Boron Containing Patents (Class 546/13)
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Patent number: 7087755Abstract: A class of 2,4-; 2,3,4-; 2,4,6-; 2,3,4,5,6-substituted pyridines is provided which include novel compounds. The substitutions are achieved according to methods disclosed herein in which a metallated pyridine is reacted with an electrophile. Suitable electrophiles include CO2, SO2, dialkylcarbonates, ureas, formamides, amides, carboxylic acid esters, mono- and dihaloalkyls, halogens such as chlorine, fluorine, bromine, and iodine, metallic salts, sulfones, sulfonyls, aldehydes, ketones, anhydrides, nitrites, and electrophilic boron compounds including, but not limited to, boron trialkoxides and boron trihalides.Type: GrantFiled: November 10, 2005Date of Patent: August 8, 2006Assignee: Frontier Scientific, Inc.Inventors: Dustin R. Cefalo, Jason I. Henderson, Homayoun H. Mokri
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Patent number: 7071175Abstract: The present invention relates to compounds of Formula I, and pharmaceutically acceptable salts or solvates thereof, or solvates of such salts, which compounds inhibit carboxypeptidase U and thus can be used in the prevention and treatment of diseases associated with carboxypeptidase U. In further aspects, the invention relates to compounds of the invention for use in therapy; to processes for preparation of such new compounds: to pharmaceutical compositions containing at least one compound of the invention, or a pharmaceutically acceptable salt or solvate thereof, as active ingredient; and to the use of the active compounds in the manufacture of medicaments for the medical use indicated above.Type: GrantFiled: May 3, 2000Date of Patent: July 4, 2006Assignee: Astrazeneca ABInventors: Marcel Linschoten, Magnus Polla
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Patent number: 7053079Abstract: A dihydroxy(3-pyridyl)borane compound of the formula (1): wherein R1 represents a hydrogen atom, halogen atom or alkoxycarbonylamino group; R2 represents a hydrogen atom, halogen atom, alkyl group or fluoroalkyl group; with the proviso that the case wherein both R1 and R2 are hydrogen atoms is excepted.Type: GrantFiled: November 27, 2002Date of Patent: May 30, 2006Assignee: KOEI Chemical Company, LimitedInventors: Mayumi Nishida, Tsuyoshi Tagata, Masaki Shimada
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Patent number: 6964966Abstract: This invention relates to new generation triple-targeting, chiral, broad-spectrum antimicrobial 7-substituted piperidino-quinolone carboxylic acid derivatives, to their optical isomers, diastereomers or enantiomers, as well as pharmaceutically acceptable salts, hydrates, prodrugs, polymorphs and pseudopolymorphs thereof, to their preparation, to their compositions and to their use.Type: GrantFiled: April 23, 2002Date of Patent: November 15, 2005Assignee: Wockhardt LimitedInventors: Noel John De Souza, Mahesh Vithalbhai Patel, Prasad Keshav Deshpande, Shiv Kumar Agarwal, Shrikant V. Gupte, Dilip J. Upadhyay, Satish B. Bhawsar, Rupinder K. Beri, Kandepu Sreenivas, Sheela Chandrasekharan Nair, Milind Chintaman Shukla, Yati Chugh, Nitin Shetty, Ravindra D. Yeole, M. Madhav Reddy
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Patent number: 6939985Abstract: The invention provides a process for covalently coupling organic compounds which comprises reacting an aromatic ring compound having a halogen or halogen-like substituent at a coupling position with a diboron derivative in the presence of a Group VIII metal catalyst and a suitable base. The invention also provides useful arylboron intermediates.Type: GrantFiled: March 5, 2003Date of Patent: September 6, 2005Assignee: Commonwealth Scientific and Industrial Research OrganisationInventors: Sebastian Mario Marcuccio, Mary Rodopoulos, Helmut Weigold
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Patent number: 6916925Abstract: Dye labeled imidazonaphthyridine, imidazopyridine and imidazoquinoline compounds having immune response modulating activity are disclosed. The compounds arc useful, inter alia, for determining the binding and/or receptor sites of the molecules.Type: GrantFiled: July 22, 2003Date of Patent: July 12, 2005Assignee: 3M Innovative Properties Co.Inventors: Michael J. Rice, Mark A. Tomai, Ai-Ping Wei
