By Oxidation Patents (Class 546/320)
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Patent number: 10566843Abstract: A wireless charging circuit is disclosed. In this regard, a wireless charging circuit is configured to charge a battery by harvesting radio frequency (RF) power from a wireless RF charging signal provided by a wireless charging station. The wireless charging circuit monitors an effective charging power provided to the battery and sends a battery charging signal indication (BCSI) to the wireless charging station to reduce the effective charging power if the effective charging power is greater than a target charging power. In another aspect, the wireless charging circuit sends the BCSI to increase the effective charging power if the effective charging power is less than the target charging power. By dynamically adjusting the effective charging power based on the charging profile of the battery, it is possible to provide fast charging to the battery while protecting the battery from overcharging damage.Type: GrantFiled: July 7, 2015Date of Patent: February 18, 2020Assignee: Qorvo US, Inc.Inventor: Nadim Khlat
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Patent number: 7560566Abstract: A process for the production of a heteroaromatic carboxylic acid comprising contacting in the presence of a catalyst, a precursor of said carboxylic acid with an oxidant, such contact being effected with said precursor and the oxidant in an aqueous solvent comprising water under supercritical conditions or near supercritical conditions close to the supercritical point.Type: GrantFiled: October 1, 2004Date of Patent: July 14, 2009Assignee: INVISTA North America S.a.r.l.Inventors: William Barry Thomas, Keith Whiston, Eduardo Cepeda Garcia-Verdugo, Martyn Poliakoff, Paul Anthony Hamley
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Patent number: 7456291Abstract: Use of a combination of two vitamin compounds, i.e. riboflavin (also known as vitamin B2) and nicotinic acid (also referred to as niacin) or, as an alternative thereto, the corresponding amide, i.e. niacinamide or nicotinamide (also known as vitamin PP) for the treatment of various forms of primary headache, such as classical migraine or migraine with an aura, common migraine or migraine without an aura, complicated migraine and cluster headache or histamine headache. The invention also concerns compositions for the treatment of primary headaches which are based on the two aforesaid active ingredients.Type: GrantFiled: July 20, 2001Date of Patent: November 25, 2008Inventor: Giampiero Valletta
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Patent number: 7371866Abstract: A process for catalytically oxidizing alkylaromatic compounds of the formula (I) Ar—CH2—R where Ar is an optionally substituted, aromatic or heteroaromatic 5-membered or 6-membered ring or a ring system having up to 20 carbon atoms where Ar may optionally be fused to a C1-C6-alkyl group in which up to 2 carbon atoms may be replaced by a heteroatom, and R is hydrogen, phenyl, benzyl or heteroaryl, where the phenyl, benzyl or heteroaryl radicals may also be joined to Ar by a bridge, or R together with Ar forms an optionally substituted ring system which may contain one or more optionally substituted heteroatoms, to the corresponding aromatic or heteroaromatic carboxylic acids in a solvent with ozone in the presence of a transition metal catalyst and optionally in the presence of an acid at a temperature between ?70° C. and 110° C. to the corresponding carboxylic acid.Type: GrantFiled: May 15, 2003Date of Patent: May 13, 2008Assignee: DSM Fine Chemicals Austria Nfg GmbH & Co KGInventors: Walther Jary, Peter Poechlauer, Thorsten Ganglberger
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Patent number: 7026340Abstract: The present invention relates to a novel malononitrile compound represented by the formula (I): wherein, R1 represents a C1 to C5 (halo)alkyl and the like, R2 represents a C1 to C5 (halo)alkyl, R3 and R4 are the same or different and are a C1 to C6 (halo)alkyl and the like, R5 represents a halogen atom and the like, n is an integer of 0 to 4 and when n is 2 or more, R5 may be the same or different.Type: GrantFiled: July 7, 2003Date of Patent: April 11, 2006Assignee: Sumitomo Chemical Company, LimitedInventors: Ken Otaka, Daisuke Oohira, Daisuke Takaoka
