Plural Piperidine Rings Patents (Class 546/186)
  • Patent number: 4691015
    Abstract: Hydroxylamines derived from hindered amines are effective in stabilizing polyolefin compositions containing a stabilizer or mixture of stabilizers selected from the group consisting of the phenolic antioxidants, the hindered amine light stabilizers, the alkylated hydroxybenzoate light stabilizers, the ultraviolet light absorbers, the organic phosphorus compounds, the alkaline metal salts of fatty acids and the thiosynergists, against degradation upon high temperature extrusion, exposure to the combustion products of natural gas, gamma irradiation or upon storage for extended periods.
    Type: Grant
    Filed: March 21, 1985
    Date of Patent: September 1, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf A. Behrens, Raymond Seltzer
  • Patent number: 4670592
    Abstract: A bisbiguanide compound of the formula:R.sup.1 R.sup.2 N.C(:NR.sup.6)NH.C(:NH)NH.CH.sub.2 X-- --(CH.sub.2).sub.3 NH.C(:NH)NH.C(:NR.sup.7)NR.sup.3 R.sup.4 Vor a tautomer thereof, wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 which may be the same or different, are each hydrogen, a 1-16C alkyl radical, a 2-16C alkoxyalkyl radical, a 3-12C cycloalkyl radical, a (3-12C cycloalkyl)-(1-4C alkyl) radical, or an optionally substituted phenyl or phenyl(1-4C alkyl) radical, or R.sup.1 and R.sup.2 and the nitrogen atom to which they are attached, or R.sup.3 and R.sup.4 and the nitrogen atom to which they are attached, which may be the same or different, are each a 1-azetidinyl, 1-pyrrolidinyl, piperidino, hexamethyleneimino, heptamethyleneimino, morpholino or 4-(1-8C alkanoyl)-1-piperazinyl radical each of which may bear 1-3C alkyl substituents; each of R.sup.6 and R.sup.7, which may be the same or different, is hydrogen or a 1-8C alkyl radical; and X is a substituted ethylene or ethylidene radical of the formula:--CH.
    Type: Grant
    Filed: May 7, 1984
    Date of Patent: June 2, 1987
    Assignee: Imperial Chemical Industries PLC
    Inventors: Murdoch A. Eakin, Philip N. Edwards, Michael S. Large
  • Patent number: 4661288
    Abstract: Water-soluble zwitterionic compounds having clay soil removal/anti-redeposition properties. The zwitterionic compounds are selected from monozwitterionic compounds, dizwitterionic compounds, polyzwitterionic compounds, and zwitterionic polymers. These zwitterionic compounds are useful in detergent compositions at from about 0.05 to about 95% by weight. In addition to the zwitterionic compounds, the detergent compositions further comprise from about 1 to about 75% by weight of a nonionic, anionic, ampholytic, zwitterionic, or cationic detergent surfactant or mixture thereof.
    Type: Grant
    Filed: March 8, 1985
    Date of Patent: April 28, 1987
    Assignee: The Procter & Gamble Company
    Inventors: Donn N. Rubingh, Eugene P. Gosselink
  • Patent number: 4652297
    Abstract: This invention relates to a new class of organic chemical compounds. More particularly, this invention is concerned with amido and hydrazido derivatives of N-phosphinothioylmethylglycine esters. This class of compounds has been found to be useful as herbicides.
    Type: Grant
    Filed: February 25, 1982
    Date of Patent: March 24, 1987
    Assignee: Monsanto Company
    Inventors: John E. Franz, Robert J. Kaufman
  • Patent number: 4632988
    Abstract: This invention relates to a new process for the preparation of N-polythiodimorpholines wherein morpholine and elemental sulfur in an alcohol mixture are oxidized with an alkali metal hypohalite or an alkaline earth metal hypohalite or N-chloromorpholine to yield N-polythiodimorpholines. The process produces N-polythiodimorpholines without the use of corrosive or toxic chemicals and the product is an economical substitute for conventional rubber curatives.
    Type: Grant
    Filed: April 30, 1985
    Date of Patent: December 30, 1986
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Angelo Bergomi, James J. Tazuma
  • Patent number: 4628094
    Abstract: Tris(disubstituted amino)sulfonium perfluoroalkoxides and tris(disubstituted amino)sulfonium perfluoroalkylmercaptides and process for their preparation.
    Type: Grant
    Filed: June 8, 1984
    Date of Patent: December 9, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: William B. Farnham, William J. Middleton
  • Patent number: 4621110
    Abstract: Alkyl-substituted 4-methyl-piperidine derivatives having formula: ##STR1## wherein X is selected from the radicals: --N R.sub.12 R.sub.13 ; ##STR2## and --O--R.sub.17 Use of the alkyl-substituted 4-methyl-piperidine derivatives of general formula (I) as stabilizers of polymeric substances and polymeric compositions stabilized with said piperidine derivatives.
    Type: Grant
    Filed: January 17, 1984
    Date of Patent: November 4, 1986
    Assignee: Montedison S.p.A.
