Plural 1,4-oxazine Rings Are Cyclos In The Polycyclo Ring System Patents (Class 544/74)
  • Patent number: 4512773
    Abstract: A dyestuff of formula: ##STR1## wherein: the groups X.sub.1 and X.sub.2 are independently hydrogen, halogen, alkyl, aryl, alkoxy, cyano, optionally substituted amino or carboxylic acid ester groups; (R).sub.n represents n substituents R each of which is independently halogen, lower alkyl, lower alkoxy or --COOH and n is 0 or 1; R.sub.1 is hydrogen, or optionally substituted lower alkyl; Y is an optionally substituted aliphatic or optionally substituted araliphatic group; R.sub.2 is hydrogen, optionally substituted lower alkyl, optionally substituted aryl or optionally substituted aralkyl; R.sub.3 is hydrogen or an optionally substituted alkyl or aralkyl group; A.sup.- is an anion; a is 0 or 1; and Z is hydrogen, optionally substituted lower alkyl, optionally substituted aryl or optionally substituted aralkyl.The dyes are useful for the coloration of materials such as textiles, leather, inks and lacquers.
    Type: Grant
    Filed: May 10, 1983
    Date of Patent: April 23, 1985
    Assignee: Imperial Chemical Industries PLC
    Inventors: Kenneth Anderton, Nigel Hall, Brian Parton, Andrew H. M. Renfrew, Malcolm G. Shaw
  • Patent number: 4491662
    Abstract: Dyes of the formula ##STR1## where F is an (m+n)-valent radical of a quinophthalone, dioxazine, indigo, quinacridone, triphenylmethane or rhodamine dye, M.sup..sym. is H.sup..sym. or one equivalent of a metal cation, m is 0, 1 or 2 and n is 1, 2, 3 or 4, and their salts, are very useful for dyeing and printing paper. If they are used for wet-end dyeing, the waste water is virtually colorless. The colorations obtained exhibit good lightfastness and good bleeding fastness.
    Type: Grant
    Filed: April 20, 1982
    Date of Patent: January 1, 1985
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Patsch, Manfred Ruske
  • Patent number: 4476125
    Abstract: New benzobisoxazinetetrones having anti-allergic activity are described. These benzobisoxazinetetrones are represented by the following formula: ##STR1## and pharmaceutically acceptable salts thereof, wherein: X and Y are independently O, S, NH, N-alkyl or N-aryl;R.sub.1 is H, lower alkyl, aryl, aralkyl, heteroalkyl, alkoxyalkyl, aminoalkyl or carboxyalkyl;R.sub.2 and R.sub.3 are independently H, OH, alkoxy, lower alkyl, aryl, aralkyl, halogen, trifluoromethyl, nitro, cyano, carboxy or sulfonamidouseful in the treatment of allergies.
    Type: Grant
    Filed: March 24, 1983
    Date of Patent: October 9, 1984
    Assignee: USV Pharmaceutical Corporation
    Inventors: Bernard Loev, Fu-Chih Huang
  • Patent number: 4459233
    Abstract: A process for purifying crude organic pigments, wherein the crude pigment is suspended in a mixture of two organic liquids which are partially or completely immiscible with one another, the suspension is mixed at 50.degree.-180.degree. C. until equilibrium has been reached, the phases are allowed to separate, the phase containing the impurities (i.e. the first liquid) is separated off and the purified pigment is isolated from the other phase (i.e. the second liquid).Finely divided crude pigments can, directly after purification, be converted, while in the second liquid, into pigmentary forms.The process gives pigments of high purity, which after conversion into pigmentary forms give deep, brilliant colorations.
    Type: Grant
    Filed: March 31, 1982
    Date of Patent: July 10, 1984
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Fabian, Rudolf Polster
  • Patent number: 4400504
    Abstract: The invention relates to new dioxazine reactive dyestuffs of the formula ##STR1## a process for their preparation and their use in dyeing and printing fibre materials which contain hydroxyl groups or amide groups.In formula (I):D denotes a radical of the dioxazine system of the formula ##STR2## the radicals Y, Z, A, X.sub.1 and X.sub.2 as well as m and n having the meaning indicated in the text of the application.The invention further relates to a process for the preparation of these new dioxazine reactive dyestuffs as well as their use in dyeing and printing fibre materials which contain hydroxyl groups or amide groups.
