Containing -c(=x)x-, Wherein The X's Are The Same Or Diverse Chalcogens Patents (Class 556/55)
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Patent number: 5756069Abstract: An amphipathic polychelating compound including a hydrophilic polymeric moiety having a main backbone and a plurality of reactive side groups, a lipid-soluble anchor linked to the N terminal of the polymeric moiety, and a plurality of chelating agents linked to the side groups of the polymeric moiety. The polychelating compounds are bound to liposomes or micelles for use as diagnostic and therapeutic agents.Type: GrantFiled: January 30, 1996Date of Patent: May 26, 1998Inventors: Vladimir P. Torchilin, Vladimir S. Trubetskoy, Gerald L. Wolf
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Patent number: 5746995Abstract: The invention relates to new diethylenetriaminepentaacetic acid derivatives, their complexes and complex salts, that contain an element of atomic numbers 20-32, 39-51 or 57-83, pharmaceutical agents that contain these compounds and their use as contrast media and antidotes.Type: GrantFiled: November 30, 1995Date of Patent: May 5, 1998Assignee: Schering AktiengesellschaftInventors: Franz-Karl Maier, Michael Bauer, Werner Krause, Ulrich Speck, Gabriele Schuhmann-Giampieri, Andreas Muhler, Thomas Balzer, Wolf-Rudiger Press
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Patent number: 5730956Abstract: The invention relates to diethylenetriaminepentaacetic acid monoamide derivatives, their complexes and complex salts, containing gadolinium, dysprosium, iron or manganese, pharmaceutical agents containing these compounds, their use as contrast media and process for their production.Type: GrantFiled: June 7, 1995Date of Patent: March 24, 1998Assignee: Schering AktiengesellschaftInventors: Johannes Platzek, Ulrich Niedballa, Peter Mareski, Bernd Raduchel, Hanns-Joachim Weinmann, Andreas Muhler, Bernd Misselwitz
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Patent number: 5693309Abstract: 1. Compounds of general Formula I ##STR1## wherein n and m in each case mean the numbers 0, 1, 2, 3 and 4,X stands for a hydrogen atom and/or a metal ion equivalent of an element of atomic numbers 21-29, 31, 32, 37-39, 42-44, 49 or 57-83,R.sup.1 and R.sup.2, being different, mean in each case a hydrogen atom or a straight-chain, branched, saturated or unsaturated C.sub.0 -C.sub.20 -alkylene group, this alkylene group exhibiting at the end either a second molecule of general Formula I.sub.A or I.sub.Type: GrantFiled: June 5, 1995Date of Patent: December 2, 1997Assignee: Schering AktiengesellschaftInventors: Julius Deutsch, Heinz Gries, Erich Klieger, Ulrich Niedballa, Franz-Josef Renneke, Jurgen Conrad, Wolfgang Muetzel, Heribert Schmitt-Willich
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Patent number: 5681544Abstract: Polymers comprising a ligand containing a carboxylic acid group, optionally at least one ion of an element of the atomic numbers 21-29, 42, 44 or 57-83 as well as optionally cations of inorganic and/or organic bases, amino acids or amino acid amides are valuable complexing agents and complexes for diagnosis.Type: GrantFiled: June 7, 1995Date of Patent: October 28, 1997Assignee: Schering AktiengesellschaftInventors: Heribert Schmitt-Willich, Julius Deutsch, Heinz Gries, Jurgen Conrad, Reinhard Neumeier
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Patent number: 5676923Abstract: Diethylenetriaminepentaacetic acid monoamide derivatives, their complexes and complex salts, containing an element of atomic numbers 21-29, 31, 32, 39, 42-44, 49 or 57-83, pharmaceutical agents containing these compounds, their use as contrast media and process for their production.Type: GrantFiled: June 7, 1995Date of Patent: October 14, 1997Assignee: Schering AktiengesellschaftInventors: Johannes Platzek, Ulrich Niedballa, Peter Mareski, Bernd Raduchel, Hanns-Joachim Weinmann, Andreas Muhler, Bernd Misselwitz
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Patent number: 5672335Abstract: Metal complexes containing a metal of atomic numbers 39-42, 44-51 or 56-83 and a complexing agent can be used for the production of contrast media for use in the contrast-enhanced computer tomography of the liver and the biliary tracts.Type: GrantFiled: June 6, 1995Date of Patent: September 30, 1997Assignee: Schering AktiengesellschaftInventors: Werner Krause, Thomas Balzer, Wolf-Rudiger Press, Gabriele Schuhmann-Giampieri, Ulrich Speck, Andreas Muhler
