The Cyclic Anhydride Has At Least Six Members And Is A Cyclo In A Polycyclo Ring System Patents (Class 549/232)
  • Patent number: 5294646
    Abstract: The invention relates to new N-alkyl-N-(meth)acryloyloxyalkylcarboxamides of aromatic carboxylic acids and aromatic carboxylic acid anhydrides, their preparation and formulations of these compounds for use as adhesives for the treatment of dental hard substance.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: March 15, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Michael Muller, Wolfgang Podszun, Werner Finger, Jens Winkel
  • Patent number: 5278319
    Abstract: An improved process is provided for the production of a partial oxidation product by the vapor phase reaction of a hydrocarbon with substantially pure oxygen in the presence of a suitable catalyst. In the improved process, the partial oxidation product is removed, carbon dioxide and excess carbon monoxide, present in the reactor effluent as by-products, are also removed and the remaining gaseous effluent, comprised mainly of carbon monoxide and unreacted hydrocarbon, is recycled to the reactor. The concentration of carbon monoxide throughout the system is maintained sufficiently high to prevent the formation of a flammable mixture in the reactor or associated equipment.
    Type: Grant
    Filed: April 14, 1992
    Date of Patent: January 11, 1994
    Assignee: The BOC Group, Inc.
    Inventors: Ramakrishnan Ramachandran, Loc Dao, Donald L. MacLean
  • Patent number: 5262548
    Abstract: An improvement in the oxidation catalyst used for the partial oxidation of n-butane and containing vanadium and phosphorus, zinc and lithium mixed oxides which comprises adding a molybdenum compound modifier in an amount of from about 0.005 to 0.025/1 Mo/V to the catalyst during the digestion of the reduced vanadium compound by concentrated phosphoric acid. The addition of Mo produces a catalyst which is very stable more active system and longer lived than the unmodified catalyst.
    Type: Grant
    Filed: August 3, 1992
    Date of Patent: November 16, 1993
    Assignee: Scientific Design Company, Inc.
    Inventor: Bruno J. Barone
  • Patent number: 5254796
    Abstract: The invention relates to an ecologically favorable process for the hydrolytic decomposition of halogen-containing compounds of the formula CX.sub.4 or CHX.sub.3 or mixtures of these compounds, in which X as halogen is chlorine or bromine or a combination thereof, in an aqueous-alkaline medium, which comprises first keeping the aqueous-alkaline reaction mixture comprising the abovementioned halogen-containing compounds at a temperature of between 0.degree. and 1000.degree. C. under the autogenous pressure which is formed in a closed reaction vessel for a period of up to 10 hours and then subjecting the mixture to a heat treatment at a temperature of between 70.degree. and 150.degree. C. under the autogenous pressure which is formed therein, in the presence of sulfite. The process according to the invention is particularly suitable for hydrolytic decomposition of halogen-containing reaction products from aqueous-alkaline hypohalite oxidations.
    Type: Grant
    Filed: June 17, 1992
    Date of Patent: October 19, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Erwin Dietz, Siegfried Schiebler
  • Patent number: 5241081
    Abstract: The invention relates to new N-alkyl-N-(meth)acryloyloxyalkylcarboxamides of aromatic carboxylic acids and aromatic carboxylic acid anhydrides, their preparation and formulations of these compounds for use as adhesives for the treatment of dental hard substance.
    Type: Grant
    Filed: August 9, 1991
    Date of Patent: August 31, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Michael Muller, Wolfgang Podszun, Werner Finger, Jens Winkel
  • Patent number: 5126463
    Abstract: This invention provides a process for the production of an anhydride by the vapor phase reaction of a hydrocarbon with substantially pure oxygen in the presence of a suitable catalyst. In the improved process, the anhydride product is removed, carbon monoxide, present in the reactor effluent as a by-product, is oxidized to carbon dioxide and part of the gaseous effluent, comprised mainly of carbon dioxide and unreacted hydrocarbon, is recycled to the reactor. Removal of carbon monoxide from the recycle stream reduces the hazard of a fire or explosion in the reactor or associated equipment. The use of carbon dioxide as the principal diluent increases heat removal from the reactor, thereby increasing the production capacity of the reactor.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: June 30, 1992
    Assignee: The BOC Group, Inc.
