Halogen Or Sulfur Containing Patents (Class 544/199)
  • Patent number: 8895731
    Abstract: The invention relates to novel intermediates for the preparation of substituted triazines used in particular in the cosmetic, detergent, coating, plastics and textile industries. The invention also relates to the processes for preparation of said intermediates and for the conversion of the latter into final products.
    Type: Grant
    Filed: June 8, 2012
    Date of Patent: November 25, 2014
    Assignee: 3V Sigma S.p.A.
    Inventors: Francesco Maestri, Luca Bemporad, Ferruccio Berte′
  • Patent number: 8828565
    Abstract: Disclosed is a lubricant composition comprising at least one kind of compound represented by following formula (1): where X represents a cyclic group that may be substituted; Y represents a divalent or higher-valent linking group having at least one polar group and having no aromatic cyclic group; p1 represents an integer of 1 to 4; p2, p3, and p4 each represent an integer of 0 to 4; q represents an integer of 0 to 30; n represents an integer of 1 to 10; s represents an integer of 1 to 4; and t represents an integer of 2 to 10.
    Type: Grant
    Filed: March 7, 2012
    Date of Patent: September 9, 2014
    Assignee: FUJIFILM Corporation
    Inventors: Hiroki Sugiura, Masayuki Harada, Ken Kawata, Akiko Hattori, Atsushi Tatsugawa
  • Publication number: 20130323777
    Abstract: A ligand design allows compact nanoparticle materials, such as quantum dots (QDs), with excellent colloidal stability over a wide range of pH and under high salt concentrations. Self-assembled biomolecular conjugates with QDs can be obtained which are stable in biological environments. Energy transfer with these ligands is maximized by minimizing distances between QDs/nanoparticles and donors/acceptors directly attached to the ligands or assembled on their surfaces.
    Type: Application
    Filed: July 16, 2013
    Publication date: December 5, 2013
    Applicant: Naval Research Laboratory
    Inventors: Igor L. Medintz, Kimihiro Susumu, Michael H. Stewart
  • Patent number: 8367823
    Abstract: The present invention includes methods, articles, compositions and colorant dyes and pigments that include biocidal N-halamine dye composition having two or more heterocyclic ring structures attached to one or more N-halamine groups, wherein one or more halogens associate with the one or more one or more N-halamine groups to affect biocidal activity.
    Type: Grant
    Filed: September 19, 2008
    Date of Patent: February 5, 2013
    Assignee: Board of Regents, The University of Texas System
    Inventors: Yuyu Sun, Jie Luo
  • Publication number: 20120231297
    Abstract: Disclosed is a lubricant composition comprising at least one kind of compound represented by following formula (1): where X represents a cyclic group that may be substituted; Y represents a divalent or higher-valent linking group having at least one polar group and having no aromatic cyclic group; p1 represents an integer of 1 to 4; p2, p3, and p4 each represent an integer of 0 to 4; q represents an integer of 0 to 30; n represents an integer of 1 to 10; s represents an integer of 1 to 4; and t represents an integer of 2 to 10.
    Type: Application
    Filed: March 7, 2012
    Publication date: September 13, 2012
    Applicant: FUJIFILM CORPORATION
    Inventors: Hiroki SUGIURA, Masayuki HARADA, Ken KAWATA, Akiko HATTORI, Atsushi TATSUGAWA
  • Publication number: 20120142647
    Abstract: The present invention includes compositions that are useful in the treatment of breathing control diseases or disorders in a subject in need thereof. The present invention also includes a method of treating a respiratory disease or disorder in a subject in need thereof, comprising administering to the subject a therapeutically effective amount of a pharmaceutical formulation of the invention. The present invention further includes a method of preventing destabilization or stabilizing breathing rhythm in a subject in need thereof, comprising administering to the subject a therapeutically effective amount of a pharmaceutical formulation of the invention.
    Type: Application
    Filed: November 29, 2011
    Publication date: June 7, 2012
    Inventors: Scott L. Dax, Richard Woodward, Sean Peng
  • Publication number: 20120040881
    Abstract: The invention relates to new triazine derivatives, the use of new triazine derivatives as graying-inhibiting active substances, and washing agent compositions comprising the new triazine derivatives as graying-inhibiting active substances along with surfactant and other ingredients found in detergent compositions.
    Type: Application
    Filed: September 22, 2011
    Publication date: February 16, 2012
    Applicant: Henkel AG & KGaA
    Inventors: Thomas Eiting, Birgit Glüsen
  • Patent number: 7122667
    Abstract: Reactive dyes of formula (1) wherein Q1, Q2, Q3 and Q4 are each independently of the others hydrogen or unsubstituted or substituted C1–C4alkyl, A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, D is the radical of a diazo component, of the benzene or naphthalene series, X is halogen, 3-carboxpyridin-1-yl, 3-carbamoylpyridin-1-yl, hydroxy, C1–C4alkoxy unsubstituted or substituted in the alkyl moiety, phenoxy unsubstituted or substituted in the phenyl moiety, C1–C4alkylthio unsubstituted or substituted in the alkyl moiety, unsubstituted or substituted amino, or an N-heterocycle which may or may not contain further hetero atoms, and Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: October 17, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Athanassios Tzikas, Bernhard Müller
  • Patent number: 6696445
    Abstract: The present invention also provides a general method to whereby mono-, bi-, or tricyclic heterocycles may be modified to obtain potent antagonists at the NPY1 receptor. The present invention provides novel, potent, non-peptidic antagonists of NPY receptors, particularly, the NPY1 receptors, designed from a selection of mono-, bi-, or tri-cyclic heterocyclic cores. This invention relates to novel compounds, compositions, and methods for the treatment of physiological disorders associated with an excess of neuropeptide Y. The novel compounds encompassed by the present invention are those of the formula I-XV.
