Plural 1,4-oxazine Rings Are Cyclos In The Polycyclo Ring System Patents (Class 544/74)
  • Patent number: 6559143
    Abstract: There is provided compounds of formula I, wherein R1, R2, R3, R4, R41 to R46, A, B and G have meanings given in the description, which are useful in the prophylaxis and in the treatment of arrhythmias, in particular atrial and ventricular arrhythmias.
    Type: Grant
    Filed: October 16, 2000
    Date of Patent: May 6, 2003
    Assignee: AstraZeneca AB
    Inventors: Annika Björe, Magnus Björsne, Kurt-Jürgen Hoffmann, Fritiof Pontén, Gert Strandlund, Peder Svensson, Michael Wilsterman
  • Patent number: 6515123
    Abstract: The invention is directed to carbamate group containing non chloranil based triphendioxazine compounds useful as pigments which are readily convertible into the corresponding triphendioxazine pigments without carbamate.
    Type: Grant
    Filed: February 9, 2001
    Date of Patent: February 4, 2003
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bansi Lal Kaul, Bruno Piastra, Pascal Steffanut
  • Patent number: 6512115
    Abstract: The invention relates to a process for preparing triphendioxazine compounds by cyclizing the intermediates (IV) in the presence of manganese oxide and sulfuric acid to form compounds of the general formula (I) a process for condensing compounds of the general formula (II) with compounds of the general formula (III) to form the chlorine-free intermediates (IV) and also compounds of the general formula (IV).
    Type: Grant
    Filed: March 6, 2001
    Date of Patent: January 28, 2003
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bansi Lal Kaul, Bruno Piastra, Pascal Steffanut
  • Patent number: 6476222
    Abstract: A process for improving the heat stability of Pigment Violet 23 by conditioning crude Pigment Violet 23 in the presence of about 1 to 10 wt. % of Pigment Violet 23 by-products (1), (2) and (3).
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: November 5, 2002
    Assignee: Sun Chemical Corporation
    Inventors: Norman W. Smith, Terrence R. Chamberlain, Barbara N. Berg, George McLaren, Russell J. Schwartz
  • Publication number: 20020123626
    Abstract: Process for phase conversion of a methyl-substituted, benzimidazolone-fused dioxazine pigment of composition C22H12Cl2N6O4 having the formula (1) 1
    Type: Application
    Filed: October 22, 2001
    Publication date: September 5, 2002
    Inventors: Martin U. Schmidt, Peter Kempter, Roland Born
  • Publication number: 20020091258
    Abstract: A mixed crystal of two or more different benzimidazolonedioxazine compounds of the formula (1) 1
    Type: Application
    Filed: October 24, 2001
    Publication date: July 11, 2002
    Applicant: Clariant GmbH
    Inventors: Martin U. Schmidt, Peter Kempter, Carsten Plueg, Roland Born
  • Publication number: 20020065401
    Abstract: The invention relates to novel soluble pigment precursors possessing not only higher thermal stability but also improved solubility characteristics and to a process for mass coloration of high temperature polymers that utilizes these novel soluble pigment precursors.
    Type: Application
    Filed: November 20, 2001
    Publication date: May 30, 2002
    Inventors: Leonhard Feiler, Zhimin Hao
  • Patent number: 6355795
    Abstract: The triphendioxazine compounds of the general formula (I) in which the rings labelled A in positions 1,2-, 2,3- or 3,4- and 8,9-, 9,10- or 10,11- carry a linearly or angularly fused heterocyclic ring containing at least one nitrogen atom which is substituted or unsubstituted, with the proviso that compounds with only unsubstituted nitrogen atoms and symmetrically disubstituted compounds with C1-2alkyl and unsubstituted phenyl substituents are excluded, are outstanding pigments and are notable over the closest comparable pigments in particular for better migration, light and solvent fastnesses, better heat stability and enhanced coloring power and also better dispersibility and capability to be brought into pigment form. The invention also relates to a process for preparing these triphendioxazine compounds which is characterized by a cyclization step conducted in the presence of manganese dioxide and concentrated sulphuric acid.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: March 12, 2002
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Patrick Boeglin, Bansi Lal Kaul, Peter Kempter
  • Publication number: 20010031863
    Abstract: Carbamate group-containing triphendioxazine compounds of the formula (I) 1
    Type: Application
    Filed: February 9, 2001
    Publication date: October 18, 2001
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Bansi Lai Kaul, Bruno Piastra, Pascal Steffanut
  • Patent number: 6274728
    Abstract: Compounds of formula A(B)x  (I), wherein x is an integer from 1 to 8, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, indanthrone, isoindolinone, isoindoline, dioxazine, azo, phthalocyanine or diketopyrrolopyrrole series that is bonded to x groups B via one or more hetero atoms, those hetero atoms being selected from the group consisting of N, O and S and forming part of the radical A, each group B independently of any other(s) is hydrogen or a group of the formula  at least one group B being a group of the formula The compounds according to the invention are used in high-molecular-weight organic materials, thermo-, photo- or chemo-sensitive recording materials, light-sensitive negative or positive resist compositions, ink compositions for ink-jet printing and color tapes for thermal transfer printing.
