Phosphorus Containing Patents (Class 544/195)
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Patent number: 4623642Abstract: N-phosphoryl- or N-thiophosphoryl-N'-s-triazinylformamidines of the formula ##STR1## wherein R.sub.1 and R.sub.2 independently of one another are each C.sub.1 -C.sub.20 -alkyl, or phenyl unsubstituted or substituted by halogen atoms,R.sub.3 is C.sub.1 -C.sub.6 -alkyl or C.sub.3 -C.sub.6 -cycloalkyl,R.sub.4 is hydrogen, C.sub.1 -C.sub.6 -alkyl or C.sub.3 -C.sub.6 -cycloalkyl, andX and Y are each oxygen or sulfur.A process for producing these triazines and their use for controlling pests are described.Type: GrantFiled: December 12, 1985Date of Patent: November 18, 1986Assignee: Ciba-Geigy CorporationInventors: Odd Kristiansen, Jozef Drabek, Victor Fluck
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Patent number: 4610824Abstract: Antibacterial activity is exhibited by novel compounds having the formula ##STR1## and pharmaceutically acceptable salts thereof.Type: GrantFiled: October 9, 1984Date of Patent: September 9, 1986Assignee: E. R. Squibb & Sons, Inc.Inventor: Uwe D. Truner
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Patent number: 4602938Abstract: Guanidine derivatives of the formula ##STR1## in which R.sup.2 represents a six-membered aromatic heterocyclic structure which contains at least one nitrogen atom and is substituted by halogen, amino, cyano or formyl and/or by optionally substituted radicals from the series comprising alkyl, alkoxy, alkylamino, dialkylamino, alkylcarbonyl and alkoxycarbonyl, and/or is optionally fused,R.sup.3 represents hydrogen, an optionally substituted radical from the series comprising alkyl, cycloalkyl, alkenyl, alkinyl and aralkyl, or the radical --S(O).sub.n --R.sup.6,the other radicals can have varied meanings, andacid adducts and salts thereof,which possess herbicidal and plant growth regulating activity.Type: GrantFiled: February 9, 1984Date of Patent: July 29, 1986Assignee: Bayer AktiengesellschaftInventors: Koichi Moriya, Theodor Pfister, Hans-Jochem Riebel, Ludwig Eue, Robert R. Schmidt, Klaus Lurssen
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Patent number: 4559078Abstract: Phosphorus-containing N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'-triazinylureas of the formula ##STR1## and the salts of these compounds with amines, alkali or alkaline earth metal bases or quaternary ammonium bases have good pre-emergence and post-emergence selective herbicidal and growth-regulating properties.In this formula, X is a group ##STR2## Y is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, trifluoromethyl, C.sub.2 -C.sub.5, alkenyl, C.sub.2 -C.sub.5 -alkynyl, nitro, --COOR.sup.6 or --Q--R.sup.6, Z is nitrogen or the methine group, E is oxygen or sulfur, R.sup.1 is hydrogen or C.sub.1 -C.sub.5 -alkyl and R.sup.2 and R.sup.3 independently of one another are C.sub.1 -C.sub.3 -alkyl, C.sub.1 -C.sub.3 -alkoxy, C.sub.1 -C.sub.3 -halogenoalkyl, C.sub.1 -C.sub.3 -halogenoalkoxy, cyclopropyl, amino, methylamino or dimethylamino, and A is oxygen, sulfur, C.sub.1 -C.sub.5 -alkylene, C.sub.2 -C.sub.5 -alkenylene, C.sub.1 -C.sub.5 -halogenoalkylene or --NR.sup.7 --(CH.sub.2).sub.m --; --CH.sub.Type: GrantFiled: December 19, 1983Date of Patent: December 17, 1985Assignee: Ciba-Geigy CorporationInventors: Ludwig Maier, Willy Meyer, Konrad Oertle, Achim Roloff, Werner Topfl
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Patent number: 4539314Abstract: N-Phosphoryl- or thiophosphoryl-N'-s-triazinylformamidines of the formula ##STR1## wherein R.sub.1 and R.sub.2 independently of one another are each C.sub.1 -C.sub.20 -alkyl, or phenyl unsubstituted or substituted by halogen, andX and Y are each oxygen or sulfur.A process for producing these triazines and their use for controlling pests are described.Type: GrantFiled: June 1, 1984Date of Patent: September 3, 1985Assignee: Ciba-Geigy CorporationInventors: Odd Kristiansen, Jozef Drabek, Victor Fluck
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Patent number: 4496726Abstract: Hitherto unknown polyalkylpiperidinylaminotriazines having a structure of the type ##STR1## are obtained from halogenotriazinyl compounds and aminoethylaminoethanols and can be converted into further derivatives with isocyanates, esters and acid chlorides to give new stabilizers for polymers, which stabilizers are distinguished by very good migration resistance.Type: GrantFiled: August 2, 1982Date of Patent: January 29, 1985Inventors: Hartmut Wiezer, Gerhard Pfahler