    Type: Grant
    Filed: November 8, 2002
    Date of Patent: February 24, 2004
    Assignees: Neurogen Corporation, Pfizer Inc.
    Inventors: Raymond F. Horvath, Jennifer N Tran, Stéphane De Lombaert, Kevin J. Hodgetts, Philip A. Carpino, David A. Griffith
  • Patent number: 6517742
    Abstract: The invention relates to new s-triazine derivatives of the formula (I): in which R1 represents an —NH—F radical, wherein F is a screening chromophore; R2 represents an —NH—Z—W radical, wherein Z is a divalent radical providing the connection between —NH— and —W, and W is a silicone-containing radical; and R3 is R1, R2, a linear or branched C1-C20 alkyl radical, a linear or branched C2-C20 hydroxyalkyl radical, a linear or branched C1-C20 alkoxy radical, an NHR8 radical or an N(R8)2 radical, with R8 being a linear or branched C1-C20 alkyl radical. The compounds of the invention are useful as organic sunscreen agents in cosmetic compositions intended for the protection of the skin and the hair against ultraviolet radiation. The invention also relates to the use of the compounds in cosmetic applications and to cosmetic compositions with improved properties containing these compounds.
    Type: Grant
    Filed: November 6, 1997
    Date of Patent: February 11, 2003
    Assignee: L'Oreal
    Inventors: Hervé Richard, Madeleine Leduc
  • Patent number: 6372729
    Abstract: This invention concerns the use of the compounds of formula the N-oxides, the pharmaceutically acceptable addition salts and the stereochemically isomeric forms thereof, wherein A is CH, CR4 or N; n is 0, 1, 2, 3 or 4; R1 and R2 are each independently selected from hydrogen, hydroxy, C1-12alkyl, C1-12alkyloxy, C1-12alkylcarbonyl, C1-12alkyloxycarbonyl, aryl, amino, mono- or di(C1-12alkyl)amino, mono- or di(C1-12alkyl)aminocarbonyl wherein each of the aforementioned C1-12alkyl groups may optionally and each individually be substituted; or R1 and R2 taken together may form pyrrolidinyl, piperidinyl, morpholinyl, azido or mono- or di(C1-12alkyl)aminoC1-4alkylidene; R3 is hydrogen, aryl, C1-6alkylcarbonyl, optionally substituted C1-6alkyl; and each R4 independently is hydroxy, halo, C1-6alkyl, C1-6alkyloxy, cyano, aminocarbonyl, nitro, amino, trihalomethyl or trihalomethyloxy; L is —X—R5 or —X-Alk-R6; wherein R5 and R6 each independently are indanyl, indolyl or phenyl; each of
    Type: Grant
    Filed: August 8, 2000
    Date of Patent: April 16, 2002
    Assignee: Janssen Pharmaceutica N.V.
    Inventors: Frederik Frans Desiré Daeyaert, Bart De Corte, Marc René De Jonge, Jan Heeres, Chih Yung Ho, Paul Adriaan Jan Janssen, Robert W. Kavash, Lucien Maria Henricus Koymans, Michael Joseph Kukla, Donald William Ludovici
  • Patent number: 6251900
    Abstract: Heterocyclic compounds in which s-triazine or pyrimidine is substituted with benzimidazole and morpholine and which are represented by the Formula I or phermaceutically acceptable acid addition salts thereof: wherein X and Y respectively represent nitrogen atom or one of them represents nitrogen atom and the other represents C—R7 wherein R7 represents hydrogen or halogen atom; R1, R2, R4, R5 and R6 represent hydrogen atom or C1-C6 alkyl; R3 represents morpholino, piperidino, piperazinyl, thiomorpholino, benzimidazolyl, cyano or the like.