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Patent number: 6911551Abstract: The present invention relates to substituted boron or aluminum spiro compounds and their use in the electronic industry. The compounds of the invention are used as electron transport material, hole blocking material and/or as host material in organic electroluminescence and/or phosphorescence devices, as electron transport material in photocopiers, as electron acceptor or electron transport material in solar cells, as charge transport material in organic ICs (circuits) and in organic solid-state lasers or organic photodetectors.Type: GrantFiled: December 20, 2001Date of Patent: June 28, 2005Assignee: Covion Organic Semiconductors GmbHInventors: Philipp Stössel, Hubert Spreitzer, Heinrich Becker, Jacqueline Drott
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Patent number: 6903214Abstract: Disclosed is a process of forming a bis(azinyl)amine-BF2 complex, where a boron atom is complexed by two ring nitrogens of a deprotonated bis(azinyl)amine compound, comprising the step of reacting BF3 with a protonated bis(azinyl)amine in the presence of a polar aprotic organic solvent that is not reactive with the BF3 under reaction conditions. Such process provides good yields, even when a bulky group is present on the bis(azinyl)amine compound.Type: GrantFiled: December 11, 2003Date of Patent: June 7, 2005Assignee: Eastman Kodak CompanyInventor: Zbyslaw R. Owczarczyk
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Publication number: 20040254076Abstract: A dihydroxy(3-pyridyl)borane compound of the formula (1): 1Type: ApplicationFiled: April 27, 2004Publication date: December 16, 2004Inventors: Mayumi Nishida, Tsuyoshi Tagata, Masaki Shimada
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Publication number: 20040249157Abstract: A new ligands that include a benzene ring in the backbone can be combined with a metal or metal precursor compound or formed into a metal-ligand complex catalyze a number of different chemical transformations, including olefin polymerization reactions. The ligands, complexes formed with the ligands and compositions including the ligands are useful catalysts, depending on the reaction.Type: ApplicationFiled: June 29, 2004Publication date: December 9, 2004Applicant: Symyx Technologies, Inc.Inventors: Anil Guram, Cheryl Lund, Howard W. Turner, Tetsuo Uno
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Patent number: 6825211Abstract: The present invention provides bicyclic metabotropic glutamate receptor ligands, as well as compositions comprising such ligands, and methods for their use.Type: GrantFiled: August 20, 2003Date of Patent: November 30, 2004Assignee: Georgetown UniversityInventors: Alan P. Kozikowski, Darryl Hugh Steensma, Werner Tueckmantel, Gian Luca Araldi
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Publication number: 20040235681Abstract: Disclosed are borate and boronate compounds of the formulae 1Type: ApplicationFiled: May 18, 2004Publication date: November 25, 2004Inventors: Jeffrey A. Levine, Si Wu
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Publication number: 20040147453Abstract: Salts of a pharmaceutically acceptable divalent metal and an organoboronic acid drug. Examples of such metals are calcium, magnesium and zinc. The organoboronic acid drug may be a boropeptide protease inhibitor. The salts may be formulated in oral dosage form.Type: ApplicationFiled: September 9, 2003Publication date: July 29, 2004Applicant: Trigen LimitedInventors: John Joseph Deadman, David Jonathan Madge, Mark Dolman, Sanjay Kumar Kakkar, Anthony James Kennedy, Sophie Marie Combe-Marzelle, Suresh Babubhai Chahwala, Oliver Vimpany Arnold Boucher
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Patent number: 6766183Abstract: Fluorescent biosensor molecules, fluorescent biosensors and systems, as well as methods of making and using these biosensor molecules and systems are described. Embodiments of these biosensor molecules exhibit fluorescence emission at wavelengths greater than about 650 nm. Typical biosensor molecules include a fluorophore that includes an iminium ion, a linker moiety that includes a group that is an anilinic type of relationship to the fluorophore and a boronate substrate recognition/binding moiety, which binds glucose. The fluorescence molecules modulated by the presence or absence of polyhydroxylated analytes such as glucose. This property of these molecules of the invention, as well as their ability to emit fluorescent light at greater than about 650 nm, renders these biosensor molecules particularly well-suited for detecting and measuring in-vivo glucose concentrations.Type: GrantFiled: December 28, 2001Date of Patent: July 20, 2004Assignees: Medtronic MiniMed, Inc., The Regents of the University of CaliforniaInventors: Joseph C. Walsh, Aaron M. Heiss, Glenn Noronha, David J. Vachon, Stephen M. Lane, Joe H. Satcher, Jr., Thomas A. Peyser, William Peter Van Antwerp, John Joseph Mastrototaro
