Phosphorus Containing Patents (Class 544/214)
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Patent number: 5350848Abstract: Triazinylphosphonic acids of general formula (I): ##STR1## obtained by subsequent condensation reaction of a cyanuric halide with a osphite and with amines, and then by hydrolysis reaction of the intermediate thus obtained; The compounds of general formula (I) are used in particular as flame retardant additives.Type: GrantFiled: December 15, 1992Date of Patent: September 27, 1994Assignee: Ministero deli'Universita e della Ricerca Scientifica e TecnologicaInventors: Roberto Cipolli, Cristina Rossi, Roberto Oriani, Enrico Masarati, Gilberto Nucida
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Patent number: 5290888Abstract: A process for stabilizing an ethylenically unsaturated monomer or oligomer from premature polymerization is disclosed whereby a stabilizing amount of an N-hydroxy substituted hindered amine is added to said polymerizable monomer or oligomer. The ethylenically unsaturated monomer or oligomer encompass vinyl monomers or oligomers bearing at least one polymerizable moiety. The N-hydroxy substituted hindered amine inhibits premature polymerization in the liquid and/or vapor phase.Type: GrantFiled: October 2, 1992Date of Patent: March 1, 1994Assignee: Ciba-Geigy CorporationInventors: Leslie R. Gatechair, James L. Hyun, Peter J. Schirmann
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Patent number: 5288865Abstract: This invention provides a process for preparing amide derivatives of acids by the reaction of haloaminotriazines and acid halides.This invention also provides a process for preparing isocyanates and isocyanate adducts from amide derivatives derived from haloaminotriazines and acid halides such as oxalyl chloride, phosgene and phosgene analogs.Melamine derived acid amides are prepared by reaction of trichloro and hexachloromelamines with chloroformates and acid chlorides. The by-product chlorine may be recycled in this process.Amides, carbamates, sulfonamides, phosphoramides, and related amide derivatives may be prepared by the novel processes of the invention.Type: GrantFiled: October 30, 1992Date of Patent: February 22, 1994Assignee: American Cyanamid CompanyInventor: Ram B. Gupta
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Patent number: 5250521Abstract: Novel substituted pyrazolopyrimidines of formula (I) which are useful as angiotensin II antagonists, are disclosed.Type: GrantFiled: November 25, 1991Date of Patent: October 5, 1993Assignee: Merck & Co., Inc.Inventors: Eric E. Allen, William J. Greenlee, Prasun K. Chakravarty, Malcolm MacCoss, Arthur A. Patchett, Thomas F. Walsh
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Patent number: 5240499Abstract: Polymeric, water-soluble triazine compounds which contain both basic and acidic groups in the molecule have out-standing surfactant properties and are suitable for the preparation of dispersions of solids, preferably of dispersions of inorganic and/or organic pigments, in an aqueous or water-dilutable medium. Since these triazine compounds are colorless or only slightly colored, they do not influence the shade of the medium used.Type: GrantFiled: December 13, 1991Date of Patent: August 31, 1993Assignee: Hoechst AktiengesellschaftInventors: Rainer Az, Wolfgang Schwab, Dieter Schnaitmann, Erwin Dietz
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Patent number: 5210191Abstract: Substituted alkoxy- or alkylthiochlorotriazines wherein the substituents on the alkoxy groups are chlorine, bromine or dialkylphosphato are useful as capping agents for polyphenylene ethers. The capped polyphenylene ethers form copolymers with other polymers containing nucleophilic groups, including polyesters, polyamides and functionalized olefin polymers. Such copolymers serve as compatibilizers in the formation of blends having high impact strength.Type: GrantFiled: November 4, 1991Date of Patent: May 11, 1993Assignee: General Electric CompanyInventors: Otto Phanstiel, Sterling B. Brown
