Epoxidizing Unsaturated Fat Or Fatty Oil, Or Unsaturated Derivative Thereof Patents (Class 549/527)
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Patent number: 11560460Abstract: The present invention relates to a plasticizer composition, a resin composition, and a method of preparing the plasticizer composition. The plasticizer composition comprising an isophthalate-based material; and an epoxy-based alkyl ester compound represented by Chemical Formula 1.Type: GrantFiled: July 22, 2016Date of Patent: January 24, 2023Assignee: LG CHEM, LTD.Inventors: Hyun Kyu Kim, Mi Yeon Lee, Jeong Ju Moon, Joo Ho Kim, Seok Ho Jeong
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Patent number: 9546143Abstract: A method for preparing a high-quality epoxidized fatty acid ester with a micro-reaction device, including: respectively pumping an aqueous hydrogen peroxide solution and a carboxylic acid at the same time into a first micro-mixer; after the reaction in the first micro-reactor, respectively pumping the output material and an unsaturated fatty acid ester into a second micro-mixer; completely mixing them and then introducing the mixture into a second micro-reactor; and after a complete reaction, water-rinsing the organic phase part of the resultant reaction liquid and drying the same to obtain the epoxidized fatty acid ester.Type: GrantFiled: July 1, 2016Date of Patent: January 17, 2017Assignee: NANJING TECH UNIVERSITYInventors: Kai Guo, Zheng Fang, Xin Li, Ning Zhu, Li Wan, Wei He, Kai Zhang, Pingkai Ouyang
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Patent number: 7932409Abstract: A process for producing oleochemical polyols comprises the steps of epoxidizing unsaturated oil using an organic acid together with oxygenated water or a per-acid to obtain epoxidized oil; washing the epoxidized oil with salt water to remove unused organic acid together with oxygenated water or a per-acid; neutralizing acidic condition of the washed epoxidized oil with a base; washing the neutralized epoxidized oil with a salt solution until the pH of the neutralized epoxidized oil reaching 6.5 to 7.5 to removed the base residue; drying the washed neutralized epoxidized oil under vacuum; and reacting the washed neutralized dried epoxidized oil with polyhydric alcohol in the presence of boron trifluoride-diethylether complex to produce the oleochemical polyols. The oleochemical polyols are then subjected to the same washing, neutralizing, washing and drying process as in preparing the washed neutralized dried epoxidized oil.Type: GrantFiled: March 28, 2008Date of Patent: April 26, 2011Assignee: Malaysian Palm Oil BoardInventors: Hazimah Abu Hassan, Tuan Noor Maznee Tuan Ismail, Mohd Norhisham Sattar, Seng Soi Hoong, Tian Lye Ooi, Salmiah Ahmad, Kosheela Devi a/p Poo Palam, Mei Yee Cheong
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Patent number: 7291621Abstract: Substituted biaryl amides of Formula I are provided. Such compounds are ligands that may be used to modulate C5a receptor activity in vivo or in vitro, and are particularly useful in the treatment of conditions associated with pathological C5a receptor activation in humans, domesticated companion animals and livestock animals.Type: GrantFiled: January 3, 2006Date of Patent: November 6, 2007Assignee: Neurogen CorporationInventors: Yang Gao, Andrew Thrukauf, He Zhao
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Patent number: 6740763Abstract: A method of epoxidizing an unsaturated compound having a carbon-to-carbon double bond to form an oxirane ring across the double bond comprising adding to said unsaturated compound (a) an organic acid capable of being oxidized to form a peracid; (b) an oxidizing agent selected from hydrogen peroxide or acetaldehyde monoperacetate, or a combination thereof; and (c) with or without an acid catalyst selected from a mineral acid or styrene sulfonic acid, or a combination thereof to form a reactant mixture; and forming the reactant mixture in a film against a wall of a thin-film reactor that is at a temperature sufficient to form a peracid from the organic acid, and contacting the film of reactant mixture against the film reactor wall for a time sufficient for reaction of a portion of the peracid with the unsaturated compound to form an oxirane ring across a double bond of the unsaturated compound. In another embodiment, preformed peracid and unsaturated compound are added directly to the thin-film reactor.Type: GrantFiled: June 27, 2003Date of Patent: May 25, 2004Assignee: The C.P. Hall CompanyInventors: James A. Nowak, Thomas A. Zillner, Leslie Patrick Mullin, III
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Patent number: 6734315Abstract: A method of epoxidizing an unsaturated compound having a carbon-to-carbon double bond to form an oxirane ring across the double bond comprising adding to said unsaturated compound an oxidizing agent selected from hydrogen peroxide, acetaldehyde monoperacetate, an organic hydroperoxide, or a combination thereof, to form a reactant mixture; and forming the reactant mixture in a film against a wall of the thin-film reactor that is at a temperature sufficient for reaction of the oxidizing agent with the unsaturated compound to form an oxirane ring across a double bond of the unsaturated compound.Type: GrantFiled: June 27, 2003Date of Patent: May 11, 2004Assignee: The C.P. Hall CompanyInventors: James A. Nowak, Thomas A. Zillner, Leslie Patrick Mullin, III