    Type: Grant
    Filed: January 21, 2000
    Date of Patent: June 26, 2001
    Assignee: Zenyaku Kogyo Kabushiki Kaisha
    Inventors: Seiichiro Kawashima, Toshiyuki Matsuno, Shinichi Yaguchi, Tetsuo Watanabe, Masahiro Inaba
  • Patent number: 6235493
    Abstract: The present invention concerns a method to detect the presence of an enzyme in in vivo or in vitro tissue or cell, which method comprises: (a) obtaining a tissue or cell sample to be analyzed; (b) contacting the tissue or cell sample with a substrate of the structure selected from the group consisting of: X=H or one or more natural or synthetic amino acids with or without amino blocking groups, Y=H or one or more natural or synthetic amino acids with or without amino blocking groups, wherein X and Y are the same or different and are amino acid sequences of between about 1 to 1,000,000 amino acids wherein each amino acid is the same or a different amino acid, with the proviso that at least one of X or Y is at least one amino acid; (c) when an enzyme is present in the tissue or cell sample which degrades X, Y and combinations thereof, fluorescent cresyl violet is released in the tissue sample producing a color change; (d) detecting the presence and amount of the enzyme pres
    Type: Grant
    Filed: August 5, 1998
    Date of Patent: May 22, 2001
    Assignee: The Regents of the University of California
    Inventors: Eugene R. Bissell, Robert F. Smith
  • Patent number: 6150360
    Abstract: This invention concerns the use of the compounds of formula ##STR1## the N-oxides, the pharmaceutically acceptable addition salts and the stereochemically isomeric forms thereof, wherein A is CH, CR.sup.4 or N; n is 0, 1, 2, 3 or 4; R.sup.1 and R.sup.2 are each independently selected from hydrogen, hydroxy, C.sub.1-12 alkyl, C.sub.1-12 alkyloxy, C.sub.1-12 alkylcarbonyl, C.sub.1-12 -alkyloxycarbonyl, aryl, amino, mono- or di(C.sub.1-12 alkyl)amino, mono- or di(C.sub.1-12 alkyl)aminocarbonyl wherein each of the aforementioned C.sub.1-12 alkyl groups may optionally and each individually be substituted; or R.sup.1 and R.sup.2 taken together may form pyrrolidinyl, piperidinyl, morpholinyl, azido or mono- or di(C.sub.1-12 alkyl)aminoC.sub.1-4 alkylidene; R.sup.3 is hydrogen, aryl, C.sub.1-6 alkylcarbonyl, optionally substituted C.sub.1-6 alkyl; and each R.sup.4 independently is hydroxy, halo, C.sub.1-6 alkyl, C.sub.1-6 -alkyloxy, cyano, aminocarbonyl, nitro, amino, trihalomethyl or trihalomethyloxy; L is --X--R.
    Type: Grant
    Filed: March 25, 1999
    Date of Patent: November 21, 2000
    Assignee: Janssen Pharmaceutica N.V.
    Inventors: Frederik Frans Desire Daeyaert, Bart De Corte, Marc Rene De Jonge, Jan Heeres, Chih Yung Ho, Paul Adriaan Jan Janssen, Robert W. Kavash, Lucien Maria Henricus Koymans, Michael Joseph Kukla, Donald William Ludovici
  • Patent number: 6136827
    Abstract: The present invention is directed to cyclic amines of the formula I: ##STR1## (wherein R.sup.1, R.sup.2, R.sup.3, m and n are defined herein) which are useful as modulators of chemokine receptor activity. In particular, these compounds are useful as modulators of the chemokine receptors CCR-1, CCR-2, CCR-2A, CCR-2B, CCR-3, CCR-4, CCR-5, CXCR-3, and/or CXCR-4.
    Type: Grant
    Filed: July 21, 1998
    Date of Patent: October 24, 2000
    Assignee: Merck & Co., Inc.
    Inventors: Charles G. Caldwell, Paul E. Finke, Malcolm Maccoss, Laura C. Meurer, Sander G. Mills, Bryan Oates
  • Patent number: 6111102
    Abstract: Compounds of the formula I or salts thereof, in whichX is oxygen, --O--NR.sup.2 -- or --SO.sub.2 --NR.sup.2 --, and Y is N or CH,R.sup.1 is (C.sub.1 -C.sub.6)alkyl, (C.sub.2 -C.sub.6)alkenyl or (C.sub.2 -C.sub.6)alkynyl, which are in each case optionally substituted, or, in the case where X=oxygen, also (subst.) phenyl,R.sup.2 is H, (C.sub.1 -C.sub.6)alkyl, (C.sub.2 -C.sub.6)alkenyl or -alkynyl or (C.sub.3 -C.sub.6)cycloalkyl,R.sup.3 and R.sup.4 are H, (subst.) (C.sub.1 -C.sub.4)alkyl or (subst.) (C.sub.1 -C.sub.4)alkoxy or halogen, (C.sub.1 -C.sub.4)alkylthio, (C.sub.1 -C.sub.4)-alkylamino or di[(C.sub.1 -C.sub.4)alkyl]-amino,R.sup.5 is H or (C.sub.1 -C.sub.4)alkyl and R.sup.6 is hydrogen,may be prepared by reacting compounds of the formula II,R.sup.1 --X--R.sup.7 (II)with compounds of the formulae III, IV and VR.sup.8 --OCN (III)SO.sub.2 Cl.sub.2 (IV) ##STR1## where R.sup.7 and R.sup.8 are H, a quarternary ammonium ion or one equivalent of a metal cation.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: August 29, 2000
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Gunter Schlegel
  • Patent number: 5925596
    Abstract: Substituted aminomethylphenylsulfonylureas, their preparation, and their use as herbicides and plant growth regulatorsCompounds of the formula (I) and salts thereof ##STR1## where R.sup.1 to R.sup.7 and A are as defined in claim 1 and, inter alia, F.sup.5 is an acyl radical or NR.sup.4 R.sup.5 together are a heterocyclic radical, are useful as herbicides and plant growth regulators. They can be prepared by the methods of known processes, using novel intermediates of the formula (II), (IV), (VI) or (VII) (cf. claim 5).
