Hydroxyethyl Patents (Class 536/96)
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Publication number: 20150144032Abstract: Disclosed are methods for the preparation of alkyl hydroxyalkyl cellulose ethers, and the use of such alkyl hydroxyalkyl cellulose ethers in the preparation and use of mortars and other cement-based systems; also disclosed is a hydraulic composition containing at least one retarder, at least one accelerator and a cellulose ether having a prolonged open time without deterioration of the other cement tile adhesive properties such as workability, setting time, strength development and sag resistance; and further disclosed are dry mortars containing encapsulated calcium chloride used in preparing mortar materials for use in construction, and the preparation and use of such mortars in cold weather environments is also disclosed.Type: ApplicationFiled: July 23, 2014Publication date: May 28, 2015Inventors: Kelly A. Brush, Patrick J. Cowan, Wilfried Adolphe Hohn, Alexander Adolphe Kindler, Vera Louise Nilles
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Patent number: 9024011Abstract: The present technology provides processes for cross-linking cellulose ethers under mild conditions. The processes include exposing a substantially dry cellulose ether film to a polyisocyanate to provide a cross-linked cellulose ether film, wherein the substantially dry cellulose ether film comprises alkoxide groups on the cellulose. The resulting cellulose ether films are highly cross-linked by polyurethane linkages and may be used as membranes in a variety of applications.Type: GrantFiled: September 2, 2010Date of Patent: May 5, 2015Assignee: University of CalcuttaInventors: Patit Paban Kundu, Ratan Pal Singh
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Publication number: 20140073777Abstract: The present invention relates to a method for producing an alkali cellulose with suppressed decrease in the degree of polymerization as well as with small use amount of a basic compound, and to a method for producing a cellulose ether by using the alkali cellulose thus obtained. Provided by the present invention are: (A) a method for producing an alkali cellulose, comprising Step 1 wherein a cellulose-containing raw material (I) is treated by a pulverizing machine thereby obtaining a cellulose-containing raw material (II) which contains a cellulose having crystallinity in the range of 10 to 55% and Step 2 wherein the cellulose-containing raw material (II) obtained in Step 1 is added by a basic compound with the amount thereof being in the range of 0.6 to 1.Type: ApplicationFiled: April 27, 2012Publication date: March 13, 2014Applicant: KAO CORPORATIONInventors: Eisuke Miyoshi, Yutaka Yoshida, Ryo Miyasato, Yoichiro Imori, Toru Nishioka
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Patent number: 8652252Abstract: A hydraulic composition comprising a water-soluble hydroxyalkyl alkyl cellulose, cement, aggregate, reinforcing fibers, and water is provided. The hydroxyalkyl alkyl cellulose has a degree of alkyl substitution of 1.2-1.7, the sum of the degree of alkyl substitution and the molar substitution of hydroxyalkyl is 1.5-2.0, and a proportion of glucose ring not substituted with alkyl and hydroxyalkyl groups per glucose ring unit is up to 10 mol %. The composition cures within a short time and is extrusion moldable even at elevated temperature.Type: GrantFiled: July 2, 2013Date of Patent: February 18, 2014Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hidekazu Konishi, Rumiko Itoh, Tsutomu Yamakawa, Kazuhisa Hayakawa
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Publication number: 20130303748Abstract: A method for making aldehyde-functionalized polysaccharides having pendant aldehyde groups is described. The method involves the hydroformylation of an alkene-functionalized polysaccharide. The resulting aldehyde-functionalized polysaccharides are useful for forming hydrogel tissue adhesives and sealants for medical applications.Type: ApplicationFiled: May 10, 2012Publication date: November 14, 2013Applicant: Actamax Surgical Materials, LLCInventors: Samuel D. Arthur, Steven W. Shuey, Barry M. Trost
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Patent number: 8580951Abstract: Novel aldehyde-functionalized polysaccharide compositions are described that are more stable in aqueous solution than oxidized polysaccharides or other types of polysaccharides containing pendant aldehyde groups. The aldehyde-functionalized polysaccharides may be reacted with various amine-containing polymers to form hydrogel tissue adhesives and sealants that may be useful for medical applications such as wound closure, supplementing or replacing sutures or staples in internal surgical procedures such as intestinal anastomosis and vascular anastomosis, tissue repair, preventing leakage of fluids such as blood, bile, gastrointestinal fluid and cerebrospinal fluid, ophthalmic procedures, drug delivery, and preventing post-surgical adhesions.Type: GrantFiled: July 1, 2010Date of Patent: November 12, 2013Assignee: Actamax Surgical Materials, LLCInventors: Helen S. M. Lu, Steven W. Shuey