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Publication number: 20040116701Abstract: The present invention relates to halo sulfonyl aryl boronates of the general formula (I): 1Type: ApplicationFiled: October 30, 2003Publication date: June 17, 2004Inventors: Per Vedso, Preben Houlberg Olesen, Thomas Hoeg-Jensen
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Publication number: 20040116700Abstract: The invention relates to chromophores exhibiting semiconductive properties, the production and use thereof as luminophores in organic light-emitting diodes (OLEDs) and organic solar cells. The invention more specifically relates to highly condensed boron complex compounds wherein the boron atoms have improved processability, solubility and the fluorescence quantum efficiency is increased by building up by spirocentres.Type: ApplicationFiled: February 2, 2004Publication date: June 17, 2004Inventors: Horst Hartmann, Andreas Kanitz, Wolfgang Rogler, Kay Steffen
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Patent number: 6747150Abstract: Disclosed herein is a method for reducing the rate of degradation of proteins in an animal comprising contacting cells of the animal with certain boronic ester and acid compounds. Also disclosed herein are novel boronic ester and acid compounds, their synthesis and uses.Type: GrantFiled: March 19, 2003Date of Patent: June 8, 2004Assignee: Millennium Pharmaceuticals, Inc.Inventors: Julian Adams, Yu-Ting Ma, Ross Stein, Matthew Baevsky, Louis Grenier, Louis Plamondon
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Publication number: 20040091785Abstract: The invention relates to a method of preparing lithium complex salts and their intermediaries and to the use of these in electrolytes.Type: ApplicationFiled: October 31, 2003Publication date: May 13, 2004Inventors: Andrei Leonov, Armin de Meijere, Michael Schmidt
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Publication number: 20040087842Abstract: The spectroscopic and photophysical properties of fluorescent probes comprising donor-acceptor derivatives comprising the boric acid group or a derivative of boric acid, B(OH)3 (or borate ion, BO(OH)2−1), arsenious acid, H3 AsO3 (or arsenite ion, H2AsO3−1), telluric acid, H6TeO6 (or tellurate ion, H5 TeO6−1) or germanic acid, Ge(OH)6 (or germanate ion, GeO(OH)3−1) are described. Method of using said probes are also provided.Type: ApplicationFiled: May 30, 2003Publication date: May 6, 2004Inventors: Joseph R. Lakowicz, Nicolas Dicesare
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Patent number: 6727361Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.Type: GrantFiled: November 6, 2001Date of Patent: April 27, 2004Assignee: Symyx Technologies, Inc.Inventors: Anne M. LaPointe, Eric D. Carlson, Thomas Crevier
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Publication number: 20040077599Abstract: The present invention relates to therapeutically active novel spiro[2,4]heptane amino carboxy compounds and derivatives thereof. Also provided is a method of preparing compounds of Formula (I), and pharmaceutical compositions comprising the compounds. The novel compounds act as modulators of metabotropic glutamate receptors and, as such, are useful in treating diseases of the central nervous system related to the metabotropic glutamate receptor system.Type: ApplicationFiled: November 13, 2003Publication date: April 22, 2004Inventor: Kenneth Curry
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Publication number: 20040038940Abstract: The invention relates to processes for preparing a compound of the formula (V) 1Type: ApplicationFiled: June 3, 2003Publication date: February 26, 2004Applicant: Pfizer Inc.Inventors: Stephane Caron, Jolanta Nowakowski