    Inventor: Piero Di Battista
  • Patent number: 4607104
    Abstract: 2,2,6,6-tetraalkyl-4-piperidylamines are produced by reacting an amine with a 2,2,6,6-tetraalkyl-4-piperidone in the presence of a catalyst selected from the group consisting of platinum, nickel and cobalt, employing a reaction medium comprising (a) between about 10 and 100 weight percent water and (b) between 0 and about 90 weight percent of a polar organic compound selected from the group consisting of C.sub.1 -C.sub.10 aliphatic alcohols and C.sub.2 -C.sub.6 aliphatic glycols.
    Type: Grant
    Filed: July 11, 1985
    Date of Patent: August 19, 1986
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Russell E. Malz, Jr., Harold Greenfield
  • Patent number: 4605743
    Abstract: 2,2,6,6-tetraalkyl-4-piperidylamines are produced by reacting an amine with a 2,2,6,6-tetraalkyl-4-piperidone in the presence of a palladium catalyst.
    Type: Grant
    Filed: April 16, 1985
    Date of Patent: August 12, 1986
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Russell E. Malz, Jr., Harold Greenfield
  • Patent number: 4598161
    Abstract: Tris(dialkylamino)sulfonium bifluoride salts are obtained by hydrolysis, methanolysis, or pyrolysis of corresponding tris(dialkylamino)sulfonium difluorotrimethylsilicates, reaction of dialkylaminotrialkylsilanes with sulfur tetrafluoride, or reaction of bis(dialkylamino)sulfur difluorides with dialkylamines. These bifluoride salts, which have the general formula (R.sup.1 R.sup.2 N)(R.sup.3 R.sup.4 N)(R.sup.5 R.sup.6 N)S.sup..sym. HF.sub.2.sup..crclbar., are useful polymerization catalysts.
    Type: Grant
    Filed: April 4, 1983
    Date of Patent: July 1, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: William B. Farnham, William J. Middleton, Dotsevi Y. Sogah
  • Patent number: 4593102
    Abstract: Novel pyrrolidine, piperidine and homopiperidinecarboxamide and thiocarboxamide compounds having the formula: ##STR1## wherein X is --S--, --S(O)-- or --S(O).sub.2 --; A is a loweralkalene chain and A.sup.1 and A.sup.2 are alkalene chains when p and d are one; R, R.sup.1 and R.sup.2 are hydrogen, loweralkyl, phenyl cycloalkyl or phenylalkyl and R.sup.1 and R.sup.2 may form a heterocyclic residue with the adjacent nitrogen atom; Q is a selected aromatic radical, and the pharmaceutically acceptable acid addition salts useful as cardiac antiarrhythmia agents are disclosed.Novel chemical intermediates, unsubstituted on pyrrolidine, piperidine and homopiperidine nitrogen but with --(A.sup.2).sub.p --X--(A.sup.2).sub.d --Q side chain are also disclosed.
    Type: Grant
    Filed: July 1, 1985
    Date of Patent: June 3, 1986
    Assignee: A. H. Robins Company, Inc.
    Inventor: James R. Shanklin, Jr.
  • Patent number: 4590268
    Abstract: Compounds containing a group of the formula I ##STR1## in which R is H or C.sub.1 -C.sub.4 -alkyl, R.sup.1 is H, CN, an acyloxy group or a free valency and R.sup.2 and R.sup.3 are organic radicals can be prepared in a simple manner from the corresponding compounds containing a group of the formula Ia ##STR2## by stepwise reaction with phosgene and a secondary amine R.sup.2 --NH--R.sup.3 in the presence of a molar amount of a base. The N-diorganocarbamoyl compounds containing the group I are outstanding light stabilizers, in particular for organic polymers. They can be converted by secondary reactions into other compounds which contain the group I and which are not accessible by direct phosgenation. Many of the products thus obtainable by phosgenation or conversion are novel compounds.
    Type: Grant
    Filed: May 2, 1983
    Date of Patent: May 20, 1986
    Assignee: Ciba-Geigy Corporation
    Inventor: Friedrich Karrer
  • Patent number: 4587296
    Abstract: Additives for rubber compositions, giving vulcanisates having improved retention of optimum physical properties, are compounds containing two or more groups of the formula --S--SO.sub.2 R linked by an organic bridging group, or polymers containing two or more groups of the formula --S--SO.sub.2 R attached to an organic polymer chain, where R represents (a) a radical OM where M is a monovalent metal, the equivalent of a multivalent metal, a monovalent in derived by the addition of a proton to a nitrogenous base, or the equivalent of a multivalent ion derived by the addition of two or more protons to a nitrogenous base, or (b) an organic radical selected from aliphatic, cycloaliphatic, aromatic and heterocyclic radicals, and radicals which are combinations of any two or more such radicals.
    Type: Grant
    Filed: April 11, 1985
    Date of Patent: May 6, 1986
    Assignee: Monsanto Europe, S.A.
    Inventor: Philippe G. Moniotte
  • Patent number: 4584301
    Abstract: Novel chemical compounds which are diphenylmethylene piperidine compounds are provided, as well as methods for their production, pharmaceutical compositions comprising the compounds, and methods of treatment using the compounds in dosage form. The compounds have pharmacological properties especially anticholinergic properties, and are useful as antiemetic, antihistamine, pulmonary, antiallergy, and antispasmodic agents.
