Having -c(=x)x-, Are The Same Or Diverse Chalcogens, Attached Indirectly To The Metal By Nonionic Bonding (e.g., Dialkyl Tin Thioglycollic Acid Esters, Etc.) Patents (Class 556/93)
  • Publication number: 20140357883
    Abstract: A compound represented by formula I or II and a method for preparing the same. The method includes: a) adding isooctyl mercaptopropionate to a reactor, adding dropwise an aqueous solution of methyltin chloride, stirring and allowing for a complete reaction, and adding aqueous ammonia, an aqueous solution of sodium hydroxide, an aqueous solution of sodium bicarbonate, an aqueous solution of sodium carbonate, or a solution of an organic base to regulate the pH value of a resulting mixture from a starting value of between 2 and 8 to an end value of between 6 and 10 for a primary stage of esterification; and b) allowing a product obtained from step a) to proceed to a secondary stage of the esterification, allowing the product to stand until phases are separated, collecting and washing an organic phase using deionized water, allowing a resulting mixture to stand until phases are separated.
    Type: Application
    Filed: May 5, 2014
    Publication date: December 4, 2014
    Applicant: Yunnan Tin Company Limited
    Inventors: Yinghui Guo, Laoyong YAN, Baoliang ZHAO, Qiangshun YI, Bing WEI, Xiangyan LI, Shu CHEN, Fuliang DUAN
  • Patent number: 8088937
    Abstract: Disclosed herein are compounds of the formula: (R)x—Sn—(R?)4-x wherein: R is alkyl; R? is a moiety selected from the group consisting of: w is 0 or 1; x is 1 or 2; y is 1, 2, 3, or 4; and Z is a linear, branched, cyclic, or aromatic hydrocarbon. These compounds are excellent stabilizers for halogen-containing resins, such as PVC.
    Type: Grant
    Filed: July 8, 2010
    Date of Patent: January 3, 2012
    Assignee: Galata Chemicals, LLC
    Inventors: Edward Krainer, Peter Frenkel
  • Publication number: 20100298589
    Abstract: Disclosed herein are compounds of the formula: (R)x—Sn—(R?)4-x wherein: R is alkyl; R? is a moiety selected from the group consisting of: w is 0 or 1; x is 1 or 2; y is 1, 2, 3, or 4; and Z is a linear, branched, cyclic, or aromatic hydrocarbon. These compounds are excellent stabilizers for halogen-containing resins, such as PVC.
    Type: Application
    Filed: July 8, 2010
    Publication date: November 25, 2010
    Applicant: Galata Chemicals, LLC
    Inventors: Edward Krainer, Peter Frenkel
  • Patent number: 6919392
    Abstract: The heat and light stability imparted to vinyl halide polymers by metal compounds conventionally employed for this purpose is considerably improved by the presence of a mercapto ester such as 2-mercaptoethyl stearate. The esters can replace a substantial portion of the metal compound with no significant reduction in stability.
    Type: Grant
    Filed: April 20, 1992
    Date of Patent: July 19, 2005
    Assignee: Arkema Inc.
    Inventors: Jean-Yves Chenard, Jean-Claude Mendelsohn
  • Patent number: 6627765
    Abstract: Novel ligated compounds of tin, titanium, and zinc are useful as metal oxide CVD precursor compounds without the detriments of extreme reactivity yet maintaining the ability to produce high quality metal oxide coating by contact with heated substrates.
    Type: Grant
    Filed: May 21, 2002
    Date of Patent: September 30, 2003
    Assignee: First Solar, LLC
    Inventor: Dean M. Giolando
  • Publication number: 20030108676
    Abstract: A glass coating agent is provided which is adapted for application onto the surface of a glass substrate and, upon heating, forms a metal oxide layer.
    Type: Application
    Filed: November 26, 2002
    Publication date: June 12, 2003
    Applicants: KIRIN BEER KABUSHIKI KAISHA, NITTO KASEI CO., LTD.
    Inventors: Eihaku Shimamura, Katsuhiro Imashita, Tsutomu Amano, Tatsuya Nagai, Takayuki Okada, Hitoshi Tabuchi, Masaaki Katayama
  • Patent number: 6531618
    Abstract: The invention relates to a process for preparing water-soluble organotin catalysts by contacting organotin compounds with polyelectrolytes and, optionally, subsequently removing the water.
    Type: Grant
    Filed: May 25, 2000
    Date of Patent: March 11, 2003
    Assignee: Crompton GmbH
    Inventors: Oliver Schumacher, Ursula Gerigk
  • Patent number: 5532272
    Abstract: A novel, eight structural polymer of 2-oxygermylpropionic acid having an empirical formula of C.sub.6 H.sub.10 Ge.sub.2 O.sub.7, a minimum constitutional unit of (O.sub.1/2).sub.3 GeCH.sub.2 CH.sub.2 COOH and the following stereostructure: ##STR1## wherein R stands for --CH.sub.2 CH.sub.2 COOH and m is an integer of 137.+-.84. A pharmaceutical composition containing the novel polymer is useful for preventing symptoms of an immune disease such as hepatitis or for curing such a disease.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: July 2, 1996
    Assignee: Sanwa Kagaku Kenkyusho Co., Ltd.