    Inventors: Ramakrishnan Ramachandran, Arthur I. Shirley, Lien-Lung Sheu
  • Patent number: 5098991
    Abstract: A process is disclosed for preparation of anhydrides containing additional carboxylic acid moieties and dianhydrides of disubstituted maleic anhydride compounds wherein the acid anhydrides and dianhydrides retain their alkene character. The resulting alkene compounds are useful as precursors for polyesters, thermally stable polyamide-imides and polyimides which are also disclosed, as well as a process for their preparation.
    Type: Grant
    Filed: January 8, 1990
    Date of Patent: March 24, 1992
    Assignee: Amoco Corporation
    Inventors: Steven J. Behrend, David A. Young, Ellis K. Fields
  • Patent number: 5072003
    Abstract: Compounds are disclosed which are anhydrides containing additional carboxylic acid moieties and dianhydrides of disubstituted maleic anhydride compounds wherein the acid anhydrides and dianhydrides retain their alkene character. These compounds are useful as precursors for polyesters, thermally stable polyamide-imides and polyimides.
    Type: Grant
    Filed: June 11, 1990
    Date of Patent: December 10, 1991
    Assignee: Amoco Corporation
    Inventors: Steven J. Behrend, Ellis K. Fields
  • Patent number: 5049699
    Abstract: Disclosed are 1- and 2-mono esters of citric acid and methods for preparing them in the pure form. These novel compounds are useful as surfactants.
    Type: Grant
    Filed: January 22, 1990
    Date of Patent: September 17, 1991
    Assignee: Haarmanns' Reimer Corp
    Inventor: Michael P. Kotick
  • Patent number: 5023346
    Abstract: Cyclic carbonic acid esters are produced by reaction of hydroxy compounds with phosgene in the presence of a heterocyclic compound containing at least one nitrogen atom as ring member in an aromatic ring.
    Type: Grant
    Filed: November 13, 1989
    Date of Patent: June 11, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Norbert Schon, Hans-Josef Buysch
  • Patent number: 5003085
    Abstract: A process is disclosed for preparation of anhydrides containing additional carboxylic acid moieties and dianhydrides of disubstituted maleic anhydride compounds wherein the acid anhydrides and dianhydrides retain their alkene character. The resulting alkene compounds are useful as precursors for polyesters, thermally stable polyamide-imides and polyimides which are also disclosed, as well as a process for their preparation.
    Type: Grant
    Filed: January 8, 1990
    Date of Patent: March 26, 1991
    Assignee: Amoco Corporation
    Inventors: Steven J. Behrend, David A. Young, Ellis K. Fields
  • Patent number: 4986852
    Abstract: Pigments of the formula I ##STR1## where A is a five- or six-membered aromatic fused or unfused heterocycle which contains one to three hetero atoms from the series consisting of nitrogen and/or oxygen and/or sulfur and which is bonded to the methylene group via a carbon atom, R.sub.1 and R.sub.2 are each hydrogen, alkyl C.sub.1 -C.sub.4, alkylene C.sub.2 or aryl, and together R.sub.1 and R.sub.2 may also be an aliphatic or aromatic ring, R.sub.3 is hydrogen, alkyl C.sub.1 -C.sub.4 hydroxylkyl C.sub.1 -C.sub.3 or alkylene C.sub.2, P is the radical of a polycyclic pigment or a radical of a mix-crystal of polycyclic pigments, and n is a number from 0.0001 to 0.
    Type: Grant
    Filed: December 20, 1988
    Date of Patent: January 22, 1991
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Erwin Dietz, Gustav Kapaun, Michael Kappert, Frank Prokschy, Adolf Kroh, Manfred Urban
  • Patent number: 4883886
    Abstract: A process in which a polymer of a C.sub.2 -C.sub.8 olefin having a number average molecular weight of about 250 and 30,000 undergoes reaction with an unsaturated aliphatic dicarboxylic acid anhydride in two stages in the presence of 5-500 ppm, based on said polymer, of a far and side product suppressing agent to form an alkenyl substituted anhydride, said process having a first stage comprising the following steps: (1) charging to a reaction zone said olefin polymer; (2) heating same to a reaction temperature of about 150.degree. C. to about 300.degree. C.