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Patent number: 4491644Abstract: A flame-retarded polymer composition wherein the polymer constituent is an olefin polymer, a polymethyl acrylate or methacrylate, or polystyrene. The polymer is rendered flame-retardant by the presence of an amino-s-triazine salt of bis-(pentaerythritol phosphate) phosphoric acid.Type: GrantFiled: May 23, 1983Date of Patent: January 1, 1985Assignee: Borg-Warner Chemicals, Inc.Inventors: Yuval Halpern, Donna M. Mott
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Patent number: 4480093Abstract: Amino-s-triazine salts of bis-(pentaerythritol phosphate) phosphoric acid. The salts are effective flame-retardant additives in a number of different types of polymers.Type: GrantFiled: May 23, 1983Date of Patent: October 30, 1984Assignee: Borg-Warner Chemicals, Inc.Inventors: Yuval Halpern, Donna M. Mott
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Patent number: 4478998Abstract: A process for preparing amino-s-triazine salts of bis-(pentaerythritol phosphate) phosphoric acid. The process involves reacting the particular amine with the corresponding acid chloride, i.e., the phosphorous oxychloride, in the presence of water. The salts are effective flame-retardants in a number of different types of polymers.Type: GrantFiled: May 23, 1983Date of Patent: October 23, 1984Assignee: Borg-Warner Chemicals, Inc.Inventors: Yuval Halpern, Donna M. Mott, Ron H. Niswander
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Patent number: 4451400Abstract: Halogenophosphazenes of the formula ##STR1## in which n denotes 3 to 100, are reacted with alcohols or amines having polyalkylpiperidyl groups to give compounds which are suitable for stabilizing synthetic polymers and are distinguished by a very high migration resistance.Type: GrantFiled: May 7, 1982Date of Patent: May 29, 1984Assignee: Hoechst AktiengesellschaftInventor: Hartmut Wiezer
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Patent number: 4413999Abstract: The invention provides amidoxime derivatives of the general formula ##STR1## wherein R.sub.1 is an alkyl group of 1 to 8 carbon atoms, phenyl, a heterocyclic ring structure of 5 to 8 atoms containing one or more nitrogen or oxygen atoms or combinations thereof or a bicyclic condensed ring system optionally containing at least one heterocyclic ring which groups may each be optionally substituted. R.sub.2 is a mono or bicyclic heterocyclic radical containing at least two nitrogen atoms which radical is also optionally substituted. R.sub.3 and R.sub.4 are independently H, or an alkyl of 1 to 4 carbon atoms or one, but not both, is ##STR2## and the other, H, wherein R.sub.5 or R.sub.6 are alkyls of 2 to 5 carbon atoms optionally substituted by R.sub.1, or a phenyl optionally substituted by R.sub.1 or R.sub.5 or R.sub.6 is combined with R.sub.1 to jointly form cyclic imidoximes or imidedioximes.Type: GrantFiled: March 5, 1982Date of Patent: November 8, 1983Assignee: Research Products Rehovot Ltd.Inventors: Charles Linder, Gershon Aviv
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Patent number: 4373103Abstract: Dibromoneopentyl phosphate melamine salt is a novel flame retardant suitable for plastics, textiles and fabric backcoatings. The dibromoneopentyl phosphate melamine salt is prepared by the reaction of dibromoneopentyl phosphoric acid with melamine.Type: GrantFiled: May 5, 1980Date of Patent: February 8, 1983Assignee: Stauffer Chemical CompanyInventors: Alfred K. Jung, Joseph Silberberg, Edward D. Weil
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Patent number: 4328132Abstract: Undesirable color formation during the preparation of a cured intumescent flame retardant is minimized by including a color stabilizing amount of at least one of certain metal phosphites, hypophosphites, sulfites and bisulfites.Type: GrantFiled: March 6, 1979Date of Patent: May 4, 1982Assignee: Phillips Petroleum CompanyInventor: Charles W. Moberly
