Heavy Metal Or Aluminum Containing Patents (Class 544/64)
  • Patent number: 4293549
    Abstract: This invention relates to new compounds, salts, complexes and acylated derivatives thereof, methods of producing said compounds, intermediates used in the method, pharmaceutical compositions containing the present compounds and methods of producing same, and a method of treating patients using the present compounds, having the general formula (I) ##STR1## in which R.sub.1 represents hydrogen, alkyl, alkoxy, hydroxy, halogen, trifluoromethyl, or phenyl; R.sub.2 represents hydrogen, alkyl, alkoxy, halogen, trifluoromethyl, or hydroxy; R.sub.3 represents alkyl, cycloalkyl which can be further mono- or disubstituted with methyl or ethyl, phenyl or phenyl-alkyl, optionally being further substituted; and R.sub.
    Type: Grant
    Filed: October 27, 1978
    Date of Patent: October 6, 1981
    Assignee: Leo Pharmaceutical Products Ltd. A/S (Lovens Kemiske Fabrik Produktion-saktieselskab)
    Inventors: Schneur Rachlin, Edoardo Arrigoni-Martelli
  • Patent number: 4291033
    Abstract: Novel oxoimidazoquinoxalines of the formula ##STR1## wherein R.sub.1 and R.sub.2 are individually selected from the group consisting of hydrogen, chlorine and bromine, X is selected from the group consisting of hydrogen, alkyl of 1 to 5 carbon atoms, cycloalkyl of 3 to 5 carbon atoms and cycloalkyl-alkyl of 4 to 6 carbon atoms, R.sub.3 is selected from the group consisting of hydrogen alkyl of 1 to 5 carbon atoms, alkali metal, alkaline earth metal, aluminum, --NH.sub.4, organic amine and ##STR2## R.sub.4 and R.sub.5 are individually alkyl of 1 to 5 carbon atoms or taken together with the nitrogen atom form a saturated heterocycle of 4 to 6 carbon atoms optionally containing an oxygen atom or second nitrogen atom and n is a number from 1 to 5 and their non-toxic, pharmaceutically acceptable acid addition salts having antiallergic activity and their preparation.
    Type: Grant
    Filed: February 4, 1980
    Date of Patent: September 22, 1981
    Assignee: Roussel Uclaf
    Inventors: Alan C. Barnes, David P. Kay
  • Patent number: 4268668
    Abstract: An acid monomethine-metal complex dyestuff of the formula ##STR1## wherein M, Z, R, A, Y, n, a and b have the meaning given in the description.The acid metal complex dyestuffs of the formula I are valuable dyestuffs which are outstandingly suitable for dyeing and printing wool, silk and especially synthetic polyamides, such as NYLON and PERLON, in very clear shades ranging from yellow to blue, and are distinguished by high tinctorial strength, good build-up capacity and affinity and very good fastness characteristics, especially fastness to light.
    Type: Grant
    Filed: October 19, 1979
    Date of Patent: May 19, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Harnisch, Peter Rasche
  • Patent number: 4263202
    Abstract: Metal phenolates having at least one piperidinyl group sterically hindered on the nitrogen atom are suitable as additives for organic material.
    Type: Grant
    Filed: July 10, 1978
    Date of Patent: April 21, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Michael Rasberger, Samuel Evans, Paul Moser
  • Patent number: 4259330
    Abstract: This invention relates to novel phosphoramidates of the formula: ##STR1## wherein R.sup.1 is hydrogen, alkyl, cycloalkyl, or optionally substituted aralkyl, aryl, pyridyl, pyridylmethyl, pyridylethyl or pyrazinyl;R.sup.2 is hydrogen provided R.sup.1 is other than optionally substituted aryl; alkyl; cycloalkyl; alkoxyalkyl; alkylthioalkyl; cyanoalkyl; alkenyl; optionally substituted aralylky; or optionally substituted aryl, provided R.sup.1 is other than hydrogen;R.sup.1 and R.sup.2 taken together with the nitrogen to which they are attached form an optionally substituted morpholino or piperidino group;R.sup.3 is hydrogen, alkyl, cycloalkyl, alkenyl, or optionally substituted aralkyl or aryl;R.sup.4 is (C.sub.1 -C.sub.6) alkyl;R.sup.5 is (C.sub.3 -C.sub.4) alkyl; andX, Y and Z are independently oxygen or sulfur;the agronomically acceptable metal salts and metal salt complexes thereof; and to methods of using them to control nematodes.