    Type: Grant
    Filed: December 16, 1999
    Date of Patent: August 14, 2001
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Véronique Hall-Goulle, Aline Bize
  • Patent number: 6255482
    Abstract: The triphendioxazine compounds of the general formula (I) in which the rings labelled A in positions 1,2-, 2,3- or 3,4- and 8,9-, 9,10- or 10,11- carry a linearly or angularly fused heterocyclic ring containing at least one nitrogen atom which is substituted or unsubstituted, with the proviso that compounds with only unsubstituted nitrogen atoms and symmetrically disubstituted compounds with C1-2alkyl and unsubstituted phenyl substituents are excluded, are outstanding pigments and are notable over the closest comparable pigments in particular for better migration, light and solvent fastnesses, better heat stability and enhanced colouring power and also better dispersibility and capability to be brought into pigment form. The invention also relates to a process for preparing these triphendioxazine compounds which is characterized by a cyclization step conducted in the presence of manganese dioxide and concentrated sulphuric acid.
    Type: Grant
    Filed: October 19, 1998
    Date of Patent: July 3, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Patrick Boeglin, Bansi Lal Kaul, Peter Kempter
  • Patent number: 6214989
    Abstract: Carbamate group-containing triphendioxazine compounds of the formula (I) where the nuclei designated A and B, as defined in claim 1, contain fused-on rings and R1, R2 and R3 have the meanings specified in claim 1, are good pigments and are convertible into the corresponding triphendioxazine pigments without carbamate groups.
    Type: Grant
    Filed: March 24, 1999
    Date of Patent: April 10, 2001
    Assignee: Clariant International, Ltd. Muttenz
    Inventors: Bansi Lal Kaul, Bruno Piastra
  • Patent number: 6162261
    Abstract: The invention relates to triphendioxazine compounds of the formula (I) ##STR1## where the rings marked with A comprise, independently of one another, rings which are fused linearly in positions 2,3 and 9,10 or angularly in positions 1,2 and 8,9 or 3,4 and 10,11 and have the radical members of the formula (i) --NR.sub.1 (CO).sub.m --NH--, (ii) --CR.sub.1 .dbd.CH--CO--NH--, (iii) --O--CH.sub.2 --CO--NH--, (iv) --CO--CH.dbd.CR.sub.1 --NH--, (v) --CO--NH--CO--NH--, (vi) --CO--NH--CR.sub.2 .dbd.N--, (vii) --CR.sub.2 .dbd.N--CO--NH--, (viii) --NR.sub.1 --(CO).sub.m --O--, (ix) --NH--CR.sub.1 .dbd.N--, (x) --NH--CO--CR.sub.1 .dbd.N--, (xi) --NH--CO--CHR.sub.1 --NH--, (xii) --NR.sub.3 --(CO).sub.m --NR.sub.4 --, (xiii) --NR.sub.5 --(CO).sub.m --NR.sub.6 --, (xiv) --NR.sub.4 --CO--O-- or (xv) --NR.sub.6 --CO--O--,m is 1 or 2,R.sub.1 is hydrogen, C.sub.1-4 alkyl or phenyl, preferably hydrogen, methyl or ethyl,R.sub.2 is hydrogen, C.sub.1-4 alkyl or phenyl, preferably hydrogen, methyl or ethyl,R.sub.3, R.sub.4, R.sub.
    Type: Grant
    Filed: June 24, 1998
    Date of Patent: December 19, 2000
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Peter Kempter, Bansi Lal Kaul
  • Patent number: 6013777
    Abstract: Compounds of formulaA(B).sub.x, (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m and n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.