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Patent number: 4305949Abstract: A series of N-(2-thiazolyl)amides has been prepared, including their pharmaceutically acceptable acid addition salts as well as pharmaceutical compositions containing same. These compounds are useful in therapy as anti-inflammatory agents in addition to being useful as immunoregulatory agents for modulating various body immune responses. Preferred member compounds include N-(2-thiazolyl)-.alpha.-methylaminoacetamide, N-(2-thiazolyl)-.alpha.-benzylaminoacetamide, N-(2-thiazolyl)-.alpha.-(p-fluorobenzylamino)acetamide, N-(2-thiazolyl)-.alpha.-(2-thenylamino)acetamide and N-(4-methyl-2-thiazolyl)-.alpha.-amino-.beta.-phenylpropionamide, and their hydrohalide acid addition salts. Three different methods of preparation are provided and these are all described in some detail, including the various synthetic routes leading to the required novel intermediates and/or starting materials.Type: GrantFiled: January 29, 1980Date of Patent: December 15, 1981Assignee: Pfizer Inc.Inventors: Charles A. Harbert, Joseph G. Lombardino
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Patent number: 4303652Abstract: Organophosphorus esters, useful in increasing the resistance of keratinous materials to attack by keratin-eating insects, have the general formula: ##STR1## wherein: X and Y are independently O or S;R.sub.1 is an alkyl, alkoxy, alkylamino, dialkylamino or alkylmercapto radical having 1 to 6 carbon atoms;an amino or aryl radical;R.sub.2 is an alkyl radical having 1 to 6 carbon atoms;R.sub.3 is a radical of the general formula:-J-(K-L).sub.n (2)wherein:J is an aliphatic radical, or radical containing an aromatic or heterocyclic ring;K is one of the following radicals: ##STR2## linked to J through the oxygen atom in the case of (3), (5) or (6), and through the nitrogen atom in the case of (4), and in which the carbonyl oxygen atom of (3), (4) or (5), or one or both carbonyl oxygen atoms of (6) may be replaced by sulphur; R.sub.Type: GrantFiled: August 30, 1978Date of Patent: December 1, 1981Assignee: Commonwealth Scientific and Industrial Research OrganizationInventors: Francis W. Jones, Robert J. Mayfield, Gary J. O'Loughlin
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Patent number: 4297492Abstract: Novel oligomeric and polymeric phenolic 1,3,5-triazines, for example those of the formula ##STR1## their preparation and their use for stabilizing organic material and also the organic material protected against oxidative and light-induced degradation with the aid of these compounds.Type: GrantFiled: March 10, 1980Date of Patent: October 27, 1981Assignee: Ciba-Geigy CorporationInventors: Michael Rasberger, Siegfried Rosenberger, Samuel Evans
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Patent number: 4265806Abstract: A process for producing a solid, intumescent, phosphorus-containing flame retardant for thermoplastic synthetic resins, comprises evaporating to dryness the reaction product of (a) 1 mole of phosphoric acid, phosphorous acid or polyphosphoric acid, (b) 0.5-2 moles of ethylene oxide or glycol, and (c) 0.2-1 mole of melamine, and tempering the thus-obtained solid at 100.degree.-250.degree. C. The product so obtained can be added to such resins to render them flameproof without deleterious side effects such as discoloration.Type: GrantFiled: July 11, 1980Date of Patent: May 5, 1981Assignee: Chemische Werke Huls AktiengesellschaftInventors: Raban Grundmann, Gunther Maahs
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Patent number: 4201705Abstract: Polyolefin compositions comprising a polyolefin and a flame retarding amount of the pentate salt of an amino-s-triazine are intumescent and self-extinguishing and non-dripping.Type: GrantFiled: August 28, 1978Date of Patent: May 6, 1980Assignee: Borg-Warner CorporationInventors: Yuval Halpern, Clifton T. Fleenor
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Patent number: 4161592Abstract: New 1,3,5-triazines containing at least one hindered phenolic moiety and at least one hindered amine moiety are useful light stabilizers and antioxidants for polymeric materials.Type: GrantFiled: July 1, 1977Date of Patent: July 17, 1979Assignee: Ciba-Geigy CorporationInventors: Samuel Evans, Michael Rasberger
