Aromatic Nucleus Containing Patents (Class 536/94)
  • Patent number: 9040682
    Abstract: Flame retardant cellulose is prepared comprising cellulose fibers and an organophosphate compound bonded to the cellulose fibers. Accordingly, the bonded phosphate-functional group provides the cellulose fibers with pendant phosphate ester functionality. Numerous phosphate derivatives can be envisaged that will accomplish the intended task.
    Type: Grant
    Filed: January 4, 2013
    Date of Patent: May 26, 2015
    Assignee: International Business Machines Corporation
    Inventors: Dylan J. Boday, Joseph Kuczynski
  • Patent number: 6534637
    Abstract: This invention provides &bgr;-D-Glucuronidase substrates of the formula: wherein R1, R2, and R7-R12 are independently selected from the group consisting of: hydrogen, fluorine, chlorine, bromine, iodine, alkyl, hydroxyl, alkoxy, carboxyl and nitro groups; R3-R6 are independently selected from the group consisting of hydrogen, fluorine, chlorine, bromine, iodine, nitro and amino; and M+ is selected from the group consisting of: proton, lithium, sodium, potassium, magnesium, calcium, barium, and ammonium ion.
    Type: Grant
    Filed: February 12, 2001
    Date of Patent: March 18, 2003
    Assignee: Beckman Coulter, Inc.
    Inventors: Gene G. Y. Shen, Chan S. Oh, Stephanie D. Yancey, Craig W. Adams
  • Patent number: 6482876
    Abstract: The invention relates to an agglomerate containing at least one of the following water-soluble or water-dispersible materials as a bonding base polymer: carboxylized and/or alkoxylized starch, cellulose ether and fully synthetic vinyl polymers and/or polyacrylates. The agglomerate is characterized in that it contains a blasting agent which produces a high swelling pressure, but, advantageously, does not gel. The agglomerate can have a regular geometric form or not. Its weight should be between 0.5 and 500 g. The agglomerate is used in particular in the production of lump-free paste.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: November 19, 2002
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Sandra Witt-Nuesslein, Werner Haller, Bernhard Schoettmer, Monika Boecker, Wolfgang Seiter, Ingo Hardacker, Heinz-Peter Hoffmann
  • Patent number: 6392035
    Abstract: The invention concerns reactive cellulose, i.e. cellulose having in particular a very low degree of crystallinity obtainable with a high degree of purity. Said novel reactive cellulose is particularly used as raw material for making cellulose ethers. The invention is characterized in that the reactive cellulose is substituted by organic groups according to a degree of substitution, DS, of less than 0.2, preferably between 0.04 and 0.2.
    Type: Grant
    Filed: November 10, 1999
    Date of Patent: May 21, 2002
    Assignee: Rhodia Acetow
    Inventors: Ties Karstens, Armin Stein, Hans Steinmeier
  • Patent number: 6372901
    Abstract: Polysaccharides, including hydroxyethyl cellulose, having alkyl-aryl hydrophobic substitution, provide latex compositions, such as paints, with improved rheology and stability. Improved processes for producing such polysaccharides are also provided.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 16, 2002
    Assignee: Union Carbide Corporation
    Inventors: Emmett Malone Partain, III, George Lewis Brode, II, Richard Charles Hoy
  • Patent number: 5612321
    Abstract: Grafted polysaccharide compositions comprising polysaccharides grafted with antioxidants on at least one hydroxyl group of the polysaccharide. The use of antioxidant grafted polysaccharides or antioxidant grafted crosslinked polysaccharides as a treatment for arthritis, as a drug delivery vehicle, to reduce the incidence of post-operative adhesion formation, to promote the healing of chronic wounds and ulcers, and as a component of cosmetic formulations.
    Type: Grant
    Filed: June 22, 1995
    Date of Patent: March 18, 1997
    Assignee: Hercules Incorporated
    Inventor: Tuyen T. Nguyen
  • Patent number: 5583214
    Abstract: Cellulose ether derivatives comprising a hydrophobic substituent having an unsaturated alkyl portion are disclosed. The unsaturation in the alkyl portion of the hydrophobic substituent can promote crosslinking of the cellulose ether derivative. The cellulose ether derivatives are useful as ingredients in latex compositions. The cellulose ether derivatives can provide associative thickening and rheological properties to latex composition during storage and application. In addition, after the latex composition is applied to the surface to be coated, the cellulose ethers of the present invention can promote crosslinking of the latex film to provide a hard and durable coating. Latex paint compositions comprising the cellulose ether derivatives of the present invention are also disclosed.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: December 10, 1996
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Emmett M. Partain, III
  • Patent number: 5426182
    Abstract: Polysaccharides, including hydroxyethyl cellulose, having complex hydrophobic group substitution, provide latex compositions, such as paints, with improved rheology and stability. Improved processes for producing such polysaccharides are also provided.
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: June 20, 1995
    Assignee: Union Carbide Chemical & Plastics Technology Corporation
    Inventors: Richard D. Jenkins, David R. Bassett, Gregory D. Shay
  • Patent number: 5120838
    Abstract: Cellulose ethers are disclosed which have sufficient nonionic substitution to render them water soluble and which are further modified with a C.sub.10 to C.sub.24 long chain alkylaryl group in an amount between 0.2% by weight and the amount which makes them less then 1% by weight soluble in water. Hydroxyethylcellulose is a preferred water soluble cellulose ether for modification according to the invention. These products exhibit substantially improved viscosifying effects compared to their unmodified cellulose ether counterparts, and provide good leveling and sag resistance in latex paints. Preferred alkylaryl groups are nonylphenyl, dodecylphenyl, and dinonylphenyl. Included are cellulose ethers with spacer groups of various lengths between the alkylaryl group and the connecting group to the cellulose molecule.
