Having -c(=x)x-, Are The Same Or Diverse Chalcogens, Attached Indirectly To The Metal By Nonionic Bonding (e.g., Dialkyl Tin Thioglycollic Acid Esters, Etc.) Patents (Class 556/93)
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Publication number: 20140357883Abstract: A compound represented by formula I or II and a method for preparing the same. The method includes: a) adding isooctyl mercaptopropionate to a reactor, adding dropwise an aqueous solution of methyltin chloride, stirring and allowing for a complete reaction, and adding aqueous ammonia, an aqueous solution of sodium hydroxide, an aqueous solution of sodium bicarbonate, an aqueous solution of sodium carbonate, or a solution of an organic base to regulate the pH value of a resulting mixture from a starting value of between 2 and 8 to an end value of between 6 and 10 for a primary stage of esterification; and b) allowing a product obtained from step a) to proceed to a secondary stage of the esterification, allowing the product to stand until phases are separated, collecting and washing an organic phase using deionized water, allowing a resulting mixture to stand until phases are separated.Type: ApplicationFiled: May 5, 2014Publication date: December 4, 2014Applicant: Yunnan Tin Company LimitedInventors: Yinghui Guo, Laoyong YAN, Baoliang ZHAO, Qiangshun YI, Bing WEI, Xiangyan LI, Shu CHEN, Fuliang DUAN
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Patent number: 8088937Abstract: Disclosed herein are compounds of the formula: (R)x—Sn—(R?)4-x wherein: R is alkyl; R? is a moiety selected from the group consisting of: w is 0 or 1; x is 1 or 2; y is 1, 2, 3, or 4; and Z is a linear, branched, cyclic, or aromatic hydrocarbon. These compounds are excellent stabilizers for halogen-containing resins, such as PVC.Type: GrantFiled: July 8, 2010Date of Patent: January 3, 2012Assignee: Galata Chemicals, LLCInventors: Edward Krainer, Peter Frenkel
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Publication number: 20100298589Abstract: Disclosed herein are compounds of the formula: (R)x—Sn—(R?)4-x wherein: R is alkyl; R? is a moiety selected from the group consisting of: w is 0 or 1; x is 1 or 2; y is 1, 2, 3, or 4; and Z is a linear, branched, cyclic, or aromatic hydrocarbon. These compounds are excellent stabilizers for halogen-containing resins, such as PVC.Type: ApplicationFiled: July 8, 2010Publication date: November 25, 2010Applicant: Galata Chemicals, LLCInventors: Edward Krainer, Peter Frenkel
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Patent number: 6919392Abstract: The heat and light stability imparted to vinyl halide polymers by metal compounds conventionally employed for this purpose is considerably improved by the presence of a mercapto ester such as 2-mercaptoethyl stearate. The esters can replace a substantial portion of the metal compound with no significant reduction in stability.Type: GrantFiled: April 20, 1992Date of Patent: July 19, 2005Assignee: Arkema Inc.Inventors: Jean-Yves Chenard, Jean-Claude Mendelsohn
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Patent number: 6627765Abstract: Novel ligated compounds of tin, titanium, and zinc are useful as metal oxide CVD precursor compounds without the detriments of extreme reactivity yet maintaining the ability to produce high quality metal oxide coating by contact with heated substrates.Type: GrantFiled: May 21, 2002Date of Patent: September 30, 2003Assignee: First Solar, LLCInventor: Dean M. Giolando
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Publication number: 20030108676Abstract: A glass coating agent is provided which is adapted for application onto the surface of a glass substrate and, upon heating, forms a metal oxide layer.Type: ApplicationFiled: November 26, 2002Publication date: June 12, 2003Applicants: KIRIN BEER KABUSHIKI KAISHA, NITTO KASEI CO., LTD.Inventors: Eihaku Shimamura, Katsuhiro Imashita, Tsutomu Amano, Tatsuya Nagai, Takayuki Okada, Hitoshi Tabuchi, Masaaki Katayama
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Patent number: 6531618Abstract: The invention relates to a process for preparing water-soluble organotin catalysts by contacting organotin compounds with polyelectrolytes and, optionally, subsequently removing the water.Type: GrantFiled: May 25, 2000Date of Patent: March 11, 2003Assignee: Crompton GmbHInventors: Oliver Schumacher, Ursula Gerigk
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Patent number: 5532272Abstract: A novel, eight structural polymer of 2-oxygermylpropionic acid having an empirical formula of C.sub.6 H.sub.10 Ge.sub.2 O.sub.7, a minimum constitutional unit of (O.sub.1/2).sub.3 GeCH.sub.2 CH.sub.2 COOH and the following stereostructure: ##STR1## wherein R stands for --CH.sub.2 CH.sub.2 COOH and m is an integer of 137.+-.84. A pharmaceutical composition containing the novel polymer is useful for preventing symptoms of an immune disease such as hepatitis or for curing such a disease.Type: GrantFiled: May 20, 1994Date of Patent: July 2, 1996Assignee: Sanwa Kagaku Kenkyusho Co., Ltd.Inventors: Kiichi Sawai, Takahiko Mitani, Naohisa Ninomiya, Yoshirou Ishiwata