    Type: Grant
    Filed: May 16, 1985
    Date of Patent: April 22, 1986
    Assignee: Warner-Lambert Company
    Inventors: David A. Downs, Haile Tecle
  • Patent number: 4574123
    Abstract: A 4,4'-alkylenebis[piperidine-1-(N-amidinoamidine)] derivative of the formula: ##STR1## or a tautomeric form thereof, wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4, which may be the same or different, is hydrogen or an alkyl, alkenyl or alkoxyalkyl radical of up to 20 carbon atoms; or R.sup.1, R.sup.2 and the nitrogen atom to which they are attached, or R.sup.3 and R.sup.4 and the nitrogen atom to which they are attached, which may be the same or different, are each a 1-azetidinyl, 1-pyrrolidinyl, piperidino, hexamethyleneimino, heptamethyleneimino, morpholino or 4-(1-8C alkanoyl)-1-piperazinyl radical each of which may bear 1-3C alkyl substituents; a 3-20C cycloalkyl radical; or an optionally substituted phenyl or phenylalkyl radical; provided that at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is other than hydrogen; X is a direct bond or a 1-6C straight- or branched-chain alkylene radical which is linked to the 3- or 4-positions of the piperidine rings; and R.sup.5 and R.sup.
    Type: Grant
    Filed: May 3, 1984
    Date of Patent: March 4, 1986
    Assignee: Imperial Chemical Industries PLC
    Inventors: Philip N. Edwards, Michael S. Large
  • Patent number: 4567174
    Abstract: A bis(1-substituted biguanide) derivative of the formula:R.sup.3 R.sup.4 N.C(:NR.sup.5)NH.C(NR.sup.9)NR.sup.1 --X--NR.sup.2.C(:NR.sup.9)NH.C(:NR.sup.6)--NR.sup.7 R.sup.8 Vor a tautomeric form thereof, wherein R.sup.1, R.sup.2 and R.sup.9, which may be the same or different, are each hydrogen, a 1-16C alkyl radical, a 3-16C cycloalkyl radical, a (3-12C cycloalkyl)-(1-4C alkyl) radical, an optionally substituted phenyl or naphthyl radical, an optionally substituted phenyl(1-4C)alkyl or naphthyl(1-4C)alkyl radical or an optionally substituted diphenylmethyl radical, provided that at least one of R.sup.1, R.sup.2 and R.sup.9 is other than hydrogen; R.sup.3, R.sup.4, R.sup.7 and R.sup.8, which may be the same or different are each hydrogen, or an alkyl, cycloalkyl, (cycloalkyl)alkyl, phenyl, naphthyl, phenylalkyl, naphthylalkyl, or diphenylmethyl radical as defined above, or a 2-16 alkoxyalkyl radical, or R.sup.3, R.sup.4 and the nitrogen atom to which they are attached, or R.sup.7 and R.sup.
    Type: Grant
    Filed: May 7, 1984
    Date of Patent: January 28, 1986
    Assignee: Imperial Chemical Industries PLC
    Inventors: Philip N. Edwards, Michael S. Large
  • Patent number: 4567257
    Abstract: Disclosed is a novel class of amidinium salts having the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 when taken individually are independently selected from lower-alkyl, aralkyl and cycloalkyl, and, when taken together with the respective nitrogen atoms to which they are attached, R.sub.1 together with R.sub.2, and R.sub.3 together with R.sub.4 independently represent heterocyclic groups having 5 to 7 ring atoms, R.sub.5, R.sub.6, R.sub.7, and R.sub.8 are independently selected from hydrogen, lower-alkyl, aryl, aralkyl, and cycloalkyl.The amidinium salts are very active catalysts for converting organic isocyanates to products containing isocyanurate and carbodiimide linkages.
    Type: Grant
    Filed: January 16, 1984
    Date of Patent: January 28, 1986
    Assignee: The Upjohn Company
    Inventor: Dale F. Regelman
  • Patent number: 4550107
    Abstract: Disclosed are novel condensed diazepinones of formula I ##STR1## wherein B is a fused ring selected from ##STR2## X is --CH-- or, when B is ortho-phenylene, X can also be nitrogen; A.sub.1 is C.sub.1 -C.sub.2 alkylene; A.sub.2 is C.sub.1 -C.sub.2 when it is in the 2-position relative to the saturated heterocyclic ring nitrogen or a single bond or methylene when it is in the 3- or 4-position; R.sub.1 is C.sub.1 -C.sub.3 alkyl; R.sub.2 is C.sub.1 -C.sub.7 alkyl, optionally hydroxy-substituted on at least one of its second to seventh carbon, or C.sub.3 -C.sub.7 cycloalkyl, optionally hydroxy substituted, or C.sub.3 -C.sub.7 cycloalkylmethyl; or R.sub.1 and R.sub.2 can, together with the nitrogen therebetween, be a 4- to 7-membered saturated monocyclic, heterocyclic ring which can optionally include an oxygen or N--CH.sub.3 ; R.sub.3 is hydrogen, chlorine, or methyl; R.sub.4 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.5 is hydrogen, chlorine or C.sub.1 -C.sub.