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Patent number: 5654456Abstract: A first metal, an alcohol, and a carboxylic acid are reacted to form a metal alkoxycarboxylate which is then reacted with an alkoxide and/or a carboxylate of a second metal to form a precursor. Alternatively, a metal carboxylate and a metal alkoxide are combined and heated to form a precursor. In either alternative, the precursor includes all or most of the metal-oxygen-metal bonds of a desired metal oxide and a carboxylate ligand. The precursor is applied to a substrate, dried and annealed to form the metal oxide, such as BST. The metal-oxygen-metal bonds in the precursor permit the desired metal oxide to be formed from the precursor in one step, providing excellent thin films suitable for integrated circuits. The carboxylate ligand provides stability to the precursor allowing it to be stored for periods common in large scale manufacturing.Type: GrantFiled: June 7, 1995Date of Patent: August 5, 1997Assignee: Symetrix CorporationInventors: Michael C. Scott, Carlos A. Paz de Araujo, Larry D. McMillan
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Patent number: 5648508Abstract: Novel metal-organic microporous materials are prepared in solution using mild reaction conditions from a metal or metalloid ion with a ligand containing multidentate functional groups in the presence of a templating agent. The resultant microporous materials are useful in the purification of liquids and gases.Type: GrantFiled: November 22, 1995Date of Patent: July 15, 1997Assignee: Nalco Chemical CompanyInventor: Omar M. Yaghi
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Patent number: 5599963Abstract: The invention relates to catalysts for the synthesis of .beta.-hydroxy carbonyl compounds, and in particular to enantioselective catalysts.Type: GrantFiled: March 29, 1995Date of Patent: February 4, 1997Assignee: California Institute of TechnologyInventors: Erick M. Carreira, Robert A. Singer
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Patent number: 5581003Abstract: Soluble zirconium and hafnium organic acid complexes are made by forming an aqueous mixture of a basic carbonate of either zirconium or hafnium and the organic acid such a propionic acid. The molar ratio of the organic acid to metal in the carbonate is greater than about 1.5. The mixture is heated with stirring to form the complex which is then recovered as a dry, free-flowing powder.Type: GrantFiled: June 7, 1995Date of Patent: December 3, 1996Assignee: Teledyne Industries, Inc.Inventor: James A. Sommers
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Patent number: 5571498Abstract: Emulsions of paramagnetic contrast agents, and processes of making and using them are disclosed. The emulsions contain water, a dispersed oil phase and a complex of a paramagnetic metal ion and an organic chelator having a C.sub.10 -C.sub.30 unsaturated aliphatic group. The emulsions are very stable and therapeutically acceptable for intravenous administration to enhance MRI.Type: GrantFiled: June 2, 1994Date of Patent: November 5, 1996Assignee: HemaGen/PFCInventors: William P. Cacheris, Robert J. Kaufman, Thomas J. Richard, Raymond C. Grabiak
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Patent number: 5565595Abstract: Reaction products of titanates with .beta.-dicarbonyl compounds and citrates and their use in one-component RTV silicones.Type: GrantFiled: March 7, 1995Date of Patent: October 15, 1996Assignee: Bayer AktiengesellschaftInventors: Robert Friebe, John Huggins, Wilhelm Weber, Karl-Heinz Sockel
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Patent number: 5554357Abstract: Novel magnetic resonance imaging agents comprise complexes of paramagnetic ions with hydrazide derivatives of polyaminocarboxylic acid chelating agents. These novel imaging agents are characterized by excellent NMR image-contrasting properties and by high solubilities in physiological solutions. A novel method of performing an NMR diagnostic procedure involves administering to a warm-blooded animal an effective amount of a complex as described above and then exposing the warm-blooded animal to an NMR imaging procedure, thereby imaging at least a portion of the body of the warm-blooded animal.Type: GrantFiled: September 30, 1994Date of Patent: September 10, 1996Assignee: Mallinckrodt Medical, Inc.Inventor: Raghavan Rajagopalan
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Patent number: 5527752Abstract: A catalyst precursor is provided which is useful, when combined with a cocatalyst, in the manufacture of polyolefins. The catalyst precursor is of the formula: ##STR1## where M is a transition metal, preferably Zr or Hf; L is a substituted or unsubstituted, .pi. bonded ligand coordinated to M, preferably a cyclopentadienyl-type ligand; Q can be the same or different and is independently selected from the group consisting of --O, --NR, --CR.sub.2 and --S; Y is either C or S; Z is selected from the group consisting of --OR, --NR.sub.2, --CR.sub.3, --SR, --SiR.sub.3, --PR.sub.Type: GrantFiled: March 29, 1995Date of Patent: June 18, 1996Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Walter T. Reichle, Frederick J. Karol, Gregory T. Whiteker