    Type: Grant
    Filed: April 24, 1997
    Date of Patent: July 20, 1999
    Assignee: Hoechst-Schering AgrEvo GmbH
    Inventors: Klaus Lorenz, Lothar Willms, Klaus Bauer, Hermann Bieringer, Christopher Rosinger
  • Patent number: 5677450
    Abstract: Disclosed are an organic acid salt of melamine represented by the following general formula (1) and a thermosetting and a photocurable and thermosetting coating compositions containing the salt mentioned above. ##STR1## wherein Z represents ##STR2## wherein R.sup.1 represents a hydrogen atom or an alkyl group, alkylene group, alicyclic hydrocarbon, or aromatic hydrocarbon severally having from 1 to 18 carbon atoms, or any of said groups or hydrocarbons whose hydrogen atom is substituted by carboxyl group, hydroxyl group, or a halogen atom, R.sup.2 represents a hydrogen atom or an alkyl group or alkylene group severally having from 1 to 9 carbon atoms, or any of said groups whose hydrogen atom is substituted by acryloyl group or methacryloyl group, R.sup.3 represents an alkyl group or alkylene group severally having from 1 to 9 carbon atoms, or any of said groups whose hydrogen atom is substituted by acryloyl group or methacryloyl group, and R.sup.
    Type: Grant
    Filed: November 5, 1996
    Date of Patent: October 14, 1997
    Assignee: Taiyo Ink Manufacturing Co., Ltd.
    Inventors: Nobuyuki Suzuki, Kazunobu Fukushima, Kyo Ichikawa, Teruo Saito, Hitoshi Inagaki
  • Patent number: 5578667
    Abstract: The invention relates to novel water-soluble antioxidants of formula ##STR1## wherein the variables are as defined in the claims, to a process for their preparation and to the use thereof for the photochemical and thermal stabilisation of dyed and undyed polyamide fibre materials.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: November 26, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Francesco Fuso, Gerhard Reinert
  • Patent number: 5571915
    Abstract: This invention provides a process for preparing amide derivatives of acids by the reaction of haloaminotriazines and acid halides.This invention also provides a process for preparing isocyanates and isocyanate adducts from amide derivatives derived from haloaminotriazines and acid halides such as oxalyl chloride, phosgene and phosgene analogs.Melamine derived acid amides are prepared by reaction of trichloro and hexachloromelamines with chloroformates and acid chlorides. The by-product chlorine may be recycled in this process.Amides, carbamates, sulfonamides, phosphoramides, and related amide derivatives may be prepared by the novel processes of the invention.
    Type: Grant
    Filed: March 3, 1995
    Date of Patent: November 5, 1996
    Assignee: Cytec Technology Corp.
    Inventor: Ram B. Gupta
  • Patent number: 5569761
    Abstract: Process for the preparation of sulfonylureasHerbicidal sulfonylureas of the formula I, ##STR1## in which X is --O--, --0--NR.sup.2 -- or --SO.sub.2 --NR.sup.2 --, Y is --N-- or CH,R.sup.1 is (substituted) alkyl, (substituted) alkenyl or (substituted) alkynyl, or else, where X.dbd.O, (substituted) phenyl,R.sup.2 is H, alkyl, alkenyl, alkynyl or cycloalkyl,R.sup.3, R.sup.4 are H, (substituted) alkyl or (substituted) alkoxy, halogen, alkylthio, alkylamino or dialkylamino andR.sup.5, R.sup.
    Type: Grant
    Filed: February 7, 1995
    Date of Patent: October 29, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Lothar Willms, Stephen Lacchein, Gunter Schlegel, Heinz Kehne
  • Patent number: 5405959
    Abstract: This invention provides a process for preparing amide derivatives of acids by the reaction of haloaminotriazines and acid halides.This invention also provides a process for preparing isocyanates and isocyanate adducts from amide derivatives derived from haloaminotriazines and acid halides such as oxalyl chloride, phosgene and phosgene analogs.Melamine derived acid amides are prepared by reaction of trichloro and hexachloromelamines with chloroformates and acid chlorides. The by-product chlorine may be recycled in this process.Amides, carbamates, sulfonamides, phosphoramides, and related amide derivatives may be prepared by the novel processes of the invention.
    Type: Grant
    Filed: November 10, 1993
    Date of Patent: April 11, 1995
    Assignee: Cytec Technology Corp.
    Inventor: Ram B. Gupta
  • Patent number: 5374725
    Abstract: A compound of formula I or salt thereof can be prepared in a process which comprises reacting a compound of formula II with a compound of formula III: ##STR1## wherein the formulae I-III the radical X is O, ONR.sup.2 or SO.sub.2 NR.sup.2 ; Y is N or CH;R.sup.1 is (subst.) alkyl, (subst.) alkenyl, (subst.) alkynyl, or in case X.dbd.O, also (subst.) phenyl;R.sup.2 is H, alkyl, alkenyl, alkynyl or cycloalkyl,R.sup.3 -R.sup.6 are defined in claim 1;Z is S or NR.sup.8 ; R.sup.7, R.sup.8 are H, alkyl, (subst.) phenyl or (subst.) benzyl, or, in case Z.dbd.NR.sup.8, R.sup.7 and NR.sup.8 are also a 5- to 7-membered heterocycle.
