Phosphorus Containing Patents (Class 544/214)
  • Patent number: 5350848
    Abstract: Triazinylphosphonic acids of general formula (I): ##STR1## obtained by subsequent condensation reaction of a cyanuric halide with a osphite and with amines, and then by hydrolysis reaction of the intermediate thus obtained; The compounds of general formula (I) are used in particular as flame retardant additives.
    Type: Grant
    Filed: December 15, 1992
    Date of Patent: September 27, 1994
    Assignee: Ministero deli'Universita e della Ricerca Scientifica e Tecnologica
    Inventors: Roberto Cipolli, Cristina Rossi, Roberto Oriani, Enrico Masarati, Gilberto Nucida
  • Patent number: 5290888
    Abstract: A process for stabilizing an ethylenically unsaturated monomer or oligomer from premature polymerization is disclosed whereby a stabilizing amount of an N-hydroxy substituted hindered amine is added to said polymerizable monomer or oligomer. The ethylenically unsaturated monomer or oligomer encompass vinyl monomers or oligomers bearing at least one polymerizable moiety. The N-hydroxy substituted hindered amine inhibits premature polymerization in the liquid and/or vapor phase.
    Type: Grant
    Filed: October 2, 1992
    Date of Patent: March 1, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Leslie R. Gatechair, James L. Hyun, Peter J. Schirmann
  • Patent number: 5288865
    Abstract: This invention provides a process for preparing amide derivatives of acids by the reaction of haloaminotriazines and acid halides.This invention also provides a process for preparing isocyanates and isocyanate adducts from amide derivatives derived from haloaminotriazines and acid halides such as oxalyl chloride, phosgene and phosgene analogs.Melamine derived acid amides are prepared by reaction of trichloro and hexachloromelamines with chloroformates and acid chlorides. The by-product chlorine may be recycled in this process.Amides, carbamates, sulfonamides, phosphoramides, and related amide derivatives may be prepared by the novel processes of the invention.
    Type: Grant
    Filed: October 30, 1992
    Date of Patent: February 22, 1994
    Assignee: American Cyanamid Company
    Inventor: Ram B. Gupta
  • Patent number: 5250521
    Abstract: Novel substituted pyrazolopyrimidines of formula (I) which are useful as angiotensin II antagonists, are disclosed.
    Type: Grant
    Filed: November 25, 1991
    Date of Patent: October 5, 1993
    Assignee: Merck & Co., Inc.
    Inventors: Eric E. Allen, William J. Greenlee, Prasun K. Chakravarty, Malcolm MacCoss, Arthur A. Patchett, Thomas F. Walsh
  • Patent number: 5240499
    Abstract: Polymeric, water-soluble triazine compounds which contain both basic and acidic groups in the molecule have out-standing surfactant properties and are suitable for the preparation of dispersions of solids, preferably of dispersions of inorganic and/or organic pigments, in an aqueous or water-dilutable medium. Since these triazine compounds are colorless or only slightly colored, they do not influence the shade of the medium used.
    Type: Grant
    Filed: December 13, 1991
    Date of Patent: August 31, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rainer Az, Wolfgang Schwab, Dieter Schnaitmann, Erwin Dietz
  • Patent number: 5210191
    Abstract: Substituted alkoxy- or alkylthiochlorotriazines wherein the substituents on the alkoxy groups are chlorine, bromine or dialkylphosphato are useful as capping agents for polyphenylene ethers. The capped polyphenylene ethers form copolymers with other polymers containing nucleophilic groups, including polyesters, polyamides and functionalized olefin polymers. Such copolymers serve as compatibilizers in the formation of blends having high impact strength.
    Type: Grant
    Filed: November 4, 1991
    Date of Patent: May 11, 1993
    Assignee: General Electric Company
    Inventors: Otto Phanstiel, Sterling B. Brown
  • Patent number: 5159075
    Abstract: Substituted alkoxy- or alkylthiochlorotriazines wherein the substituents on the alkoxy groups are chlorine, bromine or dialkylphosphato are useful as capping agents for polyphenylene ethers. The capped polyphenylene ethers form copolymers with other polymers containing nucleophilic groups, including polyesters, polyamides and functionalized olefin polymers. Such copolymers serve as compatibilizers in the formation of blends having high impact strength.
