By Oxidation Patents (Class 546/320)
  • Patent number: 10566843
    Abstract: A wireless charging circuit is disclosed. In this regard, a wireless charging circuit is configured to charge a battery by harvesting radio frequency (RF) power from a wireless RF charging signal provided by a wireless charging station. The wireless charging circuit monitors an effective charging power provided to the battery and sends a battery charging signal indication (BCSI) to the wireless charging station to reduce the effective charging power if the effective charging power is greater than a target charging power. In another aspect, the wireless charging circuit sends the BCSI to increase the effective charging power if the effective charging power is less than the target charging power. By dynamically adjusting the effective charging power based on the charging profile of the battery, it is possible to provide fast charging to the battery while protecting the battery from overcharging damage.
    Type: Grant
    Filed: July 7, 2015
    Date of Patent: February 18, 2020
    Assignee: Qorvo US, Inc.
    Inventor: Nadim Khlat
  • Patent number: 7560566
    Abstract: A process for the production of a heteroaromatic carboxylic acid comprising contacting in the presence of a catalyst, a precursor of said carboxylic acid with an oxidant, such contact being effected with said precursor and the oxidant in an aqueous solvent comprising water under supercritical conditions or near supercritical conditions close to the supercritical point.
    Type: Grant
    Filed: October 1, 2004
    Date of Patent: July 14, 2009
    Assignee: INVISTA North America S.a.r.l.
    Inventors: William Barry Thomas, Keith Whiston, Eduardo Cepeda Garcia-Verdugo, Martyn Poliakoff, Paul Anthony Hamley
  • Patent number: 7456291
    Abstract: Use of a combination of two vitamin compounds, i.e. riboflavin (also known as vitamin B2) and nicotinic acid (also referred to as niacin) or, as an alternative thereto, the corresponding amide, i.e. niacinamide or nicotinamide (also known as vitamin PP) for the treatment of various forms of primary headache, such as classical migraine or migraine with an aura, common migraine or migraine without an aura, complicated migraine and cluster headache or histamine headache. The invention also concerns compositions for the treatment of primary headaches which are based on the two aforesaid active ingredients.
    Type: Grant
    Filed: July 20, 2001
    Date of Patent: November 25, 2008
    Inventor: Giampiero Valletta
  • Patent number: 7371866
    Abstract: A process for catalytically oxidizing alkylaromatic compounds of the formula (I) Ar—CH2—R where Ar is an optionally substituted, aromatic or heteroaromatic 5-membered or 6-membered ring or a ring system having up to 20 carbon atoms where Ar may optionally be fused to a C1-C6-alkyl group in which up to 2 carbon atoms may be replaced by a heteroatom, and R is hydrogen, phenyl, benzyl or heteroaryl, where the phenyl, benzyl or heteroaryl radicals may also be joined to Ar by a bridge, or R together with Ar forms an optionally substituted ring system which may contain one or more optionally substituted heteroatoms, to the corresponding aromatic or heteroaromatic carboxylic acids in a solvent with ozone in the presence of a transition metal catalyst and optionally in the presence of an acid at a temperature between ?70° C. and 110° C. to the corresponding carboxylic acid.
    Type: Grant
    Filed: May 15, 2003
    Date of Patent: May 13, 2008
    Assignee: DSM Fine Chemicals Austria Nfg GmbH & Co KG
    Inventors: Walther Jary, Peter Poechlauer, Thorsten Ganglberger
  • Patent number: 7026340
    Abstract: The present invention relates to a novel malononitrile compound represented by the formula (I): wherein, R1 represents a C1 to C5 (halo)alkyl and the like, R2 represents a C1 to C5 (halo)alkyl, R3 and R4 are the same or different and are a C1 to C6 (halo)alkyl and the like, R5 represents a halogen atom and the like, n is an integer of 0 to 4 and when n is 2 or more, R5 may be the same or different.
    Type: Grant
    Filed: July 7, 2003
    Date of Patent: April 11, 2006
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Ken Otaka, Daisuke Oohira, Daisuke Takaoka
  • Patent number: 7022853
    Abstract: The present invention relates to a single-pot process for the preparation of metal nicotinates, useful as a dietary supplement, from beta picoline as a source of the starting material, said process comprising the steps hydrosulfonation of beta picoline with sulfuric acid, heating the reaction mixture thus obtained to a temperature of about 150°-210° C. followed by oxidation with a suitable oxidizing agent to obtain nicotinic acid sulfate, reacting the nicotinic acid sulfate with a water soluble zinc and/or chromium salt to produce a solid metal nicotinate and separating it to thereby recover the corresponding metal nicotinates of high purity.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: April 4, 2006
    Assignee: Jubilant Organosys Ltd.
