One Of The Rings And A Benzene Ring Are Bonded Directly To The Same Nitrogen (e.g., Triphenylrosaniline, Etc.) Patents (Class 552/110)
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Patent number: 6533826Abstract: Process for preparing aqueous solutions of cationic di- and triarylmethane dyes by the aqueous dye solution, which contains organic solvents, being concentrated by nanofiltration and optionally diluted with water.Type: GrantFiled: February 8, 2001Date of Patent: March 18, 2003Assignee: BASF AktiengesellschaftInventors: Thomas Gessner, Gunter-Rudolf Schröder, Robert Reinhardt
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Patent number: 5792879Abstract: A process for preparing di- or triarylmethane dyes by oxidation of di- or triarylmethanes in the presence of a diluent and of an oxygen transfer catalyst that contains a complexed heavy metal ion comprises using as oxidizing agent hydrogen peroxide, a hydrogen peroxide donor compound, an organic hydroperoxide or a percarboxylic acid and as the oxygen transfer catalyst a member of the class of the porphyrins, tetraaza?14!annulenes, phthalocyanines or tetraazacyclotetradecanes.Type: GrantFiled: May 28, 1997Date of Patent: August 11, 1998Assignee: BASF AktiengesellschaftInventors: Thomas Gessner, Udo Mayer
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Patent number: 5707747Abstract: The present invention provides novel amine compounds useful as electron-transporting materials to be incorporated in organic electro-luminescence devices. More particularly, the present invention provides an organic electro-luminescence device (organic EL device) which can find wide application in various display units, requires a low applied voltage and exhibits a high luminance and an excellent stability.Type: GrantFiled: October 25, 1996Date of Patent: January 13, 1998Assignees: Hodogaya Chemical Co., Ltd., Matsushita Electric Industrial Co., Ltd.Inventors: Hiromitsu Tomiyama, Masahiko Oshino, Ikuko Ihara, Naoko Nakanishi, Mutsumi Suzuki, Masao Fukuyama, Mutsuaki Murakami, Taro Nambu
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Patent number: 5659053Abstract: A process for preparing di- or triarylmethane dyes by oxidation of di- or triarylmethanes in the presence of a diluent and of an oxygen transfer catalyst that contains a complexed heavy metal ion comprises using as oxidizing agent hydrogen peroxide, a hydrogen peroxide donor compound, an organic hydroperoxide or a percarboxylic acid and as the oxygen transfer catalyst a member of the class of the porphyrins, tetraaza[14]annulenes, phthalocyanines or tetraazacyclotetradecanes.Type: GrantFiled: March 13, 1996Date of Patent: August 19, 1997Assignee: BASF AktiengesellschaftInventors: Thomas Gessner, Udo Mayer
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Patent number: 5639914Abstract: The present invention provides novel amine compounds useful as electron-transporting materials to be incorporated in organic electro-luminescence devices. More particularly, the present invention provides an organic electro-luminescence device (organic EL device) which can find wide application in various display units, requires a low applied voltage and exhibits a high luminance and an excellent stability.Type: GrantFiled: November 1, 1994Date of Patent: June 17, 1997Assignees: Hodogaya Chemical Co., Ltd., Matsushita Electric Industrial Co., Ltd.Inventors: Hiromitsu Tomiyama, Masahiko Oshino, Ikuko Ihara, Naoko Nakanishi
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Patent number: 5593491Abstract: A method or preparing triarylmethane dyes and pigments is disclosed. An amino-substituted triarylmethane compound is reacted with a primary or secondary aromatic amine in solvent using an acid catalyst until a composition having a desired hue is obtained. This composition is then vacuum distilled to remove the solvent and any unreacted aromatic amine, yielding a molten composition having a temperature of at least 165.degree. C. The molten composition is then cooled under conditions such that a temperature of at least 165.degree. C. is maintained for at least 1 hour. A group IA or group II metal hydroxide is added to the composition after the desired hue has been reached, either before, during, or after the vacuum distillation.Type: GrantFiled: December 22, 1994Date of Patent: January 14, 1997Assignee: BASF CorporationInventor: Leigh Ann Karnell
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Patent number: 5347022Abstract: A process for preparing di- or triarylmethane dyes by oxidation of di- or triarylmethanes in the presence of a diluent and of an oxygen transfer catalyst that contains a complexed heavy metal ion or of a catalyst based on molybdenic acid and vanadium compounds comprises using as oxidizing agent peroxomonosulfuric acid or a salt thereof.Type: GrantFiled: March 29, 1993Date of Patent: September 13, 1994Assignee: BASF AktiengesellschaftInventors: Thomas Gessner, Udo Mayer
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Patent number: 5310887Abstract: As aqueous ink composition is provided having up to 5 wt. % of a colorant of the formula:A--{Y--X--C(O)--R.sub.1 --C(O)O.sup.- }.sub.pwhere A is an organic chromophore; Y is a polyoxyalkylene substituent; X is a radical of a reactive hydroxy, amino or thio group; and R.sub.1 is C.sub.2-30, substituted or unsubstituted alkylene, alkenylene, or phenylenealkylene. A counter ion selected from alkaline metal ions, alkaline earth metal ions, ammonium ions, amine salts, and zinc ammonium complexes is present in approximately stoichiometric proportion or greater relative to the colorant in the ink composition.Type: GrantFiled: December 1, 1992Date of Patent: May 10, 1994Assignee: Milliken Research CorporationInventors: Patrick D. Moore, Clifford R. King, Raj Batlaw