    Type: Grant
    Filed: February 11, 1991
    Date of Patent: October 27, 1992
    Assignee: General Electric Company
    Inventors: Otto Phanstiel, Sterling B. Brown
  • Patent number: 5158999
    Abstract: Compounds having a nucleus of general formula (I): ##STR1## in which: n is an integer and has a value of at least 2;R.sup.1 represents an alkyl group comprising up to 20 carbon atoms; andR.sup.2 represents ##STR2## where R.sup.3 represents an alkyl group comprising up to 20 carbon atoms or an aryl nucleus comprising up to 10 carbon atoms, or R.sup.2 represents a heterocyclic ring nucleus comprising from 4 to 8 ring atoms, at least one atom comprising nitrogen and linking the ring nucleus to the triazine ring. Compounds of formula (I) are suitable for use as a flame retardant additive for polymer materials, particularly when used in combination with a second and different source of phosphorus. The flame retarded polymers are particularly suitable for use in wire and cable insulation, dimensionally recoverable products, molded parts, extruded tubings, pipes and tape type constructions.
    Type: Grant
    Filed: August 13, 1990
    Date of Patent: October 27, 1992
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Timothy G. Swales, Alan J. Lindsay, Linda M. Doolan
  • Patent number: 5120843
    Abstract: The aromatic amines (I), alkyl amines (II), bicyclic amines (III). ##STR1## cycloalkyl amines (IV), aromatic bicyclic amines (V), hydroquinone amines (VI), quinone amines (VII), amino-ethers (VIII) and bicyclic amino ethers (IX) are useful as pharmaceutical agents for treating a number of conditions including spinal trauma, mild and/or moderate to severe head injury, etc. Also disclosed is a method of treatment using the 3,4-dihydrobenzopyrans (XI).
    Type: Grant
    Filed: October 23, 1989
    Date of Patent: June 9, 1992
    Assignee: Upjohn
    Inventors: John M. McCall, Donald E. Ayer, E. Jon Jacobsen, Frederick J. VanDoornik, John R. Palmer
  • Patent number: 5108487
    Abstract: This invention relates to a novel class of sulfonylureas and their use as herbicides and plant growth regulants.
    Type: Grant
    Filed: March 8, 1990
    Date of Patent: April 28, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Stephen K. Gee
  • Patent number: 5071840
    Abstract: The present invention relates to novel heterocycle-substituted diphosphonic acids, and the pharmaceutically-acceptable salts and esters thereof, in which the diphosphonate-substituted carbon atom moiety is attached to a carbon atom in a nitrogen-containing six membered ring heterocycle, preferably a piperidine ring. The heterocycle-substituted diphosphonic acid compounds have the general structure: ##STR1## wherein Z is a nitrogen-containing six membered ring heterocycle moiety selected from piperidinyl, diazinyl and triazinyl; m, n and m+n are from 0 to 10; Q is a covalent bond or a moiety selected from oxygen, sulfur or nitrogen; and R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are substituent groups.The present invention further relates to pharmaceutical compositions containing these novel compounds. Finally this invention relates to methods for treating or preventing diseases characterized by abnormal calcium and phosphate metabolism by utilizing a compound or pharmaceutical composition of the present invention.
    Type: Grant
    Filed: July 11, 1989
    Date of Patent: December 10, 1991
    Assignee: Norwich Eaton Pharmaceuticals, Inc.
    Inventors: Frank H. Ebetino, James J. Benedict
  • Patent number: 4968797
    Abstract: 4,4-diaryldihydroquinazolones of the formula ##STR1## wherein X.sup.1, X.sup.2 and X.sup.3, independently of one another, denote hydrogen, halogen, alkyl, aryl, alkanoylamino, aroylamino, heteryl, NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3, at least one of the radicalsX.sup.1, X.sup.2 or X.sup.3 standing for NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl or the members of a bridge to the o-carbon of ring C,R.sup.2 denotes a radical of an acid,Y.sup.1, Y.sup.2 and Y.sup.3, independently of one another, denote hydrogen, alkyl, cycloalkyl, aralkyl aryl or heteryl or the remaining members of a 5- or 6-membered ring which reaches to one of the o-position benzene C atoms and may contain further hetero atoms orY.sup.1 +Y.sup.