    Type: Grant
    Filed: March 14, 1985
    Date of Patent: October 29, 1985
    Assignee: Dr. Karl Thomae GmbH
    Inventors: Wolfhard Engel, Gunter Trummlitz, Wolfgang Eberlein, Gerhard Mihm, Gunther Schmidt, Rudolf Hammer, Antonio Giachetti
  • Patent number: 4546148
    Abstract: Novel polycondensed compounds containing piperidine groups of polycarbamate structure, of the general formula: ##STR1##
    Type: Grant
    Filed: July 19, 1984
    Date of Patent: October 8, 1985
    Assignee: Ciba-Geigy S.p.A.
    Inventor: Giuseppe Cantatore
  • Patent number: 4537924
    Abstract: Quadratic acid bisamides and salts thereof having the formula I are effective stabilizers of synthetic resins, especially for imparting resistance to deterioration resulting from exposure to light ##STR1## wherein R.sub.1 is H, C.sub.1-12 alkyl or OH-substituted C.sub.2-12 alkyl; R.sub.2 is --(CH.sub.2).sub.m --O--.sub.n, wherein m is an integer of 2-6; n is 0 or 1;R.sub.3 is H, CH.sub.3, CH.sub.2 --CH.sub.2 --OH, CH.sub.2 --COOH or CH.sub.2 --CH.sub.2 --COOH;HX is an acid equivalent of an unsubstituted or substituted monobasic, dibasic or polybasic organic acid of not more than 20 carbon atoms, or of sulfuric or phosphoric acid; and0.ltoreq.p.ltoreq.2.
    Type: Grant
    Filed: September 14, 1983
    Date of Patent: August 27, 1985
    Assignee: Chemische Werke Huels, AG
    Inventors: Konrad Rombusch, Gunther Maahs, Wolfgang Schafer
  • Patent number: 4535184
    Abstract: Tris(disubstituted amino)sulfonium perfluorocarbanion salts and process for their preparation.
    Type: Grant
    Filed: June 8, 1984
    Date of Patent: August 13, 1985
    Assignee: E. I. Du Pont De Nemours and Company
    Inventor: William J. Middleton
  • Patent number: 4528374
    Abstract: Novel oligomer or polymer polyamine-1,3,5-triazines containing at least one polyalkylpiperidine radical, for example that of the formula ##STR1## processes for their production, their use for stabilizing organic material, and the organic material protected therewith against oxidative and light-induced degradation.
    Type: Grant
    Filed: November 9, 1981
    Date of Patent: July 9, 1985
    Assignee: Ciba-Geigy Corporation
    Inventor: Erwin Nikles
  • Patent number: 4526971
    Abstract: A process for producing polyalkylpiperidylamines of the formula (I): ##STR1## wherein R.sub.1 is hydrogen or a C.sub.1 -C.sub.12 alkylradical; R.sub.2 and R.sub.3 are each C.sub.1 -C.sub.5 alkylradicals or R.sub.2 and R.sub.3, taken together, are --(CH)--.sub.a or --CH.sub.2 --NR.sub.1 --C(R.sub.5,R.sub.6)--CH.sub.2 --; R.sub.4 is a C.sub.2 -C.sub.18 alkylene radical, which is unsubstituted or substituted by C.sub.1 -C.sub.3 alkyl; a C.sub.5 -C.sub.12 cycloalkylene radical, which is unsubstituted or is methyl-substituted; a cycloalkylene radical of the formula ##STR2## where the cyclohexyl rings are unsubstituted or are methyl-substituted; or groups of the formula --(CH.sub.2).sub.k --X--[CH.sub.2).sub.m --X]--.sub.n (CH.sub.2).sub.p --, where X is --O--, --NH--, --NR.sub.5 and R.sub.5 and R.sub.6 are each a C.sub.1 -C.sub.
    Type: Grant
    Filed: March 30, 1984
    Date of Patent: July 2, 1985
    Assignee: Chemische Werke Huls Aktiengesellschaft
    Inventors: Josef Disteldorf, Manfred zur Hausen, Werner Hubel, Gunter Kriebel
  • Patent number: 4526972
    Abstract: This invention relates to ultraviolet light stabilizing hindered polyoxyalkylene polyamines. The products of the present invention can be utilized as ultraviolet light stabilizers for a wide variety of commercial products such as water base paints, oil base paints, polyethylenes, polypropylenes, polyurethanes, etc. The products have the formula: ##STR1## wherein: R represents an alkylene, alkyl, aralkyl, alkaryl or aryl group containing 1 to 24 carbon atoms,R' represents hydrogen, methyl or ethyl,n represents a number having an average value of 1 to 70, andx represents an integer having a value of 1 to 3.In a modified form of the invention, the products are useful also to inhibit oxidation of such products.
    Type: Grant
    Filed: June 27, 1984
    Date of Patent: July 2, 1985
    Assignee: Texaco Inc.
    Inventors: George P. Speranza, Robert A. Grigsby, Jr.