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Patent number: 5496854Abstract: The invention relates to novel titanocene derivatives possessing chemotherapeutic activity and method for their preparation. These compounds possess two cyclopentadiene rings linked to titanium as a central atom and bound covalently to two phenoxy groups which possess a substituent R selected from the group consisting of COOCH.sub.3, COOC.sub.2 H.sub.5, H, COOCH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 OCH.sub.3 and are free from amino, nitro, chloride and fluoride groups. The novel compounds represent a compromise between the main properties for an antitumor agent, i.e., electrophilicity and stability, being water soluble. Cytotoxicity measurements of these compounds showed significant growth inhibition properties, expressed in terms of IC.sub.50 [M] values.Type: GrantFiled: February 17, 1995Date of Patent: March 5, 1996Assignees: Technion Research & Development Foundation Ltd., Ehud KeinanInventor: Ehud Keinan
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Patent number: 5494656Abstract: A second sphere contrast enhancing agent for magnetic resonance imaging comprises a paramagnetic metal ion having catecholate ligands coordinated thereto and having water molecules hydrogen bonded to the catecholate ligands.Type: GrantFiled: March 17, 1995Date of Patent: February 27, 1996Assignee: The University of ToledoInventor: Julian A. Davies
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Patent number: 5482700Abstract: 1. Compounds of general Formula I ##STR1## wherein n and m in each case mean the numbers 0, 1, 2, 3 and 4,X stands for a hydrogen atom and/or a metal ion equivalent of an element of atomic numbers 21-29, 31, 32, 37-39, 42-44, 49 or 57-83,R.sup.1 and R.sup.2, being different, mean in each case a hydrogen atom or a straight-chain, branched, saturated or unsaturated C.sub.0 -C.sub.20 -alkylene group which optionally contains imino, phenylenoxy, phenylenimino, amido, hydrazido, ester group(s), oxygen, sulfur and/or nitrogen atom(s) and is substituted, if desired, by hydroxy, mercapto, imino, epoxy, oxo, thioxo and/or amino group(s), this alkylene group exhibiting at the end either a second molecule of general Formula I.sub.A or I.sub.B ##STR2## a functional group, or, linked by way of this functional group, a bio- or macromolecule,are valuable diagnostic and therapeutic media.Type: GrantFiled: July 1, 1994Date of Patent: January 9, 1996Assignee: Schering AktiengesellschaftInventors: Julius Deutsch, Heinz Gries, Erich Klieger, Ulrich Niedballa, Franz-Josef Renneke, Juergen Conrad, Wolfgang Muetzel
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Patent number: 5474762Abstract: A sunscreen composition for application to human skin comprises an ultraviolet absorber which is introduced as an anion into a layered double hydroxide of the general formula[N.sub.m N.sub.n (OH).sub.2(m+n) ].sup.y+ X.sup.x-.sub.y/x .multidot.zH.sub.2 Owhere M is a divalent metal or lithium, N is a trivalent metal and X denotes anions present as an interlayer between layers of metal atoms joined through the OH groups.Such layered double hydroxides are, for this invention, suspended in a cosmetically acceptable vehicle.Type: GrantFiled: August 16, 1993Date of Patent: December 12, 1995Assignee: Chesebrough-Pond's USA Co. Division of Conopco, Inc.Inventors: Stuart W. Carr, Kevin R. Franklin, Charles C. Nunn, Jeffrey J. Pasternak, Ian R. Scott
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Patent number: 5466439Abstract: A polymeric contrast enhancing agent for magnetic resonance images having a chelating agent, which can be bound to metal ions having at least one unpaired electron, such as gadolinium. Examples of such chelating agents include DTPA-ethylenediamide-methacrylate copolymer and poly-(DTPA-ethylenediamide). These contrast enhancing agents, bound to the metal ions, are then administered to a patient, and following this the MR images are taken.Type: GrantFiled: July 7, 1994Date of Patent: November 14, 1995Assignee: Magnetic Research, Inc.Inventors: Wendell A. Gibby, N. Rao Puttagunta
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Patent number: 5466846Abstract: Aqueous solutions of zirconium chelates are prepared by combining an alpha-hydroxycarboxylic acid salt with a solution of a zirconium compound. That preparation first involves formulating an alpha-hydroxycarboxylic acid salt through a stoichiometric reaction between an alpha-hydroxycarboxylic acids and a base. The stoichiometric reaction product consists of an approximately neutral solution of a corresponding alpha-hydroxycarboxylic acid salt. The alpha-hydroxycarboxylic acid salt is then added to a solution of a zirconium compound to produce a mildly acidic or basic solution of the corresponding zirconium alpha-hydroxycarboxylic chelate. Alternatively, the alpha-hydroxycarboxylic acid salt may be pre-prepared and added in solid or liquid form to the zirconium compound before the zirconium compound is placed in solution so that the corresponding zirconium alpha-hydroxycarboxylic chelate is produced.Type: GrantFiled: November 16, 1994Date of Patent: November 14, 1995Assignee: Benchmark Research and Technology, Inc.Inventor: Sharif Sharif