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: November 6, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Berneth, Alfred Brack, Karlheinrich Meisel
  • Patent number: 4957921
    Abstract: Substituted cyclohexanols are described, as well as methods for the preparation and pharmaceutical composition of same, which are useful as central nervous system agents and are particularly useful as dopaminergic, antipsychotic, and antihypertensive agents as well as for treating hyperprolactinaemia-related conditions and central nervous system disorders.
    Type: Grant
    Filed: December 6, 1989
    Date of Patent: September 18, 1990
    Assignee: Warner-Lambert Company
    Inventors: Bradley W. Caprathe, Juan C. Jaen, Sarah J. Smith, Lawrence D. Wise
  • Patent number: 4948419
    Abstract: This invention relates to certain novel pyridine sulfonamide compounds, to compositions containing such compounds, and to a method of use of such compositions to control the growth of undesired vegetation.
    Type: Grant
    Filed: February 15, 1989
    Date of Patent: August 14, 1990
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Mary A. Hanagan, Barry A. Wexler
  • Patent number: 4948416
    Abstract: This invention relates to novel condensed ring sulfonylureas and their use as herbicides and growth regulants.
    Type: Grant
    Filed: March 27, 1989
    Date of Patent: August 14, 1990
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Robert J. Pasteris
  • Patent number: 4812161
    Abstract: Thia-diazole derivatives having the following partial structural formula had selective herbicidal activity on some crops.
    Type: Grant
    Filed: July 29, 1985
    Date of Patent: March 14, 1989
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Kenji Hagiwara, Hisao Ishikawa, Hideo Hosaka, Hideo Inaba
  • Patent number: 4803234
    Abstract: Compounds of formula (I) ##STR1## in which R.sub.1 is hydrogen, O.sup.., CN, NO, cyanomethyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.12 -alkenyl or C.sub.3 -C.sub.12 -alkynyl subject to the proviso that the carbon atom attached to the nitrogen atom is a primary carbon atom, C.sub.7 -C.sub.12 -aralkyl, C.sub.1 -C.sub.12 -acyl, 2,3-epoxypropyl, OH-monosubstituted C.sub.2 -C.sub.6 -alkyl or 2,3-dihydroxypropyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.18 -cycloalkyl, C.sub.6 -Chd 18-aryl or C.sub.7 -C.sub.18 -aralkyl, R.sub.3 is C.sub.6 -C.sub.18 -aryl or a group of the formula (II) ##STR2## in which R.sub.1 is as defined above, n is an integer from 1 to 4 and R.sub.4 is an organic or inorganic radical of a valency equal to n are useful for stabilizing organic material against oxidative, thermal and/or light induced degradation.
    Type: Grant
    Filed: January 29, 1987
    Date of Patent: February 7, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Valerio Borzatta
  • Patent number: 4795815
    Abstract: 1,2,4-Trisubstituted diazolidinones are intermediates to bicyclic pyrazolidinone antimicrobial compounds.
    Type: Grant
    Filed: October 29, 1987
    Date of Patent: January 3, 1989
    Assignee: Eli Lilly and Company
    Inventor: Robert J. Ternansky
  • Patent number: 4754034
    Abstract: 4,4-diaryldihydroquinazolones of the formula ##STR1## wherein X.sup.1, X.sup.2 and X.sup.3, independently of one another, denote hydrogen, halogen, alkyl, aryl, alkanoylamino, aroylamino, heteryl, NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3, at least one of the radicals X.sup.1, X.sup.2 or X.sup.3 standing for NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl or the members of a bridge to the o-carbon of ring C,R.sup.2 denotes a radical of an acid,Y.sup.1, Y.sup.2 and Y.sup.3, independently of one another, denote hydrogen, alkyl, cycloalkyl, aralkyl aryl or heteryl or the remaining members of a 5- or 6-membered ring which reaches to one of the o-position benzene C atoms and may contain further hetero atoms orY.sup.1 +Y.sup.
    Type: Grant
    Filed: October 21, 1985
    Date of Patent: June 28, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Berneth, Alfred Brack, Karlheinrich Meisel
  • Patent number: 4719045
    Abstract: A flame retardant for polyolefins, which comprises as an effective ingredient a hardly water-soluble or water-insoluble, nitrogen-containing phosphorus compound obtained by mixing 100 parts by weight of a condensed phosphoric acid compound with 10 to 100 parts by weight of a triazine compound and heating the mixture at 100.degree. to 250.degree. C. in the presence or absence of water.