    Type: Grant
    Filed: February 22, 1994
    Date of Patent: December 20, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gunter Schlegel, Hilmar Mildenberger
  • Patent number: 5364937
    Abstract: Compounds of the formula I or salts thereof, ##STR1## in which X is oxygen, --O--NR.sup.2 -- or --SO.sub.2 --NR.sup.2 --, and Y is N or CH,R.sup.1 is (C.sub.1 -C.sub.6)alkyl, (C.sub.2 -C.sub.6)alkenyl or (C.sub.2 -C.sub.6)alkynyl, which are in each case optionally substituted, or, in the case where X=oxygen, also (subst.) phenyl,R.sup.2 is H, (C.sub.1 -C.sub.6)alkyl, (C.sub.2 -C.sub.6)alkenyl or -alkynyl or (C.sub.3 -C.sub.6) cycloalkyl,R.sup.3 and R.sup.4 are H, (subst.) (C.sub.1 -C.sub.4)alkyl or (subst.) (C.sub.1 -C.sub.4)alkoxy or halogen, (C.sub.1 -C.sub.4)alkylthio, (C.sub.1 -C.sub.4)alkylamino or di[(C.sub.1 -C.sub.4)alkyl]-amino,R.sup.5 is H or (C.sub.1 -C.sub.4)alkyl and R.sup.6 is hydrogen,may be prepared by reacting compounds of the formula II,R.sup.1 --X--R.sup.7 (II)with compounds of the formulae III, IV and VR.sup.8 --OCN (III)SO.sub.2 Cl.sub.2 (IV) ##STR2## where R.sup.7 and R.sup.8 are H, a quarternary ammonium ion or one equivalent of a metal cation.
    Type: Grant
    Filed: March 4, 1993
    Date of Patent: November 15, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Gunter Schlegel
  • Patent number: 5250685
    Abstract: A process for the preparation of an S-alkyl-isothioureidoazine of the formula ##STR1## in which R is alkyl,X and Y each independently is selected from the group consisting of hydrogen, halogen, and alkyl, halogenoalkyl, alkoxyalkyl, halogenoalkoxy, alkoxy, alkylthio, halogenoalkylthio, alkylamino or dialkylamino, each of which is optionally substitued, andZ is nitrogen or CHwhich comprises in a first step reacting an thioureidoazine of the formula ##STR2## with a dialkyl sulphate of the formulaRO--SO.sub.2 --ORat a temperature between about 20.degree. C. and 150.degree. C., thereby to form an adduct of the formula ##STR3## and in a second step reacting the adduct with an acid acceptor in the presence of an aprotic polar diluent at a temperature between about 0.degree. C. and 50.degree. C.
    Type: Grant
    Filed: September 21, 1992
    Date of Patent: October 5, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventor: Hans-Jochem Riebel
  • Patent number: 5227493
    Abstract: N-fluoro perfluoroheterocyclic sulfonamides of the following Formula I ##STR1## wherein Het.sub.f represents an aromatic perfluoroheterocyclic radical of valency n and each R independently represents a substituted or unsubstituted C.sub.1 -C.sub.30 alkyl, C.sub.6 -C.sub.14 aryl substituted C.sub.1 -C.sub.10 alkyl, C.sub.6 -C.sub.14 aryl, or C.sub.1 -C.sub.10 alkyl substituted C.sub.6 -C.sub.14 aryl group, are novel electrophilic fluorinating agents. Preferably Het.sub.f is a perfluorinated nitrogen-containing aromatic group, especially pyridyl, pyrimidinyl, pyrazinyl or 1,3,5-triazinyl; n is 1; and R is perfluorinated, especially trifluoromethyl.
    Type: Grant
    Filed: August 31, 1990
    Date of Patent: July 13, 1993
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Ronald E. Banks
  • Patent number: 5225549
    Abstract: Lubricants for electromagnetic recording media are characterized in that they are amides, imides or amide-imides consisting of perfluoroalkylpolyether derivatives. The derivatives are reacted with perfluoropolyether radicals and cyclic amino compounds, nitrogen-containing heterocyclic amino compounds and phosphonitrile amide compounds. The general formula is represented by (1)(Rf) l--Z . . . (1)with the molecular weight of the Rf group being comprised between 400 and 10,000.
    Type: Grant
    Filed: January 15, 1992
    Date of Patent: July 6, 1993
    Inventor: Takateru Dekura
  • Patent number: 5079361
    Abstract: Cross-linking reagents which are highly specific for sulphydryl groups and react with thiols at an excellent rate. The essential feature of the reagents is at least one vinyl group conjugated with an armoatic nitrogen heterocycle. Particular examples include vinyl pyridines, vinyl pyrimidines and vinyl triazines.
    Type: Grant
    Filed: September 9, 1988
    Date of Patent: January 7, 1992
    Assignee: Celltech Limited
    Inventors: Rikki P. Alexander, Michael A. W. Eaton, Thomas A. Millican, Richard C. D. Titmas
  • Patent number: 5034525
    Abstract: The lubricants according to the present invention are comprised of fluorine-containing alkyl carbonyl, polyperfluorooxyalkylenefluoropropionyl, polyperfluorooxyalkylene copolymerized oxyfluoroalkyl carbonyl chains and the like, and of which compounds are reacted with hetero cyclic groups obtained by amidization with polar groups between the radicals and compounds with typical organic end-groups.The novel compounds referred to above are lubricants characterized in that they can be represented by the general formula (1) and that the molecular weight of Rf ranges from 200 to 15,000. ##STR1## wherein Rf represents any one of the following groups: ##STR2## where l is an integer having a value between 3 and 150, and m an integer ranging from 1 to 50, and where X may be H--, F--, CF.sub.3 --, C.sub.2 F.sub.5 --, C.sub.3 F.sub.7 --, CF.sub.3 O--, C.sub.2 F.sub.5 O--, or C.sub.3 F.sub.7 O--, and Y may be F--, CF.sub.3 --, or C.sub.2 F.sub.5 -- respectively.