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Patent number: 5393907Abstract: The present invention pertains to a coating solution for forming a composite metal oxide film containing:(A) at least one member selected from the group consisting of a reaction product, a partial hydrolyzate of the reaction product, and a partial acylated product of the reaction product, wherein the reaction product is obtained by reacting a .beta.-diketone compound and at least one metal compound represented by formula (I):M.sub.1 A.sub.n (I)wherein M.sub.1, A and n are as defined herein;(B) a polyhydric alcohol compound; and(C) at least one member selected from the group consisting of formulas (II), (III) and (IV); whereinformula (II) is a metal carboxylate compound represented by:M.sub.2 (OCOR).sub.m (II)wherein M.sub.2, R and m are as defined herein;formula (III) is a metal nitrate compound represented by:M.sub.2 (NO.sub.3).sub.m (III)wherein M.sub.2 and m are as defined herein;formula (IV) is a metal nitrate compound represented by:M.sub.3 (NO.sub.2)l (IV)wherein M.sub.3 and l are as defined herein.Type: GrantFiled: March 23, 1993Date of Patent: February 28, 1995Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Akira Hashimoto, Katsuya Tanitsu
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Patent number: 5384108Abstract: Novel magnetic resonance imaging agents comprise complexes of paramagnetic ions with hydrazide derivatives of polyaminocarboxylic acid chelating agents. The complexes are represented by the formula of: ##STR1## wherein A is --CHR.sup.2 --CHR.sup.3 -- or ##STR2## M.sup.+Z is a paramagnetic ion of an element with an atomic number of 21-29, 42-44 58-70, and a valence, Z, of +2 or +3; R.sup.1 groups may be the same or different and are selected from the group consisting of --O.sup.- and ##STR3## The R.sup.4, R.sup.5 and R.sup.6 groups are as defined in the disclosure. These novel imaging agents are characterized by excellent NMR image-contrasting properties and by high solubilities in physiological solutions. A novel method of performing an NMR diagnostic procedure involves administering to a warm-blooded animal an effective amount of a complex as described above and then exposing the warm-blooded animal to an NMR imaging procedure, thereby imaging at least a portion of the body of the warm-blooded animal.Type: GrantFiled: April 24, 1989Date of Patent: January 24, 1995Assignee: Mallinckrodt Medical, Inc.Inventor: Raghavan Rajagopalan
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Patent number: 5359101Abstract: Anionically polymerizable monomers containing at least one silicon or titanium atom form polymeric photoresists having good dry etch resistance for use in microlithography. The monomers are of the formula ##STR1## wherein A is --H or --CH.dbd.CH.sub.2 ; X is a strong electron withdrawing group;Y is a strong electron withdrawing group containing at least one silicon or titanium atom.Preferably Y is ##STR2## wherein n is 1-5 and R.sup.2, R.sup.3 and R.sup.4 are C.sub.1 -C.sub.10 alkyl. A particularly preferred monomer is 3-trimethylsilylpropyl 2-cyanoacrylate.Methods for applying a resist coating by vapor deposition of these monomers and exposure to radiation are described. A positive or negative tone image can be produced, depending upon the imaging method employed. The imaging layer may be applied over a planarizing layer to form a multilayer photoresist.Type: GrantFiled: October 1, 1991Date of Patent: October 25, 1994Assignee: Loctite Ireland, Ltd.Inventors: John Woods, Pauline Coakley
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Patent number: 5320770Abstract: The present invention relates to an electrorheological fluid composition comprising a dispersion of a plurality of solid particles in an electrically non-conducting liquid, the improvement comprising using as said solid particles a composition having the general formula:[(M).sup.p (H.sub.2 O).sub.x (OH).sub.y ].sup.q.sub.c [A].sup.r.sub.d.B.sub.z.nH.sub.2 Owherein M is a metal cation or a mixture of metal cations at various ratios; p is the total valence of M and has a value of greater than zero; x is zero or has a value greater than zero, y is zero or has a value greater than zero, with the proviso that only one of x or y can be zero at any given time; q has a value of p minus y with the proviso that q has a value of at least one; c has a value of greater than zero; A is an anion or a mixture of anions at various ratios; r is the total valence of A with the proviso that r has a value of at least one; d has a value of greater than zero with the proviso that (q.times.c) is always equal to (r.times.Type: GrantFiled: April 27, 1992Date of Patent: June 14, 1994Assignee: Dow Corning CorporationInventors: Lori J. Conway, Donald A. Kadlec, Joan S. Holtschlag