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Patent number: 8580950Abstract: Novel aldehyde-functionalized polysaccharide compositions containing pendant dialdehyde groups are described that are more stable in aqueous solution than oxidized polysaccharides. The aldehyde-functionalized polysaccharides may be reacted with various amine-containing polymers to form hydrogel tissue adhesives and sealants that may be useful for medical applications such as wound closure, supplementing or replacing sutures or staples in internal surgical procedures such as intestinal anastomosis and vascular anastomosis, tissue repair, preventing leakage of fluids such as blood, bile, gastrointestinal fluid and cerebrospinal fluid, ophthalmic procedures, drug delivery, and preventing post-surgical adhesions.Type: GrantFiled: December 21, 2010Date of Patent: November 12, 2013Assignee: Actamax Surgical Materials, LLCInventors: Helen S. M. Lu, Steven W. Shuey
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Patent number: 8541571Abstract: The invention is directed to a simple and new method for the homogeneous synthesis of cellulose ethers. Ionic liquids are not only used as solvent, but also as reaction media for the homogeneous etherification of cellulose. The dissolved cellulose is treated with the etherification agent in the absence of organic and/or inorganic bases and in the absence and/or in the presence of moderate amounts of water. The obtained cellulose ethers show new distributions of substitution on the polymer chain, resulting in new properties and applications.Type: GrantFiled: February 25, 2009Date of Patent: September 24, 2013Assignee: SE Tylose GmbH & Co. KGInventors: Eugen Moellmann, Thomas Heinze, Tim Liebert, Sarah Koehler
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Patent number: 8138331Abstract: A description is given of glyoxal-treated polysaccharide derivatives which, to decrease the unbound glyoxal, are treated with an aqueous solution of one or more water-soluble aluminium salts, or one or more water-soluble borates, or a combination of one or more water-soluble aluminium salts and one or more water-soluble borates, and, if appropriate, with suitable buffer substances to set the pH, and then dried. A description is likewise given of a process for decreasing the content of unbound glyoxal in glyoxal-treated polysaccharide derivatives.Type: GrantFiled: November 1, 2006Date of Patent: March 20, 2012Assignee: Dow Global Technologies LLCInventors: Meinolf Brackhagen, Hartwig Schlesiger
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Patent number: 8133991Abstract: An allergen inactivating agent is provided which has no adverse effects on the human body and which does not cause problems such as color development.Type: GrantFiled: January 31, 2005Date of Patent: March 13, 2012Assignee: Kao CorporationInventors: Mami Nonomura, Kimihiko Hori, Hiroshi Nojiri, Hiroyuki Yanagida, Fumiko Okuda
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Patent number: 8093376Abstract: The present invention relates to a process of preparing hydroxyalkyl cellulose derivatives having improved enzymatic resistance. In particular, the present invention relates to a process of preparing hydroxyalkyl cellulose derivatives by reacting cellulose and ethylene oxide in the presence of alkali metal hydroxide, wherein the reaction between cellulose and ethylene oxide is performed in the presence of isopropyl alcohol azeotropic solvent in a horizontally agitated reactor, wherein the ethylene oxide is supplied via two steps, thus resulting in a two-step reaction, and the amount of alkali metal hydroxide remaining after the first reaction is controlled, thereby enabling to provide hydroxyalkyl cellulose derivatives having improved enzymatic resistance and turbidity and to remarkably decrease the solvent usage to have economical and environmental advantages.Type: GrantFiled: December 17, 2004Date of Patent: January 10, 2012Assignee: Samsung Fine Chemicals Co., Ltd.Inventors: Seok Soo Kim, Jung Ho So, Il Yong Lee, Hee Won Hwang
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Publication number: 20120004194Abstract: Novel aldehyde-functionalized polysaccharide compositions are described that are more stable in aqueous solution than oxidized polysaccharides or other types of polysaccharides containing pendant aldehyde groups. The aldehyde-functionalized polysaccharides may be reacted with various amine-containing polymers to form hydrogel tissue adhesives and sealants that may be useful for medical applications such as wound closure, supplementing or replacing sutures or staples in internal surgical procedures such as intestinal anastomosis and vascular anastomosis, tissue repair, preventing leakage of fluids such as blood, bile, gastrointestinal fluid and cerebrospinal fluid, ophthalmic procedures, drug delivery, and preventing post-surgical adhesions.Type: ApplicationFiled: July 1, 2010Publication date: January 5, 2012Applicant: E. I. DU PONT NEMOURS AND COMPANYInventors: Helen S.M. Lu, Steven W. Shuey
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Publication number: 20100331278Abstract: Described are an oral ingestion form comprising cationic hydroxyethylcellulose, and methods of using the same in prevention and treatment of metabolic disorders.Type: ApplicationFiled: May 6, 2010Publication date: December 30, 2010Inventors: W. H. Kerr Anderson, Shao-Ching Hung, William T. Stott, Maciej Turowski, Wallace H. Yokoyama, Scott A. Young