    Type: Grant
    Filed: June 10, 1998
    Date of Patent: January 11, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Zhimin Hao, John S. Zambounis, Abul Iqbal
  • Patent number: 5973144
    Abstract: Benzoxazine monomers, oligomers and polymers are desirably modified by adding pendant functional groups to either the amine or phenolic reactants. These pendant functional groups can be activated at temperatures generally from about 25.degree. C. to about 300.degree. C. to form chemical bonds between said benzoxazine monomers, oligomers and polymers. The additional chemical bonds increase the thermal stability of benzoxazine polymers such that they can withstand higher use temperature, act as more effective flame barriers, or result in higher amounts of char if used as a precursor to high temperature (600-1000.degree. C. reaction condition) chars.
    Type: Grant
    Filed: October 3, 1997
    Date of Patent: October 26, 1999
    Inventor: Hatsuo Ishida
  • Patent number: 5886160
    Abstract: Compounds of formulaA(B).sub.x, (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m and n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.
    Type: Grant
    Filed: June 12, 1998
    Date of Patent: March 23, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Zhimin Hao, John S. Zambounis, Abul Iqbal
  • Patent number: 5859242
    Abstract: The present invention relates to a process for producing a dioxazine compound represented by the formula (1) which comprises carrying out a ring closure reaction of a compound represented by the formula (2) in the presence of a dioxazine derivative of the formula (3), colored materials containing this dioxazine compound, and dioxazine compounds having a plate-like crystal form: ##STR1##
    Type: Grant
    Filed: September 25, 1997
    Date of Patent: January 12, 1999
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Masaaki Ikeda, Junko Yoshioka, Masao Onishi
  • Patent number: 5780627
    Abstract: Compounds of formulaA(B).sub.x, (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m und n, are as defined in claim 1. These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.
    Type: Grant
    Filed: July 9, 1996
    Date of Patent: July 14, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Zhimin Hao, John S. Zambounis, Abul Iqbal
  • Patent number: 5734050
    Abstract: The present invention relates to a process for producing a dioxazine compound represented by the formula (1) which comprises carrying out a ring closure reaction of a compound represented by the formula (2) in the presence of a dioxazine derivative of the formula (3): ##STR1##
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: March 31, 1998
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Masaaki Ikeda, Junko Yoshioka, Masao Onishi
  • Patent number: 5565563
    Abstract: Triphendioxazine compounds of formula I, ##STR1## in which R.sub.1 and R.sub.2 are either both hydrogen or form a single chain linking the 8,9-; 9,10- or 10,11-positions, the single chain having the formula --NR.sub.5 ---(CO).sub.m --NH--, --CR.sub.5 .dbd.CH--CO--NH--, --CO--CH.sub.2 --CO--NH--, --CO--CH.dbd.CR.sub.5 --NH--, --CO--NH--CO--NH--, --CO--NH--CR.sub.6 .dbd.N--, --CR.sub.6 .dbd.N--CO--NH--, --NR.sub.5--(CO).sub.m --O--or --NH--CR.sub.5 .dbd.N--whereR.sub.5 is hydrogen, C.sub.1-4 alkyl or phenyl, R.sub.6 is hydrogen, C.sub.1-4 alkyl or phenyl;m is 1 or 2 and R.sub.3 and R.sub.4 are either both hydrogen or form a single chain linking the 1,2-, 2,3- or 3,4-positions, the single chain having a formula selected from --NR.sub.5 --(CO).sub.m --NH--, --CR.sub.5 .dbd.CH--CO--NH--, --O--CH.sub.2 --CO--NH--, --CO--CH.dbd.CR.sub.5 --NH--, --CO--NH--CO--NH--, --CONH--CR.sub.6 .dbd.N--, --CR.sub.6 .dbd.N--CO--NH--, --NR.sub.5 --(CO).sub.m --O--or --NH--CR.sub.5 .dbd.N--where the symbols R.sub.5, R.sub.
    Type: Grant
    Filed: December 2, 1994
    Date of Patent: October 15, 1996
    Assignee: Sandoz Ltd.