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Patent number: 4154930Abstract: Pentate salts of amino-s-triazines having the formula ##STR1## wherein x is -NH.sub.2 or -OH are useful as flame retardants and foaming agents for polymers.Type: GrantFiled: August 28, 1978Date of Patent: May 15, 1979Assignee: Borg-Warner CorporationInventor: Yuval Halpern
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Patent number: 4151356Abstract: A triazine of the formula I ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.18 -aryl, C.sub.7 -C.sub.18 -aralkyl or a radical of the formula II or III ##STR2## in which R.sub.3 is hydrogen or C.sub.1 -C.sub.8 -alkyl and R.sub.4 is hydrogen, oxyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.4 -alkinyl, C.sub.2 -C.sub.21 -alkoxyalkyl, C.sub.7 -C.sub.8 -aralkyl, 2,3-epoxypropyl, an aliphatic acyl group with 1-9 C atoms or one of the groups --CH.sub.2 COOR.sub.5, --CH.sub.2 --CH(R.sub.6)--OR.sub.7, --COOR.sub.8 or --CONHR.sub.8, in which R.sub.5 is C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.6 -alkenyl, phenyl, C.sub.7 -C.sub.8 -aralkyl or cyclohexyl and R.sub.6 is hydrogen, methyl or phenyl and R.sub.7 denotes hydrogen, an aliphatic or aromatic, araliphatic or alicyclic acyl group with 1-18 C atoms, in which the aromatic part can optionally be substituted by chlorine, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.Type: GrantFiled: October 11, 1977Date of Patent: April 24, 1979Assignee: Ciba-Geigy CorporationInventors: Samuel Evans, Michael Rasberger
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Patent number: 4140856Abstract: Undesirable color formation during the preparation of a cured intumescent flame retardant is minimized by including a color stabilizing amount of at least one color stabilizing phosphorus-containing compound.Type: GrantFiled: February 22, 1978Date of Patent: February 20, 1979Assignee: Phillips Petroleum CompanyInventors: Howard W. Bost, Ernest A. Zuech
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Patent number: 4107103Abstract: This invention relates to novel halogen-free flame retarding agents and a process in which they are used in the production of polyurethanes. These compounds are represented by the general formula: ##STR1## wherein: R.sub.1 represents C.sub.1 -C.sub.5 alkylene groups which may be branched,R.sub.2 represents C.sub.1 -C.sub.3 alkyl groups which may be branched or R.sub.1 OH andR.sub.3 represents C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -dialkylamino, C.sub.1 -C.sub.4 -oxyalkyl, C.sub.1 -C.sub.4 -thioslkyl, C.sub.6 -C.sub.14 -aryl or C.sub.7 -C.sub.15 -aralkyl groups or ##STR2## and A and L may be identical or different and represent C.sub.1 -C.sub.10 -alkyl groups, which may be branched, benzyl groups or OR groups, whereinR represents an alkyl group, with 1-8 C atoms which may be branched, or a benzyl group.Type: GrantFiled: September 26, 1977Date of Patent: August 15, 1978Assignee: Bayer AktiengesellschaftInventors: Hans Hubner, Johannes Blahak, Hans-Joachim Meiners
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Patent number: 4092466Abstract: Homopolymers, copolymers and terpolymers of a styrene based monomer are prepared by:(1) polymerizing at least one oxidized styrylphosphine monomer selected from the group of:(C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2,(c.sub.6 h.sub.5 o).sub.2 p(o)n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2,(c.sub.6 h.sub.5).sub.2 c.sub.3 n.sub.3 n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2 and(C.sub.6 H.sub.5) C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2 ; or(2) polymerizing p-diphenylphosphinestyrene and then oxidizing said polymerized p-diphenylphosphinestyrene monomer with an organoazide selected from the group of (C.sub.6 H.sub.5).sub.2 P(O)N.sub.3,(C.sub.6 H.sub.5 O).sub.2 P(O)N.sub.3,(C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 (N.sub.3) and C.sub.6 H.sub.5 C.sub.3 N.sub.3 (N.sub.3).sub.2.Type: GrantFiled: July 19, 1976Date of Patent: May 30, 1978Inventors: James C. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Fletcher, Kazimiera Jola Liliana Paciorek