    Type: Grant
    Filed: January 14, 1988
    Date of Patent: November 28, 1989
    Assignee: Amoco Corporation
    Inventor: Chente Huang
  • Patent number: 4841073
    Abstract: The invention relates to crystalline, stable radical anion salts of derivatives of 1,4,5,8-naphthalenetetracarboxylic acid of the formula ##STR1## in which p1 k, n, s, x, m, p, B, R and c have the meaning given in the description,to processes for their preparation and to their use as electrically conductive compounds.
    Type: Grant
    Filed: November 12, 1986
    Date of Patent: June 20, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Tillmann Hassel, Jurgen Hocker, Gerhard Heywang, Hans-Klaus Muller, Hans G. Fitzky
  • Patent number: 4822878
    Abstract: Novel chromophor derivatives of cyclic anhydrides are provided which have the ability to react with a variety of organic substrates forming adducts which are useful in analytical techniques for the detection and measurement of biological compounds.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: April 18, 1989
    Assignee: Viomedics, Inc.
    Inventor: Spyros Theodoropulos
  • Patent number: 4650879
    Abstract: Process for the preparation of perylene-3,4,9,10-tetracarboxylic dianhydride of high purity and in a very good yield in an ecologically unobjectionable manner, which comprises saponifying perylene-3,4,9,10-tetracarboxylic acid diimide with a 2.5-fold to 6-fold amount by weight of 92.5% to 97.5% strength sulfuric acid at temperatures of 210.degree. to 230.degree. C.
    Type: Grant
    Filed: June 9, 1986
    Date of Patent: March 17, 1987
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ernst Spietschka, Manfred Urban
  • Patent number: 4599431
    Abstract: Process for the preparation of naphthalene-1,4,5,8-tetracarboxylic acid (called "NTC" below) and its 1,8-monoanhydride in a high degree of purity, which comprises dissolving impure NTC or impure NTC-1,8-monoanhydride as the tetra-alkali metal salt of NTC in water in known manner, removing any insoluble impurities present, bringing the clarified solution to a pH value of 4-5 below 45.degree. C., separating off the di-alkali metal salt of NTC which thereby crystallizes out and converting the latter into free NTC or into free NTC-1,8-monoanhydride by treatment with a strong acid at 20.degree. to 100.degree. C.
    Type: Grant
    Filed: July 5, 1984
    Date of Patent: July 8, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Siegfried Schiessler, Ernst Spietschka
  • Patent number: 4591649
    Abstract: A compound which is bondable to tooth substrates, and has the following general formula: ##STR1## wherein: R.sub.1 is a substituted naphthyl group having a ##STR2## group at any one of the 1,2-, 2,3- and 1,8- positions, R.sub.2 is any of the following groups having any one of carboxylate, carbonyl, and --O-- moiety, to be connected to R.sub.1 :a group having the formula --(CH.sub.2).sub.m -- in which m=1-4,a group having the formula --(CH.sub.2).sub.n --COO--(CH.sub.2).sub.p -- in which n.noteq.0, p.noteq.0, and n+p=2-4, ora group having the formula --(CH.sub.2 --CH.sub.2 O).sub.q --CH.sub.2 --CH.sub.2 -- in which q=1 or 2,wherein when said R.sub.1 group is substituted at the 1,2 position, then R.sub.2 is bonded to the naphthyl group at any one of the 4, 5, 6 and 7 positions; when said R.sub.1 group is substituted at the 2,3 position, then R.sub.2 is bonded to the naphthyl group at any one of the 5 and 6 positions; and when said R.sub.1 group is substituted at the 1,8 position, then R.sub.
    Type: Grant
    Filed: March 18, 1985
    Date of Patent: May 27, 1986
    Assignee: G-C Dental Industrial Corp.
    Inventors: Tadashi Hirasawa, Ikuro Harashima
  • Patent number: 4582910
    Abstract: A method for the preparation of 4-halogenonaphthalic acid anhydrides by halogenation of an aqueous solution of an alkali salt of the naphthalic acid with halogen or alkali metal hypohalogenite wherein a solution of the alkali metal salt of the naphthalic acid is treated with a water soluble magnesium salt and at least an equal molar amount of an alkakli metal hydroxide, halogenating this reaction mixture at a temperature in the range of 10.degree. to 25.degree. C. and subsequently acidifying the reaction mixture. In a second embodiment of the invention, an aqueous solution of alkali metal carbonate is used in place of the magnesium salt and alkali metal hydroxide.