    Inventors: Bansi L. Kaul, Peter Kempter
  • Patent number: 5561232
    Abstract: Compounds of formulaA(B).sub.x, (I),whereinx is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m and n, are as defined in claim 1. These carbamate group-containing soluble chromophores am distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: October 1, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Zhimin Hao, John S. Zambounis, Abul Iqbal
  • Patent number: 5334727
    Abstract: Pyrazole derivatives of a variety of polycyclic pigments, particularly quinacridone pigments, corresponding to the general formula ##STR1## wherein Q is the primary pigment structure; and the use of such derivatives as additives to pigment systems to provide a broad range of performance benefits to the resulting pigment compositions.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: August 2, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Colin D. Campbell
  • Patent number: 5275653
    Abstract: In order to improve the application properties, in particular the rheological and coloristic properties, and the gloss behavior and the flocculation stability of dioxazine pigments in acrylic varnishes, the surface of the base pigment is modified by coating with sulfo-containing dioxazine derivatives, which in most cases have been converted into the corresponding metal salts, into specific salt-like derivatives derived therefrom or, if desired, into cyclic ammonium compounds. Such a modification of the base pigment, i.e. production of the pigment preparations according to the invention by adding the specific dispersant, can take place at the stage of the pigment synthesis, during a comminution process of the coarse-crystalline crude pigment, by addition to the already finely divided crude pigment in the course of a subsequent solvent finish treatment or by mechanical mixing of the two essential components, pigment and dispersant.
    Type: Grant
    Filed: March 20, 1992
    Date of Patent: January 4, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Erwin Dietz, Manfred Urban
  • Patent number: 5268474
    Abstract: The invention relates to an improved process for the preparation of dyestuffs based on at least one triphendioxazine which is linked to a further chromophore via a triazine at a pH of 5.5 to 2.0 and a temperature of 50 to 100.degree. C.
    Type: Grant
    Filed: January 9, 1992
    Date of Patent: December 7, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventor: Horst Jager
  • Patent number: 5166338
    Abstract: Anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone and perylenetetracarbimide dyes which contain one or two groups of the general formula ##STR1## where Y is vinyl or an ethyl group which contains in a .beta.-position a substituent which is eliminable by means of alkali to form a vinyl group, and W is a direct bond or a group of the general formula ##STR2## where M is a hydrogen atom or an alkali metal and n is zero, 1 or 2. The dyes have very good fiber-reactive properties and are advantageously suitable for dyeing carboxamino- and/or hydroxy-containing material, for example wool, in particular cellulose fiber materials; on these materials they produce strong fast shades in a high degree of fixation.
    Type: Grant
    Filed: February 13, 1991
    Date of Patent: November 24, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Holger M. Buch, Josef Geisenberger, Hartmut Springer
  • Patent number: 5138054
    Abstract: Triphendioxazine reactive dyestuffs of the general formula ##STR1## with the substituent definition given in the description, are outstandingly suitable for dyeing and printing materials containing hydroxyl groups or amide groups. They give red dyeings with high wet- and light-fastnesses.
    Type: Grant
    Filed: February 15, 1991
    Date of Patent: August 11, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventor: Wolfgang Harms
  • Patent number: 5003049
    Abstract: The compounds of the general formula (I) ##STR1## where A is a dye radical, where relevant the radicals Y independently of one another are each oxygen, sulfur, R.sup.1 --N or a direct bond, n is 1 or 2, the radicals R.sup.1 independently of one another are each hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl and Z is a bridge member, are very useful for dyeing hydroxyl-containing textile material.
    Type: Grant
    Filed: February 8, 1989
    Date of Patent: March 26, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Udo Bergmann, Alfred Hackenberger, Manfred Patsch
  • Patent number: 4968797
    Abstract: 4,4-diaryldihydroquinazolones of the formula ##STR1## wherein X.sup.1, X.sup.2 and X.sup.3, independently of one another, denote hydrogen, halogen, alkyl, aryl, alkanoylamino, aroylamino, heteryl, NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3, at least one of the radicalsX.sup.1, X.sup.2 or X.sup.3 standing for NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl or the members of a bridge to the o-carbon of ring C,R.sup.2 denotes a radical of an acid,Y.sup.1, Y.sup.2 and Y.sup.3, independently of one another, denote hydrogen, alkyl, cycloalkyl, aralkyl aryl or heteryl or the remaining members of a 5- or 6-membered ring which reaches to one of the o-position benzene C atoms and may contain further hetero atoms orY.sup.1 +Y.sup.
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: November 6, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Berneth, Alfred Brack, Karlheinrich Meisel
  • Patent number: 4923988
    Abstract: Triphendioxazines are prepared by cyclizing benzoquinone derivatives in oleum in the presence of an organic iodine compound.