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Patent number: 6448418Abstract: A process is provided for the epoxidation of olefins with percarboxylic acid in a reaction mixture consisting of an aqueous phase and an organic phase, the percarboxylic acid being formed in situ in the aqueous phase from hydrogen peroxide and a carboxylic acid or a carboxylic anhydride, and the olefins being dissolved in an organic solvent in the organic phase, wherein the epoxidation is carried out in several steps, each step being carried out with a fresh aqueous phase and the aqueous phase being separated off after each step.Type: GrantFiled: April 25, 2001Date of Patent: September 10, 2002Assignee: BASF AktiengesellschaftInventor: Christian Ott
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Patent number: 5650412Abstract: Compounds of formula ##STR1## are HIV protease inhibitors. These compounds are useful in the prevention or treatment of infection by HIV and in the treatment of AIDS, either as compounds, pharmaceutically acceptable salts, pharmaceutical composition ingredients, whether or not in combination with other antivirals, immunomodulators, antibiotics or vaccines. Methods of treating AIDS and methods of preventing or treating infection by HIV are also described.Type: GrantFiled: October 26, 1995Date of Patent: July 22, 1997Assignee: Merck & Co., Inc.Inventors: Byeong Moon Kim, Joseph P. Vacca
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Patent number: 4978395Abstract: Polyaddition product the molecule of which is characterized by the presence of one group ##STR1## Method to prepare the above mentioned product and dispersions in polar and non polar diluents which contain the said product in addition with solid organic or inorganic particles.Type: GrantFiled: February 3, 1989Date of Patent: December 18, 1990Inventor: Giuseppe Canestri
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Patent number: 4855465Abstract: Aliphatic epoxides of the formula: ##STR1## can be prepared in a technically efficient manner from the corresponding olefins by means of perpropionic acid in a benzene solution. The benzene solution can also be 1.5 weight percent of hydrogen peroxide, 1.5 weight percent of water and about 800 ppm of mineral acid.Type: GrantFiled: March 2, 1988Date of Patent: August 8, 1989Assignee: Degussa AktiengesellschaftInventors: Andreas Grund, Guenter Prescher, Georg Boehme, Willi Hofen, Heinrich Petsch
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Patent number: 4851556Abstract: Epoxidized polybutadienes with an average molecular weight of 500 to 100,000 and a certain content of epoxide oxygen were prepared from the corresponding polybutadienes with use of perpropionic acid in a benzene solution. The solution can also be employed in unpurified form with maximum contents of 1.5 weight percent hydrogen peroxide 1.5 weight percent of water, and about 800 ppm of mineral acid.Type: GrantFiled: March 2, 1988Date of Patent: July 25, 1989Assignee: Degussa AktiengesellschaftInventors: Rainer Siegmeier, Andreas Grund, Guenter Prescher, Udo Brandt
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Patent number: 4584390Abstract: In a multistage process for the continuous epoxidation of double bonds of terminal and non-terminal olefins containing more than 12 carbon atoms, unsaturated higher fatty acids and their lower alkanol and lower alkanediol esters and also unsaturated fatty alcohols containing from 8 to 18, preferably 18, carbon atoms and triglycerides of higher fatty acids including unsaturated fatty acids, preferably soyabean oil, using performic acid formed in situ from hydrogen peroxide and formic acid, the reactants, olefin and hydrogen peroxide/formic acid, are passed at ambient pressure in cross-counter flow through an at least three-stage reaction cascade. The olefinic phase is introduced into the first reaction stage, the hydrogen peroxide and the formic acid are introduced in separate streams into the penultimate reaction stage and the olefin phase and the hydrogen peroxide/formic acid phase (acid water phase) are separated from one another in a phase separator after each reaction stage.Type: GrantFiled: May 30, 1984Date of Patent: April 22, 1986Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Gerhard Dieckelmann, Klemens Eckwert, Lutz Jeromin, Eberhard Peukert, Udo Steinberner
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Patent number: 4423239Abstract: In a method for purifying a crude epoxidation product of a liquid conjugated diolefin polymer or a vegetable oil which comprises the steps of adding an aqueous washing agent to a crude epoxidation product which is obtained by the reaction of a liquid conjugated diolefin polymer or a vegetable oil with an organic peracid or an epoxidizing agent capable of generating an organic peracid in situ, stirring the mixture, leaving the mixture to stand to induce phase separation and thereafter withdrawing the organic layer, the improvement wherein 50 to 300 parts by weight, per 100 parts by weight of the crude epoxidation product, of a 10-80% by weight aqueous solution of isopropanol is used as the washing agent.Type: GrantFiled: September 28, 1982Date of Patent: December 27, 1983Assignee: Nippon Petrochemicals Company, LimitedInventors: Kazuo Miyazaki, Hajime Hara, Kojiro Teramoto, Hideo Horii, Humiaki Oshimi, Yoshihiko Araki