    Type: Grant
    Filed: April 11, 1986
    Date of Patent: January 12, 1988
    Assignee: Marubishi Yuka Kogyo Kabushiki Kaisha
    Inventors: Yoshikatsu Ogawa, Haruhiko Hisada, Takeshi Kasahara, Fumihiko Kizaki, Masahide Yoshiya
  • Patent number: 4716232
    Abstract: 1-(Vinyl phosphonate adduct) pyrazolidinones are intermediates to bicyclic pyrazolidinone antimicrobial compounds.
    Type: Grant
    Filed: May 14, 1986
    Date of Patent: December 29, 1987
    Assignee: Eli Lilly and Company
    Inventor: Robert J. Ternansky
  • Patent number: 4610824
    Abstract: Antibacterial activity is exhibited by novel compounds having the formula ##STR1## and pharmaceutically acceptable salts thereof.
    Type: Grant
    Filed: October 9, 1984
    Date of Patent: September 9, 1986
    Assignee: E. R. Squibb & Sons, Inc.
    Inventor: Uwe D. Truner
  • Patent number: 4592865
    Abstract: Intermediates of the following formula are useful for the synthesis of 1-oxacephalosporins. Their preparation from penicillins and the transformation process to make 1-oxacephalosporins are disclosed. The compounds are of the formula: ##STR1## wherein A is amino or a selected acylamino;COB is carboxy or a selected protected-carboxy;X is halogen or the group ORin which R is a group represented by following formulas: ##STR2## wherein Nu is a selected nucleophilic group; R.sup.1 is a group of the following formula: ##STR3## in which Hal is halogen or alkylsulfonyloxy and R.sup.2 is alkyl or aryl; andY is hydrogen or methoxy; with the proviso that when R is propargyl or 2-oxopropyl andR.sup.1 is ##STR4## A is in the 3.alpha.-configuration and Y is 3.beta.-hydrogen or A is in the 3.beta.-configuration and Y is 3.alpha.-methoxy.
    Type: Grant
    Filed: March 13, 1984
    Date of Patent: June 3, 1986
    Assignee: Shionogi & Co., Ltd.
    Inventors: Masayuki Narisada, Hiroshi Onoue, Teruji Tsuji, Yasuhiro Nishitani, Mitsuru Yoshioka, Yoshio Hamashima, Wataru Nagata
  • Patent number: 4562185
    Abstract: The present invention relates to combating pests with five-membered nitrogen-containing heterocyclic compounds of the formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3, X and Y have the meaning given in the description. Many of the compounds are new.
    Type: Grant
    Filed: March 15, 1984
    Date of Patent: December 31, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerhard Jager, Rudolf Fauss, Kurt Findeisen, Benedikt Becker, Bernhard Homeyer
  • Patent number: 4556710
    Abstract: The invention is phosphono-s-triazines corresponding to the formula ##STR1## wherein: X is separately in each occurrence chlorine, bromine, haloalkyl or alkyl;Y is separately in each occurrence hydrogen, chlorine or bromine;R is separately in each occurrence hydrogen, hydrocarbyl, CH.sub.2 Y, CH.sub.2 OH or CH.sub.2 OC(R.sup.1).sub.3 wherein R.sup.1 is alkyl;a is an integer from 0 to 2 inclusive; andb is an integer from 1 to 3 inclusive, with the proviso that the sum of a and b equal 3, and with the further proviso that at least one R is CH.sub.2 OH or CH.sub.2 OC(R.sup.1).sub.3.
    Type: Grant
    Filed: March 18, 1983
    Date of Patent: December 3, 1985
    Assignee: The Dow Chemical Company
    Inventors: Chester E. Pawloski, Sally P. Ginter
  • Patent number: 4551527
    Abstract: A process for preparing polyvalent metal and amine salts of the indicated phosphorinane (an acid). The salts are isolated as such and are effective, in small proportions, to impart flame-retardant properties to polymers, especially to polypropylene and to styrenic polymers such as polystyrene, ABS and MBS.
    Type: Grant
    Filed: July 2, 1981
    Date of Patent: November 5, 1985
    Assignee: Borg-Warner Chemicals, Inc.