  • Patent number: 4509971
    Abstract: Novel substituted carboxylic acid amide compound of the formula ##STR1## wherein n is an integer from 1 to 4each R is independently selected from hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, amino, alkylamino, dialkylamino, nitro, cyano and alkoxycarbonyl; and two R radicals taken together can represent methylenedioxy, dichloromethylenedioxy or difluoromethylenedioxy,R.sup.1 is hydrogen or alkyl,R.sup.2 and R.sup.3 are individually selected from hydrogen or a radical selected from alkyl, alkenyl, alkynyl, aralkyl, cycloalkyl, aryl and nitrogen-containing heterocycles, each of which radicals may be substituted and each of which radicals may, together with the nitrogen atom to which they are attached, form an optionally substituted, optionally partially unsaturated and optionally benzofused monocyclic or bicyclic radical, which may contain one or more further hetero-atoms, and X is oxygen or sulfur.
    Type: Grant
    Filed: August 19, 1983
    Date of Patent: April 9, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Heinz Forster, Wolfgang Hofer, Volker Mues, Ludwig Eue, Robert R. Schmidt
  • Patent number: 4481148
    Abstract: Hydroxyl-containing liquid polymers having an aliphatic polymeric backbone and sulfide linkages near the terminal portions of the polymer molecule are prepared by polymerizing (1) at least one of selected vinylidene monomers having at least one terminal CH.sub.2 .dbd.C< group per monomer molecule, together with (2) at least one hydroxyl-containing disulfide in the presence of (3) ultraviolet radiation.
    Type: Grant
    Filed: March 16, 1981
    Date of Patent: November 6, 1984
    Assignee: The B. F. Goodrich Company
    Inventor: Changkiu K. Riew
  • Patent number: 4469829
    Abstract: Amino-group bearing, low molecular weight 1,3-butadiene polymers used as stabilizers for molded or unshaped plastics in amounts of 0.01 to 2.0 weight percent referred to the plastic, where the amino-group bearing component is derived from a substituted piperidine having the general formula: ##STR1## where R represents similar or different alkyl groups having 1 to 3 carbon atoms.
    Type: Grant
    Filed: August 18, 1983
    Date of Patent: September 4, 1984
    Assignee: Chemische Werke Huls AG
    Inventors: Alfred Konietzny, Hans-Dieter Zagefka, Konrad Rombusch, Hanns-Jorg Bax
  • Patent number: 4440949
    Abstract: A new class of chemical compounds and their process of preparation is described. These compounds have valuable properties as anti-secretory, anti-spasmodic, anti-ulcerogenic and anti-diarrheal agents.
    Type: Grant
    Filed: December 30, 1980
    Date of Patent: April 3, 1984
    Assignee: William H. Rorer, Inc.
    Inventors: George H. Douglas, William L. Studt, Stuart A. Dodson
  • Patent number: 4435334
    Abstract: Compounds which contain ammonium groups and sulphonic acid groups and which, in the betaine form, correspond to the formula ##STR1## wherein X denotes --CO-- or --SO.sub.2 --,R.sub.1 denotes hydrogen or alkyl,R.sub.2, R.sub.3 and R.sub.4, independently of one another denote alkyl, alkenyl or aralkyl, orR.sub.4 denotes ##STR2## Y denotes alkylene or xylylene, m denotes 1 or 2,n denotes 0 or 1, andR.sub.5 and R.sub.6, independently of one another, denote hydrogen, alkyl, alkoxy or halogen,and in addition, if n=1,R.sub.2 or R.sub.4 denotes amino, alkylamino, dialkylamino, aryl or cycloalkyl,R.sub.2 and R.sub.3, together with the nitrogen atom which is bonded to them, denote a 5-membered or 6-membered ring,R.sub.2, R.sub.3 and R.sub.4, together with the nitrogen atom which is bonded to them, denote a pyridinium ring, a group of the formula ##STR3## or hydrogen, Y denotes arylene, benzylene or a radical of the formula ##STR4## Z denotes a direct bond, --(CH.sub.2).sub.p --, --O--, --O--(CH.sub.2).sub.
    Type: Grant
    Filed: December 28, 1981
    Date of Patent: March 6, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Frank-Michael Stohr, Peter Wild, Horst Nickel
  • Patent number: 4417012
    Abstract: Additives for rubber compositions, giving vulcanisates having improved retention of optimum physical properties, are compounds containing two or more groups of the formula --S--SO.sub.2 R linked by an organic bridging group, or polymers containing two or more groups of the formula --S--SO.sub.2 R attached to an organic polymer chain, where R represents (a) a radical OM where M is a monovalent metal, the equivalent of a multivalent metal, a monovalent ion derived by the addition of a proton to a nitrogenous base, or the equivalent of a multivalent ion derived by the addition of two or more protons to a nitrogenous base, or (b) an organic radical selected from aliphatic, cycloaliphatic, aromatic and heterocyclic radicals, and radicals which are combinations of any two or more such radicals.
    Type: Grant
    Filed: June 30, 1982
    Date of Patent: November 22, 1983
    Assignee: Monsanto Europe S.A.