    Type: Grant
    Filed: March 1, 1976
    Date of Patent: March 31, 1981
    Assignee: Rohm and Haas Company
    Inventors: Harold E. Aller, Edward E. Kilbourn, Ernest D. Weiler, William D. Weir
  • Patent number: 4247694
    Abstract: The invention relates to metal salts of hydroxybenzoic acids which are complexed with a 4-amino-polyalkylpiperidine derivative or to mixed metal salts of a hydroxybenzoic acid and a polyalkylpiperidine carboxylic acid which may be complexed or not with an 4-amino-polyalkylpiperidine. The metal cation may be that of a di- or trivalent metal such as Ni, Co, Al, Zn or Ca. From hydroxybenzoic acids the 3,5-di-tert.butylbenzoic acid is preferred.These salts are valuable light stabilizers for plastics, especially for polyolefins, styrene polymers and polyamides or polyurethanes respectively. The salts show a strong tendency to retain water. For high compatibility with plastics a low water content is of importance.
    Type: Grant
    Filed: October 10, 1978
    Date of Patent: January 27, 1981
    Assignee: Ciba-Geigy Corporation
    Inventor: Michael Rasberger
  • Patent number: 4234723
    Abstract: Nickel complexes containing ortho- or para-hydroxybenzoate anions and a non-ionic amine ligand are valuable light-stabilizers for polymers, particularly for polyolefins. The complexes may also contain a second carboxylate anion, different from the benzoate anion, and in this case also the amine-free nickel compounds show a high stabilizing action.
    Type: Grant
    Filed: July 30, 1979
    Date of Patent: November 18, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Michael Rasberger, Jean Rody, Paul Moser, Helmut Muller
  • Patent number: 4226987
    Abstract: Amine molybdates retard smoke formation effectively when vinyl chloride and vinylidene chloride polymers burn.
    Type: Grant
    Filed: March 22, 1979
    Date of Patent: October 7, 1980
    Assignee: The B. F. Goodrich Company
    Inventor: William J. Kroenke
  • Patent number: 4217292
    Abstract: Amine molybdates are formed by reacting molybdenum trioxide (MoO.sub.3) with an amine in an aqueous medium essentially free of acid and in which is dissolved a water-soluble ammonium or monovalent metal or divalent metal or trivalent rare earth metal salt of an acid, or a combination thereof. Although the reaction may be carried out at room temperature, the reaction mixture desirably is heated to between about 75.degree. C. to 110.degree. C. and preferably is refluxed to reduce the time required for completion of the reaction. The reaction slurry is stirred while the reaction is occurring. Upon completion of the reaction, the amine molybdate is separated from the liquid phase, and is washed and dried. After removal of the solid amine molybdate from the slurry the liquid component can be reused avoiding possible environmental difficulties.
    Type: Grant
    Filed: March 1, 1979
    Date of Patent: August 12, 1980
    Assignee: The B. F. Goodrich Company
    Inventor: William J. Kroenke
  • Patent number: 4181517
    Abstract: 1,2,3-Thiadiazole-2-id-derivative of the formula ##STR1## in which R.sub.1 is hydrogen or alkyl which may be substituted in one or several places by oxygen or sulfur and wherein R.sub.1 has the meaning as given in the attached specification and wherein X is oxygen or sulfur and B is a univalent metal atom. The compounds have properties suited for controlling the natural growth and natural development of plants and in addition have a superior defoliating property.