    Type: Grant
    Filed: October 30, 1989
    Date of Patent: June 9, 1992
    Assignee: Aqualon Company
    Inventors: Ernst K. Just, Thomas G. Majewicz, Arjun C. Sau
  • Patent number: 5055570
    Abstract: A cellulose derivative comprising substitution-modified cellulose regenerated from a cuprammonium solution, the substituents being ester groups, wherein the acyl group represents one or more, optionally substituted, carbon chains with 10-36 carbon atoms, or a residue containing at least one aromatic and/or heterocyclic, optionally substituted, ring, or wherein the substituents are carbamate groups, the carbamoyl group of which represents a group containing one or more, optionally substituted, carbon chains with 2-36 carbon atoms, or a group containing at least one aromatic and/or heterocyclic, optionally substituted, ring. A dialysis membrane made from the substitution-modified cellulose, typically in the form of a flat film, a tubular film, or a hollow filament, is also disclosed.
    Type: Grant
    Filed: August 4, 1989
    Date of Patent: October 8, 1991
    Assignee: Akzo N.V.
    Inventor: Michael Diamantoglou
  • Patent number: 5008385
    Abstract: Cellulose derivatives are disclosed which have the following formula: ##STR1## wherein Z is selected from the group consisting of alkylene, alkenylene, alkynylene, cycloalkylene or benzylene or xylylene radicals, which may or may not be substituted;X is selected from the group consisting of --H, --NR.sub.2, --N.sup.+ R.sub.3, --CN, --COOH, --SO.sub.3 H, --SO.sub.3 H, --PO(OR).sub.2, CONR.sub.2 or --Si(OR).sub.3 ;R is selected from the group consisting of hydrogen, alkyl and alkenyl groups having from 1 to 25 carbon atoms, and cycloalkyl, tolyl and phenyl groups;Y is selected from the group consisting of alkyl, alkenyl, alkynyl groups having from 1 to 36 carbon atoms, which may or may not be substituted, cycloalkyl, phenyl, tolyl and benzyl groups, ##STR2## (--CH.dbd.CH--COOH), and NHR, where R has the same meaning as in X, andm=0 to 2.5n=0.01 to 2.95,with the provision that, when m=0, n.gtoreq.1.55, if Y is an alkyl radical with 1 to 5 carbon atoms, 3-(CH.sub.2).sub.
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: April 16, 1991
    Assignee: Akzo N.V.
    Inventor: Michael Diamantoglou
  • Patent number: 4992538
    Abstract: Silated polysaccharides having 0.0005 to 2.0 silyl molar substitution per anhydrosaccharide unit form water resistant films when cast from aqueous solution and dried in the presence of atmospheric carbon dioxide. These films are soluble in aqueous caustic. A preferred water soluble polymer is a cellulose ether with 0.005 to 1.0 silyl substitution.
    Type: Grant
    Filed: June 5, 1989
    Date of Patent: February 12, 1991
    Assignee: Aqualon Company
    Inventor: Arjun C. Sau
  • Patent number: 4582899
    Abstract: A manufacturing method for cellulose ether having a high degree of substitution characterized in that an etherifying agent represented by a general formula RCH.sub.2 X (where R is aromatic group, heterocyclic group, vinyl group or ethynyl group or the same group substituted and X is chlorine or bromine) is reacted with a uniform solution of cellulose acetate having a degree of substitution of 2.0 and over in an organic solvent in the presence of a base to manufacture a highly substituted cellulose ether having a degree of substitution of 2.0 and over per anhydrous glucose unit by a one stage reaction at a good yield.As a general method for manufacturing cellulose ether, a method for reacting an etherifying agent with alkali cellulose is now in use. For the general method, several improved methods have been proposed. However, it is difficult to manufacture cellulose ether having a degree of substitution of 2.5 and over by a one stage reaction using the general method.
    Type: Grant
    Filed: April 8, 1985
    Date of Patent: April 15, 1986
    Assignee: Daicel Chemical Industries, Ltd.
    Inventor: Hiroyuki Nakamura
  • Patent number: 4229572
    Abstract: In the preparation of organosoluble cellulose ethers, the content of alkali metal (hydroxides and the salts thereof) in the resulting cellulose ether is reduced by forming a solution of the cellulose ether and an organic solvent, converting the alkali metal hydroxide therein to an alkali metal salt and heating the resulting solution at conditions sufficient to (1) increase the size of the alkali metal salt particles and (2) remove any water therefrom. Filtering the resulting mixture and drying the filtrate yields a cellulose ether containing a very small percentage of alkali metal salt, e.g., often less than about 500 ppm.
    Type: Grant
    Filed: March 5, 1979
    Date of Patent: October 21, 1980
    Assignee: The Dow Chemical Company
    Inventor: Maurice L. Zweigle
  • Patent number: RE34904
    Abstract: Cellulose ethers are disclosed which have sufficient nonionic substitution to render them water soluble and which are further modified with a C.sub.10 to C.sub.24 long chain alkylaryl group in an amount between 0.2% by weight and the amount which makes them less than 1% by weight soluble in water. Hydroxyethylcellulose is a preferred water soluble cellulose ether for modification according to the invention. These products exhibit substantially improved viscosifying effects compared to their unmodified cellulose ether counterparts, and provide good leveling and sag resistance in latex paints. Preferred alkylaryl groups are nonylphenyl, dodecylphenyl, and dinonylphenyl. Included are cellulose ethers with spacer groups of various lengths between the alkylaryl group and the connecting group to the cellulose molecule.
    Type: Grant
    Filed: July 8, 1993
    Date of Patent: April 11, 1995
    Assignee: Hercules Incorporated
    Inventors: Ernst K. Just, Thomas G. Majewicz, Arjun C. Sau