Abstract: Highly pure amidosilanes of the formula ##STR1## wherein R is alkyl having 1 to 18 carbon atoms, cycloalkyl having 5 to 18 carbon atoms, alkenyl having 2 to 18 carbon atoms and aryl having 6 to 18 carbon atoms,R.sup.1 is alkoxy having 1 to 18 carbon atoms,R.sup.2 and R.sup.3 each independently of one another are alkyl having 1 to 18 carbon atoms or aryl having 6 to 18 carbon atoms,x is 1, 2 or 3,y is 0, 1 or 2, with the sum of x and y being 1 to 3,are produced by reacting an alcohol-free suspension of alkali metal salts or organic amides with organosilanes wherein said salts of amides are prepared by reacting a compound of the formula ##STR2## with an alcoholic solution of an alkali metal alcoholate in inert organic solvents and the removing alcohol from the reaction mixture by distillation, and said organosilanes are of the formulaR.sub.x R.sub.y.sup.1 SiX.sub.

Abstract: Heavy metals can be fixed to solid carriers to which an .alpha.-amino- or an .alpha.-iminohydroxamate ligand has been covalently bound. The ligand can have the structural formula ##STR1## wherein R.sub.1 and R.sub.2 represent H or an alkyl, or may be a compound of two or more hydroxamate substituents. The carrier can be formed of polysaccharides, polygalactanes, polyacrylates or silica dioxide. The adsorbent is prepared by an .alpha.-aminohydroxamate in an aqueous solution having a pH value of 4-9 being brought into contact with an aldehyde derivative of a carrier, followed by reduction with sodiumborohydride or sodiumcyanoborohydride.

Abstract: Pesticidally active compounds of the formula ##STR1## in which R.sup.1 is an organic radical,R.sup.2 is hydrogen, trialkylsilyl, a hydrocarbon or acyl radical, andR.sup.3 and R.sup.4 independently are an amino, hydroxyl, hydroximino, alkoxy or like radical.Most of the compounds are new, as are various intermediates therefor.

Abstract: The invention is a process for the preparation of a N- or S-1,2-ethylenically unsaturated organic compound which comprises(a) contacting a N- or S-silylated organic compound with an aldehyde, wherein the aldehyde has a hydrogen atom bonded to the carbon adjacent to the carbonyl moiety, at elevated temperatures under conditions such that a N- or S-1-siloxyalkyl-substituted organic compound is prepared; and(b) pyrolyzing the N- or S-1-siloxyalkyl-substituted organic compound under conditions such that the siloxy moiety is elminated to prepare a N- or S-1,2-ethylenically unsaturated compound.

Abstract: N-Methyl-N-trimethylsilyl trifluoroacetamide can be synthesized by the reaction of N-methyl trifluoroacetamide and, N,O-bis(trimethylsilyl) acetamide at 40.degree.-130.degree. C. followed by fractionating distillation. The method is advantageous in respect of the absence of the step of filtration for the removal of the by-product salt and non-use of any corrosive reactant in comparison with conventional methods.

Abstract: Disclosed is a method of preparing bis-trimethylsilylamides of carboxylic acids from the carboxylic acid amide by mixing two equivalents of trimethylchlorosilane and an excess of hexamethyldisilazane, heating the mixture to 40.degree. to 80.degree. C. and adding two equivalents of a tertiary amine as acid acceptor. The method results in substantially improved purity and yield of end product.

Abstract: This invention relates to amine derivatives and salts thereof. These compounds have an anti-ulcer activity which is effective to human beings and animals. This disclosure relates to such compounds, a process for the preparation thereof and an anti-ulcer agent containing the same.

Abstract: Aminofunctional organopolysiloxane fluids are prepared by reacting a hydroxy-terminated organopolysiloxane fluid and an aminofunctional organopolysiloxane fluid in the presence of organo-metallic salt catalyst.