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Patent number: 5296623Abstract: A method of producing activated metal salts useful in antiperspirant compositions is disclosed. The method produces the salt through an acid base reaction wherein an acid is reacted with a metal in basic form. Preferred metals include aluminum and zirconium. Activate aluminum-zirconium hydrohalide and activated aluminum-zirconium-amino acid salts can also be produced by the method of this invention.Type: GrantFiled: September 26, 1991Date of Patent: March 22, 1994Assignee: Somerville Technology Group, Inc.Inventors: Dimitris E. Katsoulis, Walter J. Carmody
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Patent number: 5260466Abstract: A new method for the production of titanium derivatives of carboxylic acids is provided. A liquid or solid carboxylic acid is suspended in an inert liquid diluent in which it is substantially insoluble and reacted with a titanium alkoxide to form a titanium derivative which is also substantially insoluble in the inert diluent.The invention provides a simple method for the production of titanium compounds which are easily transported and can readily be dissolved in water for use, for example, as catalysts and cross-linking agents.Type: GrantFiled: August 10, 1992Date of Patent: November 9, 1993Assignee: Tioxide Specialties LimitedInventor: Graeme McGibbon
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Patent number: 5220045Abstract: Metal carboxylates which may be used for the polymerization of monomers suitable for Ziegler-Natta polymerization are prepared by reaction of the organic C.sub.2-20 carboxylic acids on which the carboxylates are based with ammonia and/or amines and/or tetraalkyl ammonium hydroxides and the corresponding metal nitrates in the presence of inert organic solvents at temperatures of 0.degree. to 150.degree. C.Type: GrantFiled: April 27, 1992Date of Patent: June 15, 1993Assignee: Bayer AktiengesellschaftInventors: Thomas Knauf, Werner Obrecht
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Patent number: 5182408Abstract: The present invention comprises reacting ammonium, sodium or potassium hydroxide or water soluble amines or amine derivatives with alpha-hydroxy carboxylic acid to prepare a neutral solution of the corresponding alpha-hydroxy carboxylic salt in a stoichiometric reaction.The alkali metal, ammonium, amine or amine derivative, alpha-hydroxy carboxylic acid salt is then added to solutions of zirconium which may be zirconium oxychloride, zirconium hydroxy chloride, zirconium acetate and the like, ammonia, water soluble amines or amine derivatives, diisopropylamine or a mixture of two or more of these bases, as well as soluble carbonates and/or bicarbonates of ammonium and alkali metals such as sodium and potassium, while mixing the solutions. The procedure produces a mildly acidic or basic solution of the zirconium alpha-hydroxy carboxylic chelate.Type: GrantFiled: April 25, 1991Date of Patent: January 26, 1993Assignee: Zirconium Technology CorporationInventor: Sharif Sharif
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Patent number: 5138040Abstract: Methods and compositions for enhancing magnetic resonance imaging in at least a portion of a warm-blooded animal.Type: GrantFiled: July 2, 1991Date of Patent: August 11, 1992Assignee: Mallinckrodt Medical, Inc.Inventors: Dennis A. Moore, Rebecca A. Wallace
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Patent number: 5132409Abstract: Macrocyclic derivatives of 1,4,7,10-tetraazacyclododecane of general formula (I) hereinbelow, wherein A is a group of formula (II) hereinbelow, in which R is H or alkyl or optionally substituted benzyl or a H(OCH.sub.2 CH.sub.2).sub.1-4-, Me(OCH.sub.2 CH.sub.2).sub.1-4-, or Et(OCH.sub.2 CH.sub.2).sub.1-4- group, X or O--R.sub.1, in which R.sub.1 is H or alkyl, hydroxyalkyl, alkoxyalkyl, alkoxyhydroxyalkyl or a polyoxaalkyl group or X is --NR.sub.2 R.sub.3, in which R.sub.2 and R.sub.3 are H or alkyl, hydroxyalkyl, alkoxyalkyl or alkoxyhydroxyalkyl, and B.sub.1, B.sub.2 and B.sub.3 have the same meanings as A or are H or a group of formula (III) hereinbelow, in which R.sub.4 is H or alkyl, Y is a O--R.sub.5 group, wherein R.sub.5 is H or alkyl, hydroxyalkyl, alkoxyalkyl, alkoxyhydroxyalkyl or a polyoxaalkyl group, or Y is a --NR.sub.6 R.sub.7 group, wherein R.sub.6 and R.sub.Type: GrantFiled: November 27, 1989Date of Patent: July 21, 1992Assignee: Bracco Industria Chimica S.p.A.Inventors: Ernst Felder, Carlo Musu, Luciano Fumagalli, Fulvio Uggeri
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Patent number: 5076847Abstract: A new titanium chelate has been developed which introduces improvements into aqueous emulsion paints. The chelate is a reaction product of a titanium orthoester, a glycol or a glycol ether, an alkanolamine and an alpha-hydroxy carboxy acid.Type: GrantFiled: May 8, 1990Date of Patent: December 31, 1991Assignee: Tioxide Group PLCInventors: Peter D. Kay, McDonald Keith