    Type: Grant
    Filed: October 14, 1988
    Date of Patent: May 8, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Uwe Nahr, Manfred Pastsch
  • Patent number: 4897223
    Abstract: Color-forming agents of the general formula ##STR1## wherein X denotes hydroxyl, alkoxy, alkenyloxy, aralkoxy, cycloalkoxy, aryloxy, acyloxy, alkoxycarbonyloxy, alkylamino, dialkylamino, acylamino, aralkylamino or arylamino,Q denotes cyano, alkoxycarbonyl, aryloxycarbonyl, aralkoxycarbonyl, carbamoyl, N-alkylcarbamoyl, N,N-dialkylcarbamoyl, N-alkyl-N-aryl-carbamoyl, acyl, alkoxysulphonyl, aralkoxysulphonyl, sulphamoyl, N-alkylsulphamoyl, N,N-dialkylsulphamoyl, alkylsulphonyl, arylsulphonyl or aralkylsulphonyl andR denotes alkyl, alkenyl or aralkyl,further isocyclic or heterocyclic rings can be fused on to the rings A, B, C and D, and the cyclic and acyclic radicals and the rings A, B, C and D can carry further substituents, are used for the preparation of pressure-sensitive recording materials.
    Type: Grant
    Filed: March 1, 1988
    Date of Patent: January 30, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Udo Eckstein, Hubertus Psaar, Roderich Raue
  • Patent number: 4876342
    Abstract: Oxazine compounds containing basic groups correspond to the formula ##STR1## wherein the symbols are as defined in the Specification. These compounds are suitable for dyeing or printing organic substrates containing hydroxy groups or nitrogen in accordance with known methods. Preferred substrates are textile materials which consist of or contain natural or regenerated cellulose, e.g. cotton, but also bast fibres or leather. Most preferred substrates are paper or paper products. Furthermore, these compounds can be used to prepare all kinds of inks, such as ball-pen inks or printing inks.Similarly, a mixture of one or more of the above compounds together with one or more copper phthalocyanine dyes containing basic and/or cationic groups can be used as dyeing or printing agent.
    Type: Grant
    Filed: May 26, 1988
    Date of Patent: October 24, 1989
    Assignee: Sandoz Ltd.
    Inventor: Reinhard Pedrazzi
  • Patent number: 4841048
    Abstract: A dioxazine compound of the formula, ##STR1## wherein A is a divalent group of the formula, ##STR2## in which * and ** denote linkages to the adjacent nitrogen and oxygen atoms, respectively, or the divalent group-containing 3- to 5-condensed aromatic ring residue, R is a substituent such as amino, cyano, nitro, halogeno and the like, V is --SO.sub.2 NR.sub.5 - or the like in which R.sub.5 is hydrogen or the like, X is aliphatic, alicyclic, araliphatic or aromatic divalent group, Y is phenylene or naphthylene, Z is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z.sub.1 in which Z.sub.1 is a splittable group, Q is halogeno, amino or the like, R.sub.1 and R.sub.2 are each hydrogen or alkyl, and O<l+m+n.ltoreq.6, provided that O.ltoreq.l.ltoreq.4, O.ltoreq.m<5 and O<n.ltoreq.
    Type: Grant
    Filed: November 19, 1987
    Date of Patent: June 20, 1989
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hirokazu Sawamoto, Takashi Omura, Naoki Harada
  • Patent number: 4835270
    Abstract: Compounds of the formula ##STR1## wherein Z.sup.1 denotes hydrogen, alkyl, cycloalkyl or ##STR2## R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl, heteroalkyl or heteryl,X.sup.1, X.sup.2 and X.sup.3 denote hydrogen, halogen, alkyl, cycloalkyl, aryl, alkanoylamino, aroylamino or heteryl, and at least one of these radicals denotes NH.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,Y.sup.1, Y.sup.2 and Y.sup.3 denote hydrogen, alkyl, cycloalkyl, aralkyl, aryl or heteryl andY.sup.1 +Y.sup.2 denote the remaining members of a 5-membered or 6-membered ring which optionally contains further hetero-atoms,are outstandingly suitable as colour-forming agents for pressure-sensitive, heat-sensitive and electrosensitive recording materials with an acid developer. Deep copies which are fast to light are obtained.