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Patent number: 7595391Abstract: This invention relates to methods of crosslinking polysaccharides to form crosslinked polysaccharides, and more particularly, to crosslinked polysaccharides that may be incorporated in fluids useful in, for example, applications requiring a crosslinked viscoelastic gel. In one embodiment, the present invention provides a method of crosslinking a polysaccharide comprising the steps of: providing a metal coordinating group having a reactive site, derivatizing a polysaccharide with the metal coordinating group to produce a derivatized polysaccharide having bidentate ligands, and crosslinking the derivatized polysaccharide having bidentate ligands with a metal ion to form a metal ligand coordination complex.Type: GrantFiled: November 20, 2003Date of Patent: September 29, 2009Assignee: Halliburton Energy Services, Inc.Inventors: Lewis R. Norman, Joseph R. Carlise, Javier Jesus Concepcion Corbea, William S. Rees, Jr., Marcus Weck
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Patent number: 7402668Abstract: A process of preparing alkylhydroxyalkylcellulose (e.g., methylhydroxyethylcellulose and methylhydroxypropylcellulose) by reaction of cellulose in the presence of alkali metal hydroxide with an alkylating agent and a hydroxyalkylating agent is described. The process includes: (a) alkalizing cellulose by means of 0.9 to 2.9 equivalents of an alkali metal hydroxide I/AGU of the cellulose in the form of an aqueous alkali metal hydroxide solution, in the presence of a suspension medium containing at least 0.2 equivalents of an alkylating agent I/AGU of the cellulose; (b) reacting the alkalized cellulose of step (a) with alkylating agent I and a hydroxyalkylating agent at a temperature above 65° C.Type: GrantFiled: July 17, 2002Date of Patent: July 22, 2008Assignee: Dow Wolff Cellulosics GmbHInventors: Wolfgang Dannhorn, Erik-Andreas Klohr, Martin Kowollik, Hartwig Schlesiger, Jörn-Bernd Pannek
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Patent number: 7351422Abstract: Proposed is a novel soluble trauma-healing and hemostatic cellulose fiber capable of absorbing and readily dissolving hemorrhaging trauma loci when applied thereto and of promoting the hemostatic action of blood platelets and fibrin and cell adhesion to the trauma site. The coagulation protein-containing soluble trauma-healing and hemostatic cellulose fiber is produced in that after treatment of a natural or regenerated cellulose fiber with an aqueous sodium hydroxide solution, said fiber is carboxymethylated by reaction with a monochloro acetic acid solution for a given time (hours) in such a manner that the degree of partial substitution of the glucose units constituting the cellulose molecule (etherification degree) is 0.5-less than 1.0% and that, furthermore, the coagulation proteins fibrinogen, thrombin, and coagulation factor XIII are imparted by surface application or chemical bonding.Type: GrantFiled: February 22, 2001Date of Patent: April 1, 2008Assignee: Hogy Medical Co., Ltd.Inventors: Yoshio Jo, Motonori Aoshima, Koji Tanabe, Koichi Matsushita, Toshiki Inoue
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Patent number: 7262181Abstract: The present invention relates to hemostatic materials made of water-soluble cellulose ether derivatives, such as methylcellulose, ethylcellulose, hydroxyethylcellulose, and pharmaceutically acceptable salts of carboxymethylcellulose, especially to hemostatic materials made of water-soluble cellulose ether derivatives capable of being absorbed in live body. The present invention also relates to the use of water-soluble cellulose hemostatic materials for the preparation of internal and external hemostatic articles and pharmaceutical compositions, and hemostatic articles and pharmaceutical compositions thereof.Type: GrantFiled: April 30, 2001Date of Patent: August 28, 2007Assignee: Beijing Textile Research InstituteInventors: Mei Zhang, Jinyu Zhang, Xia Song
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Patent number: 7049436Abstract: Alcohol based hydraulic fracturing fluids useful for treating oil and gas wells are disclosed. The fluids are compatible with carbon dioxide, and comprise an alcohol, a polymer, a crosslinking agent, and a breaker. Hydroxypropyl guar with a molar substitution of about 1.2 to about 2.2 is identified as a presently preferred polymer.Type: GrantFiled: October 9, 2002Date of Patent: May 23, 2006Assignee: BJ Services CompanyInventors: D. V. Satyanarayana Gupta, Greg Niechwiadowicz, Anita C Jerat