    Type: Grant
    Filed: November 10, 1981
    Date of Patent: August 23, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Harms, Klaus Wunderlich
  • Patent number: 4395545
    Abstract: The invention discloses novel basic dioxazine compounds of the formula ##STR1## wherein each of X.sub.1 and X.sub.2 independently is an unbranched or branched alkyl group of 1 to 4 carbon atoms, an unsubstituted or substituted phenyl group, halogen, hydrogen, cyano, a phenylamino group which is unsubstituted or substituted in the phenyl nucleus, the CONH.sub.2 group, the CONH-phenyl group which can be substituted in the phenyl moiety, or a COO--C.sub.1 -C.sub.4 alkyl group; Z is a non-quaternized or quaternized basic group, Y is an anionic group, each B independently is a fused ring system containing 2 to 4 carbocyclic and/or heterocyclic rings and which, in addition to containing the substituents Z and Y, can be further substituted; n is 1 to 4 and m is 0 to 2, with the proviso that m is not greater than n. Processes for obtaining these compounds and their use as dyes for coloring and printing in particular cellulosic fabrics, without the addition of salt, are also disclosed.
    Type: Grant
    Filed: August 14, 1981
    Date of Patent: July 26, 1983
    Inventors: Jean-Marie Adam, Pierre Galafassi
  • Patent number: 4336377
    Abstract: Novel dioxazine compounds of the formula ##STR1## in which Z is a basic group, which can be quaternized, Y is an anionic group and X and X.sub.1 independently of one another are identical or different substituents from the category comprising: hydrogen, halogen, CN, substituted or unsubstituted alkyl (C.sub.1 -C.sub.4); substituted or unsubstituted phenyl; NHCOR.sub.1 in which R.sub.1 is alkyl (C.sub.1 -C.sub.4), cycloalkyl, substituted or unsubstituted aryl or a heterocyclic radical; and OCOR.sub.2 in which R.sub.2 is substituted or unsubstituted alkyl (C.sub.1 -C.sub.4) or cycloalkyl; or X and X.sub.1 are the group ##STR2## in which R.sub.4 and R.sub.5 independently of one another are: hydrogen, substituted or unsubstituted alkyl (C.sub.1 -C.sub.4), cycloalkyl or aryl, or R.sub.4 together with R.sub.5 and with the inclusion of the N atom forms a heterocyclic ring, or X and X.sub.1 are the group COOR.sub.6, in which R.sub.
    Type: Grant
    Filed: January 28, 1980
    Date of Patent: June 22, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean-Marie Adam, Pierre Galafassi
  • Patent number: 4317908
    Abstract: Dioxazine violet pigment having a stable crystal form is advantageously produced by heating a mixture containing an aqueous suspension of a metastable dioxazine violet pigment obtainable in a conventional manner and an aromatic compound having a low solubility in water such as benzoic acid. This stable pigment is useful as a paint and excellent in tinting strength, gloss and dispersibility.
    Type: Grant
    Filed: August 12, 1980
    Date of Patent: March 2, 1982
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Iwao Sakaguchi, Yoshiaki Hayashi
  • Patent number: 4290952
    Abstract: Aryl-1-mercaptoalkanoylproline and homoproline derivatives and their cyclized thiazadione heterocyclic analogues reduce blood pressure in animals by ACE inhibition.
    Type: Grant
    Filed: June 23, 1980
    Date of Patent: September 22, 1981
    Assignee: American Home Products Corporation
    Inventors: Meier E. Freed, James L. Diebold
  • Patent number: 4288227
    Abstract: Disclosed is a process for imparting coloration of good light fastness to a substrate comprising or consisting of homo- and co-polymers of acrylonitrile or of dicyanoethylene, or acid modified synthetic polyamide or polyester, which process comprises mass dyeing, dyeing or printing such substrate, employing, as dyestuff, a compound or mixture of compounds of formula I, ##STR1## wherein either R is hydrogen, or a straight or branched chain C.sub.1--8 alkyl radical, unsubstituted or mono-substituted by OH, CN, Cl, Br, CONH.sub.2, C.sub.1--4 -alkoxy, phenyl, phenoxy, --O--CO--R.sub.5 or --CO--O--R.sub.5,and R.sub.1 is a straight or branched chain C.sub.1--8 alkyl radical, unsubstituted or mono-substituted by OH, CN, Cl, Br, --CONH.sub.2, C.sub.1--4 alkoxy, phenyl, phenoxy, --O--CO--R.sub.5 or --CO--O--R.sub.5 ; or phenyl, unsubstituted or monosubstituted by halogen, C.sub.1--4 alkyl or C.sub.1--4 alkoxy,or R and R.sub.
    Type: Grant
    Filed: May 16, 1979
    Date of Patent: September 8, 1981
    Assignee: Sandoz Ltd.
    Inventors: Berthold Gertisser, Beat Henzi