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Patent number: 7022853Abstract: The present invention relates to a single-pot process for the preparation of metal nicotinates, useful as a dietary supplement, from beta picoline as a source of the starting material, said process comprising the steps hydrosulfonation of beta picoline with sulfuric acid, heating the reaction mixture thus obtained to a temperature of about 150°-210° C. followed by oxidation with a suitable oxidizing agent to obtain nicotinic acid sulfate, reacting the nicotinic acid sulfate with a water soluble zinc and/or chromium salt to produce a solid metal nicotinate and separating it to thereby recover the corresponding metal nicotinates of high purity.Type: GrantFiled: October 29, 2002Date of Patent: April 4, 2006Assignee: Jubilant Organosys Ltd.Inventors: Nikhilesh Chandra Bhardwaj, Pradeep Kumar Verma, Agarwal Ashutosh
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Patent number: 6900330Abstract: Highly pure 2,3-pyridinedicarboxylic acid is produced by a process suitable for application in commercial production with a high yield and with recirculation of waste liquor.Type: GrantFiled: September 8, 2003Date of Patent: May 31, 2005Assignee: Hebei Sinochem Fuheng Co., Ltd.Inventors: Toshio Sato, Takeshi Namekata
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Patent number: 6403618Abstract: A metal ion chelating agent such as picolinic acid or derivatives thereof, and methods of using the same. The agents chelate metals in metal containing protein complexes and enzymes required for growth and replication of blood vessel cells. The preparations can be administered systemically or for topical use. The preparations have antineoplastic activity augmented by the antiangiogenic properties.Type: GrantFiled: October 2, 2000Date of Patent: June 11, 2002Assignee: Novactyl, Inc.Inventor: Jose A. Fernandez-Pol
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Patent number: 6376677Abstract: Nicotinic acid is produced from aqueous solutions of ammonium nicotinate by spray-drying. The nicotinic acid can be freed from residual ammonium nicotinate by a thermal post-treatment in a fluidized bed or under reduced pressure. The process is suitable in particular for the work-up of the reaction mixture produced in the oxidation of 3-methylpyridine with atmospheric oxygen, with the ammonia and, if appropriate, the water, being able to be recycled. Nicotinic acid (“vitamin PP”) is an important additive to foodstuffs and feedstuffs.Type: GrantFiled: June 20, 2000Date of Patent: April 23, 2002Assignee: Lonza AGInventors: Roderick J. Chuck, Uwe Zacher
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Patent number: 6346623Abstract: An improved process for the preparation of substituted pyridinecarboxylic acids (II), useful as herbicide intermediates, by ozonolysis of quinolines (I).Type: GrantFiled: November 30, 2000Date of Patent: February 12, 2002Assignee: DSM Fine Chemicals Austria Nfg GmbH & CoKGInventors: Gerhard Steinbauer, Curt Zimmermann, Ernst Wressnegger, Erich Steinwender
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Patent number: 6229018Abstract: A process for the preparation of nicotinic acid by the direct oxidation of &bgr;-picoline in the gas phase, wherein water and &bgr;-picoline are fed separately to the catalyst bed and the catalyst is based on a titanium dioxide support which has been prepared by the sulfate method and has a high specific surface area and a vanadium oxide content of from 5 to 50 %.Type: GrantFiled: August 31, 1999Date of Patent: May 8, 2001Assignee: Degussa AktiengesellschaftInventors: Dieter Heinz, Wolfgang Hölderich, Steffen Krill, Wolfgang Böck, Klaus Huthmacher