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Patent number: 7005515Abstract: The process for preparing an alkyl hydroxyalkyl cellulose ether comprises the steps of: a) alkalizing cellulose to obtain alkali cellulose, b) reacting alkali cellulose with an alkyl halogenide until an alkyl cellulose ether with a D.S.(alkyl) value of from 0.7 to 2.5. is attained, c) removing excess alkyl halogenide from the reaction mixture, and d) reacting the alkyl cellulose ether with an alkylene oxide in a liquid suspending agent to produce an alkyl hydroxyalkyl cellulose ether. An alkyl hydroxyalkyl cellulose ether is produced which has an D.S.(alkyl) of from 0.7 to 2.5 and an MS (hydroxyalkyl) from 0.03 to 2.0, wherein not more that 15 percent of the hydroxyalkyl groups are capped with an alkyl group.Type: GrantFiled: March 4, 2002Date of Patent: February 28, 2006Assignee: Dow Global Technologies Inc.Inventors: Hans P. Schneider, Wolfgang H. Beer, Stephen J. Merryweather
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Cellulose derivatives having gel-like rheological properties and process for the preparation thereof
Patent number: 6958393Abstract: A description is given of cellulose derivatives having gel-like rheological properties in aqueous solution characterized in that: a) cellulose is alkalized with aqueous alkali metal hydroxide solution in the presence of a suspension medium, b) the alkalized cellulose is reacted with one or more alkylene oxides, c) then reacted with an alkyl halide present in the suspension medium d) subsequently or simultaneously the alkalized cellulose is reacted with a crosslinking agent in an amount of 0.0001 to 0.05 eq, where the unit “eq” represents the molar ratio of crosslinking agent relative to the anhydroglucose unit (AGU) of the cellulose used, and e) after, if appropriate, further addition of alkali metal hydroxide and/or alkylating agent, the resultant irreversibly crosslinked cellulose derivative is separated off from the reaction mixture, if appropriate purified and dried.Type: GrantFiled: July 23, 2003Date of Patent: October 25, 2005Assignee: Wolff Cellulosics GmbH & Co. KGInventors: Hartwig Schlesiger, Arne Henning Kull, Erik-Andreas Klohr -
Patent number: 6939961Abstract: A process for preparing low-viscosity water-soluble cellulose ethers by the oxidative decomposition of higher-viscosity cellulose ethers with hydrogen peroxide is described. The process involves: (a) forming, under conditions of intensive mixing and at temperatures of 65-125° C., a mixture of, (i) one or more higher-viscosity cellulose ethers, and (ii) an aqueous solution of hydrogen peroxide, the proportions of the mixture being selected in such a way that the hydrogen peroxide content is 0.1-10 wt. % in relation to the dry cellulose ether, the solids content of the mixture is at least 25 wt. % in relation to the total weight of the mixture; and (b) agitating continuously the mixture of step (a) at temperatures of 65-125° C. until at least approximately 90% of the hydrogen peroxide has been spent.Type: GrantFiled: November 15, 1999Date of Patent: September 6, 2005Assignee: Wolf Walsrode AGInventor: Hartwig Schlesiger
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Patent number: 6891034Abstract: Described is a process of preparing alkylhydroxyalkyl cellulose, e.g., methylhydroxypropyl cellulose (MHPC). The process includes: (a) alkylating cellulose with an aqueous caustic solution containing from 1.5 to 5.5 equivalents of alkali metal hydroxide, e.g., NaOH, per anhydroglucose unit (AGU) of said cellulose, in the presence of a suspension agent, e.g., dimethyl ether, which contains alkyl halide, e.g., methyl chloride, in an amount of from (equivalents of alkali metal hydroxide per AGU minus 1.4) to (equivalents of alkali metal hydroxide per AGU plus 0.8); (b) reacting the alkalised cellulose of step (a) with one or more alkylene oxides, e.g., propylene oxide, at a temperature higher than 65° C., e.g., 85° C.Type: GrantFiled: August 3, 2001Date of Patent: May 10, 2005Assignee: Wolff Walsrode AGInventors: Wolfgang Dannhorn, Hartwig Schlesiger, Jörn-Bernd Pannek, Gerolf Weissach
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Patent number: 6849729Abstract: Provided is a cellulose polymer having a water retention property, and good feeling upon use when applied to the skin and being suitably used as a carrier. More specifically, provided is a low-substituted cellulose ether powder comprising primary particles wherein at least 95% by weight of the primary particles have an aspect ratio of 1.0 to 1.5. Also provided is a production process of a low-substituted cellulose ether powder having a molar substitution degree of 0.05 to 1.0, comprising, during or after the addition of an acid to an alkali solution of low-substituted cellulose ether to neutralize the solution, triturating a resulting mixture; and spray-drying a resulting dispersion. Further provided is a production process of a low-substituted cellulose ether powder having a molar substitution degree of 0.05 to 1.0, comprising shear-triturating a low-substituted cellulose ether powder in water so as to swell-disperse the powder and spray-drying a resulting dispersion.Type: GrantFiled: February 27, 2003Date of Patent: February 1, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Sakae Obara