    Type: Grant
    Filed: September 19, 1988
    Date of Patent: July 23, 1991
    Inventor: Takateru Dekura
  • Patent number: 4977261
    Abstract: A compound of the following formula in the free acid form, ##STR1## wherein and R and R.sub.1 are each hydrogen or alkyl, A is a divalent group of the formula, ##STR2## wherein R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, methyl, ethyl, methoxy or ethoxy, m is 0 or 1, n, u and v are each 0, 1 or 2, p is 0, 1, 2 or 3, q and s are each an integer of 2 to 6, and r is 1 or 2, B.sub.1 is phenylene or naphthylene, Z.sub.1 is vinyl, .beta.-sulfatoethyl or the like, l is 0, 1 or 2, and X is a group of the formula, ##STR3## wherein R.sub.2 is hydrogen or alkyl, B.sub.2 is phenylene or naphtylene, Z.sub.2 is vinyl, .beta.-sulfatoethyl or the like, R.sub.6 and R.sub.7 are each hydrogen, alkyl, phenyl, naphthyl or benzyl, and R, A and l are as defined above, which is useful for dyeing or printing fiber materials to give a dyed or printed product of a brilliant blue color superior in fastness properties such as light fastness and perspiration-light fastness, with superior build-up property.
    Type: Grant
    Filed: January 11, 1988
    Date of Patent: December 11, 1990
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Yutaka Kayane, Takashi Omura, Naoki Harada, Yasuji Mori, Yosuke Yamamoto, Tetsuya Miyamoto, Takehiro Kusumoto
  • Patent number: 4968796
    Abstract: Disclosed is a process for the preparation of a sulphonylisothiourea of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, X, Y, and Z are as defined herein, which comprises reacting a sulphonic acid amide of the formulaR.sup.1 --SO.sub.2 --NH.sub.2, (II)or a metal salt thereof, with an N-heteroaryl-iminodithiocarbonic acid S,S-diester of the formula ##STR2## at a temperature between about 20.degree. C. and 200.degree. C. Intermediates and a process for their preparation are also disclosed.
    Type: Grant
    Filed: August 17, 1989
    Date of Patent: November 6, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventor: Hans-Jochem Riebel
  • Patent number: 4802910
    Abstract: Novel herbicides of the formula ##STR1## in which R.sup.1 represents an organic radical,R.sup.2 represents hydrogen or an organic radical,R.sup.3 represents an organic radical or an amino radical,R.sup.4 represents hydrogen, an organic radical, an ether radical or an amino radical,X represents N or CH,Y and Z each represent N, CH or a substituted C radical, andM is H, a metal ion or an acyl radical, or a strong acid adduct thereof. Some intermediates are also new.
    Type: Grant
    Filed: January 20, 1987
    Date of Patent: February 7, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rolf Kirsten, Joachim Kluth, Klaus-Helmut Muller, Theodor Pfister, Hans-Jochem Riebel, Hans-Joachim Santel, Robert R. Schmidt
  • Patent number: 4742118
    Abstract: Novel s-triazine compounds containing at least one N,N-bis(alkoxy or hydroxyalkoxy-carbonyl-amino C.sub.2 -C.sub.10 alkyl) amino substituent function in self-condensation and as crosslinkers for compounds containing active hydrogen groups. The compositions cure to coatings with excellent properties, especially corrosion resistance, humidity resistance, abrasion resistance and flexibility. The coatings have excellent exterior durability.
    Type: Grant
    Filed: May 16, 1986
    Date of Patent: May 3, 1988
    Assignee: American Cyanamid Company
    Inventor: Girish G. Parekh
  • Patent number: 4727141
    Abstract: A process for preparing trichloromelamine starting from chlorine and melamine, with intermediate formation of an aqueous suspension of hexachloromelamine, characterized in that hexachloromelamine is solubilized by addition of a water-immiscible solvent, the aqueous phase is separated and the hexachloromelamine solution is brought into contact, in the presence of an activator, with a number of melamine moles which is equal to or lower than the number of moles of the remaining hexachloromelamine.
    Type: Grant
    Filed: March 25, 1987
    Date of Patent: February 23, 1988
    Assignee: Montedipe S.p.A.
    Inventors: Giampietro Corso, Vaifro Busati, Dino Dall'Acqua, Gianpietro Talamini
  • Patent number: 4718937
    Abstract: The compounds of the general formula (I) ##STR1## in which X denotes O or --SO.sub.2 --, Y denotes CH or N, R.sub.1 denotes alkyl, alkenyl or (C.sub.2 -C.sub.6)-alkinyl which are optionally substituted, R.sub.2 denotes alkyl, alkenyl, alkinyl or cyclohexyl, R.sub.3 and R.sub.4 denote H or alkyl, and R.sub.5 and R.sub.6 denote H, (substituted) alkyl, (substituted) alkoxy, halogen, alkylthio, monoalkylamino or dialkylamino, and also salts thereof, possess advantageous herbicidal properties against monocotyledonous and dicotyledonous weeds and are suitable for selective use in large-scale crops. In addition, they possess a good plant growth-regulating action.
