Phosphorus Containing Patents (Class 544/195)
  • Patent number: 4623642
    Abstract: N-phosphoryl- or N-thiophosphoryl-N'-s-triazinylformamidines of the formula ##STR1## wherein R.sub.1 and R.sub.2 independently of one another are each C.sub.1 -C.sub.20 -alkyl, or phenyl unsubstituted or substituted by halogen atoms,R.sub.3 is C.sub.1 -C.sub.6 -alkyl or C.sub.3 -C.sub.6 -cycloalkyl,R.sub.4 is hydrogen, C.sub.1 -C.sub.6 -alkyl or C.sub.3 -C.sub.6 -cycloalkyl, andX and Y are each oxygen or sulfur.A process for producing these triazines and their use for controlling pests are described.
    Type: Grant
    Filed: December 12, 1985
    Date of Patent: November 18, 1986
    Assignee: Ciba-Geigy Corporation
    Inventors: Odd Kristiansen, Jozef Drabek, Victor Fluck
  • Patent number: 4610824
    Abstract: Antibacterial activity is exhibited by novel compounds having the formula ##STR1## and pharmaceutically acceptable salts thereof.
    Type: Grant
    Filed: October 9, 1984
    Date of Patent: September 9, 1986
    Assignee: E. R. Squibb & Sons, Inc.
    Inventor: Uwe D. Truner
  • Patent number: 4602938
    Abstract: Guanidine derivatives of the formula ##STR1## in which R.sup.2 represents a six-membered aromatic heterocyclic structure which contains at least one nitrogen atom and is substituted by halogen, amino, cyano or formyl and/or by optionally substituted radicals from the series comprising alkyl, alkoxy, alkylamino, dialkylamino, alkylcarbonyl and alkoxycarbonyl, and/or is optionally fused,R.sup.3 represents hydrogen, an optionally substituted radical from the series comprising alkyl, cycloalkyl, alkenyl, alkinyl and aralkyl, or the radical --S(O).sub.n --R.sup.6,the other radicals can have varied meanings, andacid adducts and salts thereof,which possess herbicidal and plant growth regulating activity.
    Type: Grant
    Filed: February 9, 1984
    Date of Patent: July 29, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Koichi Moriya, Theodor Pfister, Hans-Jochem Riebel, Ludwig Eue, Robert R. Schmidt, Klaus Lurssen
  • Patent number: 4559078
    Abstract: Phosphorus-containing N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'-triazinylureas of the formula ##STR1## and the salts of these compounds with amines, alkali or alkaline earth metal bases or quaternary ammonium bases have good pre-emergence and post-emergence selective herbicidal and growth-regulating properties.In this formula, X is a group ##STR2## Y is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, trifluoromethyl, C.sub.2 -C.sub.5, alkenyl, C.sub.2 -C.sub.5 -alkynyl, nitro, --COOR.sup.6 or --Q--R.sup.6, Z is nitrogen or the methine group, E is oxygen or sulfur, R.sup.1 is hydrogen or C.sub.1 -C.sub.5 -alkyl and R.sup.2 and R.sup.3 independently of one another are C.sub.1 -C.sub.3 -alkyl, C.sub.1 -C.sub.3 -alkoxy, C.sub.1 -C.sub.3 -halogenoalkyl, C.sub.1 -C.sub.3 -halogenoalkoxy, cyclopropyl, amino, methylamino or dimethylamino, and A is oxygen, sulfur, C.sub.1 -C.sub.5 -alkylene, C.sub.2 -C.sub.5 -alkenylene, C.sub.1 -C.sub.5 -halogenoalkylene or --NR.sup.7 --(CH.sub.2).sub.m --; --CH.sub.
    Type: Grant
    Filed: December 19, 1983
    Date of Patent: December 17, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Ludwig Maier, Willy Meyer, Konrad Oertle, Achim Roloff, Werner Topfl
  • Patent number: 4539314
    Abstract: N-Phosphoryl- or thiophosphoryl-N'-s-triazinylformamidines of the formula ##STR1## wherein R.sub.1 and R.sub.2 independently of one another are each C.sub.1 -C.sub.20 -alkyl, or phenyl unsubstituted or substituted by halogen, andX and Y are each oxygen or sulfur.A process for producing these triazines and their use for controlling pests are described.
    Type: Grant
    Filed: June 1, 1984
    Date of Patent: September 3, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Odd Kristiansen, Jozef Drabek, Victor Fluck
  • Patent number: 4496726
    Abstract: Hitherto unknown polyalkylpiperidinylaminotriazines having a structure of the type ##STR1## are obtained from halogenotriazinyl compounds and aminoethylaminoethanols and can be converted into further derivatives with isocyanates, esters and acid chlorides to give new stabilizers for polymers, which stabilizers are distinguished by very good migration resistance.