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Patent number: 6843845Abstract: An admixture comprising (A) a nonionic water-soluble hydroxyethyl cellulose and/or hydroxyethyl ethyl cellulose having a viscosity of at least 500 mPa·s as measured in a 1 wt % aqueous solution at 20° C., and (B) another nonionic water-soluble cellulose ether having a viscosity of at least 1,500 mPa·s as measured in a 1 wt % aqueous solution at 20° C. is suited for use in extrudable hydraulic compositions, because the hydraulic compositions comprising the admixture are effectively extrudable into hardened products having improved surface properties, minimized spring-back and good dimensional accuracy.Type: GrantFiled: March 11, 2003Date of Patent: January 18, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yoshiaki Sasage, Tsutomu Yamakawa
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Cellulose derivatives having gel-like rheological properties and process for the preparation thereof
Publication number: 20040127700Abstract: A description is given of cellulose derivatives having gel-like rheological properties in aqueous solution characterized in that:Type: ApplicationFiled: July 23, 2003Publication date: July 1, 2004Inventors: Hartwig Schlesiger, Arne Henning Kull, Erik-Andreas Klohr -
Patent number: 6730636Abstract: Environmentally acceptable well cement fluid loss control additives, cement compositions including the additives and methods of using the compositions are provided. The environmentally acceptable fluid loss control additives are comprised of ethoxylated hydroxyethylcellulose having a reduced molecular weight.Type: GrantFiled: April 30, 2002Date of Patent: May 4, 2004Assignee: Halliburton Energy Services, Inc.Inventors: Jan Pieter Vijn, Bach Dao, Mohand Melbouci
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Patent number: 6703497Abstract: The invention concerns cellulose microfibrils with modified surface, characterised in that the hydroxyl functions present at the surface of the microfibrils are etherified with at least an organic compound comprising at least a function capable of reacting with said hydroxyl functions, and the degree of surface substitution (DSs) is at least 0.05. The invention also concerns a method for obtaining said microfibrils and their use as agent for modifying viscosity, texture and/or as reinforcing filler.Type: GrantFiled: June 25, 2001Date of Patent: March 9, 2004Assignee: Rhodia ChimieInventors: Laurence Ladouce, Etienne Fleury, Cécile Gousse, Robert Cantiani, Henri Chanzy, Gérard Excoffier
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Patent number: 6669863Abstract: An anionic cellulose ether obtainable by a process comprising reacting an alkali metal cellulose with one or more reagents A selected from the group consisting of haloacetic acids, alkali metal haloacetates, alkali metal vinyl sulfonates, vinyl sulfonic acid, and precursors thereof, and one or more reagents B having the formula R1—(OCH2CH(R2))n-P, wherein R2 represents hydrogen or a methyl group; n is 0-2; P represents a glycidyl ether group, a 1,2-epoxy group or a precursor thereof, if P represents a glycidyl ether group, R1 represents a linear C3-C5 alkyl group, optionally containing an oxygen atom, a phenyl group, or a benzyl group, and if P represents a 1,2-epoxy group, R1 represents a linear C3-C5 alkyl group, optionally containing an oxygen atom. Preferably, reagent A is chloroacetic acid and reagent B is n-butyl glycidyl ether. The invention also relates to the use of said anionic cellulose ether as an associative thickener, rheology modifier or stabilizer.Type: GrantFiled: August 31, 2001Date of Patent: December 30, 2003Assignee: Akzo Nobel N.V.Inventors: Berend Jan Dijk, Jan Gerardus Batelaan
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Patent number: 6639066Abstract: This invention relates to a suspension of a water-soluble, nonionic cellulose ether having a fairly low content of an electrolytic salt exhibiting a high stability and a low viscosity. The suspension having a pH-value of below 8.0, contains 10-30% by weight of a water-soluble, nonionic cellulose ether, and 10-22% by weight of an electrolytic salt, wherein the electrolytic salt contains a) 10-90% by weight of a salt of polyphosphate having 3-12 phosphate groups, and b) 10-90% by weight of a salt selected from the group consisting of ortophosphate, pyrophosphate, sulphate, carbonate and a mixture thereof. The suspension is advantageously produced by adding a dry blend containing the water-soluble cellulose ether in cross-linked form and the electrolytic salt to water.Type: GrantFiled: December 12, 2001Date of Patent: October 28, 2003Assignee: Akzo Nobel N.V.Inventors: Peter Boström, Gunvor Karlsson
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Patent number: 6602994Abstract: A method for producing derivatized microfibrillar polysaccharide, including but not limited to cellulose, derivatized by steric and/or electrostatic forces, where the electrostatic forces are provided by anionic charge or by a combination of both anionic and cationic charge, by stabilizing and/or microfibrillating a polysaccharide starting material. A method of modifying the rheological properties of a composition of matter using derivatized microfibrillar polysaccharide. Method of improving coatings, paper manufacture, and the stability of emulsions, dispersions, and foams using a derivatized microfibrillar polysaccharide. Compositions that include derivatized microfibrillar polysaccharide, including paper compositions, comestible compositions, non-comestible spreadable compositions, and emulsions, dispersion, and foams.Type: GrantFiled: February 10, 1999Date of Patent: August 5, 2003Assignee: Hercules IncorporatedInventors: Mary Jean Cash, Anita N. Chan, Herbert Thompson Conner, Patrick Joseph Cowan, Robert Alan Gelman, Kate Marritt Lusvardi, Samuel Anthony Thompson, Frank Peine Tise
