One Of The Rings And A Benzene Ring Are Bonded Directly To The Same Nitrogen (e.g., Triphenylrosaniline, Etc.) Patents (Class 552/110)
  • Patent number: 6533826
    Abstract: Process for preparing aqueous solutions of cationic di- and triarylmethane dyes by the aqueous dye solution, which contains organic solvents, being concentrated by nanofiltration and optionally diluted with water.
    Type: Grant
    Filed: February 8, 2001
    Date of Patent: March 18, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Gessner, Gunter-Rudolf Schröder, Robert Reinhardt
  • Patent number: 5792879
    Abstract: A process for preparing di- or triarylmethane dyes by oxidation of di- or triarylmethanes in the presence of a diluent and of an oxygen transfer catalyst that contains a complexed heavy metal ion comprises using as oxidizing agent hydrogen peroxide, a hydrogen peroxide donor compound, an organic hydroperoxide or a percarboxylic acid and as the oxygen transfer catalyst a member of the class of the porphyrins, tetraaza?14!annulenes, phthalocyanines or tetraazacyclotetradecanes.
    Type: Grant
    Filed: May 28, 1997
    Date of Patent: August 11, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Gessner, Udo Mayer
  • Patent number: 5707747
    Abstract: The present invention provides novel amine compounds useful as electron-transporting materials to be incorporated in organic electro-luminescence devices. More particularly, the present invention provides an organic electro-luminescence device (organic EL device) which can find wide application in various display units, requires a low applied voltage and exhibits a high luminance and an excellent stability.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: January 13, 1998
    Assignees: Hodogaya Chemical Co., Ltd., Matsushita Electric Industrial Co., Ltd.
    Inventors: Hiromitsu Tomiyama, Masahiko Oshino, Ikuko Ihara, Naoko Nakanishi, Mutsumi Suzuki, Masao Fukuyama, Mutsuaki Murakami, Taro Nambu
  • Patent number: 5659053
    Abstract: A process for preparing di- or triarylmethane dyes by oxidation of di- or triarylmethanes in the presence of a diluent and of an oxygen transfer catalyst that contains a complexed heavy metal ion comprises using as oxidizing agent hydrogen peroxide, a hydrogen peroxide donor compound, an organic hydroperoxide or a percarboxylic acid and as the oxygen transfer catalyst a member of the class of the porphyrins, tetraaza[14]annulenes, phthalocyanines or tetraazacyclotetradecanes.
    Type: Grant
    Filed: March 13, 1996
    Date of Patent: August 19, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Gessner, Udo Mayer
  • Patent number: 5639914
    Abstract: The present invention provides novel amine compounds useful as electron-transporting materials to be incorporated in organic electro-luminescence devices. More particularly, the present invention provides an organic electro-luminescence device (organic EL device) which can find wide application in various display units, requires a low applied voltage and exhibits a high luminance and an excellent stability.
    Type: Grant
    Filed: November 1, 1994
    Date of Patent: June 17, 1997
    Assignees: Hodogaya Chemical Co., Ltd., Matsushita Electric Industrial Co., Ltd.
    Inventors: Hiromitsu Tomiyama, Masahiko Oshino, Ikuko Ihara, Naoko Nakanishi
  • Patent number: 5593491
    Abstract: A method or preparing triarylmethane dyes and pigments is disclosed. An amino-substituted triarylmethane compound is reacted with a primary or secondary aromatic amine in solvent using an acid catalyst until a composition having a desired hue is obtained. This composition is then vacuum distilled to remove the solvent and any unreacted aromatic amine, yielding a molten composition having a temperature of at least 165.degree. C. The molten composition is then cooled under conditions such that a temperature of at least 165.degree. C. is maintained for at least 1 hour. A group IA or group II metal hydroxide is added to the composition after the desired hue has been reached, either before, during, or after the vacuum distillation.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: January 14, 1997
    Assignee: BASF Corporation
    Inventor: Leigh Ann Karnell
  • Patent number: 5347022
    Abstract: A process for preparing di- or triarylmethane dyes by oxidation of di- or triarylmethanes in the presence of a diluent and of an oxygen transfer catalyst that contains a complexed heavy metal ion or of a catalyst based on molybdenic acid and vanadium compounds comprises using as oxidizing agent peroxomonosulfuric acid or a salt thereof.
    Type: Grant
    Filed: March 29, 1993
    Date of Patent: September 13, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Gessner, Udo Mayer
  • Patent number: 5310887
    Abstract: As aqueous ink composition is provided having up to 5 wt. % of a colorant of the formula:A--{Y--X--C(O)--R.sub.1 --C(O)O.sup.- }.sub.pwhere A is an organic chromophore; Y is a polyoxyalkylene substituent; X is a radical of a reactive hydroxy, amino or thio group; and R.sub.1 is C.sub.2-30, substituted or unsubstituted alkylene, alkenylene, or phenylenealkylene. A counter ion selected from alkaline metal ions, alkaline earth metal ions, ammonium ions, amine salts, and zinc ammonium complexes is present in approximately stoichiometric proportion or greater relative to the colorant in the ink composition.