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Patent number: 6077957Abstract: Nicotinic acid is produced from aqueous solutions of ammonium nicotinate by spray-drying. The nicotinic acid can be freed from residual ammonium nicotinate by a thermal post-treatment in a fluidized bed or under reduced pressure. The process is suitable in particular for the work-up of the reaction mixture produced in the oxidation of 3-methylpyridine with atmospheric oxygen, with the ammonia and, if appropriate, the water, being able to be recycled. Nicotinic acid ("vitamin PP") is an important additive to foodstuffs and feedstuffs.Type: GrantFiled: November 23, 1998Date of Patent: June 20, 2000Assignee: Lonza AGInventors: Roderick J. Chuck, Uwe Zacher
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Patent number: 5917049Abstract: Process for the preparation of a heterocyclic o-dicarboxylic acid containing at least one N atom, in which a corresponding benzo-fused heterocyclic compound containing at least one N atom is oxidised in the presence of hydrogen peroxide, a Bronsted acid and an iron compound.Preferably Fe(NO.sub.3).sub.3 is used as the iron compound and HNO.sub.3 as the Bronsted acid. The amount of iron compound to be used preferably lies between 0.1 and 2 mol. %, relative to the amount of employed benzo-fused heterocyclic compound containing at least one N atom. Even higher yields can be obtained if a copper compound or an organic electron-transferring compound is also used, in addition to the iron compound.In particular, the process according to the invention can be used to prepare 2,3-pyridine dicarboxylic acids from corresponding quinoline compounds.Type: GrantFiled: December 12, 1997Date of Patent: June 29, 1999Assignee: DSM N.V.Inventors: Geertrudes H Suverkropp, Paulus L Alsters, Carina S Snijder, Johannes G De Vries
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Patent number: 5728837Abstract: A method has been developed for preparing nicotinic acid with a yield of 82-86% mol, in which method there is no formation of harmful gas wastes and liquid wastes.The process is carried out by gas-phase single-step oxidation of .beta.-picoline with oxygen in the presence of water vapor and a catalyst on the base of oxides of vanadium and titanium, with or without additives, at a temperature of 250.degree.-290.degree. C. and mole ratios O.sub.2 :.beta.-picoline=15-40 and H.sub.2 O:.beta.-picoline=10-70.Type: GrantFiled: July 17, 1996Date of Patent: March 17, 1998Assignee: Institut Kataliza Imeni G.K. Boreskova Sibirskogo Otdelenia Rossiiskoi Akademii NaukInventors: Evgenia Moiseevna Alkaeva, Tamara Vitalievna Andrushkevich, Galina Alexeevna Zenkovets, Mikhail Grigorievich Makarenko
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Patent number: 5614635Abstract: The present invention provides an improved method for the preparation of pyridine-2,3-dicarboxylic acids by the continuous oxidation of substituted quinolines.Type: GrantFiled: August 16, 1995Date of Patent: March 25, 1997Assignee: American Cyanamid CompanyInventor: Paul E. Miller
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Patent number: 5410062Abstract: There are provided crystalline substituted-2,3-dicarboxypyridinium nitrate salts, the preparation thereof and the use thereof in the isolation and purification of important substituted pyridinedicarboxylic acid herbicide intermediates.Type: GrantFiled: February 2, 1994Date of Patent: April 25, 1995Assignee: American Cyanamid CompanyInventor: Henry L. Strong
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Patent number: 5371229Abstract: There is provided an improved process for the preparation of substituted and unsubstituted 2,3-pyridinedicarboxylic acids in significantly enhanced yield by the nitric acid oxidation of the appropriately substituted quinoline precursor in the presence of a catalytic amount of Manganese.Type: GrantFiled: October 28, 1992Date of Patent: December 6, 1994Assignee: American Cyanamid CompanyInventors: Nicholas A. Cortese, Jr., Henry L. Strong
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Patent number: 5250542Abstract: 3,4,4-trisubstitutedpiperidinyl-N-alkylcarboxylates and intermediates for their preparation are provided. These piperidine-N-alkylcarboxylates are useful as peripheral opioid antagonists.Type: GrantFiled: July 17, 1992Date of Patent: October 5, 1993Assignee: Eli Lilly and CompanyInventors: Buddy E. Cantrell, Dennis M. Zimmerman