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Patent number: 6593468Abstract: This invention relates to a process for producing a substantially fiber-free carboxymethyl cellulose which predominantly exhibits elastic properties, to the use thereof as a superabsorbent material, and to the use thereof as an adjuvant substance for achieving suitable rheological and water retention properties for the cosmetics, pharmaceutical and food sectors, and for industrial applications, e.g. as an additive for coating materials, for the sealing of cables and for use in tunnelling and in civil and underground engineering.Type: GrantFiled: April 17, 2000Date of Patent: July 15, 2003Assignee: Wolff-Walsrode AGInventors: Werner Lange, Bernd Schriewer, Friedrich-Karl Lampert, Wilhelm Oppermann, Jörn-Bernd Pannek, René Kiesewetter
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Patent number: 6559300Abstract: A water-soluble, biodegradable hydroxyalkyl cellulose-2-hydroxycarboxylic acid ester is disclosed. The hydroxyalkyl cellulose-2-hydroxycarboxylic acid ester has: (i) a molecular degree of substitution of the hydroxyalkyl group of less than 1.5 (MShydroxyalkyl<1.5); and (ii) a molecular degree of substitution of the 2-hydroxycarboxylic acid group of greater than 0.4 and less than 3 (0.4<MS2-hydroxycarboxylic acid<3). Also described is a method of preparing the hydroxyalkyl cellulose-2-hydroxycarboxylic acid ester, and methods of using it, e.g., as a consistency regulator in at least one of foodstuffs, cosmetics, building materials, paints and strippers.Type: GrantFiled: January 11, 2000Date of Patent: May 6, 2003Assignee: Wolff Walsrode AGInventors: Joachim Simon, Hanns-Peter Müller, Rainhard Koch, Volkhard Müller, Jürgen Engelhardt, Klaus Szablikowski, Wolfgang Koch
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Patent number: 6482876Abstract: The invention relates to an agglomerate containing at least one of the following water-soluble or water-dispersible materials as a bonding base polymer: carboxylized and/or alkoxylized starch, cellulose ether and fully synthetic vinyl polymers and/or polyacrylates. The agglomerate is characterized in that it contains a blasting agent which produces a high swelling pressure, but, advantageously, does not gel. The agglomerate can have a regular geometric form or not. Its weight should be between 0.5 and 500 g. The agglomerate is used in particular in the production of lump-free paste.Type: GrantFiled: March 15, 2000Date of Patent: November 19, 2002Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Sandra Witt-Nuesslein, Werner Haller, Bernhard Schoettmer, Monika Boecker, Wolfgang Seiter, Ingo Hardacker, Heinz-Peter Hoffmann
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Patent number: 6469608Abstract: A stick-type ignition coil device has a central core, and primary and secondary windings wound concentrically around the central core in a coil casing. A positioning part is provided in the casing to define the position of the central core. An insulating resin such as epoxy resin is filled in the coil casing for electrical insulation and fixing of components in the coil casing. A thermal stress releasing member, which is less adhesive to and easily peelable from the insulating resin, is provided on the upper surface of the positioning part. The thermal stress releasing member is separated from the insulating resin and allows the positioning member to move with the central core, thereby minimizing cracks which will occur in the insulating resin formed between the central core and the positioning part.Type: GrantFiled: December 22, 2000Date of Patent: October 22, 2002Assignees: Denso Corporation, Toyo Denso Kabushiki KaishaInventors: Yoshihiro Shimoide, Toshiyuki Shinozawa, Shuichi Matsubayashi
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Publication number: 20020103368Abstract: The present inventors have discovered that the solution rheology of cellulose ethers prepared from cellulose pulp is altered by mercerizing and recovering cellulose pulp before preparing the cellulose ethers. For example, the solution viscosity of carboxymethyl cellulose (CMC) produced from mercerized and recovered cellulose pulp is significantly greater than that produced from non-mercerized cellulose pulp. The present invention provides a method of preparing cellulose ethers comprising the steps of (a) obtaining mercerized and recovered cellulose pulp, and (b) converting the mercerized and recovered cellulose pulp into the cellulose ethers. According to one embodiment, the cellulose pulp is southern softwood kraft and the mercerized cellulose pulp has a TAPPI 230 om-89 viscosity of at most 12 cP. This method, however, may be applied to all cellulose pulps, regardless of their viscosities, including those which, when mercerized, have a viscosity greater than 12 cP.Type: ApplicationFiled: October 31, 2001Publication date: August 1, 2002Applicant: BKI HOLDING CORPORATIONInventors: Roger Bruce Harding, Susan L. H. Crenshaw, Paul Eugene Gregory, Denise Hartnett Broughton