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Patent number: 5159075Abstract: Substituted alkoxy- or alkylthiochlorotriazines wherein the substituents on the alkoxy groups are chlorine, bromine or dialkylphosphato are useful as capping agents for polyphenylene ethers. The capped polyphenylene ethers form copolymers with other polymers containing nucleophilic groups, including polyesters, polyamides and functionalized olefin polymers. Such copolymers serve as compatibilizers in the formation of blends having high impact strength.Type: GrantFiled: February 11, 1991Date of Patent: October 27, 1992Assignee: General Electric CompanyInventors: Otto Phanstiel, Sterling B. Brown
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Patent number: 5158999Abstract: Compounds having a nucleus of general formula (I): ##STR1## in which: n is an integer and has a value of at least 2;R.sup.1 represents an alkyl group comprising up to 20 carbon atoms; andR.sup.2 represents ##STR2## where R.sup.3 represents an alkyl group comprising up to 20 carbon atoms or an aryl nucleus comprising up to 10 carbon atoms, or R.sup.2 represents a heterocyclic ring nucleus comprising from 4 to 8 ring atoms, at least one atom comprising nitrogen and linking the ring nucleus to the triazine ring. Compounds of formula (I) are suitable for use as a flame retardant additive for polymer materials, particularly when used in combination with a second and different source of phosphorus. The flame retarded polymers are particularly suitable for use in wire and cable insulation, dimensionally recoverable products, molded parts, extruded tubings, pipes and tape type constructions.Type: GrantFiled: August 13, 1990Date of Patent: October 27, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Timothy G. Swales, Alan J. Lindsay, Linda M. Doolan
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Patent number: 5120843Abstract: The aromatic amines (I), alkyl amines (II), bicyclic amines (III). ##STR1## cycloalkyl amines (IV), aromatic bicyclic amines (V), hydroquinone amines (VI), quinone amines (VII), amino-ethers (VIII) and bicyclic amino ethers (IX) are useful as pharmaceutical agents for treating a number of conditions including spinal trauma, mild and/or moderate to severe head injury, etc. Also disclosed is a method of treatment using the 3,4-dihydrobenzopyrans (XI).Type: GrantFiled: October 23, 1989Date of Patent: June 9, 1992Assignee: UpjohnInventors: John M. McCall, Donald E. Ayer, E. Jon Jacobsen, Frederick J. VanDoornik, John R. Palmer
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Patent number: 5108487Abstract: This invention relates to a novel class of sulfonylureas and their use as herbicides and plant growth regulants.Type: GrantFiled: March 8, 1990Date of Patent: April 28, 1992Assignee: E. I. Du Pont de Nemours and CompanyInventor: Stephen K. Gee
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Patent number: 5071840Abstract: The present invention relates to novel heterocycle-substituted diphosphonic acids, and the pharmaceutically-acceptable salts and esters thereof, in which the diphosphonate-substituted carbon atom moiety is attached to a carbon atom in a nitrogen-containing six membered ring heterocycle, preferably a piperidine ring. The heterocycle-substituted diphosphonic acid compounds have the general structure: ##STR1## wherein Z is a nitrogen-containing six membered ring heterocycle moiety selected from piperidinyl, diazinyl and triazinyl; m, n and m+n are from 0 to 10; Q is a covalent bond or a moiety selected from oxygen, sulfur or nitrogen; and R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are substituent groups.The present invention further relates to pharmaceutical compositions containing these novel compounds. Finally this invention relates to methods for treating or preventing diseases characterized by abnormal calcium and phosphate metabolism by utilizing a compound or pharmaceutical composition of the present invention.Type: GrantFiled: July 11, 1989Date of Patent: December 10, 1991Assignee: Norwich Eaton Pharmaceuticals, Inc.Inventors: Frank H. Ebetino, James J. Benedict
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Patent number: 4968797Abstract: 4,4-diaryldihydroquinazolones of the formula ##STR1## wherein X.sup.1, X.sup.2 and X.sup.3, independently of one another, denote hydrogen, halogen, alkyl, aryl, alkanoylamino, aroylamino, heteryl, NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3, at least one of the radicalsX.sup.1, X.sup.2 or X.sup.3 standing for NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl or the members of a bridge to the o-carbon of ring C,R.sup.2 denotes a radical of an acid,Y.sup.1, Y.sup.2 and Y.sup.3, independently of one another, denote hydrogen, alkyl, cycloalkyl, aralkyl aryl or heteryl or the remaining members of a 5- or 6-membered ring which reaches to one of the o-position benzene C atoms and may contain further hetero atoms orY.sup.1 +Y.sup.Type: GrantFiled: October 30, 1987Date of Patent: November 6, 1990Assignee: Bayer AktiengesellschaftInventors: Horst Berneth, Alfred Brack, Karlheinrich Meisel