    Inventor: Philippe G. Moniotte
  • Patent number: 4415688
    Abstract: Poly(piperidylamine) alkanes represented by the Formula (I) or (II): ##STR1## R is selected from the group consisting of: --NH.sub.2 ; ##STR2## and synthetic resin compositions having improved resistance to deterioration by light containing such compounds.
    Type: Grant
    Filed: November 22, 1982
    Date of Patent: November 15, 1983
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Motonobu Minagawa, Yutaka Nakahara, Toshihiro Shibata, Ryozo Arata
  • Patent number: 4408043
    Abstract: Fluorinated compounds of the formula ##STR1## are disclosed. The cationic amine compounds are useful as surfactants.
    Type: Grant
    Filed: March 8, 1982
    Date of Patent: October 4, 1983
    Assignee: Nalco Chemical Company
    Inventors: Virgil L. Seale, James R. Stanford, James E. Briscoe, Glenn S. Penny
  • Patent number: 4405737
    Abstract: N-2-Hydroxypropyl piperidines are provided, as well as a process for preparing these compounds, having the formula: ##STR1## wherein X is selected from the group consisting of , ##STR2## wherein R.sub.1 is selected from the group consisting of hydrogen; alkyl; alkenyl; cycloalkyl; alkaryl; hydroxyalkyl; oxyalkyl; acyl and aroyl having from one to about eighteen carbon atoms;R.sub.2 and R.sub.3 are each selected from the group consisting of alkyl, alkenyl, cycloalkyl, alkaryl, hydroxyalkyl, oxyalkyl and haloalkyl having from one to about eighteen carbon atoms;R.sub.4, R.sub.5 and R.sub.6 each are selected from the group consisting of hydrogen, alkyl, alkenyl, cycloalkyl, alkaryl, hydroxyalkyl, oxyalkyl and haloalkyl having from one to about eighteen carbon atoms; and --CH.sub.2 --O--R.sub.1 ;n is 1 or 2; andY, when n is 1, is hydroxy or ##STR3## and when n is 2, is oxyoxygen.
    Type: Grant
    Filed: February 5, 1982
    Date of Patent: September 20, 1983
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Bunji Hirai, Naohiro Kubota, Kazuo Sugibuchi
  • Patent number: 4404377
    Abstract: Heterocyclic/aromatic fluorinated compounds of the formula ##STR1## are disclosed. The cationic compounds are useful as surfactants.
    Type: Grant
    Filed: March 8, 1982
    Date of Patent: September 13, 1983
    Assignee: Nalco Chemical Company
    Inventors: Virgil L. Seale, James R. Stanford, James E. Briscoe, Glenn S. Penny
  • Patent number: 4396765
    Abstract: 1-[(3- or 4-Benzoylphenyl)-lower-alkyl]-[(CH.sub.2).sub.n -N.dbd.B]-substituted-piperidines useful as anti-asthmatic, anti-allergic, anti-cholinergic, bronchodilator and anti-inflammatory agents, are prepared by alkylation of an appropriate substituted piperidine with a (3- or 4-benzoylphenyl)-lower-alkyl halide or tosylate; by reaction of a 1-[2-(3- or 4-lithiophenyl)-lower-alkyl]-[(CH.sub.2).sub.n -N.dbd.B]-substituted-piperidine with benzonitrile and hydrolysis of the resulting benzimidoyl compound; or by reduction of a 1-[.alpha.-(3- or 4-benzoylphenyl)-lower-alkanoyl]-[(CH.sub.2).sub.n -N.dbd.B]-substituted-piperidine. The analogous carbinols are prepared by reduction, with an alkali metal borohydride, of the ketone.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: August 2, 1983
    Assignee: Sterling Drug Inc.
    Inventor: Bernard L. Zenitz
  • Patent number: 4391812
    Abstract: Antimicrobial agents suitable for use in aqueous systems for their preservation against biodeterioration include substitutedpiperidinomethylpropenenitriles and propanenitriles. The unsaturated compounds are prepared by reaction of a suitable piperidine with cyano acetic acid and formaldehyde: the propane derivatives therefrom by nucleophilic addition.
    Type: Grant
    Filed: March 24, 1982
    Date of Patent: July 5, 1983
    Assignee: Merck & Co., Inc.
    Inventors: Richard A. Dybas, Nathaniel Grier, Bruce E. Witzel
  • Patent number: 4377692
    Abstract: Anomalous substituted-amine or quaternary ammonium salts of dibasic acids have two dibasic acid molecules per cation of three per two cations.
    Type: Grant
    Filed: July 24, 1981
    Date of Patent: March 22, 1983
    Assignee: Sprague Electric Company
    Inventors: John E. Barry, Manuel Finkelstein, Sidney D. Ross
  • Patent number: 4374244
    Abstract: Quaternary ammonium polymers having formula ##STR1## wherein R' and R" may be the same or different alkyl groups of from 1 to 18 carbon atoms, optionally substituted by from 1 to 2 hydroxyl groups or, when taken together, with N form a saturated or unsaturated ring of from 5 to 7 atoms, or when taken together with N and an oxygen atom form the N-morpholino group; wherein Z is --CH.sub.2 CH.dbd.CHCH.sub.2 -- when Z' is --CH.sub.2 CHOHCH.sub.2 -- or Z is --CH.sub.2 CHOHCH.sub.2 -- when Z' is --CH.sub.2 CH.dbd.CHCH.sub.2 --; wherein X is a halogen of atomic weight greater than 30; wherein Y and Y' may be either the same or different and may be either X or -NR'R"; and wherein n is an integer of from 2 to 20.