    Type: Grant
    Filed: August 2, 1982
    Date of Patent: January 29, 1985
    Inventors: Hartmut Wiezer, Gerhard Pfahler
  • Patent number: 4491644
    Abstract: A flame-retarded polymer composition wherein the polymer constituent is an olefin polymer, a polymethyl acrylate or methacrylate, or polystyrene. The polymer is rendered flame-retardant by the presence of an amino-s-triazine salt of bis-(pentaerythritol phosphate) phosphoric acid.
    Type: Grant
    Filed: May 23, 1983
    Date of Patent: January 1, 1985
    Assignee: Borg-Warner Chemicals, Inc.
    Inventors: Yuval Halpern, Donna M. Mott
  • Patent number: 4480093
    Abstract: Amino-s-triazine salts of bis-(pentaerythritol phosphate) phosphoric acid. The salts are effective flame-retardant additives in a number of different types of polymers.
    Type: Grant
    Filed: May 23, 1983
    Date of Patent: October 30, 1984
    Assignee: Borg-Warner Chemicals, Inc.
    Inventors: Yuval Halpern, Donna M. Mott
  • Patent number: 4478998
    Abstract: A process for preparing amino-s-triazine salts of bis-(pentaerythritol phosphate) phosphoric acid. The process involves reacting the particular amine with the corresponding acid chloride, i.e., the phosphorous oxychloride, in the presence of water. The salts are effective flame-retardants in a number of different types of polymers.
    Type: Grant
    Filed: May 23, 1983
    Date of Patent: October 23, 1984
    Assignee: Borg-Warner Chemicals, Inc.
    Inventors: Yuval Halpern, Donna M. Mott, Ron H. Niswander
  • Patent number: 4451400
    Abstract: Halogenophosphazenes of the formula ##STR1## in which n denotes 3 to 100, are reacted with alcohols or amines having polyalkylpiperidyl groups to give compounds which are suitable for stabilizing synthetic polymers and are distinguished by a very high migration resistance.
    Type: Grant
    Filed: May 7, 1982
    Date of Patent: May 29, 1984
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Hartmut Wiezer
  • Patent number: 4413999
    Abstract: The invention provides amidoxime derivatives of the general formula ##STR1## wherein R.sub.1 is an alkyl group of 1 to 8 carbon atoms, phenyl, a heterocyclic ring structure of 5 to 8 atoms containing one or more nitrogen or oxygen atoms or combinations thereof or a bicyclic condensed ring system optionally containing at least one heterocyclic ring which groups may each be optionally substituted. R.sub.2 is a mono or bicyclic heterocyclic radical containing at least two nitrogen atoms which radical is also optionally substituted. R.sub.3 and R.sub.4 are independently H, or an alkyl of 1 to 4 carbon atoms or one, but not both, is ##STR2## and the other, H, wherein R.sub.5 or R.sub.6 are alkyls of 2 to 5 carbon atoms optionally substituted by R.sub.1, or a phenyl optionally substituted by R.sub.1 or R.sub.5 or R.sub.6 is combined with R.sub.1 to jointly form cyclic imidoximes or imidedioximes.
    Type: Grant
    Filed: March 5, 1982
    Date of Patent: November 8, 1983
    Assignee: Research Products Rehovot Ltd.
    Inventors: Charles Linder, Gershon Aviv
  • Patent number: 4373103
    Abstract: Dibromoneopentyl phosphate melamine salt is a novel flame retardant suitable for plastics, textiles and fabric backcoatings. The dibromoneopentyl phosphate melamine salt is prepared by the reaction of dibromoneopentyl phosphoric acid with melamine.
    Type: Grant
    Filed: May 5, 1980
    Date of Patent: February 8, 1983
    Assignee: Stauffer Chemical Company
    Inventors: Alfred K. Jung, Joseph Silberberg, Edward D. Weil
  • Patent number: 4328132
    Abstract: Undesirable color formation during the preparation of a cured intumescent flame retardant is minimized by including a color stabilizing amount of at least one of certain metal phosphites, hypophosphites, sulfites and bisulfites.