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Patent number: 4957921Abstract: Substituted cyclohexanols are described, as well as methods for the preparation and pharmaceutical composition of same, which are useful as central nervous system agents and are particularly useful as dopaminergic, antipsychotic, and antihypertensive agents as well as for treating hyperprolactinaemia-related conditions and central nervous system disorders.Type: GrantFiled: December 6, 1989Date of Patent: September 18, 1990Assignee: Warner-Lambert CompanyInventors: Bradley W. Caprathe, Juan C. Jaen, Sarah J. Smith, Lawrence D. Wise
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Patent number: 4948419Abstract: This invention relates to certain novel pyridine sulfonamide compounds, to compositions containing such compounds, and to a method of use of such compositions to control the growth of undesired vegetation.Type: GrantFiled: February 15, 1989Date of Patent: August 14, 1990Assignee: E. I. du Pont de Nemours and CompanyInventors: Mary A. Hanagan, Barry A. Wexler
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Patent number: 4948416Abstract: This invention relates to novel condensed ring sulfonylureas and their use as herbicides and growth regulants.Type: GrantFiled: March 27, 1989Date of Patent: August 14, 1990Assignee: E. I. du Pont de Nemours and CompanyInventor: Robert J. Pasteris
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Patent number: 4812161Abstract: Thia-diazole derivatives having the following partial structural formula had selective herbicidal activity on some crops.Type: GrantFiled: July 29, 1985Date of Patent: March 14, 1989Assignee: Nippon Soda Co., Ltd.Inventors: Kenji Hagiwara, Hisao Ishikawa, Hideo Hosaka, Hideo Inaba
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Patent number: 4803234Abstract: Compounds of formula (I) ##STR1## in which R.sub.1 is hydrogen, O.sup.., CN, NO, cyanomethyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.12 -alkenyl or C.sub.3 -C.sub.12 -alkynyl subject to the proviso that the carbon atom attached to the nitrogen atom is a primary carbon atom, C.sub.7 -C.sub.12 -aralkyl, C.sub.1 -C.sub.12 -acyl, 2,3-epoxypropyl, OH-monosubstituted C.sub.2 -C.sub.6 -alkyl or 2,3-dihydroxypropyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.18 -cycloalkyl, C.sub.6 -Chd 18-aryl or C.sub.7 -C.sub.18 -aralkyl, R.sub.3 is C.sub.6 -C.sub.18 -aryl or a group of the formula (II) ##STR2## in which R.sub.1 is as defined above, n is an integer from 1 to 4 and R.sub.4 is an organic or inorganic radical of a valency equal to n are useful for stabilizing organic material against oxidative, thermal and/or light induced degradation.Type: GrantFiled: January 29, 1987Date of Patent: February 7, 1989Assignee: Ciba-Geigy CorporationInventors: Giuseppe Cantatore, Valerio Borzatta
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Patent number: 4795815Abstract: 1,2,4-Trisubstituted diazolidinones are intermediates to bicyclic pyrazolidinone antimicrobial compounds.Type: GrantFiled: October 29, 1987Date of Patent: January 3, 1989Assignee: Eli Lilly and CompanyInventor: Robert J. Ternansky
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Patent number: 4754034Abstract: 4,4-diaryldihydroquinazolones of the formula ##STR1## wherein X.sup.1, X.sup.2 and X.sup.3, independently of one another, denote hydrogen, halogen, alkyl, aryl, alkanoylamino, aroylamino, heteryl, NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3, at least one of the radicals X.sup.1, X.sup.2 or X.sup.3 standing for NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl or the members of a bridge to the o-carbon of ring C,R.sup.2 denotes a radical of an acid,Y.sup.1, Y.sup.2 and Y.sup.3, independently of one another, denote hydrogen, alkyl, cycloalkyl, aralkyl aryl or heteryl or the remaining members of a 5- or 6-membered ring which reaches to one of the o-position benzene C atoms and may contain further hetero atoms orY.sup.1 +Y.sup.Type: GrantFiled: October 21, 1985Date of Patent: June 28, 1988Assignee: Bayer AktiengesellschaftInventors: Horst Berneth, Alfred Brack, Karlheinrich Meisel