    Inventors: Kiichi Sawai, Takahiko Mitani, Naohisa Ninomiya, Yoshirou Ishiwata
  • Patent number: 5354508
    Abstract: An organotin stabilizer mixture comprising: (a) monoalkyltin mercaptoalcohol (b) a monoalkyltin mercaptoacid ester; and (c) a monoalkyltin sulfide provides improved early color, lubricity, and weatherability to rigid vinyl polymer formulations. The formulation may also contain a monoalkyltin mercaptoalcohol ester as an optional component.
    Type: Grant
    Filed: December 1, 1993
    Date of Patent: October 11, 1994
    Assignee: Akzo Nobel N.V.
    Inventors: Donald F. Anderson, Steven Walter
  • Patent number: 5021491
    Abstract: Compounds of the formula I ##STR1## in which R is C.sub.8 -C.sub.14 alkyl, phenyl, C.sub.7 -C.sub.9 aralkyl or R"OOC-CH.sub.2 --CH.sub.2, R' is C.sub.2 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl, C.sub.7 -C.sub.30 alkaryl or C.sub.7 -C.sub.18 -aralkyl and R" is C.sub.1 -C.sub.14 alkyl, phenyl or C.sub.7 -C.sub.9 aralkyl and x is 1 or 2, are heat stabilizers for chlorine-containing thermoplastics, in particular for PVC.
    Type: Grant
    Filed: March 1, 1990
    Date of Patent: June 4, 1991
    Assignee: Ciba-Geigy Corporation
    Inventor: Gerd Abeler
  • Patent number: 4916247
    Abstract: Organometal-containing styrene derivatives of the formula I ##STR1## in which, for example, M is Si, X is 0, R.sup.1 and R.sup.2 are hydrogen, R.sup.4 to R.sup.6 are each methyl, a is zero and R.sup.7 is hydrogen or methyl, and organometal-containing compounds of the formula VII ##STR2## in which M and R.sup.1 to R.sup.6 are, for example, as defined above and Y is, for example, 4-nitrophenoxy, are valuable starting materials for the preparation of organometal-containing polymers. The polymers are suitable for the preparation of photoresists which can be developed under dry conditions, such as are required in the production of structured images, particularly in microelectronics.
    Type: Grant
    Filed: August 29, 1988
    Date of Patent: April 10, 1990
    Assignee: Ciba-Geigy Corporation
    Inventor: Alfred Steinmann
  • Patent number: 4834992
    Abstract: Organotin stabilizer compositions containing more than 5 percent by weight of monoalkyl tin derivatives of mercaptoacetic acid esters, such as mono-n-octyltin-S,S',S"-tris(isooctyl mercaptoacetate), are useful as food-grade stabilizers for vinyl halide polymers.
    Type: Grant
    Filed: February 6, 1987
    Date of Patent: May 30, 1989
    Assignee: M&T Chemicals, Inc.
    Inventor: William A. Larkin
  • Patent number: 4795820
    Abstract: A method of manufacture of tinorganic compounds.
    Type: Grant
    Filed: September 12, 1986
    Date of Patent: January 3, 1989
    Assignees: Politchnika Warszawska, Zaklady Tworzyw Sztucznych "Boryszew-Erg"
    Inventors: Ludwik Synoradzki, Jacek Lasota, Boguslaw Zielinski, Andrzej Kasprzak, Maciej Uninski, Bogdan Siwanowicz, Tomasz Dluzniewski, Andrzej Gieysztor, Roman Zadrozny, Andrzej Smyk, Andrzej Pazgan, Irena Dobosz, Teresa Brzozowska-Janiak, Zdzislaw Szawlowski, Ireneusz Dusinski
  • Patent number: 4711920
    Abstract: Compositions for stabilizing halogen-containing organic polymers against the deteriorative effects of heat, light and weathering and which are non-irritating to eyes and mucous membranes, comprise the reaction product produced by combining an organotin oxide, an ethylenically unsaturated dicarboxylic acid ester and a mercaptan, wherein the chemical equivalence of the mercaptan is less than the chemical equivalence of the diorganotin oxide and the chemical equivalence of the diorganotin oxide is less than the chemical equivalence of the ester compound.
    Type: Grant
    Filed: July 23, 1986
    Date of Patent: December 8, 1987
    Assignee: Morton Thiokol, Inc.
    Inventors: Thomas G. Kugele, Keith A. Mesch, Karl R. Wursthorn, Gary M. Conroy
  • Patent number: RE32935
    Abstract: Vinyl chloride polymers suitable for use in food packaging materials are stabilized against discoloration and embrittlement resulting from exposure to heat using mono-n-octyltin compounds of the general formula H.sub.17 C.sub.8 Sn(SCH.sub.2 COOR').sub.3, wherein R' represents an alkyl radical containing eight carbon atoms.
    Type: Grant
    Filed: November 15, 1985
    Date of Patent: May 30, 1989
    Assignee: M&T Chemicals, Inc.
    Inventor: William A. Larkin