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Publication number: 20040030137Abstract: The invention relates to heterocyclic substituted amide derivatives that display selective binding to dopamine D3 receptors. In another aspect, the invention relates to a method for treating central nervous system disorders associated with the dopamine D3 receptor activity in a patient in need of such treatment comprising administering to the subject a therapeutically effective amount of said compounds for alleviation of such disorder. The central nervous system disorders that may be treated with these compounds include Psychotic Disorders, Substance Dependence, Substance Abuse, Dyskinetic Disorders (e.g. Parkinson's Disease, Parkinsonism, Neuroleptic-Induced Tardive Dyskinesia, Gilles de la Tourette Syndrome and Huntington's Disease), Dementia, Anxiety Disorders, Sleep Disorders, Circadian Rhythm Disorders and Mood Disorders.Type: ApplicationFiled: February 19, 2002Publication date: February 12, 2004Inventors: James A. Hendrix, Joseph T. Strupczewski, Kenneth J. Bordeau, Matthias Urmann, Gregory Shutske, Horst Hemmerle, John G. Jurcak, Harpal Gill, Franz J. Weiberth, Thaddeus R. Nieduzak, Sharon Anne Jackson, Xu-Yang Zhao, Paul Justin Mueller
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Patent number: 6689494Abstract: Organic light emitting device (OLED) assemblies having light emitting layers made from boron atom rigidized monomethine cyanines are disclosed. OLED assemblies are constructed by conventional vapor deposition technique as well as by solution spin coating method. The OLED assemblies disclosed are expected to emit blue light and have improved color saturation because of smaller spectral width of the light emissive materials used.Type: GrantFiled: September 11, 2002Date of Patent: February 10, 2004Inventor: Bhalchandra M. Karandikar
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Patent number: 6680401Abstract: The invention relates to processes for the synthesis of aryl or alkene borates which comprises reacting: (i) an olefinic compound having a halogen or halogen-like substituent in a vinylic substitution position, or (ii) an aromatic ring having a halogen or halogen-like substituent in a ring substitution position, with a disubstituted monohydroborane in the presence of a Group 8-11 metal catalyst. The invention also relates to the use of these borates in coupling reactions. The invention further relates to certain disubstituted monohydroboranes and aryl or alkene borates.Type: GrantFiled: August 13, 2001Date of Patent: January 20, 2004Assignee: Commonwealth Scientific and Industrial Research OrganisationInventors: Sebastian Mario Marcuccio, Mary Rodopoulos, Helmut Weigold
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Publication number: 20040007693Abstract: The present invention relates to novel ionic liquids comprising a phosphate or borate anion. The ionic liquids may be made via metathesis or via a reaction between boric or phosphoric acid with metal hydroxide and an alcohol.Type: ApplicationFiled: July 3, 2002Publication date: January 15, 2004Inventor: Roger Moulton
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Publication number: 20040006235Abstract: In a process for the preparation of ring compounds via a combinatorial synthesis, the reaction procedure is based on a Suzuki coupling, subsequent halo-demetallation and finally a further Suzuki coupling. The Suzuki couplings are each carried out with a boronic acid or a boronic acid ester. The reaction procedure uses provides novel ring compounds and uses novel synthesis units used for this purpose. The novel ring compounds are suitable for use as constituents in liquid-crystalline mixtures.Type: ApplicationFiled: March 17, 2003Publication date: January 8, 2004Applicant: Merck Patent GmbHInventors: Detlef Pauluth, Peer Kirsch, Peter Baeuerle, Oliver Deeg
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Patent number: 6673625Abstract: The present invention provides formulae for fluorescent compounds that have a number of properties which make them uniquely suited for use in sensors of analytes such as saccharides. The advantageous fluorescent properties include favorable excitation wavelengths, emission wavelengths, fluorescence lifetimes, and photostability. Additional advantageous properties include enhanced aqueous solubility, as well as temperature and pH sensitivity. The compound comprises an aryl or a substituted phenyl botonic acid that acts as a substrate recognition component, a fluorescence switch component, and a fluorophore. Fluorescent compounds are described that are excited at wavelengths greater than 400 nm and emit at wavelengths greater than 450 nm, which is advantageous for optical transmission through skin. The fluorophore is typically selected from transition metal-ligand complexes and thiazine, oxazine, oxazone, or oxazine-one as well as anthracene compounds.Type: GrantFiled: March 30, 2001Date of Patent: January 6, 2004Assignees: The Regents of the University of California, MiniMed Inc.Inventors: Joe H. Satcher, Jr., Stephen M. Lane, Christopher B. Darrow, Douglas R. Cary, Joe Anh Tran