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Patent number: 5021596Abstract: Zirconium(IV) chelates with citric acid ester radicals and optionally with alkoxy groups are prepared from tetraalkoxy zirconate and a citric acid ester; they are useful as components of printing inks.Type: GrantFiled: February 23, 1989Date of Patent: June 4, 1991Assignee: Huels Troisdorf AktiengesellschaftInventors: Dieter Barfurth, Claus Lindzus, Heinz Nestler
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Patent number: 4996336Abstract: Water-soluble chelates represented by the formula: ##STR1## wherein R is H or alkyl (1-12C) and M is Ti or Zr. The above chelates can be prepared by reacting a Ti or Zr halide or alkoxide with between 1 & 2 molar equivalents of N,N-bix-(2-hydroxyethyl)-glycine, and used as cross-linking agents in hydraulic fracturing fluids and in gels that are used for selectively plugging permeable zones or leaks.Type: GrantFiled: November 28, 1989Date of Patent: February 26, 1991Assignee: E. I. Du Pont de Nemours and CompanyInventors: Donald E. Putzig, Kenneth C. Smeltz
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Patent number: 4978389Abstract: Surface treating agents comprising of an organic titanium compound containing at least one fluoropolyether radical linked by carboxy groups to the titanium and at least one hydrolyzable group, such compounds being obtained by reacting a fluoropolyether having one or more carboxylic groups with a titanium compound having at least one group able to react with carboxylic group and at least one residual hydrolyzable group per titanium atom. The surface treating agents have not only superior surface activity and anti-corrosion properties for the metal surface but are also chemically stable.Type: GrantFiled: February 27, 1989Date of Patent: December 18, 1990Assignee: Nippon Soda Co. Ltd.Inventors: Masayuchi Sato, Atsushi Mori, Mamoru Aizawa
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Patent number: 4965211Abstract: Species-linked diamine triacetic acids of the formula ##STR1## wherein T is an organic species containing at least one amine, hydroxyl, or thiol functional group, L is the residue of at least one of those functional groups and R is a two or more atom long covalent bridge, are disclosed. Methods for their preparation, for the preparation of metal chelates from them and for the use of the chelates are also disclosed. In a preferred embodiment, the metal ions employed in the formation of the chelates are rare earth metal ions capable of forming fluorescent chelates which can in turn be employed in fluoroassay techniques.Type: GrantFiled: November 9, 1983Date of Patent: October 23, 1990Assignee: Irwin WiederInventors: Irwin Wieder, Robert H. Wollenberg
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Patent number: 4958038Abstract: A process which comprises (A) combining (i) glycerol, erythritol, arabitol, xylitol, sorbitol, dulcitol, mannitol, inositol, a monosaccharide, or a disaccharide, (ii) water and (iii) lactic acid, glycolic acid, malic acid, citric acid, tartaric acid, saccharic acid, gluconic acid, glyceric acid or mandelic acid to provide an aqueous solution of the polyol and the .alpha.-hydroxy carboxylic acid, and (B) then at an alkaline pH of 10 or less reacting the solution with a tetravalent titanium compound of an inorganic acid at an .alpha.-hydroxy carboxylic acid:titanium mol ratio between about 0.5:1 and about 4:1 and a polyol:titanium mol ratio between about 0.25:1 and about 2:1.Type: GrantFiled: March 20, 1989Date of Patent: September 18, 1990Assignee: E. I. du Pont de Nemours and CompanyInventor: Kenneth C. Smeltz
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Patent number: 4931094Abstract: Novel alkoxy titanium(IV)-chelates are used to modify printing inks based on nitrocellulose or other cellulose ester derivatives. The novel chelates comprise citric acid alkyl esters as chelate formers. They delay, as other titanium chelates do, the well-known catalytic effect of the titanium component in cross-linking reactions. When used in printing inks, the novel titanium chelates and their alcoholic solutions have the advantage that they have an insignificant color of their own, so that they practically do not discolor the printing inks. A further advantage of the novel chelates resides in that they do not enter into alteration effects with antioxidants based on phenol, so that they can also be used for printing inks which are to be applied to polymeric substrates containing such antioxidants without the occurence of discoloration.Type: GrantFiled: October 3, 1988Date of Patent: June 5, 1990Assignee: Huels Troisdorf AGInventors: Dieter Barfurth, Claus Lindzus, Heinz Nestler
