of alkali metal hydroxide, e.g., NaOH, per anhydroglucose unit (AGU) of said cellulose, in the presence of a suspension agent, e.g., dimethyl ether, which contains alkyl halide, e.g., methyl chloride, in an amount of from (equivalents of alkali metal hydroxide per AGU minus 1.4) to (equivalents of alkali metal hydroxide per AGU plus 0.8); (b) reacting the alkalised cellulose of step (a) with one or more alkylene oxides, e.g., propylene oxide, at a temperature higher than 65° C., e.g., 85° C.
    Type: Application
    Filed: August 3, 2001
    Publication date: March 28, 2002
    Inventors: Wolfgang Dannhorn, Hartwig Schlesiger, Jorn-Bernd Pannek, Gerolf Weissach
  • Publication number: 20020016452
    Abstract: The present invention provides a low-substituted hydroxypropyl cellulose having a loose bulk density of not less than 0.40 g/mL and a tap bulk density of not less than 0.60 g/mL and a process for producing the same.
    Type: Application
    Filed: May 11, 1999
    Publication date: February 7, 2002
    Inventors: SAKAE OBARA, HIROSHI UMEZAWA, NAOSUKE MARUYAMA, FUMIE TANNO
  • Patent number: 6320043
    Abstract: The invention relates to a new, particularly economic process for preparing pulverulent polysaccharide derivatives, in particular cellulose derivatives, having a thermal flocculation point; the process comprises soaking or dissolving the polysaccharide derivative in a solvent or mixed solvent, dividing/comminuting the soaked or dissolved polysaccharide derivative by thermal and/or mechanical liquid separation and an optional drying step.
    Type: Grant
    Filed: July 8, 1999
    Date of Patent: November 20, 2001
    Assignee: Wolf Walsrode AG
    Inventors: Gunter Weber, Detmar Redeker, Bernd Klinksiek, Jürgen Hinderer, Benno Ulfik
  • Patent number: 6313287
    Abstract: Water-soluble sulfoalkyl-containing hydrophobically modified cellulose ethers, processes for preparing them, and their use in emulsion paints The present invention relates to water-soluble ionic cellulose ethers from the group of the hydroxyalkylcelluloses which are substituted by on average from 0.001 to 1.0 alkyl group per anhydroglucose unit and which carry from 0.01 to 0.1 sulfoalkyl group per anhydroglucose unit, to processes for preparing them and to the use of water-soluble ionic cellulose ethers from the group of the hydroxyalkylcelluloses which are substituted by on average from 0.001 to 1.0 alkyl group per anhydroglucose unit and which carry from 0.01 to 0.4 sulfoalkyl group per anhydroglucose unit in emulsion paints.
    Type: Grant
    Filed: October 26, 1999
    Date of Patent: November 6, 2001
    Assignee: Clariant GmbH
    Inventors: Reinhard Doenges, Juergen Kirchner
  • Patent number: 6261218
    Abstract: There is a process for making a cellulose ether. The process comprises the following: a) alkalyzing a cellulose pulp; b) etherifying the alkalyzed cellulose pulp to form a cellulose ether; c) washing the cellulose ether; d) drying the cellulose ether; e) milling the cellulose ether to a particulate form; f) heating the particulate cellulose ether; g) tumbling the particulate cellulose ether while simultaneously contacting it with an acid to partially depolymerize it to a lower molecular weight; h) partially or substantially neutralizing the acid. There is also an apparatus for making the cellulose ether.
    Type: Grant
    Filed: December 1, 1998
    Date of Patent: July 17, 2001
    Assignee: The Dow Chemical Company
    Inventor: Gary J. Schulz
  • Patent number: 6248880
    Abstract: The present invention relates to associative cellulose ethers with improved thickening effects, especially in paint. The improvement depends on the presence of a hydrophobic modifying group of the general formula where R is an aliphatic group of 12-22 carbon atoms and n is a number from 3 to 7. The DS of the hydrophobic group is 0.003 to 0.012.
    Type: Grant
    Filed: July 19, 1999
    Date of Patent: June 19, 2001
    Assignee: Akzo Nobel NV
    Inventor: Leif Karlson
  • Patent number: 6201070
    Abstract: Methods are disclosed for enhancing the toughness, e.g., resistance to cracking upon flexation, of coatings made from cycloaliphatic epoxide derivatives wherein the cycloaliphatic epoxide derivative is a cycloaliphatic epoxide ester of a hydroxy-functional compound containing at least one branched, 1,2-alkylene oxide unit. Processes for making the cycloaliphatic epoxide derivatives and coating formulations comprising the cycloaliphatic epoxide derivatives are also disclosed.
    Type: Grant
    Filed: November 20, 1996
    Date of Patent: March 13, 2001
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Naofumi Kumabe, Thomas Andrew Upshaw, Robert Francis Eaton, Bharat Kanaiyalal Patel, John Kellis Braddock
  • Patent number: 6166119
    Abstract: A cement pumpability-enhancing additive which confers good pumpability on cementitious compositions such as concrete consists essentially of(a) polyethylene glycol;(b) diethylene glycol monobutyl ether and/or a derivative thereof;(c) polysaccharide; and(d) a thickening polymer selected from the group consisting of polyacrylic acid derivatives, polyacrylic amide derivatives, cellulose ethers, polyphenyl ethers and polyalkylene glycol fatty acid esters;the weight solids proportions of (a), (b), (c), and (d) in the additive being respectively 5-55%, 10-80%, 1-20% and 1-20%. The additive is preferably used with a cement dispersing agent.
    Type: Grant
    Filed: April 14, 1999
    Date of Patent: December 26, 2000
    Assignee: MBT Holding AG
    Inventors: Shigemi Matsuo, Hidenori Nagamine, Akira Ota