    Inventors: Yuval Halpern, Donna Mott
  • Patent number: 4546180
    Abstract: A process for preparing certain phosphite-isocyanurate oligomers. The process requires the reaction of a trishydroxyalkyl isocyanurate with a tris-organophosphite and, optionally, an alcohol or alkylphenol. The process is promoted by an alkaline catalyst such as sodium methoxide. The oligomeric product is useful as a thermal stabilizer in polymer compositions.
    Type: Grant
    Filed: April 19, 1983
    Date of Patent: October 8, 1985
    Assignee: Borg-Warner Chemicals, Inc.
    Inventors: Leo L. Valdiserri, Richard P. Woodbury
  • Patent number: 4528284
    Abstract: Phosphoric acid esters of the formula ##STR1## wherein X is CH or N,Ar is optionally substituted phenyl, diphenyl or naphthyl,R is cyano, carboxylic acid ester, carboxylic acid thioester or carboxylic acid amide.R.sub.10 is alkyl,R.sub.11 alkyl, alkoxy, alkylthio or phenyl, andY is sulfur.For R: the ester groups are alkenyl, alkynyl, cycloalkyl, optionally substituted phenyl, alkyl interrupted by oxygen or sulfur and optionally substituted by halogen, phenyl, carboxylic acid ester, alkylcarbonyl, optionally substituted phenyl carbonyl, or a C.sub.5 or C.sub.6 heterocycle; the thioester groups are alkyl or optionally substituted phenyl or benzyl; the amide is optionally mono- or di-substituted by alkyl, cycloalkyl, optionally substituted phenyl or benzyl, or may form a C.sub.5 or C.sub.6 heterocyclic ring. The compounds are useful in controlling phytopathogenic fungi.
    Type: Grant
    Filed: October 5, 1983
    Date of Patent: July 9, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Wolfgang Eckhardt, Walter Kunz
  • Patent number: 4479946
    Abstract: Novel phosphorus esters of amidoximes and methods of preparing same. This invention is also directed to pesticidal compositions comprising an acceptable carrier and a pesticidally effective amount of a compound of this invention, as well as to a method of controlling pests which comprises subjecting the pests to a pesticidally effective amount of a compound of this invention.
    Type: Grant
    Filed: June 17, 1982
    Date of Patent: October 30, 1984
    Assignee: Union Carbide Corporation
    Inventors: Leonard E. Hodakowski, Dean F. Bushey
  • Patent number: 4435338
    Abstract: The compounds according to the invention correspond to the formula I ##STR1## in which R is a hydrocarbon radical, A is one of the groups --O.CO--, --O-- or ##STR2## (in which m is 0-30) and Q, depending on the definition of A, is a hydrocarbon radical, a P-containing radical, an N-heterocyclic group or a radical containing N-heterocyclic groups.The compounds according to the invention also include those which are formed by an addition reaction of an O,O-dialkyl dithiophosphate with an epoxidised soybean oil.The compounds according to the invention are very useful as lubricant additives.
    Type: Grant
    Filed: September 21, 1981
    Date of Patent: March 6, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Klaus-Peter Michaelis, Rainer Schneider
  • Patent number: 4429124
    Abstract: A method for preparing N-phosphonomethylglycine comprising (a) O,O-dialkylaminomethylphosphonate with formaldehyde to produce a triazine; (b) reacting the triazine formed in step (a) with an acyl halide to form the O,O-dialkyl-N-phosphonomethyl-N-chloromethyl acetamide of the acyl halide; (c) reacting the amide formed in step (b) with metal cyanide to form O,O-dialkyl-N-cyanomethyl-N-acetamide; and (d) hydrolyzing the acetamide formed in step (c) to yield N-phosphonomethylglycine.
    Type: Grant
    Filed: August 23, 1982
    Date of Patent: January 31, 1984
    Assignee: Stauffer Chemical Company
    Inventor: Raymond A. Felix
  • Patent number: 4376857
    Abstract: Certain phosphite-isocyanurate oligomers and their use as thermal stabilizers in polymer compositions. The phosphite-isocyanurates may be prepared from a tris-hydroxyalkyl isocyanurate by reaction with an organic phosphite such as triphenyl phosphite or tributyl phosphite. Optionally, an alcohol such as decyl alcohol may be employed as a reactant.