    Type: Grant
    Filed: March 6, 1979
    Date of Patent: May 4, 1982
    Assignee: Phillips Petroleum Company
    Inventor: Charles W. Moberly
  • Patent number: 4305949
    Abstract: A series of N-(2-thiazolyl)amides has been prepared, including their pharmaceutically acceptable acid addition salts as well as pharmaceutical compositions containing same. These compounds are useful in therapy as anti-inflammatory agents in addition to being useful as immunoregulatory agents for modulating various body immune responses. Preferred member compounds include N-(2-thiazolyl)-.alpha.-methylaminoacetamide, N-(2-thiazolyl)-.alpha.-benzylaminoacetamide, N-(2-thiazolyl)-.alpha.-(p-fluorobenzylamino)acetamide, N-(2-thiazolyl)-.alpha.-(2-thenylamino)acetamide and N-(4-methyl-2-thiazolyl)-.alpha.-amino-.beta.-phenylpropionamide, and their hydrohalide acid addition salts. Three different methods of preparation are provided and these are all described in some detail, including the various synthetic routes leading to the required novel intermediates and/or starting materials.
    Type: Grant
    Filed: January 29, 1980
    Date of Patent: December 15, 1981
    Assignee: Pfizer Inc.
    Inventors: Charles A. Harbert, Joseph G. Lombardino
  • Patent number: 4303652
    Abstract: Organophosphorus esters, useful in increasing the resistance of keratinous materials to attack by keratin-eating insects, have the general formula: ##STR1## wherein: X and Y are independently O or S;R.sub.1 is an alkyl, alkoxy, alkylamino, dialkylamino or alkylmercapto radical having 1 to 6 carbon atoms;an amino or aryl radical;R.sub.2 is an alkyl radical having 1 to 6 carbon atoms;R.sub.3 is a radical of the general formula:-J-(K-L).sub.n (2)wherein:J is an aliphatic radical, or radical containing an aromatic or heterocyclic ring;K is one of the following radicals: ##STR2## linked to J through the oxygen atom in the case of (3), (5) or (6), and through the nitrogen atom in the case of (4), and in which the carbonyl oxygen atom of (3), (4) or (5), or one or both carbonyl oxygen atoms of (6) may be replaced by sulphur; R.sub.
    Type: Grant
    Filed: August 30, 1978
    Date of Patent: December 1, 1981
    Assignee: Commonwealth Scientific and Industrial Research Organization
    Inventors: Francis W. Jones, Robert J. Mayfield, Gary J. O'Loughlin
  • Patent number: 4297492
    Abstract: Novel oligomeric and polymeric phenolic 1,3,5-triazines, for example those of the formula ##STR1## their preparation and their use for stabilizing organic material and also the organic material protected against oxidative and light-induced degradation with the aid of these compounds.
    Type: Grant
    Filed: March 10, 1980
    Date of Patent: October 27, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Michael Rasberger, Siegfried Rosenberger, Samuel Evans
  • Patent number: 4265806
    Abstract: A process for producing a solid, intumescent, phosphorus-containing flame retardant for thermoplastic synthetic resins, comprises evaporating to dryness the reaction product of (a) 1 mole of phosphoric acid, phosphorous acid or polyphosphoric acid, (b) 0.5-2 moles of ethylene oxide or glycol, and (c) 0.2-1 mole of melamine, and tempering the thus-obtained solid at 100.degree.-250.degree. C. The product so obtained can be added to such resins to render them flameproof without deleterious side effects such as discoloration.
    Type: Grant
    Filed: July 11, 1980
    Date of Patent: May 5, 1981
    Assignee: Chemische Werke Huls Aktiengesellschaft
    Inventors: Raban Grundmann, Gunther Maahs
  • Patent number: 4201705
    Abstract: Polyolefin compositions comprising a polyolefin and a flame retarding amount of the pentate salt of an amino-s-triazine are intumescent and self-extinguishing and non-dripping.
    Type: Grant
    Filed: August 28, 1978
    Date of Patent: May 6, 1980
    Assignee: Borg-Warner Corporation
    Inventors: Yuval Halpern, Clifton T. Fleenor
  • Patent number: 4161592
    Abstract: New 1,3,5-triazines containing at least one hindered phenolic moiety and at least one hindered amine moiety are useful light stabilizers and antioxidants for polymeric materials.
    Type: Grant
    Filed: July 1, 1977
    Date of Patent: July 17, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Samuel Evans, Michael Rasberger
  • Patent number: 4154930
    Abstract: Pentate salts of amino-s-triazines having the formula ##STR1## wherein x is -NH.sub.2 or -OH are useful as flame retardants and foaming agents for polymers.