    Inventors: Nikhilesh Chandra Bhardwaj, Pradeep Kumar Verma, Agarwal Ashutosh
  • Patent number: 6900330
    Abstract: Highly pure 2,3-pyridinedicarboxylic acid is produced by a process suitable for application in commercial production with a high yield and with recirculation of waste liquor.
    Type: Grant
    Filed: September 8, 2003
    Date of Patent: May 31, 2005
    Assignee: Hebei Sinochem Fuheng Co., Ltd.
    Inventors: Toshio Sato, Takeshi Namekata
  • Patent number: 6403618
    Abstract: A metal ion chelating agent such as picolinic acid or derivatives thereof, and methods of using the same. The agents chelate metals in metal containing protein complexes and enzymes required for growth and replication of blood vessel cells. The preparations can be administered systemically or for topical use. The preparations have antineoplastic activity augmented by the antiangiogenic properties.
    Type: Grant
    Filed: October 2, 2000
    Date of Patent: June 11, 2002
    Assignee: Novactyl, Inc.
    Inventor: Jose A. Fernandez-Pol
  • Patent number: 6376677
    Abstract: Nicotinic acid is produced from aqueous solutions of ammonium nicotinate by spray-drying. The nicotinic acid can be freed from residual ammonium nicotinate by a thermal post-treatment in a fluidized bed or under reduced pressure. The process is suitable in particular for the work-up of the reaction mixture produced in the oxidation of 3-methylpyridine with atmospheric oxygen, with the ammonia and, if appropriate, the water, being able to be recycled. Nicotinic acid (“vitamin PP”) is an important additive to foodstuffs and feedstuffs.
    Type: Grant
    Filed: June 20, 2000
    Date of Patent: April 23, 2002
    Assignee: Lonza AG
    Inventors: Roderick J. Chuck, Uwe Zacher
  • Patent number: 6346623
    Abstract: An improved process for the preparation of substituted pyridinecarboxylic acids (II), useful as herbicide intermediates, by ozonolysis of quinolines (I).
    Type: Grant
    Filed: November 30, 2000
    Date of Patent: February 12, 2002
    Assignee: DSM Fine Chemicals Austria Nfg GmbH & CoKG
    Inventors: Gerhard Steinbauer, Curt Zimmermann, Ernst Wressnegger, Erich Steinwender
  • Patent number: 6229018
    Abstract: A process for the preparation of nicotinic acid by the direct oxidation of &bgr;-picoline in the gas phase, wherein water and &bgr;-picoline are fed separately to the catalyst bed and the catalyst is based on a titanium dioxide support which has been prepared by the sulfate method and has a high specific surface area and a vanadium oxide content of from 5 to 50 %.
    Type: Grant
    Filed: August 31, 1999
    Date of Patent: May 8, 2001
    Assignee: Degussa Aktiengesellschaft
    Inventors: Dieter Heinz, Wolfgang Hölderich, Steffen Krill, Wolfgang Böck, Klaus Huthmacher
  • Patent number: 6077957
    Abstract: Nicotinic acid is produced from aqueous solutions of ammonium nicotinate by spray-drying. The nicotinic acid can be freed from residual ammonium nicotinate by a thermal post-treatment in a fluidized bed or under reduced pressure. The process is suitable in particular for the work-up of the reaction mixture produced in the oxidation of 3-methylpyridine with atmospheric oxygen, with the ammonia and, if appropriate, the water, being able to be recycled. Nicotinic acid ("vitamin PP") is an important additive to foodstuffs and feedstuffs.