    Type: Grant
    Filed: September 3, 1981
    Date of Patent: March 15, 1983
    Assignee: Borg-Warner Corporation
    Inventors: Leo L. Valdiserri, Richard P. Woodbury
  • Patent number: 4362830
    Abstract: Hindered bis-phenol phenyl phosphites are provided having the structure: ##STR1## wherein: R is selected from the group consisting of alkyl having from one up to about eighteen carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about eighteen carbon atoms; preferably, a bulky group such as iso, secondary or tertiary alkyl having from three to about ten carbon atoms; or cycloalkyl having six to twelve carbon atoms;R.sub.1 and R.sub.2 are each selected from the group consisting of hydrogen; alkyl having from one to about eighteen carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about eighteen carbon atoms; and are preferably in a position ortho to a phenolic hydroxyl or phenoxy group, if available;R.sub.3 is alkylene having from one to about six carbon atoms;R.sub.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: December 7, 1982
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Motonobu Minagawa, Yutaka Nakahara
  • Patent number: 4320126
    Abstract: Organophosphorus esters of the formula (I), ##STR1## wherein R is a C.sub.1 -C.sub.2 alkyl group, R.sub.1 is a C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 alkoxy, C.sub.1 -C.sub.4 alkylamino, phenyl or phenoxy group, R.sub.2 and R.sub.3, which may be the same or different, are each a C.sub.1 -C.sub.5 alkyl or methoxy C.sub.2 -C.sub.3 alkyl group and X is an oxygen or sulfur atom, a method for producing organophosphorus esters of the formula (I) characterized by condensation reaction of s-triazines of the formula, ##STR2## wherein M is a potassium or sodium atom and R.sub.2 and R.sub.3 are as defined above, with a halogenated compound of the formula, ##STR3## wherein Y is a halogen atom and R, R.sub.1 and X are as defined above, and an insecticide, acaricide and/or nematocide characterized by containing organophosphorus esters of the formula (I) as an active ingredient.
    Type: Grant
    Filed: August 27, 1979
    Date of Patent: March 16, 1982
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takayuki Okabe, Kunio Mukai, Masachika Hirano
  • Patent number: 4303652
    Abstract: Organophosphorus esters, useful in increasing the resistance of keratinous materials to attack by keratin-eating insects, have the general formula: ##STR1## wherein: X and Y are independently O or S;R.sub.1 is an alkyl, alkoxy, alkylamino, dialkylamino or alkylmercapto radical having 1 to 6 carbon atoms;an amino or aryl radical;R.sub.2 is an alkyl radical having 1 to 6 carbon atoms;R.sub.3 is a radical of the general formula:-J-(K-L).sub.n (2)wherein:J is an aliphatic radical, or radical containing an aromatic or heterocyclic ring;K is one of the following radicals: ##STR2## linked to J through the oxygen atom in the case of (3), (5) or (6), and through the nitrogen atom in the case of (4), and in which the carbonyl oxygen atom of (3), (4) or (5), or one or both carbonyl oxygen atoms of (6) may be replaced by sulphur; R.sub.
    Type: Grant
    Filed: August 30, 1978
    Date of Patent: December 1, 1981
    Assignee: Commonwealth Scientific and Industrial Research Organization
    Inventors: Francis W. Jones, Robert J. Mayfield, Gary J. O'Loughlin
  • Patent number: 4298520
    Abstract: This invention relates to a new class of phenolic compounds containing a phosphorus acid ester group which are stabilizers for synthetic resins and to synthetic resin stabilizer compositions comprising these phenolic compounds as well as to synthetic resins stabilized with such phenolic compounds and with stabilizer compositions comprising these phenolic compounds along with known polymer stabilizers.
    Type: Grant
    Filed: October 11, 1979
    Date of Patent: November 3, 1981
    Assignee: Argus Chemical Corp.
    Inventors: Motonobu Minagawa, Yutaka Nakahara, Masayuki Takahashi
  • Patent number: 4297492
    Abstract: Novel oligomeric and polymeric phenolic 1,3,5-triazines, for example those of the formula ##STR1## their preparation and their use for stabilizing organic material and also the organic material protected against oxidative and light-induced degradation with the aid of these compounds.