    Type: Grant
    Filed: April 9, 1986
    Date of Patent: January 12, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Lothar Willms, Hilmar Mildenberger, Klaus Bauer, Helmut Burstell
  • Patent number: 4657908
    Abstract: The invention relates to carbonyl derivatives which are histamine H-2 antagonists and which inhibit gastric acid secretion. According to the invention where is provided a guanidine derivative of the formula I: ##STR1## in which R.sup.1 and R.sup.2, same or different, are hydrogen or 1-10C alkyl, 3-8C cycloalkyl or 4-14C cycloalkylalkyl, each alkyl, cycloalkyl or cycloalkylalkyl optionally carrying one or more F, Cl or Br atoms, provided that one of R.sup.1 and R.sup.2 is halogen substituted, or R.sup.2 is hydrogen and R.sup.1 is R.sup.5 -E-W in which W is 2-6C alkylene optionally substituted by 1 or 2 1-4C alkyls, E is O, S, SO, SO.sub.2 or NR.sup.6 in which R.sup.6 is H or 1-6C alkyl, R.sup.5 is H or 1-6C alkyl optionally substituted by 1 or 2 1-4C alkyls, or R.sup.5 and R.sup.6 are joined to form a pyrrolidine, piperidine, morpholine, piperazine or N-methylpiperazine ring, or R.sup.2 is H and R.sup.
    Type: Grant
    Filed: February 12, 1985
    Date of Patent: April 14, 1987
    Assignees: ICI Americas, Inc., Imperial Chemical Industries PLC
    Inventors: Tobias O. Yellin, David J. Gilman, Philip N. Edwards, Michael S. Large, Derrick F. Jones, Keith Oldham
  • Patent number: 4626589
    Abstract: A compound of the formula, ##STR1## wherein D is an organic dye moiety, R.sub.1 and R.sub.2 are independently hydrogen or a substituted or unsubstituted lower alkyl group, R.sub.3 is hydrogen or a substituted or unsubstituted lower alkyl, phenyl or naphthyl group, X.sub.1 and X.sub.2 are independently hydrogen, halogen or a lower alkyl, cyano, carbamoyl, vinyl, .beta.-hydroxyethyl, .beta.-sulfoethyl, .beta.-sulfatoethyl, carboxyl, carboxylic acid ester or sulfonic acid group, and Z is appended to the above-defined D or R.sub.3 and stands for --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y, in which Y is a group capable of being split by the action of an alkali, which is useful for dyeing hydroxyl or amido group-containing fiber materials with excellent build-up properties, thereby giving dyed products having excellent various fastness properties.
    Type: Grant
    Filed: February 7, 1985
    Date of Patent: December 2, 1986
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takashi Omura, Yutaka Kayane, Mikoto Takahashi, Tetsuya Miyamoto, Akira Takeshita, Naoki Harada, Katsumasa Otake
  • Patent number: 4602938
    Abstract: Guanidine derivatives of the formula ##STR1## in which R.sup.2 represents a six-membered aromatic heterocyclic structure which contains at least one nitrogen atom and is substituted by halogen, amino, cyano or formyl and/or by optionally substituted radicals from the series comprising alkyl, alkoxy, alkylamino, dialkylamino, alkylcarbonyl and alkoxycarbonyl, and/or is optionally fused,R.sup.3 represents hydrogen, an optionally substituted radical from the series comprising alkyl, cycloalkyl, alkenyl, alkinyl and aralkyl, or the radical --S(O).sub.n --R.sup.6,the other radicals can have varied meanings, andacid adducts and salts thereof,which possess herbicidal and plant growth regulating activity.
    Type: Grant
    Filed: February 9, 1984
    Date of Patent: July 29, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Koichi Moriya, Theodor Pfister, Hans-Jochem Riebel, Ludwig Eue, Robert R. Schmidt, Klaus Lurssen
  • Patent number: 4588811
    Abstract: There are described novel cationic quinophthalone compounds of the formula I ##STR1## wherein the symbols have the meanings defined in claim 1, and also processes for producing them. These novel quinophthalone compounds can be used in particular as dyes for dyeing and printing paper, greenish-yellow dyeings having good fastness to water and to light being obtained.
    Type: Grant
    Filed: November 19, 1984
    Date of Patent: May 13, 1986
    Assignee: Ciba-Geigy Corporation
    Inventor: Jean-Marie Adam
  • Patent number: 4477498
    Abstract: The present invention relates to new condensation products of(A) 1 mole of a highly etherified hexamethylol melamine and(B) 3 to 6 moles of a thiol of the formulaR.sub.f --X--SH, (1)Rf standing for perfluorinated alkyl with 4 to 14 C-atoms and X for divalent ethylene or isopropylene radicals, wherein the components (A) and (B) are reacted under increasing temperature up to at least 145.degree. C. within a period of at least 40 minutes.In form of their aqueous dispersions, the condensation products are suitable for oil- and water-repellent finishing of fibrous, preferably textile materials.
    Type: Grant
    Filed: August 13, 1982
    Date of Patent: October 16, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans Deiner, Franz Mosch, Bernhard Sandner, Willy Bernheim
  • Patent number: 4460769
    Abstract: Vulcanizable rubber compositions are described which are inhibited from premature vulcanization by thio-substituted-1,3,5-triazine-diamine or -triamine.