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Patent number: 6673928Abstract: Compounds represented by formula (IV): are provided, as well as methods for synthesizing the compounds, wherein variable R21 to R28 are as defined herein.Type: GrantFiled: July 23, 2002Date of Patent: January 6, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Toshiki Taguchi
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Publication number: 20030220500Abstract: Novel polydioxaborines are prepared by polymerizing novel monomers that contain a dioxaborine group. Polydioxaborines are readily soluble, excellent film formers, and have semiconducting properties useful in various applications.Type: ApplicationFiled: September 3, 2002Publication date: November 27, 2003Inventors: J. Kevin Cammack, Seth R. Marder, Bernard Kippelen
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Publication number: 20030216603Abstract: To provide a practical method of manufacturing fluorine compounds in a small number of steps that can carry out fluorination reaction of substrates using easily available fluorinating agents that can be inexpensively produced industrially, and recover precursors of the fluorinating agents generated accompanying the reaction quantitatively in an easy operation, and a method of recovery and regeneration of the precursors of the fluorinating agents.Type: ApplicationFiled: May 1, 2003Publication date: November 20, 2003Applicant: DAIKIN INDUSTRIES LTD.Inventors: Kenji Adachi, Ginjiro Tomizawa, Satoshi Oishi
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Patent number: 6630588Abstract: Dye labeled imidazonaphthyridine, imidazopyridine and imidazoquinoline compounds having immune response modulating activity are disclosed. The compounds are useful, inter alia, for determining the binding and/or receptor sites of the molecules.Type: GrantFiled: February 19, 2002Date of Patent: October 7, 2003Assignee: 3M Innovative Properties CompanyInventors: Michael J. Rice, Mark A. Tomai, Ai-Ping Wei
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Patent number: 6603004Abstract: The invention relates to a process for the preparation of organic boronic acid derivatives involving the reaction of an organic compound with diboronic acid in the presence of a Group 8-11 metal catalyst.Type: GrantFiled: March 25, 2002Date of Patent: August 5, 2003Assignee: Commonwealth Scientific and Industrial Research OrganisationInventors: Sebastian Mario Marcuccio, Mary Rodopoulos, Helmut Weigold
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Patent number: 6590100Abstract: The present invention provides a process for preparing a polyaromatic compound comprising at least one sequence of two aromatic rings. The process of the invention, which consists in reacting an aromatic compound bearing a leaving group and an arylboronic acid and/or its derivatives in the presence of a base and an effective amount of a nickel catalyst, is characterized in that the reaction is conducted in a reaction solvent which is water optionally in a mixture with an organic solvent and in the presence of an effective amount of a catalyst based on nickel with at least one water-soluble phosphine ligand.Type: GrantFiled: May 15, 2002Date of Patent: July 8, 2003Assignee: Rhodia ChimieInventors: Jean-Christophe Galland, Monique Savignac, Jean-Pierre Genet
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Patent number: 6570017Abstract: The present invention relates to method for the preparation of dialkylpyridylboranes by reacting a pyridine Grignard reagent with an alkoxydialkylborane or a trialkylborane. The reaction can be conducted at a temperature ranging from about 0° C. to about 40° C. The pyridine Grignard reagent is preferably prepared in situ by the reaction of a Grignard reagent (RMgX) and a halopyridine in a suitable solvent, such as tetrahydrofuran, followed by the addition of an alkoxydialkylborane or a trialkylborane to form a dialkylpyridylborane.Type: GrantFiled: August 23, 2002Date of Patent: May 27, 2003Assignee: Pfizer IncInventor: David Harold Brown Ripin