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Patent number: 5273906Abstract: The present invention provides novel dyes for staining proteins, particularly those in electrophoretic gels. The dyes of the invention are derivatives of Coomassie.RTM. dyes. The invention also provides quantitative and qualitative methods for detecting proteins by staining the proteins with a dye of the invention.Type: GrantFiled: July 20, 1992Date of Patent: December 28, 1993Assignee: Promega CorporationInventors: John W. Shultz, David L. Leland
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Patent number: 5199985Abstract: The invention relates to readily dispersible pigment preparations having good tinctorial strength based on an arylpararosanilinesulfonic acid pigment of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 independently of one another are hydrogen, chlorine or bromine or an alkyl or alkoxy group, each having 1 to 3 carbon atoms, and at least one liquid alcohol having a chain length of C.sub.8 to C.sub.20, preferably C.sub.10 -C.sub.15, which has been modified with 2 to 8 mol, preferably 3-6 mol, of propylene oxide and with 1-14 mol, preferably 3-10 mol, of ethylene oxide.The invention furthermore relates to a process for the preparation of these pigment preparations and their use, in particular in printing inks, copying papers or typewriter ribbons.Type: GrantFiled: November 12, 1991Date of Patent: April 6, 1993Assignee: Hoechst AGInventors: Manfred Schneider, Rainer Schunck
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Patent number: 5189188Abstract: Compounds of the general formula ##STR1## in which the symbols have the meaning given in the description, are highly suitable as color formers in recording materials based on acid developers. They give deep blue, green-blue, green, violet or red shades which have excellent sublimation and light fastness.Type: GrantFiled: October 31, 1990Date of Patent: February 23, 1993Assignee: Bayer AktiengesellschaftInventor: Udo Eckstein
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Patent number: 5132439Abstract: The present invention provides novel dyes for staining protein, particularly those in elecrophoretic gels. The dyes of the invention are derivatives of Coomassie.RTM. dyes. The invention also provides quantitative and qualitative methods for detecting proteins which comprise staining the proteins with a dye of the invention.Type: GrantFiled: November 19, 1990Date of Patent: July 21, 1992Assignee: Promega CorporationInventors: John W. Schultz, David L. Leland
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Patent number: 5013857Abstract: Process for the preparation of sulpho-free triphenylmethane dyestuffs of the formula ##STR1## in which R.sup.1 -R.sup.3 denote hydrogen, C.sub.1 -C.sub.6 -alkyl, preferably methyl, or halogen, preferably chlorine,Y denotes hydrogen or NX.sup.5 X.sup.6,X.sup.1 -X.sup.6 denote hydrogen, C.sub.1 -C.sub.6 -alkyl, preferably methyl, ethyl, benzyl or phenyl andZ.sup.Type: GrantFiled: December 11, 1989Date of Patent: May 7, 1991Assignee: Bayer AktiengesellschaftInventors: Horst Berneth, Roderich Raue
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Patent number: 5011955Abstract: Synthetic procedures to tetraalkyls, tetraacids and dianhydrides substituted 1,1,1-triaryl-2,2,2-trifluoroethanes which comprises: (1) 1,1-bis(dialkylaryl)-1-aryl-2,2,2-trifluoroethane, (2) 1,1-bis(dicarboxyaryl)-1-aryl-2,2,2-trifluoroethane or (3) cyclic dianhydride or diamine of 1,1-bis(dialkylaryl)-1-aryl-2,2,2-trifluoroethanes. The synthesis of (1) is accomplished by the condensation reaction of an aryltrifluoromethyl ketone with a dialkylaryl compound. The synthesis of (2) is accomplished by oxidation of (1). The synthesis dianhydride of (3) is accomplished by the conversion of (2) to its corresponding cyclic dianhydride. The synthesis of the diamine is accomplished by the similar reaction of an aryltrifluoromethyl ketone with aniline or alkyl substituted or disubstituted anilines. Also, other derivatives of the above are formed by nucleophilic displacement reactions.Type: GrantFiled: October 10, 1989Date of Patent: April 30, 1991Inventors: William B. Alston, Roy F. Gratz
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Patent number: 4897223Abstract: Color-forming agents of the general formula ##STR1## wherein X denotes hydroxyl, alkoxy, alkenyloxy, aralkoxy, cycloalkoxy, aryloxy, acyloxy, alkoxycarbonyloxy, alkylamino, dialkylamino, acylamino, aralkylamino or arylamino,Q denotes cyano, alkoxycarbonyl, aryloxycarbonyl, aralkoxycarbonyl, carbamoyl, N-alkylcarbamoyl, N,N-dialkylcarbamoyl, N-alkyl-N-aryl-carbamoyl, acyl, alkoxysulphonyl, aralkoxysulphonyl, sulphamoyl, N-alkylsulphamoyl, N,N-dialkylsulphamoyl, alkylsulphonyl, arylsulphonyl or aralkylsulphonyl andR denotes alkyl, alkenyl or aralkyl,further isocyclic or heterocyclic rings can be fused on to the rings A, B, C and D, and the cyclic and acyclic radicals and the rings A, B, C and D can carry further substituents, are used for the preparation of pressure-sensitive recording materials.Type: GrantFiled: March 1, 1988Date of Patent: January 30, 1990Assignee: Bayer AktiengesellschaftInventors: Udo Eckstein, Hubertus Psaar, Roderich Raue