Azide Or Acyclic Nitrogen Containing Patents (Class 546/12)
  • Patent number: 4355161
    Abstract: A new composition of matter comprising molybdenum trioxide and heterocyclic nitrogen or oxygen Lewis bases. The molybdenum trioxide, upon reaction with Lewis base, forms a layered compound characterized in that the Lewis base is covalently bonded to molybdenum atoms in molybdenum oxide layers. The layered compound has the formula LMoO.sub.3 where L is a Lewis base containing nitrogen or oxygen electron donors and selected from the group consisting of 5- and 6-membered heterocyclic amines, amine oxides, triorganophosphates, phosphine oxides and sulfoxides. L has the steric requirement such that its cross-sectional area perpendicular to an axis running through the L-Mo covalent bond is less than about 30(A).sup.2.
    Type: Grant
    Filed: November 10, 1980
    Date of Patent: October 19, 1982
    Assignee: Exxon Research and Engineering Co.
    Inventors: Jack W. Johnson, Allan J. Jacobson
  • Patent number: 4354024
    Abstract: A new composition of matter comprising layered compounds of tungsten trioxide and heterocyclic nitrogen or oxygen Lewis bases which have a unique layered structure. The layered compounds have the formula LWO.sub.3 where L is a Lewis base selected from the group consisting of 5-membered heterocyclic amines, 6-membered heterocyclic amines, amine oxides, triorganophosphates, phosphine oxides and sulfoxides, the layered compounds being characterized in that L is covalently bound to a tungsten atom in the tungsten oxide layer.
    Type: Grant
    Filed: November 10, 1980
    Date of Patent: October 12, 1982
    Assignee: Exxon Research and Engineering Company
    Inventors: Jack W. Johnson, Allan J. Jacobson
  • Patent number: 4339448
    Abstract: New imidazole-copper complex compounds having a good fungicidal action, fungicides containing these compounds as active ingredients, processes for their manufacture, and their use for combating fungi.
    Type: Grant
    Filed: October 22, 1979
    Date of Patent: July 13, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Toni Dockner, Anton Frank, Ernst-Heinrich Pommer
  • Patent number: 4297342
    Abstract: Novel 3-pyridylmethyl N-(4-substituted-phenyl)thiocarbamates are disclosed. These compounds are useful as single-dose rodenticides, which have high bait acceptance.
    Type: Grant
    Filed: January 17, 1980
    Date of Patent: October 27, 1981
    Assignee: Rohm and Haas Company
    Inventors: Edward E. Kilbourn, Ernest D. Weiler, William D. Weir
  • Patent number: 4193979
    Abstract: Sodium 3-[[[2-(2-methyl-5-nitro-1H-imidazol-1-yl)ethyl]-amino]carbonyl]-2-pyridin ecarboxylic acid and related compounds which are labeled with radioactive technetium-99m are described as well as their preparations. These novel complexes are useful by reason of their utility as radiopharmaceutical imaging agents. Particularly, these complexes are useful as gallbladder and liver imaging agents.
    Type: Grant
    Filed: May 22, 1978
    Date of Patent: March 18, 1980
    Assignee: G. D. Searle & Co.
    Inventors: Patricia Frank, Stephen Kraychy, Ernest F. LeVon
  • Patent number: 4181517
    Abstract: 1,2,3-Thiadiazole-2-id-derivative of the formula ##STR1## in which R.sub.1 is hydrogen or alkyl which may be substituted in one or several places by oxygen or sulfur and wherein R.sub.1 has the meaning as given in the attached specification and wherein X is oxygen or sulfur and B is a univalent metal atom. The compounds have properties suited for controlling the natural growth and natural development of plants and in addition have a superior defoliating property.
    Type: Grant
    Filed: April 19, 1978
    Date of Patent: January 1, 1980
    Assignee: Schering Aktiengesellschaft
    Inventors: Hans-Rudolf Kruger, Reinhart Rusch, Friedrich Arndt
  • Patent number: 4172893
    Abstract: Complexes of 3-pyridylmethyl 4-substituted-phenylcarbamates with salts of an alkaline earth or transition metal are useful as rodenticides. The carbamates from which the complexes are prepared have the formula ##STR1## wherein X is a nitro, cyano, trifluoromethyl, alkylsulfinyl, alkylsulfonyl, or aminosulfonyl group.
    Type: Grant
    Filed: January 11, 1978
    Date of Patent: October 30, 1979
    Assignee: Rohm and Haas Company
    Inventor: Ernest D. Weiler
  • Patent number: 4156780
    Abstract: Novel 3-pyridylmethyl N-(4-substituted-phenyl)thiocarbamates are disclosed. These compounds are useful as single-dose rodenticides, which have high bait acceptance.
    Type: Grant
    Filed: June 30, 1975
    Date of Patent: May 29, 1979
    Assignee: Rohm and Haas Company
    Inventors: Edward E. Kilbourn, Ernest D. Weiler, William D. Weir
  • Patent number: 4130432
    Abstract: Compounds of the general formula I ##STR1## wherein M IS 4, 6 OR 8,N is 0 or 1,A is 0 or 1,B is 1, 2, 3, 4 or 5,Each ofR.sub.1, r.sub.2 and R.sub.3 independently represents an alkyl group, an alkyl group which is substituted or which contains --CO-- or --C(.dbd.O)--O-- in the chain, an alkenyl, cycloalkyl, alkylcycloalkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group,L represents NH.sub.3, pyridine, water, CO, NO or a halogen atom, andM if m is 4, represents Ni(O), Ni(I), Ni(II), Pd(II), Pt(II), Cu(I), Cu(II), Ag(I), Au(III), Zn(II),Cd(II), Hg(II), and if m is 6 represents Ti(III), V(II), V(III), Cr(I), Cr(II), Cr(III), Mn(I), Mn(II), Mn(III), Te(I), Re(I), Re(II), Re(III), Re(IV), Fe(II), Fe(III), Ru(II), Ru(III), Os(II), Co(I), Co(II), Co(III), Rh(III), Ir(III), Pt(IV), and if m is 8, represents Ti(III), Mo(IV), Mo(I), W(IV), W(V), Mn(IV) or (Re(V), as biocides.
    Type: Grant
    Filed: December 16, 1976
    Date of Patent: December 19, 1978
    Assignee: Ciba-Geigy Corporation
    Inventors: Hermann W. Wehner, Joachim Lorenz
  • Patent number: 4124533
    Abstract: Process for the homogeneous catalytic hydrogenation of .beta.-substituted-.alpha.-acylamido-acrylic acids which yields, after hydrogenation, an optically active mixture. The process comprises the hydrogenation of .beta.-substituted-.alpha.-acylamido-acrylic acids in the presence of an optically active coordinated metal complex hydrogenation catalyst, in which the metal is selected from the group consisting of rhodium, iridium, ruthenium, osmium, palladium and platinum.This process is a generalized process for any asymmetric hydrogenation of .beta.-substituted-.alpha.-acylamido-acrylic acids in which one .alpha.-amino acid enantiomorph is the desired end-product. It is especially useful for the preparation of .alpha.-amino acids found in nature which possess optical activity and which have a hydrogen attached to the asymmetric center.This invention also relates to new optically active coordinated metal complex hydrogenation catalysts.
    Type: Grant
    Filed: March 17, 1975
    Date of Patent: November 7, 1978
    Assignee: Monsanto Company
    Inventors: William S. Knowles, Milton J. Sabacky