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Publication number: 20030089920Abstract: In accordance with the present invention, nanometer-scale reversible electronic switches are provided that can be assembled to make cross-bar circuits that provide memory, logic, and communications functions. The electronic switches, or crossed-wire devices, comprise a pair of crossed wires that form a junction where one wire crosses another at an angle other than zero degrees and at least one connector species connecting the pair of crossed wires in the junction. The junction has a functional dimension in nanometers, wherein at least one connector species and the pair of crossed wires forms an electrochemical cell.Type: ApplicationFiled: November 7, 2002Publication date: May 15, 2003Inventors: Alexandre M. Bratkovski, Pavel Kornilovich, R. Stanley Williams, Xiao-An Zhang
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Patent number: 6559310Abstract: The invention provides a process for covalently coupling organic compounds which comprises reacting an aromatic ring compound having a halogen or halogen-like substituent at a coupling position with a diboron derivative in the presence of a Group VIII metal catalyst and a suitable base. The invention also provides useful arylboron intermediates.Type: GrantFiled: May 21, 2002Date of Patent: May 6, 2003Assignee: Commonwealth Scientific and Industrial Research OrganisationInventors: Sebastian Mario Marcuccio, Mary Rodopoulos, Helmut Weigold
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Publication number: 20030083312Abstract: The present invention relates to method for the preparation of dialkylpyridylboranes by reacting a pyridine Grignard reagent with an alkoxydialkylborane or a trialkylborane. The reaction can be conducted at a temperature ranging from about 0° C. to about 40° C. The pyridine Grignard reagent is preferably prepared in situ by the reaction of a Grignard reagent (RMgX) and a halopyridine in a suitable solvent, such as tetrahydrofuran, followed by the addition of an alkoxydialkylborane or a trialkylborane to form a dialkylpyridylborane.Type: ApplicationFiled: August 23, 2002Publication date: May 1, 2003Applicant: Pfizer Inc.Inventor: David Harold Brown Ripin
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Patent number: 6548668Abstract: Disclosed herein is a method for reducing the rate of degradation of proteins in an animal comprising contacting cells of the animal with certain boronic ester and acid compounds. Also disclosed herein are novel boronic ester and acid compounds, their synthesis and uses.Type: GrantFiled: March 18, 2002Date of Patent: April 15, 2003Assignee: Millennium Pharmaceuticals, Inc.Inventors: Julian Adams, Yu-Ting Ma, Ross Stein, Matthew Baevsky, Louis Grenier, Louis Plamondon
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Publication number: 20030069426Abstract: A salt-like chemical compound of the formula (I),Type: ApplicationFiled: September 13, 2002Publication date: April 10, 2003Inventors: Jorg Schottek, Gerhard Erker, Gerald Kehr
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Publication number: 20030055286Abstract: 1 This invention relates to novel compounds of Formula (I) to (VII), and compositions thereof, useful in the treatment of disease states mediated by the chemokine, Interleukin-8 (IL-8).Type: ApplicationFiled: September 5, 2002Publication date: March 20, 2003Inventors: Katherine Louisa Widdowson, Qi Jin
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Publication number: 20030050476Abstract: Compounds represented by formula ( TV): 1Type: ApplicationFiled: July 23, 2002Publication date: March 13, 2003Inventor: Toshiki Taguchi
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Patent number: 6500569Abstract: Heterocyclic organoaluminum and organoboron coordination complexes that are photoluminescent and electroluminescent, emitting intense blue light. Methods of synthesizing such compounds, methods of producing photoluminescence and electroluminescence, methods of applying the compounds in thin films, and uses of the compounds of the invention in luminescent probes, electroluminescent displays and the like.Type: GrantFiled: October 18, 2001Date of Patent: December 31, 2002Assignee: Queen's University at KingstonInventors: Suning Wang, Wang Liu, Abdi Hassan