    Type: Grant
    Filed: April 19, 1978
    Date of Patent: January 1, 1980
    Assignee: Schering Aktiengesellschaft
    Inventors: Hans-Rudolf Kruger, Reinhart Rusch, Friedrich Arndt
  • Patent number: 4178382
    Abstract: Disclosed are N-substituted triorganostannylhydrocarbylcarboxylic acid hydrazides useful as insecticides.
    Type: Grant
    Filed: June 19, 1978
    Date of Patent: December 11, 1979
    Assignee: Uniroyal, Inc.
    Inventors: Chung-Ling Mao, Richard J. Strunk, Winchester L. Hubbard
  • Patent number: 4153792
    Abstract: Amine molybdates retard smoke formation effectively when vinyl chloride and vinylidene chloride polymers burn.
    Type: Grant
    Filed: April 29, 1977
    Date of Patent: May 8, 1979
    Assignee: The B. F. Goodrich Company
    Inventor: William J. Kroenke
  • Patent number: 4150026
    Abstract: Metal salt complexes of 3-isothiazolones and compositions containing them exhibit useful biocidal properties, including bactericidal, fungicidal, and algaecidal properties.
    Type: Grant
    Filed: May 12, 1971
    Date of Patent: April 17, 1979
    Assignee: Rohm and Haas Company
    Inventors: George A. Miller, Ernest D. Weiler
  • Patent number: 4146540
    Abstract: The present invention concerns certain novel compounds falling under the general formula: ##STR1## WHEREIN R.sub.1, R.sub.2 and R.sub.3 are substituents, e.g. alkyl and Me is hydrogen or a metal cation.The compounds are useful stabilizers of organic material against the degradative effect of heat, oxidation and U.V. light.
    Type: Grant
    Filed: October 21, 1977
    Date of Patent: March 27, 1979
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Kurt Hofer, Martin Preiswerk
  • Patent number: 4144224
    Abstract: New amino phosphonates, containing 2,2,6,6-tetrasubstituted-piperidino moieties and processes for their manufacture are disclosed. These compounds are employed to stabilize organic materials such as polyolefins, polyamides and polyurethanes against degradation from the action of oxygen, heat and light.
    Type: Grant
    Filed: November 17, 1977
    Date of Patent: March 13, 1979
    Assignee: Ciba-Geigy Corporation
    Inventor: Paul Moser
  • Patent number: 4128429
    Abstract: Disclosed are the usage, preparation, and evaluation of marine antifouling quaternary halide salts containing a cation portion which includes a trialkyltin ether moiety linked to a carbon atom at least two carbon atoms removed from the quaternized nitrogen atom. Taught as providing exceptional marine fouling inhibition are the quaternary salts of benzyl bromide and tertiary amines containing a tributylstannyl ether moiety at least two carbon atoms removed from the amino nitrogen atom with illustrated specific examples including the quaternary salts of benzyl bromide and 2-dimethylamino-2-methyl-1-propyl tributylstannyl ether, benzyl bromide and 1-dimethylamino-2-propyl tributylstannyl ether, benzyl bromide and 2-[N-pyrrolidinyl]ethyl tributylstannyl ether, and benzyl bromide and 2-diisopropylaminoethyl tributylstannyl ether.
    Type: Grant
    Filed: January 6, 1977
    Date of Patent: December 5, 1978
    Assignee: Sankyo Organic Chemicals Company Limited
    Inventors: Robert E. Wyant, Henry M. Grotta
  • Patent number: 4122261
    Abstract: This invention relates to novel compounds of the isoindolenine series. More particularly, the present invention relates to certain novel 1-imino-3-(4-imino-5-thiazolidinylidene)isoindolines, 1-imino-3-(4-imino-2-thiazolin-5-ylidene)isoindolines, water-insoluble pigments prepared therefrom, and to methods for their preparation.
    Type: Grant
    Filed: July 5, 1977
    Date of Patent: October 24, 1978
    Assignee: Sterling Drug Inc.