    Type: Grant
    Filed: November 23, 1998
    Date of Patent: June 20, 2000
    Assignee: Lonza AG
    Inventors: Roderick J. Chuck, Uwe Zacher
  • Patent number: 5917049
    Abstract: Process for the preparation of a heterocyclic o-dicarboxylic acid containing at least one N atom, in which a corresponding benzo-fused heterocyclic compound containing at least one N atom is oxidised in the presence of hydrogen peroxide, a Bronsted acid and an iron compound.Preferably Fe(NO.sub.3).sub.3 is used as the iron compound and HNO.sub.3 as the Bronsted acid. The amount of iron compound to be used preferably lies between 0.1 and 2 mol. %, relative to the amount of employed benzo-fused heterocyclic compound containing at least one N atom. Even higher yields can be obtained if a copper compound or an organic electron-transferring compound is also used, in addition to the iron compound.In particular, the process according to the invention can be used to prepare 2,3-pyridine dicarboxylic acids from corresponding quinoline compounds.
    Type: Grant
    Filed: December 12, 1997
    Date of Patent: June 29, 1999
    Assignee: DSM N.V.
    Inventors: Geertrudes H Suverkropp, Paulus L Alsters, Carina S Snijder, Johannes G De Vries
  • Patent number: 5728837
    Abstract: A method has been developed for preparing nicotinic acid with a yield of 82-86% mol, in which method there is no formation of harmful gas wastes and liquid wastes.The process is carried out by gas-phase single-step oxidation of .beta.-picoline with oxygen in the presence of water vapor and a catalyst on the base of oxides of vanadium and titanium, with or without additives, at a temperature of 250.degree.-290.degree. C. and mole ratios O.sub.2 :.beta.-picoline=15-40 and H.sub.2 O:.beta.-picoline=10-70.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: March 17, 1998
    Assignee: Institut Kataliza Imeni G.K. Boreskova Sibirskogo Otdelenia Rossiiskoi Akademii Nauk
    Inventors: Evgenia Moiseevna Alkaeva, Tamara Vitalievna Andrushkevich, Galina Alexeevna Zenkovets, Mikhail Grigorievich Makarenko
  • Patent number: 5614635
    Abstract: The present invention provides an improved method for the preparation of pyridine-2,3-dicarboxylic acids by the continuous oxidation of substituted quinolines.
    Type: Grant
    Filed: August 16, 1995
    Date of Patent: March 25, 1997
    Assignee: American Cyanamid Company
    Inventor: Paul E. Miller
  • Patent number: 5410062
    Abstract: There are provided crystalline substituted-2,3-dicarboxypyridinium nitrate salts, the preparation thereof and the use thereof in the isolation and purification of important substituted pyridinedicarboxylic acid herbicide intermediates.
    Type: Grant
    Filed: February 2, 1994
    Date of Patent: April 25, 1995
    Assignee: American Cyanamid Company
    Inventor: Henry L. Strong
  • Patent number: 5371229
    Abstract: There is provided an improved process for the preparation of substituted and unsubstituted 2,3-pyridinedicarboxylic acids in significantly enhanced yield by the nitric acid oxidation of the appropriately substituted quinoline precursor in the presence of a catalytic amount of Manganese.
    Type: Grant
    Filed: October 28, 1992
    Date of Patent: December 6, 1994
    Assignee: American Cyanamid Company
    Inventors: Nicholas A. Cortese, Jr., Henry L. Strong
  • Patent number: 5250542
    Abstract: 3,4,4-trisubstitutedpiperidinyl-N-alkylcarboxylates and intermediates for their preparation are provided. These piperidine-N-alkylcarboxylates are useful as peripheral opioid antagonists.
    Type: Grant
    Filed: July 17, 1992
    Date of Patent: October 5, 1993
    Assignee: Eli Lilly and Company
    Inventors: Buddy E. Cantrell, Dennis M. Zimmerman
  • Patent number: 5231104
    Abstract: A series of novel 1-(phenethyl) and 1-(2-heteroarylethyl)-3-substituted piperidine derivatives have been prepared, including their pharmaceutically acceptable salts and various novel key intermediates therefor. The 3-substituent present in these compounds is an unsubstituted or substituted diphenylmethoxy group or a diphenylmethoxy-derived group, while the 1-substituent is unsubstituted or substituted phenethyl or 1-(2-heteroarylethyl) wherein the heteroaryl moiety is thienyl, pyridyl or pyrazinyl. These compounds in the form of both their racemates and 3R-isomers, are useful in therapy as smooth muscle muscarinic receptor antagonists and therefore, are of value in the treatment diseases associated with altered motility and/or smooth muscle tone.
    Type: Grant
    Filed: February 5, 1992
    Date of Patent: July 27, 1993
    Assignee: Pfizer Inc.