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Patent number: 4719045Abstract: A flame retardant for polyolefins, which comprises as an effective ingredient a hardly water-soluble or water-insoluble, nitrogen-containing phosphorus compound obtained by mixing 100 parts by weight of a condensed phosphoric acid compound with 10 to 100 parts by weight of a triazine compound and heating the mixture at 100.degree. to 250.degree. C. in the presence or absence of water.Type: GrantFiled: April 11, 1986Date of Patent: January 12, 1988Assignee: Marubishi Yuka Kogyo Kabushiki KaishaInventors: Yoshikatsu Ogawa, Haruhiko Hisada, Takeshi Kasahara, Fumihiko Kizaki, Masahide Yoshiya
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Patent number: 4716232Abstract: 1-(Vinyl phosphonate adduct) pyrazolidinones are intermediates to bicyclic pyrazolidinone antimicrobial compounds.Type: GrantFiled: May 14, 1986Date of Patent: December 29, 1987Assignee: Eli Lilly and CompanyInventor: Robert J. Ternansky
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Patent number: 4610824Abstract: Antibacterial activity is exhibited by novel compounds having the formula ##STR1## and pharmaceutically acceptable salts thereof.Type: GrantFiled: October 9, 1984Date of Patent: September 9, 1986Assignee: E. R. Squibb & Sons, Inc.Inventor: Uwe D. Truner
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Patent number: 4592865Abstract: Intermediates of the following formula are useful for the synthesis of 1-oxacephalosporins. Their preparation from penicillins and the transformation process to make 1-oxacephalosporins are disclosed. The compounds are of the formula: ##STR1## wherein A is amino or a selected acylamino;COB is carboxy or a selected protected-carboxy;X is halogen or the group ORin which R is a group represented by following formulas: ##STR2## wherein Nu is a selected nucleophilic group; R.sup.1 is a group of the following formula: ##STR3## in which Hal is halogen or alkylsulfonyloxy and R.sup.2 is alkyl or aryl; andY is hydrogen or methoxy; with the proviso that when R is propargyl or 2-oxopropyl andR.sup.1 is ##STR4## A is in the 3.alpha.-configuration and Y is 3.beta.-hydrogen or A is in the 3.beta.-configuration and Y is 3.alpha.-methoxy.Type: GrantFiled: March 13, 1984Date of Patent: June 3, 1986Assignee: Shionogi & Co., Ltd.Inventors: Masayuki Narisada, Hiroshi Onoue, Teruji Tsuji, Yasuhiro Nishitani, Mitsuru Yoshioka, Yoshio Hamashima, Wataru Nagata
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Patent number: 4562185Abstract: The present invention relates to combating pests with five-membered nitrogen-containing heterocyclic compounds of the formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3, X and Y have the meaning given in the description. Many of the compounds are new.Type: GrantFiled: March 15, 1984Date of Patent: December 31, 1985Assignee: Bayer AktiengesellschaftInventors: Gerhard Jager, Rudolf Fauss, Kurt Findeisen, Benedikt Becker, Bernhard Homeyer
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Patent number: 4556710Abstract: The invention is phosphono-s-triazines corresponding to the formula ##STR1## wherein: X is separately in each occurrence chlorine, bromine, haloalkyl or alkyl;Y is separately in each occurrence hydrogen, chlorine or bromine;R is separately in each occurrence hydrogen, hydrocarbyl, CH.sub.2 Y, CH.sub.2 OH or CH.sub.2 OC(R.sup.1).sub.3 wherein R.sup.1 is alkyl;a is an integer from 0 to 2 inclusive; andb is an integer from 1 to 3 inclusive, with the proviso that the sum of a and b equal 3, and with the further proviso that at least one R is CH.sub.2 OH or CH.sub.2 OC(R.sup.1).sub.3.Type: GrantFiled: March 18, 1983Date of Patent: December 3, 1985Assignee: The Dow Chemical CompanyInventors: Chester E. Pawloski, Sally P. Ginter
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Patent number: 4551527Abstract: A process for preparing polyvalent metal and amine salts of the indicated phosphorinane (an acid). The salts are isolated as such and are effective, in small proportions, to impart flame-retardant properties to polymers, especially to polypropylene and to styrenic polymers such as polystyrene, ABS and MBS.Type: GrantFiled: July 2, 1981Date of Patent: November 5, 1985Assignee: Borg-Warner Chemicals, Inc.Inventors: Yuval Halpern, Donna Mott