    Type: Grant
    Filed: December 18, 1988
    Date of Patent: May 30, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventor: Horst Berneth
  • Patent number: 4831141
    Abstract: The invention relates to chromogenic 3,1-benzoxazines of the formula ##STR1## wherein X.sup.1 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, chlorine or OY.sup.1,X.sup.2 denotes NY.sup.2 Y.sup.3,X.sup.3 denotes OY.sup.4 or NY.sup.5 Y.sup.6,R.sup.1 -R.sup.3 independently of one another denote hydrogen, C.sub.1 -C.sub.4 -alkyl, chlorine, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -mono- or -dialkylamino, orR.sup.1 together with Y.sup.2,R.sup.2 or R.sup.3 together with Y.sup.4 or Y.sup.5, orR.sup.2 and R.sup.3 simultaneously with Y.sup.5 and Y.sup.6 denote a 2 to 4-membered bridge which can contain one oxygen atom or one nitrogen atom and can carry up to 4 methyl groups, and whereinR.sup.1 and R.sup.3 simultaneously represent hydrogen only if R.sup.2 with Y.sup.4 or Y.sup.5 forms one of the abovementioned bridges,R.sup.4 denotes hydrogen, methyl or chlorine,Y.sup.1 and Y.sup.4 independently of one another denote C.sub.1 -C.sub.4 -alkyl, cyclohexyl or benzyl and Y.sup.2, Y.sup.3, Y.sup.5 and Y.sup.
    Type: Grant
    Filed: June 1, 1987
    Date of Patent: May 16, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Berneth, Gert Jabs
  • Patent number: 4812569
    Abstract: Chromogenic phthalides of the general formula ##STR1## wherein R.sub.1 and R.sub.2 independently of one another denote hydrogen, alkyl, alkenyl, aralkyl, cycloalkyl or aryl or are linked to the ring A or B respectively in the o-position to the nitrogen and then represent the remaining members of a partially or fully hydrogenated heterocyclic 5-membered or 6-membered ring which can contain a further heteroatom from the series O, S, N--R.sub.1 or N--R.sub.2,X.sub.1, X.sub.2, X.sub.3 and X.sub.4 independently of one another denote hydrogen, halogen, alkyl, alkenyl, aralkyl, cycloalkyl, aryl, hydroxyl, alkoxy, alkenyloxy, aralkoxy, cycloalkoxy, aryloxy, acyloxy, alkylmercapto, arylmercapto, aralkylmercapto, alkylsulphonyl, alkoxycarbonyl or nitro or X.sub.1 +X.sub.2, X.sub.2 +X.sub.3 or X.sub.3 +X.sub.4 denote a fused benzene ring,Z.sub.1 and Z.sub.
    Type: Grant
    Filed: February 27, 1987
    Date of Patent: March 14, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventor: Udo Eckstein
  • Patent number: 4801702
    Abstract: A process for the preparation and conditioning of organic pigments, which comprises the use of at least one tricyclodecane alcohol or tricyclodecene alcohol.
    Type: Grant
    Filed: October 30, 1986
    Date of Patent: January 31, 1989
    Assignee: Ciba-Geigy Corporation
    Inventor: Fridolin Babler
  • Patent number: 4766211
    Abstract: Chromogenic quinazolines of formula ##STR1## wherein R is an aryl radical or a heterocyclic radical,Z.sub.1 is oxygen or sulfur,Z.sub.2 is oxygen, sulfur or ##STR2## R' is hydrogen, alkyl which is unsubstituted or substituted by halogen, cyano or lower alkoxy, or is cycloalkyl, phenyl, benzyl, phenethyl or acyl, or --NRR' is a 5- or 6-membered heterocyclic radical,Q is an aliphatic radical which may be interrupted by a further member Z.sub.2,Y is the radical of a couplable compound, and the ringA is unsubstituted or substituted by halogen, cyano, nitro, lower alkyl, lower alkoxy or lower alkoxycarbonyl.These quinazolines are exceedingly fast to sublimation and are particularly suitable color formers in pressure-sensitive or heat-sensitive recording materials and give strong and lightfast yellow and orange colorations.
    Type: Grant
    Filed: August 27, 1986
    Date of Patent: August 23, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf Zink, Ian J. Fletcher
  • Patent number: 4754034
    Abstract: 4,4-diaryldihydroquinazolones of the formula ##STR1## wherein X.sup.1, X.sup.2 and X.sup.3, independently of one another, denote hydrogen, halogen, alkyl, aryl, alkanoylamino, aroylamino, heteryl, NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3, at least one of the radicals X.sup.1, X.sup.2 or X.sup.3 standing for NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl or the members of a bridge to the o-carbon of ring C,R.sup.2 denotes a radical of an acid,Y.sup.1, Y.sup.2 and Y.sup.3, independently of one another, denote hydrogen, alkyl, cycloalkyl, aralkyl aryl or heteryl or the remaining members of a 5- or 6-membered ring which reaches to one of the o-position benzene C atoms and may contain further hetero atoms orY.sup.1 +Y.sup.