    Type: Grant
    Filed: November 17, 1980
    Date of Patent: February 15, 1983
    Assignee: Kewanee Industries, Inc.
    Inventors: Harold A. Green, John J. Merianos, Alfonso N. Petrocci
  • Patent number: 4370430
    Abstract: Oligomers of the formula ##STR1## which contain at least one piperidyl radical per repeating unit are useful as light stabilizers for polymers.
    Type: Grant
    Filed: August 31, 1981
    Date of Patent: January 25, 1983
    Assignee: American Cyanamid Company
    Inventor: Joseph A. Hoffman
  • Patent number: 4366277
    Abstract: Novel compounds having two bis (2,2,6,6-tetramethyl-4-piperidyl)-substituted nitrogen heterocyclic rings are provided which are useful as stabilizers for organic polymers. Organic polymer containing the novel compounds having two bis (2,2,6,6-tetramethyl-4-piperidyl)-substituted nitrogen heterocyclic ring compounds exhibit improved resistance to deterioration induced by light, by heat or by a combination of light and heat.
    Type: Grant
    Filed: December 4, 1981
    Date of Patent: December 28, 1982
    Assignee: Carstab Corporation
    Inventor: Kenneth R. Molt
  • Patent number: 4365085
    Abstract: The present invention relates to novel bicyclic compounds useful as photographic silver halide developing agents, to the preparation of these compounds and to photographic products, processes and compositions employing the same. The subject compounds may be represented by the formula ##STR1## wherein R.sub.1 and R.sub.2, the same or different, each represents hydrogen, a hydrocarbon moiety, preferably an alkyl group, --COOH or --COOR.sup.1 wherein R.sup.1 is an alkyl group; R.sub.3 and R.sub.4, the same or different, each represent hydrogen or an alkyl group, R.sub.5 represents hydrogen or --COR.sup.2 wherein R.sup.2 is an alkyl group; R.sub.6 represents hydrogen when R.sub.5 is hydrogen and represents hydrogen or --OCOR.sup.3 wherein R.sup.3 is an alkyl group the same as R.sup.2 when R.sub.5 represents --COR.sup.2 ; X represents --OH, --NH.sub.2 or --NHCOR.sup.4 wherein R.sup.4 represents an alkyl group the same as R.sup.2 ; Y represents --OH or --OCOR.sup.5 wherein R.sup.
    Type: Grant
    Filed: February 5, 1979
    Date of Patent: December 21, 1982
    Assignee: Polaroid Corporation
    Inventors: James R. Bartels-Keith, Eva R. Karger
  • Patent number: 4362669
    Abstract: Novel compositions of matter are disclosed having the general formula UO.sub.2 AA'L.sub.n, in which A and A' are anions whose conjugate acids have boiling points less than about 200.degree. C. and pK.sub.a values of 4.8 or less, L is a neutral ligand (1) having a boiling point of greater than about 200.degree. C. and an equilibrium constant for its exchange reaction with complexed tetrahydrofuran of greater than about 10.sup.-3, or (2) having an equilibrium constant for its exchange reaction with complexed tetrahydrofuran of greater than about 10.sup.3, and n is an integer of from 1 to 4.
    Type: Grant
    Filed: February 25, 1980
    Date of Patent: December 7, 1982
    Assignee: Exxon Research and Engineering Co.
    Inventors: George M. Kramer, Donald M. Cox, Martin B. Dines, Edward T. Maas, Jr.
  • Patent number: 4348406
    Abstract: Compounds of the formula: ##STR1## and their pharmaceutically acceptable acid addition salts, useful as anthelmintics are disclosed.
    Type: Grant
    Filed: October 20, 1980
    Date of Patent: September 7, 1982
    Assignee: Schering Corporation
    Inventor: M. Mehdi Nafissi-Varchei
  • Patent number: 4342873
    Abstract: Antimicrobial agents suitable for use in aqueous systems for their preservation against biodeterioration include substitutedpiperidinomethyl-propenenitriles and propanenitriles. The unsaturated compounds are prepared by reaction of a suitable piperidine with cyano acetic acid and formaldehyde: the propane derivatives therefrom by nucleophilic addition.
    Type: Grant
    Filed: January 26, 1981
    Date of Patent: August 3, 1982
    Assignee: Merck & Co., Inc.
    Inventors: Nathaniel Grier, Richard A. Dybas, Bruce E. Witzel
  • Patent number: 4342872
    Abstract: Antimicrobial agents suitable for use in aqueous systems for their prservation against biodeterioration include substitutedpiperidinomethylpropenenitriles and propanenitriles. The unsaturated compounds are prepared by reaction of a suitable piperidine with cyano acetic acid and formaledehyde: the propane derivatives therefrom by nucleophilic addition.