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Patent number: 6380381Abstract: The present invention provides low-substituted hydroxypropyl cellulose exhibiting good granulation characteristics and tablet properties. Specifically, there is provided low-substituted hydroxypropyl cellulose having a hydroxypropoxyl content in the range of 5.0 to 16.0% by weight and an apparent average degree of polymerization in the range of 350 to 700.Type: GrantFiled: May 17, 2000Date of Patent: April 30, 2002Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Sakae Obara
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Patent number: 6372902Abstract: Polysaccharides, including hydroxyethyl cellulose, having alkyl-aryl hydrophobic substitution, provide latex compositions, such as paints, with improved rheology and stability. Improved processes for producing such polysaccharides are also provided.Type: GrantFiled: December 23, 1994Date of Patent: April 16, 2002Assignee: Union Carbide CorporationInventors: Emmett Malone Partain, III, George Lewis Brode, II, Richard Charles Hoy
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Patent number: 6372901Abstract: Polysaccharides, including hydroxyethyl cellulose, having alkyl-aryl hydrophobic substitution, provide latex compositions, such as paints, with improved rheology and stability. Improved processes for producing such polysaccharides are also provided.Type: GrantFiled: June 7, 1995Date of Patent: April 16, 2002Assignee: Union Carbide CorporationInventors: Emmett Malone Partain, III, George Lewis Brode, II, Richard Charles Hoy
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Patent number: 6320043Abstract: The invention relates to a new, particularly economic process for preparing pulverulent polysaccharide derivatives, in particular cellulose derivatives, having a thermal flocculation point; the process comprises soaking or dissolving the polysaccharide derivative in a solvent or mixed solvent, dividing/comminuting the soaked or dissolved polysaccharide derivative by thermal and/or mechanical liquid separation and an optional drying step.Type: GrantFiled: July 8, 1999Date of Patent: November 20, 2001Assignee: Wolf Walsrode AGInventors: Gunter Weber, Detmar Redeker, Bernd Klinksiek, Jürgen Hinderer, Benno Ulfik
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Patent number: 6261218Abstract: There is a process for making a cellulose ether. The process comprises the following: a) alkalyzing a cellulose pulp; b) etherifying the alkalyzed cellulose pulp to form a cellulose ether; c) washing the cellulose ether; d) drying the cellulose ether; e) milling the cellulose ether to a particulate form; f) heating the particulate cellulose ether; g) tumbling the particulate cellulose ether while simultaneously contacting it with an acid to partially depolymerize it to a lower molecular weight; h) partially or substantially neutralizing the acid. There is also an apparatus for making the cellulose ether.Type: GrantFiled: December 1, 1998Date of Patent: July 17, 2001Assignee: The Dow Chemical CompanyInventor: Gary J. Schulz
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Patent number: 6248880Abstract: The present invention relates to associative cellulose ethers with improved thickening effects, especially in paint. The improvement depends on the presence of a hydrophobic modifying group of the general formula where R is an aliphatic group of 12-22 carbon atoms and n is a number from 3 to 7. The DS of the hydrophobic group is 0.003 to 0.012.Type: GrantFiled: July 19, 1999Date of Patent: June 19, 2001Assignee: Akzo Nobel NVInventor: Leif Karlson
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Patent number: 6201070Abstract: Methods are disclosed for enhancing the toughness, e.g., resistance to cracking upon flexation, of coatings made from cycloaliphatic epoxide derivatives wherein the cycloaliphatic epoxide derivative is a cycloaliphatic epoxide ester of a hydroxy-functional compound containing at least one branched, 1,2-alkylene oxide unit. Processes for making the cycloaliphatic epoxide derivatives and coating formulations comprising the cycloaliphatic epoxide derivatives are also disclosed.Type: GrantFiled: November 20, 1996Date of Patent: March 13, 2001Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Naofumi Kumabe, Thomas Andrew Upshaw, Robert Francis Eaton, Bharat Kanaiyalal Patel, John Kellis Braddock
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Patent number: 6166119Abstract: A cement pumpability-enhancing additive which confers good pumpability on cementitious compositions such as concrete consists essentially of(a) polyethylene glycol;(b) diethylene glycol monobutyl ether and/or a derivative thereof;(c) polysaccharide; and(d) a thickening polymer selected from the group consisting of polyacrylic acid derivatives, polyacrylic amide derivatives, cellulose ethers, polyphenyl ethers and polyalkylene glycol fatty acid esters;the weight solids proportions of (a), (b), (c), and (d) in the additive being respectively 5-55%, 10-80%, 1-20% and 1-20%. The additive is preferably used with a cement dispersing agent.Type: GrantFiled: April 14, 1999Date of Patent: December 26, 2000Assignee: MBT Holding AGInventors: Shigemi Matsuo, Hidenori Nagamine, Akira Ota