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Patent number: 4086206Abstract: New phosphorus-containing condensation products are obtained by conducting dehydrocondensation of 10-hydroxymethyl-9, 10-dihydro-9-oxa-10-phosphorphenanthrene-10-oxide compounds with melamine or benzoguanamine.Alternatively, 9, 10-dihydro-9-oxa-10-phosphorphenanthrene-10-oxide compounds with alkoxymethyl melamines or alkoxymethyl benzoguanamines are condensed under heating.These phosphorus-containing condensation products are useful, particularly as a flame retardant for various synthetic resins.Type: GrantFiled: July 5, 1977Date of Patent: April 25, 1978Assignees: Sanko Kaihatsu Kagaku Kenkyosho, Asahi-Dow LimitedInventors: Toranosuke Saito, Masakatu Kitani, Kenshi Mori, Shinichi Izawa
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Patent number: 4085057Abstract: A toner for the electrostatic printing of a sheet like material, which comprises a toner substrate consisting essentially of a resin and a coloring matter, and a triazine derivative applied to the surface of or incorporated in the toner substrate.Type: GrantFiled: February 19, 1976Date of Patent: April 18, 1978Assignee: Kanebo Ltd.Inventors: Yougoro Masuda, Shigeru Kawase
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Patent number: 4080501Abstract: Melamine phosphate having hydrogen bonded thereto from about 0.5 to about 1.5 moles of phosphoric acid per mole of melamine phosphate, particleboard containing said melamine phosphate material and processes for the production thereof, are disclosed.Type: GrantFiled: June 21, 1973Date of Patent: March 21, 1978Assignee: American Cyanamid CompanyInventors: Jeffrey Donald Leman, Allan James Robertson
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Patent number: 4079051Abstract: Reactive dyestuffs of the formula ##STR1## WHEREIN ##STR2## IS AN AMINO-SUBSTITUTED AZO DYESTUFF RADICAL WHERE B is the azo dyestuff radical thereof;R is hydrogen or lower alkyl which is unsubstituted or substituted by methoxy, ethoxy or hydroxy;m is 1-2;And wherein Y is ##STR3## where X is chloro, bromo or fluoro;Z is ##STR4## where EACH M+ is alkali metal or ammonium, or both M+ together represent magnesium, calcium or zinc; andR' is hydrogen, lower alkyl or lower alkyl substituted by methoxy, ethoxy or hydroxy. These dyestuffs are useful in dyeing textile materials of cotton, regenerated cellulose, wool, silk, cellulose acetate, polyamides, polyacrylonitrile and modified polyacrylonitrile.Type: GrantFiled: December 12, 1975Date of Patent: March 14, 1978Assignee: Ciba-Geigy CorporationInventor: Rainer Begrich
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Patent number: 4062855Abstract: Synthetic, substantially water-insoluble organic polymers having a backbone or main chain including repeating units of at least one polymer forming biologically active component such as a pesticide are capable of slowly degrading in the medium where their activity is desired to slowly release the free biologically active component and thereby prolong the period of effectiveness of the biologically active component.Type: GrantFiled: September 27, 1971Date of Patent: December 13, 1977Assignee: University of WashingtonInventors: G. Graham Allan, Sreeman Amar Nath Neogi
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Patent number: 4053463Abstract: An azo pigment of the formula: ##STR1## in which R is hydrogen or methyl;R.sup.1 is cyano or carbamoyl;R.sup.2 is hydrogen, chloro, bromo, methyl, methoxy, ethoxy or cyano;R.sup.3 is hydrogen, chloro, bromo, methyl, methoxy, ethoxy, cyano, carbomethoxy, carbamoyl, sulfamoyl or methylsulfonyl; andR.sup.4 is hydrogen, chloro, bromo, methyl, methoxy or carbomethoxy.The compounds are eminently suitable as pigments in printing inks, surface coatings or plastics.Type: GrantFiled: June 25, 1976Date of Patent: October 11, 1977Assignee: BASF AktiengesellschaftInventor: Helmut Junge
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Patent number: 4043995Abstract: The present invention relates to a process for crosslinking hydrophilic colloids, preferably gelatine and most preferably gelatine present in a photographic material. A 1,3,5-triazine compound containing an NC--N.sup.- -- substituent bound to the triazine ring is incorporated into the hydrophilic colloid as a crosslinking agent.Type: GrantFiled: May 19, 1975Date of Patent: August 23, 1977Assignee: Ciba-Geigy AGInventors: Rainer Kitzing, Norman Alfred Smith