Abstract: Carboxylic acid trimethylsilyl esters (I) and trimethylsilyl carboxylic acid amides can be prepared simultaneously from the corresponding carboxylic acid anhydrides; the esters (I) and monocarboxylic acid trimethylsilyl amides are formed first and can then be recovered, or else the bis-trimethylsilyl carboxylic acid amides are formed by further transposition with trimethylchlorosilane in the presence of tertiary amines, and are separated from the carboxylic acid trimethylsilyl ester (I) and recovered.

Abstract: There is provided a process for preparing amidosilane and amidosiloxanes comprising reacting (1) an Si--H containing compound with (2) an organic amide in the presence of (3) a precious metal containing catalyst.

Abstract: The invention concerns novel compounds of formula IIIAR.sub.x.sup.a Si(NCS).sub.4-x IIIAwherein R.sup.a is selected from electron donating substituents consisting of alkoxy of 1-10 carbon atoms, cycloalkoxy of 4-8 carbon atoms, aralkoxy of 7-12 carbon atoms, phenoxy which may be substituted by alkyl of 1-10 carbon atoms, alkoxy of 1-10 carbon atoms or trifluoromethyl, the group R.sup.b R.sup.c N-wherein R.sup.b and R.sup.c are selected from alkyl of 1-6 carbon atoms, cycloalkyl of 4-6 carbon atoms, phenyl which may be substituted by alkyl of 1-10 carbon atoms, alkoxy of 1-10 carbon atoms or trifluoromethyl, and aralkyl of 7-12 carbon atoms or R.sup.b and R.sup.

Abstract: A process for the manufacture of alkyl carbamates from urea and aliphatic alcohols. The process is carried out under a vacuum, preferably at least 20 inches, and preferably in the presence of magnesium oxide catalyst.

Abstract: A process for producing a silicon isocyanate compound which comprises reacting a silicon halide compound in which a fluoride compound is excluded with an isocyanate of the formula [I] M(NCO).sub.m or a cyanate of the formula [I'] M(OCN).sub.m wherein M represents a member selected from the group consisting of alkali metals and alkaline earth metals, and m is 1 or 2, in the presence of one or more reaction accelerators selected from the group consisting of alkylene glycols, polyalkylene glycols and, ether and ester derivatives thereof, thereby to prepare a silicon isocyanate compound containing at least one Si--NCO linkage.

Abstract: Ungelled reaction products of a condensation product with an amino silane are formed. The products are capable of curing at a low temperature to form durable coatings. Polyols can optionally be blended with the ungelled reaction products to provide useful coating compositions.

Abstract: N-Methyl-N-silyl-carbamates of the formula ##STR1## where R.sup.1 denotes hydrogen or unsubstituted or halogen-substituted alkyl of a maximum of 4 carbon atoms, R.sup.2, R.sup.3 and R.sup.4 are identical or different and each denotes alkyl of a maximum of 4 carbon atoms, and R.sup.5 denotes alkyl of a maximum of 4 carbon atoms or phenyl, processes for their manufacture, and their use for combating pests.

Abstract: A process for preparing silicon-containing acetamide derivatives which comprises reacting acetamide or substituted derivatives thereof with N-trimethylsilyl imidazole while continuously removing the silicon-containing acetamide derivatives as they are formed by distillation.

Abstract: An acetamide compound of the formula, ##STR1## where R, R.sup.1, R.sup.2, R.sup.4 are monovalent hydrocarbon radicals, and R.sup.3 is a divalent hydrocarbon radical.

Abstract: N-Methyl-N-trimethylsilyl trifluoroacetamide can be synthesized by the reaction of N-methyl trifluoroacetamide and, N,O-bis(trimethylsilyl) acetamide at 40.degree.-130.degree. C. followed by fractionating distillation. The method is advantageous in respect of the absence of the step of filtration for the removal of the by-product salt and non-use of any corrosive reactant in comparison with conventional methods.