    Type: Grant
    Filed: October 21, 1985
    Date of Patent: June 28, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Berneth, Alfred Brack, Karlheinrich Meisel
  • Patent number: 4751300
    Abstract: Dioxazine compound of the formula (I) mentioned below which is useful for dyes or pigments is prepared by heating a compound of ##STR1## in the presence of inorganic acid with or without an oxidizing agent in an inert organic solvent: ##STR2## wherein R is defined above; X.sub.1 and X.sub.2 are selected from a hydrogen atom and a chlorine atom.
    Type: Grant
    Filed: January 30, 1987
    Date of Patent: June 14, 1988
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Taira Fujita, Yutaka Kayane
  • Patent number: 4727140
    Abstract: 4,4-Diaryl-2-oxobenzo-3,1-oxazines of the general formula ##STR1## wherein X.sup.1, X.sup.2 and X.sup.3, independently of one another, denote hydrogen, halogen, alkyl, aryl, alkanoylamino, aroylamino, heteryl, NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,at least one of the radicals X.sup.1, X.sup.2 or X.sup.3 standing for NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl or the members of a bridge to the o-carbon of ring B,Y.sup.1, Y.sup.2 and Y.sup.3, independently of one another, denote hydrogen, alkyl, cycloalkyl, aralkyl or aryl or the remaining members of a 5- or 6-membered ring which reaches to one of the o-position benzene C atoms and may contain further heteroatoms or Y.sup.1 +Y.sup.
    Type: Grant
    Filed: October 21, 1985
    Date of Patent: February 23, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karlheinrich Meisel, Horst Berneth
  • Patent number: 4710569
    Abstract: Dyestuffs of the formula ##STR1## wherein F stands for an organic chromophore andZ stands for radicals of the formulae ##STR2## wherein R.sub.1 -R.sub.2 denote hydrogen, alkyl, cycloalkyl, alkenyl, aryl, aralkyl or a heterocyclic structure orR.sub.2 and R.sub.3 represent an optionally substituted amino group or together form a ring orR.sub.1 with R.sub.2 and/or R.sub.3 with R.sub.4 form a ring,A.sup.(-) denotes an anion,Y denotes an anionic group,m denotes 0-2 andn denotes 1-6,and wherein the chromophore and said radicals can carry further substituents, provided that the total number of anionic substituents is smaller than the total number of quaternary and quaternizable amino groups, are used for dyeing cellulose fibres, in particular paper.
    Type: Grant
    Filed: September 10, 1985
    Date of Patent: December 1, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunter Franke, Dieter Ockelmann, Roderich Raue, Peter Wild
  • Patent number: 4695630
    Abstract: New polycyclic acetals of the formula ##STR1## in which R.sub.1 represents an optionally substituted alkyl, cycloalkyl, aralkyl, aryl or heteroaryl radical andR.sub.2, R.sub.3, R.sub.4 and R.sub.5 independently of one another denote hydrogen or an optionally substituted alkyl, cycloalkyl, aralkyl or aryl radical, orR.sub.3 and R.sub.4 together form an optionally substituted C.sub.2 -C.sub.6 -alkylene radical or R.sub.2, R.sub.3, R.sub.4 andR.sub.5 together form a fused, optionally substituted 1,2-phenylene radical,a process for their preparation and their use for the preparation of azalactones.
    Type: Grant
    Filed: January 22, 1986
    Date of Patent: September 22, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventor: Peter Haas
  • Patent number: 4695633
    Abstract: Chromogenic 4,4-diaryl-dihydroquinazolones of the formula ##STR1## wherein X.sup.1, X.sup.2 and X.sup.3 independently of one another represent hydrogen, halogen, alkyl, aryl, alkanoylamino, aroylamino, NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,and whereinat least one of the radicals X.sup.1, X.sup.2 or X.sup.3 represents NY.sup.1 Y.sup.2, OY.sup.3 or SY.sup.3,R.sup.1 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl or the members of a bridge to the o-carbon of ring C,R.sup.2 denotes hydrogen, alkyl, cycloalkyl, aralkyl, aryl, hetaralkyl or hetaryl,Y.sup.1, Y.sup.2 and Y.sup.3 independently of one another denote hydrogen, alkyl, cycloalkyl, aralkyl or aryl or the remaining members of a 5-membered or 6-membered ring which reaches to one of the benzene-C atoms in the o-position and optionally contains further hetero-atoms, orY.sup.1 +Y.sup.
