Thiocarbonyl Bonded Directly To The Six-membered Hetero Ring Patents (Class 546/313)
  • Patent number: 5169432
    Abstract: Substituted pyridines having at the 3 or 5 position a carbonyl oxy(thio)ester or a heterocyclocarbonyl and at the other a substituted alkyl group, herbicidal compositions and methods of use thereof.
    Type: Grant
    Filed: May 23, 1991
    Date of Patent: December 8, 1992
    Assignee: Monsanto Company
    Inventors: Susan M. Auinbauh, Len F. Lee, Karey A. Van Sant
  • Patent number: 5142057
    Abstract: A process for producing a carboxylic acid amide or ester, which comprises reacting an organic chloride having at least one chlorine atom on its ring of a substituted or unsubstituted, aromatic or heterocyclic hydrocarbon with carbon monoxide and an amine or an alcohol in the presence of a base by using as catalysts a palladium compound and a phosphine compound represented by the general formula (V):(R).sub.2 P--X--P(R).sub.2 (V)wherein R is an alkyl group or a substituted or unsubstituted phenyl group, and X is an alkylene group having 1 to 6 carbon atoms ##STR1## or a binaphthyl group.
    Type: Grant
    Filed: May 29, 1990
    Date of Patent: August 25, 1992
    Assignee: Nihon Nohyaku Co., Ltd.
    Inventors: Keiji Suto, Masaaki Kudo, Moriharu Yamamoto
  • Patent number: 5129943
    Abstract: Disclosed herein are 2- or 6-fluoromethyl-3-pyridinecarboxylate derivatives with 5-[(heterocyclic)ylidene]amino substitution useful as herbicides and herbicide intermediates.
    Type: Grant
    Filed: May 20, 1991
    Date of Patent: July 14, 1992
    Assignee: Monsanto Company
    Inventors: Shridhar G. Hegde, Len F. Lee, Robert D. Bryant
  • Patent number: 5099024
    Abstract: A process for dehydrofluorination of a 2,6-(bis)trifluoromethyl-dihydropyridine-3,5-dicarbothioic acid ester.
    Type: Grant
    Filed: March 19, 1990
    Date of Patent: March 24, 1992
    Assignee: Monsanto Company
    Inventors: Mitchell J. Pulwer, William Miller, Sherrol L. Baysdon
  • Patent number: 5099023
    Abstract: A process for dehydrofluorination of a 2,6-(bis) trifluoromethyl-dihydropyridine-3,5-dicarbothioic acid ester.
    Type: Grant
    Filed: March 19, 1990
    Date of Patent: March 24, 1992
    Assignee: Monsanto Company
    Inventors: William Miller, Mitchell J. Pulwer
  • Patent number: 5008276
    Abstract: Fungicidal compounds of the formula (I): ##STR1## and stereoisomers thereof, wherein K is oxygen or sulphur; Z is optionally substituted aryl or optionally substituted heteroaryl; X is O, S(O).sub.n, NR.sup.4, CR.sup.1 R.sup.2, CHR.sup.5, CO, CR.sup.1 (OR.sup.2), C.dbd.CR.sup.1 R.sup.2, CHR.sup.1 CHR.sup.2, CR.sup.1 .dbd.CR.sup.2, CHR.sup.1 CR.sup.2 .dbd.CH, C.dbd.C, OCHR.sup.1, CHR.sup.1 O, OCHR.sup.1 O, S(O).sub.n CHR.sup.1, S(O).sub.n CHR.sup.1 O, CHR.sup.1 S(O).sub.n, CHR.sup.1 OSO.sub.2, NR.sup.4 CHR.sup.1, CHR.sup.1 NR.sup.4, CO.sub.2, O.sub.2 C, SO.sub.2 O, OSO.sub.2, CO.CO, COCHR.sup.1, COCHR.sup.1 O, CHR.sup.1 CO, CHOH.CHR.sup.1, CHR.sup.1.CHOH, ##STR2## CONR.sup.4, OCONR.sup.4, NR.sup.4 CO, CSNR.sup.4, OCS.NR.sup.4, SCO.NR.sup.4, NR.sup.4 CO.sub.2, NR.sup.4 CS, NR.sup.4 CSO, NR.sup.4 COS, NR.sup.4 CONR.sup.4, S(O).sub.n NR.sup.4, NR.sup.4 S(O).sub.n, CS.sub.2, S.sub.2 C, CO.S, SCO, N.dbd.N, N.dbd.CR.sup.1, CR.sup.1 .dbd.N, CHR.sup.1 CHR.sup.2 CH(OH), CHR.sup.1 OCO, CHR.sup.1 SCO, CHR.sup.1 NR.sup.