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Patent number: 4546180Abstract: A process for preparing certain phosphite-isocyanurate oligomers. The process requires the reaction of a trishydroxyalkyl isocyanurate with a tris-organophosphite and, optionally, an alcohol or alkylphenol. The process is promoted by an alkaline catalyst such as sodium methoxide. The oligomeric product is useful as a thermal stabilizer in polymer compositions.Type: GrantFiled: April 19, 1983Date of Patent: October 8, 1985Assignee: Borg-Warner Chemicals, Inc.Inventors: Leo L. Valdiserri, Richard P. Woodbury
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Patent number: 4528284Abstract: Phosphoric acid esters of the formula ##STR1## wherein X is CH or N,Ar is optionally substituted phenyl, diphenyl or naphthyl,R is cyano, carboxylic acid ester, carboxylic acid thioester or carboxylic acid amide.R.sub.10 is alkyl,R.sub.11 alkyl, alkoxy, alkylthio or phenyl, andY is sulfur.For R: the ester groups are alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl, alkyl interrupted by oxygen or sulfur and optionally substituted by halogen, phenyl, carboxylic acid ester, alkylcarbonyl, optionally substituted phenyl carbonyl, or a C.sub.5 or C.sub.6 heterocycle; the thioester groups are alkyl or optionally substituted phenyl or benzyl; the amide is optionally mono- or di-substituted by alkyl, cycloalkyl, optionally substituted phenyl or benzyl, or may form a C.sub.5 or C.sub.6 heterocyclic ring. The compounds are useful in controlling phytopathogenic fungi.Type: GrantFiled: October 5, 1983Date of Patent: July 9, 1985Assignee: Ciba-Geigy CorporationInventors: Wolfgang Eckhardt, Walter Kunz
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Patent number: 4479946Abstract: Novel phosphorus esters of amidoximes and methods of preparing same. This invention is also directed to pesticidal compositions comprising an acceptable carrier and a pesticidally effective amount of a compound of this invention, as well as to a method of controlling pests which comprises subjecting the pests to a pesticidally effective amount of a compound of this invention.Type: GrantFiled: June 17, 1982Date of Patent: October 30, 1984Assignee: Union Carbide CorporationInventors: Leonard E. Hodakowski, Dean F. Bushey
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Patent number: 4435338Abstract: The compounds according to the invention correspond to the formula I ##STR1## in which R is a hydrocarbon radical, A is one of the groups --O.CO--, --O-- or ##STR2## (in which m is 0-30) and Q, depending on the definition of A, is a hydrocarbon radical, a P-containing radical, an N-heterocyclic group or a radical containing N-heterocyclic groups.The compounds according to the invention also include those which are formed by an addition reaction of an O,O-dialkyl dithiophosphate with an epoxidised soybean oil.The compounds according to the invention are very useful as lubricant additives.Type: GrantFiled: September 21, 1981Date of Patent: March 6, 1984Assignee: Ciba-Geigy CorporationInventors: Klaus-Peter Michaelis, Rainer Schneider
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Patent number: 4429124Abstract: A method for preparing N-phosphonomethylglycine comprising (a) O,O-dialkylaminomethylphosphonate with formaldehyde to produce a triazine; (b) reacting the triazine formed in step (a) with an acyl halide to form the O,O-dialkyl-N-phosphonomethyl-N-chloromethyl acetamide of the acyl halide; (c) reacting the amide formed in step (b) with metal cyanide to form O,O-dialkyl-N-cyanomethyl-N-acetamide; and (d) hydrolyzing the acetamide formed in step (c) to yield N-phosphonomethylglycine.Type: GrantFiled: August 23, 1982Date of Patent: January 31, 1984Assignee: Stauffer Chemical CompanyInventor: Raymond A. Felix
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Patent number: 4376857Abstract: Certain phosphite-isocyanurate oligomers and their use as thermal stabilizers in polymer compositions. The phosphite-isocyanurates may be prepared from a tris-hydroxyalkyl isocyanurate by reaction with an organic phosphite such as triphenyl phosphite or tributyl phosphite. Optionally, an alcohol such as decyl alcohol may be employed as a reactant.Type: GrantFiled: September 3, 1981Date of Patent: March 15, 1983Assignee: Borg-Warner CorporationInventors: Leo L. Valdiserri, Richard P. Woodbury