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Patent number: 5231104Abstract: A series of novel 1-(phenethyl) and 1-(2-heteroarylethyl)-3-substituted piperidine derivatives have been prepared, including their pharmaceutically acceptable salts and various novel key intermediates therefor. The 3-substituent present in these compounds is an unsubstituted or substituted diphenylmethoxy group or a diphenylmethoxy-derived group, while the 1-substituent is unsubstituted or substituted phenethyl or 1-(2-heteroarylethyl) wherein the heteroaryl moiety is thienyl, pyridyl or pyrazinyl. These compounds in the form of both their racemates and 3R-isomers, are useful in therapy as smooth muscle muscarinic receptor antagonists and therefore, are of value in the treatment diseases associated with altered motility and/or smooth muscle tone.Type: GrantFiled: February 5, 1992Date of Patent: July 27, 1993Assignee: Pfizer Inc.Inventors: David Alker, Peter E. Cross, Robert M. Wallis
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Patent number: 5008276Abstract: Fungicidal compounds of the formula (I): ##STR1## and stereoisomers thereof, wherein K is oxygen or sulphur; Z is optionally substituted aryl or optionally substituted heteroaryl; X is O, S(O).sub.n, NR.sup.4, CR.sup.1 R.sup.2, CHR.sup.5, CO, CR.sup.1 (OR.sup.2), C.dbd.CR.sup.1 R.sup.2, CHR.sup.1 CHR.sup.2, CR.sup.1 .dbd.CR.sup.2, CHR.sup.1 CR.sup.2 .dbd.CH, C.dbd.C, OCHR.sup.1, CHR.sup.1 O, OCHR.sup.1 O, S(O).sub.n CHR.sup.1, S(O).sub.n CHR.sup.1 O, CHR.sup.1 S(O).sub.n, CHR.sup.1 OSO.sub.2, NR.sup.4 CHR.sup.1, CHR.sup.1 NR.sup.4, CO.sub.2, O.sub.2 C, SO.sub.2 O, OSO.sub.2, CO.CO, COCHR.sup.1, COCHR.sup.1 O, CHR.sup.1 CO, CHOH.CHR.sup.1, CHR.sup.1.CHOH, ##STR2## CONR.sup.4, OCONR.sup.4, NR.sup.4 CO, CSNR.sup.4, OCS.NR.sup.4, SCO.NR.sup.4, NR.sup.4 CO.sub.2, NR.sup.4 CS, NR.sup.4 CSO, NR.sup.4 COS, NR.sup.4 CONR.sup.4, S(O).sub.n NR.sup.4, NR.sup.4 S(O).sub.n, CS.sub.2, S.sub.2 C, CO.S, SCO, N.dbd.N, N.dbd.CR.sup.1, CR.sup.1 .dbd.N, CHR.sup.1 CHR.sup.2 CH(OH), CHR.sup.1 OCO, CHR.sup.1 SCO, CHR.sup.1 NR.sup.Type: GrantFiled: October 17, 1988Date of Patent: April 16, 1991Assignee: Imperial Chemical Industries PLCInventors: John M. Clough, Christopher R. A. Godfrey, Stephen P. Heaney, Kenneth Anderton
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Patent number: 4820839Abstract: Nitrogen-containing heterocyclic esters of the formula I,R.sup.1 -A.sup.1 -Z.sup.1 -A.sup.2 -[Z.sup.2 -A.sup.3 ].sub.m -R.sup.2 Iin which R.sup.1, R.sup.2, A.sup.1, A.sup.2, A.sup.3, Z.sup.1, Z.sup.2 and m have the meaning specified in patent claim 1, are suitable as components of smectic liquid-crystalline phases.Type: GrantFiled: January 23, 1987Date of Patent: April 11, 1989Assignee: Merck Patent Gesellschaft Mit Beschrankter HaftungInventors: Joachim Krause, Andreas Wachtler, Volker Reiffenrath, Bernhard Scheuble, Reinhard Hittich
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Patent number: 4816588Abstract: The present invention provides a novel method for the preparation of pyridine-2,3-dicarboxylic acids by the oxidation of 8-substituted quinolines.Type: GrantFiled: August 19, 1987Date of Patent: March 28, 1989Assignee: American Cyanamid CompanyInventors: William F. Rieker, William A. Daniels
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Patent number: 4782157Abstract: The invention provides an improved process for the preparation of substituted and unsubstituted 2-carbamoyl nicotinic and 3-quinolinecarboxylic acids.Type: GrantFiled: December 3, 1984Date of Patent: November 1, 1988Assignee: American Cyanamid Co.Inventor: John J. Pascavage
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Patent number: 4754039Abstract: Pyridine-2,3-dicarboxylic acid can be prepared by oxidizing quinoline with a chlorate salt in an aqueous acidic medium. The oxidation can be conducted in the presence of cupric ions generated from an acid-soluble cupric compound.Type: GrantFiled: January 30, 1986Date of Patent: June 28, 1988Assignee: Ruetgers-Nease Chemical Co., Inc.Inventor: William Michalowicz