    Inventors: David Alker, Peter E. Cross, Robert M. Wallis
  • Patent number: 5008276
    Abstract: Fungicidal compounds of the formula (I): ##STR1## and stereoisomers thereof, wherein K is oxygen or sulphur; Z is optionally substituted aryl or optionally substituted heteroaryl; X is O, S(O).sub.n, NR.sup.4, CR.sup.1 R.sup.2, CHR.sup.5, CO, CR.sup.1 (OR.sup.2), C.dbd.CR.sup.1 R.sup.2, CHR.sup.1 CHR.sup.2, CR.sup.1 .dbd.CR.sup.2, CHR.sup.1 CR.sup.2 .dbd.CH, C.dbd.C, OCHR.sup.1, CHR.sup.1 O, OCHR.sup.1 O, S(O).sub.n CHR.sup.1, S(O).sub.n CHR.sup.1 O, CHR.sup.1 S(O).sub.n, CHR.sup.1 OSO.sub.2, NR.sup.4 CHR.sup.1, CHR.sup.1 NR.sup.4, CO.sub.2, O.sub.2 C, SO.sub.2 O, OSO.sub.2, CO.CO, COCHR.sup.1, COCHR.sup.1 O, CHR.sup.1 CO, CHOH.CHR.sup.1, CHR.sup.1.CHOH, ##STR2## CONR.sup.4, OCONR.sup.4, NR.sup.4 CO, CSNR.sup.4, OCS.NR.sup.4, SCO.NR.sup.4, NR.sup.4 CO.sub.2, NR.sup.4 CS, NR.sup.4 CSO, NR.sup.4 COS, NR.sup.4 CONR.sup.4, S(O).sub.n NR.sup.4, NR.sup.4 S(O).sub.n, CS.sub.2, S.sub.2 C, CO.S, SCO, N.dbd.N, N.dbd.CR.sup.1, CR.sup.1 .dbd.N, CHR.sup.1 CHR.sup.2 CH(OH), CHR.sup.1 OCO, CHR.sup.1 SCO, CHR.sup.1 NR.sup.
    Type: Grant
    Filed: October 17, 1988
    Date of Patent: April 16, 1991
    Assignee: Imperial Chemical Industries PLC
    Inventors: John M. Clough, Christopher R. A. Godfrey, Stephen P. Heaney, Kenneth Anderton
  • Patent number: 4820839
    Abstract: Nitrogen-containing heterocyclic esters of the formula I,R.sup.1 -A.sup.1 -Z.sup.1 -A.sup.2 -[Z.sup.2 -A.sup.3 ].sub.m -R.sup.2 Iin which R.sup.1, R.sup.2, A.sup.1, A.sup.2, A.sup.3, Z.sup.1, Z.sup.2 and m have the meaning specified in patent claim 1, are suitable as components of smectic liquid-crystalline phases.
    Type: Grant
    Filed: January 23, 1987
    Date of Patent: April 11, 1989
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Joachim Krause, Andreas Wachtler, Volker Reiffenrath, Bernhard Scheuble, Reinhard Hittich
  • Patent number: 4816588
    Abstract: The present invention provides a novel method for the preparation of pyridine-2,3-dicarboxylic acids by the oxidation of 8-substituted quinolines.
    Type: Grant
    Filed: August 19, 1987
    Date of Patent: March 28, 1989
    Assignee: American Cyanamid Company
    Inventors: William F. Rieker, William A. Daniels
  • Patent number: 4782157
    Abstract: The invention provides an improved process for the preparation of substituted and unsubstituted 2-carbamoyl nicotinic and 3-quinolinecarboxylic acids.
    Type: Grant
    Filed: December 3, 1984
    Date of Patent: November 1, 1988
    Assignee: American Cyanamid Co.
    Inventor: John J. Pascavage
  • Patent number: 4754039
    Abstract: Pyridine-2,3-dicarboxylic acid can be prepared by oxidizing quinoline with a chlorate salt in an aqueous acidic medium. The oxidation can be conducted in the presence of cupric ions generated from an acid-soluble cupric compound.
    Type: Grant
    Filed: January 30, 1986
    Date of Patent: June 28, 1988
    Assignee: Ruetgers-Nease Chemical Co., Inc.