    Inventors: Nathan N. Crounse, Nicholas A. Ambrosiano
  • Patent number: 4115413
    Abstract: Triaryl-methane dyestuffs which are free from sulfonic acid and carboxylic acid groups and are selected from the group consisting of dyestuffs having one of the following four formulae: ##STR1## wherein R is alkyl, aralkyl, cycloalkyl or aryl; R.sub.1 is hydrogen, alkyl, aralkyl or cycloalkyl; R.sub.2 is alkyl, aralkyl, cycloalkyl or aryl; R.sub.1 and R.sub.2 additionally including divalent alkylene when joined together with the nitrogen or with a carbon atom in the o-position in the ring A to form a heterocyclic ring; R.sub.3 is hydrogen, alkyl, aralkyl, aryl, aralkoxy, aryloxy, halogen, carboxylic acid ester radical, carbonamido, sulfonamido, cyano, nitro, alkylsulfonyl, aryalkylsulfonyl, arylsulfonyl or acyl; and X is the radical of an anion; ##STR2## wherein R is alkyl or cycloalkyl; R.sub.1 is hydrogen, alkyl, aralkyl, cycloalkyl or aryl; R.sub.2 is alkyl, cycloalkyl, aralkyl or aryl, halogen or cyano; R.sub.1 and R.sub.
    Type: Grant
    Filed: November 21, 1969
    Date of Patent: September 19, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roderich Raue, Willi Eifler, Hans-Peter Kuhlthau
  • Patent number: 4066653
    Abstract: This invention relates to novel compounds of the isoindolenine series. More particularly, the present invention relates to certain novel 1-imono-3-(4-imino-5-thiazolidinylidene)isoindolines, 1-imino-3-(4-imino-2-thiazolin-5-ylidene)isoindolines, water-insoluble pigments prepared therefrom, and to methods for their preparation.
    Type: Grant
    Filed: June 1, 1976
    Date of Patent: January 3, 1978
    Assignee: Sterling Drug Inc.
    Inventors: Nathan N. Crounse, Nicholas A. Ambrosiano
  • Patent number: 4048156
    Abstract: This disclosure teaches a method for employing novel carbamoylphosphonates such as ammonium ethyl carbamoylphosphonate, ammonium isopropyl carbamoylphosphonate and ammonium allyl carbamoylphosphonate to regulate the growth rate of plants. SPCROSS REFERENCE TO RELATED APPLICATIONSThis application is a division of application Ser. No. 553,423, filed Feb. 26, 1975, now U.S. Pat. No. 3,997,544, which is a division of application Ser. No. 283,769, filed Aug. 25, 1972, now U.S. Pat. No. 3,846,512, which is a continuation-in-part of application Ser. No. 85,221, filed Oct. 29, 1970, now U.S. Pat. No. 3,819,353, which is a continuation-in-part of my application Ser. No. 803,962, filed Mar. 3, 1969, now abandoned, which was in turn a continuation-in-part of my earlier application Ser. No. 731,732, filed May 24, 1968, now U.S. Pat. No. 3,627,507.
    Type: Grant
    Filed: September 14, 1976
    Date of Patent: September 13, 1977
    Assignee: E. I Du Pont de Nemours and Company
    Inventor: William P. Langsdorf, Jr.
  • Patent number: RE29681
    Abstract: Disclosed are novel metal salts of 1,1,5,5-tetrasubstituted dithiobiurets of the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4, when taken independently of each other are selected from the group consisting of C.sub.1 -C.sub.18 alkyl, C.sub.6 -C.sub.12 aryl, C.sub.3 -C.sub.12 cycloalkyl, and these radicals substituted by at least one member of the group consisting of hydroxyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.8 acyl, halo and nitro, and R.sup.1 and R.sup.2, when taken together along with the nitrogen to which they are bonded, and .?.R.sub.3 .!. .Iadd.R.sup.3 .Iaddend.and R.sup.4 when taken together with the nitrogen to which they are bonded, are selected from the group consisting of N-morpholinyl, N-piperidyl, N-pyrrolidyl and N-aziridinyl. The compounds are useful as population control agents.
    Type: Grant
    Filed: January 12, 1977
    Date of Patent: June 27, 1978
    Assignee: Hercules Incorporated
    Inventor: William R. Diveley