    Type: Grant
    Filed: March 10, 1980
    Date of Patent: October 27, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Michael Rasberger, Siegfried Rosenberger, Samuel Evans
  • Patent number: 4287339
    Abstract: This invention of the present application relates to the stabilizing component in the stabilization of olefin polymers, especially polypropylene during processing, i.e., at elevated temperatures. The stabilizing component is a phosphite-isocyanurate compound having the structural formula: ##STR1## wherein R is a hydrocarbon radical and R.sup.1 is methyl or hydrogen.
    Type: Grant
    Filed: February 29, 1980
    Date of Patent: September 1, 1981
    Assignee: Borg-Warner Corporation
    Inventor: Leo L. Valdiserri
  • Patent number: 4260779
    Abstract: Oxothia compounds, especially 2-oxo-2,3-dihydro-benzo[b]thiophene compounds of the formula ##STR1## in which Ph represents an optionally substituted 1,2-phenylene radical, X represents oxygen or sulphur, R.sub.1 represents an organic radical bonded via a carbon atom and R.sub.2 denotes hydrogen or an optionally substituted hydrocarbon radical of aliphatic character, and their salts are useful as peripheral analgetics and/or as antiphlogistic uricosuric and/or thrombolytic agents.
    Type: Grant
    Filed: November 9, 1979
    Date of Patent: April 7, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Raymond Bernasconi, Pier G. Ferrini, Richard Goschke, Jacques Gosteli
  • Patent number: 4161592
    Abstract: New 1,3,5-triazines containing at least one hindered phenolic moiety and at least one hindered amine moiety are useful light stabilizers and antioxidants for polymeric materials.
    Type: Grant
    Filed: July 1, 1977
    Date of Patent: July 17, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Samuel Evans, Michael Rasberger
  • Patent number: 4151356
    Abstract: A triazine of the formula I ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.6 -C.sub.18 -aryl, C.sub.7 -C.sub.18 -aralkyl or a radical of the formula II or III ##STR2## in which R.sub.3 is hydrogen or C.sub.1 -C.sub.8 -alkyl and R.sub.4 is hydrogen, oxyl, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.4 -alkinyl, C.sub.2 -C.sub.21 -alkoxyalkyl, C.sub.7 -C.sub.8 -aralkyl, 2,3-epoxypropyl, an aliphatic acyl group with 1-9 C atoms or one of the groups --CH.sub.2 COOR.sub.5, --CH.sub.2 --CH(R.sub.6)--OR.sub.7, --COOR.sub.8 or --CONHR.sub.8, in which R.sub.5 is C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.6 -alkenyl, phenyl, C.sub.7 -C.sub.8 -aralkyl or cyclohexyl and R.sub.6 is hydrogen, methyl or phenyl and R.sub.7 denotes hydrogen, an aliphatic or aromatic, araliphatic or alicyclic acyl group with 1-18 C atoms, in which the aromatic part can optionally be substituted by chlorine, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.
    Type: Grant
    Filed: October 11, 1977
    Date of Patent: April 24, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Samuel Evans, Michael Rasberger
  • Patent number: 4145547
    Abstract: Novel ureidoalkylphosphonates, methods for their prepration as well as for their use in preparing durable, flameproof finishes for textiles are disclosed. These ureidoalkylphosphonates are found to be low in cost, readily prepared and of minimal toxicity.
    Type: Grant
    Filed: May 26, 1977
    Date of Patent: March 20, 1979
    Assignee: Stauffer Chemical Company
    Inventor: Edward D. Weil
  • Patent number: 4140660
    Abstract: Flame-retarding compounds are disclosed which are of the formula ##STR1## wherein X is a phosphorus derivative.
    Type: Grant
    Filed: October 17, 1977
    Date of Patent: February 20, 1979
    Assignee: Stamicarbon, B.V.
    Inventors: Marinus J. A. M. Den Otter, Albert A. Van Geenen, Anne Te Mijenhuis
  • Patent number: 4085283
    Abstract: Flame retarding compounds are disclosed which are of the formula ##STR1## wherein X is a phosphonate derivative.
    Type: Grant
    Filed: April 19, 1976
    Date of Patent: April 18, 1978
    Assignee: Stamicarbon, B.V.
    Inventors: Marinus J. A. M. Den Otter, Albert A. Van Geenen, Anne Te Nijenhuis