    Type: Grant
    Filed: February 19, 1985
    Date of Patent: April 15, 1986
    Assignee: Rutgerswerke Aktiengesellschaft
    Inventors: Winfried Orth, Emmerich Pastorek, Werner Fickert
  • Patent number: 4501906
    Abstract: Perylene-3,4,9,10-tetracarboxylic acid monoanhydride mono-sodium or mono-potassium salts are obtained from neutral salts of perylene-3,4,9,10-tetracarboxylic acid, if necessary in the presence of at least one molar equivalent of sodium or potassium ions, at 20.degree. to 100.degree. C. by adding three molar equivalents of a sufficiently strong acid. The products are dye precursors, especially for asymmetric N-substituted perylenetetracarboxylic acid diimide pigments.
    Type: Grant
    Filed: February 10, 1983
    Date of Patent: February 26, 1985
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ernst Spietschka, Helmut Troster
  • Patent number: 4460410
    Abstract: A perylene-3,4,9,10-tetracarboxylic acid dianhydride pigment, useful as a varnish pigment, made by adding an aqueous solution of an alkali metal salt of perylene-3,4,9,10-tetracarboxylic acid and a surfactant to an acid at a pH below 3, at 0.degree. C. to 90.degree. C., and then heating the suspension so obtained at 50.degree. C. to 150.degree. C.
    Type: Grant
    Filed: December 21, 1982
    Date of Patent: July 17, 1984
    Assignee: Hoechst AG
    Inventors: Ernst Spietschka, Manfred Urban
  • Patent number: 4433157
    Abstract: A process for manufacturing an alkenyl dicarboxylic acid, anhydride comprises reacting at least one halogenated polyolefin with at least one unsaturated dicarboxylic acid anhydride in substantially stoichiometrical proportion, in the presence of a minor proportion of at least one organic compound containing at least one double bond bearing at least one electron attracting substituent.
    Type: Grant
    Filed: May 11, 1982
    Date of Patent: February 21, 1984
    Assignee: Institut Francais du Petrole
    Inventors: Jerome Weill, Jacques Garapon, Bernard Sillion
  • Patent number: 4371694
    Abstract: Compounds of Formula I or Formula II ##STR1## where A is an electron withdrawing group and B is a secondary or tertiary amino group or the group OD where D is H, aryl or an aliphatic group are made by reacting a corresponding compound of Formula Ia or Formula IIa ##STR2## in a solvent with a reagent selected from organic primary and secondary amines and compounds of the formula MOD where M is an alkali metal and A and D are as defined above. In this process the nitro group and the group B in Formula I and Ia are in the 2- or 4- position and the compounds of Formula I, Ia, II and IIa may optionally be further substituted. Preferably a primary or secondary amine is reacted with a compound of formula Ia, preferably using dimethylformamide as solvent. The process can result in the production of novel compounds, including (1) Compounds of Formula III wherein each group A is CO.sub.
    Type: Grant
    Filed: July 1, 1980
    Date of Patent: February 1, 1983
    Assignee: Brent Chemicals International Limited
    Inventors: Michael S. Alexiou, Philip I. Brittain, John H. P. Tyman
  • Patent number: 4358582
    Abstract: Novel polyimides and molding compositions are prepared from novel tricyclo[4.2.1.0.sup.2,5 ] nonane-3,4 dimethyl-3,4,7,8-tetracarboxylic acid dianhydride. The dianhydride is useful for the manufacture of polyimides which are useful as engineering plastics.
    Type: Grant
    Filed: August 19, 1981
    Date of Patent: November 9, 1982
    Assignee: Standard Oil Company (Indiana)
    Inventors: Tayseer S. Nimry, Ellis K. Fields
  • Patent number: 4337341
    Abstract: 4a-phenyl and substituted phenyl 2,3,4,4a,5,6,7,7a-octahydro-1H-2-pyrindines having a 2-substituent are disclosed. Such compounds are useful as analgesic agents having mixed agonist and antagonist properties. The compounds can be prepared by reacting an amine with a 4-aryl-2,6-dioxocyclopenta[c]pyran, followed by reduction, or alternatively by alkylating a 4a-aryl-octahydro-1H-2-pyrindine at the 2-position.
    Type: Grant
    Filed: February 2, 1981
    Date of Patent: June 29, 1982
    Assignee: Eli Lilly and Company
    Inventor: Dennis M. Zimmerman