    Type: Grant
    Filed: October 17, 1988
    Date of Patent: April 16, 1991
    Assignee: Imperial Chemical Industries PLC
    Inventors: John M. Clough, Christopher R. A. Godfrey, Stephen P. Heaney, Kenneth Anderton
  • Patent number: 4973429
    Abstract: A material in the form of a film is described which contains, in an orientated arrangement which does not display point symmetry, compounds of formula I ##STR1## wherein X is .dbd.CH-- or .dbd.N--, R.sup.1 is C.sub.12 -C.sub.30 -alkyl, R.sup.2 is hydrogen or C.sub.1 -C.sub.30 -alkyl, R.sup.3 is --NO.sub.2, --CN, --CF.sub.3, --COCF.sub.3, --SO.sub.2 CH.sub.3 or --SO.sub.2 CF.sub.3, R.sup.4 is hydrogen or is defined in the same way as R.sup.3, R.sup.5 is hydrogen or --NR.sup.6 R.sup.7 and R.sup.6 and R.sup.7 independently of one another are hydrogen or C.sub.1 -C.sub.30 -alkyl, it also being possible for any of the alkyl radicals to be partially fluorinated or perfluorinated.The compounds of formula I can be arranged in Langmuir-Blodgett layer systems. Such systems can be used for example for the manufacture of opto-electronic units.
    Type: Grant
    Filed: February 15, 1989
    Date of Patent: November 27, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Gero Decher, Bernd Tieke, Christian Bosshard, Peter Gunter
  • Patent number: 4950762
    Abstract: There are provided gastric antiulcer and cytoprotective substituted N-phenyl-2-pyridinecarbothioamides. The process for their production and formulation is disclosed.
    Type: Grant
    Filed: July 10, 1989
    Date of Patent: August 21, 1990
    Assignee: American Home Products Corporation
    Inventors: William A. Kinney, Amadeo A. Failli, Ghulam N. Mir
  • Patent number: 4886821
    Abstract: There are provided gastric antiulcer and cytoprotective substituted N-phenyl-2-pyridinecarbothioamides. The process for their production and formulation is disclosed.
    Type: Grant
    Filed: November 23, 1987
    Date of Patent: December 12, 1989
    Assignee: American Home Products Corporation
    Inventors: William A. Kinney, Amadeo A. Failli, Ghulam N. Mir
  • Patent number: 4873238
    Abstract: There are provided gastric antiulcer and cytoprotective substituted N-phenyl-2-pyridinecarbothioamides. The process for their production and formulation is disclosed.
    Type: Grant
    Filed: September 19, 1988
    Date of Patent: October 10, 1989
    Assignee: American Home Products Corporation
    Inventors: William A. Kinney, Nancy E. Lee
  • Patent number: 4835279
    Abstract: Disclosed herein are 3,5-pyridinedicarboxylic acid derivatives having halogen substitution at the 4 position which are useful as herbicides and herbicide precursors.
    Type: Grant
    Filed: June 17, 1987
    Date of Patent: May 30, 1989
    Assignee: Monsanto Company
    Inventors: Len F. Lee, Maria L. Miller
  • Patent number: 4782074
    Abstract: The substituted heteroaryl compounds of this invention are good fungicides. In particular, they possess especially good activity against Bean Powdery Mildew.
    Type: Grant
    Filed: March 30, 1987
    Date of Patent: November 1, 1988
    Assignee: Chevron Research Company
    Inventor: David M. Spatz
  • Patent number: 4692184
    Abstract: There are disclosed novel 2,6-substituted-3,5-pyridinedicarboxylic acids, esters, salts, amides, halides, and cyano compounds useful as herbicides, and as intermediates which provide herbicides.
    Type: Grant
    Filed: April 24, 1984
    Date of Patent: September 8, 1987
    Assignee: Monsanto Company
    Inventor: Len F. Lee
  • Patent number: 4654346
    Abstract: The substituted heteroaryl compounds of this invention are good fungicides. In particular, they possess especially good activity against Bean Powdery Mildew.