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Cellulose ethers containing butenyl groups and use thereof as protective colloids in polymerizations
Patent number: 6111011Abstract: Water-soluble, nonionic cellulose ethers selected from the group consisting of alkylcelluloses and hydroxyalkylcelluloses which are additionally substituted by butenyl groups are used as protective colloids in the preparation of aqueous polymer dispersions.Type: GrantFiled: November 19, 1998Date of Patent: August 29, 2000Assignee: Clariant GmbHInventors: Reinhard Doenges, Rudolf Ehrler, Horst Wurm -
Patent number: 6068697Abstract: A polysaccharide derivative prepared by replacing all or part of the hydroxyl hydrogen atoms of a polysaccharide or polysaccharide derivative by (A) a hydrophobic substituent having a C.sub.8 -C.sub.43 hydrocarbon chain as the partial structure and (B) an ionic hydrophilic substituent having at least one member selected from the group consisting of sulfonic, carboxyl phosphoric, and sulfate groups and salts thereof as the partial structure, wherein the average degree of replacement by the substituent (A) is 0.0001 or above but below 0.001 per constituent monosaccharide residue as determined by Zeisel's method or the diazomethane method and that by the substituent (B) is 0.01 to 2.0 per constituent monosaccharide residue as determined by colloidal titration. This polysaccharide derivative is useful as the admixture for hydraulic materials and can give stable hydraulic compositions excellent in dispersion.Type: GrantFiled: July 14, 1998Date of Patent: May 30, 2000Assignee: Kao CorporationInventors: Hotaka Yamamuro, Takeshi Ihara, Tomohito Kitsuki, Tetsuya Miyajima, Fujio Yamato, Makoto Kohama
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Patent number: 5898072Abstract: The invention concerns an aqueous suspension of a non-ionic, water-soluble cellulose ether cross-linked with glyoxal, in the presence of an electrolytic salt which gives a pH value below 8.0 in water and at the concentration involved. Conveniently, the suspension is produced by mixing the water included with a dry blend containing the cellulose ether and the electrolytic salt, and preferably the other components of the suspension as well.Type: GrantFiled: October 29, 1996Date of Patent: April 27, 1999Assignee: Akzo Nobel nvInventors: Peter Bostrom, Lars Andersson
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Patent number: 5837864Abstract: In a method of producing a suspension of a nonionic cellulose ether that has no turbidity point, the water forming part of the suspension is mixed with a dry mixture containing a cellulose ether, which is cross-linked with glyoxal, and an electrolyte salt. This electrolyte salt consists of a salt of a mixture of salts which, in water and at the concentration employed, results in a pH value below 8.0. Preferably, the cellulose ether is a hydroxyethylcellulose.Type: GrantFiled: June 10, 1997Date of Patent: November 17, 1998Assignee: Akzo Nobel NVInventors: Lars Andersson, Peter Bostrom
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Patent number: 5827835Abstract: Thermally gelling emulsion compositions which reversibly increase in either loss modulus or storage modulus, or both, upon contact with the eye, skin, mucous membrane or body cavity are disclosed. The emulsion compositions contain one or more nonionic substituted cellulose ethers and do not require a charged surfactant or a pH-sensitive polymer for such increase in loss modulus or storage modulus, or both, upon administration. In one embodiment, the compositions gel upon instillation in the eye.Type: GrantFiled: December 3, 1996Date of Patent: October 27, 1998Assignee: Alcon Laboratories, Inc.Inventor: Bhagwati P. Kabra
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Patent number: 5808052Abstract: The present invention relates to water-soluble, particularly ternary, preferably ionic, cellulose mixed ethers, more particularly to anionic water-soluble cellulose mixed ethers, as additives for drilling fluid applications.Type: GrantFiled: June 10, 1996Date of Patent: September 15, 1998Assignee: Wolff Walsrode AGInventors: Klaus Szablikowski, Werner Lange, Jorn-Bernd Pannek, Rene Kiesewetter
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Patent number: 5804166Abstract: Disclosed are hair spray compositions containing non-ionic cellulosic ethers in a solvent base containing water and volatile organic solvent wherein the level of volatile organic solvent in the composition is about 80% or less, and wherein the non-ionic cellulose ether is characterized by a solution viscosity of less than about 50 cps at 25.degree. C. for an aqueous solution containing 3 wt. % solids and 55 wt. % ethanol. The preferred non-ionic cellulosic ether is methylhydroxypropyl cellulose.Type: GrantFiled: May 9, 1997Date of Patent: September 8, 1998Assignee: Hercules IncorporatedInventors: Anita N. Chan, Anthony B. Clayton, Jashawant J. Modi