Abstract: A method for producing a vegetable oil-derived polyol having increased hydroxyl functionality by reacting a vegetable oil with an oxidizing agent in the presence of an organometallic catalyst is provided. The resulting higher functionality polyols derived from vegetable oil produced by the process are also provided. Also provided is a method for decreasing the acid value of a vegetable oil-derived polyol by reacting the vegetable oil-derived polyol with an epoxide component in the presence of a Lewis base catalyst. Urethane products produced using higher functional vegetable oil-derived polyols and/or lower acid vegetable oil-derived polyols are also provided.
Type:
Grant
Filed:
March 3, 2006
Date of Patent:
August 2, 2011
Assignee:
South Dakota Soybean Processors, LLC
Inventors:
Eric J. Geiger, Nicole M. Becker, Lawrence A. Armbruster
Abstract: A method for partially refining a crude vegetable oil utilizing physical refining techniques is described. The crude vegetable oil is first degummed by either (1) allowing the crude oil to settle over a period of time, such as twenty days, so that the oil becomes stratified into at least two layers, wherein one layer comprises gums with low oil content and a second layer comprises oil containing only a fraction of the gums originally present and then separating the oil layer from the gum layer, or (2) heating the crude oil to a temperature of about 270-300° F. with agitation and then allowing the crude oil to settle for a period of time until the oil becomes stratified into the at least two layers. The degummed oil is then aerated and agitated while being maintained at a temperature of 170-180° F. for a time period sufficient to obtain a desired oil viscosity. The resulting partially refined oil is suitable for use in industrial applications such as the preparation of urethane foams.
Type:
Grant
Filed:
April 29, 2004
Date of Patent:
August 28, 2007
Assignee:
South Dakota Soybean Processors
Inventors:
Rodney Christianson, Michael Noble, Andrew Rourke, Eric Geiger, Larry Mahlum
Abstract: A method for partially refining a crude vegetable oil utilizing physical refining techniques is described. The crude vegetable oil is first degummed by either (1) allowing the crude oil to settle over a period of time, such as twenty days, so that the oil becomes stratified into at least two layers, wherein one layer comprises gums with low oil content and a second layer comprises oil containing only a fraction of the gums originally present and then separating the oil layer from the gum layer, or (2) heating the crude oil to a temperature of about 270-300° F. with agitation and then allowing the crude oil to settle for a period of time until the oil becomes stratified into the at least two layers. The degummed oil is then aerated and agitated while being maintained at a temperature of 170-180° F. for a time period sufficient to obtain a desired oil viscosity. The resulting partially refined oil is suitable for use in industrial applications such as the preparation of urethane foams.
Abstract: A method for partially refining a crude vegetable oil utilizing physical refining techniques is described. The crude vegetable oil is first degummed by either (1) allowing the crude oil to settle over a period of time, such as twenty days, so that the oil becomes stratified into at least two layers, wherein one layer comprises gums with low oil content and a second layer comprises oil containing only a fraction of the gums originally present and then separating the oil layer from the gum layer, or (2) heating the crude oil to a temperature of about 270-300° F. with agitation and then allowing the crude oil to settle for a period of time until the oil becomes stratified into the at least two layers. The degummed oil is then aerated and agitated while being maintained at a temperature of 170-180° F. for a time period sufficient to obtain a desired oil viscosity. The resulting partially refined oil is suitable for use in industrial applications such as the preparation of urethane foams.
Abstract: This invention relates to a new process for refining and deodorizing the oil from the seeds of the neem tree by refining a neem oil solution with an alkaline solution of hydrogen peroxide to provide an edible grade of vegetable oil.
Abstract: Fluorinated carboxylic acids which do not have the required purity for use as emulsifier in the polymerization of fluorinated monomers can, if necessary after prior de-watering, be treated with oxidants, whereupon the isolation of the pure product is carried out by crystallisation or, preferably, by distillation.
Abstract: The present invention relates to a process for the regeneration of spent bleaching earth, comprising an oxidative heat treatment in which the amount of oxygen supplied exceeds the stoichiometrical requirement of complete oxidation of all organics present in the spent bleaching earth, wherein the spent bleaching earth and the oxygen are blown through a stationary fluidized bed of inert granulate material. The stationary fluidized bed should be as high as to limit the temperature in the freeboard to less than 1000.degree. C. As a matter of fact, it has been found that, if the fluidized bed is not high enough, the oxygen required to burn off the organics content of the spent bleaching earth would blow out the powdered bleaching earth from the bed at the stage of incomplete oxidation of the organics present on the earth, resulting in an uncontrolled temperature rise in the freeboard and local overheating of the bleaching earth.
Abstract: Production of stable ozonized oils from unsaturated vegetable oils by introducing an ozone-oxygen mixture into the oil until it reaches saturation, and following the ozonization, an extraction process in acid medium is carried out in the presence of a redox reaction system, which is capable of moderately reacting the radicals in the presence of a synthetic or natural anti-oxidation medium or reducing medium.