    Type: Grant
    Filed: December 1, 1992
    Date of Patent: May 10, 1994
    Assignee: Milliken Research Corporation
    Inventors: Patrick D. Moore, Clifford R. King, Raj Batlaw
  • Patent number: 5273906
    Abstract: The present invention provides novel dyes for staining proteins, particularly those in electrophoretic gels. The dyes of the invention are derivatives of Coomassie.RTM. dyes. The invention also provides quantitative and qualitative methods for detecting proteins by staining the proteins with a dye of the invention.
    Type: Grant
    Filed: July 20, 1992
    Date of Patent: December 28, 1993
    Assignee: Promega Corporation
    Inventors: John W. Shultz, David L. Leland
  • Patent number: 5199985
    Abstract: The invention relates to readily dispersible pigment preparations having good tinctorial strength based on an arylpararosanilinesulfonic acid pigment of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 independently of one another are hydrogen, chlorine or bromine or an alkyl or alkoxy group, each having 1 to 3 carbon atoms, and at least one liquid alcohol having a chain length of C.sub.8 to C.sub.20, preferably C.sub.10 -C.sub.15, which has been modified with 2 to 8 mol, preferably 3-6 mol, of propylene oxide and with 1-14 mol, preferably 3-10 mol, of ethylene oxide.The invention furthermore relates to a process for the preparation of these pigment preparations and their use, in particular in printing inks, copying papers or typewriter ribbons.
    Type: Grant
    Filed: November 12, 1991
    Date of Patent: April 6, 1993
    Assignee: Hoechst AG
    Inventors: Manfred Schneider, Rainer Schunck
  • Patent number: 5189188
    Abstract: Compounds of the general formula ##STR1## in which the symbols have the meaning given in the description, are highly suitable as color formers in recording materials based on acid developers. They give deep blue, green-blue, green, violet or red shades which have excellent sublimation and light fastness.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: February 23, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventor: Udo Eckstein
  • Patent number: 5132439
    Abstract: The present invention provides novel dyes for staining protein, particularly those in elecrophoretic gels. The dyes of the invention are derivatives of Coomassie.RTM. dyes. The invention also provides quantitative and qualitative methods for detecting proteins which comprise staining the proteins with a dye of the invention.
    Type: Grant
    Filed: November 19, 1990
    Date of Patent: July 21, 1992
    Assignee: Promega Corporation
    Inventors: John W. Schultz, David L. Leland
  • Patent number: 5013857
    Abstract: Process for the preparation of sulpho-free triphenylmethane dyestuffs of the formula ##STR1## in which R.sup.1 -R.sup.3 denote hydrogen, C.sub.1 -C.sub.6 -alkyl, preferably methyl, or halogen, preferably chlorine,Y denotes hydrogen or NX.sup.5 X.sup.6,X.sup.1 -X.sup.6 denote hydrogen, C.sub.1 -C.sub.6 -alkyl, preferably methyl, ethyl, benzyl or phenyl andZ.sup.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: May 7, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Horst Berneth, Roderich Raue
  • Patent number: 5011955
    Abstract: Synthetic procedures to tetraalkyls, tetraacids and dianhydrides substituted 1,1,1-triaryl-2,2,2-trifluoroethanes which comprises: (1) 1,1-bis(dialkylaryl)-1-aryl-2,2,2-trifluoroethane, (2) 1,1-bis(dicarboxyaryl)-1-aryl-2,2,2-trifluoroethane or (3) cyclic dianhydride or diamine of 1,1-bis(dialkylaryl)-1-aryl-2,2,2-trifluoroethanes. The synthesis of (1) is accomplished by the condensation reaction of an aryltrifluoromethyl ketone with a dialkylaryl compound. The synthesis of (2) is accomplished by oxidation of (1). The synthesis dianhydride of (3) is accomplished by the conversion of (2) to its corresponding cyclic dianhydride. The synthesis of the diamine is accomplished by the similar reaction of an aryltrifluoromethyl ketone with aniline or alkyl substituted or disubstituted anilines. Also, other derivatives of the above are formed by nucleophilic displacement reactions.
    Type: Grant
    Filed: October 10, 1989
    Date of Patent: April 30, 1991
    Inventors: William B. Alston, Roy F. Gratz
  • Patent number: 4897223
    Abstract: Color-forming agents of the general formula ##STR1## wherein X denotes hydroxyl, alkoxy, alkenyloxy, aralkoxy, cycloalkoxy, aryloxy, acyloxy, alkoxycarbonyloxy, alkylamino, dialkylamino, acylamino, aralkylamino or arylamino,Q denotes cyano, alkoxycarbonyl, aryloxycarbonyl, aralkoxycarbonyl, carbamoyl, N-alkylcarbamoyl, N,N-dialkylcarbamoyl, N-alkyl-N-aryl-carbamoyl, acyl, alkoxysulphonyl, aralkoxysulphonyl, sulphamoyl, N-alkylsulphamoyl, N,N-dialkylsulphamoyl, alkylsulphonyl, arylsulphonyl or aralkylsulphonyl andR denotes alkyl, alkenyl or aralkyl,further isocyclic or heterocyclic rings can be fused on to the rings A, B, C and D, and the cyclic and acyclic radicals and the rings A, B, C and D can carry further substituents, are used for the preparation of pressure-sensitive recording materials.
    Type: Grant
    Filed: March 1, 1988
    Date of Patent: January 30, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Udo Eckstein, Hubertus Psaar, Roderich Raue