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Patent number: 4736036Abstract: A process is disclosed for the manufacture of quinolinic acid by oxidizing quinoline with ruthenium tetraoxide in the presence of hypochlorite solution in which a certain amount of base is added prior to the inception of the oxidation reaction. The disclosed process provides greatly improved yields of high purity quinolinic acid.Type: GrantFiled: August 8, 1983Date of Patent: April 5, 1988Assignee: Appleton Papers Inc.Inventor: Ponnampalam Mathiaparanam
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Patent number: 4623726Abstract: There is provided a novel process for the preparation of carboxylic acids from alkyl groups under basic conditions utilizing oxides of copper, cobalt and silver.Type: GrantFiled: April 18, 1983Date of Patent: November 18, 1986Assignee: American Cyanamid CompanyInventor: William A. Daniels
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Patent number: 4549024Abstract: A novel process for the preparation of quinolinic acid comprising reacting quinoline in an aqueous acid with hydrogen peroxide in the presence of at least one cation selected from the group consisting of vanadyl V, cobalt III, titanyl IV and osmium VIII cations at 50.degree. to 100.degree. C. and then oxidizing with chlorite or chlorate ions to form quinolinic acid.Type: GrantFiled: November 5, 1984Date of Patent: October 22, 1985Assignee: Rutgerswerke AktiengesellschaftInventors: Winfried Orth, Emmerich Pastorek, Werner Fickert
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Patent number: 4537971Abstract: This invention relates to improved processes for the manufacture of quinolinic acid run with a higher concentration of reactants in the initial step wherein quinoline is oxidized with hydrogen peroxide in an aqueous sulfuric acid solution in the presence of copper sulfate to prepare copper quinolinate, and in subsequent steps converting the copper quinolinate from the initial step to quinolinic acid by treating the copper salt with alkali to form the water soluble alkali salt form of quinolinic acid precipitating the copper as insoluble cupric oxide and thereafter treating the soluble alkali salt form with acid to obtain the quinolinic acid, the improvement whereby the reaction of the initial step is carried out in a thermally controllable and safe manner and the formation of by-products is minimized which comprises in the initial step adding separately either in portion-wise multiple and approximately equal portions or adding continuously and simultaneously over a period of time each of the following, the suType: GrantFiled: September 26, 1983Date of Patent: August 27, 1985Assignee: The Hilton-Davis Chemical Co.Inventors: Robert W. J. Rebhahn, James E. Kassner, Raymond E. Werner
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Patent number: 4504665Abstract: A chloronicotinic acid compound is prepared by hydrolyzing a 3-trichloromethyl pyridine compound in the presence of sulfuric acid or phosphoric acid. By this process, a highly pure chloronicotinic acid compound is obtainable in good yield. This compound is useful as an intermediate for medicines.Type: GrantFiled: April 6, 1983Date of Patent: March 12, 1985Assignee: Ishihara Sangyo Kaisha Ltd.Inventors: Takahiro Haga, Tohru Koyanagi, Toshio Nakajima, Takeshi Ohshima
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Patent number: 4294969Abstract: Novel substituted (3-loweralkylamino-2-R.sub.1 O-propoxy)pyridines, their pharmaceutically acceptable salts, certain intermediates and their preparation are disclosed. These pyridines have pharmaceutically useful properties such as .beta.-adrenergic blocking activity.Type: GrantFiled: July 11, 1980Date of Patent: October 13, 1981Assignee: Merck & Co., Inc.Inventors: John J. Baldwin, Gerald S. Ponticello
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Patent number: 4217457Abstract: A highly selective oxidation process for preparing pyridin-carboxylic acids from pyridine compounds nucleus substituted with alkyl groups, through a carbon-carbon bond, and oxidizable to carboxyl, and from hydrosoluble hexavalent chromium compounds, in the presence of an acid.Particularly described is the oxidation of beta-picoline with sodium bichromate to obtain the sodium salt of nicotinic acid and 99.5% pure free acid, respectively.Type: GrantFiled: July 14, 1978Date of Patent: August 12, 1980Assignee: Luigi Stoppani S.p.A.Inventor: Giovanni Ghelli