    Type: Grant
    Filed: October 6, 1980
    Date of Patent: August 3, 1982
    Assignee: Merck & Co., Inc.
    Inventors: Nathaniel Grier, Richard A. Dybas, Bruce E. Witzel
  • Patent number: 4329478
    Abstract: Cyclic perfluoroaliphaticdisulfonic acid anhydrides, sulfonamide derivatives thereof, a process for making the same, curable compositions containing cyclic perfluoroaliphaticdisulfonic acid anhydrides or sulfonamide derivatives thereof and cationically-sensitive monomers, and a process for using cyclic perfluoroaliphaticdisulfonic acid anhydrides or sulfonamide derivatives thereof as catalysts for the cure of cationically-sensitive monomers.
    Type: Grant
    Filed: January 30, 1981
    Date of Patent: May 11, 1982
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Fred E. Behr
  • Patent number: 4325940
    Abstract: The use for anti-microbial, cosmetic and water-treatment of compounds of formula: ##STR1## in which R.sup.I and R.sup.II and (I) the same or different monovalent, branched or unbranched, alkyl groups of from 1 to 18 carbon atoms, optionally substituted by from 1 to 2 hydroxyl groups; or (II) form a 5, 6 or 7 membered ring when taken together with N, or (III) form the N-morpholino group when taken together with N and an oxygen atom; wherein R.sup.III, R.sup.IV and R.sup.V are (I) the same or different, branched or unbranched, alkyl groups of from 1 to 18 carbon atoms, optionally substituted by 1 or 2 hydroxyl groups, or (II) R.sup.III is a branched or unbranched alkyl group of from 1 to 18 carbon atoms optionally substituted by 1 or 2 hydroxyl groups and R.sup.IV and R.sup.V form a 5, 6 or 7 membered ring when taken together with N; or (III) R.sup.III is a branched or unbranched alkyl group of from 1 to 18 carbon atoms optionally substituted by 1 or 2 hydroxyl groups and R.sup.IV and R.sup.
    Type: Grant
    Filed: February 8, 1980
    Date of Patent: April 20, 1982
    Assignee: Kewanee Industries, Inc.
    Inventors: Harold A. Green, John J. Merianos, Alfonso N. Petrocci
  • Patent number: 4304910
    Abstract: A method for synthesizing compounds of formula: ##STR1## in which R' and R" (I) are the same or different monovalent branched or unbranched alkyl groups of from 1 to 18 carbon atoms, optionally substituted by from 1 to 2 hydroxyl groups, the sum of the carbon atoms in R' and R" being at least three; or (II) form a 5, 6, or seven membered ring when taken together with N; or (III) form the N-Morpholino group when taken together with N and Oxygen, wherein Z represents either X or --N R'R", wherein X is a halogen of atomic weight above 30, and wherein n represents an integer of from 2 to 20.
    Type: Grant
    Filed: April 13, 1979
    Date of Patent: December 8, 1981
    Assignee: Kewanee Industries, Inc.
    Inventors: Harold A. Green, John J. Merianos, Alfonso N. Petrocci
  • Patent number: 4293466
    Abstract: New derivatives of N,N'-4-piperidyl-tetraalkyl-substituted alkylene diamines are disclosed. These new compounds are useful for stabilizing thermoplastic polymers, in particular polyolefins, against sunlight, heat and oxidation. A process for producing the new compounds is also disclosed, as well as the use thereof as stabilizers of polymers and polymeric compositions.
    Type: Grant
    Filed: December 5, 1978
    Date of Patent: October 6, 1981
    Assignee: Montedison S.p.A.
    Inventors: Piero Di Battista, Renzo Fontanelli, Francesco Gratani, Giuseppe Nelli
  • Patent number: 4284829
    Abstract: Compounds useful for pharmacological and medicinal purposes having the formulae ##STR1## wherein R is H, C.sub.1 -C.sub.5 alkanoyl; R.sub.1 is H, benzyl, C.sub.1 14 C.sub.5 alkanoyl, P(O)(OH).sub.2, --CO(CH.sub.2).sub.2 COOH or a basic acyl group; each of R.sub.2 and R.sub.4 is H, C.sub.1 -C.sub.6 alkyl, phenyl, pyridyl or (CH.sub.2).sub.y C.sub.6 H.sub.5 ; y is 1-4; R.sub.3 is H or CH.sub.3 ; Z is C.sub.1 -C.sub.13 alkylene or --(alk.sub.1).sub.m --O--(alk.sub.2).sub.n --; each of (alk.sub.1) and (alk.sub.2) is C.sub.1 -C.sub.13 alkylene with the proviso that the summation of carbon atoms in (alk.sub.1) plus (alk.sub.2) is not greater than 13; each of m and n is 0 or 1; and W is H, pyridyl, phenyl, fluorophenyl or chlorophenyl; intermediates therefor and methods for their preparation and use.
    Type: Grant
    Filed: December 22, 1978
    Date of Patent: August 18, 1981
    Assignee: Pfizer Inc.
    Inventors: Thomas H. Althuis, Charles A. Harbert, Michael R. Johnson, Lawrence S. Melvin, Jr.