    Inventor: William Michalowicz
  • Patent number: 4736036
    Abstract: A process is disclosed for the manufacture of quinolinic acid by oxidizing quinoline with ruthenium tetraoxide in the presence of hypochlorite solution in which a certain amount of base is added prior to the inception of the oxidation reaction. The disclosed process provides greatly improved yields of high purity quinolinic acid.
    Type: Grant
    Filed: August 8, 1983
    Date of Patent: April 5, 1988
    Assignee: Appleton Papers Inc.
    Inventor: Ponnampalam Mathiaparanam
  • Patent number: 4623726
    Abstract: There is provided a novel process for the preparation of carboxylic acids from alkyl groups under basic conditions utilizing oxides of copper, cobalt and silver.
    Type: Grant
    Filed: April 18, 1983
    Date of Patent: November 18, 1986
    Assignee: American Cyanamid Company
    Inventor: William A. Daniels
  • Patent number: 4549024
    Abstract: A novel process for the preparation of quinolinic acid comprising reacting quinoline in an aqueous acid with hydrogen peroxide in the presence of at least one cation selected from the group consisting of vanadyl V, cobalt III, titanyl IV and osmium VIII cations at 50.degree. to 100.degree. C. and then oxidizing with chlorite or chlorate ions to form quinolinic acid.
    Type: Grant
    Filed: November 5, 1984
    Date of Patent: October 22, 1985
    Assignee: Rutgerswerke Aktiengesellschaft
    Inventors: Winfried Orth, Emmerich Pastorek, Werner Fickert
  • Patent number: 4537971
    Abstract: This invention relates to improved processes for the manufacture of quinolinic acid run with a higher concentration of reactants in the initial step wherein quinoline is oxidized with hydrogen peroxide in an aqueous sulfuric acid solution in the presence of copper sulfate to prepare copper quinolinate, and in subsequent steps converting the copper quinolinate from the initial step to quinolinic acid by treating the copper salt with alkali to form the water soluble alkali salt form of quinolinic acid precipitating the copper as insoluble cupric oxide and thereafter treating the soluble alkali salt form with acid to obtain the quinolinic acid, the improvement whereby the reaction of the initial step is carried out in a thermally controllable and safe manner and the formation of by-products is minimized which comprises in the initial step adding separately either in portion-wise multiple and approximately equal portions or adding continuously and simultaneously over a period of time each of the following, the su
    Type: Grant
    Filed: September 26, 1983
    Date of Patent: August 27, 1985
    Assignee: The Hilton-Davis Chemical Co.
    Inventors: Robert W. J. Rebhahn, James E. Kassner, Raymond E. Werner
  • Patent number: 4504665
    Abstract: A chloronicotinic acid compound is prepared by hydrolyzing a 3-trichloromethyl pyridine compound in the presence of sulfuric acid or phosphoric acid. By this process, a highly pure chloronicotinic acid compound is obtainable in good yield. This compound is useful as an intermediate for medicines.
    Type: Grant
    Filed: April 6, 1983
    Date of Patent: March 12, 1985
    Assignee: Ishihara Sangyo Kaisha Ltd.
    Inventors: Takahiro Haga, Tohru Koyanagi, Toshio Nakajima, Takeshi Ohshima
  • Patent number: 4294969
    Abstract: Novel substituted (3-loweralkylamino-2-R.sub.1 O-propoxy)pyridines, their pharmaceutically acceptable salts, certain intermediates and their preparation are disclosed. These pyridines have pharmaceutically useful properties such as .beta.-adrenergic blocking activity.
    Type: Grant
    Filed: July 11, 1980
    Date of Patent: October 13, 1981
    Assignee: Merck & Co., Inc.
    Inventors: John J. Baldwin, Gerald S. Ponticello
  • Patent number: 4217457
    Abstract: A highly selective oxidation process for preparing pyridin-carboxylic acids from pyridine compounds nucleus substituted with alkyl groups, through a carbon-carbon bond, and oxidizable to carboxyl, and from hydrosoluble hexavalent chromium compounds, in the presence of an acid.Particularly described is the oxidation of beta-picoline with sodium bichromate to obtain the sodium salt of nicotinic acid and 99.5% pure free acid, respectively.
    Type: Grant
    Filed: July 14, 1978
    Date of Patent: August 12, 1980
    Assignee: Luigi Stoppani S.p.A.
    Inventor: Giovanni Ghelli