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Patent number: 4861500Abstract: A crosslinker composition that can produce delayed crosslinking of an aqueous solution of a crosslinkable organic polymer. The composition comprises an organic titanium complex. The composition further contains an organic hydroxycarboxylic acid, preferably hydroxyacetic acid. The pH of the composition is preferably less than 5. The pH of the composition is further preferably such that when sufficient amount of composition is added to an aqueous polymer solution to result in delayed crosslinking of the polymer, the composition produces a pH in the resulting gel solution, preferably of between about 3 to about 4.5. Gel solutions produced using the composition are particularly useful in fracturing subterranean formations, and in particular in fracturing subterranean formations penetrated by an oil well in which fracturing process carbon dioxide and a proppant are added to the fracturing fluid.Type: GrantFiled: November 17, 1986Date of Patent: August 29, 1989Assignee: Dowell Schlumberger IncorporatedInventor: Richard M. Hodge
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Patent number: 4851142Abstract: An additive for drilling fluids employed in the deep well drilling industry, which additive comprises an organometal compound of titanium, zirconium or vanadium with humic acid and a further organic moiety which is at least one of fatty acid alkoxylates, fatty alcohol polyalkylene glycol ethers, long-chain amine alkoxylates optionally substituted with a hydroxyl group, or water-insoluble polyalkoxylate all of which are optionally mixed with fatty acids, and fatty acids alone, these having optionally been applied onto an inorganic carrier, mandatorily in the case of fatty acids alone. The fluid loss additive prevents the drilling fluid from streaming into porous drill formations. The additive may be prepared by the reaction of a metal alcoholate with a compound providing the organic moiety and humic acid or a humic acid-containing product.Type: GrantFiled: May 9, 1988Date of Patent: July 25, 1989Assignee: Henkel Kommanditgesellschaft auf AktienInventors: William C. Scoggins, Claus P. Herold, Heinz Mueller
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Patent number: 4824611Abstract: A process for preparing hydrocarbon-soluble transition metal salts of organic carboxylic acids having improved properties wherein the transition metal is one capable of having a multiplicity of oxidation states is described. The process comprises the steps of (a) providing at least one transition metal compound wherein the transition metal is at one of its higher positive oxidation states, (b) treating said transition metal compound with at least one inorganic reducing agent forming an intermediate containing the transition metal in a lower positive oxidation state, and (c) reacting said intermediate with at least one organic carboxylic acid containing at least 5 carbon atoms to form the transition metal salt of said carboxylic acid. The transition metal salts prepared in accordance with the process of the invention are useful in a variety of applications including resins, inks, paints, lubricants and fuels.Type: GrantFiled: November 21, 1985Date of Patent: April 25, 1989Assignee: Mooney Chemicals, Inc.Inventor: Paul L. Cells
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Patent number: 4816522Abstract: Halocarbons are readily bonded to a variety of substrates, including metals, polyolefins, styrenics, polyamides and thermoplastic polyesters, by treating the surface(s) to be bonded with a neoalkoxy zirconate compound. The articles produced by the aforesaid process resist delamination. Applicable fluorinated compounds include fluorinated polymers such as Teflon. The specific zirconate compound preferred is dependent on the particular substrate and the halogenated organic compound to be bonded. Preferred are organo-zirconates having the formula: ##STR1## wherein R, R.sup.1 and R.sup.2 are each monovalent hydrocarbon groups or substantive derivatives thereof; the A groups are independently selected from diester phosphates, diester pyrophosphates, oxyalkylamino, oxyalkylarylamino, or sulfonyl groups; B is an R'.sub.2 C group or a carbonyl group; R' is a hydrogen group or an alkyl group having from 1 to 6 carbon atoms; and n is 1 or 2.Type: GrantFiled: March 24, 1988Date of Patent: March 28, 1989Assignee: Kenrich PetrochemicalsInventors: Gerald Sugerman, Salvatore J. Monte
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Patent number: 4808739Abstract: Water-soluble N,N-bis-(2-hydroxyethyl)glycine/metal chelates represented by the formula: ##STR1## wherein R is H or alkyl (1-12C); M is Ti or Zr; k is a number in the range between 0 and 1, p is a number in the range between 1 and 2, and k+p=2 (in particular embodiments: k=1 and p=1; k=0 and p=2; and k=0.5 and p=1.5). The chelates can be used as crosslinking agents in hydraulic fracturing fluids and in gels that are used for selectively plugging permeable zones in subterranean formations or for plugging subterranean leaks.Type: GrantFiled: March 10, 1987Date of Patent: February 28, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventors: Donald E. Putzig, Kenneth C. Smeltz