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Publication number: 20020193672Abstract: Fluorescent biosensor molecules, fluorescent biosensors and systems, as well as methods of making and using these biosensor molecules and systems are described. Embodiments of these biosensor molecules exhibit fluorescence emission at wavelengths greater than about 650 nm. Typical biosensor molecules include a fluorophore that includes an iminium ion, a linker moiety that includes a group that is an anilinic type of relationship to the fluorophore and a boronate substrate recognition/binding moiety, which binds glucose. The fluorescence molecules modulated by the presence or absence of polyhydroxylated analytes such as glucose. This property of these molecules of the invention, as well as their ability to emit fluorescent light at greater than about 650 nm, renders these biosensor molecules particularly well-suited for detecting and measuring in-vivo glucose concentrations.Type: ApplicationFiled: December 28, 2001Publication date: December 19, 2002Inventors: Joseph C. Walsh, Aaron M. Heiss, Glenn Noronha, David J. Vachon, Stephen M. Lane, Joe H. Satcher, Thomas A. Peyser, William Peter Van Antwerp, John Joseph Mastrototaro
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Patent number: 6489081Abstract: Compounds of formula I wherein R1, R2, and R3 independently of one another are hydrogen; C1-C20alkyl which is unsubstituted or substituted by OH, C1-C4alkoxy, C1-C4alkylthio, phenylthio, F, Cl, Br, I, CN, (C1-8alkyl)O—(CO)—, (C1-C4alkyl)—(CO)O— or/and di(C1-C4alkyl)amino; or R1, R2, and R3 independently of one another are C3-C6alkenyl; phenyl which is unsubstituted or substituted by OH, C1-C4alkoxy, C1-C4alkylthio, phenylthio, F, Cl, Br, I, CN, (C1-C8alkyl)O(CO)—, (C1-C4alkyl)—(CO)O— or/— and di(C1-C4alkyl)amino; or R1 and R2 together are C2-C9alkylene, o-xylylene, 2-butenylene, C3-C9oxaalkylene or C3-C9azaalkylene; R4, R5, R6, and R7 independently of one another are sec-C3-C20alkyl, tert-C4-C20alkyl or phenyl wherein these radicals are unsubstituted or substituted by OH, C1-C4alkoxy, C1-C4alkylthio, phenylthio, F, Cl, Br, I, CN, (C1-C8alkyl)O(CO)—, (C1-C4alkyl)—(CO)O— or/and di(C1-C4alkyl)amino; or R4 and R5, and/or R6 and R7Type: GrantFiled: November 30, 2000Date of Patent: December 3, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Akira Matsumoto, Yoshihiko Ito
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Publication number: 20020177711Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.Type: ApplicationFiled: November 6, 2001Publication date: November 28, 2002Applicant: Symyx TechnologiesInventors: Anne M. LaPointe, Eric D. Carlson, Thomas Crevier
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Publication number: 20020165200Abstract: The present invention provides bicyclic metabotropic glutamate receptor ligands, as well as compositions comprising such ligands, and and methods for their use.Type: ApplicationFiled: March 6, 2002Publication date: November 7, 2002Inventors: Alan P. Kozikowski, Darryl Hugh Steensma, Werner Tueckmantel, Gian Luca Araldi
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Publication number: 20020161230Abstract: A process for preparing boronic acids of the formula (I) and borinic acids of the formula (II), 1Type: ApplicationFiled: February 28, 2002Publication date: October 31, 2002Applicant: Clariant GmbHInventors: Andreas Meudt, Michael Erbes, Klaus Forstinger
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Publication number: 20020156279Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.Type: ApplicationFiled: November 6, 2001Publication date: October 24, 2002Inventors: Thomas R. Boussie, Gary M. Diamond, Christopher Goh, Keith A. Hall, Anne M. LaPointe, Margarete K. Leclerc, Cheryl Lund, Vince Murphy
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Patent number: 6461749Abstract: An organic boron compound effective for constituting a functional layer in an organic luminescence device is represented by formula (1) below: wherein Ar1 denotes an optionally substituted aryl group or heterocyclic group; R1-R11 independently denote hydrogen, halogen, alkyl, alkenyl, amino, alkoxy, formyl, nitrile, aroyl, alkyloyl, aryl, aralkyl or heterocyclic group, each optionally substituted with the proviso that an adjacent one or more pairs of R1-R11 can form a condensed ring. The organic boron compound can be produced through a process including (A) a step of reacting an aromatic ketone compound X with an aromatic ketone compound or an aromatic aldehyde compound in the presence of ammonium chloride, and (B) a step of reacting a product of the step (A) with an aromatic boric acid compound.Type: GrantFiled: March 28, 2001Date of Patent: October 8, 2002Assignee: Canon Kabushiki KaishaInventors: Kazunori Ueno, Koichi Suzuki, Akihiro Senoo, Hiroshi Tanabe, Seiichi Yogi