    Type: Grant
    Filed: August 28, 1978
    Date of Patent: May 15, 1979
    Assignee: Borg-Warner Corporation
    Inventor: Yuval Halpern
  • Patent number: 4151356
    Abstract: A triazine of the formula I ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.18 -aryl, C.sub.7 -C.sub.18 -aralkyl or a radical of the formula II or III ##STR2## in which R.sub.3 is hydrogen or C.sub.1 -C.sub.8 -alkyl and R.sub.4 is hydrogen, oxyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.4 -alkinyl, C.sub.2 -C.sub.21 -alkoxyalkyl, C.sub.7 -C.sub.8 -aralkyl, 2,3-epoxypropyl, an aliphatic acyl group with 1-9 C atoms or one of the groups --CH.sub.2 COOR.sub.5, --CH.sub.2 --CH(R.sub.6)--OR.sub.7, --COOR.sub.8 or --CONHR.sub.8, in which R.sub.5 is C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.6 -alkenyl, phenyl, C.sub.7 -C.sub.8 -aralkyl or cyclohexyl and R.sub.6 is hydrogen, methyl or phenyl and R.sub.7 denotes hydrogen, an aliphatic or aromatic, araliphatic or alicyclic acyl group with 1-18 C atoms, in which the aromatic part can optionally be substituted by chlorine, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.
    Type: Grant
    Filed: October 11, 1977
    Date of Patent: April 24, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Samuel Evans, Michael Rasberger
  • Patent number: 4140856
    Abstract: Undesirable color formation during the preparation of a cured intumescent flame retardant is minimized by including a color stabilizing amount of at least one color stabilizing phosphorus-containing compound.
    Type: Grant
    Filed: February 22, 1978
    Date of Patent: February 20, 1979
    Assignee: Phillips Petroleum Company
    Inventors: Howard W. Bost, Ernest A. Zuech
  • Patent number: 4107103
    Abstract: This invention relates to novel halogen-free flame retarding agents and a process in which they are used in the production of polyurethanes. These compounds are represented by the general formula: ##STR1## wherein: R.sub.1 represents C.sub.1 -C.sub.5 alkylene groups which may be branched,R.sub.2 represents C.sub.1 -C.sub.3 alkyl groups which may be branched or R.sub.1 OH andR.sub.3 represents C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -dialkylamino, C.sub.1 -C.sub.4 -oxyalkyl, C.sub.1 -C.sub.4 -thioslkyl, C.sub.6 -C.sub.14 -aryl or C.sub.7 -C.sub.15 -aralkyl groups or ##STR2## and A and L may be identical or different and represent C.sub.1 -C.sub.10 -alkyl groups, which may be branched, benzyl groups or OR groups, whereinR represents an alkyl group, with 1-8 C atoms which may be branched, or a benzyl group.
    Type: Grant
    Filed: September 26, 1977
    Date of Patent: August 15, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans Hubner, Johannes Blahak, Hans-Joachim Meiners
  • Patent number: 4092466
    Abstract: Homopolymers, copolymers and terpolymers of a styrene based monomer are prepared by:(1) polymerizing at least one oxidized styrylphosphine monomer selected from the group of:(C.sub.6 H.sub.5).sub.2 P(O)N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2,(c.sub.6 h.sub.5 o).sub.2 p(o)n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2,(c.sub.6 h.sub.5).sub.2 c.sub.3 n.sub.3 n.dbd.p(c.sub.6 h.sub.5).sub.2 c.sub.6 h.sub.4 ch.dbd.ch.sub.2 and(C.sub.6 H.sub.5) C.sub.3 N.sub.3 [N.dbd.P(C.sub.6 H.sub.5).sub.2 C.sub.6 H.sub.4 CH.dbd.CH.sub.2 ].sub.2 ; or(2) polymerizing p-diphenylphosphinestyrene and then oxidizing said polymerized p-diphenylphosphinestyrene monomer with an organoazide selected from the group of (C.sub.6 H.sub.5).sub.2 P(O)N.sub.3,(C.sub.6 H.sub.5 O).sub.2 P(O)N.sub.3,(C.sub.6 H.sub.5).sub.2 C.sub.3 N.sub.3 (N.sub.3) and C.sub.6 H.sub.5 C.sub.3 N.sub.3 (N.sub.3).sub.2.