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Patent number: 4362830Abstract: Hindered bis-phenol phenyl phosphites are provided having the structure: ##STR1## wherein: R is selected from the group consisting of alkyl having from one up to about eighteen carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about eighteen carbon atoms; preferably, a bulky group such as iso, secondary or tertiary alkyl having from three to about ten carbon atoms; or cycloalkyl having six to twelve carbon atoms;R.sub.1 and R.sub.2 are each selected from the group consisting of hydrogen; alkyl having from one to about eighteen carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about eighteen carbon atoms; and are preferably in a position ortho to a phenolic hydroxyl or phenoxy group, if available;R.sub.3 is alkylene having from one to about six carbon atoms;R.sub.Type: GrantFiled: December 29, 1980Date of Patent: December 7, 1982Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Motonobu Minagawa, Yutaka Nakahara
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Patent number: 4320126Abstract: Organophosphorus esters of the formula (I), ##STR1## wherein R is a C.sub.1 -C.sub.2 alkyl group, R.sub.1 is a C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 alkoxy, C.sub.1 -C.sub.4 alkylamino, phenyl or phenoxy group, R.sub.2 and R.sub.3, which may be the same or different, are each a C.sub.1 -C.sub.5 alkyl or methoxy C.sub.2 -C.sub.3 alkyl group and X is an oxygen or sulfur atom, a method for producing organophosphorus esters of the formula (I) characterized by condensation reaction of s-triazines of the formula, ##STR2## wherein M is a potassium or sodium atom and R.sub.2 and R.sub.3 are as defined above, with a halogenated compound of the formula, ##STR3## wherein Y is a halogen atom and R, R.sub.1 and X are as defined above, and an insecticide, acaricide and/or nematocide characterized by containing organophosphorus esters of the formula (I) as an active ingredient.Type: GrantFiled: August 27, 1979Date of Patent: March 16, 1982Assignee: Sumitomo Chemical Company, LimitedInventors: Takayuki Okabe, Kunio Mukai, Masachika Hirano
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Patent number: 4303652Abstract: Organophosphorus esters, useful in increasing the resistance of keratinous materials to attack by keratin-eating insects, have the general formula: ##STR1## wherein: X and Y are independently O or S;R.sub.1 is an alkyl, alkoxy, alkylamino, dialkylamino or alkylmercapto radical having 1 to 6 carbon atoms;an amino or aryl radical;R.sub.2 is an alkyl radical having 1 to 6 carbon atoms;R.sub.3 is a radical of the general formula:-J-(K-L).sub.n (2)wherein:J is an aliphatic radical, or radical containing an aromatic or heterocyclic ring;K is one of the following radicals: ##STR2## linked to J through the oxygen atom in the case of (3), (5) or (6), and through the nitrogen atom in the case of (4), and in which the carbonyl oxygen atom of (3), (4) or (5), or one or both carbonyl oxygen atoms of (6) may be replaced by sulphur; R.sub.Type: GrantFiled: August 30, 1978Date of Patent: December 1, 1981Assignee: Commonwealth Scientific and Industrial Research OrganizationInventors: Francis W. Jones, Robert J. Mayfield, Gary J. O'Loughlin
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Patent number: 4298520Abstract: This invention relates to a new class of phenolic compounds containing a phosphorus acid ester group which are stabilizers for synthetic resins and to synthetic resin stabilizer compositions comprising these phenolic compounds as well as to synthetic resins stabilized with such phenolic compounds and with stabilizer compositions comprising these phenolic compounds along with known polymer stabilizers.Type: GrantFiled: October 11, 1979Date of Patent: November 3, 1981Assignee: Argus Chemical Corp.Inventors: Motonobu Minagawa, Yutaka Nakahara, Masayuki Takahashi