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Patent number: 5354508Abstract: An organotin stabilizer mixture comprising: (a) monoalkyltin mercaptoalcohol (b) a monoalkyltin mercaptoacid ester; and (c) a monoalkyltin sulfide provides improved early color, lubricity, and weatherability to rigid vinyl polymer formulations. The formulation may also contain a monoalkyltin mercaptoalcohol ester as an optional component.Type: GrantFiled: December 1, 1993Date of Patent: October 11, 1994Assignee: Akzo Nobel N.V.Inventors: Donald F. Anderson, Steven Walter
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Patent number: 5021491Abstract: Compounds of the formula I ##STR1## in which R is C.sub.8 -C.sub.14 alkyl, phenyl, C.sub.7 -C.sub.9 aralkyl or R"OOC-CH.sub.2 --CH.sub.2, R' is C.sub.2 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl, C.sub.7 -C.sub.30 alkaryl or C.sub.7 -C.sub.18 -aralkyl and R" is C.sub.1 -C.sub.14 alkyl, phenyl or C.sub.7 -C.sub.9 aralkyl and x is 1 or 2, are heat stabilizers for chlorine-containing thermoplastics, in particular for PVC.Type: GrantFiled: March 1, 1990Date of Patent: June 4, 1991Assignee: Ciba-Geigy CorporationInventor: Gerd Abeler
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Patent number: 4916247Abstract: Organometal-containing styrene derivatives of the formula I ##STR1## in which, for example, M is Si, X is 0, R.sup.1 and R.sup.2 are hydrogen, R.sup.4 to R.sup.6 are each methyl, a is zero and R.sup.7 is hydrogen or methyl, and organometal-containing compounds of the formula VII ##STR2## in which M and R.sup.1 to R.sup.6 are, for example, as defined above and Y is, for example, 4-nitrophenoxy, are valuable starting materials for the preparation of organometal-containing polymers. The polymers are suitable for the preparation of photoresists which can be developed under dry conditions, such as are required in the production of structured images, particularly in microelectronics.Type: GrantFiled: August 29, 1988Date of Patent: April 10, 1990Assignee: Ciba-Geigy CorporationInventor: Alfred Steinmann
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Patent number: 4834992Abstract: Organotin stabilizer compositions containing more than 5 percent by weight of monoalkyl tin derivatives of mercaptoacetic acid esters, such as mono-n-octyltin-S,S',S"-tris(isooctyl mercaptoacetate), are useful as food-grade stabilizers for vinyl halide polymers.Type: GrantFiled: February 6, 1987Date of Patent: May 30, 1989Assignee: M&T Chemicals, Inc.Inventor: William A. Larkin
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Patent number: 4795820Abstract: A method of manufacture of tinorganic compounds.Type: GrantFiled: September 12, 1986Date of Patent: January 3, 1989Assignees: Politchnika Warszawska, Zaklady Tworzyw Sztucznych "Boryszew-Erg"Inventors: Ludwik Synoradzki, Jacek Lasota, Boguslaw Zielinski, Andrzej Kasprzak, Maciej Uninski, Bogdan Siwanowicz, Tomasz Dluzniewski, Andrzej Gieysztor, Roman Zadrozny, Andrzej Smyk, Andrzej Pazgan, Irena Dobosz, Teresa Brzozowska-Janiak, Zdzislaw Szawlowski, Ireneusz Dusinski
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Patent number: 4711920Abstract: Compositions for stabilizing halogen-containing organic polymers against the deteriorative effects of heat, light and weathering and which are non-irritating to eyes and mucous membranes, comprise the reaction product produced by combining an organotin oxide, an ethylenically unsaturated dicarboxylic acid ester and a mercaptan, wherein the chemical equivalence of the mercaptan is less than the chemical equivalence of the diorganotin oxide and the chemical equivalence of the diorganotin oxide is less than the chemical equivalence of the ester compound.Type: GrantFiled: July 23, 1986Date of Patent: December 8, 1987Assignee: Morton Thiokol, Inc.Inventors: Thomas G. Kugele, Keith A. Mesch, Karl R. Wursthorn, Gary M. Conroy
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Patent number: RE32935Abstract: Vinyl chloride polymers suitable for use in food packaging materials are stabilized against discoloration and embrittlement resulting from exposure to heat using mono-n-octyltin compounds of the general formula H.sub.17 C.sub.8 Sn(SCH.sub.2 COOR').sub.3, wherein R' represents an alkyl radical containing eight carbon atoms.Type: GrantFiled: November 15, 1985Date of Patent: May 30, 1989Assignee: M&T Chemicals, Inc.Inventor: William A. Larkin