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Patent number: 4748259Abstract: Mixtures of a metal salt of formula ##STR1## and a metal salt of formula ##STR2## in which formulae (1) and (2) Me is a metal ion of valency n,n is 2, 3 or 4, andeach of the rings A and B independently of the other is unsubstituted or substituted by halogen, lower alkyl, lower alkoxy or an .alpha.Type: GrantFiled: September 26, 1986Date of Patent: May 31, 1988Assignee: Ciba-Geigy CorporationInventor: Hermann Nachbur
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Patent number: 4745203Abstract: Mixtures of a metal salt of formula ##STR1## and a metal salt of formula ##STR2## in which formulae (1) and (2) Me is a metal ion of valency n,n is 2, 3 or 4, andeach of the rings A and B independently of the other is unsubstituted or substituted by halogen, lower alkyl, lower alkoxy or an .alpha.Type: GrantFiled: September 26, 1986Date of Patent: May 17, 1988Assignee: Ciba-Geigy CorporationInventor: Hermann Nachbur
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Patent number: 4730067Abstract: A process is described for the production of zirconium carboxylate comprising combining a carboxylate and a zirconium salt within a basic environment of a basic aqueous solution. The carboxylate is provided in an amount sufficient to give a ratio of carboxylate to zirconium equivalents in a range of from about 1.0:1.0 to 1.40:1.0 and the basic environment is provided by a basic salt in an amount sufficient to leave an excess of base after the combination of the zirconium salt and the carboxylate, whereupon the zirconium reacts in one step to form the zirconium carboxylate product.Type: GrantFiled: February 18, 1986Date of Patent: March 8, 1988Assignee: Akzo America IncorporatedInventors: Lawrence A. Filachek, Stanley E. Whitehead, deceased, by James M. Whitehead, executor
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Patent number: 4687869Abstract: The invention relates to metal salicylates of the formula ##STR1## wherein Me is a metal ion of valency n,n is 2, 3 or 4, andeach of the rings A and B independently of the other is unsubstituted or substituted by halogen, lower alkyl, lower alkoxy or an .alpha.-methylbenzyl radical.The metal salicylates are particularly suitable developers for the color former in pressure-sensitive or heat-sensitive recording materials.Type: GrantFiled: October 11, 1985Date of Patent: August 18, 1987Assignee: Ciba-Geigy CorporationInventor: Hermann Nachbur
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Patent number: 4633001Abstract: A process for preparing transition metal salt compositions of organic carboxylic acids having improved properties wherein the transition metal is one capable of having a multiplicity of oxidation states is described. The process comprises the steps of (a) providing at least one transition metal compound wherein the transition metal is at one of its higher positive oxidation states, (b) treating said transition metal compound with at least one reducing agent forming an intermediate containing the transition metal in a lower positive oxidation state, (c) reacting said intermediate with at least one organic carboxylic acid to form the transition metal salt of said carboxylic acid, and (d) mixing said transition metal salt formed in step (c) with (i) at least one antioxidant, or (ii) at least one additional metal salt wherein the additional metal is more electronegative than the transition metal, or (iii) mixtures of (i) and (ii).Type: GrantFiled: December 18, 1984Date of Patent: December 30, 1986Assignee: Mooney Chemicals, Inc.Inventor: Paul L. Cells
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Patent number: 4623738Abstract: A composition of matter comprising neoalkoxy compounds having the following formula: ##STR1## wherein M is titanium or zirconium, R, R.sup.1 and R.sup.2 are each a monovalent alkyl, alkenyl, alkynyl, aralkyl, aryl or alkaryl group having up to twenty carbon atoms or a halogen or ether substituted derivative thereof, and, in addition, R.sup.2 may also be an oxy derivative or an ether substituted oxy derivative of said groups; A, B, and C are each a monovalent aroxy, thioaroxy, diester phosphate, diester pyrophosphate, oxyalkylamino, sulfonyl or carboxyl containing up to 30 carbon atoms; and a+b+c=3.Type: GrantFiled: April 22, 1985Date of Patent: November 18, 1986Assignee: Kenrich Petrochemicals, Inc.Inventors: Gerald Sugerman, Salvatore J. Monte
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Patent number: 4614827Abstract: A method for isolating a vinyl salt compound in solid form from an aqueous solution thereof by spray drying such an aqueous salt solution.Type: GrantFiled: July 10, 1984Date of Patent: September 30, 1986Assignee: Rohm GmbHInventors: Peter J. Arndt, Franz Wenzel, Manfred Muller, Fritz Schlosser