    Type: Grant
    Filed: February 3, 1983
    Date of Patent: July 17, 1984
    Assignee: Monsanto Company
    Inventor: Eiichi Morita
  • Patent number: 4440565
    Abstract: Compounds of the formula ##STR1## wherein R.sub.1 denotes an aliphatic radical which is optionally substituted by halogen and/or interrupted by oxygen, R.sub.2 and R.sub.3 denote H or alkyl, X denotes oxygen or sulfur, m denotes 0 or 1, and R.sub.4 denotes an optionally substituted six-membered heterocyclic ring having 2-3 N atoms, are effective herbicides and growth regulators.
    Type: Grant
    Filed: March 22, 1982
    Date of Patent: April 3, 1984
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Lothar Willms, Hilmar Mildenberger, Dieter Gunther, Klaus Bauer, Helmut Burstell, Hermann Bieringer
  • Patent number: 4412856
    Abstract: The novel compounds of the formula I are useful selective herbicides for postemergence application in crops of cereals, maize and rice.In formula I, ##STR1## A is an unsubstituted or substituted amino group, Q is a C.sub.2 -C.sub.6 alkylene bridge, Y is an oxygen or sulfur atom or an unsubstituted or substituted nitrogen atom, and Z is an unsubstituted or substituted phenyl, naphthyl or heterocyclic radical, which phenyl radical, containing the bridge member Y, can additionally carry one to four further substituents.
    Type: Grant
    Filed: May 22, 1981
    Date of Patent: November 1, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans-Georg Brunner, Rolf Schurter, Henry Szczepanski
  • Patent number: 4339577
    Abstract: Vulcanizable rubber compositions inhibited from premature vulcanization by 2-(thioamino)-4,6-diamino-1,3,5-triazines are described.
    Type: Grant
    Filed: June 1, 1981
    Date of Patent: July 13, 1982
    Assignee: Monsanto Company
    Inventor: Gene R. Wilder
  • Patent number: 4301260
    Abstract: Vulcanizable rubber compositions inhibited from premature vulcanization by 2-(thioamino)-4,6-diamino-1,3,5-triazines are described.
    Type: Grant
    Filed: May 12, 1980
    Date of Patent: November 17, 1981
    Assignee: Monsanto Company
    Inventor: Gene R. Wilder
  • Patent number: 4291162
    Abstract: New compounds of formula ##STR1## where R.sup.1 represents --NR.sup.2 R.sup.3, an alkyl group, a mononuclear aryl group, a phenylalkylene group, or a group of formula ##STR2## R.sup.2 and R.sup.3 each represent --H, --CHR.sup.4 OR.sup.5, --CHR.sup.4 --S--R.sup.6 --COOQ, or ##STR3## R.sup.2 and R.sup.3 in formulae I and III being such that at most one represents a group of formula III and at least two each represent a group --CHR.sup.4 --S--R.sup.6 --COOQ,R.sup.4 and R.sup.5 represent --H or alkyl groups,R.sup.6 is an alkylene group, optionally substituted by a carboxyl group,at least two Q in formula I represent --H and the remainder may alternatively represent alkyl groups,m is 1, 2, or 3, andn is zero or 1,e.g., hexakis(N-2-carboxyethylthiomethyl)melamine, a tris(N-2-carboxyethylthiomethyl)tris(N-2-(butoxymethyl)melamine, or tetrakis(N-2-carboxyethylthiomethyl)acetoguanamine,are useful as curing agents for epoxide resins.
    Type: Grant
    Filed: July 15, 1980
    Date of Patent: September 22, 1981
    Assignee: Ciba-Geigy Corporation
    Inventor: Derek J. R. Massy
  • Patent number: 4287338
    Abstract: The present invention provides novel substituted sulfooxy-pyrimidinium, -pyridinium, and -triazinium hydroxide inner salts. These compounds are useful for the treatment of hypertension and peripheral vascular diseases. They are formed by reacting the corresponding aminopyrimidine, aminotriazine, and aminopyridine N-oxides with a latent sulfate source such as pyridinium-sulfur trioxide complex, triethylamine-sulfur trioxide complex, chlorosulfonic acid or chlorosulfuryl chloride.
    Type: Grant
    Filed: March 10, 1980
    Date of Patent: September 1, 1981
    Assignee: The Upjohn Company
    Inventor: John M. McCall
  • Patent number: 4165435
    Abstract: A s-Triazine of the formula ##STR1## wherein X, Y and Z are radicals of the formula ##STR2## and R are aromatic, cycloaliphatic or aliphatic radicals or hydrogen is provided.The process for the manufacture of such s-Triazines is also provided as well as a process for fireproofing polyester fibres with such s-Triazines. The s-Triazine may also be applied in the presence of a dispersant, a protective colloid and/or water. The composition of matter for performing this process is also provided.
    Type: Grant
    Filed: June 20, 1977
    Date of Patent: August 21, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Armin Hiestand, Peter Rohringer
  • Patent number: 4043995
    Abstract: The present invention relates to a process for crosslinking hydrophilic colloids, preferably gelatine and most preferably gelatine present in a photographic material. A 1,3,5-triazine compound containing an NC--N.sup.- -- substituent bound to the triazine ring is incorporated into the hydrophilic colloid as a crosslinking agent.
    Type: Grant
    Filed: May 19, 1975
    Date of Patent: August 23, 1977
    Assignee: Ciba-Geigy AG
    Inventors: Rainer Kitzing, Norman Alfred Smith