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Patent number: 4297492Abstract: Novel oligomeric and polymeric phenolic 1,3,5-triazines, for example those of the formula ##STR1## their preparation and their use for stabilizing organic material and also the organic material protected against oxidative and light-induced degradation with the aid of these compounds.Type: GrantFiled: March 10, 1980Date of Patent: October 27, 1981Assignee: Ciba-Geigy CorporationInventors: Michael Rasberger, Siegfried Rosenberger, Samuel Evans
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Patent number: 4287339Abstract: This invention of the present application relates to the stabilizing component in the stabilization of olefin polymers, especially polypropylene during processing, i.e., at elevated temperatures. The stabilizing component is a phosphite-isocyanurate compound having the structural formula: ##STR1## wherein R is a hydrocarbon radical and R.sup.1 is methyl or hydrogen.Type: GrantFiled: February 29, 1980Date of Patent: September 1, 1981Assignee: Borg-Warner CorporationInventor: Leo L. Valdiserri
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Patent number: 4260779Abstract: Oxothia compounds, especially 2-oxo-2,3-dihydro-benzo[b]thiophene compounds of the formula ##STR1## in which Ph represents an optionally substituted 1,2-phenylene radical, X represents oxygen or sulphur, R.sub.1 represents an organic radical bonded via a carbon atom and R.sub.2 denotes hydrogen or an optionally substituted hydrocarbon radical of aliphatic character, and their salts are useful as peripheral analgetics and/or as antiphlogistic uricosuric and/or thrombolytic agents.Type: GrantFiled: November 9, 1979Date of Patent: April 7, 1981Assignee: Ciba-Geigy CorporationInventors: Raymond Bernasconi, Pier G. Ferrini, Richard Goschke, Jacques Gosteli
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Patent number: 4161592Abstract: New 1,3,5-triazines containing at least one hindered phenolic moiety and at least one hindered amine moiety are useful light stabilizers and antioxidants for polymeric materials.Type: GrantFiled: July 1, 1977Date of Patent: July 17, 1979Assignee: Ciba-Geigy CorporationInventors: Samuel Evans, Michael Rasberger
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Patent number: 4151356Abstract: A triazine of the formula I ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.18 -aryl, C.sub.7 -C.sub.18 -aralkyl or a radical of the formula II or III ##STR2## in which R.sub.3 is hydrogen or C.sub.1 -C.sub.8 -alkyl and R.sub.4 is hydrogen, oxyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.4 -alkinyl, C.sub.2 -C.sub.21 -alkoxyalkyl, C.sub.7 -C.sub.8 -aralkyl, 2,3-epoxypropyl, an aliphatic acyl group with 1-9 C atoms or one of the groups --CH.sub.2 COOR.sub.5, --CH.sub.2 --CH(R.sub.6)--OR.sub.7, --COOR.sub.8 or --CONHR.sub.8, in which R.sub.5 is C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.6 -alkenyl, phenyl, C.sub.7 -C.sub.8 -aralkyl or cyclohexyl and R.sub.6 is hydrogen, methyl or phenyl and R.sub.7 denotes hydrogen, an aliphatic or aromatic, araliphatic or alicyclic acyl group with 1-18 C atoms, in which the aromatic part can optionally be substituted by chlorine, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.Type: GrantFiled: October 11, 1977Date of Patent: April 24, 1979Assignee: Ciba-Geigy CorporationInventors: Samuel Evans, Michael Rasberger
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Patent number: 4145547Abstract: Novel ureidoalkylphosphonates, methods for their prepration as well as for their use in preparing durable, flameproof finishes for textiles are disclosed. These ureidoalkylphosphonates are found to be low in cost, readily prepared and of minimal toxicity.Type: GrantFiled: May 26, 1977Date of Patent: March 20, 1979Assignee: Stauffer Chemical CompanyInventor: Edward D. Weil
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Patent number: 4140660Abstract: Flame-retarding compounds are disclosed which are of the formula ##STR1## wherein X is a phosphorus derivative.Type: GrantFiled: October 17, 1977Date of Patent: February 20, 1979Assignee: Stamicarbon, B.V.Inventors: Marinus J. A. M. Den Otter, Albert A. Van Geenen, Anne Te Mijenhuis
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Patent number: 4085283Abstract: Flame retarding compounds are disclosed which are of the formula ##STR1## wherein X is a phosphonate derivative.Type: GrantFiled: April 19, 1976Date of Patent: April 18, 1978Assignee: Stamicarbon, B.V.Inventors: Marinus J. A. M. Den Otter, Albert A. Van Geenen, Anne Te Nijenhuis