    Type: Grant
    Filed: July 19, 1976
    Date of Patent: May 30, 1978
    Inventors: James C. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Fletcher, Kazimiera Jola Liliana Paciorek
  • Patent number: 4086206
    Abstract: New phosphorus-containing condensation products are obtained by conducting dehydrocondensation of 10-hydroxymethyl-9, 10-dihydro-9-oxa-10-phosphorphenanthrene-10-oxide compounds with melamine or benzoguanamine.Alternatively, 9, 10-dihydro-9-oxa-10-phosphorphenanthrene-10-oxide compounds with alkoxymethyl melamines or alkoxymethyl benzoguanamines are condensed under heating.These phosphorus-containing condensation products are useful, particularly as a flame retardant for various synthetic resins.
    Type: Grant
    Filed: July 5, 1977
    Date of Patent: April 25, 1978
    Assignees: Sanko Kaihatsu Kagaku Kenkyosho, Asahi-Dow Limited
    Inventors: Toranosuke Saito, Masakatu Kitani, Kenshi Mori, Shinichi Izawa
  • Patent number: 4085057
    Abstract: A toner for the electrostatic printing of a sheet like material, which comprises a toner substrate consisting essentially of a resin and a coloring matter, and a triazine derivative applied to the surface of or incorporated in the toner substrate.
    Type: Grant
    Filed: February 19, 1976
    Date of Patent: April 18, 1978
    Assignee: Kanebo Ltd.
    Inventors: Yougoro Masuda, Shigeru Kawase
  • Patent number: 4080501
    Abstract: Melamine phosphate having hydrogen bonded thereto from about 0.5 to about 1.5 moles of phosphoric acid per mole of melamine phosphate, particleboard containing said melamine phosphate material and processes for the production thereof, are disclosed.
    Type: Grant
    Filed: June 21, 1973
    Date of Patent: March 21, 1978
    Assignee: American Cyanamid Company
    Inventors: Jeffrey Donald Leman, Allan James Robertson
  • Patent number: 4079051
    Abstract: Reactive dyestuffs of the formula ##STR1## WHEREIN ##STR2## IS AN AMINO-SUBSTITUTED AZO DYESTUFF RADICAL WHERE B is the azo dyestuff radical thereof;R is hydrogen or lower alkyl which is unsubstituted or substituted by methoxy, ethoxy or hydroxy;m is 1-2;And wherein Y is ##STR3## where X is chloro, bromo or fluoro;Z is ##STR4## where EACH M+ is alkali metal or ammonium, or both M+ together represent magnesium, calcium or zinc; andR' is hydrogen, lower alkyl or lower alkyl substituted by methoxy, ethoxy or hydroxy. These dyestuffs are useful in dyeing textile materials of cotton, regenerated cellulose, wool, silk, cellulose acetate, polyamides, polyacrylonitrile and modified polyacrylonitrile.
    Type: Grant
    Filed: December 12, 1975
    Date of Patent: March 14, 1978
    Assignee: Ciba-Geigy Corporation
    Inventor: Rainer Begrich
  • Patent number: 4062855
    Abstract: Synthetic, substantially water-insoluble organic polymers having a backbone or main chain including repeating units of at least one polymer forming biologically active component such as a pesticide are capable of slowly degrading in the medium where their activity is desired to slowly release the free biologically active component and thereby prolong the period of effectiveness of the biologically active component.
    Type: Grant
    Filed: September 27, 1971
    Date of Patent: December 13, 1977
    Assignee: University of Washington
    Inventors: G. Graham Allan, Sreeman Amar Nath Neogi
  • Patent number: 4053463
    Abstract: An azo pigment of the formula: ##STR1## in which R is hydrogen or methyl;R.sup.1 is cyano or carbamoyl;R.sup.2 is hydrogen, chloro, bromo, methyl, methoxy, ethoxy or cyano;R.sup.3 is hydrogen, chloro, bromo, methyl, methoxy, ethoxy, cyano, carbomethoxy, carbamoyl, sulfamoyl or methylsulfonyl; andR.sup.4 is hydrogen, chloro, bromo, methyl, methoxy or carbomethoxy.The compounds are eminently suitable as pigments in printing inks, surface coatings or plastics.
    Type: Grant
    Filed: June 25, 1976
    Date of Patent: October 11, 1977
    Assignee: BASF Aktiengesellschaft
    Inventor: Helmut Junge
  • Patent number: 4043995
    Abstract: The present invention relates to a process for crosslinking hydrophilic colloids, preferably gelatine and most preferably gelatine present in a photographic material. A 1,3,5-triazine compound containing an NC--N.sup.- -- substituent bound to the triazine ring is incorporated into the hydrophilic colloid as a crosslinking agent.
    Type: Grant
    Filed: May 19, 1975
    Date of Patent: August 23, 1977
    Assignee: Ciba-Geigy AG
    Inventors: Rainer Kitzing, Norman Alfred Smith