    Type: Grant
    Filed: January 11, 1985
    Date of Patent: March 31, 1987
    Assignee: Chevron Research Company
    Inventor: David M. Spatz
  • Patent number: 4613356
    Abstract: Substituted aryloxyphenoxy propionyl thiourea compounds useful as herbicides, and their methods of use, a representative one of which has the structural formula ##STR1## The method comprises applying the above referenced compound to the locus where control is desired.
    Type: Grant
    Filed: August 6, 1984
    Date of Patent: September 23, 1986
    Assignee: Stauffer Chemical Company
    Inventor: Ferenc M. Pallos
  • Patent number: 4596813
    Abstract: The substituted heteroaryl compounds of this invention are good fungicides. In particular, they possess especially good activity against Bean Powdery Mildew, and other plant fungal diseases.
    Type: Grant
    Filed: November 4, 1982
    Date of Patent: June 24, 1986
    Assignee: Chevron Research Company
    Inventor: David M. Spatz
  • Patent number: 4521242
    Abstract: There are provided novel substituted phenyl (thiono)carbamates capable of effectively controlling broad-leaved annual weeds and annual weeds belonging to the families Gramineae and Cyperaceae such as wild Echinochloa species, monochoria, toothcup and umbrella plant, herbicidal compositions containing these (thiono)carbamates as active ingredient and a method of controlling weeds using these (thiono)carbamates. The (thiono)carbamates are substantially nonphytotoxic to useful crop plants such as the paddy rice plant.
    Type: Grant
    Filed: August 3, 1982
    Date of Patent: June 4, 1985
    Assignee: Kuraray Co., Ltd.
    Inventors: Tetsuo Takematsu, Makoto Konnai, Takeo Hosogai, Takashi Nishida
  • Patent number: 4504484
    Abstract: The substituted heteroaryl compounds of this invention are good fungicides. In particular, they possess especially good activity against Bean Powdery Mildew.
    Type: Grant
    Filed: November 4, 1982
    Date of Patent: March 12, 1985
    Assignee: Chevron Research Company
    Inventor: David M. Spatz
  • Patent number: 4347372
    Abstract: A process for protecting cultivated plants against aggressive agricultural chemicals is described in which oxime derivatives of the formula ##STR1## are used as antidotes. Either the cultivated area for the cultivated plants or the cultivated plants themselves or parts of the plant (seeds, tubers, stem parts and the like), as desired, can be treated with these oxime derivatives, which are used as a dressing.
    Type: Grant
    Filed: August 28, 1979
    Date of Patent: August 31, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Alfons Lukaszczyk, Henry Martin, Peter J. Diel, Werner Fory, Karl Gatzi, Haukur Kristinsson, Beat Muller, Rene Muntwyler, Johannes P. Pachlatko, Hermann Rempfler, Rolf Schurter, Henry Szczepanski
  • Patent number: 4258181
    Abstract: This disclosure describes anthracene-9,10-bis-carbonyl-hydrazones and derivatives thereof useful as antibacterial agents, for inhibiting the growth of transplanted mouse tumors, and for inducing the regression and/or palliation of leukemia and related cancers.
    Type: Grant
    Filed: May 7, 1979
    Date of Patent: March 24, 1981
    Assignee: American Cyanamid Company
    Inventors: Keith C. Murdock, Frederick E. Durr
  • Patent number: 4252814
    Abstract: There are provided novel cyanomethyl thioester compounds useful as ovicidal and larvicidal agents effective for the control of insects.
    Type: Grant
    Filed: July 5, 1979
    Date of Patent: February 24, 1981
    Assignee: American Cyanamid Company
    Inventors: Peter J. Wepplo, Donald P. Wright, Jr.
  • Patent number: 4141977
    Abstract: A treatment to alleviate the symptoms of psoriasis consisting of topical application of a cream, ointment or lotion containing, as the principal active ingredient, one or more 6-substituted nicotinamides and or 2-substituted pyrazinamides is disclosed. The therapeutic composition may include a single member of the above active ingredients present in a total amount of from 0.01 to 5 percent by weight of the total composition, or a plurality thereof present in a preferred concentration range of from 0.02 to 2 percent by weight of the total composition. Topical application of the therapeutic composition in a cream, ointment, or a water or alcohol solution has been found to achieve from substantial to complete remissions of psoriasis in humans.
    Type: Grant
    Filed: August 17, 1976
    Date of Patent: February 27, 1979
    Inventors: Ruey J. Yu, Eugene J. Van Scott