    Type: Grant
    Filed: May 17, 1985
    Date of Patent: September 22, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Berneth, Alfred Brack
  • Patent number: 4668966
    Abstract: The invention relates to bisquinazolines of the formula ##STR1## wherein the ring A is unsubstituted or substituted by cyano, nitro, halogen, lower alkyl, phenyl, benzyl, lower alkoxy or lower alkoxycarbonyl,Q is an aliphatic radical with a molecular weight of 28 to 450, or is a cycloaliphatic or araliphatic radical,Y is the radical of the formula (2a) ##STR2## or of the formula ##STR3## wherein B, D, X.sub.1, X.sub.2, X.sub.3 and Z are as hereinafter defined. These compounds are particularly suitable as colour formers in pressure-sensitive or heat-sensitive recording materials and give strong yellow or orange colours of excellent fastness to light, especially fastness to sublimation.
    Type: Grant
    Filed: April 11, 1985
    Date of Patent: May 26, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf Zink, Ian J. Fletcher
  • Patent number: 4629788
    Abstract: Dyestuffs of the formula ##STR1## where the substituents are defined as in the descriptive part are highly suitable for dyeing and printing hydroxyl- or amide-containing materials. They produce bright dyeings and prints having good fastness properties.
    Type: Grant
    Filed: September 20, 1984
    Date of Patent: December 16, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventor: Horst Jager
  • Patent number: 4628086
    Abstract: A process for the preparation of dioxazine compounds of the formula ##STR1## in which B.sub.1 and B.sub.2 designate a ring system with 1, 2, 3 or 4 carbocyclic and/or heterocyclic rings which can be substituted, andX.sub.1 and X.sub.2 designate hydrogen, halogen, --R', --OR', --NHR', --NR'R", ##STR2## R' and R" representing alkyl, cycloalkyl, aryl and aralkyl and n denoting 2, 3, 4, 5, 6, 7, 8, 9, 10 or 11, it being possible for the n bromine atoms, independently of one another, to replace both H atoms of the ring systems B.sub.1 and B.sub.2 or their substituents and H atoms of X.sub.1 and X.sub.2 as well as X.sub.1 and X.sub.2 themselves,is characterized in that compounds of the formula II ##STR3## are reacted with bromine, preferably in the presence of diluents.
    Type: Grant
    Filed: December 2, 1985
    Date of Patent: December 9, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventor: Gunter Franke
  • Patent number: 4617387
    Abstract: The present invention relates to 2,3,2',3'-bis-morpholine derivatives corresponding to the formula ##STR1## The present invention also relates to a process for the preparation of these derivatives and to their use as hydrolysis protective agents for synthetic polymers containing ester groups and/or carbonate groups. Preferred synthetic polymers are polyurethanes.
    Type: Grant
    Filed: August 15, 1984
    Date of Patent: October 14, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Haas, James M. Barnes, Wilhelm Goyert
  • Patent number: 4607102
    Abstract: A compound which is represented by a free acid of the following formula, ##STR1## wherein X is hydrogen, halogen, alkyl or cyano, R.sub.1, R.sub.2 and R.sub.3 are independently hydrogen or alkyl, R.sub.4 is alkyl, W is alkylene, cycloalkylene or arylene, Q is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 L in which L is a group capable of being splitted by the action of an alkali, D is a benzene or naphthalene ring, l and m are independently a number of not less than 0 but not more than 3, and n is a number of more than 0 but not more than 3, provided that l, m and n satisfy 0<l+m+n.ltoreq.4, and which is useful for dyeing fiber materials a blue color with a good build-up property to give a dyed product having excellent fastness properties.
    Type: Grant
    Filed: January 24, 1984
    Date of Patent: August 19, 1986
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Masao Nishikuri, Takashi Omura, Akira Takeshita
  • Patent number: 4552874
    Abstract: The invention relates to pyrazolooxazines, pyrazolothiazines and pyrazoloquinolines defined herein by Formula I. The invention also includes compositions containing said Formula I compounds and methods for the use of said compounds and compositions for their lipoxygenase-inhibiting properties. Also included in the invention are methods for the manufacture of said compounds of Formula I.
    Type: Grant
    Filed: February 1, 1983
    Date of Patent: November 12, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Mithat Mardin, Rudolf Sundermann, Friedrich Hoffmeister, Wolf-Dieter Busse, Harald Horstmann, Siegfried Raddatz
  • Patent number: 4526963
    Abstract: Disclosed are dioxazine compounds of formula I ##STR1## in which each R, independently, is C.sub.1-4 alkyl, their production and use as pigments.
    Type: Grant
    Filed: October 28, 1982
    Date of Patent: July 2, 1985
    Assignee: Sandoz Ltd.
    Inventor: Michel Deur